Heterocyclic Reactant Is An Imide Or Lactam Patents (Class 525/205)
  • Patent number: 6015859
    Abstract: A thermoplastic polymer composition contains at least two distinct polymers, characterized in that it comprises at least one polymer P1 containing at least one reactive function and at least one modified polyolefin P2 containing at least one succinimide ring substituted on the nitrogen by a reactive group, the ring being carried either by the main chain or by a side chain, and optionally at least one third polymer P3 selected from the group formed by polymers and copolymers obtained by polymerisation of one or more olefinic compounds. A mixture of polymers comprises at least one composition as defined above and at least one other polymer P5 which is identical to or different from polymer P3 and optionally at least one other polymer P6 which is identical to or different from polymer P1.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: January 18, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Yves Camberlin, Serge Gonzalez, Frederique Hauviller
  • Patent number: 6011096
    Abstract: This invention relates to an improved free radical polymerization process for directly producing stable vinylpyridine polymer particles in an aqueous suspension and in a high state of polymer purity by effecting the polymerization in the presence of a water soluble suspension agent selected from the group of polyvinyl lactam, a hydroxy-containing polymer, a polyvinyl alcohol and a mixture thereof.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: January 4, 2000
    Assignee: ISP Investments Inc.
    Inventors: Jenn S. Shih, Eduardo T. Yap, John C. Hornby, Bala Srinivas
  • Patent number: 6008317
    Abstract: The present invention generally relates to certain hydrophilic polymers. These polymers undergo negligible shrinkage when polymerized and are highly hydrophilic, rendering them useful in a variety of applications.
    Type: Grant
    Filed: May 15, 1998
    Date of Patent: December 28, 1999
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Richard M. Ozark, Paul L. Valint, Jr.
  • Patent number: 5981142
    Abstract: A copolymer useful as a photoresist resin for submicrolithography, comprising glutarimide derivatives and acrylic acid derivatives as shown in Formula I and a photoresist composition comprising the same. ##STR1## wherein, R.sub.1 is a straight or branched alkyl group containing 0-30 carbon atoms; R.sub.2 and R.sub.3 independently represent straight or branched alkoxy or cycloalkoxy groups containing 1-15 substituted or non-substituted carbon atoms; R.sub.4 and R.sub.5 independently represent hydrogen or an alkyl group; and p, q and r, which may be the same or different, each is a polymerization ratio; p ranges from 10 to 90, q ranges from 10 to 90 and r ranges from 0 to 50.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: November 9, 1999
    Assignee: Hyundai Electronics Industries, Co., Ltd.
    Inventors: Jae Chang Jung, Cheol Kyu Bok, Hyung Gi Kim
  • Patent number: 5959029
    Abstract: The invention relates to a chemical composition containing a) a copolymer based on styrene and/or at least one alkyl (meth)acrylate, the quantity of styrene and/or alkyl (meth)acrylate being .gtoreq.50% by weight, based on the total monomers, and at least one further comonomer, and b) a water-soluble polymeric protective colloid, wherein about 2 to 30 parts per weight of the water-soluble polymeric protective colloid are allotted to 100 parts by weight of the copolymer, and c) optional further additives as required. The copolymer contains appoximately 0.1 to 50% by weight units of an epoxide-group-containing ethylenically unsaturated comonomer. Such units show reactive epoxide groups. The invention relates further to an aqueous polymer dispersion of said chemical composition, the production of same and a special method for obtaining the chemical composition from the polymer dispersion and special applications of the aqueous polymer dispersion and the chemical composition.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: September 28, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Robert Koelliker, Harald Bachler
  • Patent number: 5959037
    Abstract: A novel acrylic copolymer elastomer comprising ?I! an alkyl acrylate; ?II! (a) CH.sub.a .dbd.CRCOOR.sub.2 OCOR.sub.1, (b) CH.sub.2 .dbd.CRCO?O(CH.sub.2) pCO!qOR.sub.1 or (c) CH.sub.2 .dbd.CRCOOR.sub.2 ?CO(CH.sub.2)pO!qCOR.sub.1 ; and ?III! (1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3) CH.sub.2 .dbd.CHOCO(CH.sub.2)mPhOR', (4) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (5) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (6) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' where R is a hydrogen atom or a methyl group, R.sub.1 is an alkyl group, R.sub.2 is an alkylene group, R' is a hydrogen atom, an acyl group or a trialkylsilyl group and Ph is a phenylene group, provides a blend rubber having an improved cold resistance and an intermediate heat resistance between the heat resistance of acrylic copolymer elastomer and that of fluorine-containing elastomer, when blended with the fluorine-containing elastomer.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: September 28, 1999
    Assignee: Nippon Mektron, Limited
    Inventors: Kuniyoshi Saito, Iwao Moriyama, Jun Okabe
  • Patent number: 5959009
    Abstract: The invention relates to waterproof or water resistant compositions for application to the lashes comprising a styrene-ethylene-propylene copolymer as gellant, a film forming agent, and a volatile oil.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: September 28, 1999
    Assignee: E-L Management Corp
    Inventors: Richard A. Konik, Rachel J. Painter, George J. Stepniewski
  • Patent number: 5955541
    Abstract: A thermoplastic resin composition which has low rigidity such as bending strength, bending modulus and tensile strength, high impact resistance, and further low stress and large energy absorption at the time of impact, high heat deformation resistance and excellent moldability and comprises 5 to 65 by weight of the copolymer (I) having Tg (glass transition temperature) of not more than 20.degree. C., 20 to 80 parts by weight of the maleimide copolymer (II) and 15 to 75 part by weight of the graft copolymer (III) having a graft ratio of 10 to 70% so that the total amount of the copolymers (I), (II) and (III) becomes 100 parts by weight, can be obtained.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: September 21, 1999
    Assignee: Kaneka Corporation
    Inventors: Kazuhito Wada, Ikuhiro Mishima, Shigemi Matsumoto
  • Patent number: 5936038
    Abstract: A vulcanizable elastomer having at least one pendant reactive amino group. The elastomer is vulcanized by using a phenolic-resin curative essentially in the absence of an activation catalyst, to form a vulcanizate. Also provided is a thermoplastic elastomeric vulcanizable composition of matter, employing the elastomer having the pendent reactive amino group, which may be dynamically vulcanized without the use of an activation catalyst. Further provided is a method for vulcanizing an elastomer having at least one pendent reactive amino group by utilizing a phenolic vulcanizing agent without the use of a catalyst.
    Type: Grant
    Filed: August 9, 1996
    Date of Patent: August 10, 1999
    Assignee: The University of Akron
    Inventors: Aubert Y. Coran, Oansuk Chung
  • Patent number: 5919864
    Abstract: A thermoplastic elastomer composition containing a thermoplastic resin component including 10 to 95% by weight of a polypropylene having a syndiotactic structure and an elastomer component and having a value of .alpha., defined as follows, of 1 or less:.alpha.=(.phi.d/.phi.m).times.(.eta.m/.eta.d)wherein the volume fraction of the thermoplastic resin component is .phi.m, the melt viscosity thereof at the mixing conditions is .eta.m and the volume fraction of the elastomer component is .phi.d, the melt viscosity thereof is .eta.d.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: July 6, 1999
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Jiro Watanabe, Osamu Ozawa, Noriaki Kuroda, Gou Kawaguchi
  • Patent number: 5916972
    Abstract: Disclosed are mixtures of two or more polymers of which at least one is cross-linked. Interpenetrating polymer networks are on hand. The polymers mix below a certain temperature and demix above this temperature (LCST behavior). Below the demixing temperature, such interpenetrating polymer networks are optically clear, above the demixing temperature they are milky, turbid and have reduced light transmission due to the light scattering of the phaseseparated system' if the refractive indices of the components do not coincide. The demixing process is fully reversible below the demixing temperature.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 29, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Eck, Hans-Joachim Cantow, Volker Wittwer
  • Patent number: 5907011
    Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: May 25, 1999
    Assignee: Clariant GmbH
    Inventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: 5804629
    Abstract: Molding materials comprise polyarylene ethers, copolymers containing units which are derived from aromatic vinyl compounds and cyclic .alpha.,.beta.-unsaturated carboxylic anhydrides and carboximides, and furthermore fillers and rubber impact modifiers.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: September 8, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Norbert Guentherberg
  • Patent number: 5786411
    Abstract: A light resistant polymer composition useful for molding applications is provided. The polymer composition comprises a blend of polycarbonate resin with a graft copolymer resin and an acylated sterically hindered amide. The compositions have improved physical properties as compared to compositions containing hindered amine light stabilizers.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: July 28, 1998
    Assignee: General Electric Company
    Inventors: James Paul Barren, James Edward Pickett
  • Patent number: 5756584
    Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: May 26, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
  • Patent number: 5681889
    Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer selected from the group consisting of compounds having, in the molecule, at least two polymerizable double bonds, and compounds having, in the molecule, at least one functional group selected from hydrolyzable silyl groups and 1,2-epoxy groups and one polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer. Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: October 28, 1997
    Assignee: Kansai Paint Co., Ltd
    Inventors: Masahiro Kondo, Hiroshi Inoue
  • Patent number: 5654369
    Abstract: The invention provides a thermoplastic resin composition uniformly and permanently rendered antistatic which comprises (A) 100 parts by weight of a thermoplastic resin, (B) 3-30 parts by weight of a cationic copolymer comprising 80-98 mol % of an ethylene unit and 2-20 mol % of a cationic unit and having a weight-average molecular weight of 1,000-50,000, and (C) 0.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: August 5, 1997
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takayuki Tsubaki, Yutaka Nakayama, Hideyuki Sumi, Hiroshi Hotta
  • Patent number: 5625006
    Abstract: Adhesive beads comprise a core comprising a pressure sensitive adhesive material and an essentially discontinuous organic polymer disposed about the core. The beads are free-flowing at room temperature. Upon application of heat and/or pressure the core is activated and blends with the coating to provide a pressure sensitive adhesive.
    Type: Grant
    Filed: January 24, 1996
    Date of Patent: April 29, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Joseph P. Callahan, Jr., Rudyard M. Enanoza, Mark D. Weigel
  • Patent number: 5580928
    Abstract: A resin composition is disclosed which comprises:(a) from 1 to 99% by weight of a maleimide-olefin copolymer comprising from 40 to 60 mol % of structural unit (I) shown below and from 60 to 40 mol % of structural unit (II) shown below and having a number-average molecular weight of from 1.times.10.sup.3 to 5.times.10.sup.6 : ##STR1## wherein R.sup.1 is hydrogen or an alkyl having 1 to 6 carbon atoms, ##STR2## wherein R.sup.2 and R.sup.3 each is hydrogen or an alkyl having 1 to 6 carbon atoms; and(b) from 99 to 1% by weight of an acrylonitrile-styrene copolymer containing from 21 to 45% by weight of an acrylonitrile units. The composition is excellent in optical properties including transparency and low birefringence and in heat resistance and mechanical properties.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: December 3, 1996
    Assignee: Tosoh Corporation
    Inventors: Toru Doi, Hiroshi Inoue
  • Patent number: 5578677
    Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 26, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5559187
    Abstract: This invention is directed to a thermoplastic terpolymer excelling in thermal stability and transparency and possessing high mechanical strength, specifically a thermoplastic copolymer (I) composed of 30 to 70% by weight of (A) an aromatic vinyl compound unit, 4 to 40% by weight of (B) a vinyl cyanide unit, and 26 to 50% by weight of (C) an N-substituted maleimide and characterized by having a narrow distribution of molecular weight divisions of copolymer composition as measured by GPC, having substantially no acetone-insoluble content, possessing a weight average molecular weight in the range of 100,000 to 300,000 and a number average molecular weight in the range of 50,000 to 150,000, and having a residual N-substituted maleimide content of not more than 50 ppm.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: September 24, 1996
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Katsuaki Maeda, Akihiro Watanabe, Hajime Nishihara
  • Patent number: 5548029
    Abstract: Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
  • Patent number: 5536786
    Abstract: Adhesive beads comprise a core comprising a pressure sensitive adhesive material and an essentially discontinuous organic polymer disposed about the core. The beads are free-flowing at room temperature. Upon application of heat and/or pressure the core is activated and blends with the coating to provide a pressure sensitive adhesive.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: July 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Joseph P. Callahan, Jr., Rudyard M. Enanoza, Mark D. Weigel
  • Patent number: 5536446
    Abstract: Solid state conductive polymer compositions which are ionically-conductive regardless of the amount of water present in the composition are disclosed. The compositions have solvating polymer, ionic salt, and optionally if the composition is not cohesive and pliable, essentially non-volatile plasticizer in an amount sufficient to render the composition cohesive and pliable. Biomedical electrodes having means for electrical communication contacting the compositions are also disclosed. Methods of making the compositions and electrodes are also disclosed.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: July 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Rosa Uy, Timothy M. Dietz
  • Patent number: 5510421
    Abstract: Azlactone-functional membranes prepared by solvent phase inversion techniques are disclosed. Adduct membranes prepared by the reaction of azlactone-functional membranes with nucleophilic reagents are also disclosed. Both azlactone-functional copolymers and blends of azlactone-functional homopolymers or copolymers with blending polymers can be used. These azlactone-functional membranes have azlactone functionality throughout all surfaces formed ab initio into any desired shape. Membrane properties can be modified by sacrifice of some azlactone functionality via crosslinking between azlactone moieties or coupling of hydrophilic ligands.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: April 23, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kathleen A. Dennison, Monserrat R. La Londe, James S. Stefely
  • Patent number: 5502110
    Abstract: A resin composition for an electrophotographic toner is here disclosed which comprises an ethylene series high polymer (Y) and an ethylene series polymer (X) prepared from 100 parts of a bifunctional ethylene series unsaturated monomer and 0.01-10 parts by weight of a substance having three or more peroxide groups in the molecule and/or a substance having one or more unsaturated functional groups and one or more peroxide groups in the molecule, Mw/Mb (Mw is weight-average molecular weight, and Mb is weight-average molecular weight between crosslinking points) of said polymer (X) being from 2 to 99, Mw of said polymer (X) being 50,000 or less. This resin composition is excellent in the balance of various physical properties required for the toner, and particularly, it is excellent in offset resistance and toner strength.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: March 26, 1996
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Katsuru Matsumoto, Nobuhiro Hirayama, Kenji Uchiyama, Shoji Kawasaki, Tamami Fukui, Katsuo Uramoto
  • Patent number: 5502111
    Abstract: Heat distortion temperature of polyvinyl chloride compositions can be significantly increased above the heat distortion temperature of uncompounded polyvinyl chloride while good appearance of extruded material is preserved by preblending an imidized acrylic resin having a glass transition temperature above 130.degree. C. with a third polymer melt-processable throughout the temperature range of 150.degree.-300.degree. C. under conditions where a two-phase blend is formed, wherein the third polymer forms the continuous phase and the imidized acrylic resin forms the dispersed phase and then melt-blending the two-phase blend with polyvinyl chloride at a temperature of 150.degree.-220.degree. C. to form a composition in which the imidized acrylic resin forms a substantially homogeneous blend with polyvinyl chloride.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: March 26, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 5486561
    Abstract: There is disclosed a polypropylene resin composition which comprises (a) polypropylene; (b) ethylene/.alpha.-olefin copolymer elastomer having a specific range of Mooney viscosity; (c) modified polyolefin having a specific functioal group at either or both end thereof; and (d) specific compound such as stearic acid monoglyceride, stearyl diethanolamine, N-diethanol stearylamide and N-diethanol dodecanaeamide. The above composition is excellent in elasticity, peeling strength and recoating properties, can be painted immediately after degreasing without pretreatment with trichloroethane, etc. and is well suited for polypropylene bumper materials to be painted, etc.
    Type: Grant
    Filed: April 21, 1993
    Date of Patent: January 23, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Koki Hirano, Ryuichi Ohki, Yutaka Kobayashi
  • Patent number: 5460818
    Abstract: A polymer blend composition comprising:(a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic .alpha.-olefin homopolymer or interpolymer, or an interpolymer of an .alpha.-olefin and a non-aromatic monomer interpolymerizable therewith;(b) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a homopolymer or interpolymer of monovinylidene aromatic monomers, or an interpolymer of monovinylidene aromatic monomer and a monomer interpolymerizable therewith other than an aliphatic .alpha.-olefin; and(c) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a substantially random interpolymer comprising an .alpha.-olefin and a vinylidene aromatic monomer.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: October 24, 1995
    Assignee: The Dow Chemical Company
    Inventors: Chung P. Park, George P. Clingerman, Francis J. Timmers, James C. Stevens, David E. Henton
  • Patent number: 5446094
    Abstract: A thermoplastic coupling agent mixture (A) containinga) 5 to 95% by weight of an ethylene copolymer (A.sub.I) having minor amounts of polar comonomers, andb) 5 to 95% by weight of a copolymer (A.sub.II) of aromatic monovinyl comonomers and conjugated dienesis suitable in particular as a component in thermoplastic polymer mixtures that contain polyolefins (B), copolymers of styrene (C), and also if appropriate further thermoplastic polymers (D), and the components (B), (C) and if appropriate (D) may also be used in the form of reprocessed polymers obtainable by regranulating molded parts produced from the relevant materials.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: August 29, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Friedrich Seitz, Andreas Jung, Norbert Guentherberg
  • Patent number: 5389723
    Abstract: Semi-interpenetrating polymeric networks comprising a blend of hydrophilic and hydrophobic polymers wherein at least one of the polymeric components is crosslinked after blending to form a continuous network throughout the bulk of the material, and through which the uncrosslinked polymeric components are intertwined in such a way as to form a macroscopically homogeneous composition. The integrity of such networks persists even after absorption of solvent. These materials can be used to form durable, non-tacky, ink-absorbent, transparent coatings for graphical materials.
    Type: Grant
    Filed: October 24, 1990
    Date of Patent: February 14, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mohammad Iqbal, Alan G. Miller, John J. Stofko, Jr.
  • Patent number: 5387631
    Abstract: Rubber compositions for use in pneumatic tire treads. Specified amounts of NR and/or IR and SBR are combined with a selected class of rubber components of the formula ##STR1## SBR contains in its molecular chains one or more atomic groups of the formula ##STR2## Rebound resilience, skid resistance and fuel saving are greatly improved.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: February 7, 1995
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kinya Kawakami, Atsushi Kanazawa
  • Patent number: 5376727
    Abstract: A composition comprising a blend of (a) a polymeric matrix component comprising crosslinkable polymers made from 80 to 99 parts by weight of at least one .alpha.,.beta.-ethylenically unsaturated monomer and from 1 to 20 parts by weight of at least one chelating compound, (b) a liquid-absorbent component comprising a water-absorbent, preferably water-soluble, polymer, and (c) a multivalent metal ion as a crosslinking agent. This composition is capable of forming liquid-absorbent, semi-interpenetrating networks. The composition of this invention can provide polymeric matrices which, when coated on a transparent backing, result in transparent coatings capable of providing improved combinations of ink absorption and durability, while at the same time retaining transparency and being amenable to the types of processing commonly used in producing transparent graphical materials.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: December 27, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mohammad Iqbal, Terrance P. Smith, Stofko, Jr.
  • Patent number: 5362802
    Abstract: Polymers containing a high percentage of vinyl alcohol units, especially when treated to remove impurities, when blended with copolymers of alkyl (meth)acrylates, N-vinyllactams or N-vinylamides, and unsaturated acids, preferably further with a small amount of plasticizer, may be applied as hot melt adhesives to paper, wood, and other cellulosic articles.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Newman M. Bortnick, Roger K. Graham, Edward E. LaFleur, William J. Work
  • Patent number: 5362803
    Abstract: Polymers containing a high percentage of vinyl alcohol units, when treated with acid to remove impurities, may be blended with low levels of copolymers of alkyl methacrylates and N-vinyllactams or N-vinylamides, optionally containing copolymerized acid, and processed into sheet, film, fiber and other objects which exhibit a useful balance of barrier and strength properties.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, Robert M. Amici, William J. Work
  • Patent number: 5362801
    Abstract: Polymers containing a high percentage of vinyl alcohol units, especially when treated to remove impurities, when blended with copolymers of alkyl (meth)acrylates, N-vinyllactams or N-vinylamides, and unsaturated acids, preferably further with a small amount of plasticizer, may be applied as hot melt adhesives to paper, wood, and other cellulosic articles.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Newman M. Bortnick, Roger K. Graham, Edward E. LaFleur, William J. Work
  • Patent number: 5346945
    Abstract: A thermoplastic molding material comprising (A) a copolymer composed of acrylonitrile plus styrene, a-methylstyrene or a nuclear-substituted styrene derivative or mixtures of these three monomers; (B) a graft copolymer prepared either by (B.sub.1) emulsion polymerization of a monomer mixture, based on either styreneacrylonitrile or styreneacrylonitrile-methyl methacrylate, on a latex, obtained as an emulsion, of an elastomer based on butadiene or acrylic ester as a grafting base, or by (B.sub.2) solution polymerization of a monomer mixture, based on either styreneacrylonitrile or styreneacrylonitrile-methyl methacrylate, on an elastomer, prepared in solution, based on butadiene or acrylic ester or an EPDM elastomer as grafting base; (C) a. reinforcing agent based on an inorganic glass; and (D) a copolymer composed of (D.sub.1) units of the formula I, ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or methyl and R.sup.3 is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.6 -C.sub.
    Type: Grant
    Filed: August 23, 1993
    Date of Patent: September 13, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Deckers, Norbert Guentherberg
  • Patent number: 5338490
    Abstract: A two-phase composite of ionically-conductive pressure-sensitive adhesive, biomedical electrodes using the composite and methods of preparing the composite and the electrode are disclosed. The continuous phase is a hydrophilic, solid state pressure-sensitive adhesive composition ionically-conductive regardless of an amount of water present in the composition. The discontinuous phase are domains of a hydrophobic pressure-sensitive adhesive which enhances adhesion of the composite to mammalian skin while maintaining acceptable alternating current impedance of the composite.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: August 16, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Timothy M. Dietz, Robert A. Asmus, Rosa Uy
  • Patent number: 5338799
    Abstract: A curing type resin composition used as a molding material, a paint binder, etc. comprises a curing agent and a copolymer composed of a silicone compound and an .alpha., .beta.-unsaturated vinyl monomer. The silicone compound is selected from the group consisting of silicone compounds having the following general structural formulas (1) and (2) respectively, and the curing agent has at least two functional groups, individual molecules of which react with a functional group in the groups Y of the silicone compound. ##STR1## wherein: X is selected from the group consisting of a 3-acryloxypropyl group and a 3-methacryloxypropyl group;Y is selected from the group consisting of a 3-glycidoxypropyl group; a 2-(3',4'-epoxycyclohexyl)ethyl group; a 3-hydroxypropyl group; a 3-(2'-hydroxyethoxy)propyl group; and a 3-(4'-(3',3'-dihydroxymethyl)butoxy)propyl group,R is selected from the group consisting of a phenyl group and an alkyl group having 1 to 6 carbon atoms; anda, b, and c are numbers in the following ranges:1.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: August 16, 1994
    Assignee: Nippon Paint Co. Ltd.
    Inventors: Hiroharu Ohsugi, Keita Mizutani
  • Patent number: 5332780
    Abstract: Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: July 26, 1994
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Naoki Kitazawa, Manabu Kikuta, Hiroshi Hotta, Yutaka Nakayama, Hideyuki Sumi
  • Patent number: 5331027
    Abstract: The lubricious hydrophilic coatings of the invention are significantly more lubricious when wet than when dry, are adherent to a variety of substrates, and are resistant to removal by wet abrasion. In one embodiment, the coatings include a hydrophilic polyolefin such as polyvinyl-pyrrolidone and a water-insoluble stabilizing polymer such as a cellulose ester. The coatings may also include an adherent polymer and a plasticizing agent. The coating may be applied by preparing a solution of the stabilizing polymer and a solution of the hydrophilic polyolefin, and coating the substrate first in one then the other. Alternatively, both the stabilizing and hydrophilic polymers may be dissolved in a single solvent system and applied to the substrate in a single step. In another embodiment, only a solution of a hydrophilic polyolefin is applied directly to the substrate.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: July 19, 1994
    Assignee: Sterilization Technical Services, Inc.
    Inventor: Richard J. Whitbourne
  • Patent number: 5322892
    Abstract: A melt process for forming fibers from blends of polymers containing a high percentage of vinyl alcohol units with terpolymers of alkyl methacrylates, unsaturated acids, anhydrides or glycidyl-containing esters, and N-vinyllactams or N-vinylamides is described.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: June 21, 1994
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, Robert M. Amici, William J. Work
  • Patent number: 5321078
    Abstract: A thermoplastic resin composition comprising (A) 45 to 99% by weight of a graft copolymer obtained by special graft polymerization of a monomer (b) such as an aromatic vinyl compound, a methacrylic ester, etc. in the presence of grafted polymer rubber (a), and (B) 55 to 1% by weight of a thermoplastic aromatic polyester resin can yield shaped articles excellent in impact resistance, chemical resistance, etc. with excellent processability.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: June 14, 1994
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Kiyotaka Mashita, Tatsuo Ishikawa, Susumu Era, Isamu Hattori
  • Patent number: 5314950
    Abstract: Novel resin compositions are provided which possess excellent heat resistance and thermal color stability, alone, or in admixture with bulk resins. The claimed resin compositions comprise homo- and/or copolymers of N-(2,3-dimethylphenyl) maleimide, alone, or in further combination with resins composed of copolymer components, such as vinyl copolymers and rubber-grafted vinyl copolymer resins. The resin compositions have improved heat resistance and produce molded articles with desirably light colors. Also provided is an improved process to make maleimide monomers by using selected polar solvents whereby the amount of uncyclizable trans-amic acid is held at tolerable levels and the desired maleimide is obtained in high yields, free from by-products.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: May 24, 1994
    Assignee: Cytec Technology Corp.
    Inventors: Balwant Singh, Robert J. Tynik
  • Patent number: 5296537
    Abstract: Polymer blends of a) polymers containing predominantly mers of (meth)acrylates and/or glutarimides with b) up to about 40 weight percent of polymers having greater than 50 mol % vinyl alcohol mers exhibit useful barrier properties to oxygen and other environmental gases, while maintaining or enhancing physical properties and clarity.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: March 22, 1994
    Assignee: Rohm and Haas Company
    Inventors: Edward E. La Fleur, Robert M. Amici, William T. Freed, William J. Work, William G. Carson
  • Patent number: 5252704
    Abstract: A method for preparing a polymer powder which is redispersible in water by atomizing an aqueous non-polyvinyl alcohol stabilized polymer dispersion containing a dispersing aid consisting of vinyl pyrrolidone homopolymer.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: October 12, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Randall P. Bright, Jayson C. Vassallo
  • Patent number: 5241006
    Abstract: A composition comprising a blend of (a) a polymeric matrix component comprising crosslinkable polymers made from 80 to 99 parts by weight of at least one .alpha.,.beta.-ethylenically unsaturated monomer and from 1 to 20 parts by weight of at least one chelating compound, (b) a liquid-absorbent component comprising a water-absorbent, preferably water-soluble, polymer, and (c) a multivalent metal ion as a crosslinking agent. This composition is capable of forming liquid-absorbent, semi-interpenetrating networks. The composition of this invention can provide polymeric matrices which, when coated on a transparent backing, result in transparent coatings capable of providing improved combinations of ink absorption and durability, while at the same time retaining transparency and being amenable to the types of processing commonly used in producing transparent graphical materials.
    Type: Grant
    Filed: October 24, 1990
    Date of Patent: August 31, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mohammad Iqbal, Terrance P. Smith, John J. Stofko, Jr.
  • Patent number: 5237011
    Abstract: Compatible polymer mixtures (polymer blends) comprised of polymers of a cyclopentyl (meth)acrylate and a styrene.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: August 17, 1993
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 5218051
    Abstract: Optically isotropic blends comprising styrene/acrylonitrile copolymers containing from 18 to 32 percent acrylonitrile and methyl methacrylate/glutarimide resins containing from 10 to 50 weight percent methyl methacrylate and having stress optical coefficient of between -500 Brewsters and +500 Brewsters are usefully employed in the preparation of molded objects having reduced birefringence.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: June 8, 1993
    Assignee: The Dow Chemical Company
    Inventors: Brian R. Maurer, Mitchell G. Dibbs