Solid Polymer Derived From Ethylenically Unsaturated Hydrocarbon Patents (Class 525/184)
  • Publication number: 20120136100
    Abstract: Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
    Type: Application
    Filed: February 8, 2012
    Publication date: May 31, 2012
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Yuichi Hara, Naoyuki Morooka
  • Patent number: 8133966
    Abstract: Oxymethylene copolymers having a high proportion of terminal alkyl ether groups and having terminal hydroxyalkylene groups are described. These polymers are distinguished by high thermal stability and high hot water resistance.
    Type: Grant
    Filed: April 14, 2009
    Date of Patent: March 13, 2012
    Assignee: Ticona GmbH
    Inventors: Michael Haubs, Michael Hoffmockel, Jürgen Lingnau, Robert Gronner, Michael Gene Yearwood
  • Publication number: 20120047634
    Abstract: Embodiments of the present disclosure include helmet liners, helmets, helmets with deflective structures, helmets with thermochromic features, and methods of making helmet liners, helmets, helmets with deflective structures, and helmets with thermochromic features.
    Type: Application
    Filed: May 14, 2010
    Publication date: March 1, 2012
    Inventor: Uday Vaidya
  • Patent number: 8114940
    Abstract: The present invention relates to a phenolic hydroxy group-containing rubber-modified polyamide resin which has, in the molecule, a phenolic hydroxy group-containing aromatic polyamide segment having a structure represented by the following formula (A) (wherein, m and n are average values and Ar represents a divalent aromatic group) and a butadiene (co)polymer segment selected from the following formula (B-1) or (B-2), —(CH2—CH?CH—CH2)X—??(B-1) —(CH2—CH?CH—CH2)Y—(CH2—CH(CN))Z—??(B-2) (wherein, each of x, y and z is an average value and 0.01?z/(y+z)?0.13, x represents a positive number of 5 to 200, and also y+z is a positive number of 10 to 200), and a resin composition containing said resin, in particular an epoxy resin composition; a cured product of said epoxy resin composition is excellent in flexibility, heat resistance and electrical properties especially at high temperature and high humidity.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: February 14, 2012
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Kazunori Ishikawa, Makoto Uchida, Shigeru Moteki
  • Publication number: 20110315199
    Abstract: One subject of the invention is the use of ? film as a protective backsheet in a photovoltaic module, said film comprising at least one layer of a composition containing a polyamide-grafted polymer, this polyamide-grafted polymer comprising a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, in which: • the polyamide graft is attached to the polyolefin backbone by the residue of the unsaturated monomer (X) that comprises a functional group capable of reacting via a condensation reaction with a polyamide having at least one amine end group and/or at least one carboxylic acid end group; • the residue of the unsaturated monomer (X) is attached to the backbone by grafting or copolymerization; said polyamide-grafted polymer comprising, relative to its total weight: • from 40 to 95% by weight of the polyolefin backbone comprising the unsaturated monomer (X); and • from 5 to 60% by weight of polyamide grafts, and the melting point or glass transition t
    Type: Application
    Filed: December 15, 2009
    Publication date: December 29, 2011
    Applicants: SOLUTIA SOLAR GMBH, ARKEMA FRANCE
    Inventors: Marc Vogt, Dominique Jousset, Stéphane Bizet, Jean-Jacques Flat
  • Publication number: 20110305863
    Abstract: Provided is a thermoplastic resin composition in which a modified rubber excellent in low temperature resistance is dispersedly added in a polyamide resin matrix to improve the low temperature resistance (cyclic fatigue resistance) of the polyamide resin, the composition maintaining its fluidity even at a high content of modified rubber, thus allowing film formation, and exhibiting excellent low temperature resistance. The thermoplastic resin composition includes a polyamide resin (A) and a modified rubber (B) having an acid anhydride group or an epoxy group and is characterized in that the modified rubber (B) having an acid anhydride group or an epoxy group is modified with a hydrogen bonding compound (C) having a functional group reacting with an acid anhydride group or an epoxy group and a functional group capable of hydrogen bonding with an amide bond or a hydroxyl group.
    Type: Application
    Filed: March 4, 2010
    Publication date: December 15, 2011
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventor: Naoyuki Morooka
  • Patent number: 8034876
    Abstract: There are provided an organic fiber-reinforced composite resin composition which is good in fiber dispersion, excellent in appearance, excellent in mechanical properties such as tensile elongation at break or impact strength and easy in thermal recycle; and a molded article obtained therefrom. An organic fiber-reinforced composite resin composition comprising (a) 60 to 95% by weight of a polyolefin resin (provided that an acid-modified polyolefin resin is excluded) and (b) 40 to 5% by weight (provided that (a)+(b)=100% by weight) of organic fiber to which a polar resin (provided that an acid-modified polyolefin resin is excluded) is attached, or an organic fiber-reinforced composite resin composition comprising organic fiber in an amount of 10 to 200 parts by weight based on 100 parts by weight of a polyolefin resin and having an Izod impact strength at ?40° C. of 10 kJ/m2 or more, and further, an organic fiber-reinforced composite resin molded article obtained therefrom.
    Type: Grant
    Filed: November 6, 2007
    Date of Patent: October 11, 2011
    Assignees: Mitsubishi Chemical Corporation, Teijin Fibers Limited
    Inventors: Masatoshi Oomori, Takayuki Itou, Takakazu Yoshihara, Taku Kitade
  • Patent number: 8021730
    Abstract: A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: September 20, 2011
    Assignees: ExxonMobil Chemical Patents Inc., The Yokohama Rubber Co., Ltd.
    Inventors: Andy Haishung Tsou, Yoshihiro Soeda, Yuichi Hara, Matthew Brian Measmer
  • Publication number: 20110220667
    Abstract: Disclosed is an impact-resistant modified polyamide moulding compound which is suitable in particular for the production of containers having a good oxygen barrier and low-temperature impact strength. Also disclosed are containers which are produced from the thermoplastic polyamide moulding compound. In particular, storage or transport containers for industrial chemicals, agrochemicals, the cosmetic industry, pharmaceutical industry or foodstuffs industry can be produced from the polyamide moulding compound of the invention.
    Type: Application
    Filed: March 11, 2011
    Publication date: September 15, 2011
    Applicant: EMS-PATENT AG
    Inventors: Mark Pfleghar, Gerhard Zaschke, Roland Treutlein, Ulrich Presenz
  • Publication number: 20110218281
    Abstract: Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
    Type: Application
    Filed: May 13, 2011
    Publication date: September 8, 2011
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Yuichi Hara, Naoyuki Morooka
  • Publication number: 20110213085
    Abstract: The invention pertains to the use of certain fluorinated thermoplastic polymer additives for reducing the coefficient of friction of non-fluorinated polymers and to masterbatches of said additives with non-fluorinated polymers.
    Type: Application
    Filed: October 23, 2009
    Publication date: September 1, 2011
    Applicant: SOLVAY SOLEXIS S.P.A.
    Inventors: Claudio Adolpho Pietro Tonelli, Grazia Meroni
  • Publication number: 20110195215
    Abstract: The invention relates to a copolyamide comprising at least two units corresponding to the following general formula: A/10,T in which: A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb (cyclo)aliphatic diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36; 10,T denotes a unit obtained from the polycondensation of 1,10-decanediamine and terephthalic acid, characterized in that it has a polydispersity index, denoted by Ip, of less than or equal to 3.5, measured by gel permeation chromatography. The invention also relates to the process for preparing said copolyamide, a composition comprising this polyamide and also the use of this polyamide and of such a composition.
    Type: Application
    Filed: August 6, 2009
    Publication date: August 11, 2011
    Applicant: ARKEMA FRANCE
    Inventors: Thierry Briffaud, Philippe Blondel, Thierry Lefebvre
  • Patent number: 7956134
    Abstract: A modified butyl rubber composition containing a modified butyl rubber obtained by a modification reaction of a compound (a) having a nitroxide-free radical, stable in the presence of oxygen at an ordinary temperature, in the molecule thereof and a radical initiator (b) and at least two kinds of bi- or more-functional radical polymerizable monomers (c).
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: June 7, 2011
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Makoto Ashiura, Tetsuji Kawazura
  • Patent number: 7954528
    Abstract: A thermoplastic elastomer composition having excellent durability and flexibility while possessing superior air impermeability. In particular, a process for producing a thermoplastic elastomer composition having high rubber content by multistage addition of at least one vulcanizable rubber component, in which the time required to substantially cure the at least one rubber component preferably is less the mixer residence time. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: June 7, 2011
    Assignees: ExxonMobil Chemical Patents Inc., The Yokohama Rubber Co., Ltd.
    Inventors: Andy Haishung Tsou, Yoshihiro Soeda, Yuichi Hara, Matthew Brian Measmer
  • Publication number: 20110123749
    Abstract: A polyamide moulding composition with the following constitution is described: (a) from 40 to 90% by weight of a copolyamide, where this is composed of (a1) 1,6-hexanediamine and 1,10-decanediamine and also (a2) terephthalic acid and at least one other polyamide-forming monomer selected from the group of: dicarboxylic acid having from 8 to 18 carbon atoms, laurolactam, aminolauric acid, and/or mixtures thereof; (b) from 10 to 40% by weight of macromolecular plasticizers, with the proviso that these can have been replaced to some extent by low-molecular-weight plasticizers; (c) from 0 to 20% by weight of additives and/or added substances. Uses of this type of moulding composition are also described, in particular for the production of a fuel line, cooling line, oil line or urea line for the automobile sector, as also are production processes to give mouldings.
    Type: Application
    Filed: November 19, 2010
    Publication date: May 26, 2011
    Applicant: EMS-PATENT AG
    Inventors: Manfred HEWEL, Botho HOFFMANN, Andreas BAYER
  • Patent number: 7947360
    Abstract: This invention relates to thermoplastic molding compositions with improved flowabilty based on a thermoplastic polyamide and on a copolymer composed of at least one olefin with at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the MFI of the copolymer being not less than 50 g/10 min, and to a process for preparation of these molding compositions, and also to the use of the these molding compositions, for production of moldings for the electrical, electronics, telecommunications, motor vehicle, or computer industry, in sports, in medicine, in the household or in the entertainment industry.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: May 24, 2011
    Assignee: LANXESS Deutschland GmbH
    Inventors: Detlev Joachimi, Peter Persigehl, Kurt Jeschke, Marcus Schäfer, Ralph Ulrich, Robert Hubertus Van Mullekom, Jochen Endtner, Jens Peter Joschek, Matthias Bienmüller
  • Publication number: 20110060086
    Abstract: A copolymer is formed from an isoolefin having from 4 to 7 carbon atoms and an alkylstyrene. The copolymer has a substantially homogeneous compositional distribution. The copolymer has from about 8 to about 12 wt % of alkylstyrene and at least 85 wt % of isoolefin. The copolymer is preferably halogenated with about 1.1 to about 1.5 wt % of a halogen. The copolymer may in elastomeric nanocomposites. To obtain a good dispersion of the nanoclay in a formulated compound, at least one cure accelerator is selected from the group consisting of mercaptobenzothiazole disulfide, mercaptobenzothiazole, cyclohexyl benzothiazole disulfide, dibutyl thiourea, tetramethylthiuram disulfide, 4-4-dithiodimropholine, zinc dimethyldithiocarbamate, and zinc dibutylphosphorodithiate.
    Type: Application
    Filed: August 23, 2010
    Publication date: March 10, 2011
    Inventors: Michael Brendan Rodgers, Weiqing Weng, John Patrick Soisson, Robert Norman Webb, Sunny Jacob
  • Patent number: 7887726
    Abstract: The invention is directed to a “Self-Reinforced Composite” (SRC) made of recycled thermoplastic polymers, methods and an apparatus for their manufacture. In one embodiment of the invention, the SRC is a self-reinforced composite comprising (a) a fiber comprising a first recycled thermoplastic polymer and having a Young's modulus at least about 500 MPa and (b) a matrix comprising a second recycled thermoplastic polymer. In one aspect of the invention, the source mixture is recycled immiscible thermoplastic polymers, obtained from the waste stream in the carpet and automotive industries. In another embodiment of the invention, the method for making the self-reinforced composites, comprising the steps of (a) melt-blending recycled immiscible polymers, (b) phase-migration fiber spinning the recycled immiscible polymers to form a fiber having a first recycled thermoplastic polymer substantially surrounded by a second recycled thermoplastic polymer, and (c) drawing the fiber to form a high modulus fiber.
    Type: Grant
    Filed: November 26, 2007
    Date of Patent: February 15, 2011
    Assignee: Novana, Inc.
    Inventor: Fu-Jya Daniel Tsai
  • Publication number: 20110033703
    Abstract: The present invention relates to a cutting member, especially to a cutting filament, for a plant-cutting device such as a scrub cutter or edge trimmer characterized in that at least one portion of the cutting member is a mixture of at least a polyamide and at least one another thermoplastic material. Another object of the invention relates to a composition for use in the manufacture of a cutting member by extrusion/drawing or by injection, characterized it is made from a mixture of at least a polyamide and at least one another thermoplastic material.
    Type: Application
    Filed: April 21, 2008
    Publication date: February 10, 2011
    Inventor: Emmanuel Legrand
  • Publication number: 20110023986
    Abstract: Polyamide blend molding compound, includes a polyamide blend content and at least one impact-resistant component, characterized in that the polyamide blend content includes the following polyamides: (A) 20 to 65% by weight of at least one semi-crystalline polyamide with an enthalpy of fusion >40 J/g and with an average of at least 8 C atoms per monomeric unit; (B) 8 to 25% by weight of at least one amorphous and/or microcrystalline polyamide, with the microcrystalline polyamide having an enthalpy of fusion in the range of 4 to 40 J/g, and (C) 1 to 20% by weight of at least one polyamide with an average of a maximum of 6 C atoms per monomeric unit. The impact-resistant component includes as follows: (D) 10 to 40% by weight of a polyamide elastomer which is composed of hard segments and soft segments, with the hard segments being based on lactams and/or amino-carboxylic acids, and (E) 0 to 35% by weight of a non-polyamide elastomer.
    Type: Application
    Filed: July 29, 2010
    Publication date: February 3, 2011
    Applicant: EMS-PATENT AG
    Inventors: Botho HOFFMANN, Ralph KETTL
  • Patent number: 7879272
    Abstract: An oriented thermoplastic elastomer film having reduced permeability and improved fatigue resistance comprising a dynamically vulcanized polymer blend of (A) a halogenated isobutylene elastomer and (B) polyamide, the film is produced by casting or blowing the above polymer blend under the condition such that a shear rate at a die lip for casting or blowing is regulated to control the molecular arrangement in the film, whereby the planar birefringence (PBR) of the resultant film becomes greater or equal to 0.002 and a production process of the same.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: February 1, 2011
    Assignees: ExxonMobil Chemicals Patents, Inc., The Yokohama Rubber Co., Ltd.
    Inventors: Yoshihiro Soeda, Andy Haishung Tsou, Foshee Joyce Caraway
  • Publication number: 20110015328
    Abstract: The present invention relates to a high temperature polyamide resin composition for moulded articles, articles formed therefrom and processes for producing the composition, comprising: semi-aromatic polyamide with a melt temperature above 280° C. and one or more oxidized polyethylene lubricants as internal lubricant.
    Type: Application
    Filed: July 16, 2010
    Publication date: January 20, 2011
    Applicant: E.I.DU PONT DE NEMOURS AND COMPANY
    Inventor: Yuji Orihashi
  • Patent number: 7833450
    Abstract: The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection moulding and sheet extrusion/calendering.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: November 16, 2010
    Assignee: Arkema France
    Inventors: Thibaut Montanari, Christelle Recoquille
  • Publication number: 20100234500
    Abstract: An object of the invention is to provide a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide resin, even if a halogenated isoolefin/para-alkylstyrene copolymer rubber is finely dispersed and loaded to a high content. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.
    Type: Application
    Filed: March 11, 2010
    Publication date: September 16, 2010
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Yuichi Hara, Naoyuki Morooka
  • Publication number: 20100207071
    Abstract: The present disclosure relates to thermoplastic polymer articles, and methods of making and/or selectively controlling surface properties of the same. The article includes a bulk thermoplastic polymer, and a cap layer formed in-situ thereon. A resin formulation used to form the articles includes the bulk polymer in an amount ranging from about 80 wt. % to about 99.5 wt. %, and a polymer additive (which forms the cap layer) in an amount ranging from about 0.5 wt. % to about 20 wt. %. The bulk polymer viscosity ranges from about 5 to about 1000 times higher than the polymer additive viscosity, and the polymer additive is immiscible in the bulk polymer. A predetermined surface property of the polymer additive, which is not inherent in the bulk polymer, is imparted to the cap layer, and thus to the article.
    Type: Application
    Filed: February 13, 2009
    Publication date: August 19, 2010
    Applicant: GM GLOBAL TECHNOLOGY OPERATONS, INC.
    Inventors: Bhaskar Patham, Soumendra K. Basu
  • Publication number: 20100203346
    Abstract: The invention relates to extruded transparent or translucent article that have been melt calendered to improve the physical properties and optical clarity. The polyamide article is a sheet, film, or profile.
    Type: Application
    Filed: June 26, 2008
    Publication date: August 12, 2010
    Applicant: Arkema Inc.
    Inventors: Elizabeth E. Grimes, William Todd Rogers, Claire Michalowicz
  • Patent number: 7750078
    Abstract: Disclosed herein is the preparation of reaction products which contain carboxylic acid-grafted functionalized propylene homopolymers and copolymers that can be used as additives for polyolefin-based plastic products such as hot melt adhesives. Such reaction product additives may be prepared by: a) providing a first reactant comprising a selected type of relatively low molecular weight, low melt viscosity, molten propylene-based homopolymer or copolymer; b) forming a reaction mixture by adding to this first reactant a second reactant comprising an unsaturated carboxylic acid-based functionalizing agent, and an initiator comprising a certain type of organic peroxide; and c) maintaining the resulting reaction mixture at a relatively low temperature between about 130° C. and about 165° C. for a period of time and under conditions sufficient to form a reaction product which comprises acid-grafted propylene-based polymeric material, and which has a relatively high Grafting Efficiency.
    Type: Grant
    Filed: December 7, 2005
    Date of Patent: July 6, 2010
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventor: Christopher Lewis Curry
  • Patent number: 7741407
    Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: June 22, 2010
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
  • Publication number: 20100130677
    Abstract: Polyamide-based thermoplastic polymer compositions that exhibit a good balance among the properties thereof, in particular their mechanical properties, and a high fluidity in the molten state; such compositions contain at least one high-fluidity polyamide and a shock modification agent having functional groups that react with the polyamide.
    Type: Application
    Filed: February 21, 2008
    Publication date: May 27, 2010
    Inventors: Marco Amici, Cesare Guaita
  • Publication number: 20100130688
    Abstract: A rubber composition having an excellent adhesion with a brass-plated wire and an excellent heat aging resistance of a vulcanite containing (A) 100 parts by weight of a diene-based rubber, (B) 0.1 to 10 parts by weight of, as a vulcanization accelerator, an amine salt compound of a carboxylic acid group-containing disulfide having the formula (I): and (C) 0.1 to 10 parts by weight of, as a vulcanization agent, a cyclic sulfide compound having the formula (V): wherein R is a substituted or unsubstituted C2-C20 alkylene group, a substituted or unsubstituted C2-C20 oxyalkylene group or an aromatic ring-containing alkylene group, x is an integer of 2-6 on average and n is an integer of 1-30.
    Type: Application
    Filed: August 8, 2007
    Publication date: May 27, 2010
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Yongcheng Jin, Wonmun Chio
  • Publication number: 20100113661
    Abstract: The invention relates to a method for preparing a powdered polymer selected from a polyamide, a copolyamide or a copolyesteramide by anionic polymerization in a solvent solution, characterized in that the polymerization of the monomers) generating said polymer is made in the presence of a catalyst, an activator, at least one amide one of which is always a N,N?-alkylene bisamide, and an organic or inorganic filler, the amount of N,N?-alkylene bisamide added in the medium being determined based on the specific surface are desired for the powder particles, said powder particles having an essentially constant diameter or one depending on the desired mean diameter of the powder particles, said powder particles having an essentially constant specific surface area.
    Type: Application
    Filed: December 20, 2007
    Publication date: May 6, 2010
    Applicant: ARKEMA FRANCE
    Inventors: Holger Senff, Christelle Gaboriau
  • Patent number: 7709575
    Abstract: A method for controlling a dispersion size of an elastomer in a thermoplastic elastomer composition having improved durability and impermeability obtained by melt-mixing (A) a halogenated isobutylene elastomer, (B) polyamide and (C) a dispersion aid, and dynamically vulcanizing the resultant blend to form the dynamically vulcanized polymer blend, wherein the halogenated isobutylene elastomer is dispersed in the polyamide matrix at a volume-average dispersion diameter of less than 2.0 ?m.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: May 4, 2010
    Assignees: The Yokohama Rubber Co., Ltd., ExxonMobil Chemical Patents Inc.
    Inventors: Andy Haishung Tsou, Yoshihiro Soeda, Yuichi Hara
  • Publication number: 20100098948
    Abstract: A composite yarn comprising an ultra-high-molecular-weight-polyethylene filament and an additional synthetic resin filament, at least a part of which comprises a light storage agent. The composite yarn has both visibility in a dark place and properties necessary for a fishing line or other yarns made of an ultra high molecular weight polyethylene filament.
    Type: Application
    Filed: January 22, 2008
    Publication date: April 22, 2010
    Applicant: Y. G. K CO., LTD.
    Inventor: Shigeru Nakanishi
  • Patent number: 7700695
    Abstract: A modified butyl rubber composition comprising a butyl rubber modified by mixing, under heating, (a) a compound having a nitroxide-free radical in the molecule thereof, which is stable at an ordinary temperature even in the presence of oxygen, (b) a radical initiator, and (c) a bi- or more-functional radical polymerizable monomer and further by compounded with (d) a bi- or more-functional radical polymerizable monomer, which is different from the ingredient (c).
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: April 20, 2010
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Makoto Ashiura, Tetsuji Kawazura
  • Publication number: 20100087585
    Abstract: The present invention relates to a composite obtained from a composition comprising: 50 (excluded) to 90% by weight of at least one polyamide; 10 to 50% by weight of polylactic acid (PLA); and 0 to 30% by weight of at least one compatibilizing agent. The present invention also relates to a process for manufacturing this composite and its use.
    Type: Application
    Filed: January 29, 2008
    Publication date: April 8, 2010
    Applicant: ARKEMA FRANCE
    Inventors: Maho Yasuda, Nicolas Amouroux, Benoit Brule, Nadine Decraemer, Jean-Jacques Flat
  • Patent number: 7691947
    Abstract: A controlled molecular weight polymer of styrene is provided having bromine substituted thereon. Control of molecular weight is achieved by the use of alpha-methyl styrene dimer as a chain transfer agent. The brominated polymer of styrene is useful as a flame retardant, particularly for polyamides giving improved properties including color retention after molding.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: April 6, 2010
    Assignee: Chemtura Corporation
    Inventors: Wayne Meyer, Jennifer L. Bohan, Larry D. Timberlake, James D. Siebecker
  • Patent number: 7683134
    Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 6, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: March 23, 2010
    Assignee: Eastman Chemical Company
    Inventors: Thomas David Roberts, Stephen Wayne Coe
  • Publication number: 20100056714
    Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.
    Type: Application
    Filed: September 1, 2009
    Publication date: March 4, 2010
    Applicant: Amyris Biotechnologies, Inc.
    Inventor: Derek James MCPHEE
  • Patent number: 7625972
    Abstract: The present invention relates to a flexible semiaromatic polyamide composition with a low moisture uptake, made up by weight, the total being 100: A) 60 to 99.5% (preferably 70 to 93%) of at least one copolyamide of formula X/Y,Ar in which there are between 0.5 and 0.7 mol of X per 1 mol of Y, and in which Y denotes the residues of 1,10-decanediamine, Ar denotes the residues of terephthalic acid, X denotes the residue of aminoundecanoic acid NH2—(CH2)10—COOH, the unit Y,I residue from the condensation of the diamine (Y) with isophthalic acid, wherein said composition is a flexible semiaromatic copolyamide; B) 0.5 to 40% (preferably 7 to 30%) of at least one product chosen from plasticizers, nanofillers, polyolefins, crosslinked polyolefins and additives.
    Type: Grant
    Filed: June 9, 2008
    Date of Patent: December 1, 2009
    Assignee: Arkema France
    Inventors: Philippe Blondel, Thierry Briffaud, Annett Linemann, Helene Egret, Pierre Nogues
  • Patent number: 7582342
    Abstract: A composition suitable for molding is provided having the following components: I. from 97 to 80 parts by weight of a polyetheramide, having units based on one or more linear aliphatic diamines having from 6 to 14 carbon atoms, one or more linear aliphatic or aromatic dicarboxylic acids having from 6 to 14 carbon atoms, and one or more polyetherdiamines having at least 3 carbon atoms per ether oxygen and having primary amino groups at the chain ends, II. from 3 to 20 parts by weight of a rubber containing one or more functional groups; and where the total of the parts by weight of I and II is 100; and moldings produced therefrom.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: September 1, 2009
    Assignee: Degussa AG
    Inventors: Franz-Erich Baumann, Wilfried Bartz, Martin Himmelmann, Olivier Farges
  • Patent number: 7538158
    Abstract: A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: May 26, 2009
    Assignees: ExxonMobil Chemical Patents Inc., The Yokohama Rubber Co., Ltd.
    Inventors: Andy Haishung Tsou, Yoshihiro Soeda, Hsien-Chang Wang, Matthew Brian Measmer
  • Patent number: 7528196
    Abstract: A golf ball that includes (a) a core comprising a center; (b) an outer cover layer; and (c) one or more intermediate layers; wherein at least one of the core, the outer cover layer, or the intermediate layer comprises a composition that includes (i) at least one polyalkenamer and at least one polyamide or (ii) at least one polyalkenamer. A method for making a golf ball comprising a core, one or more intermediate layers and an outer cover layer is also disclosed, wherein the method includes forming a blend comprising at least one polyalkenamer rubber and at least one polyamide; and injection molding the blend into a spherical mold to form the intermediate or outer cover layer. Also disclosed is a polymer composition that includes at least one polyalkenamer and at least one thermoplastic copolyamide elastomer.
    Type: Grant
    Filed: January 18, 2006
    Date of Patent: May 5, 2009
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 7507474
    Abstract: The invention relates to thermoplastic compositions comprising a polymer matrix and an additive which modifies the rheological behavior of the matrix in the molten state. The purpose of the invention is to provide a preferably non-reactive additive which can be dispersed in the matrix and which can be used to obtain a good compromise in terms of rheological properties/mechanical properties. According to the invention, the additive is a hyperbranched polymer which is functionalized by R<2> radicals, R<2> being a radical of the following type: substituted or non-substituted hydrocarbon, of the silicon type, linear or branched alkyl, aromatic, arylalkyl, alkylaryl or cycloaliphatic, which can comprise one or more unsaturations and/or one or more heteroatoms.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: March 24, 2009
    Assignee: Rhodianyl
    Inventors: Joël Varlet, Florence Clement, Franck Touraud, Sandrine Rochat, Natalia Scherbakoff
  • Publication number: 20080214736
    Abstract: Polymer compositions comprising a) a polymer substrate selected from the group consisting of the polyolefins, polyesters, polyamides and polylactic acids and b) a combination of i) at least one permanent antistatic additive selected from the group consisting of the polyetheresteramides and ii) at least one migratory antistatic additive selected from the group consisting of the alkylsulfonic acid salts, the alkyl diethanolamines and the alkyl diethanolamides, are effectively antistatic.
    Type: Application
    Filed: February 26, 2008
    Publication date: September 4, 2008
    Inventors: Hui Chin, Christopher J. Fagouri
  • Patent number: 7408007
    Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: August 5, 2008
    Assignee: Eastman Chemical Company
    Inventors: Thomas David Roberts, Stephen Wayne Coe
  • Patent number: 7408010
    Abstract: The present invention relates to primer compositions in non-flowable form. More particularly, the present invention relates to non-flowable primer compositions which are particularly useful for use with curable adhesive and sealant compositions in threadlocking, retaining, bonding and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: August 5, 2008
    Assignee: Henkel Corporation
    Inventors: Prakash S. Patel, Shabbir Attarwala, Matthew P. Burdzy, Qinyan Zhu
  • Patent number: 7402628
    Abstract: The invention relates to thermoplastic compositions in which (A) an isotactic polypropylene, optionally containing comonomer, with a melting point of at least 110° C. and (B) a polyamide, (A) and (B) constituting at least 70 wt %, are blended with (C) at least 2 wt % of a grafted functionalized propylene-based elastomer having isotactic crystallinity and containing at least 0.25 wt % of MAH-derived units based on the total weight of (C). Optionally (D) an ungrafted polyolefin may be added with a melting point of less than 100° C., (C) and (D) combined being at least 8 wt % and the wt % of (A), (B), (C) and (D) being calculated on the basis of the total polymer weight of the thermoplastic composition.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: July 22, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch Schauder, Guy Joseph Wouters, Sudhin Datta
  • Patent number: 7393895
    Abstract: A method of forming a poly(arylene ether)-containing solid concentrate is described. The method includes blending a poly(arylene ether), a thermosetting resin, and a compatibilizing agent in the presence of a solvent to form a homogeneous solution, and removing the solvent to yield the solid concentrate. The solid concentrate is useful for preparing curable conditions.
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: July 1, 2008
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael John Davis, James Estel Tracy
  • Patent number: 7332547
    Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: February 19, 2008
    Assignee: Henkel Corporation
    Inventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
  • Patent number: 7323515
    Abstract: The invention relates to a sealing composition which comprises a crosslinkable fluoroelastomer, a crosslinking agent for this elastomer and a reinforcing polyimide resin powder; and seals such as O-rings, made by molding the composition into a prescribed shape and crosslinking the molded article. According to the invention, seals free from metals and sulfur can be made from a fluoroelastomer suitable for the production unit for semiconductor devices without a scatter of physical properties within one seal or among seals, and the obtained seals are lowered in the compression set determined ate the same hardness level to cause little permanent set by compression in use, thus having a prolonged service life.
    Type: Grant
    Filed: November 29, 2002
    Date of Patent: January 29, 2008
    Assignees: Jtekt Corporation, Koyo Sealing Techno Co., Ltd.
    Inventors: Kazunori Hayashida, Takehisa Kida, Kazutoshi Yamamoto, Tomotaka Nakagawa, Takahiro Yamagishi, Masanobu Kato