Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 11958961
    Abstract: A polyethylene homopolymer composition comprises: a first ethylene homopolymer having a density, d1 of from 0.930 to 0.975 g/cm3, a melt index, I21 of from 0.01 to 10 g/10 min, and a molecular weight distribution, Mw/Mn of less than 2.5; and a second ethylene homopolymer having a density, d2 of from 0.945 to 0.980 g/cm3, a melt index, I22 of at least 1.0 g/10 min, and a molecular weight distribution, Mw/Mn of less than 2.5; wherein melt index, I22 of the second ethylene homopolymer is greater than the melt index, I21 of the first ethylene homopolymer. The polyethylene homopolymer compositions which may be nucleated have a weight average molecular weight, Mw of ?75,000, a molecular weight distribution, Mw/Mn of less than 4.0 and may be usefully employed in molding applications, such as, for example, in compression molded closures.
    Type: Grant
    Filed: November 28, 2019
    Date of Patent: April 16, 2024
    Assignee: NOVA Chemicals (International) S.A.
    Inventor: XiaoChuan Wang
  • Patent number: 11958962
    Abstract: A polyethylene homopolymer composition comprises: a first ethylene homopolymer having a density, d1 of from 0.943 to 0.975 g/cm3, a melt index, I21 of from 0.01 to 10 g/10 min, and a molecular weight distribution, Mw/Mn of less than 3.0; and a second ethylene homopolymer having a density, d2 of from 0.950 to 0.985 g/cm3, a melt index, I22 of at least 500 g/10 min, and a molecular weight distribution, Mw/Mn of less than 3.0; wherein the ratio of the melt index, I22 of the second ethylene homopolymer to the melt index, I21 of the first ethylene homopolymer is at least 50. The polyethylene homopolymer compositions which may be nucleated have a weight average molecular weight, Mw of ?75,000, a high load melt index, I21 of at least 200 g/10 min, a molecular weight distribution, Mw/Mn of from 4.0 to 12.0 and may be usefully employed in molding applications, such as, for example, in compression molded closures.
    Type: Grant
    Filed: November 28, 2019
    Date of Patent: April 16, 2024
    Assignee: NOVA Chemicals (International) S.A.
    Inventor: XiaoChuan Wang
  • Patent number: 11951715
    Abstract: The invention relates to a film laminate, including at least one compact decorative layer with a lacquer layer on the upper side and with a foam layer on the underside, where the density of the foam layer is more than 500 kg/m3. The invention further relates to the use of said film laminate for the coating of components for the interior trim of motor vehicles and to interior trim parts of motor vehicles provided with said film laminate. The foam layer is based on a composition which includes from 15 to 60 parts by weight of at least one thermoplastic vulcanizate, from 15 to 35 parts by weight of at least one high melt strength polyolefin, and from 30 to 60 parts by weight of at least one low density polyethylene (LDPE).
    Type: Grant
    Filed: March 19, 2020
    Date of Patent: April 9, 2024
    Assignee: Benecke-Kaliko AG
    Inventors: Joseph Mani, Volker Huelsewede
  • Patent number: 11945889
    Abstract: A bimodal ethylene-co-1-hexene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A blown film consisting essentially of the bimodal ethylene-co-1-hexene copolymer. A method of synthesizing the bimodal ethylene-co-1-hexene copolymer. A method of making the blown film. A manufactured article comprising the bimodal ethylene-co-1-hexene copolymer.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: April 2, 2024
    Assignee: Univation Technologies LLC
    Inventors: Bo Liu, Joel D. Wieliczko, John F. Szul, Daudi A. Abe, Roger L. Kuhlman, Ayush A. Bafna, Timothy R. Lynn
  • Patent number: 11912858
    Abstract: A molded bale of a rubber-like block copolymer, the rubber-like block copolymer containing 5% by mass or more and 95% by mass or less of a polymer block (a) having a content of a vinyl aromatic monomer unit of 22% by mass or less; and 5% by mass or more and 95% by mass or less of a polymer block (b) having a content of a vinyl aromatic monomer unit of 23% by mass or more and less than 50% by mass, in which the rubber-like block copolymer has an iodine value of 10 to 250, an ethylene structure content of 3% by mass or more, and a vinyl aromatic monomer block content of less than 10% by mass.
    Type: Grant
    Filed: July 2, 2021
    Date of Patent: February 27, 2024
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Yoshifumi Araki, Atsushi Yasumoto, Daigo Matsuoka, Yoshihisa Inoue, Tomohiro Kondo
  • Patent number: 11905345
    Abstract: The polyethylene according to the present disclosure has a short relaxation time and a uniform particle size, thereby preparing a chlorinated polyethylene excellent in chlorination productivity and glass transition temperature by reacting with chlorine. And, a PVC composition with improved impact strength may also be prepared by including the same.
    Type: Grant
    Filed: December 10, 2019
    Date of Patent: February 20, 2024
    Assignee: LG Chem, Ltd.
    Inventors: Si Jung Lee, Sun Mi Kim, Cheolhwan Jeong, Yi Young Choi, Bog Ki Hong, Sunghyun Park
  • Patent number: 11904580
    Abstract: The present invention relates to a multilayer blown film including at least one skin layer (A) including a Ziegler Natta catalyzed heterophasic propylene copolymer (HECO) and one inner layer (B) including a metallocene catalyzed propylene based random copolymer (PRC), and optionally one core layer (C) including either a Ziegler Natta catalyzed heterophasic propylene copolymer (HECO) or a metallocene catalyzed propylene based random copolymer (PRC).
    Type: Grant
    Filed: May 14, 2021
    Date of Patent: February 20, 2024
    Assignee: BOREALIS AG
    Inventors: Jingbo Wang, Markus Gahleitner, Klaus Bernreitner, Pauli Leskinen, Peter Niedersuess, Stefan Ortner
  • Patent number: 11904515
    Abstract: Molded-in-color thermoplastic polyolefin (TPO) compositions useful for making automotive components, such as injection molded parts, as well as other articles of manufacture are described. The molded-in-color composition has a ?E* value?2.0 (compared to a painted color master), a gloss measured at 60° from about 76 to about 90 GU, a density ranging from about 0.9 to about 0.97 g/cm3, a melt mass flow rate from about 15 to about 40 g/10 min (ASTM D 1238, 230° C./2.16 kg), a flexural modulus between about 600 to about 2000 MPa, and an as-molded shrinkage between about 0.6% and about 1.4%. The compositions can be used to prepare molded-in-color components that can undergo additional clear coating steps as required by the automotive application. The clear coated molded-in-color components have a gloss measured at 20° from about 85 to about 95 GU and a gloss retention after mar between about 85% and about 93%.
    Type: Grant
    Filed: March 5, 2021
    Date of Patent: February 20, 2024
    Assignee: LyondellBasell Advanced Polymers Inc.
    Inventors: Peter J. Glenister, Quentin R. Boll, Perry J. Banta, Changlai Yang
  • Patent number: 11905400
    Abstract: A polypropylene composition made from or containing: A) from 88.0 wt. % to 98.0 wt. %, of a random copolymer of propylene containing from 0.8 wt. % to 4.8 wt. % of 1-hexene derived units; the random copolymer of propylene having: a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 4.4 g/10 min; and B) from 2.0 wt. % to 12.0 wt. % of a terpolymer of propylene ethylene and 1-hexene having a content of ethylene derived units ranging from 35 wt. % to 60 wt.; and a content of 1-hexene derived units ranging from 1 wt. % to 6 wt. %; wherein the polypropylene composition has a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 5.0 g/10 min.
    Type: Grant
    Filed: September 11, 2019
    Date of Patent: February 20, 2024
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Monica Galvan, Claudio Cavalieri, Thomas Boehm, Roberto Pantaleoni
  • Patent number: 11894575
    Abstract: A crosslinked polyolefin separator having an average value of light transmittance of 30% or more in a region of 380 nm to 700 nm, after four sides of the separator are fixed and allowed to stand at 130° C. for 30 minutes. A method for manufacturing the crosslinked polyolefin separator is also provided. The crosslinked polyolefin separator has a low shutdown temperature to provide improved safety. The crosslinked polyolefin separator also has a high meltdown temperature and is inhibited from die-drooling.
    Type: Grant
    Filed: September 11, 2019
    Date of Patent: February 6, 2024
    Inventors: Won-Sik Bae, Joo-Sung Lee, Bi-Oh Ryu, A-Young Lee
  • Patent number: 11879026
    Abstract: The invention relates to a polypropylene composition comprising a terpolymer containing propylene, ethylene and 1-hexene wherein the polypropylene composition (i) has a content of ethylene derived units of at least 1.5 wt %; (ii) has a content of 1-hexene derived units of at least 1.5 wt %; (iii) has a melt flow rate of 0.10 to 0.70 g/10 min determined by ISO 1133-1:2011 (230° C., 2.16 kg); and (iv) has a ratio of weight average molecular weight (Mw) to numeric average molecular (Mn) weight of the terpolymer of 7.0 to 20.0, wherein Mw and Mn are measured according to ASTM D6474-12.
    Type: Grant
    Filed: July 22, 2019
    Date of Patent: January 23, 2024
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Henrica Norberta Alberta Maria Steenbakkers-Menting, Patrick Elisabeth Luc Voets, Desiree Marie Louise Seegers, Erik Delsman, Ibrahim Mohammad Alsugai, Musaad Al-Sadhan, Martin Alexander Zuideveld, Akhlaq Moman
  • Patent number: 11879080
    Abstract: Disclosed is a hot melt adhesive comprising: (A) a metallocene based propylene homopolymer, (B) a metallocene based ethylene/?-olefin copolymer, (C) a tackifier resin, and (D) a plasticizer, wherein the plasticizer (D) comprises (D1) an oil and (D2) at least one polymer selected from polybutene, polybutadiene, polyisobutylene, and polyisoprene. This hot melt adhesive has an initial adhesive strength enough to enable a pressure sensitive adhesion body to stick easily on a member, thus making it possible to firmly hold the pressure sensitive adhesion body on the member. The hot melt adhesive is also excellent in releasability, thus causing no adhesive residue on the member when the pressure sensitive adhesion body is peeled from the member.
    Type: Grant
    Filed: December 19, 2019
    Date of Patent: January 23, 2024
    Assignee: HENKEL AG & CO. KGaA
    Inventors: Atsushi Kakuda, Naohiro Maeda
  • Patent number: 11873377
    Abstract: A blown film having a bimodal ethylene-based polymer including a high density fraction (HDF) from 3.0% to 25.0%, an I10/I2 ratio from 5.5 to 7.5, a short chain branching distribution (SCBD) less than or equal to 10 C, a zero shear viscosity ratio from 1.0 to 2.5, a density from 0.902 g/cc to 0.925 g/cc, and a melt index (I2) from 0.5 g/10 mins to 2.0 g/10 mins.
    Type: Grant
    Filed: June 13, 2019
    Date of Patent: January 16, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Kyle E. Hart, Mehmet Demirors, Timothy W. Gambrel, Philip P. Fontaine, Vivek Kalihari, Francis O. Olajide, Jr., Rajen M. Patel
  • Patent number: 11873393
    Abstract: A bimodal ethylene-based polymer, including a high density fraction (HDF) from 3.0% to 25.0%, wherein the high density fraction is measured by crystallization elution fractionation (CEF) integration at temperatures from 93° C. to 119° C., an I10/I2 ratio from 5.5 to 7.5, wherein I2 is the melt index when measured according to ASTM D 1238 at a load of 2.16 kg and temperature of 190° C. and I10 is the melt index when measured according to ASTM D 1238 at a load of 10 kg and temperature of 190° C., and a short chain branching distribution (SCBD) less than or equal to 10° C., wherein the short chain branching distribution is measured by CEF full width at half height.
    Type: Grant
    Filed: June 13, 2019
    Date of Patent: January 16, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Kyle E. Hart, Mehmet Demirors, Timothy W. Gambrel, Philip P. Fontaine, Pradeep Jain
  • Patent number: 11834534
    Abstract: A propylene ethylene copolymer having the following features: an ethylene content of between 1.0 and 4.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: (C2×1.1)+1.25<XS<(C2×1.1)+2.50 where: XS=% by weight of the fraction soluble in xylene at 25° C.; C2=% by weight of ethylene units in the copolymer determined via NMR; a melt flow rate (MFR; 230° C., 2.16 kg) of between 30 to 75 g/10 min; an intrinsic viscosity of the copolymer of lower than 1.5 dl/g; and an intrinsic viscosity of the fraction soluble in xylene at 25° C. of higher than 0.32 dl/g.
    Type: Grant
    Filed: August 12, 2019
    Date of Patent: December 5, 2023
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gianpiero Ferraro, Gianni Vitale, Fabrizio Piemontesi, Benedetta Gaddi, Gianni Collina, Giampiero Morini, Caroline Cathelin, Marco Ciarafoni, Claudio Cavalieri
  • Patent number: 11827777
    Abstract: The present invention is directed to a polypropylene composition (P) comprising a first random propylene copolymer (A) and a second random propylene copolymer (B), said first random propylene copolymer (A) and said second random propylene copolymer (B) being copolymers of propylene and 1-hexene. Further, the present invention is directed to a blown film comprising said polypropylene composition (P).
    Type: Grant
    Filed: September 9, 2019
    Date of Patent: November 28, 2023
    Assignee: Borealis AG
    Inventors: Jingbo Wang, Markus Gahleitner, Klaus Bernreitner, Pauli Leskinen, Peter Niedersüss
  • Patent number: 11827758
    Abstract: The present invention is directed to an article comprising a fiber reinforced composition (C), said composition comprising a propylene polymer (PP), an elastomeric ethylene copolymer (E) and fibers (F).
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: November 28, 2023
    Assignee: Borealis AG
    Inventors: Michael Jerabek, Wolfgang Stockreiter, Thomas Lummerstorfer
  • Patent number: 11795309
    Abstract: In an embodiment, the present disclosure provides a composition composed of (A) a continuous phase composed of an olefin-based polymer, and (B) particles of a voiding agent dispersed in the continuous phase, the voiding agent composed of a functionalized styrene polymer having a glass transition temperature greater than or equal to 90° C. In another embodiment, the present disclosure provides an oriented article having (A) a continuous phase composed of an olefin-based polymer, and (B) particles of a voiding agent dispersed in the continuous phase. The voiding agent is composed of a functionalized styrene polymer having a glass transition temperature greater than or equal to 90° C. The oriented article includes (C) a plurality of elongated voids dispersed throughout the continuous phase. The oriented article has a density less than 0.9 g/cc.
    Type: Grant
    Filed: February 3, 2022
    Date of Patent: October 24, 2023
    Assignee: VOID Technologies Limited
    Inventors: Andrew Dennis Burton, Adam William Mix, Ryan James McEneany
  • Patent number: 11795338
    Abstract: An example of a build material composition for three-dimensional (3D) printing includes a polymeric or polymeric composite build material and a wetting modifying agent. The wetting modifying agent is: (i) incorporated into the polymeric component of the polymeric or polymeric composite build material and changes the wetting behavior of the polymeric component; or (ii) selected from the group consisting of: a fluorotelomer; a C8-C20 alcohol; a methyltrialkyl ammonium chloride; docusate sodium salt; a polymer having a chemical structure of the polymeric component of the polymeric or polymeric composite build material modified to include a hydrophobic group or a hydrophilic group; and a combination thereof.
    Type: Grant
    Filed: January 26, 2018
    Date of Patent: October 24, 2023
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Sterling Chaffins, Anthony P. Holden, Katrina Donovan, Garry Hinch
  • Patent number: 11773243
    Abstract: Provided is an ethylene-based modifier with which a film having good slipperiness and relatively less fish eyes can be formed. The ethylene-based modifier has a strain-hardening exponent of 0.27 or more and 0.53 or less as determined by the LAOS method.
    Type: Grant
    Filed: July 6, 2022
    Date of Patent: October 3, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Chen Liu, Takaya Ichimiya
  • Patent number: 11767385
    Abstract: A bimodal ethylene-co-1-butene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A (blown) film consisting essentially of the bimodal ethylene-co-1-butene copolymer and having improved properties. Methods of synthesizing the bimodal ethylene-co-1-butene copolymer and making the blown film. A manufactured article comprising the bimodal ethylene-co-1-butene copolymer.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: September 26, 2023
    Assignee: UNIVATION TECHNOLOGIES LLC
    Inventors: Bo Liu, Chuan He, Daudi A. Abe, Roger L. Kuhlman, Ayush A. Bafna, Timothy R. Lynn
  • Patent number: 11752706
    Abstract: The present invention relates to a method for manufacturing a textile/thermoplastic resin composite part, comprising the following steps: (a) providing a mould; (b) applying at least one composition (A) comprising at least one thermoplastic resin; (c) heating the mould; (d) applying the textile to the heated thermoplastic resin; (e) cooling the mould; (f) unmoulding.
    Type: Grant
    Filed: May 17, 2018
    Date of Patent: September 12, 2023
    Assignee: IVY GROUP HOLDING
    Inventors: Mustapha El Fouzari, Nicolas Amouroux
  • Patent number: 11746224
    Abstract: The present invention is directed to a heterophasic polypropylene composition with improved sterilization resistance and optical properties for blow molding applications, in particular for use in the blow-fill-seal process for preparing bottles. The present invention is further directed to a process for producing such a polypropylene composition using a single-site catalyst and to a container produced from such a polypropylene composition by blow molding, like a bottle, in particular a blow-fill-seal bottle, with improved haze before and after sterilization. The polypropylene composition comprises a blend of a propylene copolymer comprising 2.5 to 12.0 wt % of 1-hexene as a comonomer, and having a melt flow rate MFR2 of 0.5 to 20.0 g/10 min, and an ethylene homo- or copolymer having a melt flow rate MFR2 of 0.05 to 30.0 g/10 min and a density of 850 to 940 kg/m3, wherein the xylene cold solubles (XCS) content of the polypropylene composition is from 5.0 to 30.0 wt %.
    Type: Grant
    Filed: May 7, 2019
    Date of Patent: September 5, 2023
    Assignee: BOREALIS AG
    Inventors: Markus Gahleitner, Jingbo Wang, Klaus Bernreitner, Pauli Leskinen, Johanna Lilja
  • Patent number: 11746221
    Abstract: Provided is a thermoplastic elastomer composition obtained by melt-kneading (A) an ethylene/?-olefin/non-conjugated polyene copolymer rubber that is a copolymer of ethylene, an ?-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, (B) a polyolefin resin and (C) a mineral oil-based softening agent in the presence of (D) a crosslinking agent, at least part of the ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) being crosslinked, the thermoplastic elastomer composition having a sea-island structure in which the ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) is dispersed as a dispersed phase (island phase) in a continuous phase (sea phase) of the polyolefin resin (B), and when a cross-section of the composition is observed with an atomic force microscope (AFM), a ratio of (b) a local elastic modulus of the continuous phase to (a) a local elastic modulus of the dispersed phase being from 10 to 30.
    Type: Grant
    Filed: July 15, 2022
    Date of Patent: September 5, 2023
    Assignee: ENEOS Materials Corporation
    Inventors: Masato Kobayashi, Ryoji Usui, Yuki Sato, Osamu Kose
  • Patent number: 11738334
    Abstract: This invention relates to a supported catalyst system comprising: (i) at least one first catalyst component comprising a group 4 bis(phenolate) complex; (ii) at least one second catalyst component comprising a 2,6-bis(imino)pyridyl iron complex; (iii) activator; and (iv) support. The catalyst system may be used for preparing polyolefins, such a bimodal polyethylene, typically in a gas phase polymerization.
    Type: Grant
    Filed: February 2, 2021
    Date of Patent: August 29, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Matthew W. Holtcamp, Dongming Li, Kevin A. Stevens, Jo Ann M. Canich, John R. Hagadorn, Ramyaa Mathialagan, Timothy M. Boller
  • Patent number: 11739868
    Abstract: A female fitting includes a tube having an end that includes an upset for receiving a male fitting, the upset having an outer circumference and an inwardly extending groove extending around the outer circumference for receiving a clamp or portion of a clamp and the upset having an end face and inner surface, the upset having an undercut between the end face and inner surface for receiving a flange of the male fitting. A male fitting includes a tube having an end part; and a transition between the tube and the end part, the transition comprising a flange extending radially outward from the tube and a radiused corner connecting the flange to the end part.
    Type: Grant
    Filed: April 9, 2021
    Date of Patent: August 29, 2023
    Assignee: Vac Safe Solutions Ltd.
    Inventors: Clint Scott Van Berkel, Chris Aron Wood, Ricardo Januario
  • Patent number: 11718740
    Abstract: Provided is a method for producing a thermoplastic elastomer composition that can form a molded article having both good appearance and high stiffness. The method for producing a thermoplastic elastomer composition comprises the following first step and second step, wherein the produced thermoplastic elastomer composition contains 5 mass % or less of a mineral oil (C): first step: a step of melt-kneading polypropylene (A-1) and an ethylene-based copolymer rubber (B) in the presence of an organic peroxide, the polypropylene (A-1) being polypropylene of which 20° C. xylene insoluble fraction has an intrinsic viscosity [?cxis] of 0.1 dl/g or more and less than 1.5 dl/g; and second step: a step of further adding polypropylene (A-2) of which 20° C. xylene insoluble fraction has an intrinsic viscosity [?cxis] of 1.5 dl/g or more and 7 dl/g or less, and melt-kneading the resulting mixture.
    Type: Grant
    Filed: August 24, 2022
    Date of Patent: August 8, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Shinichiro Shimomura
  • Patent number: 11718738
    Abstract: The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, and particularly a small amount of vinylidene among the unsaturated functional groups, thereby showing excellent physical properties.
    Type: Grant
    Filed: May 3, 2019
    Date of Patent: August 8, 2023
    Inventors: Jung Ho Jun, Eun Jung Lee, Jin Sam Gong, Rae Keun Gwak, Tae Su Kim
  • Patent number: 11718693
    Abstract: The present invention provides an ethylene/alpha-olefin copolymer having narrow molecular weight distribution together with a low density and an ultra low molecular weight, having minimized number of unsaturated functional groups, and having uniform crystallinity, thereby showing excellent physical properties, and a method for preparing the same.
    Type: Grant
    Filed: May 3, 2019
    Date of Patent: August 8, 2023
    Inventors: Rae Keun Gwak, Seung Hwan Jung, Jin Sam Gong, Jung Ho Jun, Choong Hoon Lee, Eun Jung Lee, Hyun Jin Ju, In Sung Park, Sang Eun Park
  • Patent number: 11708483
    Abstract: In an embodiment, a heat-seal film includes 10-90 wt % of a first polymer component and 10-90 wt % of a second polymer component, based on a total weight of the first polymer component and the second polymer component, wherein: the first polymer component includes propylene, and optionally, up to 18 wt % of a C2 and/or a C4-C20 ?-olefin based on a total weight of the first polymer component; and the second polymer component includes 91-99.9 wt % of propylene and 0.1-9 wt % of ethylene based on a total weight of the second polymer component, the second copolymer component having a melt flow rate of 2-60 g/10 min. In another embodiment, a multi-layer film structure includes a heat-seal layer including a heat-seal film described herein; and an unoriented, an uniaxially oriented, or a biaxially oriented base layer including polypropylene homopolymer, a polypropylene random copolymer, or a combination thereof.
    Type: Grant
    Filed: March 23, 2020
    Date of Patent: July 25, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Saifudin M. Abubakar, Jie Yu Jin, Yong Xuan See
  • Patent number: 11708484
    Abstract: A polyolefin composition made from or containing: T1) 70-95 wt %, a polyolefin component containing: a1) from 30 wt % to 70 wt % of a propylene based polymer; and a2) from 30 wt % to 70 wt % of an ethylene based polymer; the sum of a1) and a2), being referred to the total weight of a1) and a2), being 100; and T2) 5-30 wt % of a propylene ethylene copolymer containing from 2.0 wt % to 10.0 wt %; of ethylene derived units and having a melt flow rate (230° C./2.16 kg) ranging from 0.5 to 20.0 g/10 min, and having a fraction soluble in xylene at 25° C. lower than 20 wt %. the sum of the amount of T1) and T2), being referred to the total weight of T1) and T2), being 100.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: July 25, 2023
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberto De Palo, Claudio Cavalieri
  • Patent number: 11697725
    Abstract: An earth plant-based compostable biodegradable composition for the formation of a bioplastic and method of producing said resin, the composition comprising: about 17.5 to 45% ethanol-based green polyethylene by weight, about 20 to 25% calcium carbonate by weight, about 2 to 12% hemp hurd or soy protein by weight, about 32 to 45% starch by weight, and about 0.5 to 1% biodegradation additive by weight to enable biodegradation and composting of the bioplastic; wherein the composition is produced by first mill grinding the ethanol-based green polyethylene, calcium carbonate, hemp hurd or soy protein, starch and the biodegradation additive into fine powders, then mechanically mixing the fine powders one by one into a final mixture for about 5-25 minutes at a time, dry and without heat, and then heating the final mixture to about 220 to 430 degrees Fahrenheit.
    Type: Grant
    Filed: August 1, 2022
    Date of Patent: July 11, 2023
    Inventor: Edward Showalter
  • Patent number: 11690932
    Abstract: Multilayer thermoplastic films, and laminates and articles comprising the films, wherein the film comprises at least one inner layer and at least two outer layers, wherein the inner layer comprises a polymeric composition comprising from about 55% to about 95% of one or more non-hydrogenated styrenic block copolymers, olefinic block copolymers, or combinations thereof; and each outer layer comprises at least 20% polypropylene and has a thickness of from about 5% to about 15% of the total film thickness, and further wherein the film has a constant force tear propagation of about 20% or less.
    Type: Grant
    Filed: August 26, 2021
    Date of Patent: July 4, 2023
    Assignee: Berry Film Products Company, Inc.
    Inventor: Iyad Muslet
  • Patent number: 11680160
    Abstract: Disclosed are a polyolefin resin composition and a production method using same. The polyolefin resin satisfies the following conditions: (1) melt index (MI2.16, 190° C., under a load of 2.16 kg) is 0.1 to 1.5 g/10 min; (2) density is 0.91 to 0.93 g/cc; (3) polydispersity Index (Mw (weight-average molecular weight)/Mn (number-average molecular weight)) is 3 to 7; (4) Mz (Z-average molecular weight)/Mw (weight-average molecular weight) is 2.3 to 4.5; and (5) COI(Comonomer Orthogonal Index) value calculated by Equation 1 in the specification is 5 to 12. In Equation 1, “SCB number at Mz” represents average number of branches derived from comonomers per 1000 carbon atoms at Z-average molecular weight (Mz), and “SCB number at Mn” represents average number of branches derived from comonomers per 1000 carbon atoms at number-average molecular weight (Mn) based on a molecular weight-comonomer distribution graph.
    Type: Grant
    Filed: April 2, 2019
    Date of Patent: June 20, 2023
    Assignee: DL CHEMICAL CO., LTD.
    Inventors: Jang Woo Lee, Byung Keel Sohn, Sah Mun Hong, Da Jung Kim, Hee Jun Lee, Sung Ho Choi, Su Hyun Park
  • Patent number: 11674023
    Abstract: A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.
    Type: Grant
    Filed: October 15, 2020
    Date of Patent: June 13, 2023
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Youlu Yu, Eric D. Schwerdtfeger, Jeffrey S. Fodor, David A. Soules
  • Patent number: 11661501
    Abstract: Bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability. The compositions comprise a base resin having a density of about 945 kg/m3 to about 955 kg/m3, and an ethylene polymer (A) having a density of at least about 968 kg/m3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A). The composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to 450 kPa·s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to 2500 Pa·s. Articles made from these compositions, such as pipes and fittings achieve long-term oxidative resistance and have a low wall thickness variability while maintaining high production output.
    Type: Grant
    Filed: September 28, 2020
    Date of Patent: May 30, 2023
    Assignee: INEOS OLEFINS & POLYMERS USA, A DIVISION OF INEOS USA LLC
    Inventors: Joshua Allen Cottle, Mark Anthony Gessner, Robert Ernest Sander, Luc Dheur
  • Patent number: 11661470
    Abstract: Butadiene-isoprene diblock copolymer formed by a block of crystalline polybutadiene (hard block) and by a block of amorphous polyisoprene (soft block). Said butadiene-isoprene diblock copolymer can be advantageously used both in the footwear industry (for example, in the production of shoe soles), and in the production of tires for motor vehicles and/or trucks.
    Type: Grant
    Filed: May 30, 2018
    Date of Patent: May 30, 2023
    Assignee: Versalis S.p.A.
    Inventors: Anna Sommazzi, Giovanni Ricci, Francesco Masi, Giuseppe Leone
  • Patent number: 11649331
    Abstract: Provided herein are polyethylene films made of the polyethylene blends having improved properties, particularly in Elmendorf tear and puncture resistance. The polyethylene blends include two primary polyethylene blends.
    Type: Grant
    Filed: November 13, 2019
    Date of Patent: May 16, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ching-Tai Lue, Dongming Li, Hasnain Rangwalla, Matthew F. Yott
  • Patent number: 11643530
    Abstract: Embodiments relate to polyolefin compositions containing one or more high-density polyethylenes (HDPEs) and linear low-density polyethylenes (LLDPEs) and methods for forming the same. The polyolefin composition contains about 40 wt % to about 60 wt % of HDPE and about 40 wt % to about 60 wt % of LLDPE, by weight of the polyolefin composition. The HDPE has a density of greater than 0.93 g/cm3 and a melt index of about 0.2 dg/min to about 10 dg/min. The LLDPE has a density of less than 0.915 g/cm3 and a melt index of about 0.2 dg/min to about 10 dg/min. The polyolefin composition has a density of about 0.91 g/cm3 or greater, a melt index of about 0.5 dg/min to about 6 dg/min, and a Tw1?Tw2 value of about ?25° C. or less.
    Type: Grant
    Filed: April 12, 2021
    Date of Patent: May 9, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Dongming Li, Ching-Tai Lue, Qingyun Qian, Ling Ge, Gang Huang
  • Patent number: 11634571
    Abstract: The present invention is directed to a polypropylene composition (C) comprising a heterophasic propylene copolymer (RAHECO) and a plastomer (PL) as well as a process for the preparation of said polypropylene composition and a film obtained from said polypropylene composition (C).
    Type: Grant
    Filed: April 20, 2021
    Date of Patent: April 25, 2023
    Assignee: Borealis AG
    Inventors: Markus Gahleitner, Jingbo Wang, Carl-Gustaf Ek, Klaus Bernreitner
  • Patent number: 11613634
    Abstract: An encapsulant film is made from a composition comprising (A) a non-polar ethylene-based polymer; (B) an organic peroxide; (C) a silane coupling agent; and (D) a co-agent comprising a compound of Structure I wherein R1-R6 each is independently selected from the group consisting of hydrogen, a C1-C8 hydrocarbyl group, a C1-C36 substituted hydrocarbyl group, and combinations thereof.
    Type: Grant
    Filed: May 31, 2017
    Date of Patent: March 28, 2023
    Assignee: Dow Global Technologies LLC
    Inventors: Hong Yang, Weiming Ma, Yonghua Gong, Lisa S. Madenjian, Yabin Sun, Yuyan Li, Brian M. Habersberger
  • Patent number: 11612524
    Abstract: A breathable thermoplastic polymer film may be produced and adapted for use as a breathable diaper backsheet. The film may include a blend of LLDPE, mLLDPE and calcium carbonate, and may have improved tear strength and melt strength such that instances of tears or break offs during the machine direction orientation portion of the production process are significantly reduced or eliminated. In addition, the film may have sufficient tear strength to permit omission of CDI processing needed to strengthen weaker prior art films. In this regard, undesired streaking of colors or printed aspects of the film may be reduced or avoided completely.
    Type: Grant
    Filed: February 19, 2020
    Date of Patent: March 28, 2023
    Assignee: COLORMASTERS, LLC
    Inventor: Robert Estill Chambliss
  • Patent number: 11603460
    Abstract: Crosslinkable insulation materials, which are commonly halogen-free, for use in wire and cable applications are provided. The insulation include a crosslinkable thermoplastic polymer and flame retardant material. The flame retardant material may include a metal hydroxide flame retardant, such as a magnesium, calcium, zinc and/or aluminum hydroxide. The crosslinkable thermoplastic polymer includes silane-grafted polymer blend, which includes a polyolefin plastomer blended with one or more other thermoplastic polymers. The crosslinkable thermoplastic polymer may be curable by exposure to moisture and may include moisture curable silane functionality in the crosslinkable thermoplastic polymer.
    Type: Grant
    Filed: August 3, 2016
    Date of Patent: March 14, 2023
    Assignee: AEI Compounds Ltd.
    Inventor: Mike Edward Slevin
  • Patent number: 11591459
    Abstract: A thermoplastic elastomer composition contains component (A-2), component (B), and component (C). The content of component (A-2) is 5 parts by weight or more and 95 parts by weight or less with respect to 100 parts by weight of the total amounts of components (A-2) and (B), and the content of component (C) is 0.005% by weight or more and 3% by weight or less with respect to 100% by weight of the whole amount of the thermoplastic elastomer composition. Component (A-2) is a crosslinked product of component (A-1), which is an ethylene copolymer containing a monomer unit derived from propylene and/or ?-olefins having 4 to 10 carbon atoms, and a monomer unit derived from ethylene, and having a Mooney viscosity (ML1+4, 125° C.) of 50 or more. Component (B) is a propylene polymer and component (C) is an antifungal agent.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: February 28, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Katsuya Kida
  • Patent number: 11535011
    Abstract: Multi-layer films for making bags for containing flowable materials, in particular to large bags for dairy products. The multi-layer films have an outer and an inner sealant layer and a core layer and optionally, an interposed layer positioned between the outer sealant layer and the core layer and between the core layer and the inner sealant layer. The outer and inner sealant layers contain an ethylene/?-olefin interpolymer composition and the intermediate layer optionally contains this interpolymer composition.
    Type: Grant
    Filed: June 18, 2018
    Date of Patent: December 27, 2022
    Assignee: Liqui-Box Corporation
    Inventor: Nicholas Farkas
  • Patent number: 11505685
    Abstract: Disclosed is a polypropylene with an MFR of at least 20 g/10 min comprising a homopolypropylene and within a range from 2 wt % to 20 wt % of a propylene-?-olefin copolymer by weight of the polypropylene, where the homopolypropylene has a MFR within a range from 30 g/10 min to 200 g/10 min, where the propylene-?-olefin copolymer comprises within a range from 30 wt % to 50 wt % ?-olefin derived units by weight of the propylene-?-olefin copolymer, and has an IV within a range from 4 to 9 dL/g. The polypropylene may be obtained by combining a Ziegler-Natta catalyst having two transition metals with propylene in reactors in series to produce the homopolypropylene followed by a gas phase reactor to produce a propylene-?-olefin copolymer blended with the homopolypropylene.
    Type: Grant
    Filed: April 11, 2018
    Date of Patent: November 22, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Todd S. Edwards, Christopher G. Bauch
  • Patent number: 11505701
    Abstract: The present disclosure relates to polymer resins, fibers, and yarns with permanent antimicrobial activity, and a method of producing the same. In one embodiment, the antimicrobial polymer resin comprises a polymer having less than 2500 ppm of zinc dispersed within the polymer, less than 1000 ppm of phosphorus, wherein the weight ratio of zinc to phosphorus is at least 1.3:1 or less than 0.64:1.
    Type: Grant
    Filed: July 12, 2019
    Date of Patent: November 22, 2022
    Assignee: Ascend Performance Materials Operations LLC
    Inventors: Scott E. Osborn, Wai-Shing Yung
  • Patent number: 11505725
    Abstract: The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, uniform crystallinity, thereby showing excellent physical properties.
    Type: Grant
    Filed: May 3, 2019
    Date of Patent: November 22, 2022
    Inventors: Rae Keun Gwak, Eun Jung Lee, Jin Sam Gong, Jung Ho Jun, Tae Su Kim
  • Patent number: 11499027
    Abstract: The present invention can provide a fiber-reinforced expanded particle molded article having a reinforcing material fused and integrated with the surface of an expanded molded article, wherein the reinforcing material is a fabric or a braided product produced by weaving a linear composite material produced by melting and integrating a thermoplastic fiber comprising a low-melting component fiber and a high-melting component fiber, as two or more threads selected from the group consisting of a warp, a weft and a slant thread, the fiber-reinforced expanded particle molded article exhibiting an excellent reinforcing effect; and a method for economically producing the molded article by in-mold molding with a small number of steps.
    Type: Grant
    Filed: February 27, 2018
    Date of Patent: November 15, 2022
    Assignee: UBE EXSYMO CO., LTD.
    Inventor: Masahiko Yokokita
  • Patent number: 11492430
    Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.
    Type: Grant
    Filed: February 3, 2022
    Date of Patent: November 8, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius