Agent Contains A Metal Atom Patents (Class 525/196)
  • Patent number: 11834570
    Abstract: A molded article formed from a blend, the blend comprising: from 1 wt. % to 30 wt. % of a polypropylene; and from 60 wt. % to 99 wt. % of an ionomer formed from a partially neutralized precursor acid copolymer, wherein the precursor acid copolymer (a) comprises copolymerized units of ethylene and 5 wt. % to 30 wt. %, based on the total weight of the precursor acid copolymer, of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms, and (b) has a melt index, I2, (according to ASTM D1238 at 190 C, 2.16 kg) of 10 g/10 min to 4,000 g/10 min, and wherein about 25% to about 65% of the acid groups derived from the ?,?-ethylenically unsaturated carboxylic acid of the precursor acid copolymer are neutralized.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: December 5, 2023
    Assignee: Dow Global Technologies LLC
    Inventor: Xian Jiang
  • Patent number: 11661503
    Abstract: The present invention relates to a cross-linkable polyolefin composition comprising a first olefin polymer (A) comprising a first comonomer comprising epoxy groups, and a second olefin polymer (B) comprising a second comonomer comprising carboxylic acid groups and/or precursor thereof.
    Type: Grant
    Filed: May 23, 2019
    Date of Patent: May 30, 2023
    Assignee: BOREALIS AG
    Inventors: Oscar Prieto, Denis Yalalov, Massimiliano Mauri, Christian Müller, Anna Peterson
  • Patent number: 11504673
    Abstract: Disclosed herein are multi-layer structures comprising a first composite layer disposed over a second composite layer, wherein the first composite layer contains a first active material dispersed in a first polymer containing an elastomeric polymer and the second composite layer contains a second polymer which may have a second active material dispersed therein, wherein the first active material chemically or physically interacts with at least one toxic chemical and is selected from the group consisting of metal-organic frameworks (MOFs), metal oxides, metal hydroxides, zeolites, and combinations thereof, and wherein the active material and the second active material (if present) are the same as or different from each other, and the first polymer and second polymer are the same as or different from each other, subject to the proviso that the first composite layer and the second composite layer compositionally differ from each other in at least one respect.
    Type: Grant
    Filed: August 15, 2018
    Date of Patent: November 22, 2022
    Assignees: GOVERNMENT OF THE UNITED STATES, AS REPRESENTED BY THE DEFENSE THREAT REDUCTION AGENCY, GOVERNMENT OF THE UNITED STATES, AS REPRESENTED BY THE SECRETARY OF THE ARMY, UNIVERSITY OF DELAWARE
    Inventors: Gregory W. Peterson, Annie Lu, Thomas H. Epps, III, Jean S. Epps
  • Patent number: 10427006
    Abstract: Golf ball comprising layer(s) comprised of plasticized neutralized acid polymer composition consisting of mixture of: (a) low molecular weight acid-containing wax(es); (b) non-acid-polymer(s) including at least one low molecular weight non-acid wax such as high density oxidized polyethylene homopolymers; ethylene maleic anhydride copolymers; polypropylene maleic anhydride copolymers; polypropylene homopolymers; ethylene-vinyl acetate copolymers; high density oxidized homopolymers; oxidized copolymers; polyethylene micronized waxes; polytetrafluoroethylene micronized waxes; emulsifiable low molecular weight non-acid waxes; non-emulsifiable low molecular weight non-acid waxes; and/or chemically modified low molecular weight non-acid waxes; (c) organic acid(s) or salt thereof; and (d) plasticizer(s). Molecular weight of each low molecular weight acid-containing wax is about 500 to 7000, or up to 30,000.
    Type: Grant
    Filed: September 24, 2018
    Date of Patent: October 1, 2019
    Assignee: Acushnet Company
    Inventors: Robert Blink, David A. Bulpett, Michael J. Sullivan, Brian Comeau, Mark L. Binette
  • Patent number: 10105576
    Abstract: A golf ball comprising at least one layer comprised of a neutralized acid polymer composition consisting of a mixture of: (a) at least one low molecular weight acid-containing wax; (b) at least one non-acid-polymer; (c) at least one organic acid or salt thereof; and (d) at least one plasticizer. Each low molecular weight acid-containing wax may have a molecular weight of from about 500 to about 7000, and in some embodiments, the molecular weight may be considered low up to 30,000. Interactions between components (a), (b), (c) and (d) as disclosed herein advantageously produce a layer of ionomeric material having desirable physical properties, such as heat stability, and processability (excellent melt flow) and softer feel without the need for blending high and low molecular weight acid-containing polymer(s).
    Type: Grant
    Filed: February 14, 2017
    Date of Patent: October 23, 2018
    Assignee: Acushnet Company
    Inventors: David A. Bulpett, Robert Blink, Brian Comeau, Mark L. Binette, Michael J. Sullivan
  • Patent number: 10012860
    Abstract: A polarizer includes a polarizer base and a plurality of protrusive microstructures being arranged on the polarizer base. The microstructure includes at least two layers of curing-light or thermosetting resin materials. The manufacturing method of the curing-light or thermosetting resin materials includes: providing a polarizer base and coating at least two layers of curing-light or thermosetting resin materials on the polarizer base; and arranging a plurality of lighting dots or heating dots on the curing-light or thermosetting resin materials such that the curing-light or thermosetting resin materials shrink and the lighting dots or heating dots are centers of the shrinkage to form a plurality of protrusive microstructures. In addition, a liquid crystal panel includes the above-mentioned polarizer.
    Type: Grant
    Filed: May 21, 2015
    Date of Patent: July 3, 2018
    Assignee: Shenzhen China Star Optoelectronics Technology Co., Ltd
    Inventors: Dandan Liu, Dejiun Li
  • Patent number: 9446289
    Abstract: A thermoplastic multi-layer golf ball has a core center having a shell from about 1-6 mm thick defining an interior space about 12-24 mm in diameter, a core layer at least about 5 mm thick outward from the core center, and a cover. The shell includes a first thermoplastic material with first flexural modulus less than about 15,000 psi. The core layer includes a second thermoplastic material with second flexural modulus up to about 15,000 psi and greater than the first flexural modulus and a specific gravity of at least about 1.5 g/cm3. The cover includes a third thermoplastic material with a third flexural modulus that in a first embodiment is up to about 5,000 psi and less than the first flexural modulus and in a second embodiment is least about 40,000 psi.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: September 20, 2016
    Assignee: NIKE, Inc.
    Inventors: Chen-Tai Liu, Chien-Hsin Chou
  • Patent number: 9242148
    Abstract: A thermoplastic multi-layer golf ball has a core center having a diameter from about 21 mm to about 29 mm and including a first thermoplastic material having a first flexural modulus of less than about 15,000 psi, a core layer disposed radially outward from the core center with a thickness of at least about 4 mm and a second thermoplastic material having a second flexural modulus of up to about 15,000 psi that is greater than the first flexural modulus, and a cover disposed radially outward from the core layer. The cover comprises a third thermoplastic material having a third flexural modulus. The first thermoplastic material and the second thermoplastic material each includes an ionomer resin, and these ionomer resins may be the same as or different from each other.
    Type: Grant
    Filed: October 21, 2013
    Date of Patent: January 26, 2016
    Assignee: NIKE, Inc.
    Inventors: Chen-Tai Liu, Chien-Hsin Chou
  • Patent number: 9174090
    Abstract: An object of the present invention is to provide a golf ball cover resin composition containing an ionomer resin with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball using an ionomer resin for a cover, with an excellent shot feeling, durability and resilience.
    Type: Grant
    Filed: June 6, 2011
    Date of Patent: November 3, 2015
    Assignee: DUNLOP SPORTS CO. LTD.
    Inventor: Takahiro Shigemitsu
  • Patent number: 9132319
    Abstract: Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. Thermoplastic ethylene acid copolymer ionomer compositions are used to form the core layers. Preferably, the ball contains a dual-core having an inner core and surrounding outer core layer. Low modulus and high modulus ionomer compositions may be used in the core structure. The ionomer compositions have varying levels of hardness. The resulting ball has high resiliency and rebounding properties.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: September 15, 2015
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Mark L. Binette
  • Patent number: 9120920
    Abstract: Provided is a polymer composition including (A) an ionomer containing an ethylene/?,?-unsaturated carboxylic acid copolymer and an ethylene/?,?-unsaturated carboxylic acid/?,?-unsaturated carboxylic acid ester terpolymer, and (B) a propylene-based polymer, wherein the mass of constituent units derived from the ?,?-unsaturated carboxylic acid ester is from 1 to 4.5% by mass of the entire mass of the ionomer. Through this, a high seal strength may be obtained in a high-temperature range when forming a lock seal, while a high seal strength, as compared with the related art, can be stably obtained over a wide temperature range with a temperature dependence suppressed when forming a peelable seal.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: September 1, 2015
    Assignee: Du Pont-Mitsui Polychemicals Co., Ltd.
    Inventors: Shigenori Nakano, Kaoru Suzuki, Toshihisa Toyoda
  • Patent number: 9108083
    Abstract: A golf ball having an inner core layer, an outer core layer enclosing the inner core layer, and a cover layer enclosing the outer core layer. The inner core layer includes a blend of a first highly neutralized acid polymer having a first Vicat softening temperature and a first specific gravity, a second highly neutralized acid polymer having a second Vicat softening temperature and a second specific gravity, and an ionomer-based masterbatch comprising an additive and an ionomer resin having a third Vicat softening temperature and a third specific gravity. The absolute values of the differences among the Vicat softening temperatures is no more than about 15° C. and the absolute value of the difference between the specific gravities is no more than about 0.015. The cover layer may include an inner cover layer enclosing the outer core layer and an outer layer enclosing the inner cover layer.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: August 18, 2015
    Assignee: NIKE, Inc.
    Inventors: Hideyuki Ishii, Yasushi Ichikawa, Chien-Hsin Chou, Chen-Tai Liu, Arthur Molinari
  • Patent number: 9108082
    Abstract: This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer. The outer cover layer and/or one or more intermediate layers includes a blend of a) 2 to 60 wt % (based on the total weight of the blend composition) of a cyclic olefin polymer which includes a norbornene-based monomer having the general formula; where R18 to R21 independently represent a hydrogen atom, a halogen atom or a hydrocarbon group and m is from 0 to about 3; and b) about 40 to about 98 wt % (based on the total weight of the blend composition) of one or more additional polymer components. The blend composition has a melt flow index (MFI) from 1 to 80 g/10 min., a material hardness of 30 to 90 Shore D, and a flex modulus of 10 to 120 kpsi.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: August 18, 2015
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 9006351
    Abstract: The invention is to provide a polycarbonate resin composition and a molded polycarbonate resin article which combine excellent transparency and strength and which are suitable for use in the field of building materials, electrical/electronic field, automotive field, field of optical parts, etc. The invention relates to a polycarbonate resin composition containing a polycarbonate resin and an impact strength modifier, the polycarbonate resin containing structural units which are derived from a dihydroxy compound that has the portion represented by the following general formula (1) as part of the structure thereof and having a glass transition temperature lower than 145° C. and a molded polycarbonate resin article obtained by molding the composition. The polycarbonate resin composition gives a molded object having a thickness of 3 mm which has a total light transmittance of 60% or higher.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: April 14, 2015
    Assignees: Mitsubishi Chemical Corporation, Mitsubishi Plastics, Inc.
    Inventors: Masashi Yokogi, Kazuya Tanaka, Haruo Sasaki, Akira Kosuge
  • Patent number: 8895667
    Abstract: Methods are provided for making reversible crosslinked polymers. Exemplary methods comprise reacting first and second thermoplastic polymers having non-hindered olefins in the presence of a metathesis catalyst under conditions sufficient to form a crosslinked polymer. In certain embodiments, the methods comprise providing a crosslink promoting additive to improve the strength of the crosslinked polymer. In some embodiments, the methods comprise decrosslinking a crosslinked polymer through a metathesis or an ozonolysis reaction.
    Type: Grant
    Filed: July 17, 2009
    Date of Patent: November 25, 2014
    Assignee: Tyco Electronics Corporation
    Inventors: Mark W. Ellsworth, Stefanie M. Gravano-Doerffler
  • Patent number: 8816009
    Abstract: The present invention is directed to a method of making a functionalized elastomer, comprising the steps of polymerizing at least one diene monomer and optionally a vinyl aromatic monomer in the presence of an initiator of formula (II) to produce a protected hydroxyl end-terminated polymer where R1, R2, R3 can all be the same or different and are selected from the group consisting of alkyls having from 1 to 8 carbon atoms, cycloalkyls having from 3 to 11 carbon atoms, or aryls having from 6 to 14 carbon atoms, R4 is an alkylene having from 1 to 8 carbon atoms, a cycloalkylene having from 3 to 11 carbon atoms, or an arylene having from 6 to 14 carbon atoms, X is S, O or NH, and Li is lithium; de-protecting the protected hydroxyl end-terminated elastomer to produce a hydroxyl end-functionalized polymer; reacting the hydroxyl end-funtionalized polymer with a maleimido acid chloride to produce a maleimido end-functionalized polymer; and reacting the maleimido end-functionalized polymer with a thiol-terminated
    Type: Grant
    Filed: May 15, 2013
    Date of Patent: August 26, 2014
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Arindam Mazumdar, Frank James Feher
  • Publication number: 20140179857
    Abstract: The organic-inorganic complex of the present invention is made using an organic-inorganic complex-forming composition containing the following components a) to c): a) at least one organic silicon compound represented by the formula (I) RnSiX4-n and in which a molar ratio of an organic silicon compound in which a solubility parameter of R (SP1) obtained by a Fedors' estimation method is smaller than a solubility parameter of an electromagnetic ray-curable compound (SP2) obtained by the Fedors' estimation method and a difference between the SP1 and the SP2 is 2.0 or more (Si1) to an organic silicon compound in which SP1 is smaller than SP2 and a difference between the SP1 and the SP2 is less than 2.0 or an organic silicon compound in which SP1 is larger than SP2 (Si2) (Si1:Si2) is within the range of 8:2 to 10:0, and/or a condensate of the organic silicon compound; b) an electromagnetic ray-curable compound; and c) metal compound particles.
    Type: Application
    Filed: August 8, 2012
    Publication date: June 26, 2014
    Applicant: NIPPON SODA CO., LTD.
    Inventor: Taiki Yamate
  • Patent number: 8759447
    Abstract: A compatibilizer contains a polymer (A) obtained by reacting a modified olefin-based polymer (a-1) with a polymer (a-2) containing a terminal functional group, wherein the modified olefin-based polymer (a-1) is a polymer modified with from 0.01 to 2 mass % of unsaturated carboxylic acid or a derivative thereof, and the polymer (a-2) is a ring opening polymer or condensation polymer containing a terminal functional group, capable of reacting with the modified olefin-based polymer (a-1), at both ends or one end thereof and has a number average molecular weight from 1,500 to 100,000. This provides an excellent compatibilizer. Particularly, upon melt processing a recovery of a multilayer structure including an EVOH layer and a thermoplastic resin layer, a recycling agent is provided that gives sufficient improvement effects to any of the adhesion of a degraded resin to a screw of a molding machine, the generation of die build-up, the generation of fish eyes, and the decrease in transparency.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: June 24, 2014
    Assignee: Kuraray Co., Ltd.
    Inventors: Takeyuki Igarashi, Shinji Tai, Tomoyuki Watanabe
  • Patent number: 8759449
    Abstract: The invention relates to a wiper rubber for windshield wipers, which contains at least one rubber component that is cured by vulcanization, the material of the wiper rubber containing, at least in the unvulcanized state, a combination of a cross-linking agent with sulfur and/or with a sulfur donor.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: June 24, 2014
    Assignee: Robert Bosch GmbH
    Inventors: Eric Pieters, Reiner Lay, Harald Kleinknecht, Hilde Parton
  • Patent number: 8674025
    Abstract: An object of the present invention is to provide a golf ball resin composition with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball resin composition with a high hardness and durability. Yet another object of the present invention is to provide a golf ball traveling a great distance with an ionomer cover. The present invention provides a golf ball resin composition comprising, (A) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms; (B) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, and (C) a zinc compound, wherein a content ratio ((A)/(B)) of (A) component to (B) component ranges from 50/50 to 80/20 in a mass ratio and a content of (C) component ranges from 0.
    Type: Grant
    Filed: April 11, 2011
    Date of Patent: March 18, 2014
    Assignee: SRI Sports Limited
    Inventor: Takahiro Shigemitsu
  • Patent number: 8669313
    Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-methacrylic acid copolymer and/or an olefin-methacrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.0 to 7.0, or a metal neutralization product thereof, (b) an olefin-acrylic acid copolymer and/or an olefin-acrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 150,000 to 220,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 5.5 to 8.5, or a metal neutralization product thereof, (c) an organic acid or a metal salt thereof, and (d) a basic inorganic metal compound for neutralizing at least 70 mol % of acid groups in components (a) to (c), which resin mixture has a Shore D hardness of from 30 to 60.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: March 11, 2014
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Patent number: 8669312
    Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.3 to 6.6, or a metal neutralization product thereof, (b) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 6.8 to 9.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: March 11, 2014
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Publication number: 20140045997
    Abstract: A method of preparing a malleable and/or self-healing polymeric or composite material is provided. The method includes providing a polymeric or composite material comprising at least one alkene-containing polymer, combining the polymer with at least one homogeneous or heterogeneous transition metal olefin metathesis catalyst to form a polymeric or composite material, and performing an olefin metathesis reaction on the polymer so as to form reversible carbon-carbon double bonds in the polymer. Also provided is a method of healing a fractured surface of a polymeric material. The method includes bringing a fractured surface of a first polymeric material into contact with a second polymeric material, and performing an olefin metathesis reaction in the presence of a transition metal olefin metathesis catalyst such that the first polymeric material forms reversible carbon-carbon double bonds with the second polymeric material.
    Type: Application
    Filed: August 8, 2013
    Publication date: February 13, 2014
    Inventors: Zhibin Guan, Yixuan Lu
  • Patent number: 8598278
    Abstract: An object of the present invention is to provide a resin composition for the golf ball that suppresses the bleed out of the low molecular weight material component, as well as improves the fluidity and repulsion performance. The present invention provides a golf ball forming resin composition comprising as a resin component, (A) a high melt viscosity resin; (B) a low melt viscosity ionomer resin having a melt viscosity (190° C.) ranging from 1 Pa·s to 10 Pa·s measured by a brookfield viscometer, in a ratio of (A) the high melt viscosity resin/(B) the low melt viscosity ionomer resin being 55 mass % to 99 mass %/45 mass % to 1 mass %; and (C) a metal ion source capable of neutralizing carboxyl groups of (A) the high melt viscosity resin and (B) the low melt viscosity ionomer resin, in an amount of from 0.1 part to 10 parts with respect to 100 parts by mass of a sum of (A) the high melt viscosity resin and (B) the low melt viscosity ionomer resin.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: December 3, 2013
    Assignee: SRI Sports Limited
    Inventors: Takahiro Shigemitsu, Sakoto Okabe
  • Patent number: 8530581
    Abstract: Provided herein is a powder comprising at least one of: (a) a propylene-based elastomer comprising, based on the total weight of said propylene-based elastomer, (i) at least about 60 wt % of propylene-derived units, (ii) about 5 wt % to about 35 wt % of units derived from at least one of ethylene and a C4-C10 alpha-olefin, and said propylene-based elastomer having a heat of fusion, as determined by DSC, of about 75 J/g or less; and (b) a polyolefin-based elastomer having a Shore A hardness, as determined by ISO 868, of less than 95; wherein the powder has an average particle size of from about 30 ?m to about 850 ?m. The powder is useful for rotational molding and for making articles having unique combination of elasticity, flexibility, and toughness.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: September 10, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Joseph M. Tomei, Daniel J. Collins
  • Patent number: 8507599
    Abstract: Golf balls containing a core having at least one layer and cover having at least one layer are provided. A thermoplastic ionomeric composition is used to form at least one layer of the ball. The composition is prepared by providing a masterbatch comprising cycloalkene (polyalkenamer) rubber and neutralizing agent and mixing the masterbatch with ethylene acid copolymer. The acid groups are neutralized to 30 weight percent or greater, preferably 50% or greater, and more preferably 70% or greater. The resulting ball has high resiliency and rebounding properties along with a soft feel.
    Type: Grant
    Filed: December 20, 2010
    Date of Patent: August 13, 2013
    Assignee: Acushnet Company
    Inventors: Mark L. Binette, Brian Comeau, Douglas S. Goguen, Robert Blink, Michael J. Sullivan, David A. Bulpett
  • Patent number: 8492485
    Abstract: Provided is a polycarbonate-based resin composition for sliding use including 0.01 to 1 part by mass of an antioxidant with respect to 100 parts by mass of a polycarbonate-polyorganosiloxane copolymer which has structural units represented by a general formula (A) and structural units represented by a general formula (B), which contains a polyorganosiloxane block moiety containing the structural units represented by the general formula (B) at a content of 1 to 30 mass %, and which has an average repetition number of the structural units represented by the general formula (B) of 110 to 1000. The polycarbonate-based resin composition for sliding use has a specific structure having improved wear resistance, in particular, improved sliding property. Also provided is a molded article using the resin composition, and excellent in wear resistance and sliding property.
    Type: Grant
    Filed: July 6, 2009
    Date of Patent: July 23, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Yasuhiro Ishikawa, Eiji Tamura
  • Patent number: 8486505
    Abstract: A release liner formed of a polypropylene resin sheet that can be highly recyclable and that can provide an excellent performance in a wide range of operating temperature is provided. A release-lined pressure-sensitive adhesive (PSA) sheet constituted with the release liner is also provided. A release-lined PSA sheet 1 according to the present invention comprises a PSA sheet 20 having a support 22 and a PSA layer 24; and a release liner 10 placed on the PSA layer 24. The release liner 10 has a layered configuration formed of a layer A 12 formed of a polypropylene resin composition containing a nucleating agent; and a layer B 14 formed of a polypropylene resin composition containing no nucleating agent; wherein the two layers stacked to form the thickness of the liner.
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: July 16, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Hiroichi Ukei, Yoshio Nakagawa, Osamu Degawa
  • Patent number: 8487027
    Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 40,000 to 80,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 5.0 to 8.0, or a metal neutralization product thereof, (b) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 6.0 to 9.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: July 16, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Patent number: 8466226
    Abstract: There is provided an adhesive composition comprising (i) at least one film forming polymer, (ii) at least one crosslinker selected from the group consisting of polynitroso compounds, polynitroso precursors, and mixtures thereof, and (iii) at least one oxidizer, wherein the molar ratio of oxidizer to crosslinker is from 0.3 to 2.0. Also provided is a method of bonding substrates together using such a composition, and an article made using such a method.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: June 18, 2013
    Assignee: Rohm and Haas Company
    Inventors: Dean Edward Hoy, James Patrick Weir, Lipa Leon Roitman
  • Patent number: 8461268
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: June 11, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8450419
    Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: May 28, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8450425
    Abstract: An object of the present invention is to provide a golf ball excellent in fluidity, adhesion of the paint film, and repulsion. Another object of the present invention is to provide a golf ball which is excellent in durability and low-temperature durability.
    Type: Grant
    Filed: September 15, 2009
    Date of Patent: May 28, 2013
    Assignee: SRI Sports Limited
    Inventors: Satoko Okabe, Takahiro Shigemitsu, Kazuhiko Isogawa, Tsutomu Hirau
  • Patent number: 8426523
    Abstract: An object of the present invention is to provide a golf ball excellent in fluidity, adhesion of the paint film, and repulsion. Another object of the present invention is to provide a golf ball which is excellent in durability and low-temperature durability. The present invention provides a golf ball comprising: a core and a cover covering the core, wherein the cover is formed from a cover composition that contains as a resin component, (A) a specific high melt viscosity ionomer resin being neutralized with at least two metal ions, and (B) a low melt viscosity ionomer resin being neutralized with at least two metal ions, in a ratio of (A) the high melt viscosity ionomer resin/(B) the low melt viscosity ionomer resin being 55 mass % to 99 mass %/45 mass % to 1 mass %.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: April 23, 2013
    Assignee: SRI Sports Limited
    Inventor: Satoko Okabe
  • Patent number: 8410220
    Abstract: Disclosed are golf balls having soft, resilient bimodal ionomeric covers with improved softness and scuff resistance and methods for their preparation. The soft, resilient bimodal ionomeric covers comprise at least partially neutralized mixtures of carboxylate functionalized terpolymers (molecular weight between about 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (molecular weight between about 2,000 and 30,000).
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: April 2, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: John Chu Chen
  • Patent number: 8399082
    Abstract: An ionomer blend composition comprises a blend of a first ionomer and a second ionomer that is different from the first ionomer. The first ionomer is derived from a first precursor acid copolymer that has a melt flow rate of about 10 to about 4000 g/10 min and that comprises copolymerized units of an ?-olefin and about 20 to about 30 wt % of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid. Moreover, the first precursor acid can be neutralized to a level of about 40% to about 90% to form a sodium ionomer that has a MFR of about 0.7 to about 25 g/10 min and a freeze enthalpy that is less than about 3.0 j/g or that is not detectable, when determined by differential scanning calorimetry (DSC). A variety of articles may comprise or be produced from the ionomer blend composition, for example by injection molding.
    Type: Grant
    Filed: June 1, 2012
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Karlheinz Hausmann, Richard Allen Hayes, Steven C Pesek, W Alexander Shaffer, Charles Anthony Smith
  • Patent number: 8399081
    Abstract: A solar cell module comprising a solar cell layer and an ionomer sheet comprising a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an ?-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein when about 40% to about 90% of the total content of the carboxylic acid groups present in the precursor acid copolymer are neutralized to carboxylate groups to comprise carboxylate groups and counterions that consist essentially of sodium ions, the resulting sodium ionomer has a freeze enthalpy that is not detectable or that is less than about 3.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Steven C. Pesek, W Alexander Shaffer, Charles Anthony Smith, George Wyatt Prejean
  • Patent number: 8399098
    Abstract: A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an ?-olefin and an ?,?-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Stephen J. Bennison, Richard Allen Hayes, Steven C. Pesek, W Alexander Shaffer, Charles Anthony Smith
  • Patent number: 8394876
    Abstract: The invention provides a golf ball in which an intermediate layer formed of a highly neutralized resin mixture obtained by using two nonionic resins of differing weight-average molecular weights and breadths of molecular weight distribution (weight-average molecular weight/number-average molecular weight) as the base resin and adding thereto an organic acid or a metal salt thereof and a basic inorganic metal compound capable of being neutralized is combined with a cover formed of an ionic resin having a weight-average molecular weight in a specific range and a breadth of molecular weight distribution (weight-average molecular weight/number-average molecular weight) in a specific range. The golf ball material of the invention has an excellent rebound and durability.
    Type: Grant
    Filed: September 20, 2010
    Date of Patent: March 12, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Patent number: 8394478
    Abstract: A release liner formed of a highly recyclable polypropylene-based resin sheet and capable of assuring excellent operability over a wide range of environmental temperature is provided. A pressure-sensitive adhesive (PSA) sheet with release liner is also provided. A PSA sheet with release liner according to the present invention comprises a PSA sheet including a support and a PSA layer; and a release liner formed of a polypropylene-based resin sheet which is obtained by molding into a sheet a polypropylene-based resin composition containing a nucleating agent. The PSA sheet with release liner provides excellent operability even in a high temperature environment of, for example, about 35° C. The PSA sheet with release liner is preferably applicable in an attachment operation wherein the PSA sheet is attached to an adherend while the liner is released from the PSA sheet.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: March 12, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Hiroichi Ukei, Yoshio Nakagawa, Osamu Degawa
  • Patent number: 8357756
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polylalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Grant
    Filed: November 4, 2009
    Date of Patent: January 22, 2013
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 8349958
    Abstract: An object of the present invention is to provide a resin composition for the golf ball that suppresses the bleed out of the low molecular weight material component, as well as improves the fluidity and repulsion performance. The present invention provides a golf ball forming resin composition comprising as a resin component, (A) a high melt viscosity resin; (B) a low melt viscosity ionomer resin having a melt viscosity (190° C.) ranging from 1 Pa·s to 10 Pa·s measured by a brookfield viscometer, in a ratio of (A) the high melt viscosity resin/(B) the low melt viscosity ionomer resin being 55 mass % to 99 mass %/45 mass % to 1 mass %; and (C) a metal ion source capable of neutralizing carboxyl groups of (A) the high melt viscosity resin and (B) the low melt viscosity ionomer resin, in an amount of from 0.1 part to 10 parts with respect to 100 parts by mass of a sum of (A) the high melt viscosity resin and (B) the low melt viscosity ionomer resin.
    Type: Grant
    Filed: September 4, 2009
    Date of Patent: January 8, 2013
    Assignee: SRI Sports Limited
    Inventors: Takahiro Shigemitsu, Satoko Okabe
  • Patent number: 8334033
    Abstract: A sodium/zinc mixed ionomer comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an ?-olefin and an ?,?-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 10 to about 4000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry. Further provided are articles comprising or prepared from the sodium/zinc mixed ionomer.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: December 18, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Karlheinz Hausmann, Richard Allen Hayes, Steven C. Pesek, W Alexander Shaffer, Charles Anthony Smith
  • Patent number: 8273827
    Abstract: Disclosed is an adhesive composition having adhesion properties, high-speed curing properties and moisture resistance. Also disclosed is an adhesion method. Specifically disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (C) a compound having an enal structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (D) a compound having an amine structure, and (E) a compound containing copper. Also disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (D) a compound having an amine structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (C) a compound having an enal structure, and (E) a compound containing copper.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: September 25, 2012
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yuki Hisha, Kimihiko Yoda, Kazuhiro Oshima
  • Patent number: 8193283
    Abstract: Disclosed are golf balls having soft, resilient bimodal ionomeric covers with improved softness and scuff resistance and methods for their preparation. The soft, resilient bimodal ionomeric covers comprise at least partially neutralized mixtures of carboxylate functionalized terpolymers (molecular weight between about 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (molecular weight between about 2,000 and 30,000).
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: June 5, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John Chu Chen
  • Patent number: 8183324
    Abstract: The present invention is an antistatic acrylic fiber which comprises 90 to 99% by weight of acrylonitrile polymer containing 80 to 100% by weight of acrylonitrile as a constituting component and 10 to 1% by weight of acrylic antistatic resin containing 10 to 70% by weight of acrylonitrile as a constituting component, characterized in that alkali metal ion is contained in the fiber in an amount of not less than 150 ppm. The acrylic fiber of the present invention has antistatic property which does not lower so much even if the fiber is subjected to a spinning and dyeing step.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: May 22, 2012
    Assignee: Japan Exlan Company Limited
    Inventors: Yoshiki Yamato, Yoshihiro Watanabe
  • Publication number: 20120108752
    Abstract: A novel polyethylene composition is described. The composition is suitable for manufacturing especially stretched bands or tapes, also coined raffia in the art.
    Type: Application
    Filed: June 24, 2010
    Publication date: May 3, 2012
    Applicant: BASELL POLYOLEFINE GMBH
    Inventors: Joachim Berthold, Bernd Lothar Marczinke, Diana Dötsch, Johannes-Gerhard Müller
  • Patent number: 8168710
    Abstract: A golf ball having a core, a cover layer, and an optional intermediate layer disposed between the core and the cover layer is disclosed and described. One or more of the core, the cover layer, or the intermediate layer is formed of a highly neutralized polymer blend of an acid copolymer and a metallocene-catalyzed copolymer, an olefinic block copolymer, a sufficient amount of a suitable cation source and a fatty acid or salt of a fatty acid. The highly neutralized polymer blend is neutralized from 80% to 100% while still retaining processability. Further, the core can have a diameter of 0.5 inches to about 1.62 inches and an Atti compression less than or equal to 105. The cover layer can have a material hardness between about 30 and 70 Shore D.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: May 1, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Michael J. Sullivan, Kevin M. Harris
  • Patent number: 8133947
    Abstract: The invention provides a golf ball material made of a resin composition composed of (a-I) an olefin-acrylic acid copolymer having a weight-average molecular weight (Mw) of from about 150,000 to about 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from about 3.0 to about 7.0, or a metal neutralization production thereof; (a-II) an olefin-methacrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from about 120,000 to about 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from about 3.0 to about 7.0, or a metal neutralization production thereof; (b) an organic acid or a metal salt thereof; and (c) a basic inorganic metal compound which is capable of neutralizing acid groups in the composition. The golf ball material of the invention enables a highly neutralized ionomer having good flow properties and moldability to be achieved.
    Type: Grant
    Filed: February 16, 2010
    Date of Patent: March 13, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Publication number: 20120035325
    Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small particles in a continuous phase of the thermoplastic resin. The elastomer in the alloy is cured by means of a cure system comprising an increased amount of curative and preferably with no cure accelerators present in the cure system. The elastomer obtains at least seventy five percent cure in not more than 15 minutes at temperatures 220° C. or greater.
    Type: Application
    Filed: August 5, 2010
    Publication date: February 9, 2012
    Inventor: Maria D. Ellul