Solid Polymer From Ethylenic Reactants Only Is Derived From Reactant Containing Halogen Atom Patents (Class 525/104)
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Patent number: 6004496Abstract: High performance silicone rubber windshield wiper blades are provided as a result of molding a tintable platinum group metal catalyzed silicone compositions having an intrinsic viscosity of less than 1.3. Improved lubricity with respect to windshield wiper glass is achieved by a molding procedure which effects a transfer such as a migration, or diffusion of release agent, for example polytetrafluoroethylene, into the surface of the silicone rubber windshield wiper blade.Type: GrantFiled: April 22, 1997Date of Patent: December 21, 1999Assignee: Specialty Silicone Products, Inc.Inventor: Ned J. Reo
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Patent number: 6001929Abstract: There is disclosed a polycarbonate resin composition which comprises an (A) polycarbonate-polyorganosiloxane copolymer, a (B) polycarbonate resin and a (C) polytetrafluoroethylene which has fibril forming capability and an average molecular weight of at least 500,000 wherein the amount of the polyorganosiloxane moiety contained in the component (A) is 0.1 to 2.0% by weight based on the total amount of the components (A) and (B). The resin composition is excellent in flame retardancy, thermal stability and fluidity while preventing melt dripping at the time of combustion. Accordingly, the resin composition is favorably used in the application field of office automation machinery and equipment, electric and/or electronic field, etc.Type: GrantFiled: November 1, 1996Date of Patent: December 14, 1999Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Jiro Chiba
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Patent number: 5986003Abstract: A vinylidene chloride polymer composition comprising a vinylidene chloride polymer and a concentrate comprising a blend of a high viscosity, high molecular weight silicone polymer and a carrier polymer, e.g. high density polyethylene, the concentrate being present in an amount sufficient to improve the extrudability of the vinylidene chloride polymer. The vinylidene chloride composition can be fabricated into flexible and rigid containers, both in monolayer and multilayer structures for use in the preservation of food, drink medicine and other perishables.Type: GrantFiled: October 30, 1997Date of Patent: November 16, 1999Assignee: The Dow Chemical CompanyInventors: Eric K. C. Lee, Steven R. Jenkins, Martin F. Debney, Carlos E. Hinton
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Patent number: 5969045Abstract: The present invention relates to thermoplastic polymer compounds comprising a blend of a chlorinated polyvinyl chloride and an impact modifier containing a polyorganosiloxane and polyalkyl(meth)acrylate. The novel thermoplastic compound has improved stability and toughness and exhibits a low rate of heat release.Type: GrantFiled: May 20, 1997Date of Patent: October 19, 1999Assignee: The B.F. Goodrich CompanyInventors: Theodore Joseph Schmitz, David Lee Milenius, Thomas Henry Forsyth, Arthur Leonard Backman, Girish Trikamlal Dalal
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Patent number: 5968996Abstract: A silicone release composition having a non-gloss, i.e., matte finished, surface and a linerless label incorporating the silicone release composition. The release composition includes a crosslinked silicone-based polymer having microparticles of a polymeric wax at least partially embedded therein. The polymeric wax may be polytetrafluoroethylene, polypropylene or other polyolefin, or a hydrocarbon-based wax. The microparticles of polymeric wax cause incidental light to scatter upon reflection, giving the release composition surface matte appearance. This makes the release composition particularly useful for linerless labels on which bar coded information will be printed. Also, a method for producing linerless label stock. The method includes mixing an uncured silicone material with microparticles of a polymeric wax. The mixture is coated onto a substrate and exposed to UV radiation to cure or crosslink the silicone around the microparticles of wax.Type: GrantFiled: June 7, 1995Date of Patent: October 19, 1999Assignee: Moore Business Forms, Inc.Inventors: Michael Sanchez, Khaled M. Khatib, David K. Rice, II
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Patent number: 5959034Abstract: A curable silicone composition having high compatibility with organic polymers, which comprises (a) 100 parts by weight of a hydroxyl group-containing organopolysiloxane represented by the following formula (I) and (b) 1-50 parts by weight of an isocyanate compound having at least two isocyanate groups per molecule, wherein the number of the hydroxyl groups per molecule in the component (a) plus the number of the isocyanate groups per molecule in the component (b) is at least 5: ##STR1## wherein R.sup.1 is a monovalent saturated hydrocarbon group; R.sup.2 is a phenyl-substituted alkyl group represented by C.sub.6 H.sub.5 --(CH.sub.2).sub.p --CH(R.sup.4)--CH.sub.2 --; R.sup.3 is a hydroxyl-substituted alkyl group represented by --CH.sub.2 --CH.sub.2 --CH.sub.2 --O--(C.sub.2 H.sub.4 O).sub.q --H; two R groups are the same group or different groups selected from the groups represented by R.sup.1, R.sup.2 or R.sup.3 ; R.sup.4 is a hydrogen atom or the same group as R.sub.Type: GrantFiled: April 17, 1998Date of Patent: September 28, 1999Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masahiko Ogawa, Naoki Omura, Shunji Aoki
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Patent number: 5929166Abstract: The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.Type: GrantFiled: November 26, 1997Date of Patent: July 27, 1999Assignee: Rhone-Poulenc ChimieInventors: Yves Bomal, Philippe Karrer, Jean-Manuel Mas, Gerard Mignani
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Patent number: 5919886Abstract: A room temperature curable fluoropolymer composition is provided which comprises (A) a straight chain fluoropolymer compound containing, in its backbone chain, at least one structure selected from a perfluoroalkylene structure and a perfluoropolyether structure and having a hydrolyzable silyl group at both ends of its molecular chain, (B) an organic compound having at least one carbonyl group per molecule, and (C) one compound selected from (C-1) an organic compound having at least one primary amino group per molecule and (C-2) a compound having at least one proton per molecule and having an acid dissociation constant (pKa) in water of 2 or less. Another room temperature curable composition is also provided which comprises said (A) component, (B') an organosilicon compound having at least two silanol groups per molecule, and (C') a condensation accelerator.Type: GrantFiled: September 19, 1997Date of Patent: July 6, 1999Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takashi Matsuda, Takafumi Sakamoto, Shinichi Sato, Noriyuki Koike, Yasuo Tarumi, Tsuneo Kimura, Yasushi Yamamoto, Masatoshi Arai
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Patent number: 5905117Abstract: A low dielectric resin composition comprising the following components (a) and (b), and the dielectric constant of a coating film formed by this composition being at most 3:(a) a resin having functional groups in its molecule and being soluble in a solvent; and(b) a partially hydrolyzed condensate of alkoxysilanes of the formula R.sup.1.sub.m R.sup.2.sub.n Si(OR.sup.3).sub.4-m-n, wherein each of R.sup.1 and R.sup.2 which may be the same or different, is a non-hydrolyzable group, R.sup.3 is an alkyl group, and m and n are integers of from 0 to 3 satisfying 0.ltoreq.m+n.ltoreq.3.Type: GrantFiled: September 19, 1996Date of Patent: May 18, 1999Assignees: Asahi Glass Company Ltd., Hitachi Chemical Co., Ltd.Inventors: Shunsuke Yokotsuka, Aya Serita, Ko Aosaki, Ikuo Matsukura, Takenori Narita, Hiroyuki Morishima, Shunichiro Uchimura
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Patent number: 5859134Abstract: Ionomeric polymers are provided which are dispersible in aqueous solvents yet which cross-link with ethylenically unsaturated monomers to form matrices having relatively low solubility in such solvents. The polymers can be incorporated into photocurable composition for use, for example, in photocurable printing elements.Type: GrantFiled: March 18, 1997Date of Patent: January 12, 1999Assignee: Polyfibron Technologies, Inc.Inventor: Jay L. Reimers
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Patent number: 5849832Abstract: This invention relates generally to sealants for insulating glass units. More specifically, this invention is a one-component, hot applied, chemically curing sealant for edge sealing insulating glass units. The sealant contains a thermoplastic hot melt resin blended with an atmospheric curing resin. The hot melt resin functions as the meltable component during the initial application, and supplies strength immediately upon cooling. The polymer phase then begins to cure by reaction with atmospheric oxygen and/or moisture to form a cross-linked thermoset elastomer which is temperature resistant. At this point, the hot melt resin functions as an inert plasticizer within the cured polymer phase. The sealant of the present invention may additionally include plasticizers, fillers, pigments, catalysts and the like.Type: GrantFiled: October 25, 1995Date of Patent: December 15, 1998Assignee: Courtaulds AerospaceInventors: Bruce Virnelson, Pat Niega
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Patent number: 5844031Abstract: A method of dispersing silicone compositions in organic thermoplastic materials is disclosed. The novel compositions produced by the method of the invention have a fine and relatively uniform dispersion or organosilicone in an organic thermoplastic. An organosilicone resin (A) and a predominantly linear silicone fluid (B) are first blended to substantial homogeneity to form an organosilicone alloy therefrom. The organosilicone alloy exhibits thermoplastic behavior and has a temperature-dependent complex viscosity .eta.*.sub.Si (T) associated therewith. Likewise the organic thermoplastic materials have a temperature-dependent complex viscosity, .eta.*.sub.OTP (T), associated therewith. The organic thermoplastic and the organosilicone alloy are thereafter mixed at a predetermined mixing temperature, T.sub.m, and a predetermined shear strain rate. The organic thermoplastic material and the organosilicone alloy are both in a flowable state at T.sub.m. The value of T.sub.m is selected to be about .+-.30.degree. C.Type: GrantFiled: August 28, 1996Date of Patent: December 1, 1998Assignee: Dow Corning CorporationInventors: Wei Chen, Hongxi Zhang, Kevin Edward Lupton, David Joseph Romenesko, Randall Gene Schmidt
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Patent number: 5840802Abstract: Low temperature ductile and impact resistant compositions are provided which comprise a polycarbonate resin and a dual graft multi-stage polyorganosiloxane/polyvinyl-based graft polymer composition. Also provided are thermally stabilized multi-stage polyorganosiloxane/polyvinyl-based graft polymers which have improved color-imparting and impact resistance-imparting properties and thermoplastic compositions containing the same.Type: GrantFiled: October 11, 1991Date of Patent: November 24, 1998Assignee: General Electric CompanyInventors: James Louis DeRudder, I-Chung Wayne Wang
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Patent number: 5840805Abstract: A highly storage-stable room-temperature-curable organopolysiloxane composition that cures to yield a product whose surface resists staining and that does not cause staining of the neighboring regions of the substrate in contact with said cured product. The organopolysiloxane composition is made from a polydiorganosiloxane, an imidazolinyl-functional organosiloxane, a filler, and a crosslinking compound which is a Si-bonded hydrolyzable group-containing organosilane or organosiloxane oligomer.Type: GrantFiled: October 25, 1995Date of Patent: November 24, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hisataka Nakashima, Shigeki Sugiyama
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Patent number: 5840806Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).Type: GrantFiled: January 7, 1997Date of Patent: November 24, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
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Patent number: 5840800Abstract: A crosslinked polymer dispersion comprising a preformed polymer, selected from the group consisting of silicon modified organic polymers, mixtures of silicon modified organic polymers, mixtures of silicon modified organic polymer(s) with regular organic polymers, mixtures of silicon modified organic polymer(s) with siloxane polymers, mixtures of above polymers, and mixtures of above polymer(s) with organic plasticizers or solvents.Type: GrantFiled: November 2, 1995Date of Patent: November 24, 1998Assignee: Dow Corning CorporationInventors: Eric Jude Joffre, Arthur James Tselepis, Andreas Thomas Franz Wolf
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Patent number: 5837774Abstract: Curable fluoropolyether rubber composition: This composition comprises (A) a straight chain fluoropolyether compound having at least two alkenyl groups in its molecule and having a divalent perfluoropolyether structure in its backbone chain, (B) a polytetrafluoroethylene, (C) an organohydrogenpolysiloxane having at least two hydrogen atoms bonded to silicon atoms in its molecule, and (D) a hydrosilylation reaction catalyst. The composition is provided in the form of a paste capable of forming into optional shapes, and its cured product is well-balanced in and is excellent in properties such as heat resistance, chemical resistance, solvent resistance, releasability, lubricating qualities, water repellency, oil repellency and weatherability.Type: GrantFiled: February 2, 1996Date of Patent: November 17, 1998Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yasuo Tarumi, Kenichi Fukuda
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Patent number: 5824421Abstract: Condensation-curable coating compositions are prepared from a mixture of and organic resin (A) and a flurosilicone (B). Water or an organic solvent may be used to provide a vehicle for application of the composition. The cured coatings of the invention exhibit superior water and oil repellency.Type: GrantFiled: October 30, 1996Date of Patent: October 20, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hideki Kobayashi, Toru Masatomi
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Patent number: 5821304Abstract: The present invention relates to a chlorinated polyvinyl chloride compound and an article made therefrom. The compound comprises a two step CPVC resin, chlorinated polyethylene as well as an impact modifier containing a polyorganosiloxane. The compound exhibits good physical properties, chemical resistance as well as ease of processability.Type: GrantFiled: May 24, 1996Date of Patent: October 13, 1998Assignee: The B. F. Goodrich CompanyInventors: Arthur Leonard Backman, Bernard Frank Cinadr
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Patent number: 5821314Abstract: This invention provides a thermosetting composition comprising (A) a compound (A-1) containing an epoxy group or groups and a reactive silicon group or groups as essential functional group components in the same molecule, or a mixture (A-2) of an epoxy group-containing compound and a reactive silicon group-containing compound, and (B) an organotin catalyst, a thermosetting composition comprising (A) a compound (A-3) containing (i) an epoxy group or groups, (ii) a reactive silicon group or groups and (iii) a hydroxyl group or groups and/or a carboxyl group or groups as essential functional group components in the same molecule, or a mixture (A-4) of at least two types of compounds, each compound containing at least one member selected from the class consisting of functional group components (i) to (iii), and all of the functional group components (i) to (iii) being present in said mixture, and (B) an organotin catalyst; and methods of forming a finish coat using these thermosetting compositions.Type: GrantFiled: December 13, 1996Date of Patent: October 13, 1998Assignee: Kansai Paint Company, LimitedInventors: Satoshi Ikushima, Yasumasa Okumura, Osamu Isozaki, Minoru Tsunoda
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Patent number: 5814703Abstract: A coating agent composition comprising:(A) an organic resin, and(B) a silicone compound represented by the average composition formula (1):(X).sub.a (Y').sub.b (R.sup.1).sub.c SiO.sub.(4-a-b-c)/2 (1)wherein X is a particular functional group containing organic group, Y' is a hydrolyzable group or an admixture of a hydrolyzable group and the silanol group, R.sup.1 is a monovalent hydrocarbon group, a ranges from 0.05 to 0.90, b 0.12 to 1.88, and c 0.10 to 1.00, a+b+c being in the range of 2.02 to 2.67. The amount of the silicon atoms to which said functional group-containing organic group x is bonded is 5 to 90 mol % based on the entire silicon atoms, and the amount of the T unit of R.sup.1 --SiO.sub.3/2 is 10 to 95 mole % based on the entire siloxane units. This composition is useful to form a coating film excellent in weathering resistance, adhesion, stain resistance, scuffing resistance, water resistance and chemical resistance and therefore suitable for protection of articles exposed outdoors.Type: GrantFiled: August 16, 1996Date of Patent: September 29, 1998Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaaki Yamaya, Masahiro Yoshizawa
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Patent number: 5773497Abstract: Disclosed is a crosslinking resin composition comprising: (A) a carboxyl group-containing resin as a main agent, having a number average molecular weight of from 1,000 to 40,000 and an acid value of from 10 to 400 mg KOH/g; (B) a cyclic or chain silicone compound as a curing agent, having a number average molecular weight of from 350 to 8,000 and containing at least two epoxy groups in one molecule thereof, wherein the silicone compound is free of a silanol group, a hydrolyzable silyl group and a vinyl polymer structure, and wherein the silicone compound has a siloxy group-containing skeleton; and (C) a medium. The crosslinking resin composition of the present invention not only exhibits excellent storage stability, but is also capable of providing, upon being crosslinked, a cured resin having excellent gloss, weatherability, acid resistance, solvent resistance, water repellency and stain resistance.Type: GrantFiled: September 16, 1996Date of Patent: June 30, 1998Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kaoru Ueyanagi, Masahiro Yamamoto
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Patent number: 5741841Abstract: There is disclosed a coating composition including water, a solvent, a grafted elastomer composed of a polyorganosiloxane bonded to a fluoroelastomer, and a liquid which forms an azeotropic mixture with the water, wherein the azeotropic mixture of the water and the liquid restrains a viscosity increase in the coating composition over time.Type: GrantFiled: April 25, 1996Date of Patent: April 21, 1998Assignee: Xerox CorporationInventors: Santokh S. Badesha, George J. Heeks, Arnold W. Henry, Biritawit Asfaw, Marko D. Saban, John Abate, Richard L. Carlston, Nam S. Ro
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Patent number: 5726247Abstract: This invention relates to a fluoropolymer nanocomposite comprising a fluoropolymer phase and an inorganic oxide phase dispersed throughout, said inorganic oxide phase having either no particles or particles substantially all of which have a particle size of less than about 75 nm which can be determined by small angle x-ray scattering and transmission electron microscopy techniques. These nanocomposites are useful as protective coatings.Type: GrantFiled: June 14, 1996Date of Patent: March 10, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Michael Joseph Michalczyk, Kenneth George Sharp, Charles Winfield Stewart
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Patent number: 5723526Abstract: A resin composition consisting essentially of (a) an aromatic polycarbonate resin, (b) a thermoplastic graft copolymer obtained by grafting a diene rubber component with a vinyl cyanide compound and an aromatic vinyl compound, (c) a phosphoric acid ester, (d) a polytetrafluoroethylene, (e) a talc, and (f) a composite rubber having a network structure in which a polyorganosiloxane rubber component and a polyalkyl (meth)acrylate rubber component interpenetrate each other, each in a specified amount. This resin composition has excellent fluidity and allows easy mold- processing. The molded article made therefrom is excellent in flame retardancy, stiffness, heat-resistance, impact strength and appearance.Type: GrantFiled: April 1, 1996Date of Patent: March 3, 1998Assignee: Teijin Chemicals LtdInventor: Masashi Nagasawa
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Patent number: 5717009Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.Type: GrantFiled: July 17, 1996Date of Patent: February 10, 1998Assignee: Toshiba Silicone Co., Ltd.Inventors: Shigeki Matsushita, Fumihiko Kobayashi
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Patent number: 5693714Abstract: Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.Type: GrantFiled: March 1, 1996Date of Patent: December 2, 1997Assignee: Composite Particles, Inc.Inventors: Bernard D. Bauman, Mark A. Williams, Reza Bagheri
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Patent number: 5691067Abstract: The present invention comprises powdered coatings for cookware to improve the non-stick and/or release characteristics at elevated temperatures. Specifically, the powdered coatings comprise a solid silicone resin that is heat resistant and an siloxane additive, with or without polytetrafluoroethylene. In the preferred embodiment of the present invention, the silicone resin is methyl phenyl silicone or phenyl silicone or methyl polysiloxane or phenyl alkyl polysiloxane resin and the additive is either methyl alkyl polysiloxane or dimethyl polysiloxane.Type: GrantFiled: August 8, 1996Date of Patent: November 25, 1997Assignee: Coatings America, Inc.Inventor: Rajendra Patel
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Patent number: 5691019Abstract: A coated article for foul release for use in aquatic applications does not require a discrete tie-layer to ensure adhesion of a coating to a substrate. An adhesion promoting layer comprising an anticorrosive material and a bonding agent is applied directly to the substrate. A release layer comprising organopolysiloxane is deposited onto the adhesion promoting layer. A method for applying the foul release coating comprises the following steps: applying an adhesion promoting layer, curing the adhesion promoting layer, applying the release layer and curing the release layer.Type: GrantFiled: May 1, 1995Date of Patent: November 25, 1997Assignee: General Electric CompanyInventors: Kenneth Michael Carroll, Owen Maynard Harblin, Slawomir Rubinsztajn
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Patent number: 5677066Abstract: A sealing part for connector waterproofing is disclosed, which comprises a vulcanized molding obtained from a composition comprising 100 parts by weight of a polyorganosiloxane (1), from 5 to 100 parts by weight of a reinforcing silica powder filler (2), from 0.01 to 10 parts by weight of a hydrogensiloxane polymer (3) having two or more Si-H bonds per molecule, and from 0.01 to 5 parts by weight of t-butyl peroxy-3,5,5-trimethylhexanoate (4). The sealing part for connector waterproofing of the present invention is satisfactory in heat resistance, low-temperature resistance, and oil resistance and can be produced at low cost in a reduced molding time.Type: GrantFiled: July 20, 1995Date of Patent: October 14, 1997Assignee: Yazaki CorporationInventors: Kiyotaka Okazaki, Masahiro Kanda
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Patent number: 5674967Abstract: A composition comprising perfluoroalkylalkylsilane and a completely hydrolyzable silane or siloxane is disclosed for providing nonwetting properties to the surface of various substrates such as glass, plastic, metal, organic polymer coated substrates or inorganic coated substrates. The nonwetting property, as measured by contact angle of a drop of water on the treated substrate surface, is more durable than the nonwetting property of a surface treated with the same perfluoroalkylalkylsilane with the hydrolyzable silane or siloxane.Type: GrantFiled: September 23, 1996Date of Patent: October 7, 1997Assignee: PPG Industries, Inc.Inventor: George B. Goodwin
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Patent number: 5652307Abstract: Graft copolymers obtained by(A) polymerizing 10 to 89 wt % of a mixture consisting essentially of either(a1) from 70 to 99.89 wt % of a C.sub.1 -C.sub.18 -alkyl ester of acrylic acid,(a2) from 0.1 to 10 wt % of a polyfunctional monomer,(a3) from 0 to 29.89 wt % of an ethylenically unsaturated monomer which differs from (a1) and (a2), is copolymerizable therewith and carries no acid group and(a4) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupor(a5) from 49.99 to 99.99 wt % of at least one diene,(a6) from 0 to 50 wt % of a monomer which is copolymerizable therewith and carries no acid group and(a7) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupin the presence of from 1 to 80 wt % of a cross-linked silicone rubber to form a copolymer A,and(B) polymerizing 10 to 89 wt % of a mixture consisting essentially of(b1) from 50 to 99.99 wt % of a styrene compound of the formula (I) ##STR1## where R.sup.1 and R.sup.Type: GrantFiled: October 17, 1996Date of Patent: July 29, 1997Assignee: BASF AktiengesellschaftInventors: Norbert Niessner, Wolfgang Fischer
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Patent number: 5648427Abstract: A curable composition which comprises (A) an oxyalkylene polymer having a silicon-containing group(s) that has a hydroxy group(s) and/or a hydrolyzable group(s) bonded to the silicon atom(s), and can be crosslinked by forming siloxane bond, and (B) hollow microspheres of vinylidene chloride polymer whose true specific gravity is 1 g/cm.sup.3 or less.Type: GrantFiled: December 20, 1995Date of Patent: July 15, 1997Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaisaInventors: Masayuki Fujita, Hiroshi Wakabayashi
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Patent number: 5643998Abstract: A recyclable polymer is formed of a plurality of oligomer units obtained by polymerizing a fixed number of monomers, and linkage units for linking the oligomer units through a chemical bond which is different from a bond between monomers constituting the oligomer units, thereby allowing repetitive scission and re-bonding of the linkage units by a predetermined treatment not cleaving the bond between monomers. The recyclable polymer is decomposable into oligomers and the oligomers can be linked again into the original polymer without degrading the quality of the polymer. A process for producing the recyclable polymer, a method for recovering the recyclable polymer, and a method for regenerating the recyclable polymer are also provided.Type: GrantFiled: March 8, 1995Date of Patent: July 1, 1997Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Mitsuru Nakano, Arimitsu Usuki, Akane Okada, Osami Kamigaito
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Patent number: 5639825Abstract: When a thermosetting composition comprising(A) a resin having hydroxyl group,(B) a hydrolyzable silyl group-containing polymer,(C) a hydrolyzable silicon compound and(D) a curing catalyst is used, coating materials having no problem as to bad-smelling can be obtained and the coating films formed therefrom are improved in physical properties such as adhesion, solvent resistance and hardness.Type: GrantFiled: October 4, 1994Date of Patent: June 17, 1997Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Toshiro Nanbu, Hirotoshi Kawaguchi, Hisao Furukawa, Yasushi Kato
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Patent number: 5637642Abstract: This invention involved the discovery of novel polymers used as adhesives and a process for their preparation. The polymers were prepared by the nucleophilic substitution, at room temperature, of PVC with substituted alkyltrialkoxysilanes, which can be cured at room temperature to give adhesion of PVC to hydrophilic substrates. These polymers are particularly useful as adhesion promoters in ion-selective electrodes. The invention also involved the application of these adhesive primers to planar electrode substrates to give greatly improved performance in the response of ion-selective electrodes.Type: GrantFiled: May 26, 1995Date of Patent: June 10, 1997Assignee: Chiron Diagnostics CorporationInventors: Mark W. Boden, Andy D. C. Chan, Susan M. Degnan, Stephen B. Ruiz
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Patent number: 5626938Abstract: A method for producing halogen-free, antimony-free and phosphorous-free polyamide fibers is described by incorporating an additive into the polyamide which comprises a vulcanizable mixture of silicones and a catalyst in a thermoplastic matrix. The fibers have improved flame retardancy and are used for the manufacture of carpets.Type: GrantFiled: May 16, 1995Date of Patent: May 6, 1997Assignee: BASF CorporationInventor: Gary W. Shore
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Patent number: 5621042Abstract: Coating compositions are described. They contain, as a film-forming component, a fluoropolymer with a silane-coupling agent containing at least one free isocyanate group. The fluoropolymer may also have been modified with a reaction product of a polysiloxane or fluorine compound containing a reactive organic functional group with an organic polyisocyanate, which reaction product contains at least one free isocyanate group.Type: GrantFiled: July 20, 1995Date of Patent: April 15, 1997Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Colour & Chemicals Mfg, Co., Ltd.Inventors: Kazuyuki Hanada, Setsuo Hirose, Katsumi Kuriyama
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Patent number: 5618605Abstract: A method for producing halogen-free, antimony-free and phorphorous-free polyamide fibers is described by incorporating an additive into the polyamide which comprises a vulcanizable mixture of silicones and a catalyst in a thermoplastic matrix. The fibers have improved flame retardancy and are used for the manufacture of carpets.Type: GrantFiled: May 16, 1995Date of Patent: April 8, 1997Assignee: BASF CorporationInventor: Gary W. Shore
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Patent number: 5604288Abstract: A method for preparing a thermoplastic resin composition, said method comprising hot-kneading, in the absence of a radical-generating catalyst,(A) 100 parts by weight of a thermoplastic resin; and(B) 0.1 to 200 parts by weight of an alkenyl-functional polyorganosiloxane filled with amorphous silica micropowder, wherein the weight ratio of said silica micropowder to said alkenyl-functional polyorganosiloxane is 0.01:100 to 50:100, whereby the polyorganosiloxane of component (B) is chemically bonded to resin (A).Type: GrantFiled: November 29, 1995Date of Patent: February 18, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Haruhiko Furukawa, Akihiro Nakamura, Akihiko Shirahata
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Patent number: 5604007Abstract: A method for producing halogen-free, antimony-free and phosphorous-free polyamide fibers is described by incorporating an additive into the polyamide which comprises a vulcanizable mixture of silicones and a catalyst in a thermoplastic matrix. The fibers have improved flame retardancy and are used for the manufacture of carpets.Type: GrantFiled: August 19, 1993Date of Patent: February 18, 1997Assignee: BASF CorporationInventor: Gary W. Shore
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Patent number: 5552485Abstract: Fluoroaluminosilicate dental cement glasses are treated with an aqueous silanol treating solution and optionally with an additional organic compound. The treated glasses form cements with improved strength. The silanol can be ethylenically-unsaturated and can contain acidic groups, and, if so, is novel in its own right.Type: GrantFiled: June 2, 1995Date of Patent: September 3, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sumita B. Mitra, Scott R. Culler, Bing Wang
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Patent number: 5547742Abstract: A fuser roll having a metal core shaft has a resilient layer placed around the metal core shaft with at least the surface layer of the resilient layer comprising a fluorosilicone rubber layer containing 5 to 50 wt. % polytetrafluoroethylene. Since this fuser roll is excellent in releasability and silicone oil resistance, the durability is excellent, and the image obtained by a copying machine wherein the roll is used becomes sharp.Type: GrantFiled: July 5, 1994Date of Patent: August 20, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Makoto Satoh, Takehide Okami, Noboru Shimamoto
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Patent number: 5548028Abstract: Blends of previously-vulcanized fluoroelastomer with fluorine-free elastomer can be cured to have unexpectedly excellent physical properties.Type: GrantFiled: February 24, 1995Date of Patent: August 20, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: David L. Tabb
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Patent number: 5545715Abstract: The present invention provides a flame-retardant resin composition comprising 100 parts by weight of a bromine-containing copolymer composition containing 1 to 40% by weight of bromine, and comprising 0 to 30 parts by weight of a flame-retarding adjuvant and 0.5 to 30 parts by weight of a polyorganosiloxane-reinforced resin component obtained by polymerizing a vinyl monomer (d) in the presence of a polyorganosiloxane polymer. The flame-retardant resin composition of the present invention has attained a remarkably higher flame retardancy by the inclusion of a polyorganosiloxane-reinforced resin. A significant improvement in the dripping phenomenon has also been achieved. Further, this composition exhibits superior impact resistance and moldability, and a superior outer appearance in the formed products.Type: GrantFiled: June 26, 1992Date of Patent: August 13, 1996Assignee: Japan Synthetic Rubber Co. Ltd.Inventors: Hiroyuki Itoh, Masanori Suzuki, Akira Kamiya, Takeki Furuyama
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Patent number: 5536304Abstract: The invention relates to a water and oil repellency imparting composition which comprises:(a) a fluoroaliphatic radical-containing agent; and(b) a cyclic carboxylic anhydride-containing polysiloxane. Additionally, the composition may comprise:(c) an extender and/or a plasticizer. The composition provides water and oil repellent properties and a soft hand to fibrous and other substrates treated therewith.Type: GrantFiled: October 14, 1994Date of Patent: July 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dirk M. Coppens, Kathy Allewaert
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Patent number: 5536568Abstract: An elastomeric composition comprising a non-conductive elastomer having dispersed therein (i) elastomer particles, 10-300 .mu.m in diameter, (ii) conductive particles, 1-40 .mu.m in diameter, and (iii) hollow and elastic microspheres, 10-50 .mu.m in particle diameter, non-conductive when not deformed, becomes conductive when deformed by compression, extension, torsion or bending. The elastomeric composition may also have dispersed therein insulating and elastic fibers less than 100 yarn denier thick and 3-6 mm in length.Type: GrantFiled: March 12, 1991Date of Patent: July 16, 1996Assignee: Inabagomu Co., Ltd.Inventor: Okamoto Teruo
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Patent number: 5525673Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.Type: GrantFiled: July 18, 1994Date of Patent: June 11, 1996Assignee: Kansai Paint Company, LimitedInventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
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Patent number: 5510406Abstract: A fluoropolymer composition for coating, which comprises a polymer having a fluorine-containing cycloaliphatic structure and at least one coupling group in its molecule and a solvent for dissolving said polymer.Type: GrantFiled: May 9, 1994Date of Patent: April 23, 1996Assignee: Asahi Glass Company, Ltd.Inventors: Masashi Matsuo, Masaru Yamauchi, Nobuko Matsunaga, Shunsuke Yokotsuka, Masao Unoki
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Patent number: 5508323Abstract: A free-flowing silicone polymer powder, having an average particle size of 1 to 1000 microns and prepared by mixing a polydiorganosiloxane with a silica filler, is uniformly dispersed in an organic resin using conventional equipment, such as a single screw or, preferably, a twin screw extruder. When employed at a concentration of about 0.5 to 25 parts by weight of powder per 100 parts by weight of resin, a significant improvement in the burn character of the modified resin is obtained such that the rate of heat release, generation of smoke and evolution of toxic carbon monoxide gas is significantly reduced relative to the unmodified resin.Type: GrantFiled: October 11, 1994Date of Patent: April 16, 1996Assignee: Dow Corning CorporationInventors: David J. Romenesko, Robert R. Buch