Two Or More Solid Polymers Present Other Than Derived From A Polycarboxylic Acid Or Derivative And A Polyol Patents (Class 525/166)
  • Patent number: 6815499
    Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: November 9, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Takashi Yasumura, Akira Takano
  • Patent number: 6809151
    Abstract: The present invention relates to the thermoplastic polyesters, which comprise, by weight (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shelf copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-saturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 90/10 and 25/75 for proportions of impact modifier between 2 and 40% in 98 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 25/75 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively. It is particularly useful for PET and PBT.
    Type: Grant
    Filed: November 24, 2000
    Date of Patent: October 26, 2004
    Assignee: Atofina
    Inventors: Christophe Lacroix, Alain Bouilloux
  • Patent number: 6806314
    Abstract: A coating composition comprising at least one hydroxyl functional polymer, a crosslinker capable of crosslinking with said hydroxyl functional polymer (a) to form a film, and a reactive diluent comprising 1,3-cyclohexane dimethanol and 1,4-cyclohexane dimethanol.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: October 19, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: David R. Fenn, David N. Walters
  • Patent number: 6790499
    Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, and an additive combination, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The additive combination comprises compounds selected from at least two groups wherein the groups are (i.) poly(vinyl alcohol) or ethylene/vinyl alcohol copolymer, (ii.) polyhydric alcohols and (iii.) polyacrylamide, polymethacrylamide or copolymer of acrylamide or methacrylamide. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: September 14, 2004
    Assignee: Ciba Speicalty Chemicals Corporation
    Inventors: Stephen M Andrews, Paul A. Odorisio, Dirk Simon
  • Patent number: 6780481
    Abstract: A melt processable polymer composition that comprises a thermoplastic non-aliphatic host polymer and a minor but effective amount of a fluoropolymer processing aid, and a method of improving the melt processability of the host polymer are provided.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: August 24, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Claude Lavallée, Maria P. Dillon, Thomas J. Blong, Susan S. Woods, Shannon S. Le Blanc
  • Patent number: 6780907
    Abstract: A means to improve thermoplastic formulations in terms of the physical properties they exhibit, such as impact strength and ductility, have been developed. The addition of a block chlorinated polyolefin (b-CPO) to polymer blends in which at least one component comprises a halogen-free hydrogen-bond acceptor polymer, achieves the desired enhancement. The synergetic effect of the b-CPO with the selected polymer blend is demonstrated. Blends of thermoplastic polyurethanes, polycarbonates, copolyesters and copolyamides with a blend partner such as thermoplastic polyolefins, styrenic copolymers such as styrene acrylonitrile copolymers, styrene ethylene butylene styrene copolymers, high rubber graft copolymers such as acrylonitrile butadiene styrene copolymers, methylmethacrylate butadiene styrene copolymers and the b-CPO have enhanced ductility and impact resistance. The addition of 0.5 wt.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: August 24, 2004
    Assignee: Noveon IP Holdings Corp.
    Inventors: A. Donald Meltzer, Dennis L. Lawson, Robert E. Detterman, Carole A. Lepilleur
  • Patent number: 6773819
    Abstract: This invention provides a paint composition for motorcars, which comprises a carboxyl-containing polyester resin which contains a unit or units derived from alicyclic polybasic acid (a) and/or alicyclic polyhydric alcohol (b), and a vinyl polymer having epoxy group(s) and hydroxyl group(s) within one molecule, and which is capable of forming cured coating having Universal Hardness (HU) not higher than 500 N/mm2.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: August 10, 2004
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Kazuhiro Kato, Kazuaki Kitazono, Yoshizumi Matsuno
  • Publication number: 20040152840
    Abstract: Acid dye stain-resistant fibers which are formed from a polyamide composition containing a mixture of a masterbatch concentrate, a fiber-forming polyamide and a polymer, the masterbatch concentrate including a carrier and a reagent having the formula: 1
    Type: Application
    Filed: May 23, 2003
    Publication date: August 5, 2004
    Inventor: Matthew Benjamin Studholme
  • Patent number: 6770378
    Abstract: Compounds which, for example, can be used as a compact substance and which are comprised of polyamide substance(s) and perfluoralkyl substance(s), and to mixtures of these compounds with additional polymer substance(s). Methods for producing such compounds are also provided in which aliphatic and/or partially aromatic homopolyamides and/or copolyamides and/or polyester amides and/or polyether amides and/or polyester ether amides and/or polyimide amides and/or polyamide amides and/or mixtures of these polyamide compound(s) with additional polymer(s) and modified perfluoralkyl substance(s) are compounded in a single step or multistep and are reactively converted during or afterwards. The homogenization of perfluoralkyl substance(s) in polyamide substance(s) melted masses is improved.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: August 3, 2004
    Assignee: Institut fur Polymerforschung E.V. Dresden
    Inventor: Dieter Lehmann
  • Patent number: 6765062
    Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: July 20, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
  • Patent number: 6759480
    Abstract: The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: July 6, 2004
    Assignee: Atofina
    Inventors: Alain Bouilloux, Christophe Lacroix, Jean-Marc Le Blevec, Thibaut Montanari
  • Publication number: 20040116603
    Abstract: Polyester compositions which contain a copolymer of ethylene, an acrylate ester, and carbon monoxide and optionally a fibrous filler having a relatively small diameter are particularly suitable for parts whose surface appearance is important, such as appliance panels and automobile body panels.
    Type: Application
    Filed: August 26, 2003
    Publication date: June 17, 2004
    Inventors: Toshikazu Kobayashi, Claire Brissot, Edmund Arthur Flexman
  • Publication number: 20040116645
    Abstract: Coating compositions comprising:
    Type: Application
    Filed: September 25, 2003
    Publication date: June 17, 2004
    Inventors: Jos Huybrechts, Ann Vaes, Lieve Bastin, Leen Tanghe
  • Patent number: 6740708
    Abstract: An impact-resistant polymer composition exhibiting improved impact resistance at no loss in creep is obtained by melt-mixing a solid matrix polymer A with a solid composition containing the rubber composition dispersed in a matrix polymer B. The dispersion of rubber composition in matrix polymer B is obtained by melt mixing the matrix polymer B with a rubber composition which includes a functionality rubber and a non-functionality rubber. The amounts of the components are such that the impact-resistant polymer composition contains 0.5 to 75 parts by weight of the rubber composition per 100 parts by weight of the matrix polymers A and B. The composition may be used in various applications, including plugs, heat bridges for aluminum windows, hammer heads and the like.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: May 25, 2004
    Assignee: DSM IP Assets B.V.
    Inventors: Wilhelmus G. M. Bruls, Johannes F. Repin, Jan De Kroon
  • Patent number: 6720380
    Abstract: The invention relates to a modular system for the production of coating compositions for coating plastics comprising the following component modules: A) at least one base module containing at least one binder, extenders and/or pigments, optionally together with conventional coating additives, water and/or organic solvents, B) at least one adhesion module containing at least one adhesion-promoting component optionally together with binders, conventional coating additives, extenders, organic solvents and/or water, C) at least one elasticity module containing at least one elasticising component optionally together with conventional coating additives, extenders, organic solvents and/or water and D) at least one binder module containing at least one binder optionally together with additives, organic solvents and/or water.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: April 13, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Udo Hellmann, Maria Weigel
  • Patent number: 6706851
    Abstract: The present invention relates to polyetheresteramides (B) containing polyamide blocks comprising dicarboxylic acid sulphonates either as polyamide-block chain limiters or combined with a diamine as one of the constituent monomers of the polyamide block, and containing polyether blocks consisting essentially of alkylene oxide units. The invention also relates to polyetheresteramides (B) containing polyamide blocks of the polyamide oligomer type of low molecular mass or of the copolyamide type which comprise dicarboxylic acid sulphonates and containing polyether blocks which are adducts of alkylene oxide with an aromatic diol. The invention also relates to antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one of the above polyetheresteramides (B).
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: March 16, 2004
    Assignee: Atofina
    Inventors: Reinhard Linemann, Thierry Briffaud, Hermann Hilgers, Christophe Lacroix
  • Patent number: 6696165
    Abstract: The invention provides a weatherable low gloss styrene copolymer composition which requires the addition of from 0.1 to 20% by weight of the total composition, of a partially crystalline polymer such as a polyalkylterephthalate, especially polybutyleneterephthalate or polyethyleneterephthalate, or polyethylenenaphthalate to a styrene copolymer (A). The low gloss styrene copolymer composition of the invention has a graft copolymer resin which results from polymerizing one or more monomers (A1) selected from the group consisting of (i) aromatic vinyl compounds, (ii) ethylenically unsaturated compounds, and (iii) mixtures thereof, in the presence of an elastomeric rubber (A2) in particulate form.
    Type: Grant
    Filed: June 28, 2000
    Date of Patent: February 24, 2004
    Assignee: BASF Corporation
    Inventors: James H. Bennett, Klaus Mühlbach, Gary Kogowski, Heiner Görrissen, Graham Edmund Mc Kee
  • Patent number: 6673873
    Abstract: A substantially transparent, moldable, thermoplastic multipolymer composition comprising a methyl methacrylate copolymer containing a predominant amount of methyl methacrylate and a minor amount of one or more ethylenically unsaturated monomers; and an effective amount of a polyetheresteramide to enhance the electrostatic charge dissipation of the copolymer. The polyetheresteramide has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition, when subjected to injection molding, is such that the injection-molded composition exhibits a haze of not greater than about 25% and a light transmission of at least about 60%. Preferably, the composition includes an impact modifier which also has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition may also include a minor amount of a polyethylene glycol having a weight average molecular weight of about 2,000 to about 10,000.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: January 6, 2004
    Assignee: Cyro Industries
    Inventor: Daniel Zimmerman
  • Patent number: 6656531
    Abstract: A method for forming a coated film comprises (1) applying a water or solvent based coating composition on an undercoated or intercoated substrate to form a base coating, (2) applying a clear coating composition thereon to form a clear coating without curing the base coating, and (3) heating and curing both the base coating and clear coating, wherein the clear coating composition comprises as a binder (a) from 10-70% by weight of an acrylic polycarboxylic acid having on average 2 or more carboxyl groups per molecule obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, then reacting the resulting copolymer with a monoalcohol; (b) from 5-70% by weight of a polyester polycarboxylic acid having an acid value of from 50-350 mg KOH/g (solid) obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; (c) from 10-80% by weight of a po
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: December 2, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
  • Patent number: 6649700
    Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and, optionally, (d) a resin that exists in the liquid form at room temperature.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: November 18, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
  • Patent number: 6642310
    Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: November 4, 2003
    Assignee: DuPont Dow Elastomers L.L.C.
    Inventors: George Richard Chapman, Jr., Steven Richard Oriani
  • Patent number: 6624250
    Abstract: A substantially transparent, moldable, thermoplastic multipolymer composition comprising a methyl methacrylate copolymer containing a predominant amount of methyl methacrylate and a minor amount of one or more ethylenically unsaturated monomers; and an effective amount of from about 1% to 35% by weight of the composition, of a polyetheresteramide to enhance the electrostatic charge dissipation of the copolymer. The polyetheresteramide has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition, when subjected to injection molding, is such that the injection-molded composition exhibits a haze of not greater than about 25% and a light transmission of at least about 60%. The composition may include an impact modifier which also has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition may also include a minor amount of a polyethylene glycol having a weight average molecular weight of about 2,000 to about 10,000.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: September 23, 2003
    Assignee: Cyro Industries
    Inventor: Daniel Zimmerman
  • Publication number: 20030153684
    Abstract: Polyester compositions useful to improve the impact and heat distortion properties of polyethylene terephthalate, providing the polyethylene terephthalate with both high notched Izod properties and high heat distortion properties. The composition is the reaction of a terpolymer of ethylene, an acrylate or a methacrylate, and glycidyl methacrylate with polyethylene terephthalate in the presence of at least one elastomer such as a copolymer of ethylene and 1-octene, and polypropylene, an ethylene propylene copolymer, polybutyleneterephthalate, polycyclohexanedimethanolterephthalate, or mixtures thereof, having a melt flow of about 6 to about 15 g/10 min. The product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.
    Type: Application
    Filed: January 31, 2003
    Publication date: August 14, 2003
    Applicant: HITECH POLYMERS INC.
    Inventor: Gerald W. Miller
  • Publication number: 20030134978
    Abstract: A powder coating composition includes an acid-functional polyester resin and a matting agent selected from styrene-maleic anhydride copolymers and acid-functional acrylic resins. The compositions provide low gloss finishes at low curing temperatures, as well as consistent gloss over a wide range of curing temperatures.
    Type: Application
    Filed: October 9, 2002
    Publication date: July 17, 2003
    Inventors: Tina L. Tullos, Brian T. Myers, Charles P. Tarnoski
  • Patent number: 6586527
    Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: July 1, 2003
    Assignee: General Electric Company
    Inventors: Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
  • Patent number: 6579943
    Abstract: A method of producing modified polyester moulded articles which is characterized in that, when producing moulded articles from a modified polyester composition comprising a polyester composed of an acid component chiefly consisting of aromatic dicarboxylic acid and glycol component chiefly consisting of aliphatic diol, and a modified polyolefin, there is incorporated an ethylene-acrylate copolymer; together with the moulded articles produced thereby.
    Type: Grant
    Filed: June 26, 2000
    Date of Patent: June 17, 2003
    Assignee: Elf Atochem S.A.
    Inventors: K Ishino, Takatoshi Ku-Ratsuji
  • Patent number: 6576309
    Abstract: Thermoplastic compositions comprising a bulk polymer, an additive, and a compatibilizer/emulsifier/surfactant (CES) are described. The bulk polymer comprises an alkylene terephthalate or naphthalate polyester such as polyethylene terephthalate. The additive comprises an amorphous or substantially amorphous co-polymer of ethylene and a co-monomer that forms polar portions, such as methacrylate, butylacrylate, ethyl acrylate, or ethylhexyl methacrylate. The CES comprises a co-polymer or ter-polymer of ethylene and a glycidyl acrylate or maleic anhydride, and optionally an acrylate such as methacrylate, ethylacrylate, propylacrylate, butylacrylate, ethylhexylacrylate, or mixtures thereof. The thermoplastic compositions of the present invention exhibit improved molding properties, high dimensional stability, high temperature resistance, and are particularly useful in food-grade applications such as dual-ovenable containers.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: June 10, 2003
    Assignee: Associated Packaging Enterprises
    Inventors: Edward J. Dalgewicz, III, John Bond
  • Publication number: 20030105231
    Abstract: Polyester compositions useful to improve the impact and heat distortion properties of polyethylene terephthalate, providing the polyethylene terephthalate with both high notched Izod properties and high heat distortion properties. The composition is the reaction of a terpolymer of ethylene, an acrylate or a methacrylate, and glycidyl methacrylate with polyethylene terephthalate in the presence of at least one elastomer such as a copolymer of ethylene and 1-octene.
    Type: Application
    Filed: November 28, 2001
    Publication date: June 5, 2003
    Applicant: HITECH POLYMERS INC.
    Inventor: Gerald W. Miller
  • Publication number: 20030100678
    Abstract: The present invention provides a low temperature curing coating powder composition comprising a mixture of a high gloss film-forming system and a low gloss film-forming system. Preferably, the high gloss film-forming system comprises a GMA (glycidyl methacrylate) resin, a curing agent, and a catalyst and forms a coating having a gloss greater than 80% measured at 60°. Preferably the low gloss film-forming system comprises a carboxyl terminated polyester, acrylic resin and a catalyst and forms a coating having a gloss less than 50% measured at 60°. The composition of the present invention provides coatings having a control gloss, which can range from a low to a high gloss and is useful for coating heat-sensitive substrates.
    Type: Application
    Filed: November 13, 2002
    Publication date: May 29, 2003
    Inventors: Edward G. Nicholl, Andrew T. Daly, Carryll A. Seeling
  • Patent number: 6509417
    Abstract: A multi-component coating composition having a hard, glossy, and tack-free finish is described. The coating composition comprises a fatty acid modified glycidyl-containing component and a hydroxy-functional polymer. The coating composition can be used to originally finish or to refinish such articles as farm, industrial, and construction equipment, automobiles, and trucks, and to paint structures such as bridges, buildings, appliances, metal furniture, and the like.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: January 21, 2003
    Assignee: Lilly Industries, Inc.
    Inventors: Wylie H. Wetzel, William G. O'Dell
  • Publication number: 20030008976
    Abstract: The invention relates to thermoplastic compositions comprising a thermoplastic polymer, in which polymer is incorporated a crosslinked phase originating from the reaction:
    Type: Application
    Filed: August 27, 1999
    Publication date: January 9, 2003
    Inventors: ALAIN BOUILLOUX, LAURENT TEZE
  • Publication number: 20020188073
    Abstract: A polyester type resin composition comprising (A) 30 to 95 parts by weight of a polybutylene terephthalate type resin containing a polybutylene terephthalate-isophthalate copolymer in which the content of an isophthalic acid ingredient to the entire dicarboxylic acid ingredient is 3 to 30 mol %, (B) 1 to 30 parts by weight of a polycarbonate resin, (C) 1 to 30 parts by weight of an elastomer and (D) 3 to 60 parts by weight of a fibrous reinforcing material, wherein the total amount for (A)-(D) is 100 parts by weight, the composition being used for insert molding.
    Type: Application
    Filed: March 21, 2002
    Publication date: December 12, 2002
    Inventors: Tomoyuki Uno, Takashi Sugata, Akira Hirai, Tetsuya Hirose, Hiroyuki Yamazaki, Kazuo Kato
  • Publication number: 20020188074
    Abstract: A method of producing extruded synthetic lumber for use in construction matting comprising the steps of first, providing a blend of ground synthetic particles, the blend selected from the group comprising primarily ground high density polyethylene particles and ground polyethylene terephthalate particles in an amount not more than 99.0 percent by weight and a composition of ground styrene-butadiene rubber comprised primarily of tire buffings in an amount from 1.0 percent to about 3.5 percent by weight. The blend is mixed, heated and extruded into dimensional lumber and then cooled. The resulting lumber has a low retained memory and reduced electrosstatic potential.
    Type: Application
    Filed: April 29, 2002
    Publication date: December 12, 2002
    Inventors: Robert S. Parker, Ernest E. Holden, Mark L. Phillips
  • Publication number: 20020177662
    Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.
    Type: Application
    Filed: March 20, 2001
    Publication date: November 28, 2002
    Inventors: Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
  • Patent number: 6476125
    Abstract: A fluorine-containing polymer alloy comprising a grafted fluorine-containing polymer (a) and a polymer (c) containing no fluorine atom, said grafted fluorine-containing polymer (a) comprising a fluorine-containing polymer (d) having hydrogen atoms bonded to carbon atoms of its main chain and a grafting compound having a linking group capable of grafting to the fluorine-containing polymer (d) and a functional group capable of providing an adhesive property, grafted to the fluorine-containing polymer (d).
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: November 5, 2002
    Assignee: Asahi Glass Company Ltd.
    Inventors: Jun-ichi Iura, Eiichi Nishi, Masataka Yokota
  • Patent number: 6476145
    Abstract: Polyester injection-moulded parts based on a polyester (A) and on a copolymer (B) of ethylene and of an unsaturated epoxy, such that weight % (B)×MFI (A+B)/MFI(A) is greater than 3 and in this expression: MFI (A+B) denotes the melt flow index of the modified polyester, that is to say the blend of (A) and (B) and of any fillers; MFI (A) denotes the melt flow index of the polyester (A) and of any fillers (without (B)); and weight % (B) denotes the percentage by weight of (B) in the blend of (A) and (B) and of any fillers.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: November 5, 2002
    Assignee: Atofina
    Inventors: Patrice Perret, Jacques Komornicki, Yoshiyuki Miyaki
  • Publication number: 20020161121
    Abstract: Disclosed is a high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprising:
    Type: Application
    Filed: April 30, 2002
    Publication date: October 31, 2002
    Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
  • Patent number: 6444754
    Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: September 3, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
  • Patent number: 6437056
    Abstract: Coating composition suitable for multilayer lacquering, containing, in addition to organic solvent, anti-sagging agents, optionally pigments, extenders and additives, a binder/crosslinkin agent system containing A) from 20 to 80 wt. % of carboxyl-functional (meth)acrylic copolymers and/or carboxyl-functional polyesters having an acid number of from 20 to 300, B) from 20 to 80 wt. % of epoxy-functional crosslinking agents, the percentages by weight of A) and B) adding up to 100 wt. %. C) from 0 to 30 wt. % of polymer polyol C), based on the sum of the weights of A) and B), E) from 0 to 20 wt. % of further crosslinking agents, based on the sum of the weights of A, B, and C), F) from 0 to 10 wt. % of monoepoxides, based on the sum of the weights of A) and B), and D) as anti-sagging agents, from 0.1 to 3 wt.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: August 20, 2002
    Assignee: E. I. du Pont de Nmeours and Company
    Inventors: Ralf Dahm, Carmen Flosbach, Hermann Kerber, Walter Schubert, Astrid Tückmantel
  • Patent number: 6428900
    Abstract: A water-sensitive hot melt adhesive composition based on sulfonated branched copolyester polymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. The adhesive composition includes about 10% to about 90%, by weight, of a sulfonated polyester copolymer or a blend of one or more sulfonated polyester polymers; about 0% to about 80%, by weight, of a tackifying resin; about 0% to about 40%, by weight, of a compatible plasticizer; about 5% to about 50% by weight of a polyethylene glycol having a molecular weight greater than 2000 and a melting point greater than 50° C; and about 0% to about 3% by weight of one or more antioxidant. The adhesive maintains the article in an assembled condition by providing adequate adhesive bond strength during normal use, but dissolves in the presence of water thereby permitting the article to be recycled or otherwise disposed of in an environmentally friendly manner.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: August 6, 2002
    Assignee: Ato Findley, Inc.
    Inventor: Baoyu Wang
  • Patent number: 6417284
    Abstract: A release coating layer comprising a continuous phase of an organic polymer binder; a discontinuous phase of a fluorinated resin having a molecular weight between 2500 and 10,000,000, wherein the ratio of organic polymer binder to fluorinated resin is between 60:39.9 to 80:18 by weight; and a priming agent composition comprising a perfluoroalkylsubstituted fluororesin-reactive compound having the formula: where R5 is H or F, Q is OH, SiR6R7R8, R6, R7, and R8 being independently selected from the group consisting of Cl, OH, an alkyl group containing 1 to about 4 carbon atoms, an alkoxy group containing 1 to about 4 carbon atoms, an acyloxy group containing 2 to about 4 carbon atoms, and an amino group containing 0 to about 4 carbon atoms; and n is an integer from 1 to about 15; with the proviso that, at least one of R6, R7, and R8 is Cl, OH, or an alkoxy, acyloxy, or amino group.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: July 9, 2002
    Assignee: NexPress Solutions LLC
    Inventors: Jiann-Hsing Chen, Biao Tan, Joseph A. Pavlisko, Robert A. Lancaster, Craig M. Cody
  • Patent number: 6414081
    Abstract: The invention relates to compatibilized blends comprising a non-polar thermoplastic elastomer, a polar thermoplastic polymer selected from thermoplastic polyurethane (TPU), chloro containing polymers, fluoro containing polymers, polyesters, acrylonitrile-butadiene-styrene copolymers, styrene-acrylonitrile copolymers, styrene-maleic anhydride copolymer, polyacetal, polycarbonate, polyphenylene oxide, and a suitable compatibilizer.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: July 2, 2002
    Assignee: Advanced Elastomer Systems, LP.
    Inventor: Trazollah Ouhadi
  • Patent number: 6410647
    Abstract: A high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprises: (a) 10 to 70% by weight of an acrylic polycarboxylic acid having 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g (solid) and a number-average molecular weight of 500 to 8000; (b) 5 to 70% by weight of a polyester polycarboxylic acid having an acid value of 50 to 350 mg KOH/g (solid), a number-average molecular weight of 400 to 3500 and a ratio of weight-average molecular weight to number-average molecular weight of 1.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: June 25, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
  • Patent number: 6407164
    Abstract: The present invention relates to a multiphase thermoplastic composition consisting of a mixture (I) including at least one ethylene polymer (A) which has units derived from unsaturated epoxy and at least one thermoplastic resin (B) partly encapsulated by the said ethylene polymer (A), the said mixture (I) being dispersed in a matrix of thermoplastic resin (C).
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: June 18, 2002
    Assignee: Atofina SA
    Inventors: Marius Hert, Patrice Perret
  • Patent number: 6399700
    Abstract: Synthetic comb copolymers which elicit controlled cellular response, methods of applying these polymers to various surfaces, and methods of using the polymers for modifying biomaterial surfaces, in tissue engineering applications and as drug delivery devices are provided. The comb copolymers are comprised of hydrophobic polymer backbones and hydrophilic, non-cell binding side chains which can be end-capped with cell-signaling ligands that guide cellular response. By mixing non-cell binding combs with ligand-bearing combs, the surface concentration and spatial distribution of one or more types of ligands, including adhesion peptides and growth factors, can be tuned on a surface to achieve desired cellular response. In one embodiment, the combs are used as stabilizing agents for dispersion polymerization of latexes. The comb-stabilized latexes can be applied to substrates by standard coating operations to create a bioregulating surface, or used as drug delivery agents.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: June 4, 2002
    Assignee: Massachusetts Institute of Technology
    Inventors: Anne M. Mayes, Linda G. Griffith, Darrell J. Irvine, Pallab Banerjee, Terry D. Johnson
  • Patent number: 6380309
    Abstract: A method of producing a synthetic structural material for use in constructing mats for temporary roads and access areas. The matting is formed from extruded synthetic structural members formed from a blend comprising HDPE; SBR in an amount less than 4.0 percent by weight of the blend; and PET. Extruded structural members so produced have low electrostatic properties with a desired structural flexibility and resistance to retained memory after loading.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: April 30, 2002
    Inventors: R. S. Parker, E. E. Holden, Jr., Mark L. Phillips
  • Patent number: 6357802
    Abstract: An air-pressure joint 1 comprising a pipe main body 2 made of a rigid thermoplastic resin and a release ring 3 made of a rigid thermoplastic resin inserted from one opening of the pipe main body, wherein the release ring includes a slip-off preventing protrusion 13 on an outer circumferential surface of its insertion site; and the pipe main body 2 includes a ring-shaped sealing portion 9 made of an elastic resin and integrally formed on an inner circumferential surface thereof, an insertion mouth pipe portion 7 made of a rigid rigid resin, coaxially disposed to abut one opening side portion of the pipe main body 2 and forming a recess groove 10 on an inner circumferential surface of an abutting portion thereof for stopping the slip-off preventing protrusion 13 of the release ring 3, and a ring-shaped connecting portion 8 made of a rigid synthetic resin and integrally molded to an outer circumferential surface of the abutting portion of this mouth pipe for connecting the insertion mouth pipe portion 7 to the p
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: March 19, 2002
    Assignees: Mikuni Plastics Co., Ltd., Daicel-Hüls, Ltd., Daicel Chemical Industries, Ltd.
    Inventors: Nobuhiro Nozato, Atsushi Inagaki, Shinichi Matsumoto, Hajime Komada, Mitsuteru Mutsuda, Masanori Hiraishi
  • Patent number: 6355319
    Abstract: The present invention provides a polyester resin composition comprising (A) a polyethylene terephthalate composed mainly of repeating units derived from a dicarboxylic acid containing terephthalate acid and/or an esterified derivative thereof and a diol containing ethylene glycol and/or esterified derivative thereof, and (B) an ethylene/(meth) acrylic acid copolymer and, optionally, (C) polyethylene. The polyethylene terephthalate contains diethylene glycol units in a ratio of 0.5 to 2.0% by weight and a cyclic trimer in an amount not greater than 0.5% by weight based on polyethylene terephthalate. The ethylene/ (meth) arcylic acid coploymer is in an amount of 0.1 to 10,000 ppb based on the composition. Also provided are a perform formed from the composition and a blow molded container produced therefrom.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 12, 2002
    Assignee: Mitsui Chemicals INC
    Inventors: Koji Nakamachi, Hiroji Niimi, Mitsuaki Masumoto
  • Patent number: 6346571
    Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C4 to C7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: February 12, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
  • Patent number: 6329450
    Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: December 11, 2001
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott