Polymer Derived From Nitrogen-containing Reactant Patents (Class 525/230)
  • Patent number: 6864314
    Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: March 8, 2005
    Inventors: Dominic Wai-Kwing Yeung, Vance Bergeron, Jean-Francois Bodet, Mark Robert Sivik, Bernard William Kluesener, William Michael Scheper
  • Patent number: 6841623
    Abstract: The present invention relates to nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art. The present invention also relates to a process for the manufacture of said nitrile rubber and the use of said nitrile rubber for the manufacture of shaped articles.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: January 11, 2005
    Assignee: Bayer Inc.
    Inventors: Frédéric Guérin, Sharon X. Guo
  • Patent number: 6828385
    Abstract: A process has now been discovered that permits the simultaneous crosslinking and derivation of an, optionally hydrogenated, polymer whose backbone is composed of a conjugated diene, an unsaturated nitrile and an unsaturated carboxylic acid in the presence of a coupling/condensing agent. This permits the preparation of a novel polymeric material that is an optionally hydrogenated polymer of a conjugated diene, an unsaturated nitrile and a derived unsaturated acid. It has also been found that this novel polymeric material has unexpected and valuable properties.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: December 7, 2004
    Assignee: Bayer Inc.
    Inventors: Janet N. Gamlin, Sharon X. Guo
  • Patent number: 6825278
    Abstract: A modified pressure sensitive adhesive (PSA) is produced by polymerizing at least one ethylenically unsaturated monomer to form a base polymer and reacting the base polymer with a modifying polymer comprising units derived from a n-vinyl lactam to thereby produce a modified polymer. The modified polymer can be used to form modified PSAs having improved adhesion properties over PSAs formed from the unmodified base polymer.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: November 30, 2004
    Assignee: Resolution Specialty Materials LLC
    Inventors: Pavel Holub, Edita Moudra, Olga Bernatova, Jiri Horalek, Jiri Havranek
  • Patent number: 6806315
    Abstract: A method for preparing a weatherable thermoplastic resin, having superior weatherability and colorability and a weatherable thermoplastic resin prepared by the method are provided. The method includes preparing a seed by adding a water-soluble initiator to either an aromatic vinyl compound or a (meth)acrylic acid alkyl ester to obtain a first compound and performing polymerization with respect to the first compound; preparing an alkyl acrylate rubber polymer by adding an alkyl acrylate monomer, a first emulsifier of pH about 3 to about 9, and an oil-soluble initiator to the seed to obtain a second compound and performing polymerization with respect to the second compound; and preparing graft copolymer by adding the aromatic vinyl compound, a vinyl cyanide compound, a second emulsifier of pH about 9 to about 13, and the oil-soluble initiator to the alkyl acrylate rubber polymer to obtain a third compound and performing graft copolymerization with respect to the third compound.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: October 19, 2004
    Assignee: LG Chem, Ltd.
    Inventors: Yang-Hyun Shin, Keun-Hoon Yoo, Tae-Bin Ahn, Chan-Hong Lee
  • Patent number: 6803420
    Abstract: An adhesive composition is provided that contains both a hydrophobic phase and a hydrophilic phase, wherein the hydrophobic phase is composed of a crosslinked hydrophobic polymer composition and the hydrophilic phase is a water-absorbent blend of a hydrophilic polymer and a complementary oligomer capable of crosslinking the hydrophilic polymer through hydrogen bonding, ionic bonding, and/or covalent bonding. The composition is useful as a bioadhesive, for affixing drug delivery systems, wound dressings, bandages, cushions, or the like to a body surface such as skin or mucosal tissue.
    Type: Grant
    Filed: May 1, 2002
    Date of Patent: October 12, 2004
    Assignees: Corium International, A.V. Topchiev Institute of Petrochemical Synthsis, Russian Academy of Sciences
    Inventors: Gary W. Cleary, Mikhail M. Feldstein, Valery G. Kulichikhin, Danir F. Bairamov
  • Patent number: 6743520
    Abstract: A primer useful in the preparation of an anti-fouling surface contains (I) a copolymer formed from acrylates, free carboxyl group containing monomer and an aromatic sulfonic acid or salt, an acrylic polymeric resin and a cross-linking agent.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: June 1, 2004
    Assignee: DuPont Teijin Films US Ltd. Partnership
    Inventors: Andrew Street, Allan Lovatt, Jane Constance Campbell, Hikaru Takeuchi, Sumio Wakabayashi, Yasuo Fujieda
  • Patent number: 6689838
    Abstract: The invention relates to a molding composition comprising, based on the total of components A to G, which is 100% by weight, a) as component A of the molding composition, from 1 to 99,59% by weight of at least one polycondensate, b) as component B, from 0.1 to 20% by weight of at least one particulate graft copolymer with a glass transition temperature of the soft phase below 0° C. and with a median particle size of from 50 to 1000 nm, c) as component C, from 0.1 to 20% by weight of at least one copolymer made from the following monomers c1) as component C1, from 50 to 90% by weight of at least one vinylaromatic monomer, and c2) as component C2, from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, in each case based on component C, d) as component D, from 0 to 20% by weight of a copolymer similar to component C, where the content in % by weight of acrylonitrile and/or methacrylonitrile in component C differs from that in component D, e) as component E, from 0.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: February 10, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Fischer, Walter Rau
  • Patent number: 6669953
    Abstract: Cross-linked block copolymers are disclosed which have drug retention properties, comprising hard and soft segments, with cross-linking between the soft segments. The block copolymers can be based upon (meth)acrylic monomers, and some possess adhesive properties.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: December 30, 2003
    Assignee: Strakan Limited
    Inventor: Fumio Kamiyama
  • Patent number: 6620886
    Abstract: The rubber mixtures according to the present invention comprising uncrosslinked butyl rubbers and nitrile-containing rubber gels as well as optionally, conventional additives and auxiliary substances, are suitable for the production of vulcanizates and molded rubber bodies of all kind having low gas permeability, low weight and acceptable mechanical properties, the mixtures exhibiting good processability.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: September 16, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Obrecht, Anthony Sumner
  • Patent number: 6506840
    Abstract: A process for producing a succinimide resin composition is provided which comprises reacting a maleic anhydride-olefin type copolymer constituted of 40-60 mol % of maleic anhydride units, 60-40 mol % of olefin units, and 0-20 mol % of a copolymerizable monomer units with one or more amine compounds for imide formation in the presence of a second polymer other than the succinimide resin. This process improves the productivity by lowering the torque in the extrusion reaction, giving a succinimide copolymer resin composition having low yellowness and high transparency with high production efficiency.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: January 14, 2003
    Assignee: Tosoh Corporation
    Inventors: Takeshi Harunari, Yoshiki Uchida, Toru Doi
  • Patent number: 6479147
    Abstract: An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: November 12, 2002
    Assignee: Noveon IP Holdings Corp.
    Inventors: Alexander V. Lubnin, Vic Stanislawezyk
  • Publication number: 20020120062
    Abstract: The present invention relates to a thermoplastic resin composition comprising a rubber-reinforced thermoplastic resin (A) obtained by graft polymerizing a monomeric mixture (b) comprising an aromatic vinyl compound, a vinyl cyanide compound and optionally other copolymerizable monomeric compound(s) in the presence of a rubber-like polymer (a),
    Type: Application
    Filed: December 20, 2001
    Publication date: August 29, 2002
    Inventors: Tadashi Nagahara, Masanori Suzuki, Kazuki Iwai
  • Patent number: 6417277
    Abstract: The present invention provides a coating composition which is excellent in a curing property (particularly a low temperature curing property) of a coating film and which forms a coating film having excellent chipping resistance and adhesive property, and it comprises a hydroxyl group-containing resin (A), a cross-linking agent (B) and a phosphoric acid group-containing vinyl resin (C).
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: July 9, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yasuhiro Tomizaki, Akira Kasari
  • Patent number: 6403716
    Abstract: A thermoplastic rubber composition prepared by crosslinking 1-99 parts by weight of a crosslinkable rubbery polymer (A) and 1-99 parts by weight of a polypropylene resin (B) (total amount of (A) and (B) being 100 parts by weight), wherein said (B) comprises a polypropylene resin (B-1) characterized by generation of a torque higher than Mo after melting and a polypropylene resin (B-2) characterized by generation of a torque not higher than Mo after melting, in a melting test of said (B) in the presence of an organic peroxide (temperature condition being at 200° C.), and Mo being a torque right after complete melting.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: June 11, 2002
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Hajime Nishihara
  • Patent number: 6395828
    Abstract: A thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a gloss reducing agent and a process for making the same are disclosed. The gloss reducing agent is the reaction product of (i) a compound having two or more epoxy groups per molecule and (ii) a compound having two or more amine groups per molecule, with the proviso that the total of epoxy groups of (i) and amine groups of (ii) per molecule is greater than 4. The gloss reducing agent may be either incorporated in ASA as the reaction product of (i) and (ii) or, in the alternative, formed upon the reaction of (i) with (ii) in the course of the thermal processing of the a blend containing ASA, (i) and (ii).
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: May 28, 2002
    Assignee: Bayer Corporation
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa
  • Patent number: 6388015
    Abstract: A rubber composition comprising (A) a rubber ingredient comprised of (a) a nitrile group-containing highly saturated copolymer rubber having an iodine value of not larger than 120, preferably a hydrogenated product of an unsaturated nitrile-conjugated diene copolymer rubber, and (b) an acrylic ester polymer rubber, preferably a copolymer rubber comprising at least 80 mol % of alkyl acrylate or alkoxyalkyl acrylate units, at an (a)/(b) ratio of 40/60 to 90/10 by weight, and (B) an ethylene-&agr;-olefin copolymer, the (A)/(B) ratio being in the range of 30/70 to 70/30 by weight. This rubber composition is useful as a covering material for forming a protective covering layer on electric wires.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: May 14, 2002
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yoshiaki Aimura, Manabu Asai
  • Publication number: 20020013416
    Abstract: The present invention provides a mineral filled thermoplastic olefin (MFTPO) composition comprising a polymer mixture, a mineral and a flexural modulus modifying agent and/or a heat deflection temperature modifying agent, and a method for producing the same. The flexural modulus modifying agent and/or a heat deflection temperature modifying agent significantly increases the flexural modulus and/or a heat deflection temperature of the MFTPO without substantially affecting the falling weight impact resistance of the MFTPO relative to a similar MFTPO composition which lacks the flexural modulus modifying agent and/or a heat deflection temperature modifying agent.
    Type: Application
    Filed: June 14, 2001
    Publication date: January 31, 2002
    Inventor: Oscar French Noel
  • Patent number: 6316107
    Abstract: An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: November 13, 2001
    Assignee: PMD Group Inc.
    Inventors: Alexander V. Lubnin, Vic Stanislawczyk
  • Patent number: 6313223
    Abstract: This invention relates to a polymeric composition that can be molded into rubbery articles having excellent oil resistance and excellent heat resistance. The properties of the polymeric composition of this invention are similar to those of hydrogenated nitrile rubber. However, the polymeric compositions of this invention offer a significant economic advantage over traditional hydrogenated nitrile rubbers. This is because the polymeric compositions of this invention are made by blending hydrogenated nitrile rubber with a much less expensive rubbery polymer. Unexpectedly, the physical properties of the polymeric blends of this invention are very similar to those of pure hydrogenated nitrile rubbers.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: November 6, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Michael Kenneth Stockdale
  • Patent number: 6300407
    Abstract: An elastomer composition, including: at least one elastomer; a plasticizer which includes at least one polymeric material having a weighted average molecular weight of (Mw) of 500 to 1,000,000, formed from at least one ethylenically unsaturated monomer, and a curing agent, wherein the at least one polymeric material is substantially permanent within the elastomer. The subject elastomer compositions have enhanced plasticity and processability without attendant migration, heat or solvent extraction and compatibility problems.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: October 9, 2001
    Assignee: Rohm and Haas Company
    Inventors: Warren Harvey Machleder, Robert Howard Gore, David Sterett Moorman, Michael Damian Bowe
  • Patent number: 6277952
    Abstract: Doped polyanilines are prepared by contacting aniline with an oxidizing agent such as ammonium peroxydisulfate in aqueous solution at a temperature of at most about 10° C. in the presence of at least one organic sulfonic acid, preferably an alkylbenzenesulfonic acid such as dodecylbenzenesulfonic acid. The products may be blended with thermoplastic resins such as polystyrene to produce blends having excellent static discharge properties.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: August 21, 2001
    Assignee: General Electric Company
    Inventors: Sundeep Kumar Dhawan, David Ernest Rodrigues
  • Patent number: 6255398
    Abstract: The invention provides thermosetting coating compositions in which acrylic copolymers are used as carriers for fluorocarbon resins. The compositions have a combination of high fluorocarbon content, high solids content, and a low viscosity suitable for coil coating. Thus, the solids are borne in organic solvent systems which permit minimization of the viscosity and a moderate evaporation rate. The solvent system has a &dgr;H of from 1.7 to 2.6 (calories/cubic centimeter)½ and a &dgr;V of from 8 to 9.5 (calories/cubic centimeter)½ and is exemplified by a mixture of 4 or more of the following solvents: aliphatic ketones having from 4 to 10 carbon atoms, alkyl esters having a total of from 5 to 7 carbon atoms, aromatic acid esters having from 8 to 12 carbon atoms, lactones, and aromatic solvents.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: July 3, 2001
    Assignee: BASF Corporation
    Inventors: Joseph J. Zupancic, Jack C. Allman, James V. Lang
  • Patent number: 6245854
    Abstract: A hydrophilic coating composition for hydrophilically coating a metallic surface. The coating composition comprises a fluorocarbon-containing hydrophilic polymer comprising units of hydrophilic monomer and fluorocarbon-containing hydrophobic comonomer. The coating composition produces hydrophilic coatings on the metallic surface having a contact angle below about 50°.
    Type: Grant
    Filed: December 11, 1998
    Date of Patent: June 12, 2001
    Assignee: Visteon Global Technologies, Inc.
    Inventors: Chimere N. Obioha, Riad A. Farah, Dennis Schuetzle, Yun-xiang Zhang
  • Patent number: 6214938
    Abstract: The present invention is a coating composition comprising at least one first water insoluble polymer having a Tg equal to or less than 30° C. and at least one second water insoluble polymer having a Tg equal to or greater than 60° C. wherein the first polymer comprises a monomer at a weight percent of 75 to 100 of the monomer represented by the following formula 1: wherein: X is selected from the group consisting of —Cl, —F, or —CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF3, CH3, C2H5, n—C3H7, iso—C3H7, n—C4H9, n—C5H11, n—C6H13, OCH3, OC2H5, phenyl, C6F5, C6Cl5, CH2Cl, CH2F, Cl, F, CN, CF3, C2F5, n—C3F7, iso—C3F7, OCF3, OC2F5, OC3F7, C(CF3)3, CH2(CF3), CH(CF3)2, COCF3, COC2F5, COCH3, COC2H5; and the second polymer is a microgel particle.
    Type: Grant
    Filed: May 10, 2000
    Date of Patent: April 10, 2001
    Assignee: Eastman Kodak Company
    Inventors: Hwei-Ling Yau, Tienteh Chen, David E. Decker, Stephan L. Twist, Kevin M. O'Connor
  • Patent number: 6194516
    Abstract: A method for producing a hydroxyl-terminated (meth) acrylic polymer which comprises converting a halogen atom in a terminal structure of the general formula (1) —CH2—C(R1)(CO2R2)(X)  (1) wherein R1 is hydrogen or methyl, R2 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 20 carbon atoms or aralkyl containing 7 to 20 carbon atoms, and X is chlorine, bromine or iodine, of a (meth)acrylic polymer obtained by polymerizing a (meth)acrylic monomer using an organic halide or a halogenated sulfonyl compound as an initiator and, as a catalyst, a metal complex with a central metal selected from the elements belonging to the groups 8, 9, 10 and 11 in the periodic table, into a hydroxyl-containing substituent. The present invention can provide, in an easy and simple manner, a (meth)acrylic polymer which is hydroxyl-terminated at both ends in a high proportion and which has been difficult to produce in the prior art. It can give a cured product with good curing characteristics.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: February 27, 2001
    Assignee: Kaneka Corporation
    Inventors: Masato Kusakabe, Kenichi Kitano, Yoshiki Nakagawa
  • Patent number: 6187867
    Abstract: A rubber composition comprising: at least one hydrogenated nitrile rubber, and at least one thermoplastic polyolefin, wherein the weight ratio (hydrogenated nitrile rubber:thermoplastic polyolefin) is in the range from 95:0.5 to 50:50. The composition retains substantially the resistance to heat and chemicals and the mechanical properties characteristic of hydrogenated nitrile rubber upon curing.
    Type: Grant
    Filed: March 26, 1999
    Date of Patent: February 13, 2001
    Assignee: Zeon Chemicals L.P.
    Inventors: Paul Rau, Philippe Milazzo
  • Patent number: 6150450
    Abstract: A plastic composition comprising an acrylonitrile component, a butadiene component and a styrene component, wherein the content of the butadiene component is from 5 to 15 mol %, the content of the acrylonitrile component is from 40 to 50 mol % and the content of the styrene component is from 40 to 50 mol %, said composition having a melt flow index of at least 5 g/10 min (as measured at 260.degree. C. with a force of 2.16 kg in accordance with JIS K7210).
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: November 21, 2000
    Assignee: Mitsubishi Plastics, Inc.
    Inventors: Masayoshi Sekiyama, Tetsuya Yamaoka, Nobuyasu Suzuki
  • Patent number: 6114442
    Abstract: Disclosed is a chemical and heat-resistant styrene-based resin composition which uses the following as the primary resin: (A) a graft copolymer of a diene rubber component and at least two compounds selected from vinyl compounds, cyanide vinyl compounds, and maleic anhydrides; (B) a graft copolymer of an alkyl acrylate rubber component and at least two compounds selected from aromatic vinyl compounds, cyanide vinyl compounds, and maleic anhydride compounds; (C) a copolymer of styrene and a cyanide vinyl compound; (D) a copolymer of styrene, .alpha.-methylstyrene, and a cyanide vinyl compound; and (E) a copolymer of styrene, a cyanide vinyl compound, and a maleimide compound. An oil component, a lubricant, a thermal stabilizer, and an antioxidant are added at suitable ratios to the above primary resin.
    Type: Grant
    Filed: August 28, 1998
    Date of Patent: September 5, 2000
    Assignee: Hyundai Motor Company
    Inventor: Soon-joon Jung
  • Patent number: 6100338
    Abstract: The present invention is directed to particulate carriers useful as drug carries in a drug delivery system (DDS) and to pharmaceutical compositions making use of such carriers. The invention is characterized by the use, as the particulate carrier, of: graft copolymer (A) whose graft chain is poly N-alkylacrylamide chain, poly N-alkylmethacrylamide chain, etc.; and composition containing a combination of the graft copolymer (A) and at least one graft copolymer selected from the group consisting of graft copolymers (B-1) having polyacrylic acid or polymethacrylic acid as the graft chain and graft copolymers (B-2) having a polyvinyl amine compound as the graft chain.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: August 8, 2000
    Assignee: Daiichi Pharmaceutical Co., Ltd.
    Inventors: Mitsuru Akashi, Akio Kishida, Shinji Sakuma, Hiroshi Kikuchi
  • Patent number: 6087453
    Abstract: This invention provides a vulcanizable rubber composition comprising (a) 100 parts by weight of a nitrile-containing highly saturated copolymer rubber obtained by hydrogenating the conjugated diene portions of an unsaturated nitrile-conjugated diene-unsaturated carboxylic acid ester copolymer, (b) 10 to 100 parts by weight of a metallic salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, (c) 0.1 to 30 parts by weight of an organic peroxide vulcanizing agent, and optionally (d) 0.5 to 30 parts by weight of a compound of a group 2A metal in the periodic table. The vulcanized product of this composition is useful as a seal for Freons because it is excellent in low-temperature resistance and resistance to Freon gas permeation and has resistance to the production of cracks in the rubber surface due to the foaming of Freon gas.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: July 11, 2000
    Assignee: Nippon Zeon Co., Ltd.
    Inventor: Koichi Nishimura
  • Patent number: 6040025
    Abstract: The present invention is directed to a multilayer material having in order a layer of fluorinated polymer, a layer of binder for fluorinated polymer having a polymer A with moieties (1)-(4), and a layer of polymer which is incompatible with the fluorinated polymer. The multilayer material is useful for making a pipe which has a superior barrier properties to petroleum products and the additives thereof. The present invention also relates to a pipe having a multilayer structure having two layers of polyamide and a layer of binder comprising a polymer A with glutarimide moieties (1)-(4) in between. The pipe has superior barrier properties to petroleum products and the additives.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: March 21, 2000
    Assignee: Elf Atochem S.A.
    Inventor: Serge Lorek
  • Patent number: 5969042
    Abstract: Thermoplastic molding materials contain a mixture of(A) a methacrylate polymer,(B) a copolymer of vinylaromatic monomers and vinyl cyanide,(C) a graft copolymer comprising a core and a graft shell and(D) a further graft copolymer comprising a core and a graft shell,the average particle size (d.sub.50)-C of the graft copolymer (C) being from 25 to 60 nm and that of the graft copolymer (D) being from 90 to 300 nm and the ratio of the average particle size (d.sub.50)-C to (d.sub.50)-D being kept in the range from 2:1 to 5:1.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: October 19, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Kristin Tiefensee, Norbert Guntherberg
  • Patent number: 5942578
    Abstract: An energy beam curable pressure sensitive adhesive composition is disclosed which comprises at least two energy beam curable copolymers having energy beam polymerizable groups in side chains thereof. This energy beam curable pressure sensitive adhesive composition has satisfactory adhesive strength before the irradiation with energy beam and can be cured by the irradiation with energy beam to a degree such that the amount of adhesive residue remaining on an adherend after peeling is extremely small. Further, the above composition ensures excellent expansibility at the expanding step and excellent recognition at the time of pickup. Still further, the above composition exhibits high work efficiency because of very low pickup strength at the bonding step, irrespective of the execution of the expanding step.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: August 24, 1999
    Assignee: Lintec Corp.
    Inventors: Hayato Noguchi, Takeshi Kondoh
  • Patent number: 5856389
    Abstract: A solid thermoplastic filler-filled surfacing material having a deep semi-translucent appearance, in the form of a thin, rigid sheet contains 19-25% polymethyl methacrylate, 19-25% styrene acrylonitrile copolymer, 5-20% styrene maleic anhydride copolymer, and 30-60% finely divided filler of barium sulfate, kaolin, basic aluminum oxalate and/or wollastonite.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: January 5, 1999
    Assignee: International Paper
    Inventors: Witold Kostrzewski, Leonard Elbon, Robin D. O'Dell, Eric Franzoi
  • Patent number: 5853900
    Abstract: Paper coating slips contain an emulsion copolymer, comprising overallfrom 0 to 60% by weight of a vinylaromatic,from 40 to 95% by weight of a C.sub.1 -C.sub.10 -alkyl (meth)acrylate,from 5 to 40% by weight of an alkenylnitrile,from 0 to 10% by weight of an ethylenically unsaturated acid andfrom 0 to 20% by weight of further monomersas a binder, wherein the emulsion copolymer is a mixture of at least two polymers or an emulsion copolymer comprising at least two stages, one polymer or one stage whose content in the emulsion copolymer is from 10 to 75% by weight containing at least 90% by weight of the total amount of alkenylnitrile (alkenylnitrile-rich polymer or stage).
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: December 29, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard Schuler, Elmar Schwarzenbach, Jurgen Hartmann, Chung-Ji Tschang
  • Patent number: 5849862
    Abstract: Processes for spray drying water-soluble and water-swellable vinyl-addition polymer-containing dispersions, emulsions and microemulsions to obtain substantially dry water-soluble or water-swellable polymer particles, compositions of substantially dry water-soluble or water-swellable polymer particles, methods of agglomerating spray-dried polymer particles, and methods of using spray-dried polymer particles and agglomerates in water-treating, mining, paper, food processing, soil conditioning, solution thickening, biotechnological, and oil recovery applications are disclosed.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: December 15, 1998
    Assignee: Cytec Technology Corp.
    Inventors: William Bloor Davies, John Edward Healy, Gary Kaui Lani Miller, Joseph J. Kozakiewicz
  • Patent number: 5840829
    Abstract: An adhesive is provided for bonding cyanate ester composite parts together which is also plateable with metal once chemically etched. The adhesive comprises a polymeric matrix and a filler of cyanate ester polymer. The polymeric matrix comprises at least one polyepoxide resin and a curing agent, while the cyanate ester polymer filler is present in the adhesive as a powder. In practice, the present adhesive is applied to the surface of cyanate ester composite articles to be bonded and is allowed to cure at room temperature. Thereafter, the surface of the assembly is chemically etched and then plated with metal. The present adhesive enable the complete coverage of the cyanate ester composite assembly with the plated metal, including the adhesive bondlines.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: November 24, 1998
    Assignee: Hughes Electronics Corporation
    Inventors: Ralph D. Hermansen, Brian M. Punsly, Wai-Cheng Seetoo
  • Patent number: 5795939
    Abstract: This invention provides an adhesion binder for binding fluorinated polymers, for example PVDF, with incompatible polymers such as polyamides. The binder is a polymer A which has glutarimide, acid, anhydric and acrylate units, and is useful for the production of fuel hoses. When mixed with a fluorinated polymer such as PVDF, copolymer A acts both as a binder and as a barrier.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: August 18, 1998
    Assignee: Elf Atochem S.A.
    Inventor: Serge Lorek
  • Patent number: 5780581
    Abstract: An adhesive is provided for bonding cyanate ester composite parts together which is also plateable with metal once chemically etched. The adhesive comprises a polymeric matrix and a filler of cyanate ester polymer. The polymeric matrix comprises at least one polyepoxide resin and a curing agent, while the cyanate ester polymer filler is present in the adhesive as a powder. In practice, the present adhesive is applied to the surface of cyanate ester composite articles to be bonded and is allowed to cure at room temperature. Thereafter, the surface of the assembly is chemically etched and then plated with metal. The present adhesive enable the complete coverage of the cyanate ester composite assembly with the plated metal, including the adhesive bondlines.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: July 14, 1998
    Assignee: Hughes Aircraft Company
    Inventors: Ralph D. Hermansen, Brian M. Punsly, Wai-Cheng Seetoo
  • Patent number: 5741860
    Abstract: A thermoplastic resin composition is disclosed, which comprizes 5-55 weight % of a copolymer (A) whose glass transition temperature is not more than 0.degree. C., and 95-45 weight % of a high .alpha.-methylstyrene-content ABS resin (B) and/or a maleimide-type ABS resin (C), both (B) and (C) being not less than 100.degree. C. in thermal deformation temperature (load 18.6 kg/cm.sup.2), and said resin composition being not less than 10 kg.cm/cm in Izod impact strength (23.degree. C.). The resin composition provides molded articles less deformable at high temperatures, low in impact-induced stress, i.e, high in impact energy absorptivity, and thus is suitable for trim parts for use in interior decoration of automobiles.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: April 21, 1998
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shigemi Matsumoto, Akinaga Goda
  • Patent number: 5731377
    Abstract: A polymer blend useful as a binder in an aqueous coating composition containing no coalescent is provided. The polymer blend comprises from about 20 to about 60 weight percent of a hard emulsion polymer, having a glass transition temperature greater than about room temperature, and from about 80 to about 40 weight percent of a soft emulsion polymer, having a glass transition temperature less than about 15 degrees Centigrade.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: March 24, 1998
    Assignee: Rohm and Haas Company
    Inventor: John Michael Friel
  • Patent number: 5605964
    Abstract: A polymer blend comprising (a) a block copolymer comprising (i) a polystyrene block and (ii) a polydiene block or a hydrogenated polydiene block, said block copolymer (a) being non-maleated; and (b) a polymer comprising a polymerization reaction product of two or more monoethylenically unsaturated monomers in which (i) at least one of the monomers is an acrylic or methacrylic acid ester of a non-tertiary alcohol having 1 to 14 carbon atoms, inclusive, and (ii) at least one of the monomers is a nitrogen-containing monomer and, optionally, (iii) from 1-10 parts, based upon 100 parts of polymer, of a monomer having at least one of carboxylic acid functionality, hydroxy functionality, and epoxy functionality as well as a method of priming a substrate comprising applying the blend to the substrate.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: February 25, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: James D. Groves
  • Patent number: 5589544
    Abstract: The invention relates to a soft thermoplastic elastomeric composition having improved resistance to oil swell and compression set comprising a blend of an engineering thermoplastic resin, a cured rubber concentrate and optionally a compatibilizer and a method for its preparation. The invention further relates to the cured rubber concentrate, a method for its preparation and the use thereof.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: December 31, 1996
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Jacques Horrion
  • Patent number: 5576385
    Abstract: Thermoplastic molding materials containing a mixture of(A) from 15 to 70% by weight of a methacrylate polymer,(B) from 10 to 50% by weight of a copolymer obtained by polymerization of a mixture of(B1) a vinylaromatic monomer and(B2) a vinyl cyanide,(C) from 20 to 50% by weight of a graft copolymer of(C1) 50-80% by weight of a core of(C11) from 50 to 100% by weight of a 1,3-diene and(C12) from 0 to 50% by weight of a vinylaromatic monomer and(C2) 20-50% by weight of a graft shell of(C21) a C.sub.1 -C.sub.8 -alkyl ester of methacrylic or acrylic acid and(C22) a vinylaromatic monomer,with the proviso that the medium particle size (d.sub.50) of the graft copolymer is chosen in the range from 40 to 500 nm, and(D) from 0.5 to 15% by weight of a crosslinked methacrylate polymer.
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: November 19, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Kristin Tiefensee, Norbert G untherberg, Rainer Neumann, Ekkehard Jahns
  • Patent number: 5502108
    Abstract: A repositionable pressure-sensitive adhesive comprising from about 70% to about 99% solid, polymeric, acrylate, inherently tacky, infusible, solvent-insoluble, solvent-dispersible, elastomeric microspheres comprising at least one alkyl acrylate or alkyl methacrylate ester; and at least one polar monomer, and correspondingly, from about 30% to about 1% of a binder copolymer comprising an elastomeric polymeric backbone having pendant therefrom high Tg polymeric moieties.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: March 26, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Spencer F. Silver, Roger W. Leinen, Joaquin Delgado
  • Patent number: 5491192
    Abstract: A non-aqueous dispersion for modifying alkyd-containing coating formulations and a method for manufacturing the non-aqueous dispersion are provided. The non-aqueous dispersion contains from about 10 to about 60 parts by weight of a low molecular weight solution polymer, having a selected glass transition temperature greater than about -10.degree. C., and from about 90 to about 40 parts by weight of a polymer which is insoluble in the non-aqueous medium, and where the soluble polymer is attached to or adsorbed onto the insoluble polymer particles. The non-aqueous dispersion is preferably prepared by dispersion polymerization to form the insoluble polymer in a non-aqueous medium in the presence of the soluble polymer.
    Type: Grant
    Filed: August 28, 1991
    Date of Patent: February 13, 1996
    Assignee: Rohm and Haas Company
    Inventors: Frederick H. Walker, Chao-Jen Chung, Andrew Mercurio
  • Patent number: 5475055
    Abstract: A thermoplastic molding material containing, based on the sum of its constituents A, B and C,A: 70 to 99% by weight of a thermoplastic resin A comprising, based on A,A1: 50 to 100% by weight of a hard matrix A1 comprising, based on A1,A11: 50 to 95% by weight of units of an aromatic vinyl compound or methyl methacrylate or their mixtures (A11) andA12: 5 to 50% by weight of units of acrylonitrile A12;A2: up to 50% by weight of a rubber-elastic particulate graft copolymer A2 comprising, based on A2,A21: 30 to 80% by weight of at least one elastomeric graft base A21 having a median particle size of from 30 to 1000 nm comprising, based on A21,A211: 50 to 100% by weight of units of a 1,3-diene or a C.sub.4 -C.sub.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: December 12, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Deckers, Norbert Guentherberg, Rainer Bueschl, Ekkehard Jahns
  • Patent number: 5362533
    Abstract: A rubber composition including (i) a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value not larger than 120, (ii) an ethylene-propylene copolymer and (iii) a material selected from an ethylene-vinyl acetate copolymer, an acrylic rubber and a halogenated butyl rubber. The rubber composition prodides a vulcanized rubber having an improved constant-elongation fatigue performance, as well as balanced thermal resistance, oil resistance and other properties.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: November 8, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Hideo Fukuda, Hideyoshi Shimoda
  • Patent number: 5342897
    Abstract: Aqueous polymer dispersions containing,I as the disperse phase, a film-forming dispersion polymer andII in the aqueous phase, from 5 to 40% by weight, based on the total dry mass of I and II, of a completely or partially neutralized water-soluble copolymer ofa) from 50 to 80 mol % of an olefinically unsaturated mono- or dicarboxylic acid, of an anhydride of these acids or of a mixture of these monomers,b) from 20 to 50 mol % of a C.sub.3 -C.sub.12 -alkene, of styrene or of a mixture of these monomers andc) from 0 to 10 mol % of further monomers which can be subjected to free radical polymerization,and the powders obtained by spray-drying these polymer dispersions are suitable as binders for water-resistant plastics renders and coatings and as adhesives or adhesive components.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gernot Franzman, Folf Petri, Walter Pitteroff