Block Copolymer Derived From Nitrogen-containing Reactant Patents (Class 525/294)
  • Patent number: 4695607
    Abstract: Large acrylic star polymers, are made by group transfer polymerization techniques by arm-first, core-first, or arm-core-arm approaches.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: September 22, 1987
    Assignee: E. I. Du Pont De Nemours and Company
    Inventor: Harry J. Spinelli
  • Patent number: 4668742
    Abstract: N,N-disubstituted acrylamides are polymerized at temperatures from about -80.degree. to 100.degree. centigrade by anionically initiated polymerization to provide homogeneous polymerization by employing a solvent containing from about 25 to 100 weight percent of a pyridine type compound. Homopolymers or block polymers may be obtained.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: May 26, 1987
    Assignee: The Dow Chemical Company
    Inventors: Gia Huynh-Ba, James E. McGrath
  • Patent number: 4659783
    Abstract: Large acrylic star polymers, having a low polydispersity of polymer molecular weight and of arm molecular weight and containing multifunctional monomers in the core.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: April 21, 1987
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Harry J. Spinelli
  • Patent number: 4659782
    Abstract: Large acrylic star polymers, having a low polydispersity of polymer molecular weight and of arm molecular weight and containing single- and multi-functional monomers in the core.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: April 21, 1987
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Harry J. Spinelli
  • Patent number: 4659784
    Abstract: ABA block copolymers containing N,N-disubstituted acrylamides in the A blocks and butadiene polymer in the B block provides thermoplastic elastomer adhesives or compatibilizing agents for polymer blends.
    Type: Grant
    Filed: June 27, 1986
    Date of Patent: April 21, 1987
    Assignee: The Dow Chemical Company
    Inventors: David Y. Chung, Lu H. Tung
  • Patent number: 4631188
    Abstract: There is disclosed a non-toxic physiologically-acceptable polymeric composition comprised of water insoluble, non-crosslinked polymeric compounds having a solubility parameter of between 9.2 and 15.5 (cal/cc).sup.1/2 dissolved in a polar, non-toxic water miscible solvent, which polymeric composition solidifies when placed in contact with living tissue by absorbtion of water and by gradual release of solvent into the surrounding tissue.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: December 23, 1986
    Assignee: S.K.Y. Polymers, Ltd. (Kingston Technologies)
    Inventors: Vladimir A. Stoy, Milos Chvapil
  • Patent number: 4540498
    Abstract: Water soluble block copolymers having two or more water soluble polymer blocks useful for controlling the viscosity of aqueous media used in enhanced oil recovery techniques are described.
    Type: Grant
    Filed: May 31, 1983
    Date of Patent: September 10, 1985
    Assignee: The Standard Oil Company
    Inventors: Muyen M. Wu, Lawrence E. Ball
  • Patent number: 4486572
    Abstract: A novel terminally functional (i.e., telechelic) polymers having a polyisobutylene are described. The end groups are styryl and can be reacted with conventional monomers to form copolymers having unique physical properties. Copolymerizations with N-vinyl-2-pyrrolidone produce amphiphilic polymers which are useful in the areas of medicine and agricultural chemicals.
    Type: Grant
    Filed: July 6, 1983
    Date of Patent: December 4, 1984
    Assignee: University of Akron
    Inventor: Joseph P. Kennedy
  • Patent number: 4427834
    Abstract: Lubricating oil additives having both dispersant and viscosity index-improving properties comprise a poly(polyalkenyl aromatic)nucleus, at least three hydrogenated conjugated diene homopolymer or copolymer arms linked to the nucleus, and at least one polymerized nitrogen containing polar compound arm linked to the nucleus.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: January 24, 1984
    Assignee: Shell Oil Company
    Inventor: Michael K. Martin
  • Patent number: 4420589
    Abstract: There is disclosed a process for producing a novel polymer composition comprised of a polyacrylonitrile polymer and a block copolymer with acrylonitrile and non-crystalline polymer sequences wherein the polymer composition is formed by the removal of a solvent from a solution of a polyacrylonitrile polymer and a block copolymer with acrylonitrile and non-crystalline polymer sequences.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: December 13, 1983
    Inventor: Vladimir A. Stoy
  • Patent number: 4409120
    Abstract: Lubricating oil additives having both dispersant and viscosity index-improving properties are prepared by contacting a star-shaped polymer having a poly(polyalkenyl aromatic) nucleus, at least three conjugated diene homopolymer or copolymer arms linked to the nucleus, and at least one polymerized nitrogen containing polar compound arm linked to the nucleus, with a rectant selected from p-toluenesulfonylhydrazide and hydrazine under conditions wherein the reactants release H.sub.2 N.sub.2, which adds across the residual double bonds in the polymer therein hydrogenating the aliphatic unsaturation and releasing N.sub.2 gas.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: October 11, 1983
    Assignee: Shell Oil Company
    Inventor: Michael K. Martin
  • Patent number: 4379874
    Abstract: There is disclosed a process for producing a novel polymer composition comprised of a polyacrylonitrile polymer and a block copolymer with acrylonitrile and non-crystalline polymer sequences wherein the polymer composition is formed by the removal of a solvent from a solution of a polyacrylonitrile polymer and a block copolymer with acrylonitrile and non-crystalline polymer sequences.
    Type: Grant
    Filed: July 7, 1980
    Date of Patent: April 12, 1983
    Inventor: Vladimir A. Stoy
  • Patent number: 4370451
    Abstract: There is disclosed novel block copolymers formed of acrylonitrile sequences and sequences containing at least about 50 mole percent of acrylamide units and at most about 50 mole percent organo-substituted amide units and formed by reacting a block copolymer having acrylonitrile sequences and sequences of glutarimide units with a low molecular weight compound having a functional group selected from the group consisting of primary amino and secondary amino group. The reaction is effected at a pH of about 7.5 and higher, preferably in the presence of a solvent and/or swelling agent.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: January 25, 1983
    Assignee: S.K.Y. Polymers
    Inventor: Vladimir A. Stoy
  • Patent number: 4369294
    Abstract: There is disclosed block copolymers having acrylonitrile sequences and sequences of glutarimide units of a molecular weight of from about 10,000 to about 2,000,000 where the acrylonitrile sequences and sequences including glutarimide units are of a molecular weight of at least about 400 with the number of sequences being at least about 2 and preferably 5 and higher.
    Type: Grant
    Filed: November 20, 1981
    Date of Patent: January 18, 1983
    Assignee: S.K.Y. Polmers
    Inventor: Vladimir A. Stoy
  • Patent number: 4358355
    Abstract: Polymeric material comprising at least four polymeric constituents which comprise mer units of the following types:I acrylamide or derivatives thereofII acrylonitrile or derivatives thereofIII acrylic acid and esters, or derivatives thereofIV alkylol, sulphonyl or phosphonyl derivatives of I.The polymeric materials are useful as components of water bearing systems which are in the form of gels or suspensions.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: November 9, 1982
    Assignee: ICI Australia Limited
    Inventors: Georgina Kalu, Michael Markus
  • Patent number: 4337327
    Abstract: There is disclosed novel block copolymers formed of acrylonitrile sequences and sequences containing at least about 50 mole percent of acrylamide units and at most about 50 of units selected from the group consisting of carboxyl, ester, amide, hydrazide and hydroxylamide units and formed by reacting a block copolymer having acrylonitrile sequences and sequences of glutarimide units with a low molecular weight compound having a functional group selected from the group consisting of hydroxyl, primary amino, secondary amino, hydrazo and hydroxylamino group. The reaction is effected at a pH of about 7.5 and higher, preferably in the presence of a solvent and/or swelling agent.
    Type: Grant
    Filed: September 17, 1980
    Date of Patent: June 29, 1982
    Assignee: S.K.Y. Polymers, Inc.
    Inventor: Vladimir A. Stoy
  • Patent number: 4331783
    Abstract: There is disclosed block copolymers having acrylonitrile sequences and sequences of glutarimide units of a molecular weight of form about 10,000 to about 2,000,000 where the acrylonitrile sequences and sequences including glutarimide units are of a molecular weight of at least about 400 with the number of sequences being at least about 2 and preferably 5 and higher.
    Type: Grant
    Filed: September 17, 1980
    Date of Patent: May 25, 1982
    Assignee: S.K.Y. Polymers
    Inventor: Vladimir A. Stoy
  • Patent number: 4299931
    Abstract: Compatibilized polymer blends are described comprising a blend of olefin polymer, nitrile rubber, and a compatibilizing amount of block copolymer comprising nitrile rubber compatibilizing segments and olefin polymer compatibilizing segments.
    Type: Grant
    Filed: March 10, 1980
    Date of Patent: November 10, 1981
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman Patel