Abstract: The invention relates to a composition comprising a rubber-modified monovinylaromatic polymer comprising: 70 wt % or more of a monovinylaromatic polymer matrix, from 2 to 12 wt % of at least one rubber, and from 0.1 to 3.4 wt % of metallocene-catalyzed poly-alpha-olefins (mPAO) all based on the total weight of the rubber-modified monovinylaromatic polymer, with the mPAO having a kinematic viscosity of at least 950 mm2/s at 40° C. and at most 2,000 mm2/s at 40° C. as measured according to ISO 3104. The invention also relates to articles made from such composition and to the process to produce said composition and said articles.

Abstract: The purpose of the present invention is to provide a gasket material that is capable of preventing corrosion caused by sulfur element, can be used as a seal part for a product that is easily damaged by corrosion, such as an electronic part, and is capable of forming a tight seal under low surface pressure with a material having low rigidity and inadequate reliability such as to have a blowhole, and that can prevent reduction in bolt axial load without producing plastic flow (setting) under pressure. The purpose is achieved by a gasket material in which a foamed rubber layer having a closed cell structure is formed, via an adhesive layer, on at least one side of a metal plate, wherein the foamed rubber layer comprises a carboxyl group-modified nitrile rubber, the expansion ratio of the foamed rubber layer is 2.0 to 3.0, and the foamed rubber layer is crosslinked with an epoxy compound.

Abstract: In some embodiments, systems and methods according to the presentation use RFID signaling to detect patch cord connections in a patch panel, and also to provide visible indicators to technicians making moves, adds, or changes to patch cord connections. In one embodiment, the present invention includes a series of RFID antennae combined into an antenna array and mounted on an add-on adapter, which in turn may be mounted on corresponding telecommunication equipment.

Abstract: The present invention is directed to a copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diolefin monomer and optionally at least one vinyl aromatic monomer; and a polymeric side-chain bonded exclusively to a terminal end of the backbone chain, the side-chain comprising a polymer derived from a monomer having a hydrogen bond donor moiety and a hydrogen bond acceptor moiety.

Abstract: The present application relates to a rubber composition, preparation method and vulcanized rubber thereof. The rubber composition comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, e.g.

Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.

Abstract: The present invention is directed to a copolymer comprising: a polyisoprene backbone chain with a microstructure comprising grater than 98 percent by weight of cis 1,4 linkages; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer derived from a monomer having a hydrogen bond donor site and a hydrogen bond acceptor site.

Abstract: A rubber-reinforced styrene type resin composition for resin foams, the resin foams having a specific gravity of 0.3 to 0.7 and a ratio of the thickness of a skin layer to the thickness of the resin foam of 0.3 to 20%; the composition comprising: 10 to 99% by weight of a rubber-reinforced styrene type resin (A) which is obtained by bulk polymerization of a rubber polymer and an aromatic vinyl monomer, a vinyl cyanide monomer, and if necessary, another monomer that is copolymerizable with these monomers, a weight average particle diameter of the rubber polymer being 0.7 to 3 ?m, and 1 to 90% by weight of a copolymer (B) which is obtained by copolymerizing an aromatic vinyl monomer, a vinyl cyanide monomer, and if necessary, another monomer that is copolymerizable with these monomers (with the total of the rubber-reinforced styrene type resin (A) and the copolymer (B) being 100% by weight).

Abstract: Disclosed are a method for producing a polymer by a polymerization of a mixture at a temperature of 210° C. or lower, wherein the mixture comprises 0.01 to 35 mol % of a monomer or a polymer thereof which has a piperidine skeleton represented by formula (1), and a molded body thereof. R1 represents a hydrogen atom or a methyl group, X represents an oxygen atom, an imino group, or a specific oxygen atom containing a hydrocarbon group, and R2 and R3 represent a hydrogen atom, a linear alkyl group with C1 to C8, a branched alkyl group with C1 to C8, an alicyclic hydrocarbon with C6 to C8, or an aryl group, wherein R2 and R3 may also form a cyclic structure.

Abstract: The invention relates to a high-molecular-weight, linear, neodymium-catalysed polybutadiene having a high proportion, >95%, of cis-1,4 units having a low proportion, <1%, of 1,2-vinyl content, and also having a small molar-mass-polydispersity index (MPI), characterized in that Mooney viscosity (ML1+4 100° C.) of the polybutadiene is from 70 to 90 and The molar-mass-polydispersity index of the polybutadiene is smaller than 10.

Abstract: The present invention is related to dispersion compositions and asphalt compositions including the dispersion compositions. The dispersion compositions include a microgels dispersed in a continuous oil phase. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof. The asphalt compositions include bitumen, aggregate, and a dispersion composition having a microgels dispersed in oil. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof.

Abstract: The invention relates to a thermoplastic composition comprising at least one thermoplastic matrix; and at least one copolymer obtained by copolymerization of C1-C4 alkyl methacrylate, a C1-C8 alkyl acrylate comonomer, and a styrene monomer. The invention also relates to molded bodies based on said thermoplastic composition.

Abstract: The present application relates to a modified rubber masterbatch and preparation method thereof, rubber composition prepared therewith and vulcanized rubber and preparation method thereof. The modified rubber component comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, have an average particle size of 20-500 nm and a gel content of 60% by weight or higher, and wherein the uncrosslinked rubber is styrene-butadiene rubber. The weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20. The rubber composition comprises a blend of modified rubber component and base rubber, in which the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.

Abstract: The present invention provides an optical pressure-sensitive adhesive sheet excellent in anti-foaming release property in which whitening due to humidification hardly occurs. The invention relates to an optical pressure-sensitive adhesive sheet including a pressure-sensitive adhesive layer formed from a pressure-sensitive adhesive composition including: an acrylic polymer (A) which has a weight average molecular weight of 100,000 to 3,000,000 and is formed from a component including, as essential monomer components, a monomer having a nitrogen atom in a molecule thereof and a monomer having a hydroxyl group in a molecule thereof; and an acrylic polymer (B) having a weight average molecular weight of 1,000 to 30,000.

Abstract: The present invention is directed to a method of making a graft copolymer, comprising the steps of: obtaining a first polymer comprising at least one carbon-carbon double bond, the first polymer derived from at least one monomer, the at least one monomer comprising a conjugated diene monomer; polymerizing a second monomer in the presence of a thiocarbonylthio RAFT chain transfer agent to form a polymer comprising a terminal thiocarbonylthio group; cleaving the terminal thiocarbonylthio group to a thiol group to form the second polymer comprising a terminal thiol group; reacting the second polymer with the first polymer to form a graft copolymer, the graft copolymer comprising a backbone derived from the first polymer and sidechains derived from the second polymer.

Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.

Abstract: A novel vulcanizable composition is provided, based on at least one hydrogenated nitrile rubber, on at least one peroxide, on at least one unsaturated carboxylic acid and/or salts thereof, and also on specific microgels. These vulcanizable compositions can be used to obtain vulcanized products which can in particular be used for drive belts, roll coverings, hoses and cables.

Abstract: The invention relates to functionalized, telechelic polymers synthesized by enzymatic catalysis and methods, and the functionalization of polymers via Michael addition with a lipase catalyst, and the crosslinking of mono- or difunctional (telechelic) polymers made by enzymatic catalysis, such as by using multifunctional coupling agents and enzyme catalysts. Quantitative transesterification of vinyl methacrylate with poly(ethylene glycol), poly(isobutylene) and poly(dimethylsiloxane) was achieved using Candida antarctica lipase B. In addition, methacrylate-functionalized poly(ethylene glycol) monomethyl ether has been successfully coupled to aminoethoxy poly(ethylene glycol) monomethyl ether via Michael addition using Candida antarctica lipase B. Amine-functionalized poly(ethylene glycol)s have also been used for the preparation of poly(ethylene glycol)-based dendrimers and gels through Michael addition of the polymer onto triacryloyl hexahydro-triazine using the same enzyme.

Abstract: A waterborne coating composition contains a film forming binder dispersed in an aqueous carrier; wherein the binder is an admixture including (A) about 40-60% by weight of an acrylic silane polymer derived from a monomer blend including alkyl (meth)acrylate monomers and at least one silane containing alkyl (meth)acrylate monomer; and (B) about 60-40% by weight of a polyurethane/acrylic hybrid dispersion. The composition is useful for plastic and metal substrates.

Abstract: The present invention is generally directed to methods and systems for making thermoformed structural elements and composites, including the use of composites, dissimilar or variable processing materials. The present invention avoids the expense and the technical issues of the present art on how difficult it is to ‘clean’ said ‘dirty’ recycled materials so that they are acceptable to the extrusion process and or the injection mold process. The end products can have the same outward appearance as those products made by the more demanding, more expensive extrusion process and or injection process, but the present invention's end products can be pre-engineered to have significantly, unexpectedly, improved physical and chemical properties.

Abstract: The present invention is directed to a method of increasing the green strength of a rubber composition, comprising the step of combining in the rubber composition, a copolymer comprising: a polymeric backbone chain comprising a diene based elastomer selected from the group consisting of solution polymerized styrene butadiene rubber, emulsion polymerized styrene butadiene rubber, natural polyisoprene rubber, synthetic polyisoprene rubber, and polybutadiene; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer derived from an N-substituted monoalkyl acrylamide.

Abstract: A rubber material of a wiper blade for windshield wipers is described, which comprises a first rubber component of a first polarity and a second rubber component of a second greater polarity. To equalize the first and second polarities, the first rubber component is at least partially replaced by a chemically functionalized derivative.

Abstract: A novel process for reducing the molecular weight of nitrile rubber in the presence of specific catalyst systems containing the metathesis catalyst and also a specific addition of fluorine-containing boron compounds is provided.

Abstract: The invention relates to a high-molecular-weight, linear, neodymium-catalysed polybutadiene having a high proportion, >95%, of cis-1,4 units having a low proportion, <1%, of 1,2-vinyl content, and also having a small molar-mass-polydispersity index (MPI), characterized in that Mooney viscosity (ML1+4100° C.) of the polybutadiene is from 70 to 90 and The molar-mass-polydispersity index of the polybutadiene is smaller than 10.

Abstract: A floor covering including one of a sheet-shaped or plate-shaped matrix made of an elastomeric material. The matrix is provided with particles made of a thermoplastic material, where the elastomeric material of the matrix and the thermoplastic material of the particles each have at least one matching monomer.

Abstract: A reduced cost elastomeric blend suitable for use in vehicle timing belts and other applications constructed with elastomeric portions having a high HNBR concentration. The blends comprise from about 50 to less than 100 phr of HNBR and from about 0.1 to about 50 phr of lower cost diluent unsaturated nitrile rubber with from about 0.1 to about 30 phr of a heat resistant additive, which may be THERBAN HT. The elastomeric blends may be cured with a peroxide/co-agent cure system. The elastomeric blends may be mixed by a Y-mix method to improve ozone resistance. A timing belt constructed of the elastomeric blend is also taught.

Abstract: The present invention is directed to a vulcanizable rubber composition comprising: a diene based elastomer; and a compound of formula I where Q is an n-valent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; X is a divalent polymer group capable of exhibiting a lower critical solution temperature; R is independently a hydrogen atom or a monovalent group of formula (II) where Z is a monovalent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; and n is an integer greater than or equal to 2. The invention is further directed to a rubber composition comprising the reaction product of a diene based elastomer and a compound of formula I, and a pneumatic tire with a tread comprising the rubber composition.

Abstract: Providing an NBR composition substantially free of containment of an insolubilized substance-generating causative substance so as to prevent generation of an insolubilized substance due to extraction by a fuel while which composition is excellent in ozone resistance, ejectability from kneader, and which composition realizes a first compression set and a second compression set which are both 46% or less. An NBR composition including a polymer obtained by mixing an acrylonitrile-butadiene rubber (NBR) with polyvinyl chloride (PVC), wherein the NBR composition is obtained without blending an insolubilized substance-generating causative substance, or, in case of blending, by blending an insolubilized substance-generating causative substance at an upper limit of 0.15 parts by weight or less, into 100 parts by weight of the polymer having a PVC content of 15.70 to 17.50 wt %.

Abstract: Disclosed herein are methods of injection molding at low, substantially constant melt pressures. Embodiments of the disclosed method now make possible a method of injection molding that is more energy—and cost—effective than conventional high-velocity injection molding processes. Embodiments of the disclosed method surprisingly allow for the filling of a mold cavity at low melt pressure without undesirable premature hardening of the thermoplastic material in the mold cavity and without the need for maintaining a constant temperature or heated mold cavity. Heretofore, it would not have been expected that a constant pressure method could be performed at low pressure without such premature hardening of the thermoplastic material when using an unheated mold cavity or cooled mold cavity.

Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties.

Abstract: Vinyl aromatic (co) polymer reinforced with a rubber selected from a linear diene rubber (i) with a solution viscosity lower than 70 cPs; a partially radial diene rubber (ii), with a solution viscosity lower than 70 cPs; a three-chain diene rubber (iii) with a solution viscosity lower than 70 cPs; a blend of linear diene rubbers (i) and radial diene rubbers (iv) in a maximum ratio between them (i)/(iv) of between 99.5/0.5 and 85/15.

Abstract: A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an ?,?-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.

Abstract: The ductility/stiffness balance of a rubber-modified monovinylidene aromatic polymer, e.g., HIPS, is increased without increasing the rubber content of the polymer and/or changing the size of the average rubber particle by a process comprising the step of crosslinking the rubber such that the rubber-modified polymer has an optical crosslink index (OCLI) of <0.5 and an injection molded/compression molded (IM/CM) modulus ratio ?1.3.

Abstract: A thermoplastic composition comprising in combination a polycarbonate, a polycarbonate-polysiloxane copolymer, an impact modifier composition comprising ABS or BABS, a second impact modifier different from BABS or ABS, an aromatic vinyl copolymer, and optionally a gel-type low gloss additive, wherein the 60° gloss of the thermoplastic composition is measured to be less than or equal to 14 GU on 3 millimeter chips having a textured surface when measured according to ASTM D2457, and wherein a molded sample of the thermoplastic composition has a low temperature notched Izod impact at ?40° C. of at least 65 KJ/m2 when measured according to ISO 180/1A is disclosed. The composition has low gloss, high low temperature impact, and a significantly improved balance of properties.

Abstract: A thermoplastic composition comprising in combination a polycarbonate, an impact modifier composition comprising ABS or BABS, a second impact modifier different from BABS or ABS, an aromatic vinyl copolymer, and a gel-type low gloss additive, wherein the 60° gloss of the thermoplastic composition is measured to be less than or equal to 11.3 GU on 3 millimeter chips having a textured surface when measured according to ASTM D2457, and wherein a molded sample of the thermoplastic composition has a low temperature notched Izod impact at ?40° C. of at least 30 KJ/m2 when measured according to ISO 180/1A is disclosed. The composition has low gloss and a significantly improved balance of properties.

Abstract: A multicomponent system is provided, composed of a thermoplastic component and of a rubber component, which comprises at least two different peroxidic crosslinking agents with specific decomposition temperatures, as also is a process for production of rubber-thermoplastic composite mouldings using the multicomponent system, and also the resultant rubber-thermoplastic composite mouldings.

Abstract: A positive electrode for non-aqueous electrolyte battery includes a positive electrode active material layer containing at least a positive electrode active material and a binder and a coating layer containing a polymer provided on the positive electrode active material layer, wherein the polymer has a block chain A composed of a random copolymer containing a repeating unit (I) represented by formula (I) and a repeating unit (II) represented by formula (II) and a block chain B containing a repeating unit (III) represented by formula (III) wherein R1-R3, R4a, R4b, R5-R13 are as defined herein.

Abstract: A backbone modified polymer comprising the reaction product of an elastomeric polymer and a sulfide modifier represented by Formula 1: AS—Y-Zm (Formula 1), and wherein Y is (C12-C100) aralkyl, (C12-C100) aryl, (C12-C100) alkyl, or (C12-C100) dialkylether (alkyl-O-alkyl), and wherein each may be optionally substituted with (C1-C4alkyl, (C1-C4alkoxy, (C7-C16aryl, (C7-C16 aralkyl, nitrile, amine, NO2, alkoxy, or thioalkyl; S is sulfur; A is hydrogen, —(S)p—R1 or -MR2R3R4; Z is —SH, —S-MR5R6R7, —S—(S)p—R8, —NR9R10, —NR11COR12, —O—CO—R13, —NCO, or —COOR14; M is silicon or tin; N is nitrogen; O is oxygen; m is the number one, two or three; p is the number one, two, three, four or five; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14 are the same or different, and are each, independently, selected from hydrogen (H), (C1-C16) alkyl, (C6-C16) aryl, (C7-C16) aralkyl or (C3-C30) tri(hydrocarbyl)silyl, and wherein the hydrocarbyl groups are each independently selected from (C1-C16) alkyl, (C6-C16) aryl, or

Abstract: Aqueous binder compositions for fiber mats include a urea-formaldehyde resin and an aqueous emulsion of a copolymer prepared by polymerization of a monomer mixture including styrene, an alkyl(meth)acrylate, acrylonitrile, and an unsubstituted or substituted acrylamide. Even when used in relatively low concentration, the copolymer provides improved physical properties to the fiber mat. The fiber mats can be used in composite flooring, asphalt roofing shingles, siding, and dry wall.

Abstract: An activated carbon fiber for fabricating a supercapacitor electrode and its precursor material are provided. The precursor material of the activated carbon fiber includes polyacrylonitrile (PAN) and a polymer having formula (I): wherein R1 is cyano, phenyl, acetate, or methoxycarbonyl, R2 is ?R3 is C1-7 alkyl, X is chlorine, bromine, tetrafluoroborate (BF4), hexafluorophosphate (PF6), or NH(SO2CH3)2, and m/n is 1-99/99-1.

Abstract: New branched or star-branched styrene polymeric, telomeric, and monomeric product distributions, their preparation, their use as raw materials for bromination to produce flame retardants, the flame retardants themselves, and their use as flame retardants in various polymeric substrates are described.

Abstract: Novel crosslinkable compositions are provided and are based on thermoplastic polymers and elastomers, these compositions comprising, as crosslinking system, specific organic salts of metal ions. Ionically crosslinked thermoplastic elastomers can be obtained therefrom and have excellent physical properties, high-temperature resistance extending above 150° C., and also oil resistance. They can be used for production of moldings.

Abstract: A composition suitable for use in a packer element for a wellbore includes: a hydrocarbon-swellable polymer, the hydrocarbon-swellable polymer present in the composition in an amount between about 10 and 30 percent by weight; an oil-resistant polymer, the oil-resistant polymer present in the composition in an amount between about 10 and 30 percent by weight; and a hydrocarbon swelling agent, the hydrocarbon swelling agent present in the composition in an amount between about 15 and 60 percent by weight. A composition as described may have a good balance of the swelling properties of the hydrocarbon-swellable polymer and the mechanical properties of the oil-resistant polymer. These properties may be useful in a packer element for a wellbore.

Abstract: This invention relates flame retardant compositions containing low molecular weight brominated anionic, chain transfer, vinyl aromatic polymers, hereinafter “ACTVAP”. The compositions can accommodate high bromine content while still exhibiting a low thermally labile bromine content. The compositions have glass transition temperatures, Tg, that are predictive of acceptable melt flows and heat distortion temperatures (HDT) in HIPS and ABS based formulations substrates. The compositions, are suitable flame retardant candidates for use in thermoplastic formulations, e.g. polystyrene and ABS formulations.

Abstract: The present invention concerns a vulcanizable composition, vulcanized products produced from it, and their use in particular in the production of golf balls or roll coverings.

Abstract: Resin beads having an average particle size of from 0.001 mm to 10 mm and containing a continuous phase and a particulate dispersed phase are described. The continuous phase includes elastomeric polymers; the dispersed phase includes homopolymers and/or copolymers containing repeat units resulting from the polymerization of one or more aryl polymerizable monomers. The unexpanded polymer resin beads can be prepared by dispersing an organic phase containing elastomeric polymers and one or more monomers, into droplets and polymerizing the monomers in the organic droplets in a low shear flow pattern. The beads can be impregnated with blowing agents, expanded and can be used to make molded articles. Resin beads having a continuous phase comprising a nitrile rubber, and a dispersed phase comprising one or more homopolymers and/or copolymers containing repeat units resulting form the polymerization of one or more aryl polymerizable show prolonged retention of blowing agents in unexpanded form.

Abstract: The invention provides a composition that contains at least one specific non-crosslinkable organic medium at least one microgel and at least one thickening agent, a process for the preparation thereof and uses of the compositions.

Abstract: A thermoplastic molding composition having reduced gloss sensitivity and no unpleasant odor is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, using an inorganic radical generating substance and a limited amount of chain transfer agent, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer using an inorganic radical generating substance while the use of a chain transfer agent is excluded. The thermoplastic polymer is a copolymer of a vinyl aromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of unpleasant odor coupled with reduced gloss sensitivity and good mechanical properties.

Abstract: Compositions comprising (a) a monovinylidene aromatic polymer, e.g., HIPS, and (b) an ethylene/alpha-olefin (EAO) copolymer, e.g., an ethylene-propylene copolymer, that satisfies the mathematical relationship: y?20+2.35x in which y is the ethylene content in mole percent (mol %) of the EAO copolymer and x is the Brookfield viscosity in centipoise (cP) at 10O° C. of the EAO copolymer and the viscosity is at least 1 centipoise (cP), exhibit improved environmental stress crack resistance as compared to compositions containing monovinyiidene aromatic polymers but without such an EAO copolymer. The compositions are useful in the manufacture of articles, e.g., refrigerator liners and food packaging, which come in contact with the oils contained in various food stuffs.

Abstract: The present invention relates to nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art. The present invention also relates to a process for the manufacture of said nitrile rubber and the use of said nitrile rubber for the manufacture of shaped articles.