At Least One Diverse Hetero Atom In Same Ring Patents (Class 524/95)
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Patent number: 7235663Abstract: The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.Type: GrantFiled: November 12, 2001Date of Patent: June 26, 2007Assignee: Ciba Specialty Chemicals Corp.Inventors: Francesco Fuso, Wiebke Wunderlich, Andreas Kramer, Jochen Fink
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Patent number: 7214742Abstract: Compounds of the general formula I? in which R1 is H, C1–C12alkyl; C5–C12cycloalkyl; C2–C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III R2, R21 and R3 independently of one another, are H or —Y—T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.Type: GrantFiled: November 21, 2002Date of Patent: May 8, 2007Assignee: Ciba Specialty Chemicals Corp.Inventors: Thomas Bolle, Andreas Valet, David George Leppard, Stephen Mark Andrews, Ramanathan Ravichandran, Markus Grob, Dirk Simon
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Patent number: 7176260Abstract: The invention is the manipulation of the zinc oxide content and sulfur content of nitrile butadiene rubbers and selected vulcanization conditions that can be achieved economically with common production facilities. The manipulation of these components affects the relaxation property of gloves formed by this material. Produced are gloves that have a relaxation property, higher than 50%, and a low modulus (approximately 3 Mpa). The glove maintains decent ultimate tensile strength (>20 Mpa) and elongation (>500%). The glove is produced by a vulcanization process, which lasts from 5 to 60 minutes at temperatures ranging from 300° F. to 400° F. The tensile strength and elongation are well above the ASTM requirements for medical gloves. The current ASTM requirements are ASTM D412-92. Thanks to sufficient vulcanization, the films produced provide satisfactory protection from viral penetration. The tearing strength is also better because of the lower modulus.Type: GrantFiled: January 13, 2004Date of Patent: February 13, 2007Assignee: Microflex CorporationInventor: Jian Tao
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Patent number: 7133209Abstract: A molding composition which is composed of at least 60% by weight of transparent polyamide, where the molding composition comprises an effective amount of one or more optical brighteners, and where the amount of the optical brightener has been judged in such a way that a) the b value, which is a measure of yellowness, is at most 7, and moreover b) between 370 and 430 nm, at least in a lower part of the range, the transmittance is smaller than 1%, measured at a layer thickness of 4 mm, can be processed to give products which are substantially impermeable to UV light.Type: GrantFiled: February 24, 2004Date of Patent: November 7, 2006Assignee: Degussa AGInventors: Roland Wursche, Dagmar Kaufhold, Berthold Teloeken
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Patent number: 7094818Abstract: The present invention relates to a flame retardant polycarbonate thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified vinyl-grafted copolymer, a phosphorous mixture of a cyclic phosphazene oligomer compound and a phosphoric acid ester as a flame retardant, and a fluorinated polyolefin resin.Type: GrantFiled: November 7, 2001Date of Patent: August 22, 2006Assignee: Cheil Industries, Inc.Inventors: Jong Cheol Lim, Sang Hyun Hong, Kyung Hoon Seo, Sam Joo Yang
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Patent number: 7008985Abstract: An aerosol solvent weld cement composition for joining ends of plastic pipe. The composition contains at least one polymer capable of welding the plastic pipes to each other, at least one solvent for the polymer, and at least one propellant for the polymer/solvent solution. The composition is maintained under pressure greater than atmospheric pressure in an aerosol container. A female omnidirectional valve is disclosed for use in the aerosol container. This valve allows the solvent weld cement composition to be applied to pipes from any angle.Type: GrantFiled: August 21, 2003Date of Patent: March 7, 2006Inventor: Ronald D. Green
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Patent number: 7005460Abstract: The present invention relates to a multi-component system for making impressions which contains (a) at least one compound having at least two alkenyl groups; (b) at least one organohydrogenpolysiloxane; (c) at least one hydrosilylation catalyst; characterized by containing (d1) at least one polymeric compound having at least one alkynyl group and/or (d2) at least one compound having at least one Si—OR structural unit, wherein R=H, alkyl, alkoxyalkyl or acyl; and when a compound (d2) having at least one Si—OR structural unit is contained, (e) at least one condensation catalyst and/or condensation cross-linking agent. After the mixing of the components, the materials according to the invention cure in two steps.Type: GrantFiled: January 24, 2002Date of Patent: February 28, 2006Assignee: Kettenbach GmbH & Co. KGInventors: Alexander Bublewitz, Jens-Peter Reber, Ulrich Nagel
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Patent number: 6992124Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprising A) at least one component from the group of peroxide-destroying phosphorus or sulfur compounds, B) at least one component from the group of phenolic antioxidants, C) at least one component from the group of sterically hindered amines, and D) if desired, further additives. Using this additive mixture prevents sticking to the hot roll surfaces and reduces the degradation of the polymer.Type: GrantFiled: February 3, 1999Date of Patent: January 31, 2006Assignee: Clariant GmbHInventors: Christian Wick, Gerhard Pfahler, Alexander Lichtblau
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Patent number: 6902760Abstract: Aqueous bonding agents based on at least one phenolic resin, at least one aromatic dinitroso compound and a polyvinyl alcohol are suitable as a one-coat aqueous rubber-metal bonding agent to achieve permanent rubber-metal bonds. These bonding agents can be substantially free from organic solvents and halogen compounds, and allow one-coat application without an additional, previous application of a primer.Type: GrantFiled: June 13, 2003Date of Patent: June 7, 2005Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rainer Wefringhaus, Hans-Joachim Purps
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Patent number: 6869992Abstract: A stabilizer mixture containing (A) a sterically hindered amine compound, and (B) a polymer containing polar residues, the weight ratio of components (A) (B) being 20:1 to 1:20, with the provisos that, (1) component (B) is different from component (A) and does not contain groups of formulae (I) or (II) in which G is hydrogen or methyl, and G1 and G2, independently of one another, are hydrogen, methyl or together are a substituent ?O; and (2) component (B) is different from a polymer having an acidic hydrogen atom.Type: GrantFiled: February 15, 2001Date of Patent: March 22, 2005Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus
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Patent number: 6863844Abstract: Photochromic compositions are disclosed herein. The compositions comprise mixtures of methacrylate monomers, which when polymerized, provide a polymer matrix that exhibits improved fading characteristics of incorporated photochromic dyes and good photochromic temperature stability. The compositions are particularly useful as a composite layer on polymer-based ophthalmic lenses.Type: GrantFiled: August 30, 2002Date of Patent: March 8, 2005Assignee: Signet Armorlite, Inc.Inventors: Thomas J. Engardio, Paul D. Schlunt
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Patent number: 6858290Abstract: Microporous articles formed by thermally induced phase separation from a diluent in combination with a thermoplastic polymer and a fluorochemical additive providing novel fluid repellent articles. Such articles are useful in clothing, barrier membranes, optical films in electronic devices (such as light reflective and dispersive films), and protective garments.Type: GrantFiled: May 29, 2002Date of Patent: February 22, 2005Assignee: 3M Innovative Properties CompanyInventors: James S. Mrozinski, Chetan P. Jariwala
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Patent number: 6855435Abstract: A transparent film whose thickness is in the range from 1 to 500 ?m and which comprises, as principal constituent, a crystallizable thermoplastic, wherein the film comprises at least one UV stabilizer as light stabilizer and at least one optical brightener, and to the use of the film, and also to a process for its production.Type: GrantFiled: May 2, 2003Date of Patent: February 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Guenther Crass, Guenter Bewer, Klaus Oberlaender
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Patent number: 6855758Abstract: The invention relates to transparent, biaxially oriented and heat-set films having one or more layers and compris, as main constituent, at least one crystallizable thermoplastic, in particular a polyester, and also comprise at least one hydrolysis stabilizer. The hydrolysis stabilizer is preferably a phenolic compound, an oxazoline, and/or a monomeric or polymeric carbodiimide, where appropriate combined with an organic phosphite. It is preferably added in the form of a masterbatch. The film exhibits low longitudinal and transverse shrinkage. On exposure to moisture and heat it shows practically no embrittlement and retains its ultimate tensile strength. The additional functionality is preferably that the film has been made UV-resistant, or flame-retardant, or on one side or on both sides has been coated, or is sealable, and/or has been corona- or flame-treated.Type: GrantFiled: June 15, 2001Date of Patent: February 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Thorsten Kiehne, Harald Hessberger
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Patent number: 6849116Abstract: Quinophthalone derivatives have the general formula I where R1, R2, R3 and R5 are independently hydrogen, halogen or C1-C4-alkyl; R4 is —SO3H, —SO3+N+R6R7R8R9, —SO2NR6R7, —CH2NR6R7, —CH2R10, —COOH, —COO?N+R6R7R8R9, —COOR11, —COR11, —NO2 or C1-C4-alkyl; R6, R7, R8 and R9 are independently hydrogen; C1-C22-alkyl or C2-C22-alkenyl whose carbon chains may be interrupted by one or more moieties selected from the group consisting of —O—, —S—, —NR12—, —CO— and —SO2— and/or which may each be mono- or polysubstituted by hydroxyl, halogen, aryl, C1-C4-alkoxy and/or acetyl; C3-C8-cycloalkyl whose carbon skeleton may be interrupted by one or more moieties selected from the group consisting of —O—, —S—, —NR12— and —CO— and/or which may be mono- or polysubstituted by hydroxyl, halogen, aryl, C1-C4-alkoxy and/or acetyl; dehydroabietyl or aryl; R6 and R7 or R6, R7 and R8 are together a 5- to 7-membered cyclic radical which includes the nitrogen atom and may include further heteroatoms; R10 is R11 is alkyl R6; R12 isType: GrantFiled: June 22, 2001Date of Patent: February 1, 2005Assignee: BASF AktiengesellschaftInventors: Jianing He, Manfred Schröck
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Patent number: 6841598Abstract: A quaternary onium aromatic sulfonate represented by the formula: wherein each R1 independently comprises substituted or unsubstituted, aliphatic or aromatic, hydrocarbyl, carbocyclic or heterocyclic radicals, each X is selected from the group consisting of phosphorus and nitrogen; wherein “a” has a value of 0, 1 or 2, and “b” has a value of 0 or 1 with the proviso that (a+b) is equal to 1 or 2; G1 is an aromatic group; E comprises a bis(carbonyloxyalkyl) polydiorganosiloxane, a bis (carbonyloxyaryl) polydiorganosiloxane, and an ether linkage; each Y independently comprises hydrogen, a monovalent hydrocarbon group, alkenyl, allyl, halogen, bromine, chlorine; nitro; and OR, wherein R is a monovalent hydrocarbon group; “q” represents any integer from and including zero through the number of positions on G1 available for substitution; “t” represents an integer equal to at least one; “s” represents an integer equal to either zero or one; and “u” represents any integer including zero; with the proviso that wheType: GrantFiled: August 16, 2002Date of Patent: January 11, 2005Assignee: General Electric CompanyInventors: Sanjoy Kumar Chowdhury, Prakash P. Wadgaonkar, Theodorus Lambertus Hoeks, Alex Bernard Scholten, Suresh K. Rajaraman, Bhimrao D. Sarwade, Chilukuri Ver Avadhani
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Patent number: 6835424Abstract: A marking composition includes a polymerizable first material that comprises silicon and a second material capable of extending polymeric chains of the first material, wherein the marking composition is capable of undergoing a change that can be detected optically when the composition is contacted with energy.Type: GrantFiled: March 3, 2003Date of Patent: December 28, 2004Assignee: Markem CorporationInventors: Richard J. Larson, Jr., Michael P. Secord, Richard C. Woudenberg, Jr.
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Patent number: 6835457Abstract: A marking composition includes a polymerizable first material that comprises silicon and a second material capable of extending polymeric chains of the first material, wherein the marking composition is capable of undergoing a change that can be detected optically when the composition is contacted with energy.Type: GrantFiled: May 15, 2001Date of Patent: December 28, 2004Assignee: Markem CorporationInventors: Richard J. Larson, Jr., Michael P. Secord, Richard C. Woudenberg, Jr.
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Patent number: 6833405Abstract: Excellent tracking index as well as flame-resistant properties are achieved with other desirable characteristics of LCPs in a resin composition consisting essentially of: a) a wholly aromatic polyester which is melt processible and which displays anisotropy in the molten state; b) a non-conductive filler material having a diameter of less than about 3 m, with said non-conductive filler material being present in an amount sufficient to increase the comparative tracking index (CTI) rating of said composition to above 220 volts and render the composition non-burning. Optionally, an extraordinarily small amount of non-volatile fluorescent brightener can be added to the resin composition. In combination with the non-conductive filler, the fluorescent brightener is found to surprisingly and significantly improves the flame-retardant property of the resin. Such compositions are advantageously employed in electrical and electronic apparatuses.Type: GrantFiled: July 5, 2000Date of Patent: December 21, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Steve Gust Cottis
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Publication number: 20040249027Abstract: The present invention relates to a flame retardant polycarbonate thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified vinyl-grafted copolymer, a phosphorous mixture of a cyclic phosphazene oligomer compound and a phosphate ester morpholide compound as a flame retardant, and a fluorinated polyolefin resin, which has good flame retardancy, heat resistance, mechanical strength, impact strength, heat stability, processability, and appearance.Type: ApplicationFiled: March 12, 2004Publication date: December 9, 2004Applicant: CHEIL INDUSTRIES INC.Inventors: Jong Cheol Lim, Kyung Hoon Seo, Sam Joo Yang
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Patent number: 6828364Abstract: A stabilizer mixture containing (I) two different sterically hindered amine compounds, and (II) at least one compound selected from the group consisting of an organic salt of Zn, an inorganic salt of Zn, Zn oxide, Zn hydroxide, an organic salt of Mg, an inorganic salt of Mg, Mg oxide and Mg hydroxide.Type: GrantFiled: July 5, 2001Date of Patent: December 7, 2004Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus
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Publication number: 20040186206Abstract: A polishing composition comprising silica particles, polymer particles and a cationic compound in an aqueous medium; a polishing process for a substrate for a precision part with the polishing composition as defined above; a method for planarization of a substrate for a precision part, including the step of polishing the substrate for a precision part with the polishing composition as defined above; and a method for planarization of a substrate for a precision part, including the steps of polishing the substrate for a precision part with the polishing composition as defined above, the polishing composition being a first polishing composition, with applying a polishing load of 50 to 1000 hPa, and polishing the substrate after the first step with a second polishing composition comprising silica particles in an aqueous medium with applying a polishing load of 50 to 1000 hPa.Type: ApplicationFiled: December 22, 2003Publication date: September 23, 2004Inventors: Yasuhiro Yoneda, Shigeaki Takashina, Toshiya Hagihara
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Publication number: 20040176512Abstract: The invention is the manipulation of the zinc oxide content and sulfur content of nitrile butadiene rubbers and selected vulcanization conditions that can be achieved economically with common production facilities. The manipulation of these components affects the relaxation property of gloves formed by this material. Produced are gloves that have a relaxation property, higher than 50%, and a low modulus (approximately 3 Mpa). The glove maintains decent ultimate tensile strength (>20 Mpa) and elongation (>500%). The glove is produced by a vulcanization process, which lasts from 5 to 60 minutes at temperatures ranging from 300° F. to 400° F. The tensile strength and elongation are well above the ASTM requirements for medical gloves. The current ASTM requirements are ASTM D412-92. Thanks to sufficient vulcanization, the films produced provide satisfactory protection from viral penetration. The tearing strength is also better because of the lower modulus.Type: ApplicationFiled: January 13, 2004Publication date: September 9, 2004Inventor: Jian Tao
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Patent number: 6783859Abstract: An epoxy resin composition comprising an epoxy resin, a phenolic resin curing agent, an inorganic filler, zinc molybdate on an inorganic support, and a complementary combination of two phosphazene compounds is effectively moldable, flame retardant and suitable for semiconductor encapsulation. A semiconductor device encapsulated with the cured epoxy resin composition is improved in flame retardance and moisture-proof reliability.Type: GrantFiled: February 5, 2003Date of Patent: August 31, 2004Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Shoichi Osada, Shingo Ando, Hiroyuki Takenaka, Kazutoshi Tomiyoshi, Toshio Shiobara
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Patent number: 6770710Abstract: The process comprises: (1) the preparation of a mixture comprising at least one organic monomer Z with a C═C group, polymerizable by a radical process, at least one organic photochromic compound, at least one surfactant, water and optionally a polymerization primer; (2) the treatment of the mixture obtained in step (1) in order to form a miniemulsion consisting of an organic phase dispersed in the form of droplets having a diameter of 50 to 500 nm, and preferably 50 to 300 nm, in an aqueous phase; (3) the addition to the miniemulsion of a polymerization primer, if this latter was not introduced in step (1), or of a quantity of primer additional to that added in step (1); (4) the polymerization of the reaction mixture obtained in step (3), and (5) the recovery of the photochromic latex.Type: GrantFiled: November 16, 2001Date of Patent: August 3, 2004Assignee: Essilor International Compagnie Generale d'OptiqueInventors: Anne Robert, Pascale Tardieu, Sylvette Maisonnier, Jean-Paul Cano
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Patent number: 6767940Abstract: A golf ball comprising a core, a cover, and optionally an intermediate layer between the core and the cover, wherein a stable free radical is incorporated into at least one portion of the core, the cover, and the optional intermediate layer.Type: GrantFiled: July 25, 2002Date of Patent: July 27, 2004Assignee: Acushnet CompanyInventors: Peter R. Voorheis, David A. Bulpett
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Publication number: 20040044142Abstract: 0.3-5.0 parts by weight of phenol resin, sulfur, and vulcanizing accelerator are added to 100 parts by weight of EPDM rubber. They are kneaded, and the EPDM rubber is vulcanized and molded. Generation of blooming can be suppressed without inhibiting the vulcanizing speed and the vulcanizing start timing.Type: ApplicationFiled: June 10, 2003Publication date: March 4, 2004Applicant: Sumitomo Rubber Industries, Ltd.Inventor: Kenichi Uesaka
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Publication number: 20040019137Abstract: The invention concerns a stabilising composition for halogenated polymer comprising at least a compound of formulae (I) and/or (II), wherein: X, Y, Z, identical or different, represent an oxygen atom, a nitrogen atom, a sulphur atom, or a phosphorus atom; R1 represents a radical comprising 1 to 20 carbon atoms; R2 represents a hydrogen atom, a radical comprising 1 to 20 carbon atoms, a —COR radical; R1 and R2 are optionally mutually bound so as to form a cycle; R3 and R4, identical or different, represent a hydrogen atom, a radical comprising 1 to 20 carbon atoms; n=1 depending on the valence of X, m=0 to 2 depending on the valence of Y; p=0 to 2 depending on the valence of Z; q is an integer between 1 and 10, preferably between 1 and 4.Type: ApplicationFiled: June 4, 2003Publication date: January 29, 2004Inventor: Dominique Hebrault
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Publication number: 20030216494Abstract: The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.Type: ApplicationFiled: November 5, 2002Publication date: November 20, 2003Inventors: Michael Roth, Rudolf Pfaendner, Peter Nesvadba, Marie-Odile Zink
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Publication number: 20030187107Abstract: The present invention provides an epoxy resin composition for encapsulation of semiconductors which contains substantially neither halogen-based flame retarding agents nor antimony compounds and is excellent in moldability, flame retardance, high-temperature storage characteristics, reliability for moisture resistance, and solder cracking resistance. That is, the present invention is an epoxy resin composition for encapsulating semiconductors which contains (A) an epoxy resin, (B) a phenolic resin, (C) a curing accelerator, (D) an inorganic filler and (E) a phosphazene compound as essential components, the total weight of phosphate ion and phosphite ion contained in the phosphazene compound being not more than 500 ppm. Further, the epoxy resin composition may optionally contain a flame-retarding assistant or an ion scavenger.Type: ApplicationFiled: October 31, 2002Publication date: October 2, 2003Inventors: Takafumi Sumiyoshi, Ayako Mizushima, Ken Oota, Yoshio Fujieda, Hiroki Nikaido, Takashi Aihara
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Patent number: 6613186Abstract: A pressurized aerosol solvent cement product and a method of using the same is disclosed. The aerosol solvent cement product includes an aerosol solvent cement composition disposed in a container. The aerosol solvent cement composition includes tetrahydrofuran, a thermoplastic resin soluble in tetrahydrofuran, a propellant, and a stabilizing composition.Type: GrantFiled: July 27, 2001Date of Patent: September 2, 2003Assignee: The Sherwin-Williams CompanyInventor: James J. Johnson
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Publication number: 20030153653Abstract: A stabilizer mixture containingType: ApplicationFiled: October 22, 2002Publication date: August 14, 2003Inventor: Francois Gugumus
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Patent number: 6583250Abstract: The bondability of a polyolefin, particularly to cyanoacrylate adhesives, is improved by incorporating in the polyolefin a polymerization initiator capable of initiating the polymerization of the monomers constituting the cyanoacrylate adhesive. The polymerization initiator may, for example, be a sterically hindered nitrogen base and may be mixed with the polyolefin at a temperature above the polyolefin's glass transition temperature using, for example, co-extrusion or co-injection methods.Type: GrantFiled: November 20, 1998Date of Patent: June 24, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Birnbrich, Herbert Fischer, Manfred Gorzinski, Thomas Huver
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Publication number: 20030096889Abstract: The present invention relates to benzoxazinone compounds having a yellow index less than about 0, and a sodium concentration less than about 50 ppm. This invention also relates to a process for preparing these compounds comprising the step of reacting an isatoic anhydride with approximately stoichiometric amounts of an acylating compound, where the isatoic anhydride is purified by re-crystallization or other purification methods.Type: ApplicationFiled: July 31, 2002Publication date: May 22, 2003Inventor: Asim K. Sarkar
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Patent number: 6566427Abstract: The invention relates to a mixture for stabilizing polyolefins against damage caused by light, which mixtures contain: (A) a hindered amine light stabilizer; (B) an oxide, hydroxide or organic salt of zinc or magnesium; and (C) a pigment and/or a UV absorber.Type: GrantFiled: July 31, 1997Date of Patent: May 20, 2003Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus
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Patent number: 6566425Abstract: Colorants comprising a chromophore having two methine moieties attached to a benzodifuranone backbone, wherein said moieties optionally have at least one poly(oxyalkylene) chain, preferably at least two such chains attached thereto are provided. Such colorants exhibit excellent thermal stability, effective colorations, excellent low extraction rates, and effective lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain substrates, particularly polyesters. The optional poly(oxyalkylene) chains also increase the solubility in different solvents or resins thereby permitting the introduction of such excellent coloring chromophores within diverse media and/or on diverse substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such colorants are provided as are methods for producing such inventive colorants.Type: GrantFiled: September 18, 2001Date of Patent: May 20, 2003Assignee: Milliken & CompanyInventors: Daniel M. Connor, Eric B. Stephens
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Patent number: 6559201Abstract: The antifouling composition of the present invention includes a glassy matrix formed by crosslinking a mixture of a silanol-terminated silicone and an alkoxy functionalized siloxane to provide an interpenetrating polymer network of glass and silicone and at least two materials capable of microphase separation, at least one of which is graftable to the glassy matrix.Type: GrantFiled: February 12, 2001Date of Patent: May 6, 2003Assignee: Microphase Coatings, Inc.Inventor: William H. Simendinger, III
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Publication number: 20030060543Abstract: The present invention provides additive packages for polyolefins The additive packages of the present invention comprise at least one non-phenolic antioxidant and a hindered amine light stabilizer. The additive packages may contain other additives as needed, and may optionally include an acid scavenger. Articles made from the resultant polymers, such as radiator surge tanks, exhibit enhanced stain and discoloration resistance upon exposure to high temperatures and harsh chemicals such as those experienced in “under the hood” spaces of modem automobiles.Type: ApplicationFiled: May 29, 2001Publication date: March 27, 2003Inventors: Steven David Seip, Sharon Edwards Thompson, Edwin B. Townsend
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Patent number: 6521689Abstract: An object of this invention is to impart excellent flame retardancy to an aromatic polyamide resin without use of a halogen compound which is responsible for generation of gases harmful to the human body and without decreasing preferred properties (e.g. mechanical properties, and molding processability) inherently possessed by aromatic polyamide resins, the flame-retardant aromatic polyamide resin composition of this invention comprising (a) 100 parts by weight of an aromatic polyamide resin, (b) 0.1 to 100 parts by weight of a crosslinked phosphazene compound which is a compound crosslinked with a crosslinking group, such as phenylene groups, the crosslinking group being interposed between the two oxygen atoms left after the elimination of phenyl groups from the phosphazene compound, no free hydroxyl group being present in the molecule, the amount of all phenyl groups in the crosslinked compound being 50 to 99.Type: GrantFiled: July 6, 2001Date of Patent: February 18, 2003Assignee: Otsuka Chemical Co., Ltd.Inventors: Tadao Yabuhara, Yuji Tada, Shinji Nakano, Takashi Kameshima, Yoichi Nishioka, Hiroyuki Takase
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Publication number: 20030008950Abstract: Optical disc adhesives and lacquers comprising components that undergo free-radical polymerization when exposed to radiation and a cure-enhancing amount of R-SH, wherein R is a heterocycle; cationic, free-radical, and hybrid adhesives for digital versatile discs (DVD) comprising components that undergo cationic and/or free-radical polymerization when exposed to radiation and a corrosion-inhibiting amount of R-SH, R1-R2 and/or an acyclic thiol, wherein R is a heterocycle, R1 is a substituted or unsubstituted phenyl as a substituent of R2 or forming with R2 a bicyclic structure, and R2 is a heterocycle comprising at least one double bond and at least two N atoms; and optical media, e.g., CD-DA, CD-ROM, CD-R, DVD, and the like, that include one, or a combination, of the foregoing inventive adhesive or lacquer compositions.Type: ApplicationFiled: November 13, 2001Publication date: January 9, 2003Applicant: DSM N.V.Inventors: Chander P. Chawla, Michael G. Sullivan, Vadim V. Krongauz, Christopher F. Tronche
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Publication number: 20020193488Abstract: The invention is the manipulation of the zinc oxide content and sulfur content of nitrile butadiene rubbers and selected vulcanization conditions that can be achieved economically with common production facilities. The manipulation of these components affect the relaxation property of gloves formed by this material. Produced are gloves that have a relaxation property, higher than 50%, and a low modulus (approximately 3 Mpa). The glove maintains decent ultimate tensile strength (>20 Mpa) and elongation (>500%). The glove is produced by a vulcanization process which lasts from 5 to 60 minutes at temperatures ranging from 300° F. to 400° F. The tensile strength and elongation are well above the ASTM requirements for medical gloves. The current ASTM requirements are ASTM D412-92. Thanks to sufficient vulcanization, the films produced provide satisfactory protection from viral penetration. The tearing strength is also better because of the lower modulus.Type: ApplicationFiled: April 12, 2002Publication date: December 19, 2002Inventor: Jian Tao
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Publication number: 20020188043Abstract: Novel photochromic diarylethenes substituted with an isoxazole group and the method of preparation are disclosed. Also disclosed are compositions made with the photochromic diarylethenes. The preparation of thin films with the photochromic diarylethenes or compositions thereof are disclosed. The photochromic diarylethenes or compositions thereof may be used, for example in recording materials, photochromic windows, indicating elements, plastic mirrors, photochromic filters, photo switches, photosensitive drums, recording elements, solar cells, lens, fibers and optical elements.Type: ApplicationFiled: June 28, 2001Publication date: December 12, 2002Inventors: Eun K. Kim, Song Y. Cho, Dong J. Jeon, Young M. Kim
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Patent number: 6492440Abstract: A product obtainable by 1) reacting a compound of the formula (&agr;) with a compound of the formula (&bgr;) in a molar ratio of 1.2:1 to 1.4:1; 2) reacting the end groups of the formula (&ggr;) being present in the product of the reaction 1) with e.g. dibutylamine in a molar ratio of 2:1.7 to 2:3; the reactions 1) and 2) being carried out in an organic solvent in the presence of an inorganic base; and 3) transferring the groups of the formula being present in the product of the reaction 2) to groups of the formula said transfer being carried out by reacting the product of the reaction 2) with a hydroperoxide in a hydrocarbon solvent in the presence of a peroxide decomposing catalyst. The products obtained are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers such as polyolefins.Type: GrantFiled: June 9, 2000Date of Patent: December 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: James Peter Galbo, Nicola Lelli, Valerio Borzatta, Jean-Pierre Wolf, Michael Ackerman, Piero Piccinelli, Ivan Orban
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Patent number: 6492032Abstract: A blend of optical brighteners includes (a) from about 45 to 95 weight % of a mixture of benzoxazolyl stilbenes; and (b) from about 55 to about 5 weight % of at least one bis(benzoxazolyl)naphthalene based brightener, bis(benzoxazolyl)thiophene based brightener, a pyrazoline based brightener, a coumarin based brightener, and mixtures thereof, wherein the weight percents of the optical brightener blend are based on the total weight of optical brighteners in the blend. The optical brightener blend is useful for admixing with a polyolefin resin which in turn may be used for photo imaging applications.Type: GrantFiled: October 12, 2000Date of Patent: December 10, 2002Assignee: Eastman Chemical CompanyInventors: Gether Irick, Jr., Jeffrey Dan Daily
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Patent number: 6476095Abstract: The antifouling composition of the present invention includes a glassy matrix formed by crosslinking a mixture of a silanol-terminated silicone and an alkoxy-functionalized siloxane to provide an interpenetrating polymer network of glass and silicone and at least two materials capable of microphase separation, at least one of which is graftable to the glassy matrix. A primer composition is also provided and is a mixture of an epoxy, an alkoxy-functionalized siloxane and a silane capable of compatabilizing the epoxy and the alkoxy-functionalized siloxane; a glassy matrix formed by crosslinking a mixture of a silanol-terminated silicone and an alkoxy-functionalized siloxane.Type: GrantFiled: May 30, 2001Date of Patent: November 5, 2002Assignee: Microphase Coatings, Inc.Inventor: William H. Simendinger, III
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Patent number: 6451893Abstract: A new formulation for producing nitrile gloves has been developed. The resulting glove shows following outstanding characteristics: stress at six minutes greater than 50% of its initial value; ultimate tensile strength and elongation well above ASTM requirements; and much lower modulus than almost all the nitrile gloves currently commercially available. The unique formulation is zinc oxide free and is vulcanized from 5 to 60 minutes at temperatures ranging from 300° F to 400° F.Type: GrantFiled: June 11, 2001Date of Patent: September 17, 2002Assignee: Microflex CorporationInventor: Jian Tao
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Patent number: 6433044Abstract: The present invention provides a methyl methacrylate resin composition exhibiting superior durability without impairing the transparency inherent to a methyl methacrylate resin, which comprises a methyl methacrylate resin and a 2-(1-arylalkylidene)malonic acid ester in an amount of 0.0005 to 0.1 parts by weight per 100 parts by weight of the methyl methacrylate resin.Type: GrantFiled: July 24, 2001Date of Patent: August 13, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Tomohiro Maekawa, Kenji Manabe
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Patent number: 6420461Abstract: The present invention relates to novel compounds of the formula (III) in which the substituents are as defined in the description, to a process for their preparation and to mixtures with other compounds. The compounds of the formula (III) are suitable for stabilizing organic material against the effect of light and heat.Type: GrantFiled: November 12, 1999Date of Patent: July 16, 2002Assignee: Clariant GmbHInventors: Thomas Stährfeldt, Mathias Mehrer, Matthias Zäh, Gerhard Pfahler
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Patent number: 6417293Abstract: The present invention, therefore, relates to a method for preparing a thermoplastic elastomer, said method comprising: (I) mixing (A) a thermoplastic resin comprising more than 50 percent by volume of a polyester resin other than poly(butylene terephthalate), said thermoplastic resin having a softening point of 23° C. to 300° C., (B) a silicone elastomer comprising (B′) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups in its molecule and, optionally, (B″) up to 200 parts by weight of a reinforcing filler, the weight ratio of said silicone elastomer (B) to said thermoplastic resin (A) being greater than 35:65 to 85:15, (C) 0.Type: GrantFiled: December 4, 2000Date of Patent: July 9, 2002Assignee: Dow Corning CorporationInventors: Igor Chorvath, Craig Steven Gross, Kenneth Gerard Gruszynski, Michael Kang-Jen Lee, Jun Liao, Koji Nakanishi, Richard Leroy Rabe, David Joseph Romenesko
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Patent number: 6365651Abstract: A synergistic stabilizer mixture comprising a component a) and, for example, a component b), where component a) is at least one compound of the formula I in which R1 is C1-C10alkyl, C5-C12cycloalkyl, C1-C4alkyl-substituted C5-C12cycloalkyl, phenyl or C1-C10alkyl-substituted phenyl, R2 is C3-C10alkylene, R3 is hydrogen, C1-C8alkyl, O, —CH2CN, C3-C6alkenyl, C7-C9phenylalkyl, C7-C9phenylalkyl which is substituted on the phenyl radical by C1-C4alkyl; or C1-C8acyl, and n1 is a number from 1 to 50, and component b) another HALS compound.Type: GrantFiled: March 18, 1999Date of Patent: April 2, 2002Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus