Two Or More Diverse Phenolic Reactants; Or Phenolic Reactant Contains An Atom Other Than C, H, Or O Patents (Class 525/147)
  • Patent number: 11912865
    Abstract: The present invention relates to a thermoplastic composition comprising at least one aromatic polycarbonate, talc, at least one anhydride-modified alpha-olefin polymer, at least one organic flame retardant selected from: fluoropolymer-containing anti-drip agents, fluorinated sulfonic acid salts, organic phosphoric acid esters, phosphazenes or mixtures of at least two of the abovementioned agents and barium sulfate. The invention further relates to a production process for such a composition and to a molded article producible from this composition. The composition contains barium sulfate in an amount of ?3% by weight based on the total weight of the composition. ?5% by weight is preferred.
    Type: Grant
    Filed: April 9, 2020
    Date of Patent: February 27, 2024
    Assignee: Covestro Intellectual Property GmbH & Co. KG
    Inventors: Christopher Schirwitz, Tim Hungerland, Tanja Grueter-Reetz, Helmut Kruells
  • Patent number: 11697708
    Abstract: Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a): 15?wM1??(F1a) wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.
    Type: Grant
    Filed: March 1, 2018
    Date of Patent: July 11, 2023
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventors: Yasuhiro Ishikawa, Tomoko Abe, Takafumi Akimoto
  • Patent number: 9969841
    Abstract: The present invention relates to a copolycarbonate and a molded article comprising the same. The copolycarbonates according to the present invention has a structure in which a specific siloxane compound is introduced in a main chain of the polycarbonate, and has effects of improving impact strength at room temperature, impact strength at low temperature, and melt index properties.
    Type: Grant
    Filed: November 16, 2015
    Date of Patent: May 15, 2018
    Assignee: LG Chem, Ltd.
    Inventors: Young Young Hwang, Hyong Min Bahn, Jung Jun Park, Moo Ho Hong, Ki Jae Lee, Byoung Kyu Chun, Un Ko, Young Wook Son
  • Patent number: 9718958
    Abstract: Disclosed is a copolycarbonate including aromatic polycarbonate-based repeating units represented by Chemical Formula 1 and Chemical Formula 2; and aromatic polycarbonate-based repeating units having siloxane bonds represented by Chemical Formula 3 and Chemical Formula 4: copolycarbonate provides improved impact strength at low-temperature, improved YI (yellow index), and improved melt index simultaneously.
    Type: Grant
    Filed: December 4, 2015
    Date of Patent: August 1, 2017
    Assignee: LG Chem, Ltd.
    Inventors: Young Wook Son, Moo Ho Hong, Ki Jae Lee, Jung Jun Park
  • Publication number: 20140061533
    Abstract: Disclosed herein are indane bisphenol monomer units, and polymers derived from such monomer units. Also disclosed herein are blends including such polymers, articles made from such polymers and blends, methods of using such monomers, polymers, and blends, and processes for preparing such monomers, polymers, and blends.
    Type: Application
    Filed: September 5, 2012
    Publication date: March 6, 2014
    Inventors: Laura G. Schultz Hume, S/shri. Shubashree Swaminathan, Ganapathy Bhotla Venkata Ramanarayanan
  • Patent number: 8586183
    Abstract: A laser composition comprises a combination of: (a) from more than 45 to less than 94 weight percent of a crystalline or semi-crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers poly(ethylene terephthalate) copolymers, and combinations thereof; (b) from greater than 6 to less than 25 weight percent of an amorphous thermoplastic poly(ester) copolymer, poly(ester-carbonate), or combination thereof; (c) optionally, from 1 to 30 weight percent of a filler; and (d) optionally, from 0.01 to 5 weight percent of an antioxidant, mold release agent, colorant, stabilizer, or a combination thereof; wherein an article having a 2 mm thickness and molded from the composition has (i) a near infrared transmission at 960 nanometers of greater than 30 percent and (ii) a Vicat softening temperature of at least 170° C.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: November 19, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Tony Farrell, Johannes Hubertus G. M. Lohmeijer
  • Publication number: 20120022204
    Abstract: The invention relates to (co)polycarbonate compositions and molding compositions which feature improved optical properties, good flowability, and high heat resistance.
    Type: Application
    Filed: March 18, 2010
    Publication date: January 26, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Rolf Wehrmann, Helmut Werner Heuer
  • Patent number: 7851529
    Abstract: Provided are a polycarbonate resin composition which does not contain halogen and phosphorus as a flame retardant component and which is excellent in a fluidity while maintaining a flame resistance, a heat resistance and an impact resistance and a molded article thereof.
    Type: Grant
    Filed: November 26, 2007
    Date of Patent: December 14, 2010
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Kenichi Mitsuhashi, Akio Nodera, Hiroshi Kawato, Toshio Isozaki
  • Patent number: 7790807
    Abstract: The instant invention relates to new compounds of the formula I R1 and R2 are each independently of the other a fluorine containing group, R3 and R4 are each independently of the other hydrogen, a fluorine containing group, C1-C12alkyl, phenyl or R4, together with the carbon atom to which they are bonded, form a C5-C8-cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl groups; R5, R6, R7 and R8 are each independently of the other hydrogen, C1-C12alkyl or C3-C12alkenyl, X1 and X2 are each independently of the other a direct bond or C1-C12alkylene, m is 1 to 10,000, and n is 0 to 10,000. These new compounds of the formula I are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: September 7, 2010
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Martin Brunner, Archana Kishore Desai, Shrirang Bhikaji Hindalekar, Suhas Dattatraya Sahasrabudhe, Armin Schneider, Paragkumar Nathalal Thanki, Michael Tinkl, Alessandro Zedda, Michèle Gerster, Fabien Jean Brand
  • Patent number: 7671169
    Abstract: A polycarbonate-polyester block copolymer includes a polycarbonate block and a polyester block, each having specific structures. The block copolymer can be prepared, at least in part, from renewable feedstocks. In some forms, the block copolymer includes biodegradable segments that facilitate structural breakdown of objects molded from the block copolymer. Methods of preparing the block copolymer are described as are compositions that include it and articles prepared from it.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: March 2, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Brian Mullen, Tara Mullen
  • Patent number: 7268193
    Abstract: Branched polyarylene polymers are provided comprising monovalent endcappers, divalent linear units, and polyvalent branching units. The composition of the polymers is controlled by adjusting the ratio of the three types of monomers.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: September 11, 2007
    Assignee: Mississippi Polymer Technologies, Inc.
    Inventors: Matthew L. Marrocco, III, Mark S. Trimmer, Ying Wang
  • Patent number: 7057005
    Abstract: The present invention is a process for producing branched polycarbonate providing for optimum utilization of the branching agent. It was surprisingly found that adding at least a portion of the coupling catalyst to the polymerization at a point during the oligomerization in the reaction results in a higher degree of branching and improved rheological properties.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: June 6, 2006
    Assignee: Dow Global TechnologiessInc.
    Inventors: Susanne Rohde, Bernhard Elbert
  • Patent number: 6979716
    Abstract: This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon—carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having well controlled side chain molecular weights.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: December 27, 2005
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Shigeki Ono, Masayuki Fujita, Kenichi Kitano
  • Patent number: 6630525
    Abstract: A polycarbonate is provided which contains residues of a dihydric phenol, at least one comonomer of a siloxane functional bisphenol, optionally, a branching agent and optionally, a flame retardant. Further embodiments of the present invention includes a method for producing a flame retardant polycarbonate.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: October 7, 2003
    Assignee: General Electric Company
    Inventors: James Anthony Cella, James Ross Fishburn, James Alan Mahood
  • Publication number: 20010044003
    Abstract: Disclosed is an article for the optical storage of data having low birefringence prepared from a mixture of a polycarbonate and a cycloaliphatic polyester. The article may optionally have stabilization and mold release additives that retain transparency, color and processability.
    Type: Application
    Filed: February 23, 2001
    Publication date: November 22, 2001
    Applicant: General Electric Co.
    Inventors: Robert R. Gallucci, Frank A. Hoefflin, Steven F. Hubbard, Ramesh Hariharan, Irene Dris
  • Patent number: 6143823
    Abstract: Thermoplastically processable thermotropic molding compounds of thermotropic polycondensates and 0.05 to 5% by weight functionalized polymers, such as for example functionalized polybutadiene oils, polyethylene or polypropylene.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: November 7, 2000
    Assignee: Bayer AG
    Inventors: Rolf Wehrmann, Alexander Karbach, Thomas Elsner, Peter Tappe
  • Patent number: 5945491
    Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a ma
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: August 31, 1999
    Assignee: Carnegie-Mellon University
    Inventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
  • Patent number: 5849845
    Abstract: Blends ofA) 80 to 99 wt. % of high molecular weight, thermoplastic, aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000, which contains bifunctional carbonate structural units of the formula (I), ##STR1## in which R.sup.1 and R.sup.2 mutually independently mean hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl, preferably phenyl, and C.sub.7 -C.sub.12 aralkyl,m means an integer from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4 individually selectably for each X, mutually independently mean hydrogen or C.sub.1 -C.sub.6 alkyl andX means carbon,providing that on at least one atom X, R.sup.3 and R.sup.4 simultaneously mean alkyl,B) 1 to 20 wt. % of a terpolymer prepared from 60 to 70 wt. % of ethylene, 37 to 20 wt. % of an acrylic acid ester of a C.sub.2 -C.sub.12 alcohol and 3 to 10 wt. % of a monomer with epoxy groups.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: December 15, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Peter Bier
  • Patent number: 5583174
    Abstract: Mixtures ofA) 75 to 99.5 wt. % of a high molecular weight, thermoplastic, aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000 which contains bifunctional carbonate structural units of the formula (I), ##STR1## in which R.sup.1 and R.sup.2, independently of each other, represent hydrogen, halogen, preferably chlorine or bromine, or a C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, preferably phenyl, or C.sub.7 -C.sub.12 -aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, in particular a benzyl group,m is an integer from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4 can be selected separately for each X and, independently of each other, represent hydrogen or a C.sub.1 -C.sub.6 -alkyl group andX represents carbon,with the proviso that R.sup.3 and R.sup.4 simultaneously represent an alkyl group on at least one X atom.B) 0.5 to 15 wt.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: December 10, 1996
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Peter Bier
  • Patent number: 5565515
    Abstract: Improved flow copolycarbonate compositions are provided containing resorcinol repeat units and containing styrene-acrylonitrile copolymers. The compositions may additionally comprise a rubbery polymer and an inorganic filler, such as glass fibers.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: October 15, 1996
    Assignee: General Electric Company
    Inventors: Kenichi Ishiwa, Hideyuki Itoi
  • Patent number: 5512632
    Abstract: The invention relates to mixtures of special polyesters and/or special polyester carbonates with amorphous thermoplastics and/or with partly crystalline thermoplastics and/or with rubbers and/or with graft polymers useful for molding articles.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: April 30, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Ulrich Grigo
  • Patent number: 5416148
    Abstract: A blend of polycarbonate and a substantially linear ethylene polymer which has a desirable balance of impact and solvent resistance properties.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: May 16, 1995
    Assignee: The Dow Chemical Company
    Inventors: Hani Farah, Michael K. Laughner, Chai-Jing Chou, Morgan M. Hughes
  • Patent number: 5380795
    Abstract: The invention relates to a polymer mixture which comprises an aromatic polycarbonate, a styrene-containing copolymer and/or a styrene-containing graft polymer and a given type of polysiloxane-polycarbonate block copolymer. It has been found that the use of this given type of polysiloxane-polycarbonate block copolymer leads to a polymer mixture having improved impact strength properties. The polysiloxane-polycarbonate block copolymer used is built up from(a) 1-50% by weight of polysiloxane blocks of formula II and(b) 50-99% by weight of polycarbonate blocks of formula III, wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each independently of each other represent a hydrogen atom, a hydrocarbyl or a halogenated hydrocarbyl, D is an integer from 5-140, Y is a hydrogen atom or an alkoxy, and wherein A is a bivalent hydrocarbon group having 1-15 carbon atoms, which bivalent hydrocarbon group may be substituted, is an --S--; an --S--S--; an --S--(O)--; an --S(O).sub.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: January 10, 1995
    Assignee: General Electric Company
    Inventors: Johannes C. Gosens, Adelbert H. Leonardus, Hendrikus J. Eugene
  • Patent number: 5369172
    Abstract: The invention provides a low gloss polymer blend comprising an aromatic carbonate without reactive groups, a polymer or copolymer having a reactive epoxygroup and an aromatic carbonate polymer or copolymer having a reactive group which react with the epoxy group. Optionally, the composition may contain further usual compounds, such as polymeric materials which are normally used to modify the mechanical properties of polycarbonate, particularly rubbery or non-rubbery polymeric materials containing units of a styrene; also additives like colorants, flame retarding agents may be routinely incorporated.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: November 29, 1994
    Assignee: General Electric Company
    Inventors: Sarah E. Morgan, Charles F. Pratt, Hermannus B. Savenije
  • Patent number: 5321086
    Abstract: A polycarbonate resin composition which comprises (a) a polycarbonate containing a repeating unit (I) derived from tetrahalogenobisphenol A and a repeating unit (II) derived from bisphenol A and trihalogenophenoxy groups bonded at the terminals, and (b) at least one thermoplastic resin selected from the group consisting of (i) a polyamide resin selected from the group consisting of nylon 6 and nylon 6,6, (ii) a thermoplastic polyester selected from the group consisting of polyethylene terephthalate and polybutylene terephthalate and (iii) a polyolefin. The polycarbonate resin composition has desirable physical properties including desirable mechanical properties, moldability, heat resistance, flame retardance, thermostability, rigidity, impact resistance, solvent resistance, and fluidity, and can be used to make parts for automobiles, home electric appliances, and office automation appliances.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: June 14, 1994
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shiro Kozakura, Takashi Komatsu
  • Patent number: 5310793
    Abstract: The mixtures according to the present invention of polyalkylene terephthalates, certain new polycarbonates and/or polyester-carbonates and elastomers have a particularly favourable low temperature strength/heat distortion point relationship compared with conventional moulding compositions containing known polycarbonates. The mixtures are used for the production of, in particular, shaped articles.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: May 10, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Karsten-Josef Idel, Gerd Fengler, Ulrich Grigo, Jurgen Kirsch, Uwe Westeppe
  • Patent number: 5292809
    Abstract: Bisphenol A polycarbonate containing at least 15 mole % of fluorinated bisphenol monomer units such as 2,2-bis-(4-hydroxyphenyl) hexafluoropropane (6F-Bisphenol A) can be blended with polymethyl methacrylate (PMMA) to form thermodynamically miscible, transparent, single phase blends at all compositions.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: March 8, 1994
    Assignee: Enichem S.p.A.
    Inventor: Michael A. Drzewinski
  • Patent number: 5286794
    Abstract: Bisphenol A polycarbonate containing at least 15 mole % of 2,2-bis-(4-hydroxyphenyl)hexafluoropropane (6F-Bisphenol A) can be blended with polyvinyl chloride (PVC) to form a thermodynamically miscible, transparent, single phase blend at all compositions. Such blends are flame resistant as well as resistant to attack by acids, bases and many organic solvents.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: February 15, 1994
    Assignee: Enichem S.p.A.
    Inventor: Michael A. Drzewinski
  • Patent number: 5278257
    Abstract: Compositions containing A) a copolymer based on at least one 1,3-diene and at least one polar, ethylenically unsaturated comonomer and B) a phenol-terminated polyurethane, polyurea or polyurea-urethane of the formula I ##STR1## in which m is 1 or 2, n is 2 to 6, R.sup.1 is the n-valent radical of an elastomeric prepolymer which is soluble or dispersible in epoxide resins, X and Y independently of one another are --O-- or --NR.sup.3 --, it being necessary for one of these groups to be --NR.sup.3 --, R.sup.2 is an m+1-valent radical of a polyphenol or aminophenol after the removal of the phenolic hydroxy group(s) or the amino group or both the amino group and the phenolic hydroxyl group, respectively, and R.sup.3 is hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, are described.Compounds containing the components A) and B) as well as an epoxide resin C) are also described.The cured products are distinguished by a high peel strength and high resistance to crack propagation.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: January 11, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Jeremy H. Powell, Christopher S. Adderley, Werner Rufenacht
  • Patent number: 5273685
    Abstract: A thermoplastic resin composition comprising (a) 100 parts by weight of thermoplastic copolycarbonate comprising 0.1 to 50% by weight of structural unit of the following general formula (1) and 99.9 to 50% by weight of structural unit of the following general formula (2): ##STR1## and (b) 0.1 to 30 parts by weight of electroconductive carbon black can produce a molding product having good mechanical properties and surface smoothness with good moldability.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: December 28, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Toshiaki Takata, Tadami Kinugawa, Hideo Otaki
  • Patent number: 5274034
    Abstract: The invention relates to polymer compositions comprising an aromatic polycarbonate, an aromatic polycarbonate with acid or ester functionality, a styrene based polymer and a styrene polymer with oxazoline groups.The polymer composition of the invention is suitable for molding objects with a mat surface.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: December 28, 1993
    Assignee: General Electric Company
    Inventors: Sarah E. Morgan, Charles F. Pratt, Constantinus L. J. A. Verbraak, Stanley Y. Hobbs, Edward J. Fewkes, Jr.
  • Patent number: 5258432
    Abstract: A blended composition containing polycarbonate and polyester and/or an acrylate polymer, modified with poly(tetrafluoroethylene), an organophosphorous compound and an aromatic halogenated carbonate oligomer to obtain ignition resistance properties, and, optionally, an elastomeric impact modifier.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: November 2, 1993
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Michael K. Laughner, Jack W. Muskopf, Jeffrey E. Lackey
  • Patent number: 5242981
    Abstract: The improved resin composition comprises:(A) a melt-workable liquid-crystal polyester resin obtained by polymerizing components selected from the group consisting of a dicarboxylic acid represented by the general formula (a) HOOC--R.sub.1 --COOH, a diol represented by the general formula (b) HO--R.sup.2 --OH, and an oxycarboxylic acid represented by the general formula (c) HO--R.sup.3 --COOH;(B) a polycarbonate resin having a recurring unit represented by the general formula: ##STR1## (C) a polyolefin and/or an olefinic copolymer, and the polyolefin and/or olefinic copolymer (C) is contained in an amount of 1-15 parts by weight per 100 parts by weight of a resin consisting of 95-5 wt % of the liquid-crystal polyester resin (A) and 5-95 wt % of the polycarbonate resin(B). This resin composition is balanced between various physical properties including moldability, heat resistance, impact resistance, dimensional stability and stiffness.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: September 7, 1993
    Assignee: Kawasaki Steel Corporation
    Inventors: Mitsuhiko Izumi, Kenji Yoshino, Tadahiro Wakui
  • Patent number: 5219936
    Abstract: A preferred rigid thermoplastic resin composition having high impact strength and resistance to thermal distortion includes a vinyl chloride resin/polycarbonate alloy and at least 3 parts by weight of butadiene-modified acrylic per 100 parts by weight of the alloy. A particularly preferred thermoplastic resin composition includes the alloy and both butadiene-modified acrylic and ethylene-vinyl acetate copolymer.
    Type: Grant
    Filed: January 7, 1992
    Date of Patent: June 15, 1993
    Assignee: Great Lakes Chemical Corporation
    Inventors: David J. Honkomp, Nicolai A. Favstritsky, Enrico J. Termine
  • Patent number: 5177145
    Abstract: A thermoplastic molding composition comprising a polycarbonate resin and ABS is rendered improved levels of resistance to gasoline environment and thermal stability upon the incorporation therewith of a particular vinyl copolymer.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: January 5, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Jochen Schoeps, Martin Wandel
  • Patent number: 5162411
    Abstract: A carbonate corresponding to formula (I) ##STR1## in which R is aromatically bound polystyrene moiety and --O--D--O-- is a diphenolate moiety in which --D-- is a divalent group containing 6 to 30 carbon atoms and r is 0 or 1 is disclosed. The carbonate is useful as a flow aid for thermoplastic molding compositions.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: November 10, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Fennhoff, Uwe Westeppe, Werner Nouvertne, Karsten-Josef Idel, Edgar Leitz, Ulrich Grigo
  • Patent number: 5140066
    Abstract: The invention relates to poly(meth)acrylates having grafted-on polycarbonate chains, to their production and to their use as modifiers for thermoplastic polycarbonates having improved resistance to gasoline and/or improved impact strength at low temperatures and to their production.
    Type: Grant
    Filed: April 3, 1990
    Date of Patent: August 18, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Leo Morbitzer, Rolf Dhein, Werner Nouvertne
  • Patent number: 5137971
    Abstract: A process for producing a graft copolymer is disclosed. The graft copolymer, based on a rubber which contains phenolic OH groups and grafted with polycarbonate chains is produced under the conditions of the two-phase interfacial polycondensation. Also disclosed are gasoline resistant thermoplastic polycarbonate compositions containing the graft.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: August 11, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Richard Weider, Peter Horlacher, Werner Nouvertne
  • Patent number: 5109079
    Abstract: The invention relates to polyacrylates corresponding to formula (I) ##STR1## to their production in a quasi-ionic polymerization and to their use as monofunctional chain terminators, optionally in combination with typical other chain terminators, for the production of aromatic polycarbonates.The invention also relates to the polycarbonates or polycarbonate mixtures obtained using the compounds corresponding to formula (I) and to their use as additives for other thermoplastic polycarbonates.
    Type: Grant
    Filed: December 7, 1990
    Date of Patent: April 28, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Gerd Renner, Karl-Erwin Piejko, Bruno Boemer, Alfred Jung, Werner Nouvertne
  • Patent number: 5100960
    Abstract: The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: March 31, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Grigo, Peter Horlacher, Dieter Freitag, Karsten-Josef Idel, Uwe Westeppe, Wolfgang Beer, Werner Nouvertne
  • Patent number: 5062984
    Abstract: The invention relates to polymer mixtures comprising A. an aromatic polycarbonate and B. a polyalkylene terephthalate. It has been found that the cosmetic properties of articles obtained by injection-moulding the polymer mixture can be improved by the addition of cross-linked polymer particles having an average particle size from 1 to 30 micrometers.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: November 5, 1991
    Assignee: General Electric Company
    Inventors: Wilhemus M. M. Roovers, Jan de Boer
  • Patent number: 5055523
    Abstract: An aromatic polycarbonate composition contains aromatic polycarbonate in which a ratio of the phenolic end group to the non-phenolic end group is at least 1/19, and a copolymer having epoxy or oxazolinyl group, aromatic vinyl-diene-vinyl cyanide copolymer or aromatic polyester, or glass filler. Compatability between the specific aromatic polycarbonate and the other resin, weld strength, melt stability or adhesion to glass filler are improved.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: October 8, 1991
    Assignee: CE Plastics Japan Limited
    Inventors: Kazushige Inoue, Akhiro Saito, Takorou Kitamura, Takashi Ohtomo, Hidenori Tazaki, Tetsuji Kodaira, Yumiko Yoshida, Hiromi Ishida, Takahiro Yokoshima, Hideyuki Itoi
  • Patent number: 5034458
    Abstract: Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: July 23, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Karsten-Josef Idel, Ulrich Grigo
  • Patent number: 5034457
    Abstract: Thermoplastic blends ofA) 1 to 99% by weight of at least one thermoplastic aromatic polycarbonate which contains difunctional carbonate structural units of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon radical or halogen and R.sup.5, R.sup.6 and R.sup.7 independently of one another are H or a hydrocarbon radical, with the proviso that at least one of the radicals R.sup.5, R.sup.6 and R.sup.7 is a hydrocarbon radical, that when only one of the radicals R.sup.5, R.sup.6 or R.sup.7 is present as a hydrocarbon radical this is a C.sub.3 -C.sub.12 -hydrocarbon radical with the exception of C.sub.3 -C.sub.12 -n-alkyl, and that when two or three radicals R.sup.5, R.sup.6 and R.sup.7 are present as hydrocarbon radicals these are any C.sub.1 -C.sub.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: July 23, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Karsten Idel, Ulrich Grigo
  • Patent number: 5030675
    Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: July 9, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
  • Patent number: 5026777
    Abstract: Thermoplastic molding compositions having an inherent matte or low gloss surface finish comprise a polymer blend of a polycarbonate and an emulsion grafted ABS polymer, and a low gloss enhancing amount of a poly(epoxide).
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: June 25, 1991
    Assignee: General Electric Company
    Inventors: Ronald L. Jalbert, David O. Phillips
  • Patent number: 4988748
    Abstract: The invention relates to thermoplastic polycarbonate molding compounds containing polycarbonates, copolymers, phosphorus compounds, tetrafluoroethylene polymers and, optionally, graft polymers and also further additives and other thermoplastics and also stabilizers, pigments, flow aids, mold release agents, antistatic agents and/or other flameproffing agents, characterized in that they contain as phosphorus compounds those corresponding to formula (I) ##STR1## and to a process for the production of the polycarbonate molding compounds.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Hans-Dieter Block, Bernd Urbanneck, Werner Ballas
  • Patent number: 4983677
    Abstract: An extrudable composition comprising hydrocarbon polymer, organophosphite or organophosphate compound and fluorocarbon polymer. The organophosphite or organophosphate and the fluorocarbon polymer are present in the composition in such relative proportions and concentrations as to reduce the occurrence of melt defects during the extrusion of said thermoplastic hydrocarbon polymer.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: January 8, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Bryce V. Johnson, Joyce M. Kunde
  • Patent number: 4895897
    Abstract: Aromatic carbonate compositions having improved impact properties comprising an aromatic carbonate resin and a functionalized elastomeric polymer that is the reaction product of an ethylene elastomer having reactive polar groups and an oxazoline functionalized polystyrene are disclosed.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: January 23, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Lawrence G. Kaufman
  • Patent number: 4840995
    Abstract: Disclosed herein is a resin composition comprising(a) an aromatic polyester,(b) an aromatic polycarbonate and(c) a reaction product of an .alpha.-olefin having a molecular weight of 40 to 2,000 and an unsaturated carboxylic acid or a derivative thereof, the content of said unsaturated carboxylic acid or said derivative thereof in said reaction product being 5 to 70 wt %.The resin composition according to the present is suitable as electric and electronic parts, automotive parts and other industrial materials.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: June 20, 1989
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Mitsuhiko Tamura, Masaaki Miyamoto, Kazuo Miyamoto