Acyclic Hydrocarbon Is Propylene Patents (Class 525/322)
  • Patent number: 5212246
    Abstract: Disclosed are films or sheets comprising an olefin polymer composition which is comprised of(a) from about 10 to 50 parts of a propylene homopolymer having an isotactic index greater than 80, or a copolymer of propylene with ethylene and/or an another alpha-olefin, containing over 80% propylene and having an isotactic index greater than 80;(b) from about 5 to 20 parts of a semi-crystalline copolymer fraction, which copolymer is insoluble in xylene at room or ambient temperature; and(c) from about 40 to 80 parts of a copolymer fraction of ethylene with propylene and/or another alpha-olefin, and optionally with minor amounts of a diene, said copolymer fraction containing less than 40% ethylene and/or other alpha-olefin, being soluble in xylene at room temperature, and having an intrinsic viscosity from 1.5 to 4 dl/g.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: May 18, 1993
    Assignee: Himont Incorporated
    Inventor: Kumar Ogale
  • Patent number: 5212247
    Abstract: Disclosed herein is a polypropylene resin composition of a high syndiotacticity comprising a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, and a preparation process thereof.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: May 18, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Tutomu Iwatani, Katsumi Takeuchi
  • Patent number: 5210146
    Abstract: Composition of matter useful as a multifunctional viscosity index improver for lubricating oils comprising reaction product of:(i) (a) copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystalliity segment contains not greater, than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: May 11, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Antonio Gutierrez, David Y. Chung
  • Patent number: 5210139
    Abstract: A thermoplastic olefin comprising an alloy of an olefin copolymer elastomer and a propylene/comonomer random copolymer is provided. The comonomer is selected from one or more of ethylene and C.sub.4 to C.sub.10 alpha-olefins. Polypropylene is an optional component of the alloy. The alloy may be produced by melt blending, reactor blending or a combination thereof, of the various components.
    Type: Grant
    Filed: February 6, 1991
    Date of Patent: May 11, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Terrence Huff, James J. McAlpin
  • Patent number: 5206303
    Abstract: A grafted and/or functionalized macromolecule comprises entanglement-inhibited architecture wherein the polymer exhibits reduced melt viscosity. In one embodiment, the macromolecule comprises a polymer of an isoolefin having about 4 to about 7 carbon atom and a para-alkylstyrene, wherein a grafted macromonomer such as a terminally functionalized polystyryl chain of very narrow molecular weight distribution is attached to the para-alkyl group of the para-alkylstyrene such that entanglement of adjacent chains in the melt are inhibited. In addition to distributed macromonomer grafts, other functionality may be attached to the para-alkyl group of the para-alkylstyrene to introduce other desirable properties such as radiation curability. In another embodiment the macromolecule comprises a polymer of one or more simple olefinic monomers wherein a macromolecule is attached to pendent functionality and/or copolymerized into the polymer backbone.
    Type: Grant
    Filed: December 27, 1990
    Date of Patent: April 27, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Mun-Fu Tse, Anthony J. Dias, Prasadarao Meka, Kenneth O. McElrath
  • Patent number: 5202380
    Abstract: The addition of a polyolefin-acrylic graft copolymer to blends of polyolefin and core-shell polymers improves compatibility and allows core-shell polymers to be used as processing and performance modifiers polyolefins. Generally the compatibilizing additive is a graft copolymer of a polyolefin and a methacrylate. More specifically, the graft copolymer is derived from at least about 80% of a monomer of a methacrylic ester of the formula CH.sub.2 .dbd.C(CH.sub.3)COOR, where R may be alkyl, aryl, or aralkyl, substituted or unsubstituted, and less than 20%, based on a total monomer weight, of an acrylic or styrenic monomer copolymerizable with the methacrylic ester grafted on to a non polar polyolefin trunk, so that at least one chain is a polymer with a weight average molecular weight greater than about 20,000 and is present in a weight ratio with the polyolefin trunk of from about 1:9 to about 4:1.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: April 13, 1993
    Assignee: Rohm and Haas Company
    Inventors: Casmir S. Ilenda, David L. Dunkelberger, Dennis J. Labanoski
  • Patent number: 5198502
    Abstract: A thermoplastic elastomer composition comprising a thermoplastic elastomeric block or graft polymer comprising at least one hard segment and at least one soft segment and a vulcanizing agent, which can be molded under high shearing stress at a temperature lower than a melting or softening point of the hard sements under shear force to give a molded article having a substantially smooth surface.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: March 30, 1993
    Assignee: Daikin Industries Ltd.
    Inventor: Masayoshi Tatemoto
  • Patent number: 5189106
    Abstract: A polyethylene composition which has excellent flow characteristics and mechanical properties, especially low temperature mechanical properties as well as thermal stability, elasticity and workability for molding. The polyethylene composition comprises 20 to 80 wt. % of an ethylene-.alpha.-olefin copolymer of higher molecular weight having (a) intrinsic viscosity (.eta..sub.1) of 1.2 to 9.0 dl/g, (b) density (d.sub.1) of 0.890 to 0.935 g/cm.sup.3 (c) a specific areal ratio calculated with an elution temperature-eluate volume curve in elution fractionation, and (d) a specific quantity of the content which is soluble in 25.degree. C. o-dichlorobenzene, and 80 to 20 wt. % of ethylene homopolymer or ethylene-.alpha.-olefin copolymer of lower molecular weight having (e) intrinsic viscosity (.eta..sub.2) of 0.2 to 1.6 dl/g, (f) density (d.sub.2) of 0.890 to 0.980 g/cm.sup.3 and, wherein the above (.eta..sub.1) is larger than (.eta..sub.2), and the prepared composition has an intrinsic viscosity (.eta.) of 0.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: February 23, 1993
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Toshifumi Morimoto, Takaaki Hattori, Noboru Ikegami, Hirofumi Nishibu, Toshiyuki Miyauchi, Kunimichi Kubo
  • Patent number: 5180788
    Abstract: The invention relates to graft-modified linear polyethylene with low density (<940 kg/dm.sup.3) (LLDPE), and in particular with very low density (density <915 kg/dm.sup.3) (VLDPE), grafted particularly with styrene/maleic anhydride.These polyethylenes are very good impact modifiers with a high UV resistance and a high degree of toughness and do not cause discoloration of the polyamides and polyesters modified with them. They can be prepared in a simple and economically efficient manner with a high degree of conversion.These polyethylenes are also highly suited as impact modifiers, adhesives or adhesive layers, heat-seal layers, bonding layers in composite films, compatibility enhancement agents as well as bonding promotors, or as components of such agents or layers.Graft-modified polyethylene can be prepared by converting a linear low-density polyethylene with the grafting material at at temperature higher than 110.degree. C.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: January 19, 1993
    Assignee: Stamicarbon B.V.
    Inventor: Hubertus J. Vroomans
  • Patent number: 5166268
    Abstract: A process for the solid phase forming of an impact polypropylene copolymer comprising (a) providing an impact polypropylene copolymer comprising (i) a matrix, which is either a homopolymer of propylene or a copolymer of propylene and up to about 5 percent by weight of at least one other alpha-olefin based on the weight of the copolymer, and, incorporated into said matrix, (ii) a copolymer of ethylene and at least one other alpha-olefin, said copolymer having a crystallinity of at least about 20 percent and being present in the impact copolymer in an amount of at least about 10 percent by weight based on the total weight of the impact copolymer; and (b) forming the impact polypropylene copolymer at a temperature above the melting point of component (ii) but below the melting point of component (i).
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: November 24, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Harold K. Ficker
  • Patent number: 5164451
    Abstract: The maleimide copolymer of the invention is of the class of N-substituted maleimide copolymer such as N-alkyl or N-aromatic maleimide copolymer having peroxy bonds in a molecule, utilizable as a precursor for preparing a maleimide block copolymer and as a modifier for other resins. The maleimide block copolymer, which is useful as a molding material or a thermal resistance improver, is obtained by polymerizing maleimide monomers in the presence of a polymeric peroxide followed by polymerizing vinyl monomers.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: November 17, 1992
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Kenji Kato, Kazunori Doiuchi, Yasumi Koinuma, Yukinori Haruta, Kazuyoshi Aoshima
  • Patent number: 5162443
    Abstract: In a process for producing granular propylene block copolymers by Ziegler-Natta polymerization of an .alpha.-olefin wherein the Ziegler-Natta catalyst comprises a granular solid transition metal catalyst component and an organometal component in two steps wherein a resinous homopolymer of propylene is produced in the first step and an elastomeric copolymer of propylene with ethylene is produced in the second step, the improvement which comprises the use as the granular solid transition metal component of a mixture of the solid transition metal components, one made up substantially of particles of particle size of more than 5 microns and the other made up substantially of particles of particle size of 1 to 5 microns thereby to produce granular propylene copolymers endowed with an improved granulometric properties such as lowered tackiness and thus improved flowing characteristics. The component (B) is preferably produced from the particles for the component (A) by reducing the particle size of its particles.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: November 10, 1992
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Mitsuyuki Matsuura, Takashi Fujita
  • Patent number: 5162442
    Abstract: In a process for producing granular propylene block copolymers in two steps wherein a resinous homopolymer of propylene is produced in the first step and an elastomeric copolymer of propylene with ethylene is produced in the second step, the improvement which comprises conducting the second step in the presence of a granular propylene homopolymer added thereby to produce granular propylene copolymers endowed with an improved granulometric properties such as lowered tackiness and thus improving flowing characteristics.
    Type: Grant
    Filed: September 14, 1989
    Date of Patent: November 10, 1992
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Mitsuyuki Matsuura, Takashi Fujita
  • Patent number: 5153270
    Abstract: Maleic anhydride is grafted onto unsaturated elastomeric terpolymers consisting of monomeric units coming from at least two different monomers having the formula R--CH.dbd.CH.sub.2 (R=hydrogen or an alkyl group containing from 1 to 6 carbon atoms) and from a conjugated or non-conjugated dienic monomer by mass reaction, which is carried out by heating at 120.degree.-350.degree. C. a mixture of said maleic anhydride with the terpolymer in the presence of a catalyst consisting of a compound having the formula:M.sub.n X.sub.zwherein:M=a metal of group VIII of the periodic system, and in particular Rh and Ru;X=a counterion,N=valence of the counterion; andZ=valence of the metal.
    Type: Grant
    Filed: August 1, 1989
    Date of Patent: October 6, 1992
    Assignee: Ausimont S.r.l.
    Inventors: Lucia Roncetti, Viviano Banzi
  • Patent number: 5147928
    Abstract: Propylene-ethylene copolymers are prepared in an agitated bed of solids by first polymerizing propylene from the gas phase in a first polymerization zone at 20-40 bar and 60.degree.-90.degree. C. by addition of a Ziegler-Natta catalyst system, and copolymerizing in a second polymerization zone at 7-35 bar and 40.degree.-70.degree. C. the finely divided polymer from the first polymerization zone with a mixture of olefins a process which comprises copolymerizing in the second polymerization zone with a mixture of propylene, ethylene and a further .alpha.-olefin of from 4 to 10 carbon atoms, setting the ratio of the partial pressures between propylene and ethylene within the range from 100:20 to 100:120 and that of the partial pressures between propylene and the further .alpha.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: September 15, 1992
    Inventors: Juergen Kerth, Harald Schwager, Ralf Zolk
  • Patent number: 5143978
    Abstract: Disclosed is a dynamically partially crosslinked thermoplastic elastomer comprising a propylene polymer material, an amorphous ethylene-propylene copolymer rubber, a semi-crystalline, low density, essentially linear ethylene-propylene copolymer and a polybutene-1 polymer.
    Type: Grant
    Filed: August 28, 1990
    Date of Patent: September 1, 1992
    Assignee: Himont Incorporated
    Inventor: Dominic A. Berta
  • Patent number: 5132371
    Abstract: A methacrylimide-containing polymer comprising a polymer (A) comprised of 5-100 weight % of units represented by the formula (I): ##STR1## wherein R is H or C1-20 hydrocarbon group, and 0-95 weight % of units derived from an ethylenic monomer, wherein a polymer derived from at least one ethylenic monomer has been grafted onto the polymer (A). The methacrylimide-containing polymer is used as a blend with another thermoplastic polymer.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: July 21, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Isao Sasaki, Kozi Nishida, Masaharu Fujimoto
  • Patent number: 5118757
    Abstract: In the gas phase, two stage process for the production of polypropylene impact copolymer, the fouling of the second stage recycle loop and the heat exchange unit incorporated therein is reduced by the addition to the substantially gaseous material passing through the loop of a small amount of alkylene compound selected from alkylene glycol compounds, alkylene glycol derivatives of alkylene diamines or ethers or esters thereof.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: June 2, 1992
    Assignee: Shell Oil Company
    Inventor: James D. McCullough, Jr.
  • Patent number: 5091479
    Abstract: The present invention relates to a process for modifying or crosslinking polymers by the use of novel co-agents in the reaction of polymers with organic peroxides. The novel co-agents comprise oligomers of dialkenyl substituted aromatic compounds, preferably oligodiisopropenylbenzene.
    Type: Grant
    Filed: November 30, 1989
    Date of Patent: February 25, 1992
    Assignee: Akzo NV
    Inventors: Wilhelmus M. Beijleveld, Willem C. Endstra
  • Patent number: 5084513
    Abstract: A process for the manufacture of stable interpenetrating polymer blend networks is provided, comprising the preparation of a gel of a poly(alkylene) polymer by dissolving it in a mixture of one or more organic solvents and one or more vinyl aromatic monomers, optionally mixed with a compatible monomer, cooling this solution to a temperature of at most 80.degree. C., adding of a radical forming initiator for the polymerization of the vinyl aromatic monomer(s), homogenizig the solution, cooling the solution to a temperature to obtain gelation of the polyalkylene polymer in the solvent mixture, followed by heating the obtained gel to a temperature of at least 80.degree. C. and subsequently polymerization of the vinyl aromatic monomer(s) in bulk or suspending the heated solution in a vigorously stirred aqueous medium of a lower temperature to obtain gelation and polymerizing the suspended gel into polymer blend beads, stable interpenetrating polymer blend networks and intermediate gel used therewith.
    Type: Grant
    Filed: February 9, 1990
    Date of Patent: January 28, 1992
    Assignee: Shell Internationale Research Maatschappij B.V.
    Inventors: Johannes M. Zijderveld, Philippe M. Scheerlinck, Hugo A. A. Berghmans
  • Patent number: 5081189
    Abstract: Provided herein is a propylene-ethylene copolymer composition which comprises (a) 10 to 25 parts by weight of a first propylene-ethylene copolymer containing 90 wt % or more of ethylene and (b) 75 to 90 parts by weight of a second propylene-ethylene copolymer containing 0.5 to 2.5 wt % of ethylene, the first copolymer having intrinsic viscosity of .eta..sub.a and the second copolymer having an intrinsic viscosity of .eta..sub.b, said intrinsic viscosities being defined by .eta..sub.a -.eta..sub.b =-0.2 to +1.2 dl/g.
    Type: Grant
    Filed: August 11, 1989
    Date of Patent: January 14, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Takayuki Yamada, Takashi Kanbayashi, Shigeru Kimura, Takeo Inoue
  • Patent number: 5079295
    Abstract: A thermoplastic resin composition having excellent heat resistance and impact resistance as well as having excellent rigidity, chemical resistance and processibility, comprising:(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,(b)(i) a modified propylene polymer grafted with a styrene-based monomer and an unsaturated carboxylic acid or its derivative, or(ii) a propylene-based resin composition containing the modified propylene polymer and a propylene polymer, and(c) a rubbery substance. The thermoplastic resin compositions not only have good mold-processibility but also exhibit well-balanced physical properties when molded into articles.
    Type: Grant
    Filed: August 15, 1989
    Date of Patent: January 7, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonobu Furuta, Takeshi Maruyama
  • Patent number: 5079302
    Abstract: A catalytic process for free radically induced polymerization and graft copolymerization of a free radically polymerizable monomer onto a compound in the presence of a free radical initiator, an organic catalyst and in the presence or absence of an organic diluent where the organic catalyst is an alkenyl substituted cyanurate or isocyanurate and composition thereof.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: January 7, 1992
    Assignee: University of Akron
    Inventors: Sunggyu Lee, Ramesh Rengarajan
  • Patent number: 5075376
    Abstract: Disclosed are thermoplastic resin compositions comprising:(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,(b) (i) a modified propylene polymer obtainable by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition comtaining said modified propylene polymer and a propylene polymer, and(c) a rubbery substance,wherein the number mean particle size of the component (a) and (c) in the dispersion phase being from 0.01 to 20 .mu.m, the proportion of the component (a) to the sum of the components (a) and (b) being 1 to 80% by weight, that of the component (b) to the sum of the components (a) and (b) being 99 to 20% by weight, and the proportion of the component (c) to the sum of the components (a) and (b) being 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).
    Type: Grant
    Filed: January 5, 1990
    Date of Patent: December 24, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonobu Furuta, Takashi Maruyama, Satoru Hosoda
  • Patent number: 5071911
    Abstract: Disclosed herein is a thermoplastic resin composition which comprises:(a) a polyphenylene ether resin or a polyphenylene ether-containing resin composition,(b) a polypropylene grafted with a styrene-based monomer and/or a propylene copolymer grafted with a styrene-based monomer,(c) an ethylene-.alpha.-olefin copolymer grafted with a styrene-based monomer, said ethylene-.alpha.-olefin copolymer having a density of 0.85-0.91 g/cm.sup.3 and a maximum melting peak temperature of 100.degree. C. and above measured with a differential scanning calorimeter (DSC), and(d) optionally, rubbery substance. Also disclosed herein is a process for producing a thermoplastic resin composition which comprises incorporating a preblend composed of:(a') a polyphenylene ether resin or a polyphenylene ether-containing resin composition,(b') a polypropylene and/or a propylene copolymer,(c') an ethylene-.alpha.-olefin copolymer having a density of 0.85-0.91 g/cm.sup.3 and a maximum melting peak temperature of 100.degree. C.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: December 10, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonobu Furuta, Hiroyuki Harada, Takashi Maruyama
  • Patent number: 5071912
    Abstract: Disclosed is a thermoplastic resin composition, comprising:(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,(b) (i) a modified propylene polymer obtainable by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition containing said modified propylene polymer and a propylene polymer, and(c) two or more rubbery substances, at least one rubbery substance being compatible with the component (a), and at least one rubbery substance being not compatible with the component (a). The thermoplastic resin composition has good moldability and yields molded articles having well-balanced physical properties.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: December 10, 1991
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Motonobu Furuta, Takashi Maruyama
  • Patent number: 5066726
    Abstract: A process to graft epoxy containing functional monomers to a base polymer is provided, the process comprising the steps of: providing a melt of a base polymer; containing the melt of the base polymer with a functional monomer in the presence of a free radical initiator at a temperature of less than 240.degree. C., the functional monomer comprising alpha-beta ethylenic unsaturation and an epoxy group; and recovering an epoxy functionalized polymer. Grafting the epoxy containing monomer to the base polymer at temperatures of 240.degree. C. and less results in a low level of hydrolyzed epoxy groups.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: November 19, 1991
    Assignee: Shell Oil Company
    Inventor: Michael J. Modic
  • Patent number: 5066723
    Abstract: Impact-modified polymeric materials are produced by visbreaking certain reactor blends. In a preferred embodiment, impact-modified polypropylene materials are produced by visbreaking a reactor blend of polypropylene and thermoplastic polyethylene. The polypropylene material is preferably homopolypropylene having a melt flow rate of less than about 1 dg/min. Such impact-modified polymeric materials manifest unexpected compatibility characteristics, increased impact resistance at low temperatures, improved antiblush characteristics and improved flow characteristics.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: November 19, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: James C. Randall, Jr., Terrence Huff
  • Patent number: 5037890
    Abstract: A copolymer of an .alpha.-olefin with an aromatic diolefin such as divinylbenzene produced by means of Ziegler-Natta polymerization and having a vinylphenyl moiety is subjected to polymerization with an ethylenically unsaturated monomer by means of anion polymerization or free radical polymerization, whereby a graft-modified .alpha.-olefin copolymer is obtained.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: August 6, 1991
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Masuzo Yokoyama, Shinichi Yamauchi, Hiroshi Nakano, Michiharu Kihira, Hiroshi Omori
  • Patent number: 5023300
    Abstract: A thermoplastic olefin comprising an alloy of an olefin copolymer elastomer and a propylene/comonomer random copolymer is provided. The comonomer is selected from one or more of ethylene and C.sub.4 to C.sub.10 alpha-olefins. Polypropylene is an optional component of the alloy. The alloy may be produced by melt blending, reactor blending or a combination thereof, of the various components.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: June 11, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Terrence Huff, James J. McAlpin
  • Patent number: 5011883
    Abstract: Stabilized aqueous polymer latex compositions comprising: (A) a polymeric latex particle; (B) a protective colloid; and (C) a polyoxyalkylene-containing alkyd resin which is the reaction product of (i) at least one polyoxyalkylene, (ii) at least one polyol; (iii) at least one polycarboxylic acid anhydride; and (iv) at least one monocarboxylic acid are disclosed. Also detailed is a method of producing such a stabilized polymer latex composition.
    Type: Grant
    Filed: February 7, 1990
    Date of Patent: April 30, 1991
    Assignee: ICI Americas Inc.
    Inventor: Igor Aksman
  • Patent number: 4999403
    Abstract: Graft polymer comprising functionalized ethylene-alpha-olefin copolymer having polypropylene grafted thereto through one or more functional linkages, the process for making the graft polymer comprising combining the functionalized ethylene-alpha-olefin with maleated polypropylene, the use of the graft polymer for improving the impact properties of polypropylene compositions, and improved polypropylene blends.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: March 12, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Sudhin Datta, David J. Lohse
  • Patent number: 4990571
    Abstract: Composite resin particles each comprising a particulate crosslinked polymer to which a number of substantially linear, metal-containing polymer chains are chemically bonded. The invention also provide methods for the preparation of said composite resin particles. The present composite resin particles have self-film forming properties, can give a stable dispersion in an organic solvent or a resinous varnish and are specifically useful in paint industries. The particles are further characterized by having the desired properties of the metal element contained therein, as, for example, self-catalytic function in crosslinking, excellent biological activities and the like.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: February 5, 1991
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tadafumi Miyazono, Akio Kashihara, Shinichi Ishikura
  • Patent number: 4990572
    Abstract: Composite resin particles each comprising a particulate crosslinked polymer to which a number of substantially linear, metal-containing polymer chains are chemically bonded. The invention also provide methods for the preparation of said composite resin particles. The present composite resin particles have self-film forming properties, can give a stable dispersion in an organic solvent or a resinous varnish and are specifically useful in paint industries. The particles are further characterized by having the desired properties of the metal element contained therein, as, for example, self-catalytic function in crosslinking, excellent biological activities and the like.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: February 5, 1991
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tadafumi Miyazono, Akio Kashihara, Shinichi Ishikura
  • Patent number: 4980415
    Abstract: Compositions comprising polyphenylene ether copolymers are prepared by blending, preferably in the melt, a functionalized polyphenylene ether with a graft polymer, which is in turn prepared by the free radical reaction of a base polymer such as polyethylene or polypropylene with an olefinic compound containing a tertiary alkyl ester group, which may be a simple carboxylic acid or a carbamic acid ester group. The t-butyl groups are removed by thermal degradation under the reaction conditions to yield a carboxylic acid- or amino-functionalized graft polymer which reacts with the polyphenylene ether.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: December 25, 1990
    Assignee: General Electric Company
    Inventor: John R. Campbell
  • Patent number: 4977210
    Abstract: Propylene/ethylene block copolymers are prepared by a continuous process in which, in each case in an agitated fixed bed of finely divided polymer from the gas phase, first (I) in a first polymerization zone, propylene is homopolymerized by feeding in a Ziegler-Natta catalyst system consisting of (1) a titanium component which contains titanium, magnesium, chlorine and a phthalic acid derivative, (2) an aluminumalkyl component and (3) a silane component, and (II) in a second polymerization zone, a mixture of propylene and ethylene is polymerized with the propylene homopolymer present in the reaction mixture obtained in the first polymerization zone by feeding in the said reaction mixture. In the process, (A) a titanium component (1) is used which is obtained by a method in which (1.1) first, (1.1.1) in a liquid hydrocarbon, (1.1.2) a finely divided magnesium halide, (1.1.3) an alkanol, (1.1.4) a certain phthalic acid derivative and (1.1.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: December 11, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Kerth, Rainer A. Werner, Ralf Zolk, Klaus-Dieter Ruempler, Guenther Schweier, Rudolf Mueller-Mall, Wolfgang Gruber
  • Patent number: 4950720
    Abstract: A modified polypropylene having a substantially isotactic homopolypropylene and a propylene/olefin random copolymer, the modified polypropylene including up to about 50 chain disruptors per 1000 propylene repeat units. The chain disruptors are racemic polypropylene diads and olefin, the olefin being incorporated into the high end of the molecular weight distribution of the modified polypropylene.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: August 21, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventors: James C. Randall, Jr., Ferdinand C. Stehling, Michael C. Chen, Larry W. Colwell
  • Patent number: 4948841
    Abstract: The present invention relates to a propylene polymer composition comprising:65 to 95% by weight of a propylene homopolymer having (a) an intrinsic viscosity ([.eta..sub.1 ]) of 0.5 to 3.5 dl/g, (b) a xylene soluble content at ordinary temperature (Xs) of not more than 3% by weight, and a difference (.DELTA.[.eta..sub.1 ]) between ([.eta..sub.1 ]) of xylene insoluble portion at the ordinary temperature and ([.eta..sub.1 ]) of xylene soluble portion at the ordinary temperature of not more than 0.5 dl/g, (c) an isotactic pentad fraction (IP) falling within the range represented by the following equation:IP.gtoreq.-0.624[.eta..sub.1 ]+97.5,and (d) a crystallization temperature (Tc) falling within the range represented by the following equation:Tc.gtoreq.-2.33[.eta..sub.1 ]+116.0;and5 to 35% by weight of a propylene-ethylene random copolymer having (e) an intrinsic viscosity ([.eta..sub.2 ]) of less than 2.8 dl/g and (f) an ethylene content of 10 to 35% by weight.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: August 14, 1990
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Toshikazu Kasahara, Hideo Funabashi
  • Patent number: 4946898
    Abstract: The present invention relates to a propylene polymer composition comprising:60 to 94% by weight of a propylene homopolymer having (a) an intrinsic viscosity ([.eta..sub.1 ]) of 0.5 to 5 dl/g, (b) a xylene soluble content at ordinary temperature (Xs) of not more than 3% by weight, and a difference (.DELTA.[.eta..sub.1 ]) between ([.eta..sub.1 ]) of xylene insoluble portion at the ordinary temperature and ([.eta..sub.1 ]) of xylene soluble portion at the ordinary temperature of not more than 0.5 dl/g, (c) an isotactic pentad fraction (IP) falling within the range represented by the following equation:IP.gtoreq.-0.624[.eta..sub.1 ]+97.5,and (d) a crystallization temperature (Tc) falling within the range represented by the following equation:Tc.gtoreq.-2.33[.eta..sub.1 ]+116.0; and6 to 40% by weight of a propylene-ethylene random copolymer having (e) an intrinsic viscosity ([.eta..sub.2 ]) of not less than 2.8 dl/g and (f) an ethylene content of 30 to 80% by weight.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: August 7, 1990
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Toshikazu Kasahara, Hideo Funabashi
  • Patent number: 4882406
    Abstract: Nodular copolymer and method of preparing a nodular copolymer by preparing a copolymer chain and coupling it with a coupling agent. The copolymers which form the nodular copolymer are formed of first and second segments, of which the second segments, containing the coupling agent, react to form the nodular region. The nodular copolymer is particularly useful as a lube oil additive.
    Type: Grant
    Filed: March 5, 1986
    Date of Patent: November 21, 1989
    Assignee: Exxon Research & Engineering Company
    Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
  • Patent number: 4853478
    Abstract: This invention is directed to the preparation of polymerizable monomers that are prepared from 1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl) benzene (m-TMI) and 1-(1-isocyanato-1-methylethyl)-4-(1-methylethenyl) benzene (p-TMI). The monomers prepared from m- and p-TMI can contain numerous chemical moieties, and when polymerized, produce polymers that have chemically bonded to the polymeric backbone the functional moiety. More specifically, these TMI derived monomers may contain chain breaking antioxidant moieties, peroxide decomposing antioxidant moieties, ultraviolet stabilizing moieties, triplet quenching moieties, and other chemical moieties that are useful in polymers.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: August 1, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Howard A. Colvin, Kirkwood S. Cottman, Dane K. Parker
  • Patent number: 4839423
    Abstract: A graft precursor is formed by preparing a propylene polymer suspension having a propylene polymer suspended in water and a solution having a specific radically (co)polymerizable organic peroxide and a specific radical polymerization initiator dissolved in specific amounts in a vinyl monomer, mixing the propylene suspension and the solution in a specific ratio, heating and stirring the resultant mixture under conditions incapable of inducing substantial decomposition of the polymerization initiator, and further elevating the temperature of the mixture after the total amount of the vinyl monomer, the radically (co)polymerizable organic peroxide, and the radical polymerization initiator has decreased to less than 50% by weight of the initial total amount. Then a graft resin composition is produced by melting and kneading the graft precursor, either by itself or in combination with a propylene polymer and a vinyl polymer, at a temperature in the range of 100.degree. to 300.degree. C.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: June 13, 1989
    Assignee: Nippon Oil & Fats Co., Ltd.
    Inventors: Yasuo Moriya, Nobuyoshi Suzuki, Hiroshi Goto
  • Patent number: 4822840
    Abstract: A novel low-crystalline propylene random copolymer composition comprising[I] 60 to 95% by weight of a propylene random copolymer and[II] 5 to 40% by weight of a low-crystalline propylene random copolymerwhich has excellent heat-sealability, heat-seal imparting property, transparency and antiblocking property and containing a reduced amount of a hydrocarbon-soluble component, a process for production thereof, and polypropylene composite laminated structure having improved heat-sealability and heat seal strength at low temperatures.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: April 18, 1989
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Kioka, Masahiro Sugi, Akinori Toyota, Norio Kashiwa
  • Patent number: 4814388
    Abstract: A rubber-modified thermoplastic resin composition obtained by copolymerizing an aromatic vinyl compound and optionally other monomers copolymerizable therewith in the presence of an ethylene-.alpha.-olefin type rubbery polymer having a molecular weight distribution parameter Mw/Mn of 1.2 to 4.5. Said polymer preferably has Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 40 or less. Said composition is excellent not only in weather resistance and impact resistance but also in rigidity, surface gloss and molded product appearance.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: March 21, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hisao Nagai, Yuzi Nakagawa, Katsurou Oomura, Shinichi Kimura
  • Patent number: 4812526
    Abstract: An impact polypropylene composition comprising:(i) isotactic polypropylene; and(ii) a copolymer of ethylene and an alpha-olefin comonomer having 3 to 8 carbon atoms, said copolymer (a) having a density of about 0.87 to about 0.90 gram per cubic centimeter and a crystallinity in the range of about 20 to about 35 percent by weight based on the weight of the copolymer and (b) being present in the composition in the range of about 20 to about 50 percent by weight based on the weight of the polypropylene.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: March 14, 1989
    Assignee: Union Carbide Corporation
    Inventor: Mahmoud R. Rifi
  • Patent number: 4810612
    Abstract: A heat-fixable electrophotographic toner composition comprising(A) a graft modified polyolefin composed of 100 parts by weight of a polyolefin having an intrinsic viscosity, measured in decalin at 135.degree. C., of from 0.04 to 1.2 dl/g, and grafted thereto a monomer selected from the group consisting of (a) 1.0 to 100 parts by weight of acrylonitrile or methacrylonitrile, (b) 3 to 200 parts by weight of an aromatic carboxylic acid vinyl ester and (c) 2 to 43 parts by weight of an unsaturated carboxylic acid ester, and(B) a coloring agent.
    Type: Grant
    Filed: June 8, 1988
    Date of Patent: March 7, 1989
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Ueda, Toshihiro Sagane
  • Patent number: 4806581
    Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article.
    Type: Grant
    Filed: March 10, 1987
    Date of Patent: February 21, 1989
    Assignee: Occidental Chemical Corporation
    Inventor: Leigh E. Walker
  • Patent number: 4777216
    Abstract: The invention relates to a process for the controlled polymerization of alpha-olefins selected from the group consisting of propylene and butylene in order to form a polymer containing by weight about 10% to 30% isotactic polyolefin, 25% to 70% atactic polyolefin and 0% to 65% by weight of an amorphous ethylene/olefin copolymer which process comprises combinations of the steps of:(a) homopolymerizing the alpha-olefin at a temperature of from about 0.degree. C. to about 90.degree. C. (preferably from about 20.degree. C. to about 60.degree. C.) in the presence of a high yield catalyst comprising a titanium compound supported on activated MgCl.sub.
    Type: Grant
    Filed: January 30, 1987
    Date of Patent: October 11, 1988
    Assignee: Dureco Chemicals, Inc.
    Inventors: Vincenzo Busico, Paolo Corradini, Vito Savino
  • Patent number: 4696979
    Abstract: A process for producing a propylene copolymer having improved transparency and rigidity, which comprises carrying out (A) the polymerization of a vinyl cycloalkane having at least 6 carbon atoms and (B) the polymerization of propylene either alone or with ethylene in a multiplicity of steps in the presence of a catalyst system composed of a titanium compound and an organoaluminum compound. The content of the vinyl cycloalkane unit in the resulting copolymer is 0.05 to 10,000 weight ppm.
    Type: Grant
    Filed: December 27, 1984
    Date of Patent: September 29, 1987
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Akinobu Shiga, Masahiro Kakugo, Junpei Kozima, Kizuku Wakatsuki
  • Patent number: 4666987
    Abstract: A process for in mold polymerization and a composition for use therein comprising a polymerizable vinyl aromatic monomer and a particulated, semicrystalline nonmiscible polymer.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: May 19, 1987
    Assignee: The Dow Chemical Company
    Inventors: Alan F. Burmester, John S. Trent