Solid Polymer Derived From Ethylenic Reactants Only Derived From At Least One Reactant Containing An Oxygen Atom Patents (Class 525/176)
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Patent number: 8268738Abstract: A biodegradable fiber that is formed from a thermoplastic composition that contains polylactic acid, a plasticizer, and a compatibilizer is provided. The compatibilizer includes a polymer that is modified with a polar compound that is compatible with the plasticizer and a non-polar component provided by the polymer backbone that is compatible with polylactic acid. Such functionalized polymers may thus stabilize each of the polymer phases and reduce plasticizer migration. By reducing the plasticizer migration, the composition may remain ductile and soft. Further, addition of the functionalized polymer may also promote improved bonding and initiate crystallization faster than conventional polylactic acid fibers. The polar compound includes an organic acid, an anhydride of an organic acid, an amide of an organic acid, or a combination thereof. Such compounds are believed to be more compatible with the generally acidic nature of the polylactic acid fibers.Type: GrantFiled: May 30, 2008Date of Patent: September 18, 2012Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ryan J. McEneany, Vasily A. Topolkaraev, Aimin He
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Production method of polyethylene terephthalate graft copolymerized resin and molded product thereof
Patent number: 8258239Abstract: The present invention provides a method of producing a polyethylene terephthalate graft copolymerized resin, comprising subjecting the following mixture to a homogeneous reaction at a temperature of 250° C. or higher to impart a high melt viscosity to the mixture, the mixture containing (A) 100 parts by weight of a polyethylene terephthalate polyester as a main material, (B) 0.01 to 2 parts by weight of a polymeric polyfunctional epoxy compound containing 7 to 100 epoxy groups in a molecule and having a molecular weight of 1,000 to 300,000 as a coupling agent, (C) 0.01 to 1 part by weight of a metal salt of an organic acid as a coupling reaction catalyst, and (D) 0 to 100 parts by weight of an aromatic alicyclic polyester and/or an aromatic aliphatic polyester each having a carboxyl group in an aromatic nucleus as an auxiliary material.Type: GrantFiled: December 28, 2007Date of Patent: September 4, 2012Assignee: Ftex, IncorporatedInventors: Takashi Fujimaki, Yoshitomo Urata, Hiroshi Shibano -
Patent number: 8257821Abstract: A light diffusion film which has excellent light transmittance and light diffusibility while maintaining excellent heat resistance, mechanical strength and thickness accuracy intrinsic to a biaxially stretched film, and is suppressed in generation of curling after heat treatment, wherein the film comprises a biaxially stretched laminated film having a supporting layer consisting of a crystalline polyester, and a light diffusion layer laminated on at least one side of the supporting layer by a co-extrusion method, wherein the light diffusion layer comprises 60 to 98 parts by mass of the crystalline polyester and 2 to 40 parts by mass of a light diffusion additive incompatible with the polyester, and the light diffusion film has a planar orientation degree (?P) of 0.080 to 0.160, a total light transmittance of 85% or more, and a haze of 30% or more.Type: GrantFiled: March 29, 2007Date of Patent: September 4, 2012Assignee: Toyo Boseki Kabushiki KaishaInventors: Yasushi Sasaki, Yoshitomo Ikehata, Jun Inagaki
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Patent number: 8242209Abstract: A composition is disclosed which comprises a mixture of a poly(trimethylene terephthalate) polymer composition, a nucleating agent, and an ethylene copolymer. Also disclosed in a method for reducing the melt viscosity of nucleated poly(trimethylene terephthalate) polymer composition.Type: GrantFiled: January 23, 2009Date of Patent: August 14, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Charles John Talkowski, Karlheinz Hausmann, David J. Walsh
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Patent number: 8236727Abstract: An oxygen-absorbing resin composition having excellent performance is provided which contains an oxygen-absorbing polyester and a polyolefin and has enhanced compatibility between the polymers to give an oxygen-absorbing layer inhibited from having a reduced cohesive force or an appearance failure such as roughness unevenness. The oxygen-absorbing resin composition is characterized by being obtained by melt-kneading the following ingredients (A) and (B) together with the following ingredient (C) as a compatibilizing agent. Ingredient (A): an oxygen-absorbing polyester; Ingredient (B): a polyolefin; and Ingredient (C): a copolymer of ethylene and a vinyl monomer having a hydroxy group or an ester bond, the copolymer having an ethylene proportion of 70-99 mol %.Type: GrantFiled: January 19, 2009Date of Patent: August 7, 2012Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Yoshihiro Ohta, Yui Yamaguchi, Yoichi Ishizaki
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Publication number: 20120196064Abstract: Thermoplastic polyester compositions, comprising: (a) 54-98% by weight of at least one polytrimethylene terephthalate; (b) 1-45% by weight of at least one impact modifier, and the at least one impact modifier is selected from ethylene copolymers having a general formula of E/X/Y, wherein: E is a radical derived from ethylene and accounts for 40-90% by weight of the total weight of the ethylene copolymer; X accounts for 9-55% by weight of the total weight of the ethylene copolymer and is a radical derived from a monomer having the following general formula: wherein, R1 is an alkyl containing 2-8 carbon atoms; R2 is H, CH3 or C2H5; Y is a radical derived from a monomer unit selected from glycidyl methacrylates and glycidyl acrylates and accounts for 0.5-40% by weight of the total weight of the ethylene copolymer; and (c) 0.01-3.0% by weight of a cationic catalyst, and the cation is selected from the group consisting of Mg2+, Sn2+, and Zn2+ and mixtures of these.Type: ApplicationFiled: July 29, 2010Publication date: August 2, 2012Applicant: E.I.DU PONT DE NEMOURS AND COMPANYInventors: Lin Fang, Hua Jiao, Lei Ying, Linda S. Ankrom, Edmund Arthur Flexman
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Publication number: 20120184678Abstract: Methods for forming high molecular weight chain-extended condensation polymers are disclosed. The methods include adding a chain extender during the polymerization process of a condensation polymer to provide a chain-extended condensation polymer, wherein the chain extender comprises a polymerization product of at least one epoxy-functional (meth)acrylic monomer, and at least one styrenic and/or (meth)acrylic monomer.Type: ApplicationFiled: July 21, 2010Publication date: July 19, 2012Inventors: Gary A. Deeter, Marco A. Villalobos
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Patent number: 8211979Abstract: A multicomponent system is provided, composed of a thermoplastic component and of a rubber component, which comprises at least two different peroxidic crosslinking agents with specific decomposition temperatures, as also is a process for production of rubber-thermoplastic composite mouldings using the multicomponent system, and also the resultant rubber-thermoplastic composite mouldings.Type: GrantFiled: December 15, 2006Date of Patent: July 3, 2012Assignee: LANXESS Deutschland GmbHInventors: Dirk Achten, Stefanie Nickel, Maik Schulte, Michael Münker, Detlev Joachimi
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Publication number: 20120149844Abstract: Toughened polyhydroxyalkanoate resin compositions are disclosed, comprising thermoplastic polyhydroxyalkanoate compositions and a toughener comprising a vinyl acetate homopolymer or copolymer and optionally polyvinyl alcohol.Type: ApplicationFiled: August 27, 2010Publication date: June 14, 2012Inventor: Robert S. Whitehouse
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Publication number: 20120149794Abstract: The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N?-trimethyl-bis-(aminoethyl)ether. N,N,N?-trimethyl-bis-(aminoethyl)ether and its derivatives can be used as polyurethane catalysts.Type: ApplicationFiled: February 22, 2012Publication date: June 14, 2012Applicant: Air Products and Chemicals, Inc.Inventors: Juan Jesus Burdeniuc, Stephan Herman Wendel, John William Mitchell
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Patent number: 8188186Abstract: An object of the present invention is to provide a golf ball having excellent durability and flight distance. The present invention provides a golf ball comprising: a core consisting of a center and one or more intermediate layers covering the center; and a cover covering the core, wherein, at least one piece or one layer of said intermediate layers is formed from a highly elastic intermediate layer composition that contains a highly elastic resin (A) having a flexural modulus in a range from 700 MPa to 5000 MPa and an ionomer resin (B) having a flexural modulus in a range from 150 MPa to 1000 MPa in an amount ratio ((A)/(B)) of the highly elastic resin (A) to the ionomer resin (B) being (20 mass % to 80 mass %)/(80 mass % to 20 mass %) (the total is 100 mass %).Type: GrantFiled: April 17, 2009Date of Patent: May 29, 2012Assignee: SRI Sports LimitedInventor: Satoko Okabe
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Publication number: 20120128984Abstract: A polyester resin composition containing 70 to 99.5% by mass of a polyester resin (A) which contains a dicarboxylic acid unit and a diol unit and in which 1 to 60 mol % of the diol unit is a diol unit having a cyclic acetal skeleton, and 0.5 to 30% by mass of a core/shell type rubber which has an average particle size of 1 ?m or less and which exhibits an absolute difference between the refractive index thereof and the refractive index of the polyester resin (A) is 0.02 or less.Type: ApplicationFiled: July 28, 2010Publication date: May 24, 2012Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventor: Tadashi Kawabata
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Publication number: 20120116020Abstract: A copolyester composition includes: an aliphatic-aromatic copolyester; a coupling agent including a compound having an epoxy functional group; and a cocatalyst including a carboxylate of manganese and a carboxylate of zinc, wherein a weight ratio of the carboxylate of manganese to the carboxylate of zinc ranges from 1:3 to 3:1, and the cocatalyst is present in an amount ranging from 0.03-0.2 part by weight based on 100 parts by weight of the aliphatic-aromatic copolyester.Type: ApplicationFiled: August 30, 2011Publication date: May 10, 2012Inventors: Chih-Ying KUO, Chuan-Hao Hsu, Chi-Wei Ciou, Li-Ling Chang, Roy Wu
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Patent number: 8168721Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.Type: GrantFiled: February 6, 2009Date of Patent: May 1, 2012Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
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Publication number: 20120100263Abstract: A method and system for oxygen molecule scavenging is disclosed. The system employs as a novel terpolymer as the reducing agent for oxygen molecules. The terpolymer is the polymerization product of macrocyclic poly(alkylene dicarboxylate) oligomer, unsaturated functional polymer, and epoxy-functional styrene-acrylate oligomer.Type: ApplicationFiled: June 17, 2010Publication date: April 26, 2012Applicant: POLYONE CORPORATIONInventors: Ling Hu, Roger W. Avakian
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Patent number: 8163850Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.Type: GrantFiled: February 6, 2009Date of Patent: April 24, 2012Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt
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Patent number: 8114522Abstract: Disclosed is a resin composition forming an adhesive layer between a polylactic acid resin substrate layer and a polyolefin resin substrate layer. The resin composition includes a modified polyolefin resin (A) and a terpene resin (B), and the mass ratio (A)/(B) between the both resins (A) and (B) is 20/80 to 99/1. Alternatively, the resin composition may be a resin composition including 10 to 90% by mass of a polylactic acid resin (C), 5 to 89% by mass of the modified polyolefin resin (A) and 1 to 80% by mass of a hydrogenated petroleum resin (D), with the total amount of these resins constrained to be 100% by mass.Type: GrantFiled: February 16, 2009Date of Patent: February 14, 2012Assignee: Unitika Ltd.Inventors: Yuji Kitora, Mitsuhiro Kawahara, Kazue Ueda
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Publication number: 20120028783Abstract: A plasticized binder composition suitable as a binder for chopped strand mats comprising (a) a copolymer obtainable by reacting; (i) 60-95 pphwm of vinyl acetate; and (ii) 5-40 pphwm of vinyl ester of ?-substituted alkanoic acid; and b) a plasticizer, wherein the weight ratio of copolymer/plasticizer is from 1 to 6.Type: ApplicationFiled: June 17, 2011Publication date: February 2, 2012Inventors: Hendrikus van Boxtel, Paolo Bavaj, Steve Laborda, Marc T. Ratering, Peter M. Zeimentz
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Patent number: 8106115Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: February 20, 2009Date of Patent: January 31, 2012Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8097076Abstract: Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one ?,?-unsaturated monocarboxylic acid and/or at least one ?,?-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.Type: GrantFiled: July 28, 2010Date of Patent: January 17, 2012Assignee: BYK-Chemie GmbHInventors: Bernd Göbelt, Carsten Nagel, Jürgen Omeis, Marcus Meichsner, Diana Walter
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Patent number: 8093334Abstract: A dispersion of polymer microparticles in organic liquid, the polymer comprising the reaction product of i) from 2 to 40 parts by weight of a first polymer being polypropylene polymer having sufficient carboxylic acid and/or carboxylic acid anhydride groups equivalent to an acid value of from 2 to 50 mg KOH/g nv polymer and ii) from 60 to 98 parts by weight of a second polymer having a molar excess of functional groups capable of reacting with the carboxylic acid and/or carboxylic acid anhydride groups of the polypropylene polymer and wherein the organic liquid is chosen to be a good solvent for the second polymer and a poor solvent for the polypropylene polymer.Type: GrantFiled: April 30, 2008Date of Patent: January 10, 2012Assignee: Akzo Nobel Coatings International B.V.Inventors: Riaz Ahmad Choudhery, David George James
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Publication number: 20110318519Abstract: Polymer blends suitable for packaging are disclosed that include one or more impact modifiers; and one or more polyethylene terephthalate homopolymers or copolymers obtained by a melt phase polymerization using a catalyst system comprising aluminum atoms in an amount, for example, from about 3 ppm to about 60 ppm and one or more alkaline earth metal atoms, alkali metal atoms, or alkali compound residues in an amount, for example, from about 1 ppm to about 25 ppm, in each case based on the weight of the one or more polyethylene terephthalate homopolymers or copolymers The polymer blends disclosed exhibit improved low temperature toughness compared with blends made using polymers prepared with conventional catalyst systems.Type: ApplicationFiled: August 31, 2011Publication date: December 29, 2011Applicant: GRUPO PETROTEMEX, S.A. DE C.V.Inventors: Frederick Leslie COLHOUN, Mark Edward Stewart, Stephen Weinhold, Richard Dalton Peters, Roger Lee Martin
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Patent number: 8084539Abstract: A resin composition is provided which comprises 10 to 88% by mass of a propylene-based polymer (A) composed of 30 to 70% by mass of a propylene-based polymer (a) having a melt flow rate of 0.1 to 17 g/10 minutes measured at a temperature of 230° C. and a load of 21.18N and 30 to 70% by mass of a propylene-based polymer (b) having a melt flow rate of 80 to 300 g/10 minutes measured at a temperature of 230° C. and a load of 21.18N; 10 to 88% by mass of a polylactic acid-based resin (B); 1 to 50% by mass of an ethylene-based polymer having an epoxy group (C); and 1 to 50% by mass of an elastomer (D).Type: GrantFiled: December 14, 2009Date of Patent: December 27, 2011Assignee: Sumitomo Chemical Company, LimitedInventor: Koji Kameo
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Patent number: 8084540Abstract: There is provided a propylene-based resin composition containing 10 to 89% by mass of a propylene-based polymer (A) (excluding a modified propylene-based polymer (C) defined below), 10 to 89% by mass of a polylactic acid-based resin (B), and 1 to 80% by mass of a modified propylene-based polymer (C) which is an ?,?-unsaturated glycidyl ester-grafted propylene-based polymer having an ?,?-unsaturated glycidyl ester-derived structural unit content of 0.1% by mass or more and less than 1.0% by mass, provided that each of the contents of the propylene-based polymer (A), the polylactic acid-based resin (B) and the modified propylene-based polymer (C) is an amount based on the total amount of the three components.Type: GrantFiled: October 24, 2008Date of Patent: December 27, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Koji Kameo, Mitsuyoshi Shimano
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Patent number: 8076406Abstract: The present invention relates to a composite having improved impact resistance. According to the invention, this composite is obtained from a composition comprising the following polymers: polylactic acid (PLA) which forms the matrix; at least one polyamide forming a dispersed phase within the PLA matrix; at least one functionalized polyolefin (A) comprising alpha-olefin units and epoxy, carboxylic acid or carboxylic acid anhydride units; and, optionally, at least one unfunctionnalized polyolefin (B).Type: GrantFiled: June 14, 2007Date of Patent: December 13, 2011Assignee: Arkema FranceInventors: Benoit Brule, Thomas Fine, Jean-Jacques Flat, Maho Yasuda
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Patent number: 8063145Abstract: An object of the present invention is to provide a golf ball which is superior in durability to a golf ball having an ionomer resin cover which has conventionally been used. Another object of the present invention is to provide a golf ball using a non-petroleum based material. The golf ball of the present invention comprises a core and a cover covering the core, wherein at least either the core or the cover includes, as a resin component, a polyester resin containing a non-petroleum based material as a constitutional component.Type: GrantFiled: December 27, 2007Date of Patent: November 22, 2011Assignee: SRI Sports LimitedInventor: Satoko Okabe
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Patent number: 8053524Abstract: A golf ball material composed of (A) an olefin-containing thermoplastic polymer having an acid content of at least 0.5 wt % but less than 5.0 wt %, (B) a resin composition which includes one or more selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) an oxygen-containing inorganic metal compound has a good thermal stability, flow and processability, making it suitable for injection molding. The golf ball material is ideal for the production of high-performance golf balls endowed with durability, scuff resistance and optimal hardness without a loss of rebound in the molded article.Type: GrantFiled: July 15, 2009Date of Patent: November 8, 2011Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8048959Abstract: Disclosed are poly(hydroxyalkanoic acid) compositions comprising a poly(hydroxyalkanoic acid) polymer, such as poly(lactic acid), and an impact modifier comprising a copolymer of ethylene and one or more alkyl acrylates of the formula CH2?C(R1)CO2R2, where R1 is hydrogen or an alkyl group with 1-8 carbon atoms and R2 is an alkyl group with 1-8 carbon atoms, such as methyl, ethyl, or butyl.Type: GrantFiled: April 14, 2009Date of Patent: November 1, 2011Assignee: E.I. du Pont de Nemours and CompanyInventor: Julius Uradnisheck
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Patent number: 8044143Abstract: Disclosed are a polyester/polycarbonate alloy resin composition that includes: (A) a mixed resin including (A-1) a polycarbonate resin having a weight average molecular weight ranging from about 30,000 to about 200,000 g/mol and (A-2) a polyester resin having an intrinsic viscosity of about 0.85 to about 1.52 dl/g; (B) an acryl-based resin; and (C) an impact-reinforcing agent, and a molded product made using the polyester/polycarbonate alloy resin composition.Type: GrantFiled: December 18, 2009Date of Patent: October 25, 2011Assignee: Cheil Industries Inc.Inventors: Jung-Eun Park, Bang-Duk Kim, In-Sik Shim, Doo-Han Ha
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Publication number: 20110245393Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more Bifunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.Type: ApplicationFiled: June 17, 2011Publication date: October 6, 2011Inventors: Husam A.A. Rasoul, Dejan D. Andjelkovic, Dennis H. Fisher
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Publication number: 20110223365Abstract: The present disclosure relates to the preparation of acrylate, alkacrylate, allyl, and polycarbonate derivatives of hydroxy ketal esters, and uses thereof.Type: ApplicationFiled: September 25, 2009Publication date: September 15, 2011Applicant: SEGETIS, INC.Inventors: Sergey Selionov, Brian Daniel Mullen, Douglas Alan Wicks, Vivek Badarinarayana
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Patent number: 8013067Abstract: A curable thermoplastic elastomeric blend comprising: (a) from 15 to 60 weight percent of a polyalkylene phthalate polyester polymer or copolymer and; (b) from 40 to 85 weight percent of a poly(meth)acrylate or polyethylene/alkyl (meth)acrylate rubber in combination with an effective amount of peroxide free-radical initiator and an organic multiolefinic coagent to cross-link which upon extrusion or injection molding dynamically cross-link producing a melt processible thermoplastic elastomeric composition having a polyalkylene phthalate polyester polymer or copolymer continuous phase and of a cross-linked polyacrylate or polyethylene/acrylate rubber dispersed phase. Such compositions are useful in the manufacture of rubber parts having excellent resistance to lubricating oils and greases.Type: GrantFiled: July 30, 2004Date of Patent: September 6, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Herbert Vernon Bendler, Chun Sing Wong, David J. Walsh
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Patent number: 8003731Abstract: The invention relates to biodegradable polyester mixture, comprising i) from 5 to 80% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 20 to 95% by weight, based on the total weight of components i to ii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactide, polycaprolactone, polyhydroxyalkanoates, and polyesters composed of aliphatic dicarboxylic acids and of aliphatic diols, and iii) from 0.Type: GrantFiled: December 31, 2005Date of Patent: August 23, 2011Assignee: BASF SEInventors: Ursula Seeliger, Gabriel Skupin, Dirk Stärke
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Patent number: 7989556Abstract: An object of the present invention is to provide a modifier which improves moldability in melt molding, particularly, injection molding, extrusion molding, profile molding, direct blow molding, or calendar processing molding using a polyester resin and, furthermore, which can improve mechanical physical property while maintaining transparency, and a polyester molded article using the modifier. The present invention relates to a modifier for a polyester resin, comprising an amorphous polyester resin (I), and a reactive compound (II) containing two or more glycidyl groups and/or isocyanate groups per one molecule and having a weight average molecular weight of not less than 200 and not more than 500 thousands.Type: GrantFiled: December 1, 2004Date of Patent: August 2, 2011Assignee: Toyo Boseki Kabushiki KaishaInventors: Kenji Shiga, Mitsuo Nishida
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Patent number: 7989557Abstract: The invention is a composition comprising a blend of two or more epoxide containing compositions selected from epoxidized vegetable oils, epoxidized alkyl esters or cycloaliphatic epoxides. In another embodiment, the invention is a blend of one or more epoxidized vegetable oils, epoxidized alkyl esters, or cycloaliphatic epoxides with one or more aromatic epoxides or epoxy functionalized polyoxyalkylene polyols.Type: GrantFiled: October 6, 2010Date of Patent: August 2, 2011Assignee: Ashland Licensing and Intellectual Property LLCInventors: Robert L. Seats, Carroll G. Reid
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Patent number: 7989548Abstract: The invention relates to a new polymer blend comprising: 20 to 70 wt % of a mixture (A) of two or more polyalkylene phthalates; 2 to 60 wt % of a cross-linked acrylate rubber; 0.5 to 20 wt % of an ionomer; and 1 to 30 wt % of a terpolymer of ethylene, butylacrylate (BA) and glycidylmethacrylate (GMA); wherein the weight percentages are based on the sum of the above ingredients. The polymer blend of the invention is particularly suitable for blow-moulding, to make parts for high-temperature, high-oil-exposure uses.Type: GrantFiled: July 7, 2009Date of Patent: August 2, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Vincent Descombes, Philippe Leboeuf, Jean-Michel Philippoz, Michel C. Renaud, Serge Cavalli
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Publication number: 20110178247Abstract: The presently disclosed formula utilizes a composition of a rigid, semi-crystalline polymer, such as polybutylene terephthalate, and an amorphous polymer, such as poly(vinyl acetate), to create a thermoplastic shape memory polymer that can be processed through methods such as extrusion and injection molding, which require high heat. The polybutylene terephthalate acts as a cross-linker for the poly(vinyl acetate), therefore the thermoplastic shape memory polymer that is created has a much higher melting point and greater heat stability than other shape memory polymers.Type: ApplicationFiled: September 14, 2009Publication date: July 21, 2011Applicant: CORNERSTONE RESEARCH GROUP, INCInventors: Tat H. Tong, Lisa A. Bartlett
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Patent number: 7960473Abstract: A thermoplastic resin composition includes a thermoplastic resin (A) and a reactive functional group-containing resin (B), which has a specific structure in the morphology of the resin composition observed by transmission electron microscopy tomography, and the relaxation time T1C of each carbon nucleus by the solid NMR measurement of the thermoplastic resin composition containing a polyamide resin is kept in a specific range. The composition is excellent in the balance between contradictory properties such as impact resistance and heat resistance, remarkably exhibits a peculiar viscoelastic behavior not observed in the conventional polymeric materials, and is remarkably excellent in impact energy absorbing performance and vibration energy absorbing performance at the time of high-speed deformation.Type: GrantFiled: March 22, 2007Date of Patent: June 14, 2011Assignee: Toray Industries, Inc.Inventors: Sadayuki Kobayashi, Daisuke Sato, Masaru Akita, Hiroshi Jinnai, Takashi Inoue
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Patent number: 7943699Abstract: Disclosed are films, tapes, and melt-spun fibers prepared from a composition comprising (a) at least one polyester polymer and (b) from about 1 to 30 weight % of at least one ethylene copolymer such as ethylene/vinyl acetate dipolymers, ethylene/vinyl acetate terpolymers, ethylene/alkyl (meth)acrylate dipolymers, ethylene/alkyl (meth)acrylate terpolymers, functionalized ethylene copolymers, ethylene/acid copolymers, and salts thereof. The films, tapes and fibers exhibit improved tensile properties such as tensile strength and elongation at break compared to non-modified polyester compositions. Also disclosed are textiles and articles prepared from the fibers described.Type: GrantFiled: October 20, 2004Date of Patent: May 17, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Loic Pierre Rolland, Sam Louis Samuels
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Patent number: 7935759Abstract: The present invention is directed to a golf ball comprising a shield layer having heat resistant properties to facilitate compression molding of a thermosetting polybutadiene-comprising layer over at least one thermoplastic layer. The invention utilizes a thermoplastic inner core comprising of a low vicat highly neutralized ionomer material having a low melting point of less than 100° C., and a Shore C surface hardness of less than 80 and a compression of less than 70, wherein a shield layer is placed around the low vicat softening point temperature thermoplastic to shield it from the high heat necessary to mold a thermoset material about it.Type: GrantFiled: May 12, 2008Date of Patent: May 3, 2011Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Derek A. Ladd, Murali Rajagopalan
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Patent number: 7901780Abstract: It has now been discovered, according to the present invention, that interlayers comprising a blend of plasticized poly(vinyl butyral) and poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester can be used to form interlayers having a pearly white appearance. Such interlayers are useful in applications in which a colored multiple layer glass interlayer is desirable.Type: GrantFiled: June 25, 2008Date of Patent: March 8, 2011Assignee: Solutia Inc.Inventors: Wenjie Chen, Aristotelis Karagiannis, Witold Szydlowski, John Joseph D'Errico
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Publication number: 20110017751Abstract: Described are restaurant smallware comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylicacidcomponent having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: ApplicationFiled: October 7, 2010Publication date: January 27, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Publication number: 20100311896Abstract: There is described a thermosetting and/or radiation curable powder with a binder prepared from a polyester (PE) obtained from a polyol with lower amounts of neopentyl glycol (NPG). The powder forms smooth defect free coats and is resistant to contamination from conventional NPG-rich PE. The powder comprises a binder of a co-reactable blend of (i) 40-98% by weight (w/w) at least one OH, COOH or ethylenically functional (fn) PE having acid or OH number 10-100 mg KOH/g, T9>40° C., where the PE is obtained from reacting a polyacid comprising 70-100% weight of terephthalic acid (TPA) and/or isophthalic acid (IPA) and 0-30% w/w another polyacid; with a polyol comprising 0-85% w/w NPG and 15-100% w/w another polyhydric polyol; (ii) 2-60% w/w at least one glycidyl or isocyanate fn polyphenoxy resin; polyepoxy and/or ?-hydroxyalkylamide crosslinker or ethylenically functional oligomer; and (iii) 0.Type: ApplicationFiled: January 30, 2009Publication date: December 9, 2010Applicant: CYTEC ITALY S.R.L.Inventors: Roberto Cavalieri, Alessandro Minesso, Luc Moens, Delfio Favrin
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Patent number: 7847021Abstract: A modified polyolefin resin comprising a copolymer having a structure that a propylene-based polyolefin segment (a) and a segment (b) containing a lactic acid as a constituent are bonded in a block state and/or a graft state through a vinyl monomer having a hydroxyl group, wherein a number average molecular weight of the propylene-based polyolefin segment (a) is from 1,000 to 100,000, a number average molecular weight of the segment (b) containing lactic acid as a constituent is from 1,000 to 200,000, and a weight composition of the propylene-based polyolefin segment (a) and the segment (b) containing lactic acid as a constituent is from 10/90 to 90/10. The modified polyolefin resin can be used in a resin composition containing an aliphatic polyester resin (A), a polyolefin resin (B) and the modified polyolefin resin (C). The composition can exhibit excellent heat resistance and impact resistance and can be used for molding various parts.Type: GrantFiled: February 9, 2005Date of Patent: December 7, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Hosei Shinoda, Takeshi Kashima, Masahiro Enna, Shinichi Kojoh, Hideyuki Kaneko, Shingo Matsuo, Nobuo Kawahara, Tomoaki Matsugi, Yuichi Matsuda, Takayuki Onogi, Fumio Kageyama
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Patent number: 7842756Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: March 17, 2008Date of Patent: November 30, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Erick B. Iezzi
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Publication number: 20100273947Abstract: To obtain an ultrafine heat-shrinkable conjugate fiber at high productivity, in which a flow-drawing state of a polyester undrawn yarn is realized easily and stably. By drawing undrawn yarn comprising a conjugated polyester polymer and olefin polymer, a flow-drawing process can be easily and stably realized using conventional production facilities; and the heat-shrinkable fiber, a drawn intermediate, and an ultrafine hot-melt adhesive conjugate fiber produced by redrawing the drawn intermediate of the present invention can be obtained with high productivity and excellent runnability. More specifically, the ultrafine hot-melt adhesive conjugate fiber obtained by redrawing can be drawn at a heretofore unseen high drawing magnification, and the fiber structure of the olefin polymer constituting part of the conjugate fiber is markedly developed.Type: ApplicationFiled: October 20, 2008Publication date: October 28, 2010Applicants: ES FIBERVISIONS CO., LTD., ES FIBERVISIONS HONG KONG LIMITED, ES FIBERVISIONS LP, ES FIBERVISIONS APSInventors: Minoru Miyauchi, Tadashi Ideguchi, Masashi Teranaka
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Patent number: 7803874Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: July 18, 2006Date of Patent: September 28, 2010Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 7799412Abstract: The polylactic acid-based resin laminate sheet is a laminate sheet including Layer A and Layer B of a polylactic acid-based resin composition, and the Layer A and the Layer B contain poly(meth)acrylate in a specified amount. The laminate sheet is excellent in transparency and heat resistance and, in addition, provides a polylactic acid-based resin laminate sheet capable of obtaining a molded product of high biobased content therefrom.Type: GrantFiled: November 29, 2006Date of Patent: September 21, 2010Assignee: Toray Industries, Inc.Inventors: Go-hei Yamamura, Hiroshi Shinnumadate, Masahiro Kimura
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Publication number: 20100204363Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.Type: ApplicationFiled: February 6, 2009Publication date: August 12, 2010Applicant: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
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Patent number: 7771828Abstract: A binder composition for polyester type films showing superior transparency, film hardness and solvent resistance as well as superior adhesion to polyester type films and an optical film using the composition are provided. The binder composition for polyester type films of the present invention contains a high-molecular weight polymethyl methacrylate (a), an acrylic polyol (b), an isocyanate type curing agent (c), and a polyester resin (d). The optical film of the present invention is an optical film including a polyester type film and a functional layer provided on the polyester type film, the functional layer containing a high-molecular weight polymethyl methacrylate (a), an acrylic polyol (b), an isocyanate type curing agent (c), and a polyester resin (d).Type: GrantFiled: March 6, 2007Date of Patent: August 10, 2010Assignee: Kimoto Co., Ltd.Inventor: Yasumaro Toshima