Ethylenic Reactant Contains Nitrogen Heterocycle, E.g., Pyridine, Diazines, Etc. Patents (Class 525/279)
  • Patent number: 6914100
    Abstract: A crosslinked polymer particle can be obtained by carrying out a crosslinking reaction between a non-crosslinked polymer particle containing a succinimidoxycarbonyl group and a compound having two or more amino groups.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: July 5, 2005
    Assignee: Fuji Xerox, Co., Ltd.
    Inventors: Chisato Urano, Yoshihiro Inaba, Masato Mikami, Takako Kobayashi
  • Patent number: 6874885
    Abstract: This invention is directed to a processing approach for the rapid and efficient in-situ polymerization of specially prepared precursor mixtures to achieve near-net-shape production of objects/articles with exact dimensions. The process relies on the use of polymerizable compositions comprised of a mixture of a dead polymer, a reactive plasticizer and, optionally, an initiator, which compositions are semi-solid-like prior to curing and induce low shrinkage upon curing as a result of their partially polymerized nature prior to processing. The partially polymerized nature of the precursor mixtures also allows extremely impact-resistant objects/articles to be fabricated. Other desirable engineering property attributes can similarly be achieved via the judicious blending of starting ingredients in formulating the polymerizable (curable) mixtures.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: April 5, 2005
    Assignee: ZMS, LLC
    Inventors: David S. Soane, Michael R. Houston, Toshiaki Hino
  • Patent number: 6852803
    Abstract: A polymer dispersant for pigments based on a graft copolymer which contains a new type of urea functional group as the pigment anchoring group. The urea groups are attached to the graft copolymer by a convenient method which involves reaction of hydroxyl functional groups built in the graft copolymer with a diisocyanate that is capped at one end with ammonia or a primary or secondary amine. The reaction is convenient and clean. Substantial crosslinking or gelling of the polymer can be easily avoided by judicious selection of appropriate ingredients and processing conditions. These materials are effective in dispersing and stabilizing a wide range of pigments in solvent based systems and are particularly useful in forming pigment dispersions that are used in a variety of solvent borne coating compositions for automobiles and trucks, where they provide improved efficiency of pigment use, lower paint viscosity, and reduced emission of volatile organic solvent.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: February 8, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sheau-Hwa Ma
  • Publication number: 20040220346
    Abstract: A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.
    Type: Application
    Filed: March 11, 2004
    Publication date: November 4, 2004
    Inventors: Hideyuki Kaneko, Tomoaki Matsugi, Shin-ichi Kojoh, Shingo Matsuo, Nobuo Kawahara, Norio Kashiwa
  • Patent number: 6803447
    Abstract: The invention relates to the synthesis of polymers containing self-complementary quadruple hydrogen groups by copolymerizing monomers containing a quadruple hydrogen bonding group with one or more monomers of choice. The resulting polymers show unique new characteristics due to the presence of additional physical interactions between the polymer chains that are based on multiple hydrogen bonding interactions (supramolecular interactions).
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: October 12, 2004
    Assignee: Eutechpark MMP1.28
    Inventors: Henricus Marie Janssen, Gaby Maria Leonarda Van Gemert, Aafke Tessa Ten Cate, Dimphna Johanna Maria Van Beek, Rintje Pieter Sijbesma, Egbert Willem Meijer, Anton Willem Bosman
  • Patent number: 6759481
    Abstract: A shape memory polymer which is a reaction product of styrene, a vinyl compound, a multifunctional crosslinking agent and an initiator. The shape memory polymer has particular application as a contact lens mold.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: July 6, 2004
    Inventor: Tat Hung Tong
  • Patent number: 6750298
    Abstract: The invention generally concerns a novel family of biocompatible surfactant copolymers having a wide range of uses, in particular in pharmaceutics and for synthesizing substances in dispersed state and for surface treatment of materials or biomaterials. Said copolymers are characterised in that they comprise a hydrophobic sequence constituted by: either a homopolymer consisting of recurrent units corresponding to the general formula (I): in which: R1 represents a C1-C6 alkyl group or a (CH2)m—COOR3 group wherein m is an integer between 1 and 5 and R3 represents a C1-C6 alkyl group; R2 represents a C1-C6 alkyl group; and n is an integer between 1 and 5; or a random copolymer consisting of different recurring units corresponding to formula (I) as defined above; or finally a random copolymer consisting for the major part of units corresponding to formula (I) as defined above.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: June 15, 2004
    Assignee: Virsol
    Inventors: Nicole Bru-Magniez, Virginie Larras, GĂ©rard Riess, Pascal Breton, Patrick Couvreur, Claude Roques-Carmes
  • Patent number: 6723796
    Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: April 20, 2004
    Assignee: Castrol Limited
    Inventors: Irwin L. Goldblatt, Richard P Sauer
  • Patent number: 6699939
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 2, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6686321
    Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: February 3, 2004
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 6669815
    Abstract: There is provided a treating agent for a sheet surface comprising a graft copolymer composed of a back bone polymer and branch polymer, either of which is a polymer having vinyl alcohol units, and the other of which is a polymer having cationic groups, the treating agent is applied onto a pulp sheet or plastic sheet, and the coated sheet is used in ink jet printing. Cationic groups are introduced by graft copolymerization using di(meth)allylamine-based and/or (meth)acryl-based monomer. Alternatively, the graft copolymer of the present invention is obtained by grafting N-vinylcarboxylic acid amide monomer followed by hydrolysis thereof. A formula weight ratio of vinylalcohol units and the introduced cationic groups of 1:20 to 2:1 is preferable in terms of balanced performance.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: December 30, 2003
    Assignee: Hymo Corporation
    Inventors: Toshiaki Sugiyama, Motosuke Ono, Osamu Kamada
  • Patent number: 6652440
    Abstract: Provided is an electroactive organic polymer, which polymer comprises conductive polymer segments and non-conductive polymer segments, having one or more of these polymer segments bonded to polysulfide chains, and wherein the polysulfide chains comprise one or more moieties selected from the group consisting of —(Sm)—, —(Sm)−, and (Sm)2−, where m is an integer from 3 to 200 and is the same or different at each occurrence. Also provided are composite cathodes comprising such polymers, electrochemical cells comprising such cathodes, and methods of making such polymers, composite cathodes, and cells.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: November 25, 2003
    Assignee: Moltech Corporation
    Inventors: Igor P. Kovalev, Vadim V. Annenkov, Steven A. Carlson, Boris A. Trofimov
  • Patent number: 6632889
    Abstract: A method of forming a branched polymer includes forming a plurality of growing linear polymer chains by polymerizing a monomer which is protected against branching and which forms a reactive end group which is in a first condition which is one of electrophilic or nucleophilic, exposing the growing linear polymer chains to a chain transfer agent to cause the reactive end group of at least a first growing linear polymer chain to reverse its electrophilic or nucleophilic character, whereby a non-reversed reactive end group on a second growing linear polymer chain reacts with the reversed reactive end group on the first growing linear polymer chain to create a branched polymer and reverses the electrophilic or nucleophilic character of the reversed reactive end group back to its first condition, whereby it may continue adding monomer in a linear fashion; and quenching the polymerization by adding a compound having multiple reactive sites capable of reacting with the reactive end groups of the polymer chains when
    Type: Grant
    Filed: August 2, 1999
    Date of Patent: October 14, 2003
    Inventors: Rui Yin, Donald A. Tomalia, Dujie Qin, Jamie Dunham
  • Patent number: 6630554
    Abstract: (1) A methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of a conjugated diene compound and an organic alkali metal compound, in the presence of a tertiary organoaluminum compound having in the molecule thereof a chemical structure represented by a formula: Al—O—Ar wherein Ar represents an aromatic ring; or (2) a methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of an organic alkali metal compound and a compound having a 1,1-diaryl-1-alkene structure, by adding the ester in the form of a mixture with the above-mentioned specific tertiary organoaluminum compound to the polymerization system.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: October 7, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenichi Hamada, Kazushige Ishiura, Toru Takahashi, Sachie Yaginuma, Makoto Akai, Tomohiro Ono, Kenji Shachi
  • Publication number: 20030165779
    Abstract: Infra-red absorbing polymers useful in imageable products and the lithographic printing field comprise infra-red absorbing groups carried as pendent groups on a polymer backbone. Certain infra-red absorbing groups may also act to insolublize the polymer in a developer, until it is imagewise exposed to infra-red radiation. The resulting heat renders the polymer soluble in the developer. Imageable products employing the infra-red absorbing polymers may include positive working lithographic printing plates.
    Type: Application
    Filed: December 30, 2002
    Publication date: September 4, 2003
    Applicant: KODAK POLYCHROME GRAPHICS, LLC
    Inventors: Eduard Kottmair, Hans-Horst Glatt, Stefan Hilgart, Paul West
  • Publication number: 20030087982
    Abstract: A method of modifying a polymeric material which comprises the steps of activation-treatment and a hydrophilic polymer-treatment, or comprises the steps of activation-treatment, a hydrophilic polymer-treatment, and monomer grafting in this order, or comprises the step of a solvent-treatment followed by these steps. Thus, the polymeric material, e.g., polyolefin, is improved in hydrophilicity, adhesion, etc. without lowering the practical strength thereof The polymeric material thus improved in adhesion and other properties can be used in many applications where water absorption and adhesion are required, such as an absorption material, e.g., a wiping/cleansing material, a water retention material, a material for microorganism culture media, a separator for batteries (or cells), a synthetic paper, a filter medium, a textile product for clothing, a medical/sanitary/cosmetic supply, and reinforcing fibers for composite materials.
    Type: Application
    Filed: August 27, 2001
    Publication date: May 8, 2003
    Inventor: Hitoshi Kanazawa
  • Patent number: 6555028
    Abstract: Described are polymeric matrix compatibilized naphthopyran compounds, examples of which are certain 2H-naphtho[1,2-b]pyrans, 3H-naphtho[2,1-b]pyrans and indeno[2,1-f]naphtho[1,2-b]pyrans each having at least one substituent containing terminal and/or pendant groups selected from hydroxyl, carboxyl, sulfo, sulfono, (meth)acryloxy, 2-(methacryloxy)ethylcarbamyl, epoxy or a mixture thereof. Specific substituents are also present on the naphtho, indeno and/or pyrano portions of the compounds. These compounds may be represented by the following graphic formulae: Also described are various substrates that contain or that are coated with such compounds. Optically clear articles such as contact lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, are also described.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: April 29, 2003
    Assignee: Transitions Optical, Inc.
    Inventors: Robert W. Walters, Barry Van Gemert
  • Patent number: 6552130
    Abstract: A resin composition comprising (A) a (meth)acrylic acid ester (B) and an acrylic polymer soluble in the component (A) and further (C) a compound having a mercapto group (—SH) and a carboxyl group (—COOH) in the molecule or an component (C) and (F) an organic amine or an component (F) and (G) a radical trapping agent. The composition is suitably used as a covering material for civil engineering and construction applications.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: April 22, 2003
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Takayuki Makino, Toshio Takemoto
  • Patent number: 6521715
    Abstract: A polymer dispersant for pigments based on an acrylic graft copolymer wherein the graft copolymer has a weight average molecular weight of 3,000-100,000 and comprises a polymeric backbone and macromonomer side chains attached to the backbone, wherein (1) the polymeric backbone is formed of polymerized ethylenically unsaturated monomers and (2) the side chains are macromonomers that are attached to the backbone at a single terminal point and are formed from polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 1,000-30,000 wherein the graft copolymer contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized ethylenically unsaturated monomers containing acetoacetate groups that are polymerized into the backbone, side chains, or both, and the acetoacetate groups are reacted with a primary amine to form a pendant acetoacetyl amine group on the graft copolymer which serves as the pigment anchoring group.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: February 18, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sheau-Hwa Ma
  • Publication number: 20030032746
    Abstract: Hetero-telechelic polymers having the formula:
    Type: Application
    Filed: June 21, 2002
    Publication date: February 13, 2003
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6512054
    Abstract: Methods for preparing free radical or visible light curable (VLC) acid-containing polymers in an aqueous solution are provided. In one embodiment, the method comprises reacting polymers having reactive carboxylic acid groups with a methacrylated oxazoline or oxazine, collectively referred to hereafter as “methacrylated unsaturated cyclic imino ethers,” in an aqueous solution at a temperature of from about 50° C. to about 75° C. In another embodiment, the method comprises an additional step of preparing the carboxylic acid-containing polymer in an aqueous solution and then reacting the carboxylic acid-containing polymer with the methacrylated cyclic imino ether in the aqueous solution. The present invention also relates to free radical or VLC acid-containing polymers, and dental restoratives that comprise such polymers. Methods of attaching an oxazoline or oxazine to a carboxylate group on a polymer in an aqueous solution are also provided.
    Type: Grant
    Filed: January 17, 2001
    Date of Patent: January 28, 2003
    Assignee: The Ohio State University Research Foundation
    Inventors: Bill M. Culbertson, Scott R. Schricker
  • Publication number: 20020193529
    Abstract: Melt-processable thermally crosslinkable compositions comprising:
    Type: Application
    Filed: March 17, 2000
    Publication date: December 19, 2002
    Inventors: Julio A. Abusleme, Giambattista Besana, Giandomenico Vita
  • Patent number: 6495618
    Abstract: A polymer dispersant for pigments based on a graft copolymer wherein the graft copolymer has a weight average molecular weight of at least 3000 and has 10 to 90% by weight of a polymeric backbone and 90 to 10% by weight of macromonomer side chains attached to the backbone and wherein at least 20% by weight of the polymeric backbone has attached thereto an amide group which serves as a pigment anchoring group. The backbone may also have attached thereto an additional pigment anchoring group selected from the group consisting of aromatic ester, aromatic amine, aliphatic amine, and quaternary ammonium groups, or mixtures thereof. These materials disperse a wide variety of pigments and are useful in solvent borne coatings where they can provide improved efficiency of pigment use, lower paint viscosity, and reduced emission of volatile organic solvent.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: December 17, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sheau-Hwa Ma
  • Publication number: 20020183456
    Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.
    Type: Application
    Filed: March 11, 2002
    Publication date: December 5, 2002
    Applicant: Castrol Limited
    Inventors: Irwin L. Goldblatt, Richard P. Sauer
  • Patent number: 6476150
    Abstract: The present invention is related to melt-processable thermally crosslinkable compositions consisting of I) thermoprocessable copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chlorotrifluoroethylene (CTFE), and acrylic monomers of formula CH2═CH—CO—O—R2 (a); and II) one or more crosslinking agents.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: November 5, 2002
    Assignee: Ausimont S.p.A.
    Inventors: Julio A. Abusleme, Giambattista Besana, Giandomenico Vita
  • Patent number: 6472353
    Abstract: Graft copolymers useful as a dispersant-viscosity improver for lubricating oil compositions comprise a hydrocarbon polymer having graft polymerized thereon at least two nitrogen containing units, at least one of the nitrogen containing units being derived from at least one of a neutral N-(lower hydrocarbyl group)- (meth)acrylamide and a neutral N,N-di-(lower hydrocarbyl group)- (meth)acrylamide, wherein the total number of carbon atoms in the lower hydrocarbyl groups does not exceed 9, and at least one of the nitrogen containing units being derived from at least one vinylic nitrogen containing heterocyclic compound.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: October 29, 2002
    Assignee: The Lubrizol Corporation
    Inventors: John C. Smoggie, Richard M. Lange
  • Patent number: 6414089
    Abstract: A method of manufacturing a polymer film having second order non-linear optical properties which has excellent stability of orientated molecules and does not become disorientated, and a polymer film and a non-linear optical element are provided. A polymer solution is placed between two substrates, which are disposed substantially perpendicular with respect to a rotating stand and substantially symmetrical with respect to a rotation axis of the rotating stand, and the rotating stand is rotated. A polymer film having second order non-linear optical properties is formed by the centrifugal force generated at the polymer solution.
    Type: Grant
    Filed: August 29, 2000
    Date of Patent: July 2, 2002
    Assignees: Riken, Japan Science and Technology Corporation
    Inventors: Hiromi Kimura-Suda, Hiroyuki Sasabe, Tatsuo Wada
  • Patent number: 6414102
    Abstract: The invention relates to polyolefin copolymers (I) and to graft copolymers (II) which are prepared from the copolymers (I), wherein the copolymers (I) are linear copolymers containing divinylbenzene comonomer units selected from the group consisting of 1,4-divinylbenzene units, mixtures of 1,4- and 1,3-divinylbenzene units and mixtures of 1,4-, 1,3- and 1,2-divinylbenzene units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independently, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. In the graft copolymer (II), the combined alpha-olefin mole % (x+y) is from about 50 and 99.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: July 2, 2002
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jin Yong Dong
  • Patent number: 6410652
    Abstract: Methods for making graft copolymers include (a) providing (i) an ethylene/propylene 9EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing the EP copolymer or other graftable polymer into an extruder, (c) introducing the monomer into the extruder, (d) introducing the initiator into the extruder, wherein at least one of the reactants employed in step (a) is introduced in the presence of a polar solvent, and (e) reacting the EP copolymer or other graftable polymer, monomer and initiator by operating the extruder, thereby forming the graft copolymer. Methods of making dispersant viscosity index improver and methods for making a lubricating oil, as well as graft copolymers, viscosity index improvers and lubricating oils made by such methods are also contemplated.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: June 25, 2002
    Assignee: Castrol Limited
    Inventors: Irwin L. Goldblatt, Richard P Sauer
  • Publication number: 20020042488
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Application
    Filed: January 10, 2001
    Publication date: April 11, 2002
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Publication number: 20020042349
    Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.
    Type: Application
    Filed: October 9, 2001
    Publication date: April 11, 2002
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 6369163
    Abstract: There is described the use of monomeric and polymeric N-pyrrolidinone-containing compounds as compatibilizers for plastic compositions, a process for improving the compatibility of plastic compositions, the improved plastic compositions obtainable thereby as well as novel polymeric N-pyrrolidinone-containing compounds.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: April 9, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Yefim Blyakhman
  • Patent number: 6367929
    Abstract: A wettable silicone hydrogel made by including a high molecular weight hydrophilic polymer into the silicone hydrogel monomer mix is presented. The hydrophilic polymer is entrapped in the hydrogel with little or no covalent bonding between it and the hydrogel matrix.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: April 9, 2002
    Assignee: Johnson & Johnson Vision Care, Inc.
    Inventors: Annie C. Maiden, Douglas G. Vanderlaan, David C. Turner, Robert N. Love, James D. Ford, Frank F. Molock, Robert B. Steffen, Gregory A. Hill, Azaam Alli, Kevin P. McCabe
  • Publication number: 20020037988
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Application
    Filed: October 10, 2001
    Publication date: March 28, 2002
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Patent number: 6362274
    Abstract: The invention relates to grafted copolymers comprising at least three sequences of distinct chemical nature, among which one or more sequence(s) for anchoring on solid particles, one or more sequence(s) of hydrophobic character and one or more sequence(s) of hydrophilic character. The invention also concerns their process of preparation, the compositions containing them, their use as agent for dispersing, stabilizing solid particles and/or emulsifying in an aqueous and/or organic medium, as well as use thereof for preparing pigmentary dispersions in aqueous and/or organic medium.
    Type: Grant
    Filed: February 23, 1999
    Date of Patent: March 26, 2002
    Assignee: Les Peintures Jefco
    Inventors: Pierre Legrand, Gerard Riess, Jean-Phillipe Lerch, Daniel Lefevre
  • Patent number: 6349753
    Abstract: A tire component comprising a plurality of elastomers, where at least one of said elastomers has a functional group defined by the formula where R1 is selected from the group consisting of a divalent alkylene group, an oxy-alkylene group, an amino alkylene group, and a substituted alkylene group, each group having from about 6 to about 20 carbon atoms, and R2 is covalently bonded to the elastomer and is selected from the group consisting of a linear-alkylene group, a branched-alkylene group, and a cyclo-alkylene group, each group having from about 2 to about 20 carbon atoms.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: February 26, 2002
    Assignee: Bridgestone Corporation
    Inventors: David F. Lawson, Thomas A. Antkowiak, James E. Hall, Mark L. Stayer, Jr., John R. Schreffler
  • Publication number: 20020010281
    Abstract: Electron donor compounds, suitable for use as adhesives or as components in adhesives, contain a carbon to carbon double bond attached to an aromatic ring and conjugated with the unsaturation in the aromatic ring.
    Type: Application
    Filed: August 3, 2001
    Publication date: January 24, 2002
    Inventors: Osama M. Musa, Donald E. Herr, Nikola A. Nikolic
  • Publication number: 20020007042
    Abstract: A thermoplastic or thermosetting adhesive for bonding an electronic component to a substrate in which the adhesive is cured in situ from a curable composition comprises one or more poly- or mono-functional maleimide compounds, or one or more poly- or mono-functional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, a curing initiator and optionally, one or more fillers.
    Type: Application
    Filed: February 1, 2001
    Publication date: January 17, 2002
    Inventors: Donald E. Herr, Rose Ann Schultz
  • Patent number: 6313252
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: November 6, 2001
    Assignee: The Dow Chemical Company
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Patent number: 6300289
    Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: October 9, 2001
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 6265530
    Abstract: A thermoplastic or thermosetting curable adhesive composition for bonding an electronic component to a substrate in which the adhesive is cured in situ comprises one or more poly- or mono-functional maleimide compounds, or one or more poly- or mono-functional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, a curing initiator and optionally, one or more fillers.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: July 24, 2001
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Donald Herr, Rose Ann Schultz, Pingyong Xu, Scott R. McLaughlin
  • Patent number: 6265493
    Abstract: The invention relates to a process for preparing polyolefin graft copolymers (II) from linear and well defined polyolefin copolymers (I) containing divinylbenzene comonomer units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independantly, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal, e.g., Li, Na, K and Ca) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. G and G′ can be selected singly or in a combination of two or more thereof. In the graft copolymer composition, the combined alpha-olefin mole .% (x+y) is from about 50 to 99.9 mole %. Preferably, x+y is from 85 to 99.9 mole %, and most preferably x+y is from 95 to 99.9 mole %.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: July 24, 2001
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jinyong Dong
  • Patent number: 6197891
    Abstract: A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M—Qn—Z—O—[A(R1R2R3)] wherein M is an alkali metal selected from the group consisting of lithium, sodium and potassium; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof into the M—Z linkage; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R1, R2, and R3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monof
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: March 6, 2001
    Assignee: FMC Corporation
    Inventors: James Anthony Schwindeman, Eric John Granger, Robert Charles Morrison, Conrad William Kamienski, Robert James Letchford
  • Patent number: 6187721
    Abstract: Soot in a lubricated diesel engine is effectively dispersed without adversely affecting the viscosity of the lubricant by using a particular lubricant. The lubricant utilized comprises a lubricant base stock (e.g. more than 75% by weight), a dispersant (e.g. from 0.2-less than 4% from a detergent inhibitor (D1) package), and a functionalized viscosity index improver (e.g. from 0.1-2.5% by solids weight). The functionalized viscosity index improver is a highly functionalized graft copolymer reaction product of an oxygen, a nitrogen, or an oxygen and nitrogen containing, ethylenically unsaturated, aliphatic or aromatic monomer having from 2 to about 50 carbon atoms grafted onto a polyolefin copolymer. Also, 0-2.5% by solids weight of another viscosity index improver besides the highly functionalized graft copolymer reaction product may be added, as well as other conventional additives.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: February 13, 2001
    Assignee: Castrol Limited
    Inventors: Irwin Goldblatt, Michael McHenry, Kenneth Henderson, Danny Carlisle, Niall Ainscough, Myron Brown, Richard Tittel
  • Patent number: 6184302
    Abstract: The present invention relates to water-insoluble cationized solids obtained by treating solids with cationic homopolymers and/or copolymers comprising allylic and/or vinylic double bonds, where cationization is carried out using nitrogen-containing cationic polymers and/or copolymers which comprise from 0.5 to 100 mol-%, preferably from 5 to 20 mol-%, of said double bonds, based on nitrogen equivalents. The invention relates in particular to cationized solids obtained by cationization with allylated and/or vinylated derivatives of amino-containing polymers and/or copolymers. The invention also embraces the preparation of cationized solids by free-radical crosslinking of the abovementioned cationic polymers and/or copolymers in the presence of solids. The products obtained are in general at least 95% insoluble in water. They are obtained by cationizing mineral materials and, preferably, cellulose and are used preferably as retention aids and/or fixing agents in papermaking.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: February 6, 2001
    Assignee: Clariant Corporation
    Inventor: Oliver Eyrisch
  • Patent number: 6160054
    Abstract: Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: December 12, 2000
    Assignee: FMC Corporation
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6114473
    Abstract: A resin composition for powder coating, which comprises the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1,000 to 20,000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120.degree. C.; (B) tris(.beta.-methylglycidyl) isocyanurate of formula (1); and (C) as a ring opening polymerization inhibitor, at least one compound selected from the group consisting of amines having in their molecules a bond of formula (2); and onium salts.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: September 5, 2000
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Satoru Miyake, Hisao Ikeda, Motohiko Hidaka, Takeo Moro
  • Patent number: 6113814
    Abstract: Described are novel photochromic polymerizable polyalkoxylated naphthopyran compounds, examples of which are certain 2H-naphtho[1,2-b]pyrans, 3H-naphtho[2,1-b]pyrans and indeno[2,1-f]naphtho[1,2-b]pyrans each having at least one polyalkoxylated substituent of from 1 to 50 alkoxy units per substituent which is end-capped with a polymerizable group. Specific substituents are also present on the naphtho, indeno and pyrano portions of the compounds. These compounds may be represented by the following graphic formulae: ##STR1## Also described are various substrates, e.g., paper, glass, polymeric organic materials, etc., that contain or that are coated with such compounds. Optically clear articles such as contact lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, indenonaphthopyrans, benzopyrans, oxazine-type compounds, etc., are also described.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: September 5, 2000
    Assignee: Transitions Optical, Inc.
    Inventors: Barry Van Gemert, Anu Chopra, Anil Kumar
  • Patent number: 6099759
    Abstract: The present invention has for subjects, novel benzopyran derivatives, substituted in position 2 with an adamantyl group as well as the compositions and (co)polymer matrices containing such derivatives. Said derivatives possess interesting photochromic properties.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: August 8, 2000
    Assignee: Corning Incorporated
    Inventor: You-Ping Chan
  • Patent number: 6083888
    Abstract: A lubricating oil composition comprising:(a) from 0.01 to 10 percent by weight of a dispersant viscosity index improver linear diblock copolymer or a radial or star copolymer with each arm having an overall number average molecular weight of 7500 to 250,000 and comprising a block of a conjugated diene having a number average molecular weight of 5000 to 200,000 and a block of a vinyl aromatic hydrocarbon having a number average molecular weight of 2500 to 100,000, and a vinyl aromatic hydrocarbon content of 5 to 50 weight percent, wherein from 5 to 10 N-vinyl imidazole functional groups per molecule have been grafted onto the copolymer;(b) from 5 to 20 percent by weight of a dispersant inhibitor package containing 40 percent by weight less ashless dispersant than is required for use with a non-dispersant viscosity index improver; and(c) from 80 to 95 percent by weight of a base oil.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: July 4, 2000
    Assignee: Shell Oil Company
    Inventor: Robert Jude Sutherland