Hydrolyzed; Neutralized; Or Metal Containing Chemical Treating Agent Patents (Class 525/330.2)
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Patent number: 11815658Abstract: Films having high light transmission values, low haze and high glass transition temperatures and useful, for example, as optical protection films and zero-zero optical retardation films, are prepared using one or more copolymers of methyl methacrylate having certain characteristics.Type: GrantFiled: February 20, 2018Date of Patent: November 14, 2023Assignee: Trinseo Europe GmbHInventors: Jiaxin Jason Ge, Florence Mehlmann, Estelle Meurice Pierrat
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Patent number: 10821418Abstract: The present invention relates to a super absorbent polymer exhibiting more improved liquid permeability and/or absorption rate while maintaining excellent absorption performance. Such super absorbent polymer comprises a base polymer powder including a first cross-linked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer formed on the base polymer powder and including a second cross-linked polymer in which the first cross-linked polymer is further cross-linked through an alkylene carbonate having 2 to 5 carbon atoms, and satisfies predetermined physical properties.Type: GrantFiled: January 10, 2017Date of Patent: November 3, 2020Assignee: LG Chem, Ltd.Inventors: Dae Woo Nam, Chang Sun Han, Hyemin Lee, Hwayoon Jung, Hyung Ki Yoon
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Patent number: 10451990Abstract: A toner comprising a toner particle including a resin component, wherein the resin component includes an olefin copolymer including ester group having specific structures Y1 and Y2 and an olefin copolymer including acid group having an acid value of from 50 mg KOH/g to 300 mg KOH/g, the amount of the olefin copolymer including ester group is 50% by mass or more, the toner particle has a surface layer including the olefin copolymer including acid group which has formed a salt with a metal, the metal is at least one metal selected from the group consisting of Mg, Ca, Sr, Al, and Zn, and the total amount of the metal in the toner is from 25 ppm to 500 ppm.Type: GrantFiled: September 20, 2018Date of Patent: October 22, 2019Assignee: CANON KABUSHIKI KAISHAInventors: Kentaro Kamae, Ryuji Murayama, Junichi Tamura, Hayato Ida, Takashi Hirasa
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Patent number: 9232786Abstract: An agrochemical formulation and its method of manufacture comprising an agrochemical active and a dispersant polymer comprising a copolymer of benzylmethacrylate, acrylic acid and 2-acrylamido-2-methyl propane sulfonic acid.Type: GrantFiled: April 19, 2010Date of Patent: January 12, 2016Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Klin A. Rodrigues, Mark Alexander
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Patent number: 9095748Abstract: Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the core layers comprises a thermoplastic ionomer composition, preferably a highly neutralized ethylene acid copolymer. And, at least one of the core layers comprises a thermoplastic polyamide composition. The ionomer composition is preferably used to form the inner core and the polyamide composition is preferably used to form the outer core layer. More preferably, the ionomer composition has a flex modulus of 80,000 psi or less and the polyamide composition has a flex modulus of 90,000 psi or greater. The resulting ball has high resiliency and rebounding properties.Type: GrantFiled: June 30, 2011Date of Patent: August 4, 2015Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Mark L. Binette
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Patent number: 9006346Abstract: The present invention provides a resin composition for a golf ball and a golf ball which have high resilience while maintaining soft compression and also have low spin on driver shots, and therefore can achieve a long flight distance. The present invention relates to a resin composition for a golf ball, including an ionomer resin consisting of a metal ion-neutralized copolymer of (A) a C3-8 ?,?-unsaturated carboxylic acid and (B) a C3-8 ?,?-unsaturated carboxylic acid ester, the ionomer resin having a mass ratio of (A)/(B) of 10/90 to 25/75, and a degree of neutralization of 30 to 105 mol %.Type: GrantFiled: December 26, 2012Date of Patent: April 14, 2015Assignee: Dunlop Sports Co., Ltd.Inventors: Kazuki Shiga, Ryo Murakami, Yoshiyuki Ikeda
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Patent number: 8975339Abstract: Provided is a surface treatment method for a water-absorbent resin having excellent production efficiency, absorption capacity against pressure, fluid permeability or the like. Provided is a method for the surface treatment of a water-absorbent resin which comprises a) a step for mixing 0.1 to 20 parts by weight of an acid group-containing radically polymerizable compound and 5 to 20 parts by weight of water, relative to 100 parts by weight of a water-absorbent resin; and b) a step for polymerizing the acid group-containing radically polymerizable compound, wherein neutralization ratio of the acid group-containing radically polymerizable compound is 0 to 60% by mol, and is lower than neutralization ratio of the water-absorbent resin.Type: GrantFiled: October 8, 2008Date of Patent: March 10, 2015Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshiro Mitsukami, Taku Iwamura, Makoto Matsumoto
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Patent number: 8907022Abstract: Disclosed is a method for forming an aqueous dispersion of an ionomer composition comprising mixing a solid ionomer composition with water heated to a temperature from about 80 to about 90° C., the solid ionomer composition comprising an ethylene acid copolymer comprising about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising sodium cations.Type: GrantFiled: August 20, 2012Date of Patent: December 9, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Richard Allen Hayes, Elliott Echt
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Publication number: 20140350191Abstract: The present invention relates to a process for the preparation of water-absorbing polymer structures, comprising the following process steps: i) providing an untreated, water-absorbing polymer structure; and ii) bringing the untreated, water-absorbing polymer structure into contact with a salt comprising a divalent or higher-valent cation of a metal and at least one organic base as anion. The invention relates also to the water-absorbing polymer structures obtainable by that process, to water-absorbing polymer structures, to a composite comprising a water-absorbing polymer structure and a substrate, to a process for the preparation of a composite, to the composite obtainable by that process, to chemical products, such as foams, molded articles and fibers comprising water-absorbing polymer structures or a composite, to the use of water-absorbing polymer structures or of a composite in chemical products and to the use of a salt in the treatment of the surface of water-absorbing polymer structures.Type: ApplicationFiled: August 13, 2014Publication date: November 27, 2014Inventors: Mirko Walden, Harald Schmidt, Rainer Teni, Armin Reimann, Franck Furno, Jorg Issberner, Peter Herbe, Ursula Nielinger, Michael Keup
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Publication number: 20140336335Abstract: The present invention is concerned with an emulsion copolymer latex comprising an acrylic/methacrylic copolymer obtainable by the emulsion copolymerisation of the following monomer components: A: from 75% weight to 97.5% by weight, based on the total weight of monomer components A+B+C+D, of methyl acrylate; B: from 0.1% to 15% by weight, based on the total weight of monomer components A+B+C+D, of at least one ethylenically unsaturated carboxylic acid monomer containing one C?C double bond capable of free radical copolymerisation with component A and at least one carboxylic acid (CO2H) group; C: from 1% to 20% by weight based on the total weight of monomer components A+B+C+D of at least one associative monomer being a (meth)acrylate ester of an alkoxylated alcohol; and D: from 0% to 15% by weight of one or more non-ionic ethylenically unsaturated monomers other than those defined above as A, B or C; wherein the total monomer components A+B+C+D together add up to 100%.Type: ApplicationFiled: November 16, 2012Publication date: November 13, 2014Inventors: Mark Thomas Stanion, Paul Edward Hunt
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Patent number: 8859685Abstract: A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC).Type: GrantFiled: August 27, 2010Date of Patent: October 14, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Kozo Nogi, Kunihiko Ishizaki, Kazumasa Konishi
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Publication number: 20140249278Abstract: An ionomer has an ABA-type triblock structure, wherein an A-block is an ionic polymer block including a structural unit having a general formula (i) expressed as follows: —(CH2—CR1(COOM1/y)- where R1 is one of a methyl group and hydrogen, M is one of metal, NH4, organic ammonium and imidazolium, and y is a valence of an M ion, and a B-block is a nonionic polymer block selected from a group consisting of an olefin (co) polymer block, a vinyl (co) polymer block, a diene (co) polymer block, a polyester resin block and a polycarbonate resin block.Type: ApplicationFiled: May 16, 2014Publication date: September 4, 2014Inventors: Takashi SAWAGUCHI, Daisuke SASAKI
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Patent number: 8808816Abstract: Gas-barrier multilayer structures and gas-barrier shaped articles are sufficiently prevented from clouding even when exposed to cold water at 30° C. or below and have excellent gas barrier properties. Processes for producing such gas-barrier multilayer structures, and coating liquids (A) of excellent coating properties that are used to produce the multilayer structures are also provided. A coating liquid (A) includes a solvent mixture of water and an organic solvent and a polycarboxylic acid polymer partially neutralized with a polyvalent metal wherein the polymer is both dissolved and dispersed as particles in the solvent mixture and wherein the particles dispersed account for 5 to 80 wt% of 100 wt% of the polycarboxylic acid polymer partially neutralized with a polyvalent metal.Type: GrantFiled: September 28, 2007Date of Patent: August 19, 2014Assignee: Toppan Printing Co., Ltd.Inventors: Masahiro Yamazaki, Chisato Fujimura, Katsumi Kawaguchi
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Patent number: 8802786Abstract: The present invention relates to a particulate superabsorbent polymer composition which absorbs water, aqueous liquids, and blood, and a process to make the superabsorbent polymers, wherein a superabsorbent polymer is surface treated with a neutralized multivalent metal salt solution having a pH value similar as that of human skin. The present invention also relates to particulate superabsorbent polymer composition having high Gel Bed Permeability and high Absorbency Under Load.Type: GrantFiled: April 21, 2011Date of Patent: August 12, 2014Assignee: Evonik CorporationInventors: Yaru Shi, Gonglu Tian, Mark Joy, Geoff Blake, Scott Smith, Bernfried Messner
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Publication number: 20140206822Abstract: The present invention relates to a surface treatment method for magnetic particles, a magnetic composite prepared thereby, and a magnetic composite for labeling target materials. More specifically, the invention relates to a surface treatment method for magnetic particles and a magnetic composite having excellent dispersibility prepared thereby, wherein the surface treatment method comprises the steps of: performing the acid-treatment of magnetic particles and mixing the acid-treated magnetic particles with a water-soluble solvent in order to form a hydroxyl group (—OH) on the surface of the magnetic particles; and mixing the magnetic particles, in which the hydroxyl group is formed, with a surface treatment agent containing an organic ligand, which can be bonded to the hydroxyl group, so that the organic ligand is treated on the surface of the magnetic particles.Type: ApplicationFiled: June 22, 2012Publication date: July 24, 2014Applicant: NANOBRICK CO., LTD.Inventors: Jae Hyun Joo, Sung-Bok Wee, Youn-Jung Park, Sung-Wan Hong, Hyong-Ku Chang
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Patent number: 8742026Abstract: The invention relates to a process for producing water-absorbing polymer particles with improved permeability, comprising the steps of polymerization, drying, grinding, classification and thermal surface postcrosslinking, with pneumatic conveying between grinding and classification.Type: GrantFiled: March 2, 2012Date of Patent: June 3, 2014Assignee: BASF SEInventors: Matthias Weismantel, Markus Braun
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Patent number: 8729191Abstract: An embodiment of the present invention allows for production, with a high productivity, of a water-absorbent resin including an improved relationship between absorption capacity and water-soluble polymer which are conflicting properties of the water-absorbent resin, being easily controlled for polymerization reaction, being of no odor, being less colored, and being of high absorption properties. In one embodiment of the present invention, acrylic acid composition is neutralized with a basic composition including an iron content of 0.2 to 5 ppm by weight (relative to a basic compound exclusive of a solvent); and then polymerizing a resultant neutralized product, the acrylic acid composition including: (i) a methoxyphenol content of 10 to 200 ppm by weight relative to the weight of acrylic acid; and (ii) at least one compound content of which is 0 to 10 ppm by weight relative to the weight of acrylic acid, the compound being selected from the group consisting of protoanemonin and furfural.Type: GrantFiled: April 6, 2006Date of Patent: May 20, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Takaaki Kawano, Hirotama Fujimaru, Kunihiko Ishizaki, Katsuyuki Wada
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Patent number: 8729190Abstract: A particulate water-absorbent agent containing a polyacrylate salt-type water-absorbent resin. The agent has an absorption capacity without load of 28 g/g or higher and has a diffusion absorption index of 1.40 to 10.0 g/g min. The amount of water-soluble components in the agent, with stirring, is 15-60% by mass. The difference between this amount and the amount of water-soluble components, without stirring, is 15-50% by mass. Also disclosed is a method of making the above-identified agent.Type: GrantFiled: February 28, 2008Date of Patent: May 20, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Takahiro Kitano, Takaaki Kawano, Katsuyuki Wada
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Patent number: 8674025Abstract: An object of the present invention is to provide a golf ball resin composition with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball resin composition with a high hardness and durability. Yet another object of the present invention is to provide a golf ball traveling a great distance with an ionomer cover. The present invention provides a golf ball resin composition comprising, (A) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms; (B) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, and (C) a zinc compound, wherein a content ratio ((A)/(B)) of (A) component to (B) component ranges from 50/50 to 80/20 in a mass ratio and a content of (C) component ranges from 0.Type: GrantFiled: April 11, 2011Date of Patent: March 18, 2014Assignee: SRI Sports LimitedInventor: Takahiro Shigemitsu
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Patent number: 8669313Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-methacrylic acid copolymer and/or an olefin-methacrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.0 to 7.0, or a metal neutralization product thereof, (b) an olefin-acrylic acid copolymer and/or an olefin-acrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 150,000 to 220,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 5.5 to 8.5, or a metal neutralization product thereof, (c) an organic acid or a metal salt thereof, and (d) a basic inorganic metal compound for neutralizing at least 70 mol % of acid groups in components (a) to (c), which resin mixture has a Shore D hardness of from 30 to 60.Type: GrantFiled: November 30, 2010Date of Patent: March 11, 2014Assignee: Bridgestone Sports Co., Ltd.Inventors: Kae Iizuka, Eiji Takehana
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Patent number: 8669312Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.3 to 6.6, or a metal neutralization product thereof, (b) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 6.8 to 9.Type: GrantFiled: November 30, 2010Date of Patent: March 11, 2014Assignee: Bridgestone Sports Co., Ltd.Inventors: Kae Iizuka, Eiji Takehana
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Publication number: 20140065288Abstract: Anticaking agents for inhibiting or preventing caking of inorganic salt granules are provided. The anticaking agents comprise a coordination complex of iron and a salt anion of an organic acid, wherein the salt anion is selected from the group consisting of malate, polyacrylate, diphosphonate, and mixtures thereof. Free-flowing, solid salt compositions resistant to caking are also described herein, along with methods of melting ice and/or snow on a surface or inhibiting the accumulation or formation of ice and/or snow on a surface, and methods of preventing or inhibiting caking of solid inorganic salt granules.Type: ApplicationFiled: September 4, 2013Publication date: March 6, 2014Applicant: North American Salt CompanyInventors: Geoffrey A. Brown, Joshua M. Shipman
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Patent number: 8534465Abstract: A process for removing metallic impurities from a product mass flow comprising water-absorbing polymer particles, wherein the product mass flow has a temperature of 35 to 90° C.Type: GrantFiled: December 7, 2009Date of Patent: September 17, 2013Assignee: BASF SEInventors: Rüdiger Funk, Jürgen Schröder, Matthias Weismantel
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Patent number: 8492470Abstract: Disclosed are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compressions greater than 100. Also disclosed is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.Type: GrantFiled: September 22, 2011Date of Patent: July 23, 2013Assignee: E.I. du Pont de Nemours and CompanyInventor: James R. De Garavilla
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Patent number: 8487048Abstract: Objects of the present invention are: to provide a water-absorbent resin which exhibits excellent balances between water absorption performances; and further to provide a process by which a water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment; and further to provide a water-absorbent resin optimum to absorbent articles such as diapers.Type: GrantFiled: May 7, 2004Date of Patent: July 16, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Katsuyuki Wada, Masatoshi Nakamura, Kazuki Kimura, Kunihiko Ishizaki
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Patent number: 8461268Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: November 15, 2011Date of Patent: June 11, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8450419Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: August 24, 2010Date of Patent: May 28, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8410223Abstract: There is provided a production method for a water-absorbing resin for stably and continuously producing the water-absorbing resin with industrially high property, in particular, the water-absorbing resin with high liquid permeation. A method of the present invention relates to a production method for a water-absorbing resin including: a polymerization step of an aqueous solution of an unsaturated monomer; a drying step of the resultant hydrogel polymer; and a surface cross-linking step after drying; characterized by including a pneumatic transportation step for pneumatic transporting the water-absorbing resin powder substance in a pipeline with a surface roughness (Rz) of the inner surface of equal to or smaller than 800 nm, by using gas with a dew point of ?5° C. to ?100° C.Type: GrantFiled: March 26, 2009Date of Patent: April 2, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Koji Matsumoto, Kozo Nogi, Kunihiko Ishizaki
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Patent number: 8410219Abstract: Provided is a method for increasing the melt flow of a composition comprising a mixture of high molecular weight carboxylate functionalized ethylene copolymers (Mw between 80,000 and 500,000 Da) with low molecular weight carboxylate functionalized ethylene copolymers (Mw between 2,000 and 30,000 Da), wherein the carboxylic acid groups are at least partially neutralized to form salts containing zinc cations. The method comprises melt mixing the composition with ionomers containing cations other than zinc. Also disclosed are trimodal compositions comprising high molecular weight terpolymers, high molecular weight dipolymers and low molecular weight dipolymers wherein the carboxylic acid groups are at least partially neutralized to salts containing zinc cations and non-zinc cations. The compositions are used in films, multilayer structures and other articles of manufacture.Type: GrantFiled: December 22, 2009Date of Patent: April 2, 2013Assignee: E I du Pont de Nemours and CompanyInventor: John Chu Chen
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Patent number: 8410222Abstract: A process for producing water-absorbing polymer particles, comprising polymerization, drying, comminution, classification and recycling of the undersize obtained in the classification, wherein the recycled undersize is coated with a reducing agent and/or inorganic particles.Type: GrantFiled: July 3, 2009Date of Patent: April 2, 2013Assignee: BASF SEInventors: Rüdiger Funk, Matthias Weismantel, Sylvia Bertha
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Patent number: 8399549Abstract: Described are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compression greater than 100. Also described is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.Type: GrantFiled: April 10, 2012Date of Patent: March 19, 2013Assignee: E I du Pont de Nemours and CompanyInventor: James R. De Garavilla
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Patent number: 8394895Abstract: A process for continuous thermal postcrosslinking of water-absorbing polymer particles, wherein the postcrosslinker is applied to the water-absorbing polymer particles by means of suitable nozzles and the nozzles are exchanged or cleaned via the interior of a glovebox adjoining the plant section comprising the nozzle.Type: GrantFiled: June 10, 2009Date of Patent: March 12, 2013Assignee: BASF SEInventors: Oskar Stephan, Karl J. Possemiers, Ann Becker, Leo Van Miert, Ronny De Kaey
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Publication number: 20130046063Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.Type: ApplicationFiled: October 22, 2012Publication date: February 21, 2013Applicant: Lubrizol Advanced Materials, Inc.Inventor: Lubrizol Advanced Materials, Inc.
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Patent number: 8372920Abstract: The present invention relates to a water-absorbing polymer structure comprising about 10 to about 100,000 ppm, based on the solids content of the water-absorbing polymer structure, of a non-polymerized sulphonate, a non-polymerized salt of a sulphonate or a mixture of a non-polymerized sulphonate and a non-polymerized salt of a sulphonate, and less than 1,000 ppm, based on the solids content of the water-absorbing polymer structure, of non-polymerized sulphites, non-polymerized bisulfites, non-polymerized sulphinates or non-polymerized salts of these compounds.Type: GrantFiled: November 7, 2008Date of Patent: February 12, 2013Assignee: Evonik Stockhausen GmbHInventor: Mirko Walden
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Patent number: 8362139Abstract: The present disclosure relates to a coating composition that can be applied to a conductive substrate via an anodic electrodeposition process, a substrate coated with the coating composition and a process for applying the coating to a substrate. The coating composition comprises an aqueous dispersion of at least partially neutralized copolymer comprising ?-olefin and unsaturated carboxylic acid. After a layer of the coating has been applied to the substrate, it can be heated to cure the coating and form a crosslinked network that provides a durable chip and corrosion resistant finish.Type: GrantFiled: October 3, 2008Date of Patent: January 29, 2013Assignee: E I du Pont de Nemours and CompanyInventor: Allisa Gam
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Patent number: 8349621Abstract: A ligand molecule-immobilized polymer has a structure represented by the following general formula (1). In the general formula (1), R1 represents a ligand molecule-containing group, R2 represents a hydrophobic group, R3 represents a spacer site, R4 represents a hydrophilic group, R5 represents a group having charge, a to d specify a composition ratio and each represent an integer of 1 or more, and n and m specify chain lengths and represent integers satisfying the relationships of 1?n(a+b+c+d)?10,000 and 1?m?350.Type: GrantFiled: November 24, 2008Date of Patent: January 8, 2013Assignee: Canon Kabushiki KaishaInventor: Kousuke Mukumoto
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Publication number: 20120296034Abstract: An acid-functional polymer is reacted with a transition metal compound having an average particle size small enough to react with the polymer at a temperature below the glass transition temperature of the polymer, e.g., at room temperature, to produce cross-linked polymer. The process produces a liquid polymer product that dries to a cross-linked film without the required presence of volatile ligands. Improved coatings such as floor polishes that can be formed from these cross-linked polymers are also disclosed.Type: ApplicationFiled: July 27, 2012Publication date: November 22, 2012Inventors: Jay M. Shaffer, Tracy L. Eifolla
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Patent number: 8293845Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.Type: GrantFiled: November 9, 2007Date of Patent: October 23, 2012Inventors: Krishnan Tamareselvy, William F. Masler, III, Deborah S. Filla, Gary Gray
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Patent number: 8258223Abstract: The invention concerns a process for producing water-absorbing polymer, which comprises a base polymer A being mixed with a first aqueous solution B of at least one surface postcrosslinker and a second aqueous solution C of at least one polyvalent cation and thermally treated, wherein said base polymer A is based on at least 50% neutralized acid-functional monomer and said solutions B and C are metered wholly or partly concurrently through separate nozzles whereby a water-absorbing polymer having a high saline flow conductivity value is obtained.Type: GrantFiled: June 28, 2011Date of Patent: September 4, 2012Assignee: BASF SEInventors: Ulrich Riegel, Thomas Daniel, Matthias Weismantel, Mark Elliott, Dieter Hermeling
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Patent number: 8247499Abstract: A water-absorbing polymer structure is disclosed, whose surface has been brought into contact with a combination of a metal salt and an oxide of a metal. The invention also relates to a process for treating the surface of water-absorbing polymer structures whereby the surface of water-absorbing polymer structures is brought into contact with a combination of a metal salt and an oxide of a metal at a temperature of from about 50 to about 300° C. The present invention further relates to the water-absorbing polymer structures obtainable by this process, a composite comprising a water-absorbing polymer structure and a substrate, chemical products such as foams and fibers comprising water-absorbing polymer structures or a composite, and the use of a combination of an oxide of a metal and of a metal salt for treatment of the surface of super-absorbing polymer structures.Type: GrantFiled: April 21, 2006Date of Patent: August 21, 2012Assignee: Evonik Stockhausen GmbHInventors: Mirko Walden, Franck Furno, Harald Schmidt
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Patent number: 8236903Abstract: An acid-functional polymer is reacted with a transition metal compound having an average particle size small enough to react with the polymer at a temperature below the glass transition temperature of the polymer, e.g., at room temperature, to produce cross-linked polymer. The process produces a liquid polymer product that dries to a cross-linked film without the required presence of volatile ligands. Improved coatings such as floor polishes that can be formed from these cross-linked polymers are also disclosed.Type: GrantFiled: August 6, 2008Date of Patent: August 7, 2012Inventors: Jay M. Shaffer, Tracy L. Eifolla
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Publication number: 20120165121Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The golf ball resin composition of the present invention is characterized in that a storage modulus E? (Pa) and a loss modulus E? (Pa) satisfy a following expression; log(E?/E?2)??6.08 when measured at the conditions of the temperature of 12° C., the oscillation frequency of 10 Hz, and a strain of 0.05% in a tensile mode using a dynamic viscoelasticity measuring apparatus.Type: ApplicationFiled: November 23, 2011Publication date: June 28, 2012Inventors: Kazuyoshi SHIGA, Ryo MURAKAMI, Takahiro SHIGEMITSU
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Publication number: 20120165120Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The present invention provides a golf ball resin composition having the spin-lattice relaxation time (T1) of 13C nucleus measured by a High resolution solid state carbon nuclear magnetic resonance (NMR) method of 7.3 seconds or shorter.Type: ApplicationFiled: November 23, 2011Publication date: June 28, 2012Inventors: Kazuyoshi SHIGA, Ryo Murakami, Hideaki Kimura, Tomoka Kitago, Takahiro Shigemitsu
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Patent number: 8202925Abstract: Described are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compression greater than 100. Also described is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.Type: GrantFiled: May 26, 2009Date of Patent: June 19, 2012Assignee: E. I. du Pont de Nemours and CompanyInventor: James R. De Garavilla
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Patent number: 8188193Abstract: A process for thermally surface postcrosslinking water-absorbing polymer particles in a fluidized bed generated by means of a carrier gas, wherein the surface postcrosslinker is supplied to the fluidized bed in gaseous form.Type: GrantFiled: July 3, 2009Date of Patent: May 29, 2012Assignee: BASF SEInventors: Stefan Blei, Marco Krüger, Wilfried Heide, Matthias Weismantel, Uwe Stueven
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Patent number: 8106115Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: February 20, 2009Date of Patent: January 31, 2012Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Publication number: 20120014874Abstract: Provided are a photosensitizer-metal nanoparticle charge complex and a composition for photodynamic therapy or diagnosis containing the same. The complex includes a metal nanoparticle, a photosensitizer charged with a first charge, and a linker bound to the metal nanoparticle and charged with a second charge having an opposite polarity to the first charge. During circulation in blood, the photosensitizer-metal nanoparticle charge complex is maintained in a complex type, and thus duration of a side effect of photosensitivity can be reduced. In a tumor tissue, the complex is specifically accumulated, but in a normal tissue, it is difficult for the complex to penetrate. Thus, the complex can selectively destroy the tumor tissue. Moreover, selective fluorescence in the tumor tissue can provide further improvement in accuracy of diagnosing a tumor using the complex.Type: ApplicationFiled: October 28, 2009Publication date: January 19, 2012Inventors: Yong-Doo Choi, Bo-seung Jang, JIn-Young Park, Jung-Im Lee, In-Hoo Kim
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Patent number: 8053524Abstract: A golf ball material composed of (A) an olefin-containing thermoplastic polymer having an acid content of at least 0.5 wt % but less than 5.0 wt %, (B) a resin composition which includes one or more selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) an oxygen-containing inorganic metal compound has a good thermal stability, flow and processability, making it suitable for injection molding. The golf ball material is ideal for the production of high-performance golf balls endowed with durability, scuff resistance and optimal hardness without a loss of rebound in the molded article.Type: GrantFiled: July 15, 2009Date of Patent: November 8, 2011Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8026315Abstract: The present invention relates to a process for producing water-absorbing polymeric particles by polymerizing a monomer solution, which comprises removing the polymer gel from the reactor when the gel temperature is at least 50° C. and the monomer conversion is not more than 90 mol %, and also to a process for producing hygiene articles.Type: GrantFiled: March 28, 2006Date of Patent: September 27, 2011Assignee: Basf AktiengesellschaftInventors: Ulrich Riegel, Thomas Daniel, Dieter Hermeling, Mark Elliott
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Patent number: 8017679Abstract: The invention concerns the use of hydrosoluble homopolymers and/or copolymers of acrylic/or methacrylic acid with one or more acrylic, vinyl or ally monomers as an aid to the grinding of mineral particles in aqueous suspension, providing them by their use particular optical properties. The invention also concerns the said aqueous suspensions and their uses in the fields of paper and paint.Type: GrantFiled: March 6, 2006Date of Patent: September 13, 2011Assignee: Coatex S.A.S.Inventors: Xueping Qiu, Jacques Mongoin, Christian Jacquemet