Solid Polymer From Ethylenic Reactants Only Derived From Hydrocarbon Reactant Patents (Class 525/130)
  • Patent number: 11394055
    Abstract: An electrolyte for a lithium secondary battery, the electrolyte including: a block copolymer including a structural domain and a rubbery domain, wherein the structural domain includes a structural block including a plurality of structural repeating units, and wherein the rubbery domain includes a rubbery block including a plurality of rubbery repeating units.
    Type: Grant
    Filed: April 1, 2016
    Date of Patent: July 19, 2022
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Yonggun Lee, Yooseong Yang, Wonseok Chang, Hongsoo Choi
  • Patent number: 10590221
    Abstract: Provided is a modified diene based polymer in which a diene based polymer is graft modified with a polyether having a mercapto group attached via diurethane bonding. Formation of diurethane bonding is performed by allowing sequential reactions of two species of hydroxyl group-containing compounds with an diisocyanate compound. By adding the modified diene based polymer to a silica-containing rubber composition for automobile pneumatic tires, the dispersibility of silica compounded in the rubber composition can be improved, and a property inherent in silica which simultaneously allows a reduction of rolling resistance and a stability on wet road surfaces can be sufficiently effected.
    Type: Grant
    Filed: December 2, 2015
    Date of Patent: March 17, 2020
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kazuya Uenishi, Takahiro Okamatsu, Ryota Takahashi
  • Patent number: 9659832
    Abstract: The disclosure relates to a method of making an electronic assembly with a reactive hot-melt adhesive composition that include an atmospheric curing prepolymer and optionally a thermoplastic component with a softening point of at least about 120° C., and the electronic assembly made therewith.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: May 23, 2017
    Assignee: H.B. Fuller Company
    Inventors: Albert M. Giorgini, Andrew Hilley
  • Patent number: 9587067
    Abstract: The present invention generally relates to alcohol-terminated polyisobutylene (PIB) compounds, and to a process for making such compounds. In one embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds, and to a process for making such compounds. In still another embodiment, the present invention relates to polyisobutylene compounds that can be used to synthesize polyurethanes, to polyurethane compounds made via the use of such polyisobutylene compounds, and to processes for making such compounds. In yet another embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds having two or more primary alcohol termini and to a process for making such compounds. In yet another embodiment, the present invention relates to primary terminated polyisobutylene compounds having two or more primary termini selected from amine groups or methacrylate groups.
    Type: Grant
    Filed: October 9, 2015
    Date of Patent: March 7, 2017
    Assignee: THE UNIVERSITY OF AKRON
    Inventors: Joseph Kennedy, Yongmoon Kwon, Subramanyam Ummadisetty
  • Patent number: 9487683
    Abstract: The reactive moisture cure hot melt adhesives of the invention have substantially improved assembly properties as a result of the unique combination of materials that provide excellent green strength. The adhesive includes at least an isocyanate compound, a polyether polyol, an aromatic tackifying composition, a thermoplastic polymer, and a block polymer having at least an A block and at least a B block, wherein the A block comprises a crystalline or semi-crystalline block and the B block comprises a rubbery or amorphous block. Such block polymers can have linear, branched, radial, or dendritic morphologies.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: November 8, 2016
    Assignee: IFS Industries Inc.
    Inventors: William L. Bunnelle, John K. Fromwiller
  • Patent number: 9340639
    Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a bismuth thiophosphoric acid diester salt.
    Type: Grant
    Filed: March 26, 2013
    Date of Patent: May 17, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Richard J. Keaton, Peter M. Margl, Rajat Duggal, Scott D. Boelter, Duane R. Romer, Debra L. Nowlin, Nathan Wilmot, David R. Wilson, Dean M. Welsh
  • Publication number: 20150094425
    Abstract: Provided is a modified diene based polymer in which a diene based polymer is graft modified with a polyether having a mercapto group attached via diurethane bonding. Formation of diurethane bonding is performed by allowing sequential reactions of two species of hydroxyl group-containing compounds with an diisocyanate compound. By adding the modified diene based polymer to a silica-containing rubber composition for automobile pneumatic tires, the dispersibility of silica compounded in the rubber composition can be improved, and a property inherent in silica which simultaneously allows a reduction of rolling resistance and a stability on wet road surfaces can be sufficiently effected.
    Type: Application
    Filed: May 22, 2013
    Publication date: April 2, 2015
    Inventors: Kazuya Uenishi, Takahiro Okamatsu, Ryota Takahashi
  • Patent number: 8987374
    Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: March 24, 2015
    Assignee: The Lubrizol Corporation
    Inventors: Stuart Nicholas Richards, Andrew James Shooter
  • Patent number: 8962771
    Abstract: Elastomer composites are prepared by wetting particles of a natural or synthetic rubber with a liquid one-component moisture-curable resin composition and then exposing the wetted particles to moisture to cure the resin composition. The moisture-curable resin composition comprises (a) an isocyanate-terminated polyurethane prepolymer having an isocyanate content of from 0.5 to 12% by weight and (b) from 1 to 30%, based on the combined weight of components (a) and (b), of an epoxide or lactone compound having a molecular weight of from about 70 to about 1000 and which is miscible in the prepolymer at the relative proportions thereof that are present. In addition, the composition contains no more than 0.1% by weight of compounds having a primary or secondary amino group.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: February 24, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Blndu Radhakrishnan, William Aaron Koonce
  • Publication number: 20150037524
    Abstract: A sustainable thermoplastic composition made by forming a mixture of virgin polypropylene and post-industrial-recycled material (PIR). The PIR may include a thermoplastic, elastomeric-polymer and a spunbond component. The mixture is melt-blended in an extruder. Extruded materials made from the mixture demonstrate little variance in the results of the IZOD Impact Test of materials containing 30 to 70 percent PIR, and a material containing 100 percent virgin polypropylene. In addition, the extruded materials containing 30 to 70 percent PIR demonstrate a substantially constant strain at yield, that strain at yield being substantially equal to that demonstrated by a material containing 100 percent virgin polypropylene.
    Type: Application
    Filed: December 23, 2013
    Publication date: February 5, 2015
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Brent Merrik Thompson, James Hongxue Wang, Gregory James Wideman
  • Publication number: 20150025198
    Abstract: The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties.
    Type: Application
    Filed: February 24, 2014
    Publication date: January 22, 2015
    Applicant: Interface Biologics Inc.
    Inventors: Sanjoy MULLICK, Weilun CHANG, Alexandra PIOTROWICZ, Jeannette HO, Richard WITMEYER
  • Patent number: 8927653
    Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: January 6, 2015
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Shawn Ricci, Michael J. Sullivan, Kevin M. Harris, Pamela V. Arnold
  • Publication number: 20150005450
    Abstract: An adhesive for solar battery back sheets obtainable by mixing (A) a urethane prepolymer having an isocyanate group at the end with (B) a polyol, wherein the urethane prepolymer (A) is obtainable by a reaction of a hydroxyl group-containing compound with an isocyanate compound, and the hydroxyl group-containing compound comprises a polycaprolactone polyol. Also, cured reaction products of the adhesive. Also, a solar battery back sheet and a solar cell module comprising the adhesive.
    Type: Application
    Filed: September 18, 2014
    Publication date: January 1, 2015
    Inventors: Yuichi Matsuki, Noriyoshi Kamai, Yasushi Yamada
  • Patent number: 8877875
    Abstract: The object of the present invention is to provide a golf ball that satisfies both of the flight distance at the shot with a driver, a long iron, and a middle iron and the controllability at the approach shot with a short iron and is also excellent in the abrasion resistance of the cover.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: November 4, 2014
    Assignee: SRI Sports Limited
    Inventors: Kazuya Kamino, Keiji Ohama, Toshiyuki Tarao
  • Patent number: 8853295
    Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: October 7, 2014
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
  • Patent number: 8822031
    Abstract: An adhesive composition that includes: one or more polyester polyether copolymers of formula I: wherein Nu is a predominately cyclic nucleus and R1 is randomly selected from either a C2-6 alkylene or an amorphous, long-chain polyether subunit including a polyoxyalkylene group; one or more polyisocyanate prepolymers that includes the reaction product of: one or more polyols; and a polyfunctional isocyanate having a functionality of more than about 2; polymeric MDI; and a first aromatic or aromatic-aliphatic polymer tackifying resin having a softening point of equal to or greater than about 100° C.
    Type: Grant
    Filed: May 10, 2012
    Date of Patent: September 2, 2014
    Assignee: H.B. Fuller Company
    Inventors: Marietta B. Helmeke, Jeffrey G. Schmierer, Theresa Unze-Schmierer
  • Publication number: 20140231706
    Abstract: A binder for a battery including polyurethane particles and a binder polymer is disclosed. Additionally, a binder composition, and an anode and a lithium battery which include the binder are also disclosed.
    Type: Application
    Filed: February 19, 2014
    Publication date: August 21, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Jun-Kyu Cha, Beom-Wook Lee, Bum-Jin Chang, Myoung-Sun Kim
  • Patent number: 8772409
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: July 8, 2014
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 8680204
    Abstract: The present invention relates to golf balls comprising a crosslinked ionomer composition formed by the reaction of either one or more ionomers, or an ionomer precursor composition, with one or more crosslinking agents including polyisocyanates, blocked polyisocyanates, polyurethane prepolymers, blocked polyurethane prepolymers, polyurea prepolymers, blocked polyurea prepolymers, polyamines, blocked polyamines and dicyanodiamides. The resulting modified ionomer compositions exhibit increased tensile strength and a decrease in tensile elongation as compared to the uncrosslinked ionomer analogs while maintaining Shore D hardness.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: March 25, 2014
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20140058030
    Abstract: Composite materials including rubber particles and silane-terminated polyurethane binders are disclosed.
    Type: Application
    Filed: August 23, 2012
    Publication date: February 27, 2014
    Applicant: Bayer MaterialScience LLC
    Inventors: Jay A. Johnston, Sandrea Zielinski
  • Publication number: 20140018501
    Abstract: In the belt according to the present invention, the whole or a part of a belt body is formed from a thermoplastic resin composition (C) comprising a thermoplastic resin (A) and a modified ethylene copolymer (B) dispersed and contained therein. The modified ethylene copolymer (B) is preferably a copolymer, modified with an unsaturated carboxylic acid or a derivative thereof, of ethylene with at least one monomer component selected from (i) olefin components except for ethylene, (ii) diene components and (iii) ester components having an ethylenically unsaturated group. The belt according to the present invention hardly causes abrasion, damage, cracks, breakage and the like on the belt body and is remarkably excellent in durability, even if the belt is used at a high load for a long time.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 16, 2014
    Applicant: NITTA CORPORATION
    Inventors: Takahiko Yoshida, Shoji Shimizu, Akihiko Matsumoto
  • Publication number: 20140017429
    Abstract: The thermoplastic resin composition according to the present invention includes a thermoplastic resin (A), and a modified ethylene copolymer (B) dispersed and contained therein, wherein the modified ethylene copolymer (B) in the thermoplastic resin composition has an average dispersed particle aspect ratio of 1 to 3.5, and an average dispersed particle diameter of not more than 3 ?m. The modified ethylene copolymer (B) is preferably a copolymer, modified with an unsaturated carboxylic acid or a derivative thereof, of ethylene with at least one monomer component selected from the group consisting of (i) olefin components except for ethylene, (ii) diene components and (iii) ester components having an ethylenically unsaturated group.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 16, 2014
    Applicant: NITTA CORPORATION
    Inventors: Toshiaki Kasazaki, Takahiko Yoshida, Shoji Shimizu, Shinsuke Uegaki, Yoko Onishi
  • Patent number: 8629228
    Abstract: Certain disclosed embodiments of the present invention concern a golf ball, including a core having a center, an outer cover layer, and optionally one or more intermediate layers, where at least one or more of the core, outer cover layer, or one or more intermediate layers if present, includes an isobutylene maleic anhydride copolymer having the general formula where n is greater than 10 and having a weight average molecular weight Mw of greater than about 2,000. The present invention also relates to golf ball including a core having a center, an outer cover layer; and optionally one or more intermediate layers, where at least one or more of the core, outer cover layer, or one or more intermediate layers if present, includes an isobutylene maleic anhydride ionomer formed by hydrolysis and neutralization of the isobutylene maleic anhydride copolymer.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: January 14, 2014
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 8598275
    Abstract: A golf ball has a layer comprising a compatibilized blend of thermoplastic polyurethane, polyolefin, and hydrophobic thermoplastic polyurethane. The layer may be part of the cover, for example an inner layer of a two-layer cover layer. The layer may be an intermediate layer between the core and the cover.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: December 3, 2013
    Assignee: Nike, Inc.
    Inventor: Bradley C. Tutmark
  • Patent number: 8575280
    Abstract: Disclosed is a thermosetting resin composition including; (A) a carboxyl group-containing polyurethane prepared by using (a) a polyisocyanate compound (b) polyol compounds (c) a carboxyl group-containing dihydroxy compound as raw materials, (B) a curing agent, wherein the polyol compounds (b) are one or more kinds of polyol compound(s) selected from Group (I) and one or more kinds of polyol compound(s) selected from Group (II); Group I: polycarbonate polyol, polyether polyol, polyester polyol, and polylactone polyol, Group II: polybutadiene polyol, polysilicone having terminal hydroxyl groups, and such a polyol that has 18 to 72 carbon atoms and oxygen atoms present only in hydroxyl groups. The thermosetting resin composition can give a protection film for flexible printed circuits that has excellent long-term reliability of electric insulation, flexibility, and low warpage from curing shrinkage, and particularly low tackiness.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: November 5, 2013
    Assignee: Showa Denko K.K.
    Inventors: Hiroshi Uchida, Ritsuko Azuma
  • Patent number: 8563654
    Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75, and the cover has a thickness of 2.5 mm or less.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: October 22, 2013
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8461268
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: June 11, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8450397
    Abstract: The present invention provides a golf ball comprising a core and a cover covering the core, wherein the cover is formed from a cover composition containing a non-petroleum based polyester resin as a resin component (A) and a needle-like and/or fibrous filler (B). The present invention further provide a golf ball comprising a core and a cover covering the core, wherein the cover is formed from a cover composition containing, a non-petroleum based polyester resin (A-1), at least one petroleum based thermoplastic resin (A-2), and a compatibilizer (C) containing at least a (meth)acrylic resin (C-1) having a polar functional group and an olefin resin (C-2) having a polar functional group. According to the present invention, durability, abrasion resistance and repulsion of a golf ball can be improved.
    Type: Grant
    Filed: September 24, 2008
    Date of Patent: May 28, 2013
    Assignee: Dunlop Sports Co. Ltd.
    Inventor: Satoko Okabe
  • Patent number: 8450419
    Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: May 28, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Publication number: 20130074718
    Abstract: A laser-engraveable flexographic printing precursor or patternable element comprises a laser-engraveable layer having two orthogonal dimensions. This laser-engraveable layer comprises one or more elastomeric resins and non-metallic fibers that are oriented in the laser-engraveable layer predominantly in one of its two orthogonal dimensions. The non-metallic fibers have an average length of at least 0.1 mm and an average diameter of at least 1 ?m. The oriented non-metallic fibers reduce curl and shrinkage in the precursor and improve print quality and press life.
    Type: Application
    Filed: September 27, 2011
    Publication date: March 28, 2013
    Inventors: Ido Gal, Ophira Melamed
  • Patent number: 8404780
    Abstract: The adhesion between a low surface energy (i.e., nonpolar) material, e.g., a polyolefin such as polyethylene, and a high surface energy (i.e., polar) material, e.g., a polyester, polyurethane, polycarbonate or polylactic acid, is promoted by blending with the nonpolar material typically from 15 to less than 50 wt % of a diol-based thermoplastic polyurethane (d-TPU), e.g., a polydiene diol-based TPU, based on the combined weight of the nonpolar material and the d-TPU. The promoted adhesion allows for the effective painting, printing, over-molding or HF-welding of a nonpolar substrate, e.g., a polyolefin film, with a polar coating, e.g., a paint, ink, etc. Aqueous dispersions can also be made from the blend of nonpolar material and d-TPU.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 26, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Laura B. Weaver, Ashish Batra, Patricia Ansems, Gary M. Strandburg, Matthew J. Kalinkowski
  • Publication number: 20130037213
    Abstract: The present disclosure relates to impact strength modifiers, the derivative products thereof, and the use thereof in producing two-component epoxy resin compositions. The disclosure in particular relates to amino group terminated impact strength modifiers prepared by reacting a polyurethane prepolymer having isocyanate groups, a primary diamine, and optionally at least one Michael acceptor. The two-component epoxy resin compositions thus formulated are characterized by a great increase in impact strength while retaining an acceptable tensile shear strength. The impact strength modifiers according to the disclosure and the epoxy resin compositions comprising same are in particular suitable for vehicle manufacturing.
    Type: Application
    Filed: September 4, 2012
    Publication date: February 14, 2013
    Applicant: Sika Technology AG
    Inventors: Karsten FRICK, Jürgen FINTER, Andreas KRAMER, Ulrich GERBER
  • Patent number: 8372914
    Abstract: Urethane modified water-reducible alkyd resins ABCD, comprising moieties derived from polyhydric alcohols A, modified fatty acids B made h? grafting olefinically unsaturated carboxylic acids B2 onto fatty acids B1, ungrafted fatty acids C and polyfunctional isocyanates D, a process for their production, and a method of use thereof in coating binders
    Type: Grant
    Filed: February 20, 2006
    Date of Patent: February 12, 2013
    Assignee: Cytec Surface Specialties Austria GmbH
    Inventors: Gerhard Reidlinger, Edmund Urbano, Ewald Zrin, Manfred Gogg, Johannes Scherz
  • Patent number: 8367781
    Abstract: The invention provides a golf ball having a core and one or more cover layer encasing the core, wherein at least one cover layer is formed by injection-molding a single resin composition of primarily (A) a thermoplastic polyurethane and (B) a polyisocyanate compound, and at least some polyisocyanate compound in which all the isocyanate groups on the molecule remain in an unreacted state is present in the resin composition. The golf ball has a high rebound, an excellent spin performance and an excellent scuff resistance, and the cover layer-forming resin composition has excellent flow properties and an excellent cover layer manufacturability.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: February 5, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroyuki Nagasawa, Hiroshi Higuchi, Motoki Aoyagi, Daisuke Arai
  • Patent number: 8362149
    Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: January 29, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
  • Patent number: 8318305
    Abstract: A resin composition comprising a fiber component and a resin component, wherein the fiber component is (A) a surface-treated fiber (component A) which comprises 100 parts by weight of a fiber comprising a polyalkylene terephthalate and/or a polyalkylene naphthalene dicarboxylate (component Af) and 0.1 to 10 parts by weight of a sizing agent having a glass transition point of ?80° C. or higher and lower than 70° C.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: November 27, 2012
    Assignees: Sumitomo Chemical Company, Limited, Teijin Fibers Limited
    Inventors: Kenji Watanabe, Kenji Atarashi, Kumiko Chatani, Motoomi Arakawa
  • Publication number: 20120288720
    Abstract: An adhesive composition that includes: one or more polyester polyether copolymers of formula I: wherein Nu is a predominately cyclic nucleus and R1 is randomly selected from either a C2-6 alkylene or an amorphous, long-chain polyether subunit including a polyoxyalkylene group; one or more polyisocyanate prepolymers that includes the reaction product of: one or more polyols; and a polyfunctional isocyanate having a functionality of more than about 2; polymeric MDI; and a first aromatic or aromatic-aliphatic polymer tackifying resin having a softening point of equal to or greater than about 100° C.
    Type: Application
    Filed: May 10, 2012
    Publication date: November 15, 2012
    Applicant: H.B. Fuller Company
    Inventors: Marietta B. Helmeke, Jeffrey G. Schmierer, Theresa Unze-Schmierer
  • Patent number: 8288476
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: October 16, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8288477
    Abstract: Flowable bioabsorbable compounds are provided which are useful in producing surgical adhesive or sealant compositions.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: October 16, 2012
    Assignee: Tyco Healthcare Group LP
    Inventors: Ahmad R. Hadba, John Kennedy, Nadya Belcheva, Jon T. Reinprecht, Sajida S. Faroogi
  • Patent number: 8193283
    Abstract: Disclosed are golf balls having soft, resilient bimodal ionomeric covers with improved softness and scuff resistance and methods for their preparation. The soft, resilient bimodal ionomeric covers comprise at least partially neutralized mixtures of carboxylate functionalized terpolymers (molecular weight between about 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (molecular weight between about 2,000 and 30,000).
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: June 5, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John Chu Chen
  • Publication number: 20120045651
    Abstract: A composition of matter comprising a hydrophobic or hydrophilic (or both) interpenetrating polymer network containing a non-ionic/ionic polymer and a hydrophobic thermoset or thermoplastic polymer, articles made from such composition and methods of preparing such articles. The invention also includes a process for preparing a hydrophobic/hydrophilic IPN or semi-IPN from a hydrophobic thermoset or thermoplastic polymer including the steps of placing an non-ionizable/ionizable monomer solution in contact with a hydrophobic thermoset or thermoplastic polymer; diffusing the monomer solution into the hydrophobic thermoset or thermoplastic polymer; and polymerizing the monomers to form a penetrating polymer inside the hydrophobic thermoset or thermoplastic polymer, thereby forming the IPN or semi-IPN.
    Type: Application
    Filed: August 26, 2011
    Publication date: February 23, 2012
    Inventors: David Myung, Michael J. Jaasma, Lampros Kourtis, Daniel Chang, Curtis W. Frank
  • Publication number: 20120037410
    Abstract: A thermoplastic resin composition including a polyphenylene ether-based polymer having hydroxyl groups in its chemical structure and having 2,6-dimethylphenylene ether as a repeating unit, an isocyanate compound having a plurality of isocyanate groups in its structure; or a reaction product of the polyphenylene ether-based polymer having 2,6-dimethylphenylene ether as a repeating unit and the isocyanate compound having a plurality of isocyanate groups in its structure; and a hydrogenated styrene-based elastomer, and an adhesive film and a wiring film using the same are disclosed.
    Type: Application
    Filed: August 10, 2011
    Publication date: February 16, 2012
    Inventors: Satoru Amou, Kosuke Kuwabara, Nobuhito Akutsu, Tomiya Abe
  • Publication number: 20120028020
    Abstract: The present invention relates to the use of an adhesive compound, in particular a pressure-sensitive adhesive compound, based on silylated polyurethanes for bonding optical components, in particular optical films, wherein the adhesive compound has a transmission according to ASTM D 1003 of greater than 86% and a haze according to ASTM D 1003 of less than 5%.
    Type: Application
    Filed: February 16, 2010
    Publication date: February 2, 2012
    Applicant: tesa SE
    Inventor: Nils Utesch
  • Patent number: 8106115
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: January 31, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8106125
    Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: January 31, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
  • Patent number: 8053524
    Abstract: A golf ball material composed of (A) an olefin-containing thermoplastic polymer having an acid content of at least 0.5 wt % but less than 5.0 wt %, (B) a resin composition which includes one or more selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) an oxygen-containing inorganic metal compound has a good thermal stability, flow and processability, making it suitable for injection molding. The golf ball material is ideal for the production of high-performance golf balls endowed with durability, scuff resistance and optimal hardness without a loss of rebound in the molded article.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: November 8, 2011
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8048958
    Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a polyisocyanate (b-1) having at least three isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and the cover has the thickness of 2.5 mm or less.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: November 1, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8022141
    Abstract: In a golf ball composed of a core and a cover having a plurality of layers that encloses the core, at least a first layer of the cover is formed primarily of a heated mixture of (A) a metal ion neutralization product of an olefin-unsaturated carboxylic acid copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer, (B) at least one type of olefin-unsaturated carboxylic acid copolymer and/or olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having the same content of unsaturated carboxylic acid as component A, and (C) a thermoplastic polyurethane elastomer; and at least one other cover layer adjoining the at least first cover layer is formed primarily of a non-ionomeric thermoplastic elastomer.
    Type: Grant
    Filed: April 20, 2009
    Date of Patent: September 20, 2011
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Rinya Takesue
  • Patent number: 8017690
    Abstract: An object of the present invention is to provide a golf ball comprising a core consisting of a center and at least one intermediate layer covering the center, and a cover covering the core, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and at least one piece or one layer of the intermediate layer is formed from a low hardness intermediate layer composition which has a slab hardness of 40 or less in Shore D hardness.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: September 13, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8003730
    Abstract: An epoxy resin mixture with at least one epoxy resin of between approximately 60 wt % and 90 wt %, a maleic anhydride of between approximately 1 wt % and approximately 30 wt %, and an imidazole catalyst of less than approximately 2 wt % where the resin mixture is formed from at least one epoxy resin with a 1-30 wt % maleic anhydride compound and an imidazole catalyst at a temperature sufficient to keep the maleic anhydride compound molten, the resin mixture reacting to form a foaming resin which can then be cured at a temperature greater than 50° C. to form an epoxy foam.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: August 23, 2011
    Assignee: Sandia Corporation
    Inventor: Mathias C. Celina