Solid Polymer Derived From Cycloaliphatic-containing Reactant Patents (Class 525/216)
  • Patent number: 6087447
    Abstract: Blends of polymeric materials comprising (A) from about 1 to about 99 weight percent of at least one interpolymer containing (1) from about 1 to about 65 mole percent of (a) at least one vinylidene aromatic monomer, or (b) at least one hindered aliphatic vinylidene monomer, or (c) a combination of at least one vinylidene aromatic monomer and at least one hindered aliphatic vinylidene monomer, and (2) from about 35 to about 99 mole percent of at least one aliphatic .alpha.-olefin having from 2 to about 20 carbon atoms; and (B) from about 1 to about 99 weight percent of at least one homopolymer or interpolymer of one or more vinylidene aromatic monomers and/or one or more hindered aliphatic vinylidene monomers. These blends have been observed to possess improved properties when compared to the individual polymers comprising the blend and to provide materials with enhanced processability and temperature ranges of performance.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: July 11, 2000
    Assignee: The Dow Chemical Company
    Inventors: James C. Stevens, Francis J. Timmers, Martin J. Guest, John J. Gathers, Yunwa W. Cheung, Pak-Wing S. Chum, Chung P. Park, George P. Clingerman, Kevin D. Sikkema
  • Patent number: 6033826
    Abstract: A polymer of polyhydroxystyrene derivative containing an acetal or ketal group which can easily be eliminated in the presence of an acid in the molecule and having a very narrow molecular weight distribution gives a resist material suitable for forming ultrafine patterns excellent in resolution, heat resistance, mask linearity, and other properties without causing problems of delay time and the like.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: March 7, 2000
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
  • Patent number: 6008298
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles having a diameter of 0.01 to 0.7 micrometer.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: December 28, 1999
    Assignees: Hoechst Aktiengesellschaft, Mitsui Petrochemical Ind., Ltd.
    Inventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schonherr
  • Patent number: 6005034
    Abstract: A propylene-ethylene copolymer composition is obtained which has good moldability and an excellent balance of rigidity, toughness, and impact-strength. The composition has a melt flow rate of 10 to 300 g/10 minutes and is obtained by producing 60 to 95% by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112.degree. C., and a temperature of 112.degree. C. or higher, respectively, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40% by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer to react so that the content of ethylene becomes 30 to 80% by weight.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: December 21, 1999
    Assignees: Chisso Corpoation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Teruaki Hayashida, Shinei Gima, Kouichi Hatada, Osamu Kojima, Ken Shimizu, Hirokazu Nakajima, Takao Nomura, Yoshihiro Kanome, Takeyoshi Nishio
  • Patent number: 5981644
    Abstract: A method of producing ABS moulding compositions wherein a solution of polymers in group (A) solvents is gradually supplied to a polymerizing mixture of previously-formed soluble rubber, aromatic mono-alkenyl compounds, ethylenically unsaturated nitrites, optional other copolymerizable compounds and optionally a group (B) solvent or a mixture of group (A) and group (B) solvents, the gradual addition of the polymer solution to the polymerizing mixture being started before the beginning of phase inversion and at a monomer conversion rate of 5 to 15% and a viscosity of the polymerizing mixture of less than 20 Pa.sec with simultaneous continuation of polymerization, the group (A) solvent is an aliphatic (C.sub.1 -C.sub.8) or cycloaliphatic alcohol, ketone, ether, ester and/or nitrile, and the group (B) solvent is an aliphatic (C.sub.4 -C.sub.10), cycloaliphatic and/or aromatic hydrocarbon.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: November 9, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralph Ostarek, Herbert Eichenauer, Karl-Erwin Piejko, Frank Wingler, Claus Wulff
  • Patent number: 5977271
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one .alpha.-olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: November 2, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5976759
    Abstract: A polymer composition comprising (i) a polymer (a) having a monomer unit containing a functional group A which becomes alkali-soluble by heating in the presence of an acid, (ii) a polymer (b) having a monomer unit containing a functional group B which also becomes alkali-soluble, but less easily than the functional group A, by heating in the presence of an acid, and if necessary in addition to (i) and (ii) or in place of (ii), (iii) a phenolic compound having a weight-average molecular weight of 300 to 15,000 gives together with an photoacid generator a resist material suitable for forming a pattern excellent in sensitivity, resolution, mask linearity and other properties.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: November 2, 1999
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
  • Patent number: 5959010
    Abstract: Reduction of dust formation for particleized resin is achieved by adding low density high molecular weight polyethylene to molten resin at a temperature and under conditions sufficient to cause the polyethylene to become dispersed within the resin. The resin/polyethylene mixture is then formed into solid particles. The addition of low density, high molecular weight polyethylene significantly reduces the generation of dust during handling, such as in the particleizing and packaging stages of the manufacturing process, while providing resin particles with higher effective softening points as compared to resin particles augmented with polyethylene wax.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: September 28, 1999
    Assignee: Arizona Chemical Company
    Inventor: Robert W. Schluenz
  • Patent number: 5942569
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: August 24, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5916972
    Abstract: Disclosed are mixtures of two or more polymers of which at least one is cross-linked. Interpenetrating polymer networks are on hand. The polymers mix below a certain temperature and demix above this temperature (LCST behavior). Below the demixing temperature, such interpenetrating polymer networks are optically clear, above the demixing temperature they are milky, turbid and have reduced light transmission due to the light scattering of the phaseseparated system' if the refractive indices of the components do not coincide. The demixing process is fully reversible below the demixing temperature.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 29, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Eck, Hans-Joachim Cantow, Volker Wittwer
  • Patent number: 5907011
    Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: May 25, 1999
    Assignee: Clariant GmbH
    Inventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
  • Patent number: 5883192
    Abstract: Disclosed is a resin composition comprising (.alpha.) at least one polymer selected from the group consisting of a non-modified cyclic monomer unit-containing polymer and a modified cyclic monomer unit-containing polymer having a number average molecular weight of from 10,000 to 5,000,000, wherein the cyclic monomer unit is derived from a cyclic conjugated diene, and (.beta.) at least one polymer other than the polymer (.alpha.), and wherein the polymer (.alpha.) is present in an amount of at least 1% by weight, based on the total weight of the polymers (.alpha.) and (.beta.). The molecular structure of the polymer (.alpha.) which is contained in the novel resin composition of the present invention and which is selected from a non-modified cyclic monomer unit-containing polymer and a modified cyclic monomer unit-containing polymer, wherein the cyclic monomer unit is derived from a cyclic conjugated diene, can be controlled with large freedom. Therefore by combining the polymer (.alpha.) with a polymer (.beta.
    Type: Grant
    Filed: June 10, 1996
    Date of Patent: March 16, 1999
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Itaru Natori, Kimio Imaizumi, Kiyoo Kato
  • Patent number: 5874512
    Abstract: Resins which are the copolymers of an alpha-olefin, a cyclic olefin, and an aromatic-group-containing monomer are provided. The cyclic olefins retain their cyclic structures and the aromatic-group-containing monomers retain their aromatic structures after copolymerization into the resin product. Methods for production of the new resins in the presence of a metallocene catalyst system are also provided. New adhesive compositions containing the resin and articles using the new adhesive compositions are also part of the invention.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: February 23, 1999
    Inventors: James McCleod Farley, Martha Hetzel Robertson, Charles Lewis Sims
  • Patent number: 5869591
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of monomer units derived from at least one a-olefin, (b) from 30 to 70 weight percent of monomer units derived from at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of monomer units derived from at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: February 9, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5869555
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: February 9, 1999
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5763532
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5756584
    Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: May 26, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
  • Patent number: 5723545
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: March 3, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5683798
    Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: November 4, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
  • Patent number: 5652308
    Abstract: Novel tackifier resins having a M.sub.n of 5,000 or less and a T.sub.g of 0.degree. C. or above are produced by combining a metallocene catalyst with an alpha-olefin and a cyclic monomer. New adhesives are produced by blending the novel tackifier with a base polymer.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: July 29, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Natalie Ann Merrill, James McLeod Farley, Martha Hetzel Robertson, Charles Lewis Sims, Richard Byron Pannell, Angelo Anthony Montagna
  • Patent number: 5589526
    Abstract: The present invention provides a master batch composition based on elastomeric carriers, comprising an organic peroxide, a plasticizer and a filling material and optionally further additives compatible with the organic peroxide, wherein, in addition to the elastomeric carrier, it contains a polyoctenamer.The present invention also provides a process for the production of a master batch composition, wherein (a) the elastomeric carrier, the polyoctenamer, the plasticizer and optionally a part of the filling material or filling material mixture are homogeneously mixed and thereafter (b) the filling material or the filling material mixture or possibly the remaining amounts thereof, together with the organic peroxide, are incorporated at a temperature below the decomposition temperature of the peroxide.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: December 31, 1996
    Assignee: Peroxid-Chemie GmbH
    Inventors: Gunter Sienel, Maximilian Dorn, Heinz Zimmermann
  • Patent number: 5569716
    Abstract: A rubber composition composed of (A) a hydrocarbon rubber, (B) a vulcanizing agent and/or crosslinking agent, and (C) a hydrogenated petroleum resin having a bromine number not greater than 10 (g/100 g). The rubber composition exhibits improved processability over hydrocarbon rubber used alone but has no bad influence on the physical properties and heat resistance of its vulcanizate. It is free from any trouble involved in crosslinking with a peroxide which is often used for EPR and EPDM. Therefore, it will find general use in the rubber industry.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: October 29, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Kohei Okamoto, Kyoichi Inoue, Takayoshi Kutuno
  • Patent number: 5556920
    Abstract: An at least monoaxially stretched polypropylene film made of a composition comprising a crystalline polypropylene and a monocyclic olefin polymer (e.g. a polycyclobutene or a polycyclopentene), wherein the content of the monocyclic olefin polymer is 0.1-1,000 ppm by weight.The polypropylene film is superior not only in transparency but also in image clarity by which an image is clearly seen through the film.The polypropylene film, when further comprising talc having an average particle diameter of 0.1-10 .mu.m in an amount of 50-4,000 ppm by weight, can prevent the surface roughening or edge roughening of sheet during the sheet formation conducted before stretched film production.The polypropylene film, when further comprising an anti-blocking agent and a polyethylene together, can prevent the generation of voids caused by the anti-blocking agent.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: September 17, 1996
    Assignee: Tokuyama Corporation
    Inventors: Shinsuke Tanaka, Manabu Kaminaka, Isao Masada, Junichi Fujii, Naoki Ueda
  • Patent number: 5552489
    Abstract: Tackifiers having Mn's of 5,000 or less and Tg's above 0.degree. C. are produced by combining a single site catalyst with an alpha-olefin and a cyclic monomer under conditions designed to produce low molecular weight.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: September 3, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: . Natalie A. Merrill, James M. Farley, Martha H. Robertson, Charles L. Sims, Richard B. Pannell, Angelo A. Montagna
  • Patent number: 5547746
    Abstract: A nonwoven fiber and fabric and process for production are provided which have comparable strength characteristics to conventional fibers and fabrics and are of a finer diameter. This is accomplished through a process of producing a nonwoven fabric made from at least one polymer which has a melt temperature between about 410.degree. and 470.degree. F. (210.degree. and 243.degree. C.), xylene solubles between about 3.5 and 7.0%, a melt flow rate between about 30 and 45, and an isotacticity of at least about 94%, extruding the polymer through fine openings, drawing the polymer to produce fibers of a denier of 1.4 or less, and then depositing the fiberized polymer on a collecting surface to form a web of disbursed fibers.The nonwoven fabric of this invention may be used in products such as, for example, diapers, feminine hygiene products, adult incontinence products, wound dressings, bandages, sterilization wraps, surgical drapes and wipers.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: August 20, 1996
    Assignee: Kimberly-Clark Corporation
    Inventor: Robert M. Burton, Sr.
  • Patent number: 5536773
    Abstract: Disclosed are a polypropylene resin composition comprising a crystalline polypropylene having a high stereoregularity and a terpene resin and a petroleum resin each having no polar group; a polypropylene stretched film formed from the polypropylene resin composition; and a polypropylene multi-layer stretched film having a base layer formed from the polypropylene resin composition and a surface layer formed from a polypropylene type polymer. The polypropylene stretched film and a polypropylene multi-layer stretched film have excellent water-vapor barrier properties and transparency, and a high Young's modulus.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: July 16, 1996
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaya Yamada, Michio Toriumi, Yasuo Futami, Tetsunori Shinozaki, Mamoru Kioka
  • Patent number: 5482993
    Abstract: A rubber composition suitable for use in grips of articles such as golf clubs, tennis rackets, bicycles and tools, comprising (1) a rubber component containing a blend of an ethylene-propylene-diene rubber (EPDM) and natural rubber, (2) 2 to 40 parts by weight of a transpolyoctenamer per 100 parts by weight of the rubber blend, and (3) a filler containing a hydrated aluminum silicate powder, which provides grips having good non-slipping property, good feeling of touch and good response to mis-shot of golf balls.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: January 9, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Hidenori Hiraoka
  • Patent number: 5461114
    Abstract: Disclosed are a composition for use in sculpturing, which comprises a resin composition consisting essentially of a polyoctenamer resin and an inorganic filler, and a process for manufacturing a sculptured product comprising using a sculpturing material composition comprising a polyoctenamer resin.The composition for use in sculpturing can be not only molded at moderate temperature by hands and a trowel but also sculptured or shaved with a chisel or a boaster, and even polished with a rasp or a sandpaper.The composition can be made easier by mixing with an inorganic filler and said mixing provides excellent surface smoothness and massiveness effects in handling the sculptured products.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: October 24, 1995
    Assignee: Daicel-Huls Ltd.
    Inventor: Masami Kita
  • Patent number: 5446095
    Abstract: Compatible polymer blends PM, exhibiting a single glass transition temperature Tg comprise(A) 0.1-99.9 wt. % of a polymer P1 comprising at least 95 wt. % styrene; and(B) 99.9-0.1 wt % of a polymer P2 comprising(a) more than 90 wt. % and up to 100 wt. % of ethyl methacrylate, and(b) 0 wt. % up to less than 10 wt. % of at least one monomer copolymerizable with ethyl methacrylate, provided that (a) plus (b) add up to 100 wt. %.The compatible polymer blends may be formulated with another polymer P3, chemically differentiable from P1 and P2, with P3 being incompatible with P1, P2 and PM, to form compositions of better impact resistance than PM. The compatible polymer blends find use in the production of weather-resistant items; data-storage discs, especially for optically readable information; and optical gradient fibers.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: August 29, 1995
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Erwin Felger, Ulrich Terbrack
  • Patent number: 5446098
    Abstract: A covulcanizable rubber composition including a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value not larger than 120, a chlorinated ethylene-propylene copolymer and a vulcanizer. The composition exhibits an improved processing property when mixed, and provides a vulcanized rubber having an improved constant-elongation fatigue resistance.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: August 29, 1995
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Hideo Fukuda, Haruhiko Fujita, Hideyoshi Shimoda, Shiryu You
  • Patent number: 5422409
    Abstract: Polymers of polycyclic olefins such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins with a very narrow molecular weight distribution are obtained without ring opening by a polymerization in which a catalyst which is composed of an aluminoxane and of a stereorigid, chiral metallocene compound of an element of groups IVb to VIb is used, and in which the reaction is stopped at a time when the molecular weight distribution Mw/Mn of the polymer formed is <2.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: June 6, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Frank Osan
  • Patent number: 5391624
    Abstract: A novel thermosettable composition-of-matter is disclosed. One embodiment of the composition-of-matter includes a polymeric thermosettable ingredient having at least three acetoacetoxy-type functional pendant moieties as well as at least three acid-functional pendant moieties. Another embodiment of the composition-of-matter includes at least two polymeric thermosettable ingredients, one of which includes at least three acid-functional pendant moieties and the other of which includes at least three acetoacetoxy-type functional pendant moieties. The novel composition is characterized in that the acid-functional and acetoacetoxy-type functional pendant moieties crosslinkably-react together, when subjected to elevated-temperature conditions for a predetermined period of time, thereby producing a crosslinked polymeric network. The novel thermosettable composition-of-matter can be used "as is" if either of the polymeric thermosettable components is a "fluid" (i.e., is able to flow) at room temperature.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: February 21, 1995
    Assignee: S. C. Johnson & Son, Inc.
    Inventors: Husam A. A. Rasoul, James R. Beam
  • Patent number: 5387631
    Abstract: Rubber compositions for use in pneumatic tire treads. Specified amounts of NR and/or IR and SBR are combined with a selected class of rubber components of the formula ##STR1## SBR contains in its molecular chains one or more atomic groups of the formula ##STR2## Rebound resilience, skid resistance and fuel saving are greatly improved.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: February 7, 1995
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kinya Kawakami, Atsushi Kanazawa
  • Patent number: 5362782
    Abstract: Polypropylene impact copolymer compositions containing a nucleating agent demonstrate not only good low temperature properties, including impact strength, but also resistance to stress whitening when the numerical ratio of the intrinsic viscosity of the copolymer rubber phase to the intrinsic viscosity of the homopolymer phase is near unity and ethylene contents of the copolymer phase are in the range of 38% to 60% by weight. The impact copolymer compositions are useful in the production of molded and extruded articles, shaped containers, and films having good clarity.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: November 8, 1994
    Assignee: Shell Oil Company
    Inventors: James D. McCullough, Jr., Harold K. Ficker
  • Patent number: 5349019
    Abstract: New copolymers, mixtures thereof with poly(meth)acrylate esters and the use thereof for improving the cold fluidity of crude oils.Copolymers comprising as comonomers therein from 50 to 99.9% by weight of a C.sub.14 -C.sub.22 -alkyl(meth)acrylate and 50 to 0.1% by weight of a comonomer derived from a compound comprising a single polymerizable C.dbd.C group and these copolymers or their mixture with C.sub.14 -C.sub.22 -alkyl poly(meth)acrylates having enhanced pour point depressant properties.
    Type: Grant
    Filed: September 2, 1993
    Date of Patent: September 20, 1994
    Assignee: Hoechst
    Inventors: Herbert Wirtz, Sigmar-Peter von Halasz, Michael Feustel, Juliane Balzer
  • Patent number: 5331057
    Abstract: Cycloolefin block copolymers, which in particular are suitable as phase promoters, are preferably obtained by copolymerization of polycyclic olefins, such as norbornene, with acyclic olefins, such as ethylene, by, at a molecular weight distribution M.sub.w /M.sub.n of the polymer block forming of less than 2, changing the reaction conditions one or more times in such a way that the monomer/comonomer ratio changes by at least 10 % or a further polymerizable monomer is metered into the monomer or the monomers.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: July 19, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Frank Osan, Jurgen Rohrmann
  • Patent number: 5322900
    Abstract: Compatible polymer blends PM, exhibiting a single glass transition temperature Tg comprise(A) 0.1-99.9 wt. % of a polymer P1 comprising at least 95 wt. % styrene; and(B) 99.9-0.1 wt % of a polymer P2 comprising(a) more than 90 wt. % and up to 100 wt. % of ethyl methacrylate, and(b) 0 wt. % up to less than 10 wt. % of at least one monomer copolymerizable with ethyl methacrylate, provided that (a) plus (b) add up to 100 wt. %.The compatible polymer blends may be formulated with another polymer P3, chemically differentiable from P1 and P2, with P3 being incompatible with P1, P2 and PM, to form compositions of better impact resistance than PM. The compatible polymer blends find use in the production of weather-resistant items; data-storage discs, especially for optically readable information; and optical gradient fibers.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: June 21, 1994
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Erwin Felger, Ulrich Terbrack
  • Patent number: 5298553
    Abstract: Disclosed are a composition for use in sculpturing, which comprises a resin composition consisting essentially of a polyoctenamer resin and an inorganic filler, and a process for manufacturing a sculptured product comprising using a sculpturing material composition comprising a polyoctenamer resin.The composition for use in sculpturing can be not only molded at moderate temperature by hands and a trowel but also sculptured or shaved with a chisel or a boaster, and even polished with a rasp or a sandpaper.The composition can be made easier by mixing with an inorganic filler and said mixing provides excellent surface smoothness and massiveness effects in handling the sculptured products.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: March 29, 1994
    Assignee: Daicel-Huls Ltd.
    Inventor: Masami Kita
  • Patent number: 5278237
    Abstract: Disclosed are a sculpturing resin composition which comprise comprising a polyoctenamer resin and a polyolefin copolymer and/or a modified polyolefin resin, and a process for sculpturing a sculptured product.The sculpturing composition has an excellent property of not shrinking even after elapse a long period of time, and is capable of being molded by hand at moderate temperatures, sculptured or shaved with a chisel, etc., and also being polished or ground with a rasp, etc., in comparison with conventional sculpturing materials.The anti-shrinking property of the polyoctenamer resin is found to be improved specifically by the mixing with a polyolefin copolymer and/or a modified polyolefin resin.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: January 11, 1994
    Assignee: DAICEL-Huls Ltd.
    Inventor: Masami Kita
  • Patent number: 5278238
    Abstract: Alloys of polycycloolefin polymers are produced by dissolving an ethylene-based functional polymer in at least one polycycloolefin monomer and polymerizing the mixture. Various polycycloolefin catalysts can be utilized. Often it is desirable to utilize bulk polymerization including reaction injection molding (RIM), liquid injection molding (LIM), reinforced reaction injection molding (RRIM), resin transfer molding (RTM), and the like. The alloys have improved properties such as impact strength, solvent resistance, as well as improved thermal aging properties such as retention of impact strength.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: January 11, 1994
    Assignee: The B. F. Goodrich Company
    Inventors: Biing-Lin Lee, Robert J. Minchak
  • Patent number: 5237011
    Abstract: Compatible polymer mixtures (polymer blends) comprised of polymers of a cyclopentyl (meth)acrylate and a styrene.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: August 17, 1993
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 5223577
    Abstract: A rubber-modified, impactresistant acrylonitrile-butadiene-styrene (ABS) molding material, as obtained by polymerizing styrene and acrylonitrile in the presence of a preformed rubber, dissolved in monomeric styrene and acrylonitrile and, if necessary, a solvent, wherein the rubber is a styrene-butadiene block copolymer and at least one further polymer which is compatible with the styrene-butadiene block rubber or its polystyrene component and is incompatible with polystyrene-acrylonitrile.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: June 29, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Ehrenfried Baumgartner, Juergen Hofmann, Rainer Moors, Hansjoerg Schaech, Rainer Bueschl, Rudolf H. Jung
  • Patent number: 5219935
    Abstract: A composition universally usable as an impact modifier for synthetic resins comprising(A) from 10 to 80 percent by weight of a polymer of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, R.sub.2 is C.sub.5 -C.sub.7 cycloalkyl or such cycloalkyl substituted by C.sub.1 -C.sub.12 alkyl, y has a value such that the corresponding monomer or monomers are from 5 to 50 percent by weight of polymer (A), and x has a value such that the corresponding monomer, together with up to 20 percent by weight of one or more optional comonomers, is the balance by weight, and(B) from 20 to 90 percent by weight of an optionally crosslinked polymer having a glass transition temperature, T.sub.g, below 10.degree. C. and preferably less than -10.degree. C., polymer (B) being at least partially bonded covalently to polymer (A).
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: June 15, 1993
    Assignee: Rohm GmbH
    Inventors: Werner Siol, Jens-Dieter Fischer, Klaus Koralewski, Ulrich Terbrack
  • Patent number: 5141994
    Abstract: Crystalline polypropylene excellent in rigidity, heat resistance and surface hardness is disclosed, having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) (Mw/Mn) of 10 or more, an intrinsic viscosity [.eta.] of from 0.8 to 5.0 dl/g as measured in tetralin at 135.degree. C., a cold xylene-soluble content (CXS) of not more than 4% by weight, a density (d) of 0.910 g/cm.sup.3 or more as measured at 23.degree. C., and a long period (L) (.ANG.) as measured at 25.degree. C. by a small-angle X-ray scattering method satisfying relationship:L.ltoreq.LC=6667d-5894wherein d is a density at 23.degree. C.; and Lc is a value (.ANG.) obrained by equation:Lc=6667d-5894.A crystalline polypropylene composition containing the foregoing crystalline polypropylene, which is excellent in rigidity and heat resistance, is also disclosed.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: August 25, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Masahiro Kakugo, Hajime Sadatoshi, Jiro Sakai, Kazuki Wakamatsu, Kazuhiro Chikaishi, Toshiro Kojima, Hideo Nomura, Tomohisa Fukao
  • Patent number: 5114638
    Abstract: The present invention relates a process to a process of producing an opacified molded product composed mainly of a polypropylene resin. More particularly, according to the present invention, there is provided a process of producing an opacified stretched molded product having a total light transmittance of 50% of less and a density of 0.89 or less including a composition including 100 parts by weight of polypropylene and 3 to 40 parts by weight of a cyclopentadiene petroleum resin and/or a hydrogeneated cyclopentadiene petroleum resin, the molded product being a product stretched in at least one direction. Also provided are methods of producing a resin composition comprising 100 parts by weight of a crystalline polypropylene and 30 to 40 parts by weight of a copolymer resin comprising a copolymer of a cyclopentadiene compound and an aromatic hydrocarbon or its hydrogenated product, and a stretched molded product thereof.
    Type: Grant
    Filed: May 1, 1991
    Date of Patent: May 19, 1992
    Assignee: Chisso Corporation & Maruzen Petrochemical Co., Ltd.
    Inventors: Takashi Kuroda, Kazuhiro Yamada, Tadao Ishibashi, Suetou Hayashida, Kyoichiro Kimura, Masaru Sameshima
  • Patent number: 5115027
    Abstract: The polypropylene stretched film of the present invention is prepared by stretching a composition comprising a crystalline propylene polymer and 0.1 ppm by weight to 10% by weight of a nucleating agent, the composition having a melting point of 160.degree. C. or more, a crystallization temperature of 128.degree. C. or more and a 20.degree. C. xylene soluble portion of 3.0% by weight or less. The film has a high rigidity and a beautiful appearance as well as the characteristic properties inherent to crystalline propylene polymers. The film can be suitably used for food packaging and textile packaging.
    Type: Grant
    Filed: June 5, 1991
    Date of Patent: May 19, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadatoshi Ogawa, Seiichiro Ima, Kazuki Wakamatsu
  • Patent number: 5110872
    Abstract: Rubber compositions are disclosed which are comprised of a selected rubber made up of ethylene and an .alpha.-olefin and/or an unconjugated diene, and specified amounts of one or more cyclopentadiene resins. The resins are derived by copolymerizing (1) component A with component B, component A being either one or both of a conjugated double bond-containing compound and its Diels-Alder adduct and represented by the formula ##STR1## where H is hydrogen, R is C.sub.1-3 alkyl, m and n each are 0-6, and the sum of m and n is 6, and component B being a component having a carbon double bond and a benzene nucleus, (2) component A with component C having a selected polar group and a carbon double bond, (3) a homopolymer of component A with component C, and (4) component A with component D having one or more selected phenols and their alkyl-substituted derivatives. The resulting composition is highly retentive and tacky on roll mills in an unvulcanized state.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: May 5, 1992
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Makoto Sasaki, Yukio Kobayashi, Shozo Tsuchiya
  • Patent number: 5091477
    Abstract: Molding materials of high impact polystyrene (HIPS) and one or more further polymers as essential components contain, as a third or further compatibility-imparting component, a polymer or copolymer containing not less than 45% by weight of units of cyclohexyl (meth)acrylate.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: February 25, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Bueschl, Peter Klaerner
  • Patent number: 5059487
    Abstract: Disclosed is a hot-melt adhesive composition comprising (a) 20 to 70 parts by weight of a vinyl aromatic compound/conjugated diene copolymer or a hydrogenation product thereof, (b) 30 to 80 parts by weight of an alicyclic hydrocarbon resin tackifier, the total amount of the components (a) and (b) being 100 parts by weight, and (c) 0.3 to 20 parts by weight of a random copolymer of a cyclic olefin and ethylene.
    Type: Grant
    Filed: January 30, 1991
    Date of Patent: October 22, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tsuneaki Muro, Masami Takeda
  • Patent number: 5047481
    Abstract: The invention relates to compatible polymer blends comprised of a polymer component containing cyclohexyl (meth)acrylate as a monomer, and further comprised of a polymer component containing styrene as a monomer.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: September 10, 1991
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack