Abstract: A method for making a dry blend for use in the preparation of a friction material, a dry blend per se and dry friction materials is disclosed wherein the components thereof include a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.

Abstract: A method for producing wet processed friction materials are disclosed wherein the components thereof include blends of a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.

Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.

Abstract: A laminate of vulcanizable rubber composition layers, which comprises (i) a vulcanizable fluororubber composition layer comprising a fluororubber and a metal oxide and (ii) a vulcanizable nitrile rubber composition layer consisting essentially of a nitrile rubber, an organic phosphonium salt of the following formula (1), an organic peroxide crosslinking system, and an organic basic vulcanization accelerator: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrocarbyl, and no more than three thereof may be amino or fluoroalkyl; and R.sub.5 is hydrogen or alkyl. A vulcanized laminate made of the vulcanizable rubber composition layers is useful for a fuel hose or a diaphragm.

Abstract: A thermoplastic molding composition which contains (i) a grafted copolymer rubber having a grafted phase of styrene-acrylonitrile phase and a crosslinked (meth)acrylate-acrylonitrile substrate, and (ii) an ungrafted, uncrosslinked SAN having a number average molecular weight of about 20,000 to 100,000 is disclosed. The composition which is further characterized in that it contains no additional grafted copolymer rubber based on crosslinked (meth)acrylate-acrylonitrile substrate and in that the grafted copolymer rubber is present in particulate form where the particles have a monomodal size distribution and a weight average particle size of 0.05 to 0.5 microns exhibits improved mechanical properties.

Abstract: The invention encompasses a new methacrylate resin blend composition, and a method of making the blend composition, having improved solvent craze resistance. The new blend composition contains a methacrylate matrix resin, particles of a single layer polymer, and, optionally, an acrylic multi-layer polymer. Particles of the single layer polymer derived from 50% or more methyl methacrylate, and having weight average molecular weight (Mw) at least 120% of the Mw of the methacrylate matrix resin component of the blend, the particles having a diameter of from 50 to 500 nanometers, have been discovered to confer a solvent craze resistance value to the methacrylate resin blend which is at least twice the solvent craze resistance value of the methacrylate resin absent particles of the single layer polymer. Solvent craze resistance of the blend may be improved by as much as 10-fold or more over the solvent craze resistance of the methacrylate matrix resin alone.

Abstract: A resin composition suitable for a toner, more particularly, a resin composition suitable as a binder for an electrophotographic toner is disclosed.

Abstract: A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.

Abstract: Thermoplastic molding composition, containing: A) 5-95 weight percent of a thermoplastic homo-, co-, or terpolymer of styrene, alpha-methylstyrene, ring-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof; B) 5-95 weight % of a graft polymer of B.1) 5-90 parts by weight of styrene, alpha-methylstyrene, ring-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof on B.2) 95-10 parts by weight of a rubber with a glass transition temperature .ltoreq. 10.degree. C; and C) 0.1-10 parts bye weight per 100 parts by weight of A+B of one or more EPM and/or EPDM rubbers.

Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids and processed into sheet, film, fiber and other objects which exhibit an useful balance of barrier and strength properties.

Abstract: A chloroprene polymer composition containing an .alpha.,.beta.-unsaturated carboxylate polymer having a number average molecular weight of at least 300,000.

Abstract: A pressure-sensitive adhesive composition comprising an ethylene-vinyl chloride polymer containing at least 40% by weight of the polymer of vinyl-acetate to serve as a permanent pressure-sensitive adhesive for bonding front materials to plasticizer vinyl and other substrates.

Abstract: Blends of a polyacrylate elastomer with a partially hydrogenated rubber, when peroxide-cured, provide a product which is excellent in resistance to degradation by heat or contact with oil, and which is particularly suitable for making belts, hoses, gaskets and the like for use in automobile engines.

Abstract: A flame retarding resin composition comprising 100 parts by weight of a specific rubber-reinforced resin, 1-200 parts by weight of a phenol resin, 1-200 parts by weight of an organic phosphorus compound, 1-50 parts by weight of a nitrogen-containing compound, 0-40 parts by weight of an oligomer-type polymer containing a functional group, 0-30 parts by weight of a metal compound, a silicon compound, and/or polytetrafluoroethylene, and 0-300 parts by weight of a styrene-type resin. The composition has high impact resistance, excellent heat resistance, and a superior self-fire-extinguishing characteristic.

Abstract: The invention relates to a soft thermoplastic elastomeric composition having improved resistance to oil swell and compression set comprising a blend of an engineering thermoplastic resin, a cured rubber concentrate and optionally a compatibilizer and a method for its preparation. The invention further relates to the cured rubber concentrate, a method for its preparation and the use thereof.

Abstract: Reduced gloss polycarbonate graft polymer blends are provided by a process which involves compounding styrene-acrylonitrile copolymer in the presence of an electrophilic reagent and preferably an acid to form gels, and then compounding the resultant gels with polycarbonate, a styrene-acrylonitrile copolymer and ABS graft polymer to form reduced gloss PC/ABS/SAN composition. The process limits side reactions during gel formation by preparing the gels first and then compounding the gels with the other resin materials. The blends are useful as molding resins and the gelled acrylonitrile polymer is useful as a gloss reducing additive.

Abstract: A chloroprene polymer composition containing an .alpha.,.beta.-unsaturated carboxylate polymer having a number average molecular weight of at least 300,000.

Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids and processed into sheet, film, fiber and other objects which exhibit an useful balance of barrier and strength properties.

Abstract: This invention is directed to a thermoplastic terpolymer excelling in thermal stability and transparency and possessing high mechanical strength, specifically a thermoplastic copolymer (I) composed of 30 to 70% by weight of (A) an aromatic vinyl compound unit, 4 to 40% by weight of (B) a vinyl cyanide unit, and 26 to 50% by weight of (C) an N-substituted maleimide and characterized by having a narrow distribution of molecular weight divisions of copolymer composition as measured by GPC, having substantially no acetone-insoluble content, possessing a weight average molecular weight in the range of 100,000 to 300,000 and a number average molecular weight in the range of 50,000 to 150,000, and having a residual N-substituted maleimide content of not more than 50 ppm.

Abstract: A rubber composition comprising (i) a nitrile group-containing highly saturated copolymer rubber, which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer, and (ii) an ethylene-.alpha.-olefin-non-conjugated diene copolymer rubber. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and has a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the highly saturated copolymer. rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80.

Abstract: A thermoplastic resin composition comprising (A) 100 parts by weight of a diene rubber-containing styrene resin, (B) from 1 to 50 parts by weight of a vinyl resin-containing acrylic rubber polymer obtained by polymerizing from 1 to 200 parts by weight of at least one vinyl monomer in the presence of 100 parts by weight of an acrylic rubber polymer, and (C) from 0 to 48 parts by weight of a polymer of a vinyl monomer having a weight average molecular weight of at least 200,000, provided that the sum of components (B) and (C) is from 1 to 60 parts by weight.

Abstract: Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.

Abstract: The present invention relates to a novel antioxidant-peroxide compound of Structure A,(Y--[--R--OO--X).sub.x --An].sub.y Ain which the definitions of X, Y, R, An, x, and y are given in the Summary of the Invention section, for example, t-butyl peroxy-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate, processes for producing polymeric compositions of enhanced oxidative stability via initiation of polymerization of ethylenically unsaturated monomers, curing of elastomers and unsaturated polyester resins, modification of polypropylene and other polymers and copolymers, and crosslinking of olefin polymers and copolymers, and the resulting polymers having enhanced oxidative stability.

Abstract: Polymer blends of at least one polar polymer are prepared by admixture with a poly(vinyl alcohol) and a (meth)acrylate copolymer also containing vinyl amide and/or unsaturated acid units. The ternary compositions have attractive processing and performance properties.

Abstract: Heat distortion temperature of polyvinyl chloride compositions can be significantly increased above the heat distortion temperature of uncompounded polyvinyl chloride while good appearance of extruded material is preserved by preblending an imidized acrylic resin having a glass transition temperature above 130.degree. C. with a third polymer melt-processable throughout the temperature range of 150.degree.-300.degree. C. under conditions where a two-phase blend is formed, wherein the third polymer forms the continuous phase and the imidized acrylic resin forms the dispersed phase and then melt-blending the two-phase blend with polyvinyl chloride at a temperature of 150.degree.-220.degree. C. to form a composition in which the imidized acrylic resin forms a substantially homogeneous blend with polyvinyl chloride.

Abstract: Polymeric powder coating compositions featuring improved physical properties including improved impact strength, improved adhesivity and other properties is provided by a polymeric powder coating composition which comprises: (a) polymeric powder coating resin, (b) at least one low molecular weight ethylene copolymer having a degree of saponification of at least 25%, (c) a further constituent selected from the group consisting of catalyzing agents, flow control agents, coloring agents, fillers, processing aids, wherein the weight ratio of (b) to (a) is preferably in the range of 0.01%-20% to 99.99%-80%. The powder coating composition may be applied to articles using conventional techniques. Processes for producing the polymeric powder coating compostiions, and articles comprising the same are also disclosed.

Abstract: A nonflammable injection-molding resin composition. The composition includes a nonflammable resin component containing a low-molecular-weight styrene resin having a high .alpha.-methylstyrene content; a rubbery polymer having grafted thereon a vinyl cyanide and/or alkyl (meth)acrylate monomer and an aromatic vinyl monomer; a low-molecular weight post-chlorinated polyvinyl chloride resin and, optionally, a vinyl chloride resin; and, as a moldability-improving agent, a specific alkyl acrylate resin comprising a vinyl cyanide monomer, an alkyl acrylate monomer and an optional copolymerizable vinyl monomer. The nonflammable resin composition provides injection-molded articles with a good balance of impact strength and non-peeling properly and is excellent in moldability.

Abstract: A polymer blend composition comprising:(a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic .alpha.-olefin homopolymer or interpolymer, or an interpolymer of an .alpha.-olefin and a non-aromatic monomer interpolymerizable therewith;(b) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a homopolymer or interpolymer of monovinylidene aromatic monomers, or an interpolymer of monovinylidene aromatic monomer and a monomer interpolymerizable therewith other than an aliphatic .alpha.-olefin; and(c) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a substantially random interpolymer comprising an .alpha.-olefin and a vinylidene aromatic monomer.

Abstract: A composite vinylidene chloride copolymer composition excellent in processability which comprises a vinylidene chloride copolymer A having a molecular weight of not less than 50,000 and not more than 300,000 and a vinylidene chloride copolymer B having a molecular weight of not less than 5,000 and not more than the smaller one of either 0.8 times the weight average molecular weight of the vinylidene chloride copolymer A or 80,000, and a monolayer film which comprises the composite vinylidene chloride copolymer composition and is excellent in various properties including barrier property, non-extractability by oily foods and high frequency sealability, and is suitable as a barrier packaging material and wrapping film used for ham, sausage and other like foods.

Abstract: A covulcanizable rubber composition including a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value not larger than 120, a chlorinated ethylene-propylene copolymer and a vulcanizer. The composition exhibits an improved processing property when mixed, and provides a vulcanized rubber having an improved constant-elongation fatigue resistance.

Abstract: Rubber-modified, impact-resistant molding materials contain, based on the sum of A, B1 and B2,A: from 70 to 98% by weight of a polymer matrix A formed by free radical polymerization of a mixture of from 60 to 90% by weight of styrene and from 10 to 40% by weight of acrylonitrile,B1: from 1 to 29% by weight of a particulate, first graft copolymer B1 which is distributed in the matrix A and consists of a grafting base of polybutadiene and grafts of a copolymer of styrene and acrylonitrile having a mean particle size of about 100-500 nm, andB2: from 1 to 29% by weight of a particulate, second graft copolymer B2 distributed in the matrix A and consisting of a grafting base of polybutadiene and grafts of a copolymer of styrene and acrylonitrile having a mean particle size of from 600 to 10,000 nm, as obtained if both graft copolymers have been prepared by solution and/or mass polymerization and have been incorporated in the polymer matrix in a conventional manner.

Abstract: This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.

Abstract: The present invention provides grafted polymers that have pendent functional groups on the core of the polymer wherein the core is a polymerized alkylmethacrylate having a number average molecular weight from 500 to 1,000,000. The arms of the grafted polymer comprise anionically polymerized segments that have number average molecular weights from 1,000 to 300,000.

Abstract: Crimped acrylic fibers with a small diameter, a minimum aspect ratio in the 20-50 range, and having a crimp of greater than about 10% so as to enhance the viscosity of polymers, resistance to gravity-induced slumping when applied to vertical surfaces, and mix stability, as well as provide matrix reinforcement and toughness, are adapted to act as improved physical thixotropes in adhesives, sealants, coatings, paints, grouts, building materials and the like.

Abstract: Disclosed is a short fiber-reinforced rubber wherein a fibrilated polyacrylonitrile short fiber is uniformly dispersed in a rubber, and a process for producing the same.

Abstract: Ternary alloys of PVC/CPVC/alloying polymers are disclosed which make use of the unexpected results of interactions between alloying polymers and CPVC and PVC, interactions which result in higher heat distortion temperatures than predictable by linear addition of the properties of the binary blends of PVC/CPVC and PVC/alloying polymer systems. This effect allows replacement of substantial amounts of alloying polymer with a predetermined amount of CPVC without changing substantially HDT or melt viscosity. Such effects allow the use of these ternary alloys in place of binary PVC/alloying polymer systems in injection molding and extrusion applications.

Abstract: A solid state process for modifying polyvinyl alcohol using a Michael-type addition wherein dry polyvinyl alcohol powder is sprayed with a solution of a monomer capable of Michael-type addition in an amount sufficient to swell the polyvinyl alcohol or maintain its swollen state, but not dissolve or form a slurry of the polyvinyl alcohol. The swollen polyvinyl alcohol is sprayed with a catalyst and the temperature is raised to initiate the reaction between the polyvinyl alcohol and the monomer.

Abstract: A modified polyvinyl alcohol and a solid state process for producing modified polyvinyl alcohol wherein polyvinyl alcohol powder is sprayed with a sufficient amount of a solution of a polymerizable monomer to swell the polyvinyl alcohol powder but not dissolve it or form a slurry. The swollen polyvinyl alcohol powder is sprayed with a free radical source (an initiator) and the temperature is raised to initiate a reaction between polyvinyl alcohol and the polymerizable monomer.

Abstract: Tough transparent thermoplastics blends may be prepared by blending 10 to 99 weight percent of a block copolymer; 0.1 to 1 weight percent of particulate rubber having a particle size from 0.1 to 10 microns; and the balance a clear glassy polymer. These clear polymers are useful in a number of application, particularly for those applications requiring quite high toughness and transparency such as packaging, containers or protective covering.

Abstract: Polymeric fibrids reinforce elastomers to yield well-blended products of high modulus and elongation.

Abstract: The disclosure describes a resin and rubber composition with good heat-shrinkability characteristics. Also described is a resin and/or rubber composition having dispersed therein a metal compound used for heating the composition.

Abstract: A thermoplastic resin composition comprising (A) 45 to 99% by weight of a graft copolymer obtained by special graft polymerization of a monomer (b) such as an aromatic vinyl compound, a methacrylic ester, etc. in the presence of grafted polymer rubber (a), and (B) 55 to 1% by weight of a thermoplastic aromatic polyester resin can yield shaped articles excellent in impact resistance, chemical resistance, etc. with excellent processability.

Abstract: An improved thermoplastic resin composition obtained by subjecting a mixture of at least an engineering plastic and a rubber material containing an .alpha.,.beta.-unsaturated carboxylic acids or their derivatives, to dynamic heat treatment in the presence of a carbon radical inducing agent. The thermoplastic resin composition of the invention excels in thermal resistance, rigidity, impact resistance, and moldability.

Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.

Abstract: Thermoplastic molding compounds comprising three resin components with different molecular weights and two graft rubbers. The thermoplastic molding compounds have high toughness, adequate heat resistance, adjustable surface gloss and excellent thermoplastic processability. The invention also relates to a process for the production of the molding compounds.

Abstract: Thermoplastic molding compounds comprising three resin components with different molecular weights and two graft rubbers. The thermoplastic molding compounds have good toughness, high heat resistance, adjustable surface gloss and good thermoplastic processability. The invention also relates to a process for the production of the molding compounds.

Abstract: This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.

Abstract: An ultra low density polyolefin foam having a density of about 0.6 to about 1.5 pounds per cubic foot comprising a heat-plastified mixture comprising (1) a non-elastomeric olefin polymer resin selected from the group consisting of ethylene homopolymers, non-elastomeric copolymers of ethylene and a copolymerizable monomer, and propylene homopolymers; (2) an elastomer in an amount of about 3 to about 30 wt. parts per 100 wt. parts of said non-elastomeric olefin polymer resin; (3) polystyrene in an amount of about 1 to about 15 wt. parts per 100 wt. parts of said olefin polymer resin; (4) a stability control agent selected from the group consisting of partial esters of long chain fatty acids with polyols, higher alkyl amines, fatty acid amides, and olefinically unsaturated carboxylic acid copolymers, and (5) a hydrocarbon blowing agent having from 1 to 6 carbon atoms and a boiling point between -175.degree. C. and 50.degree. C.

Abstract: A thermoplastic resin composition is prepared by blending 50-95 wt. % of a copolymer (A) of 10-75 wt. % of .alpha.-methyl styrene, 10-60 wt. % of methyl methacrylate, 5-35 wt. % of acrylonitrile and 0-20 wt. % of a monomer copolymerizable therewith; and 5-50 wt. % of a graft copolymer (B) comprising 50-85 wt. parts of a butadiene-based rubber polymer and 15-50 wt. parts of a vinyl monomer graft-polymerized onto the rubber polymer. The butadiene-based rubber polymer includes 50-98 wt. % of butadiene, 2-50 wt. % of an aromatic polycyclic vinyl monomer represented by a formula (I) below and 0-20 wt. % of a monomer copolymerizable therewith: ##STR1## wherein R denotes an optionally substituted biphenylyl or naphthyl group, and R.sub.1 denotes a hydrogen atom or a methyl group.

Abstract: A polymer composition comprising2-50 parts by weight of a fine particles component dispersed in a matrix described later, of (1) a high-nitrile (co)polymer, wherein the proportion of the nitrile polymeric unit (a) is at least 86% by weight based on the total of the high-nitrile (co)polymer, and98-50 parts by weight of a matrix of (2) a low-nitrile copolymer comprising the nitrile polymeric unit (a), the acrylic ester polymeric unit (b) and the aryl vinyl polymeric unit (c), wherein the proportion of the polymeric unit (a) is 50-85 % by weight and the polymeric unit (b) and the polymeric unit (c) occupy the remaining portion.