Ester Is Derived From A Polyol Patents (Class 525/305)
  • Patent number: 5567775
    Abstract: This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R.sub.4 is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; andb) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 22, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Hsien C. Wang, Irwin J. Gardner, James V. Fusco
  • Patent number: 5552491
    Abstract: A star-branched polymer comprising a core portion and polymeric arms. The core portion is obtained by anionic polymerization of at least one unsaturated acrylate or methacrylate ester of a polyol and the polymeric arms are obtained by anionic polymerization of at least one acrylic or methacrylic monomer.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: September 3, 1996
    Assignee: Ethyl Additives Corporation
    Inventors: Munmaya K. Mishra, Shailaja M. Shirodkar, Alfred K. Jung
  • Patent number: 5519083
    Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a non-functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a non-functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: May 21, 1996
    Assignee: Imperial Chemical Industries PLC
    Inventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
  • Patent number: 5519081
    Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: May 21, 1996
    Assignee: Imperial Chemical Industries PLC
    Inventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
  • Patent number: 5519064
    Abstract: Disclosed is a surface-modified polymeric adsorbent material comprising a porous post-crosslinked polymer as a substrate and at least one surface-modifying polymer. The porous post-crosslinked polymer comprises a polymer of at least one monoethylenically unsaturated monomer, wherein the polymer has been post-crosslinked in a swollen state in the presence of a Friedel-Crafts catalyst. A process for preparing the surface-modified polymeric adsorbent materials, and the use of these materials in the separation of organic compounds, enantioselective synthesis and resolution of racemic mixtures are also disclosed.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: May 21, 1996
    Assignee: The Dow Chemical Company
    Inventors: Richard T. Stringfield, Mladen Ladika
  • Patent number: 5516845
    Abstract: A thermoplastic basic polymers in pourable form are mixed with similarly pourable carrier polymers dispersable or soluble in the basic polymers with a cross-linking agent to produce cross-linked polymer moldings. These mutually compatible components are heated under further mixing to a reaction temperature above the melting range of the basic polymer and processed. The reaction of free radicals leads to bonds between polymer chains and/or the degradation of polymer chains.Porous carrier polymers which contain at least one organic peroxide and/or coagent incorporated in the fine pore structure as a fluid silane-free cross-linking agent are mixed in the basic polymer. Peroxide-containing carrier polymers are heated, coagent-containing carrier polymers are irradiated.The moldings are used for example for cable and sheath isolation, pipes for hot water lines and highly stressed injection moldings.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: May 14, 1996
    Assignee: Brugg Kabel AG
    Inventors: Ulrich Heese, Renato Salvel
  • Patent number: 5516834
    Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable polyester compound having a (meth)acryloyl group at one end, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: May 14, 1996
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5502114
    Abstract: The present invention provides a linear polyolefin wherein one of the terminals of linear polypropylene or linear ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit or styrene derivative unit to give a substantially monodipersed system. The feature thereof consists in such a linear polyolefin in which the terminal of linear polypropylene or linear ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit or styrene derivative unit. For the production thereof, there are used methacrylic acid chloride, acrylic acid chloride, ethylene glycol dimethacrylate, etc. as the (meth)acrylic derivative, and divinylbenzene, etc. as the styrene derivative.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: March 26, 1996
    Assignee: Tonen Corporation
    Inventors: Naomi Murakami, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
  • Patent number: 5494974
    Abstract: Disclosed is a reactive particulate resin which is characterized by each particle thereof having a core of three-dimensionally crosslinked resin having a degree of crosslinking from 0.05 to 2.0 mmol/g, and a shell formed thereon having a radical-polymerizable ethylenic unsaturated bond and is formed by polymerization of one or more polyfunctional monomers (A) and one or more non-aromatic radical-polymerizable monomers (B), the polyfunctional monomer (A) having in the molecule (a) at least one species of 1-monosubstituted and 1,1-disubstituted radical-polymerizable ethylenic unsaturated bonds and also (b) at least one of at least one species of 1,2-disubstituted, 1,1,2-trisubstituted, and 1,1,2,2-tetrasubstituted radical-polymerizable ethylenic unsaturated bonds.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: February 27, 1996
    Assignees: Ferro Enamels (Japan) Limited, Nippon Paint Co., Ltd.
    Inventors: Yasumasa Asanaka, Hiroshi Takeuchi, Masanori Ohiwa, Tohru Nakatsuka, Shuhei Yamoto
  • Patent number: 5494973
    Abstract: In a first step of this process an elastomer latex is prepared in aqueous emulsion in the presence of at least one ionic surfactant and at least one ethylenically unsaturated monomer; then in a second step at least one vinyl monomer, which is insoluble in water or sparingly soluble in water, is added to the latex thus obtained and the ionic charges introduced by the said latex are neutralised by adding to the mixture of latex and monomer at least one transfer agent carrying ionic charges opposite to those of the surfactant used in the first step, in order to effect the transfer of particles of the latex into the vinyl monomer; then in a third step the aqueous phase is separated from the organic phase comprising the latex and the vinyl monomer; and in a fourth step the bulk polymerisation of the organic phase is carried out in such a way as to obtain the cast sheet after cooling and release from the mould.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: February 27, 1996
    Assignee: Elf Atochem S.A.
    Inventors: Philippe Heim, Patrice Gaillard
  • Patent number: 5494508
    Abstract: A method is disclosed for improving the erasability of erasable marking compositions, while maintaining the opacity of the coating and without producing burnishing, by incorporating into the compositions voided latex particles having a shell polymerized from either:(1) at least about 25% by weight, based on the weight of the shell, of a crosslinking comonomer;(2) at least about 5% by weight, based on the weight of the shell, of a crosslinking comonomer, when at least about 50% by weight of methyl methacrylate is used as a comonomer in the shell.An improved liquid marking composition is also disclosed.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: February 27, 1996
    Assignee: Rohm and Haas Company
    Inventor: Martin Vogel
  • Patent number: 5455306
    Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable compound, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 3, 1995
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5447560
    Abstract: A method is disclosed for improving the erasability of erasable marking compositions, while maintaining the opacity of the coating and without producing burnishing, by incorporating into the compositions voided latex particles having a shell polymerized from either:(1) at least about 25% by weight, based on the weight of the shell, of a crosslinking comonomer;(2) at least about 5% by weight, based on the weight of the shell, of a crosslinking comonomer, when at least about 50% by weight of methyl methacrylate is used as a comonomer in the shell.An improved liquid marking composition is also disclosed.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: September 5, 1995
    Assignee: Rohn and Haas Company
    Inventor: Martin Vogel
  • Patent number: 5424370
    Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: June 13, 1995
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Kanki Matsumoto, Shinji Date
  • Patent number: 5409776
    Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: April 25, 1995
    Assignee: Mitsui Tomatsu Chemicals, Incorporated
    Inventors: Kousuke Someya, Akihiro Yamazaki, Futoshi Hoshino, Takeshi Yanagihara
  • Patent number: 5408007
    Abstract: A rubber composition permits good adhesion upon crosslinking to fiber materials and offers good adhesion after thermal aging. The rubber composition includes about 1/10 to about 1/1000 mol of an organic peroxide and either about 0.5 or about 10 parts by weight of an organic compound having two or more acrylate groups or methacrylate groups and one or more carboxyl groups in the molecular structure or about 1 to about 30 parts by weight of a carboxy-modified rubber per 100 parts by weight of a rubber crosslinkable with the organic peroxide.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: April 18, 1995
    Assignee: Mitsuboshi Belting Ltd.
    Inventors: Takahide Mizuno, Masayoshi Nakajima, Takashi Hamada, Nobutake Osako, Kasutoshi Ishida
  • Patent number: 5408003
    Abstract: A styrene resin composition comprising a crosslinked styrene resin and uniformly dispersed therein an uncrosslinked resin capable of being extracted with an organic solvent, the amount of the uncrosslinked resin being from 3 to 50% by weight based on the total amount of the composition; and a method of producing a molding of a styrene resin composition, which method comprises the step of subjecting to cast polymerization a liquid mixture comprising: (a) a styrene monomer in an amount of 30% by weight or more based on the total amount of the ingredients (a), (b), and (c); (b) a monofunctional monomer having one radical-polymerizable double bond in the molecule, in an amount less than 70% by weight based on the total amount of the ingredients (a), (b), and (c); (c) a polyfunctional monomer having at least two radical-polymerizable double bonds in the molecule, in an amount of from 0.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: April 18, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Honda, Kazuhiro Yokoo, Hideaki Matsuura
  • Patent number: 5401806
    Abstract: A biocompatible moldable curable polymer/monomer system capable of curing at ambient temperatures to provide an elastomer product while producing a lower exotherm than previously used systems. The system includes an alkyl acrylate or methacrylate homopolymer or copolymer; a monomer mixture of higher alkylacrylate or methacrylate combined with one or more of acrylic acid, methacrylic acid and their lower alkyl esters; and a plasticizer and optionally cross-linking agents, anti-tack agents, and activators or photoinitiators. The moldable systems is a dough used for making earmoulds and earpieces or in fabrication of prostheses.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: March 28, 1995
    Assignee: The Secretary of State for Health in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Michael Braden, Allison O. Okpojo
  • Patent number: 5401803
    Abstract: Additive compositions comprising ethylene-vinyl acetate copolymers suitable for use in molding compositions are disclosed. The ethylene-vinyl acetate copolymers have a low degree of crystallinity which can provide a desirable balance of pigmentability, shrinkage resistance and solubility in styrene when used in molding compositions containing the ethylene-vinyl acetate copolymers.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: March 28, 1995
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Gary C. Rex
  • Patent number: 5382633
    Abstract: A modified polymer is described comprising a thermoplastic polymer composition comprising a graft copolymer between (1) a preformed thermoplastic polymer and (2) a monomer composition comprising (a) at least one polymerisable monomer containing a polymerisable group and at least one functional polymer-modifying group and (b) at least one comonomer containing at least two polymerisable groups, said copolymer being substantially free of unbound monomer. Such polymers can be produced by reacting together, in a melt and in the presence of free radicals whilst applying shear to the melt, the preformed thermoplastic polymer to be modified, the polymerisable monomer, and the comonomer, thereby to graft said monomer to said preformed polymer leaving substantially no unbound monomer, the reaction being continued for a period of time sufficient to produce a graft copolymer that is thermoplastic and can be blended with an unmodified polymer. A free radical generator can be added, if desired.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: January 17, 1995
    Assignee: 3i Research Exploitation Limited
    Inventors: Gerald Scott, Sahar Al-Malaika
  • Patent number: 5374684
    Abstract: Clusters of water-swellable polymer particles, having high rates of absorbency without gel-blocking are prepared by suspending water-swellable polymer particles in an inert hydrophobic liquid, such as hydrocarbon, and slowly adding to the particles a suspension of an aqueous solution optionally containing an .alpha.,.beta.-ethylenically unsaturated monomer in an inert hydrophobic liquid.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: December 20, 1994
    Assignee: The Dow Chemical Company
    Inventor: Eva F. Tai
  • Patent number: 5362807
    Abstract: An acrylic molded product comprising an acrylic polymer coagulated material having excellent characteristics in impact resistance, optical properties, and hydrothermal resistance; an acrylic polymer coagulated material used for the preparation thereof; an composition comprising thereof; and a process for manufacture thereof; characterized by using an emulsion polymerization and a polymer with multiphase structured material comprising a hard phase and a soft phase and being freeze-coagulated.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: November 8, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Kouichi Nogura, Kouichi Fujie, Chouji Suga, Naokiyo Inomata, Mitsuo Ootani
  • Patent number: 5362813
    Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macrononomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing CO.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer. The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: November 8, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Christopher Scopazzi
  • Patent number: 5362804
    Abstract: An unsaturated polyester resin composition for the production of cured molded article which comprises:an unsaturated polyester resin; anda core-shell polymer as a low shrinking agent which comprises:(a) a cross-linked core layer polymerized from a first monomer comprising an aromatic vinyl monomer in an amount of not less 50% by weight, the core layer being contained in the core-shell polymer in an amount of 50-90% by weight; and(b) a shell layer polymerized from a monomer comprising methyl methacrylate in an amount of not less 50% by weight;and the core-shell polymer having a refractive index in the range of 1.52-1.58 and within .+-.0.02 from the refractive index of the cured material of the unsaturated polyester resin.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: November 8, 1994
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Junji Oshima, Susumu Okatani, Koichi Akiyama, Masato Sakurai
  • Patent number: 5349017
    Abstract: A polyvinyl chloride resin composition comprising (i) 100 parts by weight of a polyvinyl chloride resin and (ii) 2 to 40 parts by weight of a multi-stage copolymer obtained by polymerizing resin component formable monomers in the range of from more than 30 parts by weight to 50 parts by weight in three stages onto 50-70 parts by weight of a butadiene elastomer having a glass transition temperature ranging from -40.degree. C. to 5.degree. C. obtained by a copolymerization of a monomer mixture of 70 to 90% by weight of butadiene, 10 to 30 percent by weight of an aromatic vinyl monomer and a polyfunctional monomer added in an amount corresponding to 3 to 10 parts by weight per 100 parts by weight of the total amount of the butadiene and aromatic vinyl monomer.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: September 20, 1994
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Koji Matsumoto, Masaru Morimoto, Masahiro Osuka, Naomi Uno
  • Patent number: 5346961
    Abstract: A process for crosslinking comprising (a) introducing into a reactor, under crosslinking conditions, a mixture comprising(i) one or more polyolefins;(ii) organic peroxide;(iii) an ester, ether, or ketone containing two or more unsaturated groups; and(iv) a compound having the formula: ##STR1## wherein R=hydrogen, methyl, or ethyl; R.sup.1 =an alkylene having 1 to 6 carbon atoms;andR.sup.2 =an alkyl having 8 or more carbon atoms or Si(R.sup.3).sub.3 wherein R.sup.3 is hydrogen or alkoxy having 1 to 6 carbon atoms; each R.sup.3 is the same or different; and at least one R.sup.3 is an alkoxy,and (b) crosslinking the polyolefin(s).
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: September 13, 1994
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Richard G. Shaw, Paul J. Caronia
  • Patent number: 5344889
    Abstract: The invention relates to a heat-sealable plastic film PF with an at least two-stage construction ranging in thickness up to 400 micrometer, that is suitable for tightly sealing plastic containers, comprising:a) a high molecular weight or crosslinked polymer P with a molecular weight in excess of 50,000 and a glass transition point Tg of <10.degree. C.; andb) a copolymer CP with a glass transition point Tg higher than 20.degree. C. and where said copolymer comprises.alpha.) 20 to 80% by weight of at least one monomer of Formula I ##STR1## wherein R.sub.1 stands for methyl or ethyl (preferably methyl); .beta.) 80 to 20% by weight of at least one monomer of Formula II ##STR2## wherein R.sub.2 stands for a C.sub.4-18 alkyl residue, preferably C.sub.4-12 or a C.sub.4-12 cycloalkyl residue different from cyclopentyl or cyclohexyl; and.gamma.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: September 6, 1994
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 5338804
    Abstract: Disclosed is a methacrylic resin cast plate which is comprised of 100 parts by weight of [I] polymethyl methacrylate or a methyl methacrylate copolymer containing at least 90% by weight of methyl methacrylate units and, dispersed therein, a graft copolymer [IV] obtained by graft-polymerizing a hard resin component [III] containing at least 90% by weight of methyl methacrylate units onto a crosslinked rubbery copolymer [II] containing at least 45% by weight of butyl acrylate units and having an average particle diameter of 0.1 to 1 .mu.m, the amount of the graft copolymer [IV] being 2 to 30 parts by weight as the amount of the crosslinked rubbery copolymer.The methacrylic resin cast plate has a high transparency and impact resistance.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: August 16, 1994
    Assignee: Mitsubishi Rayon Company, Inc.
    Inventors: Akihiro Toritani, Suehiro Tayama, Yasunori Kawachi
  • Patent number: 5328947
    Abstract: A two-part adhesive consisting of a first liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.1 to 20 parts by weight of an organic peroxide and a second liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.05 to 15 parts by weight of a reducing agent, wherein either one or both of the first and second liquids contain from 0.4 to 5% by weight of water, and the content of water is more than 0.2% by weight based on the total amount of the first and second liquids.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: July 12, 1994
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Koichi Taguchi, Kinpei Iwata, Hideki Matsudo
  • Patent number: 5310811
    Abstract: Free radically curable rubbers are crosslinked with the aid of a free radical initiator and a co-curing agent, which is an acrylate or methacrylate ester of a hydroxybenzene or hydroxynaphthalene compound containing two or more hydroxyl groups, at least two of which are esterified. The rubbers which are used in the present invention are natural rubber and synthetic rubbers derived from a diene monomer. Preferred co-curing agents are acrylate and methacrylate esters of hydroxybenzene compounds in which the ester contains two or three acrylate or methacrylate groups per molecule. The amount of co-curing agent may be about 1-50 parts by weight per one hundred parts by weight of rubber (phr). Outstanding abrasion resistance and air oven aging are observed.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: May 10, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Kirkwood S. Cottman, Kevin L. Rollick
  • Patent number: 5310807
    Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macromonomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing Co.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer.The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: May 10, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Christopher Scopazzi
  • Patent number: 5306777
    Abstract: An acrylic molded product comprising an acrylic polymer coagulated material having excellent characteristics in impact resistance, optical properties, and hydrothermal resistance; an acrylic polymer coagulated material used for the preparation thereof; an composition comprising thereof; and a process for manufacture thereof; characterized by using an emulsion polymerization and a polymer with multiphase structured material comprising a hard phase and a soft phase and being freeze-coagulated.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: April 26, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Kouichi Nogura, Kouichi Fujie, Chouji Suga, Naokiyo Inomata, Mitsuo Ootani
  • Patent number: 5306776
    Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: April 26, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kanki Matsumoto, Shinji Date
  • Patent number: 5294676
    Abstract: A methacrylic resin composition with improved tacky adhesion comprising 100 parts by weight of a partially cross-linked polymer gel obtained by partially polymerizing a mixture comprising (A) 40 to 99% by weight of unsaturated monomer mixtures with or without containing the polymers thereof dissolved and (B) 60 to 1% by weight of a cross-linking agent, thereby allowing the total polymer content to be kept not exceeding 80% by weight, and increased by 4 to 62% by weight over the polymer content of said mixture, and 1 to 100 parts by weight of a syrup mainly composed of alkyl methacrylates containing the polymers thereof dissolved.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: March 15, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Michio Chatani, Tadayuki Tsuchiya, Kazuo Ohse, Akio Hara
  • Patent number: 5292818
    Abstract: According to the present invention, a production method of a carrier appropriate for cation exchange liquid chromatography and a method for determining glycosylated hemoglobins using the carrier obtained by the production method are provided.The production method of the carrier comprises the steps of providing hydrophobic particles to which a polymerization initiator is adhered; and adding a polymerizable monomer having a carboxyl group to an aqueous dispersion in which the hydrophobic crosslinked polymer particles are dispersed and polymerizing the monomer on surfaces of the hydrophobic crosslinked polymer particles, thereby obtaining polymer particles the surfaces of which are coated with polymer layers having carboxyl groups.
    Type: Grant
    Filed: July 20, 1982
    Date of Patent: March 8, 1994
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuyuki Oishi, Kazutoshi Yamazaki, Toshiki Kawabe, Masahiro Takechi, Makoto Takahara
  • Patent number: 5284495
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of anhydrides and one or more of the following long-chain diols: aminodiols, diaminodiols, amidodiols, with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: February 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5272213
    Abstract: This invention pertains to scorch retardant systems for peroxide curable elastomers. Polyunsaturated monomers copolymerizable with the elastomer in the presence of peroxides are mixed with hydroquinone and sulfenamides and incorporated into elastomer formulations. The formulations are milled and cured. Excellent Mooney scorch times and hardness values, as well as other physical properties are obtained.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: December 21, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Eric Knowles, David A. Cornforth, Francis M. Carney
  • Patent number: 5270120
    Abstract: A data-carrying laminate such as a credit card or identity card comprises a sheet of cellulosic material or synthetic material and a thermoplastic polymeric film, at least one of said sheet and said thermoplastic film carrying data, said sheet and said thermoplastic film being bonded together by a cured adhesive layer obtained by curing a solid film adhesive comprising (A) a solid polymer of a vinyl carboxylic acid and (B) a curable material having at least one acrylate or methacrylate group.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: December 14, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Christopher M. Andrews, Edward Irving
  • Patent number: 5248733
    Abstract: Matte vinyl chloride polymers are prepared by suspension polymerizing a vinyl chloride monomer or a vinyl monomer mixture mainly comprising vinyl chloride in an aqueous medium in the presence of (A) a polyfunctional monomer having at least two ethylenic double bonds in a molecule and (B) a polymeric matting agent containing 3 to 25% by weight of a tetrahydrofuran-insoluble gel fraction. The polymers are effectively moldable and present uniform matte effect.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 28, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hajime Kitamura, Ichiro Kaneko
  • Patent number: 5247025
    Abstract: Graft copolymers obtained byA) emulsion polymerization of from 5 to 35% by weight of a monomer mixture ofa.sub.1) 60-80% by weight of one or more vinylaromatic monomers,a.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,B) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage A), of 20-45% by weight of a monomer mixture ofb.sub.1) 50-75% by weight of one or more vinylaromatic monomers,b.sub.2) 25-50% by weight of one or more C.sub.1 -C.sub.18 -alkyl acrylates,C) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage B), of 5-35% by weight of a monomer mixture ofc.sub.1) 60-80% by weight of one or more vinylaromatic monomers,c.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,D) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage C), of 15-45% by weight of a monomer mixture ofd.sub.1) 80-99.9% by weight of one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: September 21, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Helmut Goertz, Guenter Hatzmann, Werner Oschmann
  • Patent number: 5239007
    Abstract: Oil-absorbent compositions are disclosed. The compositions are crosslinked interpolymers of an alkylated styrene and a rubber. The compositions of the invention have high absorption capacities and absorption rates compared with prior-art compositions.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: August 24, 1993
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5223568
    Abstract: A forming process for producing a hard shaped molded article that includes subjecting a moldable thermosetting composition to a high temperature cure condition at a temperature greater than about 250.degree. C. and less than the decomposition temperature of the composition to form a crosslinked polymeric network. In particular, the invention features a forming process for producing a hard shaped molded article that includes the steps of(a) providing a moldable thermosetting composition that includes 1) a polybutadiene or polyisoprene resin which is a liquid at room temperature and which has a molecular weight less than 5,000 and a large number of pendent vinyl groups and 2) a solid butadiene- or isoprene-containing polymer (e.g, a thermoplastic elastomer);(b) forming the composition into a shape; and(c) curing the composition to produce the article including subjecting the composition to a high temperature cure condition at a temperature greater than about 250.degree. C.
    Type: Grant
    Filed: May 9, 1989
    Date of Patent: June 29, 1993
    Assignee: Rogers Corporation
    Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins
  • Patent number: 5219945
    Abstract: This application discloses linear methacrylic ABC triblock polymers in which the composition of each of the three blocks is different and wherein at least one of the blocks is hydrophobic and at least one of the blocks is hydrophilic.
    Type: Grant
    Filed: February 20, 1992
    Date of Patent: June 15, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ira B. Dicker, Walter R. Hertler, Sheau-Hwa Ma
  • Patent number: 5206299
    Abstract: There is disclosed a core-shell polymer which comprises:(a) a core comprising an elastomeric polymer having a glass transition temperature of not more than -30.degree. C. in an amount of 50-90% by weight;(b) an intermediate layer comprising a polymer having a glass transition temperature of not less than 60.degree. C. in an amount of 5-30% by weight; and(c) a shell comprising an aromatic vinyl polymer in an amount of 5-30% by weight,each based on the core-shell polymer, and the total of the core, the intermediate layer and the shell amounting to 100% by weight.Preferably, the core is composed of polybutadiene or polyalkyl acrylate wherein the alkyl has 2-8 carbon atoms, the intermediate layer of polymethyl methacrylate and the shell of polystyrene.A high impact polyphenylene ether resin composition is further disclosed which contains such a core-shell polymer as an impact modifier.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: April 27, 1993
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Junji Oshima, Takao Teraoka, Minoru Yamada, Shizuo Togo, Goro Shimaoka, Kazuhiko Ishii
  • Patent number: 5187235
    Abstract: There is provided a radiation-curable, pressure-sensitive-adhesive layer formed of at least one monomer having a glass-transition temperature greater than about -25.degree. C. and an entanglement molecular-weight less than about 20,000; at least one monomer having a glass-transistion temperature less than about -25.degree. C. and an entanglement molecular-weight greater than about 20,000; and at least one tackifier monomer having a glass-transistion temperature greater than -25.degree. C. and an entanglement molecular-weight of at least about 20,000 and present in an interpolymerized amount sufficient to form an interpolymer having a glass-transition temperature less than about -25.degree. C. and an entanglement molecular-weight greater than about 20,000. Cure is preferably by electron beam, and a multifunctional monomer is preferably provided to improve shear.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: February 16, 1993
    Assignee: Avery Dennison Corporation
    Inventors: Binoy K. Bordoloi, Sebastian S. Plamthottan, Yehuda Ozari, Robert V. Ham
  • Patent number: 5182332
    Abstract: Disclosed is a dental composition comprising a (meth)acrylic ester compound as the principal component and containing a polymerization initiator, which is characterized by having incorporated therein a grafted rubber obtained by polymerizing at least one ethylenically unsaturated monomer in the presence of a rubber. This dental composition can be cured to yield a cured product having excellent strength properties and, therefore, is particularly useful in applications such as a molar restoration material and a denture base resin.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: January 26, 1993
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Naoki Yamamoto, Nobuhiro Mukai, Hitoshi Ige, Junko Atarashi
  • Patent number: 5153065
    Abstract: An oriented elastomeric filament spun from a thermoplastic elastomeric material selected from the group consisting of a block copolymer of polybutylene terephthalate and polytetramethylene glycol, a block copolymer of polybutylene terephthalate/polybutylene isophthalate and polyethylene glycol/polypropylene glycol, a block copolymer of polybutylene terephthalate/polyhexene terephthalate and polytetramethylene glycol, and a block copolymer of polyurethane and polytetramethylene glycol, the mole fraction of the polybutylene terephthalate, polybutylene terephthalate/polybutylene isophthalate and polybutylene terephthalate/polyhexene terephthalate in the block copolymers is less than 0.5, the elastomeric filament is further oriented after the spinning by stretching at temperatures between 20.degree. C. to 120.degree. C.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: October 6, 1992
    Assignee: General Motors Corporation
    Inventor: Ismat A. Abu-Isa
  • Patent number: 5143947
    Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from copolymers of 4-hydroxystyrene and an alkadiene or an allyl ester of an ethylenically unsaturated acid blended wit ethylenically unsaturated compounds.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: September 1, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Balaram Gupta
  • Patent number: 5130376
    Abstract: Compositions comprised of ultra-high molecular weight polyethylene slurried in a styrene monomer containing a styrene crosslinker and a free radical catalyst are disclosed. These slurries are subjected to heating in a mold whereby the polyethylene phase is dissolved in the styrene monomer and the styrene monomer is polymerized to form a shaped article. The polystyrene/polyethylene product has unique properties.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: July 14, 1992
    Assignee: Hercules Incorporated
    Inventor: Keith S. Shih
  • Patent number: 5110873
    Abstract: A thermosetting resin composition comprising(A) 60 to 95% by weight of a prepolymer or precopolymer selected from the group consisting of (A-1), (A-2) and (A-3) below,(A-1) a prepolymer of diallyl phthalate,(A-2) a precopolymer of diallyl terephthalate derived from diallyl terephthalate of the following formula (1) ##STR1## and an aromatic benzyl hydrocarbon having at least one hydrogen atom at the benzyl position and represented by the following formula (2) ##STR2## wherein each of R.sup.1 and R.sup.2 represents a member selected from the class consisting of a hydrogen atom and lower alkyl groups, and n is an integer of 1 to 3, and(A-3) a mixture of (A-1) and (A-2), and(B) 40 to 5% by weight of a polyacrylate or polymethacrylate of dipentaerythritol having at least 4 acryloyl or methacryloyl groups in the molecule and represented by the following formula ##STR3## wherein each R.sup.3 represents a hydrogen atom, --COCH.dbd.CH.sub.2 or ##STR4## and at least four R.sup.3 groups represents --COCH.dbd.CH.sub.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: May 5, 1992
    Assignee: Osaka Soda Co., Ltd.
    Inventors: Yoshimi Kono, Sabee Maeda