Ester Is Derived From A Polyol Patents (Class 525/305)
-
Patent number: 5567775Abstract: This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R.sub.4 is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; andb) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g.Type: GrantFiled: June 6, 1995Date of Patent: October 22, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Hsien C. Wang, Irwin J. Gardner, James V. Fusco
-
Patent number: 5552491Abstract: A star-branched polymer comprising a core portion and polymeric arms. The core portion is obtained by anionic polymerization of at least one unsaturated acrylate or methacrylate ester of a polyol and the polymeric arms are obtained by anionic polymerization of at least one acrylic or methacrylic monomer.Type: GrantFiled: May 31, 1995Date of Patent: September 3, 1996Assignee: Ethyl Additives CorporationInventors: Munmaya K. Mishra, Shailaja M. Shirodkar, Alfred K. Jung
-
Patent number: 5519083Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a non-functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a non-functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.Type: GrantFiled: June 15, 1994Date of Patent: May 21, 1996Assignee: Imperial Chemical Industries PLCInventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
-
Patent number: 5519081Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.Type: GrantFiled: July 26, 1994Date of Patent: May 21, 1996Assignee: Imperial Chemical Industries PLCInventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
-
Patent number: 5519064Abstract: Disclosed is a surface-modified polymeric adsorbent material comprising a porous post-crosslinked polymer as a substrate and at least one surface-modifying polymer. The porous post-crosslinked polymer comprises a polymer of at least one monoethylenically unsaturated monomer, wherein the polymer has been post-crosslinked in a swollen state in the presence of a Friedel-Crafts catalyst. A process for preparing the surface-modified polymeric adsorbent materials, and the use of these materials in the separation of organic compounds, enantioselective synthesis and resolution of racemic mixtures are also disclosed.Type: GrantFiled: October 28, 1994Date of Patent: May 21, 1996Assignee: The Dow Chemical CompanyInventors: Richard T. Stringfield, Mladen Ladika
-
Patent number: 5516845Abstract: A thermoplastic basic polymers in pourable form are mixed with similarly pourable carrier polymers dispersable or soluble in the basic polymers with a cross-linking agent to produce cross-linked polymer moldings. These mutually compatible components are heated under further mixing to a reaction temperature above the melting range of the basic polymer and processed. The reaction of free radicals leads to bonds between polymer chains and/or the degradation of polymer chains.Porous carrier polymers which contain at least one organic peroxide and/or coagent incorporated in the fine pore structure as a fluid silane-free cross-linking agent are mixed in the basic polymer. Peroxide-containing carrier polymers are heated, coagent-containing carrier polymers are irradiated.The moldings are used for example for cable and sheath isolation, pipes for hot water lines and highly stressed injection moldings.Type: GrantFiled: December 6, 1994Date of Patent: May 14, 1996Assignee: Brugg Kabel AGInventors: Ulrich Heese, Renato Salvel
-
Patent number: 5516834Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable polyester compound having a (meth)acryloyl group at one end, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.Type: GrantFiled: June 28, 1995Date of Patent: May 14, 1996Assignee: Toagosei Chemical Industry Co., Ltd.Inventors: Yoshio Mori, Shiro Kojima
-
Patent number: 5502114Abstract: The present invention provides a linear polyolefin wherein one of the terminals of linear polypropylene or linear ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit or styrene derivative unit to give a substantially monodipersed system. The feature thereof consists in such a linear polyolefin in which the terminal of linear polypropylene or linear ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit or styrene derivative unit. For the production thereof, there are used methacrylic acid chloride, acrylic acid chloride, ethylene glycol dimethacrylate, etc. as the (meth)acrylic derivative, and divinylbenzene, etc. as the styrene derivative.Type: GrantFiled: March 16, 1994Date of Patent: March 26, 1996Assignee: Tonen CorporationInventors: Naomi Murakami, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
-
Patent number: 5494974Abstract: Disclosed is a reactive particulate resin which is characterized by each particle thereof having a core of three-dimensionally crosslinked resin having a degree of crosslinking from 0.05 to 2.0 mmol/g, and a shell formed thereon having a radical-polymerizable ethylenic unsaturated bond and is formed by polymerization of one or more polyfunctional monomers (A) and one or more non-aromatic radical-polymerizable monomers (B), the polyfunctional monomer (A) having in the molecule (a) at least one species of 1-monosubstituted and 1,1-disubstituted radical-polymerizable ethylenic unsaturated bonds and also (b) at least one of at least one species of 1,2-disubstituted, 1,1,2-trisubstituted, and 1,1,2,2-tetrasubstituted radical-polymerizable ethylenic unsaturated bonds.Type: GrantFiled: June 3, 1994Date of Patent: February 27, 1996Assignees: Ferro Enamels (Japan) Limited, Nippon Paint Co., Ltd.Inventors: Yasumasa Asanaka, Hiroshi Takeuchi, Masanori Ohiwa, Tohru Nakatsuka, Shuhei Yamoto
-
Patent number: 5494973Abstract: In a first step of this process an elastomer latex is prepared in aqueous emulsion in the presence of at least one ionic surfactant and at least one ethylenically unsaturated monomer; then in a second step at least one vinyl monomer, which is insoluble in water or sparingly soluble in water, is added to the latex thus obtained and the ionic charges introduced by the said latex are neutralised by adding to the mixture of latex and monomer at least one transfer agent carrying ionic charges opposite to those of the surfactant used in the first step, in order to effect the transfer of particles of the latex into the vinyl monomer; then in a third step the aqueous phase is separated from the organic phase comprising the latex and the vinyl monomer; and in a fourth step the bulk polymerisation of the organic phase is carried out in such a way as to obtain the cast sheet after cooling and release from the mould.Type: GrantFiled: January 9, 1995Date of Patent: February 27, 1996Assignee: Elf Atochem S.A.Inventors: Philippe Heim, Patrice Gaillard
-
Patent number: 5494508Abstract: A method is disclosed for improving the erasability of erasable marking compositions, while maintaining the opacity of the coating and without producing burnishing, by incorporating into the compositions voided latex particles having a shell polymerized from either:(1) at least about 25% by weight, based on the weight of the shell, of a crosslinking comonomer;(2) at least about 5% by weight, based on the weight of the shell, of a crosslinking comonomer, when at least about 50% by weight of methyl methacrylate is used as a comonomer in the shell.An improved liquid marking composition is also disclosed.Type: GrantFiled: May 24, 1995Date of Patent: February 27, 1996Assignee: Rohm and Haas CompanyInventor: Martin Vogel
-
Patent number: 5455306Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable compound, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.Type: GrantFiled: February 28, 1994Date of Patent: October 3, 1995Assignee: Toagosei Chemical Industry Co., Ltd.Inventors: Yoshio Mori, Shiro Kojima
-
Patent number: 5447560Abstract: A method is disclosed for improving the erasability of erasable marking compositions, while maintaining the opacity of the coating and without producing burnishing, by incorporating into the compositions voided latex particles having a shell polymerized from either:(1) at least about 25% by weight, based on the weight of the shell, of a crosslinking comonomer;(2) at least about 5% by weight, based on the weight of the shell, of a crosslinking comonomer, when at least about 50% by weight of methyl methacrylate is used as a comonomer in the shell.An improved liquid marking composition is also disclosed.Type: GrantFiled: March 3, 1994Date of Patent: September 5, 1995Assignee: Rohn and Haas CompanyInventor: Martin Vogel
-
Patent number: 5424370Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.Type: GrantFiled: February 1, 1994Date of Patent: June 13, 1995Assignee: Sumitomo Chemical Company, Ltd.Inventors: Kanki Matsumoto, Shinji Date
-
Patent number: 5409776Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..Type: GrantFiled: February 1, 1994Date of Patent: April 25, 1995Assignee: Mitsui Tomatsu Chemicals, IncorporatedInventors: Kousuke Someya, Akihiro Yamazaki, Futoshi Hoshino, Takeshi Yanagihara
-
Patent number: 5408007Abstract: A rubber composition permits good adhesion upon crosslinking to fiber materials and offers good adhesion after thermal aging. The rubber composition includes about 1/10 to about 1/1000 mol of an organic peroxide and either about 0.5 or about 10 parts by weight of an organic compound having two or more acrylate groups or methacrylate groups and one or more carboxyl groups in the molecular structure or about 1 to about 30 parts by weight of a carboxy-modified rubber per 100 parts by weight of a rubber crosslinkable with the organic peroxide.Type: GrantFiled: May 22, 1992Date of Patent: April 18, 1995Assignee: Mitsuboshi Belting Ltd.Inventors: Takahide Mizuno, Masayoshi Nakajima, Takashi Hamada, Nobutake Osako, Kasutoshi Ishida
-
Patent number: 5408003Abstract: A styrene resin composition comprising a crosslinked styrene resin and uniformly dispersed therein an uncrosslinked resin capable of being extracted with an organic solvent, the amount of the uncrosslinked resin being from 3 to 50% by weight based on the total amount of the composition; and a method of producing a molding of a styrene resin composition, which method comprises the step of subjecting to cast polymerization a liquid mixture comprising: (a) a styrene monomer in an amount of 30% by weight or more based on the total amount of the ingredients (a), (b), and (c); (b) a monofunctional monomer having one radical-polymerizable double bond in the molecule, in an amount less than 70% by weight based on the total amount of the ingredients (a), (b), and (c); (c) a polyfunctional monomer having at least two radical-polymerizable double bonds in the molecule, in an amount of from 0.Type: GrantFiled: April 30, 1993Date of Patent: April 18, 1995Assignee: Sumitomo Chemical Company, LimitedInventors: Satoshi Honda, Kazuhiro Yokoo, Hideaki Matsuura
-
Patent number: 5401806Abstract: A biocompatible moldable curable polymer/monomer system capable of curing at ambient temperatures to provide an elastomer product while producing a lower exotherm than previously used systems. The system includes an alkyl acrylate or methacrylate homopolymer or copolymer; a monomer mixture of higher alkylacrylate or methacrylate combined with one or more of acrylic acid, methacrylic acid and their lower alkyl esters; and a plasticizer and optionally cross-linking agents, anti-tack agents, and activators or photoinitiators. The moldable systems is a dough used for making earmoulds and earpieces or in fabrication of prostheses.Type: GrantFiled: July 19, 1993Date of Patent: March 28, 1995Assignee: The Secretary of State for Health in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Michael Braden, Allison O. Okpojo
-
Patent number: 5401803Abstract: Additive compositions comprising ethylene-vinyl acetate copolymers suitable for use in molding compositions are disclosed. The ethylene-vinyl acetate copolymers have a low degree of crystallinity which can provide a desirable balance of pigmentability, shrinkage resistance and solubility in styrene when used in molding compositions containing the ethylene-vinyl acetate copolymers.Type: GrantFiled: December 23, 1993Date of Patent: March 28, 1995Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Gary C. Rex
-
Patent number: 5382633Abstract: A modified polymer is described comprising a thermoplastic polymer composition comprising a graft copolymer between (1) a preformed thermoplastic polymer and (2) a monomer composition comprising (a) at least one polymerisable monomer containing a polymerisable group and at least one functional polymer-modifying group and (b) at least one comonomer containing at least two polymerisable groups, said copolymer being substantially free of unbound monomer. Such polymers can be produced by reacting together, in a melt and in the presence of free radicals whilst applying shear to the melt, the preformed thermoplastic polymer to be modified, the polymerisable monomer, and the comonomer, thereby to graft said monomer to said preformed polymer leaving substantially no unbound monomer, the reaction being continued for a period of time sufficient to produce a graft copolymer that is thermoplastic and can be blended with an unmodified polymer. A free radical generator can be added, if desired.Type: GrantFiled: April 8, 1991Date of Patent: January 17, 1995Assignee: 3i Research Exploitation LimitedInventors: Gerald Scott, Sahar Al-Malaika
-
Patent number: 5374684Abstract: Clusters of water-swellable polymer particles, having high rates of absorbency without gel-blocking are prepared by suspending water-swellable polymer particles in an inert hydrophobic liquid, such as hydrocarbon, and slowly adding to the particles a suspension of an aqueous solution optionally containing an .alpha.,.beta.-ethylenically unsaturated monomer in an inert hydrophobic liquid.Type: GrantFiled: September 1, 1993Date of Patent: December 20, 1994Assignee: The Dow Chemical CompanyInventor: Eva F. Tai
-
Patent number: 5362807Abstract: An acrylic molded product comprising an acrylic polymer coagulated material having excellent characteristics in impact resistance, optical properties, and hydrothermal resistance; an acrylic polymer coagulated material used for the preparation thereof; an composition comprising thereof; and a process for manufacture thereof; characterized by using an emulsion polymerization and a polymer with multiphase structured material comprising a hard phase and a soft phase and being freeze-coagulated.Type: GrantFiled: December 14, 1993Date of Patent: November 8, 1994Assignee: Kuraray Co., Ltd.Inventors: Kouichi Nogura, Kouichi Fujie, Chouji Suga, Naokiyo Inomata, Mitsuo Ootani
-
Patent number: 5362813Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macrononomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing CO.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer. The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.Type: GrantFiled: December 22, 1993Date of Patent: November 8, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Joseph A. Antonelli, Christopher Scopazzi
-
Patent number: 5362804Abstract: An unsaturated polyester resin composition for the production of cured molded article which comprises:an unsaturated polyester resin; anda core-shell polymer as a low shrinking agent which comprises:(a) a cross-linked core layer polymerized from a first monomer comprising an aromatic vinyl monomer in an amount of not less 50% by weight, the core layer being contained in the core-shell polymer in an amount of 50-90% by weight; and(b) a shell layer polymerized from a monomer comprising methyl methacrylate in an amount of not less 50% by weight;and the core-shell polymer having a refractive index in the range of 1.52-1.58 and within .+-.0.02 from the refractive index of the cured material of the unsaturated polyester resin.Type: GrantFiled: February 24, 1993Date of Patent: November 8, 1994Assignee: Takeda Chemical Industries, Ltd.Inventors: Junji Oshima, Susumu Okatani, Koichi Akiyama, Masato Sakurai
-
Patent number: 5349017Abstract: A polyvinyl chloride resin composition comprising (i) 100 parts by weight of a polyvinyl chloride resin and (ii) 2 to 40 parts by weight of a multi-stage copolymer obtained by polymerizing resin component formable monomers in the range of from more than 30 parts by weight to 50 parts by weight in three stages onto 50-70 parts by weight of a butadiene elastomer having a glass transition temperature ranging from -40.degree. C. to 5.degree. C. obtained by a copolymerization of a monomer mixture of 70 to 90% by weight of butadiene, 10 to 30 percent by weight of an aromatic vinyl monomer and a polyfunctional monomer added in an amount corresponding to 3 to 10 parts by weight per 100 parts by weight of the total amount of the butadiene and aromatic vinyl monomer.Type: GrantFiled: December 1, 1992Date of Patent: September 20, 1994Assignee: Mitsubishi Rayon Company Ltd.Inventors: Koji Matsumoto, Masaru Morimoto, Masahiro Osuka, Naomi Uno
-
Patent number: 5346961Abstract: A process for crosslinking comprising (a) introducing into a reactor, under crosslinking conditions, a mixture comprising(i) one or more polyolefins;(ii) organic peroxide;(iii) an ester, ether, or ketone containing two or more unsaturated groups; and(iv) a compound having the formula: ##STR1## wherein R=hydrogen, methyl, or ethyl; R.sup.1 =an alkylene having 1 to 6 carbon atoms;andR.sup.2 =an alkyl having 8 or more carbon atoms or Si(R.sup.3).sub.3 wherein R.sup.3 is hydrogen or alkoxy having 1 to 6 carbon atoms; each R.sup.3 is the same or different; and at least one R.sup.3 is an alkoxy,and (b) crosslinking the polyolefin(s).Type: GrantFiled: April 7, 1993Date of Patent: September 13, 1994Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Richard G. Shaw, Paul J. Caronia
-
Patent number: 5344889Abstract: The invention relates to a heat-sealable plastic film PF with an at least two-stage construction ranging in thickness up to 400 micrometer, that is suitable for tightly sealing plastic containers, comprising:a) a high molecular weight or crosslinked polymer P with a molecular weight in excess of 50,000 and a glass transition point Tg of <10.degree. C.; andb) a copolymer CP with a glass transition point Tg higher than 20.degree. C. and where said copolymer comprises.alpha.) 20 to 80% by weight of at least one monomer of Formula I ##STR1## wherein R.sub.1 stands for methyl or ethyl (preferably methyl); .beta.) 80 to 20% by weight of at least one monomer of Formula II ##STR2## wherein R.sub.2 stands for a C.sub.4-18 alkyl residue, preferably C.sub.4-12 or a C.sub.4-12 cycloalkyl residue different from cyclopentyl or cyclohexyl; and.gamma.Type: GrantFiled: December 17, 1992Date of Patent: September 6, 1994Assignee: Rohm GmbH Chemische FabrikInventors: Werner Siol, Ulrich Terbrack
-
Patent number: 5338804Abstract: Disclosed is a methacrylic resin cast plate which is comprised of 100 parts by weight of [I] polymethyl methacrylate or a methyl methacrylate copolymer containing at least 90% by weight of methyl methacrylate units and, dispersed therein, a graft copolymer [IV] obtained by graft-polymerizing a hard resin component [III] containing at least 90% by weight of methyl methacrylate units onto a crosslinked rubbery copolymer [II] containing at least 45% by weight of butyl acrylate units and having an average particle diameter of 0.1 to 1 .mu.m, the amount of the graft copolymer [IV] being 2 to 30 parts by weight as the amount of the crosslinked rubbery copolymer.The methacrylic resin cast plate has a high transparency and impact resistance.Type: GrantFiled: July 17, 1992Date of Patent: August 16, 1994Assignee: Mitsubishi Rayon Company, Inc.Inventors: Akihiro Toritani, Suehiro Tayama, Yasunori Kawachi
-
Patent number: 5328947Abstract: A two-part adhesive consisting of a first liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.1 to 20 parts by weight of an organic peroxide and a second liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.05 to 15 parts by weight of a reducing agent, wherein either one or both of the first and second liquids contain from 0.4 to 5% by weight of water, and the content of water is more than 0.2% by weight based on the total amount of the first and second liquids.Type: GrantFiled: December 23, 1992Date of Patent: July 12, 1994Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Koichi Taguchi, Kinpei Iwata, Hideki Matsudo
-
Patent number: 5310811Abstract: Free radically curable rubbers are crosslinked with the aid of a free radical initiator and a co-curing agent, which is an acrylate or methacrylate ester of a hydroxybenzene or hydroxynaphthalene compound containing two or more hydroxyl groups, at least two of which are esterified. The rubbers which are used in the present invention are natural rubber and synthetic rubbers derived from a diene monomer. Preferred co-curing agents are acrylate and methacrylate esters of hydroxybenzene compounds in which the ester contains two or three acrylate or methacrylate groups per molecule. The amount of co-curing agent may be about 1-50 parts by weight per one hundred parts by weight of rubber (phr). Outstanding abrasion resistance and air oven aging are observed.Type: GrantFiled: September 22, 1993Date of Patent: May 10, 1994Assignee: The Goodyear Tire & Rubber CompanyInventors: Kirkwood S. Cottman, Kevin L. Rollick
-
Patent number: 5310807Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macromonomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing Co.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer.The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.Type: GrantFiled: December 30, 1992Date of Patent: May 10, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Joseph A. Antonelli, Christopher Scopazzi
-
Patent number: 5306777Abstract: An acrylic molded product comprising an acrylic polymer coagulated material having excellent characteristics in impact resistance, optical properties, and hydrothermal resistance; an acrylic polymer coagulated material used for the preparation thereof; an composition comprising thereof; and a process for manufacture thereof; characterized by using an emulsion polymerization and a polymer with multiphase structured material comprising a hard phase and a soft phase and being freeze-coagulated.Type: GrantFiled: July 17, 1991Date of Patent: April 26, 1994Assignee: Kuraray Co., Ltd.Inventors: Kouichi Nogura, Kouichi Fujie, Chouji Suga, Naokiyo Inomata, Mitsuo Ootani
-
Patent number: 5306776Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.Type: GrantFiled: April 28, 1993Date of Patent: April 26, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Kanki Matsumoto, Shinji Date
-
Patent number: 5294676Abstract: A methacrylic resin composition with improved tacky adhesion comprising 100 parts by weight of a partially cross-linked polymer gel obtained by partially polymerizing a mixture comprising (A) 40 to 99% by weight of unsaturated monomer mixtures with or without containing the polymers thereof dissolved and (B) 60 to 1% by weight of a cross-linking agent, thereby allowing the total polymer content to be kept not exceeding 80% by weight, and increased by 4 to 62% by weight over the polymer content of said mixture, and 1 to 100 parts by weight of a syrup mainly composed of alkyl methacrylates containing the polymers thereof dissolved.Type: GrantFiled: April 30, 1990Date of Patent: March 15, 1994Assignee: Kuraray Co., Ltd.Inventors: Michio Chatani, Tadayuki Tsuchiya, Kazuo Ohse, Akio Hara
-
Patent number: 5292818Abstract: According to the present invention, a production method of a carrier appropriate for cation exchange liquid chromatography and a method for determining glycosylated hemoglobins using the carrier obtained by the production method are provided.The production method of the carrier comprises the steps of providing hydrophobic particles to which a polymerization initiator is adhered; and adding a polymerizable monomer having a carboxyl group to an aqueous dispersion in which the hydrophobic crosslinked polymer particles are dispersed and polymerizing the monomer on surfaces of the hydrophobic crosslinked polymer particles, thereby obtaining polymer particles the surfaces of which are coated with polymer layers having carboxyl groups.Type: GrantFiled: July 20, 1982Date of Patent: March 8, 1994Assignee: Sekisui Kagaku Kogyo Kabushiki KaishaInventors: Kazuyuki Oishi, Kazutoshi Yamazaki, Toshiki Kawabe, Masahiro Takechi, Makoto Takahara
-
Patent number: 5284495Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of anhydrides and one or more of the following long-chain diols: aminodiols, diaminodiols, amidodiols, with optional termonomers.Type: GrantFiled: September 17, 1992Date of Patent: February 8, 1994Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
-
Patent number: 5272213Abstract: This invention pertains to scorch retardant systems for peroxide curable elastomers. Polyunsaturated monomers copolymerizable with the elastomer in the presence of peroxides are mixed with hydroquinone and sulfenamides and incorporated into elastomer formulations. The formulations are milled and cured. Excellent Mooney scorch times and hardness values, as well as other physical properties are obtained.Type: GrantFiled: May 14, 1992Date of Patent: December 21, 1993Assignee: Air Products and Chemicals, Inc.Inventors: Eric Knowles, David A. Cornforth, Francis M. Carney
-
Patent number: 5270120Abstract: A data-carrying laminate such as a credit card or identity card comprises a sheet of cellulosic material or synthetic material and a thermoplastic polymeric film, at least one of said sheet and said thermoplastic film carrying data, said sheet and said thermoplastic film being bonded together by a cured adhesive layer obtained by curing a solid film adhesive comprising (A) a solid polymer of a vinyl carboxylic acid and (B) a curable material having at least one acrylate or methacrylate group.Type: GrantFiled: July 14, 1992Date of Patent: December 14, 1993Assignee: Ciba-Geigy CorporationInventors: Christopher M. Andrews, Edward Irving
-
Patent number: 5248733Abstract: Matte vinyl chloride polymers are prepared by suspension polymerizing a vinyl chloride monomer or a vinyl monomer mixture mainly comprising vinyl chloride in an aqueous medium in the presence of (A) a polyfunctional monomer having at least two ethylenic double bonds in a molecule and (B) a polymeric matting agent containing 3 to 25% by weight of a tetrahydrofuran-insoluble gel fraction. The polymers are effectively moldable and present uniform matte effect.Type: GrantFiled: July 8, 1991Date of Patent: September 28, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Kitamura, Ichiro Kaneko
-
Patent number: 5247025Abstract: Graft copolymers obtained byA) emulsion polymerization of from 5 to 35% by weight of a monomer mixture ofa.sub.1) 60-80% by weight of one or more vinylaromatic monomers,a.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,B) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage A), of 20-45% by weight of a monomer mixture ofb.sub.1) 50-75% by weight of one or more vinylaromatic monomers,b.sub.2) 25-50% by weight of one or more C.sub.1 -C.sub.18 -alkyl acrylates,C) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage B), of 5-35% by weight of a monomer mixture ofc.sub.1) 60-80% by weight of one or more vinylaromatic monomers,c.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,D) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage C), of 15-45% by weight of a monomer mixture ofd.sub.1) 80-99.9% by weight of one or more C.sub.1 -C.sub.Type: GrantFiled: March 2, 1992Date of Patent: September 21, 1993Assignee: BASF AktiengesellschaftInventors: Hans-Helmut Goertz, Guenter Hatzmann, Werner Oschmann
-
Patent number: 5239007Abstract: Oil-absorbent compositions are disclosed. The compositions are crosslinked interpolymers of an alkylated styrene and a rubber. The compositions of the invention have high absorption capacities and absorption rates compared with prior-art compositions.Type: GrantFiled: October 22, 1991Date of Patent: August 24, 1993Assignee: ARCO Chemical Technology, L.P.Inventor: Bi Le-Khac
-
Patent number: 5223568Abstract: A forming process for producing a hard shaped molded article that includes subjecting a moldable thermosetting composition to a high temperature cure condition at a temperature greater than about 250.degree. C. and less than the decomposition temperature of the composition to form a crosslinked polymeric network. In particular, the invention features a forming process for producing a hard shaped molded article that includes the steps of(a) providing a moldable thermosetting composition that includes 1) a polybutadiene or polyisoprene resin which is a liquid at room temperature and which has a molecular weight less than 5,000 and a large number of pendent vinyl groups and 2) a solid butadiene- or isoprene-containing polymer (e.g, a thermoplastic elastomer);(b) forming the composition into a shape; and(c) curing the composition to produce the article including subjecting the composition to a high temperature cure condition at a temperature greater than about 250.degree. C.Type: GrantFiled: May 9, 1989Date of Patent: June 29, 1993Assignee: Rogers CorporationInventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins
-
Patent number: 5219945Abstract: This application discloses linear methacrylic ABC triblock polymers in which the composition of each of the three blocks is different and wherein at least one of the blocks is hydrophobic and at least one of the blocks is hydrophilic.Type: GrantFiled: February 20, 1992Date of Patent: June 15, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Ira B. Dicker, Walter R. Hertler, Sheau-Hwa Ma
-
Patent number: 5206299Abstract: There is disclosed a core-shell polymer which comprises:(a) a core comprising an elastomeric polymer having a glass transition temperature of not more than -30.degree. C. in an amount of 50-90% by weight;(b) an intermediate layer comprising a polymer having a glass transition temperature of not less than 60.degree. C. in an amount of 5-30% by weight; and(c) a shell comprising an aromatic vinyl polymer in an amount of 5-30% by weight,each based on the core-shell polymer, and the total of the core, the intermediate layer and the shell amounting to 100% by weight.Preferably, the core is composed of polybutadiene or polyalkyl acrylate wherein the alkyl has 2-8 carbon atoms, the intermediate layer of polymethyl methacrylate and the shell of polystyrene.A high impact polyphenylene ether resin composition is further disclosed which contains such a core-shell polymer as an impact modifier.Type: GrantFiled: March 16, 1992Date of Patent: April 27, 1993Assignee: Takeda Chemical Industries, Ltd.Inventors: Junji Oshima, Takao Teraoka, Minoru Yamada, Shizuo Togo, Goro Shimaoka, Kazuhiko Ishii
-
Patent number: 5187235Abstract: There is provided a radiation-curable, pressure-sensitive-adhesive layer formed of at least one monomer having a glass-transition temperature greater than about -25.degree. C. and an entanglement molecular-weight less than about 20,000; at least one monomer having a glass-transistion temperature less than about -25.degree. C. and an entanglement molecular-weight greater than about 20,000; and at least one tackifier monomer having a glass-transistion temperature greater than -25.degree. C. and an entanglement molecular-weight of at least about 20,000 and present in an interpolymerized amount sufficient to form an interpolymer having a glass-transition temperature less than about -25.degree. C. and an entanglement molecular-weight greater than about 20,000. Cure is preferably by electron beam, and a multifunctional monomer is preferably provided to improve shear.Type: GrantFiled: December 27, 1991Date of Patent: February 16, 1993Assignee: Avery Dennison CorporationInventors: Binoy K. Bordoloi, Sebastian S. Plamthottan, Yehuda Ozari, Robert V. Ham
-
Patent number: 5182332Abstract: Disclosed is a dental composition comprising a (meth)acrylic ester compound as the principal component and containing a polymerization initiator, which is characterized by having incorporated therein a grafted rubber obtained by polymerizing at least one ethylenically unsaturated monomer in the presence of a rubber. This dental composition can be cured to yield a cured product having excellent strength properties and, therefore, is particularly useful in applications such as a molar restoration material and a denture base resin.Type: GrantFiled: August 1, 1990Date of Patent: January 26, 1993Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Naoki Yamamoto, Nobuhiro Mukai, Hitoshi Ige, Junko Atarashi
-
Patent number: 5153065Abstract: An oriented elastomeric filament spun from a thermoplastic elastomeric material selected from the group consisting of a block copolymer of polybutylene terephthalate and polytetramethylene glycol, a block copolymer of polybutylene terephthalate/polybutylene isophthalate and polyethylene glycol/polypropylene glycol, a block copolymer of polybutylene terephthalate/polyhexene terephthalate and polytetramethylene glycol, and a block copolymer of polyurethane and polytetramethylene glycol, the mole fraction of the polybutylene terephthalate, polybutylene terephthalate/polybutylene isophthalate and polybutylene terephthalate/polyhexene terephthalate in the block copolymers is less than 0.5, the elastomeric filament is further oriented after the spinning by stretching at temperatures between 20.degree. C. to 120.degree. C.Type: GrantFiled: December 19, 1990Date of Patent: October 6, 1992Assignee: General Motors CorporationInventor: Ismat A. Abu-Isa
-
Patent number: 5143947Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from copolymers of 4-hydroxystyrene and an alkadiene or an allyl ester of an ethylenically unsaturated acid blended wit ethylenically unsaturated compounds.Type: GrantFiled: November 13, 1989Date of Patent: September 1, 1992Assignee: Hoechst Celanese CorporationInventor: Balaram Gupta
-
Patent number: 5130376Abstract: Compositions comprised of ultra-high molecular weight polyethylene slurried in a styrene monomer containing a styrene crosslinker and a free radical catalyst are disclosed. These slurries are subjected to heating in a mold whereby the polyethylene phase is dissolved in the styrene monomer and the styrene monomer is polymerized to form a shaped article. The polystyrene/polyethylene product has unique properties.Type: GrantFiled: April 23, 1990Date of Patent: July 14, 1992Assignee: Hercules IncorporatedInventor: Keith S. Shih
-
Patent number: 5110873Abstract: A thermosetting resin composition comprising(A) 60 to 95% by weight of a prepolymer or precopolymer selected from the group consisting of (A-1), (A-2) and (A-3) below,(A-1) a prepolymer of diallyl phthalate,(A-2) a precopolymer of diallyl terephthalate derived from diallyl terephthalate of the following formula (1) ##STR1## and an aromatic benzyl hydrocarbon having at least one hydrogen atom at the benzyl position and represented by the following formula (2) ##STR2## wherein each of R.sup.1 and R.sup.2 represents a member selected from the class consisting of a hydrogen atom and lower alkyl groups, and n is an integer of 1 to 3, and(A-3) a mixture of (A-1) and (A-2), and(B) 40 to 5% by weight of a polyacrylate or polymethacrylate of dipentaerythritol having at least 4 acryloyl or methacryloyl groups in the molecule and represented by the following formula ##STR3## wherein each R.sup.3 represents a hydrogen atom, --COCH.dbd.CH.sub.2 or ##STR4## and at least four R.sup.3 groups represents --COCH.dbd.CH.sub.Type: GrantFiled: March 21, 1991Date of Patent: May 5, 1992Assignee: Osaka Soda Co., Ltd.Inventors: Yoshimi Kono, Sabee Maeda