Cyclic Anhydride Patents (Class 525/285)
  • Publication number: 20120308532
    Abstract: There is disclosed a composition formed by a reaction of at least one component A and at least one component B, wherein component A is selected from the group consisting of a compound comprising at least two thiol-groups and a disulfide derivative of a compound comprising at least two thiol groups, and wherein component B is a compound comprising at least two vinyl groups, for the manufacture of an implant for the treatment of a bone fracture. Advantages include that the adhesive patch formed by the composition will be solid in body fluid upon curing and will exhibit excellent mechanical strength. Advantages include that the composition is biocompatible, the material can be applied in small and inaccessible areas, the process requires less surgeon training, it solves drawback with open surgery, and it is possible to use cost effective materials and methods in the process.
    Type: Application
    Filed: October 19, 2010
    Publication date: December 6, 2012
    Applicant: PROPPABORT AB
    Inventors: Anders Hult, Michael Malkoch, Hans Von Holst, Axel Nordberg
  • Patent number: 8324317
    Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: December 4, 2012
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
  • Patent number: 8288476
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: October 16, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8283419
    Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: October 9, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
  • Publication number: 20120245299
    Abstract: This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.
    Type: Application
    Filed: March 5, 2012
    Publication date: September 27, 2012
    Inventors: Peijun Jiang, Patrick Brant
  • Publication number: 20120225992
    Abstract: The invention relates to amino and hydroxy-functional compounds other than polyesters, wherein the compound includes an amine in the form of aspartic acid esters functionality, and wherein the amino and hydroxy-functional compound has (a) a molecular weight (Mn) of at least about 500, (b) an acid value of about 5 or less, (c) a hydroxyl value of about 30 or more, and (d) an amine value of about 30 or more. Preferably, the compound includes molecules having on the average: at least 1 secondary amino group as an aspartate, and/or at least 1 hydroxy group, and an average total functionality of about 1.8 or higher.
    Type: Application
    Filed: May 16, 2012
    Publication date: September 6, 2012
    Applicant: NUPLEX RESINS B.V.
    Inventors: Mohamad Deeb SHALATI, NANDA Ajaya, HELLEMS Stephen
  • Patent number: 8221840
    Abstract: A method to prepare a carbon fiber bundle which can develop satisfactory interfacial adhesion to polyolefin-based resins, especially polypropylene resins, is provided. The carbon fiber bundle comprises a plurality of single fibers sized with a sizing agent comprising: a polymer having a main chain formed of carbon-carbon bonds, containing an acid group in at least part of side chains or at least a part of main chain ends, and having an acid value of 23 to 120 mg KOH/g as measured in accordance with ASTM D1386; or a polymer having a main chain formed of carbon-carbon bonds and containing at least either of an epoxy group and an ester group in at least a part of side chains or at least a part of main chain ends.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: July 17, 2012
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Naoki Sugiura, Akihiko Fukushima, Shinobu Fujie
  • Publication number: 20120178656
    Abstract: The disclosed invention relates to a composition comprising a grafted polymer. The polymer backbone comprises an olefin block and a vinyl aromatic block. The polymer backbone is grafted with a pendant carbonyl containing group, the grafting being conducted in oil in the presence of an initiator. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.
    Type: Application
    Filed: July 6, 2010
    Publication date: July 12, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Michael R. Sutton, William R.S. Barton, David Price, Mark C. Davies
  • Patent number: 8211982
    Abstract: The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
    Type: Grant
    Filed: February 21, 2011
    Date of Patent: July 3, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: William J. Harris, John D. Weaver, Brian W. Walther, Stephen F. Hahn, Yunwa W. Cheung, Pankaj Gupta, Thoi H. Ho, Kenneth N. Reichek, Selim Yalvac, Teresa P. Karjala, Benjamin R. Rozenblat, Cynthia L. Rickey
  • Publication number: 20120138004
    Abstract: The invention relates to quaternary ammonium amide and/or ester salts and their use as additives, including their use in fuels, such as diesel fuel. The invention particularly relates to the use of quaternary ammonium amide and/or ester salts as detergents in diesel fuels.
    Type: Application
    Filed: May 6, 2010
    Publication date: June 7, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Paul R. Stevenson, James C. Ray, David J. Moreton, James H. Bush
  • Publication number: 20120122359
    Abstract: Adhesive (co)polymers of this disclosure comprise: a) an isobutylene copolymer having pendent succinate groups and optionally a tackifier. The pendent succinic acid groups ionically crosslinks the isobutylene copolymer by hydrogen boding with adjacent pendent succinic acid groups.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 17, 2012
    Inventors: Hae-Seung Lee, Joon Chatterjee, Gregg A. Caldwell, Babu N. Gaddam
  • Publication number: 20120095157
    Abstract: The present invention describes polymer comprising one or more C3 to C40 olefins and having a Mw of 100,000 or less and a Dot T-Peel of 1 Newton or more. The polymer may have a branching index (g?) of 0.95 or less measured at the Mz of the polymer, and a heat of fusion of 1 to 70 J/g. Also described are polymers of homopolypropylene or a copolymer of propylene and up to 5 mole % ethylene having: an isotactic run length of 1 to 30 as determined by Carbon 13 NMR and a percent of r dyad of greater than 20%, preferably from 20 to 70% as determined by Carbon 13 NMR. Also described are methods of making these and other polymers.
    Type: Application
    Filed: October 25, 2011
    Publication date: April 19, 2012
    Inventors: Peijun Jiang, Armenag Hagop Dekmezian, Jo Ann Marie Canich, Charles Lewis Sims, Ramin Abhari, Cesar Alberto Garcia-Franco, David Raymond Johnsrud
  • Publication number: 20120088883
    Abstract: A bonding base for electronic components, and a method. The bonding base comprises: a dielectric basic layer formed of a mixture comprising thermoplastic polymer, the polymer part of which mixture comprises 75 to 95% by weight of thermoplastic PPO, the polymer part further comprising 5 to 20% by weight of elastomer which is incompatible with PPO.
    Type: Application
    Filed: May 14, 2010
    Publication date: April 12, 2012
    Applicant: Teknologian tutkimuskeskus VTT
    Inventors: Mikko Karttunen, Satu Kortet
  • Publication number: 20120088885
    Abstract: The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.
    Type: Application
    Filed: June 9, 2010
    Publication date: April 12, 2012
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Matthias Krull, Roman Morschhaeuser
  • Publication number: 20120059101
    Abstract: The application provides a terpolymer obtainable by copolymerizing (A) 1% to 70% by weight of at least one electron-deficient olefin, an example being an anhydride of a monoethylenically unsaturated C4 to C6 dicarboxylic acid, (B) 1% to 85% by weight of at least one olefin which on its olefinic double bond carries only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, an example being an isobutene homopolymer or copolymer having a number-average molecular weight of 100 to 500 000, and (C) 1% to 70% by weight of at least one alkoxyvinylsilane, and also derivatives of this terpolymer that are obtainable by modification or crosslinking.
    Type: Application
    Filed: September 2, 2011
    Publication date: March 8, 2012
    Applicant: BASF SE
    Inventors: Arno Lange, Matthias Scheibitz, Manoranjan Prusty
  • Patent number: 8129450
    Abstract: Durable and disposable articles are provided which include a thermoplastic polymer composition, which includes a blend of a polymer and a modified polymer. The modified polymer has covalently bonded pendant substituents derived from cyclodextrin. The articles can be a films, coatings, nonwoven webs, or monolithic articles. An article can have the polymer composition as one part of the article, such as in one distinct area of the article, or on the surface of the article, for example as a coating or surface film. The article can be, for example, a multilayer barrier film, a nonwoven sheet or pad, an absorbent article, or a storage container.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: March 6, 2012
    Assignee: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Timothy H. Bohrer, Stanley R. Kellenberger, Neil J. Beaverson
  • Publication number: 20120048373
    Abstract: A sealing material for a solar cell and a solar cell including the same, and the sealing material includes a polymer resin having a vicat softening point at 100° C. or 130° C. or between 100° C. and 130° C.
    Type: Application
    Filed: March 28, 2011
    Publication date: March 1, 2012
    Inventors: Nam-Choul Yang, Do-Young Park, Si-Young Cha, Yi-Hyun Chang
  • Publication number: 20120015411
    Abstract: The present application relates to a process for manufacturing maleic anhydride that comprising the following steps: a) fermentation of renewable raw materials and optionally purification to produce a mixture comprising at least butanol; b) oxidation of the butanol to maleic anhydride at a temperature generally between 300° C. to 600° C., using a catalyst based on oxides of vanadium and/or molybdenum; c) isolation of the maleic anhydride obtained at the end of step b). It also relates to the maleic anhydride obtained from renewable raw materials, to the copolymers and compositions comprising said maleic anhydride and also uses of use of this maleic anhydride.
    Type: Application
    Filed: July 17, 2009
    Publication date: January 19, 2012
    Applicant: Arkema France
    Inventor: Jean-Luc Dubois
  • Patent number: 8076407
    Abstract: Hot melt adhesives are provided that have improved heat resistance. The adhesives comprise a metallocene polyolefin, an amorphous ?-olefin polymer, a tackifier and a functional polyolefin. The functional polyolefin is used in an amount sufficient to increase the heat resistance. A preferred functional polyolefin is a maleated polyolefin such as maleated polypropylene. A preferred tackifier is a hydrogenated hydrocarbon tackifier.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: December 13, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Richard J. Ellis, Michaela Stolbova
  • Publication number: 20110288203
    Abstract: The invention provides a fire resistant material and a formulation thereof. The formulation comprises a liquid suspension of a modified inorganic particle and an organic component. The modified inorganic particle comprises an inorganic particle with hydroxyl groups and a surface modifier coupled to the inorganic particle via a urethane linkage, wherein the surface modifier has an ethylenically unsaturated end group. The organic component comprises a monomer, oligomer, prepolymer, polymer, or combinations thereof, capable of reacting with the ethylenically unsaturated end group.
    Type: Application
    Filed: August 2, 2011
    Publication date: November 24, 2011
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Shou I. Chen, Che I. Kao, Chih-Chien Chen, Jin-Her Shen, Wei-Feng Teng, Hsiao-Pin Chiang, Kai-Wen Chang, Fan-Jeng Tsai
  • Publication number: 20110278503
    Abstract: The invention relates to an amphiphilic polymer (A) comprising repeat units of the general formulae (I), (II) and (III): or salts thereof, wherein the repeat unit of general formula (I) is comprised in the amphiphilic polymer with a number of m units, the repeat unit of general formula (II) is comprised in the amphiphilic polymer with a number of o units and repeat unit of general formula (III) is comprised in the amphiphilic polymer with a number of p units, wherein each of m, o and p is an independently selected integer from about 3 to about 400 and wherein the sum of m+o+p is selected in the range from about 10 to about 10000, R1 in repeat units (I)-(III) is H or methyl, R2 in repeat unit (II) is an aliphatic moiety with a main chain of about 3 to about 30 carbon atoms and 0 to about 3 heteroatoms selected from the group N, O, S, Se and Si, and, R3 in repeat unit (III) is one of (i) an alicyclic moiety with a main chain of about 5 to about 80 carbon atoms and 0 to about 30 heteroatoms selected from the gro
    Type: Application
    Filed: October 12, 2009
    Publication date: November 17, 2011
    Applicant: Agency for Science,Technology and Research
    Inventors: Dominik Janczewski, Nikodem Tomczak, Ming-Yong Han, G. Julius Vancso
  • Publication number: 20110274941
    Abstract: It is an object of the present invention to provide an active energy ray curable resin composition exhibiting good adhesion to a polyolefin-based resin base material. More specifically, there is provided an active energy ray curable resin composition comprising: a block copolymer (C) that includes a polymer block (A) composed mainly of an olefin-based monomer unit and a polymer block (B) composed of a vinyl-based monomer unit having a carboxyl group, a carboxylic anhydride group, or a sulfonic acid group and/or a second vinyl-based monomer unit copolymerizable with the aforementioned vinyl-based monomer unit, the block copolymer (C) having a weight-average molecular weight from 5,000 to 100,000; and an active energy ray curable compound (D).
    Type: Application
    Filed: January 21, 2010
    Publication date: November 10, 2011
    Applicant: NIPPON PAPER CHEMICALS CO., LTD.
    Inventors: Minoru Yada, Yuuki Kokufu, Yuu Takata, Hideo Hosaka, Kenichi Fujino
  • Publication number: 20110214980
    Abstract: The present invention relates to the field of corrosion inhibition in hydrocarbon fluid processing units. The present invention comprises a new additive for inhibiting acid corrosion comprising polymeric thiophosphate ester, which is obtained by reaction of a polymer compound having mono, di or poly hydroxyl group, preferably polymer compound which is hydroxyl-termination, more preferably said polymer compound comprising hydroxyl-terminated polyisobutylene or polybutene and phosphorous pentasulphide. Said polymeric thiophosphate ester is further reacted with any oxide selected from group consisting of ethylene oxide, butylenes oxide or propylene oxide or such other oxide, preferably ethylene oxide, capably forming ethylene oxide derivative of thiophosphate ester. The invention is useful effecting acid corrosion inhibition on the metal surfaces of a distillation unit, distillation column, trays, packing and pump around piping.
    Type: Application
    Filed: August 25, 2009
    Publication date: September 8, 2011
    Inventor: Mahesh Subramaniyam
  • Patent number: 7989083
    Abstract: To provide an acid-modified polypropylene resin which can be used for an adhesive capable of bonding a polyolefin type resin and a polar resin with sufficient force, its production process and a resin composition using it. An acid-modified polypropylene resin, which is obtained by grafting an organic acid component to a polypropylene resin, wherein the polypropylene resin is an isotactic polypropylene resin, the grafted amount X (wt %) of the organic acid component in the acid-modified polypropylene resin is within a range of from 1.0 wt % to 20.0 wt %, and the melt flow rate Y (g/10 min) of the acid-modified polypropylene resin satisfies the expression: Y?18.5 exp(0.82X), a process for producing such an acid-modified polypropylene resin, a resin composition using it and a laminate.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: August 2, 2011
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kenichi Morikawa, Katsutoshi Ohno
  • Publication number: 20110177328
    Abstract: [Problem] To provide an ionomer resin capable of forming a polyolefin molded product having well-balanced two properties of molding processability and mechanical property, a resin composition including the ionomer resin and a molded product formed from the ionomer resin or the resin composition. [Solution to problem] An ionomer resin (X1) formed from 100 parts by weight of (A) an olefin polymer having constitutional units derived from an ?-olefin of 2 to 20 carbon atoms and having a functional group (a) and 0.01 to 100 parts by weight of (B) a metal salt having two or more functional groups (b).
    Type: Application
    Filed: August 26, 2009
    Publication date: July 21, 2011
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Hirokazu Tanaka, Takayuki Onogi, Hiroyasu Oochi, Shigenobu Ikenaga
  • Publication number: 20110172368
    Abstract: The present disclosure provides a functionalized olefin-based polymer, a process for producing the same, and articles containing the functionalized olefin-based polymer. The functionalized olefin-based polymer includes an olefin-based polymer, and a functional agent grafted to the olefin-based polymer by way of a coagent. The coagent is either a cinnamoyl derivative and/or a cyano-acrylate compound. The presence of the coagent inhibits a change in the molecular weight during radical functionalization of the olefin-based polymer.
    Type: Application
    Filed: September 22, 2009
    Publication date: July 14, 2011
    Inventor: Sandra K. Stolz-Dunn
  • Publication number: 20110152437
    Abstract: The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
    Type: Application
    Filed: February 21, 2011
    Publication date: June 23, 2011
    Inventors: William J. Harris, John D. Weaver, Brian W. Walther, Stephen F. Hahn, Yunwa W. Cheung, Pankaj Gupta, Thoi H. Ho, Kenneth N. Reichek, Selim Yalvac, Teresa P. Karjala, Benjamin R. Rozenblat, Cynthia L. Rickey
  • Publication number: 20110152454
    Abstract: The invention relates to a method for production of grafted polyethylene comprising the following steps: a) fermentation of primary renewable material with optional purification to give at least one alcohol chosen from ethanol or a mixture of alcohols comprising ethanol; b) dehydration of the alcohol obtained to give in a first reactor at least one alkene selected from ethylene and mixtures of alkenes containing ethylene and optional purification of the alkene to give ethylene; c) polymerization, in a second reactor, of the ethylene to give polyethylene; d) isolation of the polyethylene obtained in step c); e) grafting the polyethylene with at least one grafting monomer selected from the unsaturated carboxylic acids or theifunctional derivatives thereof, the unsaturated dicarboxylic acids having 4-10 carbon atoms and the functional derivatives thereof being C1-C8 alkyl esters or glycidyl ester derivatives of the unsaturated carboxylic acids and the metal salts of the unsaturated carboxylic acids.
    Type: Application
    Filed: July 27, 2009
    Publication date: June 23, 2011
    Applicant: Arkema France
    Inventors: Samuel Devisme, Fabrice Chopinez, Jean-Laurent Pradel, Guillaume Le, Thomas Roussel
  • Patent number: 7960479
    Abstract: A copolymer of formula 1 in which M1 is a unit obtainable from ring opening metathesis polymerization (ROMP); R is an alkyl, ether, ester or aryl unit; M2 and M3 are independently selected from units obtainable by reversible addition fragmentation chain transfer polymerization (RAFT); X is a terminal unit selected from the group consisting of dithioester, trithiocarbonate, xanthate; and m is an integer from 2 to 1 million, n is an integer from 2 to 500,000 and k is an integer from 2 to 500,000.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: June 14, 2011
    Assignee: Conopco, Inc.
    Inventors: Chong Cheng, Ezat Khoshdel, Karen Lynn Wooley
  • Patent number: 7829636
    Abstract: The embodiments herein relate to a method of synthesizing new improved reactive terpolymer, S-MMA-X (styrene/modified maleic anhydride/X) wherein X is any type of polymers. The method involves synthesizing styrene-modified maleic anhydride complex (SMMA) with the ability to react with all kinds of polymers to produce new reactive terpolymer with formation of nano particles inside them. The nanoparticle formations improve the physio-chemical, thermal and mechanical properties of the newly formed reactive terpolymer when compared to natural rubber, their derivatives, EPDM or other known polymer etc. Depending on the property of the end product polymers produced by the invention, the end use can be varied. In one embodiment, the polymer X is natural rubber (NR) and the end product terpolymer is used as bitumen modifier. In another embodiment, the polymer X is ethylene-propylene diene monomer (EPDM) and the end product terpolymer behaves like a smart particle and absorbs oil and water contaminants.
    Type: Grant
    Filed: August 27, 2007
    Date of Patent: November 9, 2010
    Inventors: Sara Shaghaghi, Reza Shaghaghi
  • Patent number: 7825188
    Abstract: The present invention provides curatives for thermosetting adhesive compositions, methods of preparation and uses thereof. In particular, the present invention relates to elastomeric epoxy curative compounds that can be used in thermosetting compounds, methods for preparing the curative compounds and epoxy compositions containing the curative compounds.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: November 2, 2010
    Assignee: Designer Molecules, Inc.
    Inventor: Stephen M Dershem
  • Patent number: 7795333
    Abstract: Thermoplastic polymer compositions, films, continues, closures, laminates can comprise a modified vinyl polymer said modified polymer having a moiety comprising a cyclodextrin compound. The cyclodextrin compound, locked into the polymer structure, can absorb impurities, permeants, or other undesirable volatile materials. The cooperation between the cyclodextrin grafted onto the thermoplastic polymer and the polymer structure can provide barrier properties to a film, web or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film or Web preventing the permeant or contaminant from passing into the interior of a container or enclosure.
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: September 14, 2010
    Assignee: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Neil J. Beaverson, Kasyap V. Seethamraju
  • Patent number: 7767765
    Abstract: Process for modifying a polyolefin grafted with acid or anhydride groups, by at least partial neutralization of these groups with at least one neutralizing agent comprising an organic salt (1) that releases an organic acid (I) during the neutralization, according to which the organic acid (I) derived from the neutralization of the grafted polyolefin is reacted with at least one inorganic salt (2). Modified polyolefin (that can be) obtained by the process described above. Polymeric composition containing (A) at least one polymer, and (B) at least one modified polyolefin (that can be) obtained by the process above. Article comprising the modified polyolefin or the composition described above.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: August 3, 2010
    Assignee: Addcomp Holland BV
    Inventors: Henri Wautier, Fernand Gauthy, Dino Manfredi
  • Patent number: 7741407
    Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: June 22, 2010
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
  • Patent number: 7700689
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: April 20, 2010
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7683136
    Abstract: An elastomeric compound comprises 20-80 parts per hundred cross-linkable materials of liquid elastomer. The liquid elastomer has a complex dynamic viscosity less than 5 McP (5,000 N*s/m2) at a temperature between 20° C. and the maximum flow temperature TF, and the elastomeric compound the elastomeric material has a complex dynamic viscosity of less than 5 McP (5,000 N*s/m2) for at least 2 minutes at a maximum flow temperature TF.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: March 23, 2010
    Assignee: VeyanceTechnologies, Inc.
    Inventors: Douglas Bruce Wood, Thomas George Burrowes
  • Patent number: 7683134
    Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 6, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: March 23, 2010
    Assignee: Eastman Chemical Company
    Inventors: Thomas David Roberts, Stephen Wayne Coe
  • Patent number: 7659346
    Abstract: A process for converting distillation residues obtained from polymerization processes to useful maleated products is provided.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: February 9, 2010
    Assignee: Equistar Chemicals, LP
    Inventors: Chun D. Lee, Jeffrey A. Jones
  • Patent number: 7655725
    Abstract: This invention relates to a process for the preparation of a hydrogenated polymer comprising the steps of hydrogenation of at least one carbon-carbon double bond of an unsaturated polymer in latex in the presence of hydrazine, an oxidizing compound and a catalyst, followed by separation of the hydrogenated polymer from the latex. After the separation of the hydrogenerated polymer from the latex a mixing step is carried out in which the hydrogenated polymer is first mixed with an amine group containing compound and next the hydrogenated polymer is mixed with a compound that is capable of reacting with an amine. The invention also relates to the hydrogenated polymer. The invention further relates to the use of this polymer in a compounds to make an article by shaping and vulcanisation.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: February 2, 2010
    Assignee: Zeon Corporation
    Inventors: Johannes Wilhelmus Belt, Marco Marcus Matheus Driessen, Gerhard Vliet Van
  • Publication number: 20090297857
    Abstract: The invention concerns an adhesive composition consisting of at least one ethylene polymer or copolymer, said composition comprising at least one unsaturated carboxylic acid ester comonomer, and at least one functional comonomer, useful in an extrusion-coating process for application on a support or in an extrusion-lamination process for bonding together several supports of different type or not, in a wide temperature range. The invention is characterized in that said composition has an unsaturated carboxylic acid ester content, higher than 5 wt. % and in that the functional comonomer consists of at least one reactive function in the form of acid group, anhydride or epoxy, whereof the proportion is less than 1 wt. % of the composition.
    Type: Application
    Filed: December 13, 2005
    Publication date: December 3, 2009
    Applicant: ARKEMA FRANCE
    Inventors: Jerome Pascal, Fabrice Chopinez, Damien Rauline
  • Publication number: 20090247706
    Abstract: A continuous extrusion process for the functionalization of polymers through reactive extrusion. The process uses a continuous extrusion reactor comprising at least two sequential, very closely-coupled, independently driven screw extruders having a total effective length to diameter ratio greater than 60 to 1 and as high as 112 to 1 and providing greatly extended reaction times for efficiently producing a grafted polymer having a high level of functionalization. Drying of the polymer feed is performed in the continuous extrusion reactor. Multiple injections of reactants may be provided. Shear modification of the molecular weight of the grafted polymer is performed in the continuous extrusion reactor after the functionalization reactions. A continuous extrusion reactor and a grafted polymer having a high level of functionalization are also disclosed.
    Type: Application
    Filed: January 31, 2005
    Publication date: October 1, 2009
    Inventors: Rayner Krista, John Joseph Decair, James Nicholas Fowler, Michael T. Gallagher, John Lovegrove, Shrikant V. Phadke
  • Patent number: 7585565
    Abstract: The invention relates to a multilayered film comprising at least one upper layer a), a middle layer b) made of (meth)acrylate copolymer, and a supporting layer c) made of polycarbonate. Upper layer a) contains a light-stability agent and is made of a (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures. A test piece, which is made from a mixture consisting of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate, has a breaking elongation (ISO 527-2) of at least 75% at 23° C. The middle layer b) contains a colorant and, optionally, a light-stability agent and is made from an identical or different (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures.
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: September 8, 2009
    Assignees: Roehm GmbH, Senoplast Klepsch & Co. GmbH
    Inventors: Klaus Schultes, Michael Wicker, Klaus Albrecht, Mona Rueppel, Gabriele Dassinger, Eric Reinheimer, Johann Kappacher, Andreas Hollebauer
  • Patent number: 7563849
    Abstract: An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an ?-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an ?-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9?7.15×SR; and the intrinsic viscosity ([?]) and the melt flow rate (MFR) satisfy the relation; [?]>1.85×MFR?0.192 in the case of MFR<1 and the relation; [?]>1.85×MFR?0.213 in the case of MFR?1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: July 21, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Mamoru Takahashi, Tetsuji Kasai, Junji Saito, Naoto Matsukawa, Kazutaka Tsuru, Makoto Mitani, Terunori Fujita, Shiro Otsuzuki, Tetsuhiro Matsumoto, Toshiyuki Tsutsui
  • Patent number: 7560509
    Abstract: A method of producing an engineered plastic selected from the group consisting of high impact polystyrene, styrene-maleic anhydride copolymer, methylmethacrylate-butadiene-styrene copolymer, transparent impact polystyrene, and acrylonitrile butadiene styrene copolymer is provided. The method comprises the steps of: (a) adding a polymer containing at least one high vinyl segment having a 1,2-vinyl bond content of greater than 45% to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein the presence of the at least one high vinyl segment in the polymer allows direction of the grafting site during preparation of the engineered plastic.
    Type: Grant
    Filed: December 29, 2006
    Date of Patent: July 14, 2009
    Assignee: Bridgestone Corporation
    Inventor: James E. Hall
  • Publication number: 20090105407
    Abstract: An adhesive composition comprising a copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and C4-20?-olefins, the copolymer having (i) a content of units derived from propylene of greater than about 50 mole percent, (ii) a Brookfield viscosity at 190 C from about 50 to about 100,000 cP, (iii) an MWD from about 1.5 to about 15, and (iv) containing less than about 50 ppm residual catalyst metal.
    Type: Application
    Filed: December 21, 2005
    Publication date: April 23, 2009
    Inventors: Teresa P. Karjala, Patricia Ansems, Charles F. Diehl, Selim Yalvac, Cynthia L. Rickey, Seema V. Karande, Angela N. Taha
  • Patent number: 7465768
    Abstract: A novel method of preparing carboxyl-terminated polymers. A monomer is mixed with an organolithium initiator in a hydrocarbon solvent so as to anionically polymerize linear living polymer lithium chains. A trialkyl aluminum compound is also mixed so as to form polymer lithium: aluminate complexes in equilibrium with the linear living polymer lithium chains. When a cyclic anhydride terminator is mixed, the cyclic anhydride terminator preferentially reacts with the C—Li center on a living polymer lithium chain rather than with the C—Al—Li center on a polymer lithium: aluminate complex.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: December 16, 2008
    Assignee: Bridgestone Corporation
    Inventors: James E. Hall, James Oziomek
  • Patent number: 7465777
    Abstract: The present disclosure relates to hybrid polymers, methods of making such hybrid polymers, and medical devices that include the hybrid polymers. Such hybrid polymers are suitable for forming biomaterials in a predetermined shape for use in medical devices and medical device components. The hybrid polymers of the present disclosure are formed through a reactive extrusion process prior to being formed into the predetermined shape of the medical device or medical device component.
    Type: Grant
    Filed: March 2, 2006
    Date of Patent: December 16, 2008
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Michele L. Zoromski, Liliana L. Atanasoska, Robert W. Warner
  • Patent number: 7452941
    Abstract: A process for preparing a surfactant, useful for dispersing tackifier resins in aqueous media, comprises reacting an ?,?-unsaturated carboxylic acid or anhydride, or an ester thereof, with a terpene- or hydrocarbon-based resin to form an adduct, then reacting the adduct with a polyalkylene polyol to yield the surfactant. In a related embodiment, the surfactant is subsequently functionalized. Also disclosed are surfactants prepared using a disclosed process; compositions comprising a disclosed surfactant and a tackifier resin; aqueous dispersions comprising a disclosed surfactant; tackifier resin and water; adhesive compositions comprising a disclosed aqueous dispersion and a polymer latex; and pressure sensitive adhesive overlays prepared using a disclosed adhesive composition.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: November 18, 2008
    Assignee: Arizona Chemical Company
    Inventors: Erwin R Ruckel, Kerry L Thompson, George L Gergely
  • Publication number: 20080281050
    Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 6, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.
    Type: Application
    Filed: July 21, 2008
    Publication date: November 13, 2008
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Thomas David Roberts, Stephen Wayne Coe
  • Patent number: 7439307
    Abstract: Articles made from propylene ethylene copolymers with an ethylene content between 8 and 32 mole % have been grafted with maleic anhydride and a peroxide. The functionality level is higher than what is reported with polypropylene.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: October 21, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch H. Schauder, Sudhin Datta