Contacting Two Or More Solid Polymers With A Phenolic Reactant; Or Contacting A Solid Polymer With A Phenolic Reactant And Subsequently Contacting The Treated Polymer With An Additional Solid Polymer Patents (Class 525/133)
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Patent number: 8273825Abstract: A method of making resin composition having excellent wear properties that includes 50 to 99 wt. % of a polycarbonate resin and from 1 to 50 wt. % of a polyolefin that has been modified with at least one functional group selected from a carboxyl, an acid anhydride, an epoxy groups or mixtures containing at least one of the foregoing functional groups, each based on the total combined weight of the resin composition, exclusive of any filler. The resin composition optionally contains an unmodified polyolefin and/or a bi-functional monomer. The resin composition can be molded into articles having improved wear characteristics. The process is a one-step process that improves the efficiency and/or yield of the resin composition as compared to prior-art two-step processes.Type: GrantFiled: March 20, 2007Date of Patent: September 25, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ye-Gang Lin, Donghai Sun, David Xiangping Zou
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Patent number: 8268450Abstract: Thermoplastic polyamide resin compositions include the essential components of polyamide resins, polyalcohol and epoxy resin, and, optionally, one or more additives selected from among thermoplastic impact modifiers, reinforcement agents, and polyoxides; such thermoplastic polyamide resin compositions provide superior impact resistance, heat resistance, low degree of deformation, low degree of contraction, and external appearance, but also superior paint adhesion properties without requiring a primer, and function as an adhesion medium that advantageously may be applied to the interior and exterior parts of an automobile requiring painting.Type: GrantFiled: June 27, 2008Date of Patent: September 18, 2012Assignee: Rhodia Polyamide Co., Ltd.Inventors: Lee-Wook Jang, Yeong-Chool Yu, Jong-Su Lee
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Patent number: 8211979Abstract: A multicomponent system is provided, composed of a thermoplastic component and of a rubber component, which comprises at least two different peroxidic crosslinking agents with specific decomposition temperatures, as also is a process for production of rubber-thermoplastic composite mouldings using the multicomponent system, and also the resultant rubber-thermoplastic composite mouldings.Type: GrantFiled: December 15, 2006Date of Patent: July 3, 2012Assignee: LANXESS Deutschland GmbHInventors: Dirk Achten, Stefanie Nickel, Maik Schulte, Michael Münker, Detlev Joachimi
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Publication number: 20120149837Abstract: A thermoplastic resin composition obtained by mixing 100 parts by weight of at least one thermoplastic resin (A) with 0.1 to 4 parts by weight of (B) a polyfunctional compound having three or more functional groups in which at least one of the terminal structures haying the functional groups is a structure represented by formula (1): where R is an alkylene group with 1-15 carbon atoms; n is an integer of 1 to 10; and X is at least one functional group selected from the group consisting of hydroxyl group, aldehyde group, carboxyl group, sulfo group, amino group, isocyanate group, carbodiimide group, oxazoline group, oxazine group, amide group, silanol group and silyl ether group.Type: ApplicationFiled: January 27, 2012Publication date: June 14, 2012Applicant: TORAY INDUSTRIES, INC.Inventors: Sadanori Kumazawa, Hiroyuki Ohme, Yuki Amano, Takamasa Owaki
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Patent number: 8188186Abstract: An object of the present invention is to provide a golf ball having excellent durability and flight distance. The present invention provides a golf ball comprising: a core consisting of a center and one or more intermediate layers covering the center; and a cover covering the core, wherein, at least one piece or one layer of said intermediate layers is formed from a highly elastic intermediate layer composition that contains a highly elastic resin (A) having a flexural modulus in a range from 700 MPa to 5000 MPa and an ionomer resin (B) having a flexural modulus in a range from 150 MPa to 1000 MPa in an amount ratio ((A)/(B)) of the highly elastic resin (A) to the ionomer resin (B) being (20 mass % to 80 mass %)/(80 mass % to 20 mass %) (the total is 100 mass %).Type: GrantFiled: April 17, 2009Date of Patent: May 29, 2012Assignee: SRI Sports LimitedInventor: Satoko Okabe
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Patent number: 8158038Abstract: A halogenated aryl ether oligomer is formed by halogenation of an aryl ether oligomer and is useful as a flame retardant for flammable macromolecular materials. Typically, the halogenated aryl ether oligomer comprises the following repeating monomeric units: wherein R is hydrogen or alkyl, especially C1 to C4 alkyl, Hal is halogen, m is at least 1, n is 0 to 3 and x is at least 2.Type: GrantFiled: October 22, 2010Date of Patent: April 17, 2012Assignee: Chemtura CorporationInventors: Larry D. Timberlake, James D. Siebecker
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Patent number: 8114928Abstract: Disclosed is a transparent/translucent molding composition and process for making prepared from an impact modifier and a resin blend of polycarbonate and a cycloaliphatic polyester having a matching index of refraction.Type: GrantFiled: June 21, 2010Date of Patent: February 14, 2012Assignee: SABIC Innovative Plastics IP BVInventors: Satish Kumar Gaggar, Johannes Jacobus de Moor, Paul Honigfort, Gabrie Hoogland, Mark van Heeringen, Eelco M. S. van Hamersveld
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Patent number: 8114929Abstract: A composition comprising a clear thermoplastic blend comprising: (a) a polycarbonate component; and (b) a polyester component comprising (i) a polyester based substantially on 1,4 cyclohexane dimethanol and terephthalic acid monomer units, (ii) copolymers polyester based substantially on 1,4 cyclohexane dimethanol and terephthalic acid monomer units and modified with up to 25 mol % of copolymerizable acid and/or diol monomers, and (iii) combinations thereof. The polycarbonate component and the polyester component are present in sufficient proportions to form a molding composition capable of being molded into an article that exhibits transparency and structural integrity after the article is exposed to a caustic aqueous environment for at least 70 hours. The invention also relates to articles made from the composition, methods for making the compositions, and methods for using articles.Type: GrantFiled: December 19, 2006Date of Patent: February 14, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Parminder Agarwal, Rodney W. Fonseca
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Publication number: 20120010365Abstract: A method of making resin composition having excellent wear properties that includes 50 to 99 wt. % of a polycarbonate resin and from 1 to 50 wt. % of a polyolefin that has been modified with at least one functional group selected from a carboxyl, an acid anhydride, an epoxy groups or mixtures containing at least one of the foregoing functional groups, each based on the total combined weight of the resin composition, exclusive of any filler. The resin composition optionally contains an unmodified polyolefin and/or a bi-functional monomer. The resin composition can be molded into articles having improved wear characteristics. The process is a one-step process that improves the efficiency and/or yield of the resin composition as compared to prior-art two-step processes.Type: ApplicationFiled: September 20, 2011Publication date: January 12, 2012Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Ye-Gang Lin, Donghai Sun, David Xiangping Zou
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Publication number: 20110306730Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: ApplicationFiled: August 23, 2011Publication date: December 15, 2011Applicant: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20110254204Abstract: The present invention relates to methods of modulating the gloss of plastics materials and products made from them, such as articles in the automotive industry e.g. for the interior of automobiles, as well as the use of certain additives for that purpose and related invention embodiments. The modulating comprises adding a modified polymer as matting agent to a polymer composition used as polymer substrate for the articles.Type: ApplicationFiled: October 21, 2009Publication date: October 20, 2011Applicant: BASF SEInventors: Martin Brunner, Gregor Huber, Laurent Simonpietri, Michael Tinkl
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Publication number: 20110256395Abstract: A pressure-sensitive adhesive consisting of a homogeneous mixture of at least one natural rubber component and at least one polyacrylate component displays significantly improved properties in cohesion and aging and weathering resistance compared to the individual components. Particularly good properties are achieved when the adhesive contains x% by weight of at least one natural rubber component, y% by weight of at least one polyacrylate component, v% by weight of at least one adhesive resin component and w% by weight of additives, where 10?×x?80, 10?y<95, 0?v?50, 0?w?10 and x+y+v+w=100. A single- or double-sided adhesive tape consisting of at least one support and at least one layer of such a pressure-sensitive adhesive therefore likewise has good cohesion and aging resistance properties.Type: ApplicationFiled: December 7, 2009Publication date: October 20, 2011Applicant: TESA SEInventors: Franziska Zmarsly, Sabine Thormeier, Christian Kreft, Axel Burmeister, Stephan Bunz
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Patent number: 8039526Abstract: A method for preparing a nanoclay-filled thermoplastic vulcanizate, the method comprising introducing an olefinic thermoplastic vulcanizate, a functionalized thermoplastic resin, and a surface-modified nanoclay, where the blending takes place at a temperature above the melt temperature of the thermoplastic vulcanizate but below the temperature at which the surface-modified nanoclay degrades.Type: GrantFiled: April 5, 2006Date of Patent: October 18, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria Dolores Ellul, Paul Edward McDaniel, Thomas Gregory Lengyel
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Publication number: 20110251325Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.Type: ApplicationFiled: June 21, 2011Publication date: October 13, 2011Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Allen Wai-Yee Ko, Michael L. Todt
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Patent number: 8034857Abstract: Compositions comprise phase separated polyetherimide/polyphenylene ether sulfone blends. The dispersed phase has an average cross sectional size of 0.1 to 10 micrometers. The composition retains has good hydrolytic stability and is capable of withstanding steam autoclaving at temperatures of 130 to 138° C.Type: GrantFiled: September 11, 2007Date of Patent: October 11, 2011Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ganesh Kailasam, Robert R Gallucci, Mark Alan Sanner
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Patent number: 8013066Abstract: A process for the production of impact-modified composition that contains polyalkylene terephthalate and polycarbonate resins is disclosed. The process includes (i) in a first step combining in the melt at 90 to 175° C. glycidyl ester with at least one member selected from the first group consisting of polyalkylene terephthalate and polycarbonate to obtain a molten mixture, said member in powder form, and (ii) in a subsequent step combining the molten mixture with at least one component selected from the second group consisting of polyalkylene terephthalate and polycarbonate to obtain a composition. The composition is characterized in high gloss value.Type: GrantFiled: June 14, 2007Date of Patent: September 6, 2011Assignee: Bayer MaterialScience AGInventor: Pierre Moulinie
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Publication number: 20110168288Abstract: Flexible pipe (fP) suitable for transporting hydrocarbons, said flexible pipe comprising at least one polymer layer (L) composed of a polymer composition (C) comprising at least one poly(aryl ether ketone) (P1), and at least one per(halo)fluoropolymer (P2). The poly(aryl ether ketone) (P1) and the per(halo)fluoropolymer (P2) are advantageously homogeneously distributed in the polymer composition (C). The polymer composition (C) is profitably prepared by a method comprising tumble blending the per(halo)fluoropolymer (P2) on one hand, and the poly(aryl ether ketone) (P1) or part of the poly(aryl ether ketone) (P1) on the other hand.Type: ApplicationFiled: September 18, 2009Publication date: July 14, 2011Applicant: SOLVAY ADVANCED POLYMERS, L.L.C.Inventors: Shari W. Axelrad, Mohammad Jamal El-Hibri, Brian A. Stern, Johan Billiet, Brian Alexander
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Publication number: 20110166286Abstract: There is described a powder composition curable by radiation and thermally, comprising a mixture of (a) from about 1% to about 15%, by weight of the mixture, of a polyester of Tg?40° C.Type: ApplicationFiled: April 18, 2008Publication date: July 7, 2011Inventor: Luc Moens
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Patent number: 7932314Abstract: This invention relates to a thermoplastic polymer composition that exhibits an excellent combination of properties for use in manufacturing shipping combs for use in conjunction with moving actuators for hard disk drives. The thermoplastic polymer composition of this invention is comprised of (1) from 10 weight percent to 90 weight percent polycarbonate, (2) from 1 weight percent to 6 weight percent carbon nanotubes, (3) from 5 weight percent to 85 weight percent of a sulfone polymer, (4) from 0.5 weight percent to 10 weight percent of a functionalized rubbery polymer, and (5) from 0.5 weight percent to 5 weight percent of a lubricant selected from the group consisting of high density polyethylene and polyester wax, wherein all weight percentages are based upon the total weight of the thermoplastic polymer composition.Type: GrantFiled: July 28, 2008Date of Patent: April 26, 2011Assignee: Ovation Polymer Technology and Engineered Materials, Inc.Inventors: Hrishikesh Manian, Nishant Negandhi
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Patent number: 7851529Abstract: Provided are a polycarbonate resin composition which does not contain halogen and phosphorus as a flame retardant component and which is excellent in a fluidity while maintaining a flame resistance, a heat resistance and an impact resistance and a molded article thereof.Type: GrantFiled: November 26, 2007Date of Patent: December 14, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kenichi Mitsuhashi, Akio Nodera, Hiroshi Kawato, Toshio Isozaki
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Patent number: 7772323Abstract: The present invention relates to conjugated copolymers comprising blocks which are linked by random or partly random sections. The materials of the invention display an improved efficiency, a reduced operating voltage and a longer life.Type: GrantFiled: August 12, 2004Date of Patent: August 10, 2010Assignee: Merck Patent GmbHInventors: Heinrich Becker, Esther Breuning, Aurélie Falcou, Amir Parham
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Patent number: 7767738Abstract: Disclosed is a transparent/translucent molding composition and process for making prepared from an impact modifier and a resin blend of polycarbonate and a cycloaliphatic polyester having a matching index of refraction.Type: GrantFiled: October 5, 2005Date of Patent: August 3, 2010Assignee: Sabic Innovative Plastics IP B.V.Inventors: Satish Kumar Gaggar, Johannes Jacobus de Moor, Paul Honigfort, Gabrie Hoogland, Mark van Heeringen, Eelco M. S. van Hamersveld
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Publication number: 20100173164Abstract: The adhesive film of the present invention is adapted to be used for bonding a semiconductor element and a substrate together or bonding semiconductor elements together. The adhesive film is formed of a resin composition containing an epoxy resin, an acrylic resin, and an acrylic oligomer having a weight average molecular weight of 6,000 or less. The resin composition is characterized in that in the case where an amount of the acrylic resin contained in the resin composition is defined as Wa and an amount of the acrylic oligomer contained therein is defined as Wb, a ratio of Wa/Wb is in the range of 0.5 to 4. Further, the semiconductor device of the present invention is characterized in that a semiconductor element and a substrate or semiconductor elements are bonded together using the above mentioned adhesive film.Type: ApplicationFiled: December 27, 2007Publication date: July 8, 2010Applicant: SUMITOMO BAKELITE COMPANY LIMITEDInventor: Masato Yoshida
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Patent number: 7728060Abstract: A rubber component containing at least one of diene rubber and ethylene-propylene-diene rubber is dynamically crosslinked. Thereby the rubber component is dispersed in a mixture of a thermoplastic elastomer and a thermoplastic resin. An ethylene oxide-propylene oxide-allyl glycidyl ether and an anion-containing salt having fluoro groups and sulfonyl groups are added to the elastomer composition to obtain a conductive dynamically crosslinked thermoplastic elastomer composition. A mixture of the obtained conductive dynamically crosslinked thermoplastic elastomer composition and a micro-capsule composed of a polymer, having acrylic groups, which forms an outer shell thereof is molded to obtain a conductive roller having Shore A hardness specified in JIS K6253 not more than 40 measured at 23° C.Type: GrantFiled: August 23, 2007Date of Patent: June 1, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Akira Minagoshi, Kei Tajima
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Patent number: 7655727Abstract: A process for the preparation of dynamically vulcanized thermoplastic elastomers comprising melt processing under shearing conditions in melt reaction extruder, A) at least one thermoplastic resin, B) at least one vulcanizable gas-phase elastomer having a Mooney viscosity (ML.sub.1+4(125° C.)) of from about 65 to about 450, C) a curing agent or agents, and D) process oil, wherein said process oil D) is added to the extruder in at least three oil injection positions located a) at least one location before or within the first 15% of the total length of the extruder; b) at least one other location prior to, at or within 10% total extruder length after the onset of the vulcanization of said gas-phase elastomer; and c) at least one location subsequent to the location of the point at which the vulcanization of said gas-phase elastomer is substantially completed.Type: GrantFiled: December 9, 2005Date of Patent: February 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria D. Ellul, Jianya Cheng
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Patent number: 7615522Abstract: The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.Type: GrantFiled: April 29, 2003Date of Patent: November 10, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Hugo Camenzind, Paul Dubs, Peter Hänggi, Roger Martin, Andreas Mühlebach, François Rime
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ADHESIVE COMPOSITIONS USEFUL IN FLEXIBLE CIRCUIT SUBSTRATE APPLICATIONS AND METHODS RELATING THERETO
Publication number: 20090253834Abstract: This invention is directed to an adhesive composition having (1) a elastomer component, (2) a resole phenolic resin, and (3) a flame retardant resin that is not (2) a resole phenolic resin. Further, the adhesive compositions of the invention includes (1) a elastomer component and (2) a resole phenolic resin, wherein the (2) resole phenolic resin content is 20 to 50 wt % based on the total amount of the adhesive composition excluding any solvent.Type: ApplicationFiled: November 11, 2008Publication date: October 8, 2009Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: TAKASHI KINO, Tsutomu Mutoh -
Patent number: 7592464Abstract: Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 99 weight percent phenolphthalein, based on the total weight of the phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is purified by a combination of techniques to produce a solid comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine with sufficient purity to be used as a monomer in the synthesis of clear polymers.Type: GrantFiled: March 30, 2007Date of Patent: September 22, 2009Assignee: SABIC Innovative Plastics IP BVInventors: Rajshekhar Basale, Hyacinth Mary Bastian, Balakrishnan Ganesan, Venkata Rama Narayanan Ganapathy Bhotla, Gurram Kishan, Pushpa Narayanan, Swaminathan Shubashree, Ravindra Vikram Singh
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Patent number: 7514524Abstract: Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 95 weight percent phenolphthalein, based on the total weight of phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is then triturated with a trituration solvent and washed to obtain a second solid, wherein the second solid comprises greater than or equal to 97 weight percent 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, based on the total weight of the second solid. The second solid may be polymerized to form a polycarbonate.Type: GrantFiled: March 30, 2007Date of Patent: April 7, 2009Assignee: SABIC Innovative Plastics IP B.V.Inventors: Rajshekhar Basale, Balakrishnan Ganesan, Venkata Rama Narayanan Ganapathy Bholta, Gurram Kishan, Surendra Kulkarni, Pradeep Nadkarni, Suresh Shanmugam, Ravindra Vikram Singh
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Patent number: 7498401Abstract: A thermoplastic composition, contains a polycarbonate resin, a polycarbonate-polysiloxane copolymer, an aromatic vinyl copolymer, an impact modifier, and a mineral filler, wherein the composition has least about 40% ductility under multiaxial impact strength test conditions per ASTM D3763 at ?30° C. Alternatively, a composition contains a polycarbonate resin, a polycarbonate-polysiloxane copolymer in an amount sufficient to provide at least about 2.5 wt. % siloxane by weight of the composition, an aromatic vinyl copolymer comprising SAN, an impact modifier comprising ABS, and a mineral filler. Such compositions may be made by combining, by weight of the composition, polycarbonate resin, a polycarbonate-polysiloxane copolymer, an aromatic vinyl copolymer, an impact modifier, and a mineral filler, wherein the composition has at least 40% ductility under multiaxial impact strength test conditions per ASTM D3763 at ?30° C.Type: GrantFiled: March 3, 2005Date of Patent: March 3, 2009Assignee: SABIC Innovative Plastics IP B.V.Inventor: Naveen Agarwal
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Patent number: 7439304Abstract: A composition comprising (i) a dynamically-cured rubber, (ii) from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber, (iii) from 0.2 to 0.9 parts by weight stannous chloride per 100 parts by weight rubber, and (iv) from 0.25 to 4.0 parts by weight metal oxide per 100 parts by weight rubber.Type: GrantFiled: September 1, 2004Date of Patent: October 21, 2008Assignee: Advanced Elastomer Systems, L.P.Inventors: Maria D. Ellul, Christopher Hrbacek
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Patent number: 7411021Abstract: A clear thermoplastic blend comprises from about 25 to about 90 percent by weight of low flow polycarbonate resin having a MVR (Melt Viscosity Rate) of from about 1 to about 7 cc/10 min at 300° C./1.2 kg and from about 10 to about 75 percent by weight of a polyester resin derived from the condensation of a cyclohexanedimethanol or equivalent thereof alone or with an ethylene glycol or equivalent thereof with a terephthalic acid or equivalents thereof or a combination of terephthalic acid and isophthalic acid or equivalents thereof.Type: GrantFiled: November 2, 2004Date of Patent: August 12, 2008Assignee: SABIC Innovative Plastics IP B.V.Inventors: Huiping Zhang, Peter H. Th. Vollenberg
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Patent number: 7365124Abstract: A polymer blend consisting essentially of at least one thermoplastic polymer, and a polymer comprising structural units derived from a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine is disclosed.Type: GrantFiled: August 24, 2004Date of Patent: April 29, 2008Assignee: General Electric CompanyInventors: Veeraraghavan Srinivasan, Chandrashekhar Lingannaiah, Anantharaman Dhanabalan
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Patent number: 7365125Abstract: A thermoplastic composition, comprising: about 10 to about 84 wt. % of a polycarbonate resin; about 0.5 to about 40 wt. % of a polycarbonate-polysiloxane copolymer; 1 to about 40 wt. % of an impact modifier composition; and about 1 to about 50 wt. % of an alkyl (meth)acrylate polymer; each based on the total combined weight of the thermoplastic composition, exclusive of any filler. In another embodiment, the thermoplastic composition may comprise about 10 to about 85 wt. % of a polycarbonate resin; about 1 to about 40 wt. % of an impact modifier composition; and about 1 to about 50 wt. % of an impact-modified alkyl (meth)acrylate polymer; each based on the total combined weight of the thermoplastic composition, exclusive of any filler. The compositions have improved weld line strength, and are useful in the manufacture of molded parts, especially for electronic devices.Type: GrantFiled: August 16, 2004Date of Patent: April 29, 2008Assignee: General Electric CompanyInventors: Luc Govaerts, Wim Steendam, Rob Venderbosch
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Patent number: 7268193Abstract: Branched polyarylene polymers are provided comprising monovalent endcappers, divalent linear units, and polyvalent branching units. The composition of the polymers is controlled by adjusting the ratio of the three types of monomers.Type: GrantFiled: March 4, 2005Date of Patent: September 11, 2007Assignee: Mississippi Polymer Technologies, Inc.Inventors: Matthew L. Marrocco, III, Mark S. Trimmer, Ying Wang
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Patent number: 7265172Abstract: Thermoplastic molding composition comprising components A, B, C and D and, if appropriate, E, F, G and H, A) from 1 to 97.5% by weight of at least one aromatic polycarbonate A, B) from 1 to 97.5% by weight of at least one graft polymer B made from b1) from 40 to 80% by weight of a graft base made from an elastomeric polymer B1, b2) from 20 to 60% by weight of a graft B2 made from b21) from 60 to 95% by weight of styrene or of substituted styrenes B21 and b22) from 5 to 40% by weight of at least one unsaturated nitrile B22, C) from 1 to 97.5% by weight of at least one thermoplastic copolymer C made from c1) from 60 to 85% by weight of styrene or of substituted styrenes C1 or mixtures thereof and c2) from 15 to 40% by weight of at least one unsaturated nitrile C2, D) from 0.Type: GrantFiled: April 8, 2003Date of Patent: September 4, 2007Assignee: BASF AktiengesellschaftInventors: Martin Weber, Xaver Hopfenspirger, Reinhard Jakobi, Walter Heckmann
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Patent number: 7256228Abstract: A stabilized thermoplastic resin composition is disclosed which comprises structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester and a combination of at least two quenchers, wherein said quencher is selected from a group consisting of phosphorus compound, carboxylic acid, derivates of carboxylic acids, epoxy functional polymers and boron compound. Also disclosed is a stabilized thermoplastic resin composition comprising: structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester, an epoxy functional polymers and a combination of at least one quenchers, wherein said quencher is selected from a group consisting of phosphorus compounds, carboxylic acid compounds, polyols, and boron compounds. In addition the composition disclosed possess good optical properties, thermal properties and stability.Type: GrantFiled: March 31, 2004Date of Patent: August 14, 2007Assignee: General Electric CompanyInventors: Parminder Agarwal, Peter H. Th. Vollenberg, Gabrie Hoogland, Vishvajit Chandrakant Juikar, Ganesh Kannan, Abbas-Alli Ghudubhai Shaikh, Sachin Ashok Shelukar
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Patent number: 7247366Abstract: The object of the present invention is to provide a masking member which has good heat resistance and can be used repeatedly. To attain this object, the present invention provide a masking member made of a polymer alloy including one or more kinds of engineering plastics selected from a group consisting of methylpentene copolymer, polysulphone, polyethersulphone, polyphenylene, sulphide, polyphenylene ether, polyamideimide, polyetherimide, polyether-etherketone; and polyamide and/or polystyrene, and styrenic thermoplastic elastomer wherein said engineering plastics and said polyamide and/or polystyrene are mixed together in a weight ratio between 30:70 to 70:30, and 2 to 20 parts by weight of said styrenic thermoplastic elastomer is added in 100 parts by weight of said engineering plastics and polyamide and/or polystyrene. Said masking member has excellent moldability, a high level of mechanical strength and a good affinity with the coating film.Type: GrantFiled: October 4, 2001Date of Patent: July 24, 2007Assignee: Nagoya Oilchemical, Co., Ltd.Inventors: Masanori Ogawa, Kuninori Ito
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Patent number: 7247388Abstract: A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.Type: GrantFiled: August 27, 2003Date of Patent: July 24, 2007Assignee: NOK CorporationInventors: Kiyofumi Fukasawa, Tomohiro Kaise
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Patent number: 7241403Abstract: PROBLEM TO BE SOLVED: To provide a production method for a thermoplastic resin composition, composed of a polyphenylene ether and a polyamide, having an electric conductivity, and excellent in balance of fluidity and impact strength, by producing with a specific process, and to provide the thermoplastic resin composition obtained thereby. SOLUTION: The thermoplastic resin composition is composed of the following component (A)-(E), wherein a weight ratio of (A)/(B) is 5/95-70/30, an amount of (C) is effective to phase-solvate (A) and (B), the amount of (D) is 0.8-10 pts.wt. per the total 100 pts.wt. of (A) and (B), and the amount of component (E) is 5-40 pts.wt. per the total 100 pts.wt. of (A) and (B). The production method for the thermoplastic resin composition is provided. (A): a polyphenylene ether, (B): a polyamide. (C): a phase-solvating agent, (D): an electrically conductive carbon black and/or a fine fibrous carbon, and (E) an improving agent for shock resistance.Type: GrantFiled: May 29, 2003Date of Patent: July 10, 2007Assignee: General Electric CompanyInventors: Robert Hossan, Sai-Pei Ting
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Patent number: 7226973Abstract: A thermoplastic blend suitable for blow molding comprising a branched polycarbonate and a polyester resin derived from the condensation of a) a cyclohexanedimethanol or equivalent thereof alone or with an ethylene glycol or equivalent thereof, b) together with a terephthalic acid or equivalents thereof alone or with an isophthalic acid or equivalent thereof.Type: GrantFiled: November 5, 2004Date of Patent: June 5, 2007Assignee: General Electric CompanyInventors: Rodney W. Fonseca, Peter H. Th. Vollenberg, Richard C. Cook
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Composition and method for improving the surface adhesion of resin compositions to polyurethane foam
Patent number: 7214739Abstract: A resin composition for improving adhesion with polyurethane foam is disclosed which comprises: (a) about 10 to about 80 percent by weight of at least one polyphenylene ether resin; (b) about 20 to about 70 percent by weight of at least one polyolefin polymer; (c) about 1 to about 20 percent by weight of at least one amine compound; and (d) 0 to about 4 percent by weight of at least one adhesion promoter, wherein all percentages are based on the weight of the entire composition. In preferred embodiments, the resin composition further comprises at least one member of the group consisting of polyphenylene ether-polyolefin copolymers, polystyrene-polyolefin copolymers, and polystyrene resins. Also disclosed herein is a method for improving adhesion between a resin composition and polyurethane foam.Type: GrantFiled: April 22, 2003Date of Patent: May 8, 2007Assignee: General Electric CompanyInventors: Ganesh Kannan, Vijay Ramchandra Mhetar, Mark Denniston, Mark Lewis -
Patent number: 7211628Abstract: A plastic composition including polymeric nanoparticles having a diameter of 1 to 100 nanometers, and a polymeric component. Also provided is a method for providing such a plastic composition.Type: GrantFiled: November 14, 2005Date of Patent: May 1, 2007Assignee: Rohm and Haas CompanyInventor: Carlos Alfonso Cruz
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Patent number: 7172808Abstract: The object of the present invention is to provide a masking member(11) which has good heat resistance and can be used repeatedly. To attain this object, the present invention provides a masking member made of a polymer alloy having a sea-island structure containing polyolefin in a continuous phase and one or more kind(s) of engineering plastic selected from among a group consisting of methyl pentene copolymer, polysulphone, polyethersulphone, polyphenylenesulphide, polyphenyleneether, polyamideimide, polyetherimide, and polyether-etherketone in a dispersed phase.Type: GrantFiled: September 24, 2002Date of Patent: February 6, 2007Assignee: Nagoya Oilchemical Co., Ltd.Inventors: Masanori Ogawa, Kuninori Itou
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Patent number: 7125930Abstract: A block copolymer comprising two or more blocks and having fluorescence in the solid state, wherein blocks thereof may be the same or different, and in each of the blocks, one or more kinds of repeating units are bonded through conjugated bonds, and bonding between the blocks is made by junction unit having conjugated bond, and the polystyrene reduced number average molecular weight of at least one block is 1×103 to 1×108.Type: GrantFiled: April 24, 2002Date of Patent: October 24, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Takanobu Noguchi, Yoshiaki Tsubata, Shuji Doi
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Patent number: 7109274Abstract: The present invention relates to a polymer composition comprising a transparent polymer blend. The polymer blend comprises a first resin and a second resin. The first resin comprises polyarylate structural units of formula I, wherein R1 is independently at each occurrence a C1–C2 alkyl group, or a halogen atom, and p is 0 to 3. The second resin is selected from the group consisting of polycarbonates, polyarylates and copolyestercarbonates. The first resin and the second resin are further characterized by a difference in polyarylate structural unit content, said difference being less than about 40 mole percent.Type: GrantFiled: June 28, 2004Date of Patent: September 19, 2006Assignee: General Electric CompanyInventors: Ali Ersin Acar, Paul Dean Sybert, Xiangyang Li, Karthik Balakrishnan, Gregory Allen O'Neil
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Patent number: 7105601Abstract: An adhesive resin composition comprising, based on the total weight of the composition, a first resin component having one or more glass transition temperatures of about ?15 to about 50° C.; optionally, up to about 49 weight percent of a second resin component having one or more glass transition temperatures greater than about 100° C.; and up to about 50 weight percent of a particulate inorganic filler; wherein a tan ? value of the adhesive resin composition is greater than about 0.2 over a temperature range of about ?15 to about 50° C. when measured at a frequency of 1 Hz. The adhesive resin compostions are of particular utility in suspension assemblies.Type: GrantFiled: December 19, 2002Date of Patent: September 12, 2006Assignee: World Properties, Inc.Inventors: Hong-Fei David Guo, Robert Henry Walker, III
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Patent number: 7091267Abstract: Disclosed are resinous compositions with excellent balance of impact, heat, flow and environmental stress crack resistance, comprising (i) at least one aromatic polycarbonate, (ii) at least one low molecular weight hydrocarbon resin derived from petroleum C5–C9 feedstock and (iii) optionally a second thermoplastic resin which is not polycarbonate resin, (iv) optionally a rubber modified graft copolymer, and (v) optionally a polymeric or non-polymeric organic phosphorus species. Also disclosed is a method for the manufacture of the compositions and for the manufacture of articles thereof.Type: GrantFiled: March 18, 2003Date of Patent: August 15, 2006Assignee: General Electric CompanyInventors: Robert W. Venderbosch, Sjef G. Berndsen, William A. Kernick, III
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Patent number: 7087679Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150° C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.Type: GrantFiled: December 31, 2002Date of Patent: August 8, 2006Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Patent number: RE40508Abstract: Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.Type: GrantFiled: August 15, 2003Date of Patent: September 16, 2008Assignee: SABIC Innovative Plastics IP B.V.Inventors: Daniel Joseph Brunelle, Joseph Anthony Suriano, Taeseok Jang, Tiberiu Mircea Sielovan, Edward Pickett, Gregory Allen O'Neil