With Ethylenically Unsaturated Reactant; Or Reactant Contains A Heterocyclic Ring Other Than Solely As A Lactam Or Cyclic Anhydride Of A Polycarboxylic Acid Patents (Class 525/181)
  • Patent number: 4968749
    Abstract: A resin composition comprising (a) a polyphenylene ether resin, (b) a non-crystalline or low-crystalline polyamide resin, (c) a crystalline polyamide resin and, if desired, (d) a polar compound or a low-molecular diene polymer or the component (d) and (e) a rubbery polymer or an alkenyl aromatic compound/conjugated diene copolymer or a hydrogeneration product thereof. The composition is excellent in both impact strength, particularly on a plane part of a plate-molded article, and dimensional stability.
    Type: Grant
    Filed: March 29, 1989
    Date of Patent: November 6, 1990
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Nobuhiro Shibuya, Kiyoji Takagi, Satoru Hattori, Tatsuo Kobayashi, Hironari Sano
  • Patent number: 4957980
    Abstract: A polyester resin composition having excellent gas barrier properties and transparency which comprises 100 parts by weight of a thermoplastic polyester resin (A), 1 to 100 parts by weight of a polyamide resin having metaxylylene group (B) and 0.01 to 50 parts by weight of a compatibilizing agent (C); and a polyester hollow molded article in the form of a single or multi-layered hollow molded article, wherein at least one of the layers is made of the above polyester resin composition.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: September 18, 1990
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shigeo Kobayashi, Toshio Hiramatsu, Katsumasa Yamamoto, Nobuhiko Ichikawa
  • Patent number: 4946907
    Abstract: A curable thermosetting prepolymerized imide resin composition is prepared by chemically reacting, at a temperature below 150.degree. C., a liquid mixture of a carboxy-terminated polybutadiene/acrylonitrile (CTBN) and a co-reactant containing at least one N,N'-bisimide of an unsaturated carboxylic acid of general formula (I) ##STR1## where B represents a divalent radical containing a carbon-carbon double bond and A represents a divalent radical having at least two carbon atoms, at least one monoimide, and at least one organic hydrazide, to yield a curable thermosetting prepolymerized imide resin composition containing copolymerized CTBN and co-reactant. A resin composition prepared by this method may be cured at a temperature between 100.degree. C. and 350.degree. C. to yield a fully cross-linked polymimide matrix containing a dispersion of phase-separated solid particles of copolymerized CTBN and co-reagent, said matrix having a lap shear strength at 20.degree. C.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: August 7, 1990
    Assignee: The Secretary of State for Defense in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Anthony J. Kinloch, Stephen J. Shaw
  • Patent number: 4923925
    Abstract: Resin compositions of (A) 50-95 percent by weight of a polyamide and (B) 5-50 percent by weight of a modified polyolefin containing in side chains 0.005-5 molar percent of functional groups expressed by formulas (I) and/or (II) below and 0.005-5 molar percent of functional groups expressed by formulas (III) and/or (IV) below provide molds having a high impact resistance and are applicable to automobile parts. ##STR1## Where R.sub.1 represents hydrogen or methl and wherein R.sub.2, R.sub.3 and R.sub.4 represent hydrogen, aliphatic, alicyclic or aromatic residual groups having 1-30 carbon atoms.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: May 8, 1990
    Assignee: Toray Industries, Inc.
    Inventors: Kazumasa Chiba, Kazuhiko Kobayashi, Osamu Ueno
  • Patent number: 4874817
    Abstract: Mixtures of imidized acrylic polymers and polyamides are described which have good flexural modulus properties.
    Type: Grant
    Filed: March 23, 1983
    Date of Patent: October 17, 1989
    Assignee: E. I. Du Pont De Nemours and Company
    Inventors: Harold K. Inskip, Marion G. Waggoner
  • Patent number: 4843127
    Abstract: The present invention includes a reactive elastomeric block co-oligomer; a copolymer containing a lactam, a co-catalyst/coupling agent, and the elastomeric block co-oligomer; and processes to make the block co-oligomer, and the copolymer.The reactive elastomeric block co-oligomer is the reaction product of a polycarboxylic acid, and a reactive moiety which can include a reactive polyether or a reactive polysulfide.The block co-oligomer of the present invention has been found to be useful to make a polymer containing lactam monomers, at least one coupling catalyst compound, and the block co-oligomer with the use of a catalyst.The present invention includes a process of forming the block co-oligomer of a polycarboyxlic acid and a reactive moiety. The reactive moiety can include a reactive polyether of a reactive polysulfide.The present invention further comprises a process of forming the block co-oligomer, and the process to form the lactam-block co-oligomer copolymer.
    Type: Grant
    Filed: April 19, 1985
    Date of Patent: June 27, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Murali K. Akkapeddi, David E. Bradley, Thomas D. Gallagher, deceased
  • Patent number: 4834933
    Abstract: A method of molding fiber-reinforced thermoset resin articles having improved mechanical properties. A thermosettable organic material is injected into a mold containing a fiber web. The molding composition includes (a) a thermosettable organic material containing two or more polymerizable carbon-carbon double bonds, (b) an ethylenically unsaturated monomer which forms a liquid homogeneous mixture with and is copolymerizable with (a) and is different from (a), and (c) an effective amount of an initiator or a mixture of initiators characterized by a ten-hour half life temperature, or in the case of a mixture of initiators, and average ten-hour half life temperature, of greater than about 50.degree. C. and less than 105.degree. C., which produces on decomposition less than 1.0 milliliter of gas per gram of resin as measured at a temperature of 25.degree. C. and a pressure of one atmosphere.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: May 30, 1989
    Assignee: Union Carbide Corporation
    Inventors: Hugh C. Gardner, Linda A. Domeier
  • Patent number: 4822688
    Abstract: Adhesive composition consisting essentially of polypropylene modified by grafting with an acid anhydride to further reacted with a compound bearing at least two groups capable of reacting with the anhydride preferrably a polyol or a polyamine.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: April 18, 1989
    Inventor: Pierre Nogues
  • Patent number: 4783511
    Abstract: A process for the preparation of moulded bodies of thermoplastic polyamides, which comprises intensively mixing a polyamide and a masterbatch, converting the mixture by conventional thermoplast processing to moulded bodies and, before use, conditioning the bodies by contact with ambient moisture or, briefly, with water, in which the masterbatch contains at least 5% by weight of a silane substituted by one, 2 or 3 hydrolysable radicals and a functional group which can undergo a chemical reaction, to form a bond, with amino groups and/or carboxyl groups and/or amide groups in the polyamide chain.
    Type: Grant
    Filed: June 11, 1987
    Date of Patent: November 8, 1988
    Assignee: Ems-Inventa AG
    Inventor: Eduard Schmid
  • Patent number: 4757112
    Abstract: This invention is an improvement over the copending Olivier application Ser. No. 537,789, now U.S. Pat. No. 4,594,386, filed Sept. 30, 1983 and entitled "Polyamide Grafted EPM Blend". This invention relates to the further improvement in impact strength and toughness of polycaprolactams and other polyamide based resinous compositions and to a new and improved method for the manufacture of same.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: July 12, 1988
    Assignee: Copolymer Rubber & Chemical Corp.
    Inventor: Shrikant V. Phadke
  • Patent number: 4728693
    Abstract: A thermoplastic resin composition, which comprises (a) from 5 to 85 parts by weight of a melted or remelted preliminary molding compound consisting of from 60 to 98 parts by weight of polyphenylene ethers, 40 to 2 parts by weight of polyoctylenes, from 0.1 to 5 parts by weight of maleic anhydride and from 0.1 to 5 parts by weight of a further acid derivative which has a melting point below 100.degree. C. and which is selected from the group consisting of an unsaturated mono- or dicarboxylic acid having up to 14 carbon atoms, an anhydride thereof, which excludes maleic anhydride, and an ester of mono- or dicarboxylic acid with an alcohol of up to 6 carbon atoms; and (b) from 95 to 15 parts by weight of an aliphatic homopolyamide or a copolyamide containing a preponderant amount of aliphatic monomer units.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: March 1, 1988
    Assignee: Huls Aktiengesellschaft
    Inventors: Michael Droscher, Hans Jadamus, Wolfgang Neugebauer, Martin Bartmann, Klaus Burzin, Roland Feinauer, Christian Gerth, Wilfried Ribbing, Jorg Lohmar
  • Patent number: 4695488
    Abstract: A soil release composition comprising:(A) a polymer comprising 10 to 100% by weight of constituting units of the formula: ##STR1## wherein R.sub.f is a C.sub.3 --C.sub.21 fluoroalkyl group; R.sup.1 is a hydrogen atom or a C.sub.2 --C.sub.4 acyl group; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are, the same or different, each a hydrogen atom, a methyl group or an ethyl group; A is a group of the formula: --CH.sub.2 CH(OR.sup.1)CH.sub.2 --OCO-- which R.sup.1 is the same as defined in the above, --CO--, --(CH.sub.2).sub.k N(R.sup.2)CO-- in which R.sup.2 is the same as defined in the above and k is an integer of 1 to 10, or --(CH.sub.2).sub.
    Type: Grant
    Filed: March 3, 1986
    Date of Patent: September 22, 1987
    Assignee: Daikin Industries, Ltd.
    Inventors: Iwao Hisamoto, Masaru Hirai, Sueyoshi Ishikawa
  • Patent number: 4595730
    Abstract: Unsaturated polyamide polymers are provided which are comprised of a polyamide chain terminated at one end by a group containing at least one double bond. The polymers are particularly useful in the preparation of molded object coatings, water tight joints, grafting onto thermoplastic polymers or copolymers, and the like.
    Type: Grant
    Filed: October 31, 1984
    Date of Patent: June 17, 1986
    Assignee: Atochem
    Inventors: Philippe Blondel, Camille Jungblut
  • Patent number: 4497935
    Abstract: A rubber-toughened addition-type polyimide composition having excellent high temperature bonding characteristics in the fully cured state and improved peel strength and adhesive fracture resistance physical property characteristics is disclosed. The process for making the improved adhesive involves preparing the rubber-containing amic acid prepolymer by chemically reacting an amine-terminated elastomer and an aromatic diamine with an aromatic dianhydride with which a reactive chain stopper anhydride has been mixed, and utilizing solvent or mixture of solvents for the reaction.
    Type: Grant
    Filed: January 28, 1983
    Date of Patent: February 5, 1985
    Assignee: The Unites States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Anne K. St. Clair, Terry L. St. Clair
  • Patent number: 4469829
    Abstract: Amino-group bearing, low molecular weight 1,3-butadiene polymers used as stabilizers for molded or unshaped plastics in amounts of 0.01 to 2.0 weight percent referred to the plastic, where the amino-group bearing component is derived from a substituted piperidine having the general formula: ##STR1## where R represents similar or different alkyl groups having 1 to 3 carbon atoms.
    Type: Grant
    Filed: August 18, 1983
    Date of Patent: September 4, 1984
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Konietzny, Hans-Dieter Zagefka, Konrad Rombusch, Hanns-Jorg Bax
  • Patent number: 4415706
    Abstract: This invention relates to compatible polymer blends of from about 1 to about 99 percent by weight of an imidized acrylic polymer, containing at least 5 percent by weight glutarimide units, and from about 99 to about 1 percent by weight of a polyamide or mixtures thereof. The compatible polymer blends of polyglutarimides and polyamides possess certain desirable characteristics of each of the polymer components. Compatible polymer blends of polyglutarimides and polyamides improve the melt flow, melt strength, tensile strength, and modulus of polyamides. Compatible polymer blends of polyamides and polyglutarimides possess improved impact resistance and ductility compared with neat polyglutarimides. The addition of a high service temperature polyglutarimide to a lower service temperature nylon results in improved service temperature for the nylon.
    Type: Grant
    Filed: November 10, 1982
    Date of Patent: November 15, 1983
    Assignee: Rohm and Haas Company
    Inventor: William H. Staas
  • Patent number: 4389504
    Abstract: A rubber-toughened addition-type polyimide composition having excellent high temperature bonding characteristics in the fully cured state and improved peel strength and adhesive fracture resistance physical property characteristics is disclosed. The process for making the improved adhesive involves preparing the rubber-containing amic acid prepolymer by chemically reacting an amine-terminated elastomer and an aromatic diamine with an aromatic dianhydride with which a reactive chain stopper anhydride has been mixed, and utilizing solvent or mixture of solvents for the reaction.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: June 21, 1983
    Assignee: The United States of America as represented by the United States National Aeronautics and Space Administration Office of General Counsel-Code GP
    Inventors: Anne K. St. Clair, Terry L. St. Clair
  • Patent number: 4381372
    Abstract: Polymers and oligomers of the formula ##STR1## are useful as ultraviolet light stabilizers for various polymers, especially polyolefins.
    Type: Grant
    Filed: April 8, 1981
    Date of Patent: April 26, 1983
    Assignee: American Cyanamid Company
    Inventor: Frank F. Loffelman
  • Patent number: 4370467
    Abstract: A curable resin composition comprising (i) a catalytic composite comprising a peroxide and other catalytic component and (ii) a mixture or a preliminary reaction product of (a) a polyfunctional cyanate ester, prepolymer of the cyanate ester or coprepolymer of the cyanate ester and an amine and (b) a polyfunctional maleimide, prepolymer of the maleimide or coprepolymer of the maleimide and an amine and optionally (c) other component is disclosed. The composition cures rapidly at a low temperature and is preferable from view point of quantity production and workability. The composition is excellent in respect of adhering property, heat-resistance, moisture-resistance and chemical-resistance, and is useful for preparing laminated products, molded products, paint, powder paint, adhesive or varnish.
    Type: Grant
    Filed: July 3, 1980
    Date of Patent: January 25, 1983
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Morio Gaku, Nobuyuki Ikeguchi
  • Patent number: 4348502
    Abstract: Thermoplastic compositions are described comprising blends of nylon and cured ethylene-vinyl acetate (EVA) rubber.
    Type: Grant
    Filed: January 23, 1981
    Date of Patent: September 7, 1982
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman Patel
  • Patent number: 4262098
    Abstract: A halogenated polyethylene, or a mixture of it with a sulfur-curable rubber and/or a vinyl chloride resin can be cured with a combination of sulfur and/or a sulfur donor, and at least one amino acid selected from the group consisting of lysine, ornithine, arginine and proline.
    Type: Grant
    Filed: July 10, 1978
    Date of Patent: April 14, 1981
    Assignee: Sanyo Trading Co., Ltd.
    Inventor: Masao Onizawa
  • Patent number: 4224206
    Abstract: An essentially linear polymer having a plurality of amide, imide and ester groups therein, which is the condensation product of (1) at least one polycarboxylic acid imide-forming reactant, (2) at least one ethylenically unsaturated polycarboxylic acid carboxypyrrolidone-forming reactant, (3) at least one polycarboxylic acid ester-forming reactant, (4) at least one glycoly, (5) at least one other polyfunctional hydroxyl compound, and (6) at least one polyfunctional amino compound having at least one primary amine group thereon. The equivalent molar ratio of the functional hydroxyl groups of the glycols and hydroxyl compounds to the functional ester-forming carboxyl groups of the acid reactants is from about 1.0 to 1 to about 3.0 to 1.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: September 23, 1980
    Assignee: Phelps Dodge Industries, Inc.
    Inventor: George H. Sollner
  • Patent number: 4185045
    Abstract: A powdery coating composition comprising (1) 10 to 40% by weight of a solid cross-linking agent having a softening point of 50.degree. to 120.degree. C. and prepared by heating 40 to 75% by weight of an acrylic resin having free hydroxyl groups and 60 to 25% by weight of an alkoxyaminotriazine at 50.degree. to 120.degree. C., and (2) 90 to 60% by weight of a base resin having a softening point of 60.degree. to 130.degree. C. and an acid value of up to 30 and containing 0.4 to 2.0 moles of free hydroxyl groups per kilogram of the resin, the alkoxyaminotriazine having 0 to 1 non-methylolated NH bond per triazine ring, at least 80% of the methylol groups of the alkoxyaminotriazine having been etherified with an aliphatic or alicyclic alcohol or ethylene glycol monoalkyl ether.
    Type: Grant
    Filed: February 24, 1978
    Date of Patent: January 22, 1980
    Assignee: Kansai Paint Company, Limited
    Inventors: Ichiro Yoshihara, Tadashi Watanabe, Osamu Iwase
  • Patent number: 4177178
    Abstract: Thermosetting acrylic copolymer compositions useful in coating applications are disclosed. The acrylic polymer has a weight average molecular weight of about 15,000 to 100,000 and contains from about 2 to 20 percent by weight of an alkyl ester of an unsaturated carboxylic acid containing from 14 to 20 carbon atoms in the alkyl group, for example, stearyl methacrylate. The compositions are particularly useful as water-based exterior coatings for automobiles and trucks.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: December 4, 1979
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Charles M. Kania
  • Patent number: 4171330
    Abstract: A fire-retardant resin composition comprising(A) an aromatic copolyester derived from(1) a mixture of terephthalic acid and isophthalic acid or the functional derivatives thereof and(2) a bisphenol or the functional derivatives thereof,(B) a polyamide,(C) a polyalkylene phenylene ester or a polyalkylene phenylene ester ether and(D) an aromatic halogen compound. The resin composition has superior moldability, and molded articles prepared from the resin composition have superior chemical properties, thermal stability, mechanical properties and fire retardancy. The resin composition may additionally contain (E) a fire-retardant assistant.
    Type: Grant
    Filed: January 20, 1978
    Date of Patent: October 16, 1979
    Assignee: Unitika Ltd.
    Inventors: Kayomon Kyo, Katsuhiro Hirose, Kenji Yasue, Sinichi Tokumitsu, Haruo Kohyama
  • Patent number: 4170612
    Abstract: Pressure sensitive adhesive compositions are prepared from a mixture of a specific pressure sensitive polymer, a chlorosulphonated polyethylene and a polymerizable vinyl compound. The compositions are cured to form a strong bond upon contact with a condensation reaction product of a primary or secondary amine and an aldehyde.
    Type: Grant
    Filed: April 13, 1978
    Date of Patent: October 9, 1979
    Assignee: National Starch and Chemical Corporation
    Inventors: Stephen D. Pastor, Martin M. Grover
  • Patent number: T102101
    Abstract: A hydrophilic polymer shaped article adapted for use as a soft contact lens is treated to provide at least on the surfaces thereof a modified, less hydrophilic polymeric structure inhibiting penetration by bacteria and proteins, whereby development of clouding and discoloration of the lens material during use is significantly retarded. Modification of the lens surfaces is effected by treatment of the lenses, either unhydrated or in a partially hydrated state, at a temperature ranging from room temperature to 100.degree. C. and for a time period of 1 to 24 hours, with a water-soluble mono- or poly-carboxylic acid selected from alpha-amino acids, such as arginine, cysteine, glycine and like acids, aliphatic dicarboxylic acids or aromatic dicarboxylic and tricarboxylic acids, such as malonic, maleic, glutaric, citraionic, itaconic acid and the like.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: August 3, 1982
    Inventors: Nancy J. Drake, Charles J. Hora