Chemical Treating Agent Contains Elemental Hydrogen Or An Elemental Hydrogen-liberating Compound, E.g., Hydrogenation, Etc. Patents (Class 525/338)
  • Patent number: 6875819
    Abstract: The present invention is to provide a fluorine-containing polymer having excellent light transmission in the vacuum ultraviolet region of not more than 193 nm, a monomer favorably used for preparing the fluorine-containing polymer, a process for preparing the fluorine-containing polymer, and uses of the fluorine-containing polymer. The fluorine-containing polymer has at least a repeated unit structure represented by the following formula (1) and has an absorption coefficient of not more than 3.0 ?m?1 at 157 nm of ultraviolet rays. wherein R1 to R12 are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, or the like; X1 is —CRaRb—, —NRa— or —PRa— (Ra and Rb are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, hydrogen, —O—, —S—, an alkyl group of 1 to 20 carbon atoms, or the like); at least one of R1 to R12 and X1 is fluorine or a fluorine-containing group; and n is 0 or an integer of 1 to 3.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: April 5, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadahiro Sunaga, Hiroshi Kouno, Kazumori Kawamura, Takashi Ochiai, Shigeto Shigematsu, Takashi Nakano, Tomoyuki Morita, Yoshihiro Yamamoto, Hirofumi Io
  • Patent number: 6872785
    Abstract: A multi-layer nano-particle composition including a polymer core and at least two additional layers is provided. The nano-particles have a mean average diameter less than about 100 nm. The nano-particles can be modified via, for example, hydrogenation or functionalization. The nano-particles can be advantageously incorporated into rubbers, elastomers, and thermoplastics.
    Type: Grant
    Filed: December 30, 2002
    Date of Patent: March 29, 2005
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz
  • Patent number: 6864326
    Abstract: The present invention relates to a process for polymer hydrogenation that includes: polymerizing or copolymerizing at least one conjugated diene in a hydrocarbon solvent using an organic alkali metal polymerization initiator to generate a living polymer; adding a terminating agent selected from amines, esters, ketones, or halogen compounds to deactivate the active terminal of the living polymer; and selectively hydrogenating the conjugated diene polymer using at least one organotitanium compound and a lithium hydride, which is prepared from a reactor equipped with a high-speed injection nozzle and thereby precisely controlled in regard to particle diameter.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: March 8, 2005
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Young-Hoon Ko, Hoo-Chae Kim, Jae-Yun Kim, Jin-Man Hwang
  • Patent number: 6855776
    Abstract: Improved amine-terminated polybutadienes (ATPBs) having one or two terminal groups of the formula —CHRNH2 wherein R is C1-C20 alkyl, are prepared by aminating a secondary hydroxyl-terminated polybutadiene having no ether groups. The ATPBs may be hydrogenated or partially hydrogenated, either prior to or after the animation, to saturate or partially saturate the polymers. Preferred ATPBs are of the formula H2NCHR-(polybutadiene)-CHRNH2 wherein R is C1-C20 alkyl. Polyureas, polyurethanes, crosslinked epoxies, polyamides, and other derivatives with improved properties can be prepared from the ATPBs. The resultant derivatives are useful in liquid binders for braking systems, electric potting compositions, coatings, adhesives, sealants, and water proofing membranes, for example.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: February 15, 2005
    Assignee: Sartomer Technology Company, Inc.
    Inventors: Herbert Shin-I Chao, John Schmidhauser, Alain Robert Drexler, Nan Tian
  • Patent number: 6852806
    Abstract: Disclosed is a hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the unhydrogenated copolymer having at least one polymer block (H) of vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics (1) to (5): (1) a content of the vinyl aromatic monomer units of from more than 60% by weight to less than 90% by weight, based on the weight of the hydrogenated copolymer; (2) a content of the polymer block (H) of from 1 to 40% by weight, based on the weight of the unhydrogenated copolymer; (3) a weight average molecular weight of from more than 100,000 to 1,000,000; (4) a hydrogenation ratio of 85% or more, as measured with respect to the double bonds in the conjugated diene monomer units; and (5) substantially no crystallization peak observed at ?50 to 100° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.
    Type: Grant
    Filed: October 23, 2002
    Date of Patent: February 8, 2005
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masahiro Sasagawa, Shigeki Takayama, Shigeru Sasaki, Takahiro Hisasue, Katsumi Suzuki, Shigeo Nakajima
  • Patent number: 6841626
    Abstract: A process for hydrogenating aromatic polymers is disclosed. The process entails using a supported catalyst wherein support contains alumina and where the catalyst comprise at least one metal of subgroup VIII of the Periodic Table. The catalyst is characterized in that the pore volume of the pores having diameters of 1000 to 10,000 Angstrom is 15 to 100% relative to the total pore volume, as determined by mercury porosimetry.
    Type: Grant
    Filed: January 26, 2000
    Date of Patent: January 11, 2005
    Assignees: Bayer Aktiengesellschaft, Teijin Limited
    Inventors: Volker Wege, Konstadinos Douzinas, Johann Rechner
  • Publication number: 20040260028
    Abstract: A block copolymer having a polymer block [A] including two or more specific repeating units [1] and a polymer block [B] including one or more specific repeating unit [2] and/or repeating unit [3], and when a polymer block having heaviest weight average molecular weight is a polymer block [A1], the weight average molecular weight of the polymer block [A1] is Mw (A1) and a polymer block having the lightest weight average molecular weight is a polymer block [B], and the weight average molecular weight of the polymer block [A2] is Mw (A2) in the polymer block [A], having the ratio (Mw (A1)/Mw (A2)) of the Mw (A1) and Mw (A2) of 1.5 or more is provided according to the present invention, and the block copolymer has excellent fluidity at the time of molding and mechanical strength at the time of punching processing.
    Type: Application
    Filed: August 12, 2004
    Publication date: December 23, 2004
    Inventor: Atsushi Sone
  • Patent number: 6833413
    Abstract: An object of the present invention is to provide a block copolymer having the excellent improving characteristics. Specifically, the block copolymer is a hydrogenated block copolymer capable of obtaining a molded product, as a polyolefin based resin composition, having excellent physical property balance between impact resistance, in particular, low temperature impact resistance and rigidity, and molding processability, and further, capable of providing, as a viscous adhesive composition, a composition having an excellent balance between adhesion characteristics such as adhesive power and retentivity, and having excellent melt viscosity stability under heating at a high temperature.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: December 21, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masahiro Sasagawa, Shigeki Takayama, Shigeo Nakajima
  • Patent number: 6831136
    Abstract: Improved amine-terminated polybutadienes (ATPBs) having one or two terminal amino groups, are prepared by cyanoalkylating a hydroxyl-terminated polybutadiene by Michael addition of acrylonitrile in the presence of a base, forming nitrile termination, followed by hydrogenation in the presence of a Group VIII metal as catalyst. The ATPBs may be hydrogenated or partially hydrogenated, either prior to or after the amination, to saturate or partially saturate the polymers. Polyureas, polyurethanes, crosslinked epoxies, polyamides, and other derivatives with improved properties can be prepared from the ATPBs. The resultant derivatives are useful in liquid binders for braking systems, electric potting compositions, coatings, adhesives, sealants, and water proofing membranes, for example.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: December 14, 2004
    Assignee: Sartomer Technology Company, Inc.
    Inventors: Herbert Chao, Nan Tian, Alain Drexler, John Schmidhauser
  • Patent number: 6831135
    Abstract: A process is described for the hydrogenation of olefin double bonds present in polymers and copolymers of conjugated dienes, which comprises putting the above polymer or copolymer of conjugated dienes in contact with hydrogen in an inert solvent, in the presence of a catalytic system, characterized in that the above catalytic system essentially consists of one or more titanium compounds selected from those having general formula (I) wherein: M is selected from Ti(III) and Ti(IV) and their mixtures.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: December 14, 2004
    Assignees: ENI S.p.A., Polimeri Europa S.p.A.
    Inventors: Francesco Masi, Anna Sommazzi, Roberto Santi
  • Patent number: 6828385
    Abstract: A process has now been discovered that permits the simultaneous crosslinking and derivation of an, optionally hydrogenated, polymer whose backbone is composed of a conjugated diene, an unsaturated nitrile and an unsaturated carboxylic acid in the presence of a coupling/condensing agent. This permits the preparation of a novel polymeric material that is an optionally hydrogenated polymer of a conjugated diene, an unsaturated nitrile and a derived unsaturated acid. It has also been found that this novel polymeric material has unexpected and valuable properties.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: December 7, 2004
    Assignee: Bayer Inc.
    Inventors: Janet N. Gamlin, Sharon X. Guo
  • Publication number: 20040242800
    Abstract: A process for hydrogenating a conjugated diene polymer wherein a conjugated diene polymer is hydrogenated in the presence of a catalyst comprising a platinum group metal or its compound, and a basic compound. More specifically, (1) hydrogenation is conducted in a reaction system prepared by incorporating the catalyst and the basic compound in a solution or latex of the conjugated diene polymer; (2) hydrogenation is conducted in a reaction system prepared by incorporating a catalyst system comprising a combination of the catalyst with the basic compound, in a solution or latex of the conjugated diene polymer; or (3) hydrogenation is conducted in a reaction system prepared by incorporating the catalyst in a solution of a composition comprising the conjugated diene polymer and the basic compound. Thus, a hydrogenated conjugated diene polymer can be efficiently and industrially advantageously produced using a small amount of a catalyst.
    Type: Application
    Filed: March 19, 2004
    Publication date: December 2, 2004
    Inventors: Kazuhiro Takahashi, Takafumi Kawanaka
  • Publication number: 20040236029
    Abstract: The present invention relates to hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art. The present invention is also related to shaped articles containing hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art.
    Type: Application
    Filed: June 28, 2004
    Publication date: November 25, 2004
    Inventors: Frederic Guerin, Sharon X. Guo, Zsolt Szentivanyi, Stephan Glander
  • Publication number: 20040224085
    Abstract: Hydrogen-plasma modification of a contact lens made from a fluorinated polymer reduces the surface chemistry of by removing fluorine, leaving behind a carbon-enriched surface that is further plasma processed into a hydrophilic surface for a lens material to be inserted into the ocular environment.
    Type: Application
    Filed: June 9, 2004
    Publication date: November 11, 2004
    Applicant: Bausch & Lomb Incorporated
    Inventor: George L. Grobe
  • Patent number: 6815475
    Abstract: Compositions comprising hydrogenated block copolymers can be successfully used in a variety of applications including films, profiles, sheets, pultruded articles, fibers, coated articles, injection molded articles and blow or rotational molded articles.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: November 9, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Robert J. Donald, Jerry L. Hahnfeld, Gary D. Parsons, Stephen F. Hahn, Rajen M. Patel, Calvin P. Esneault, Laura M. Phipps, James E. Pate, III
  • Patent number: 6815509
    Abstract: A process for hydrogenating a polymer, which process comprises contacting a polymer containing an olefinic unsaturated group with hydrogen in the presence of a hydrogenation catalyst to hydrogenate the olefinic unsaturated group of the polymer, and recycling at least one part of the hydrogenated polymer for hydrogenation. According to the process of the present invention, there can be provided a polymer having a desirable degree of hydrogenation steadily for a long period.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: November 9, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Koichi Miyamoto, Yasumasa Yamakoshi, Toshinori Shiraki
  • Patent number: 6806322
    Abstract: The present invention relates to a hydrogenated styrene polymer that has excellent transparency, can be used suitably for an optical application such as an optical disk substrate, has stability and transparency in a hot and humid environment, and has excellent heat resistance; and a process for producing same; etc. The hydrogenated styrene polymer of the present invention has a hydrogenated polymerized styrene unit content of at least 70 wt %, a content of fine particulate foreign matter having a particle size of 0.2 &mgr;m or more and less than 0.5 &mgr;m of at most 1×106 per g of the hydrogenated styrene polymer, and a phosphorus atom content of at most 0.01 parts by weight in 100 parts by weight of the hydrogenated styrene polymer. Furthermore, the process for producing a hydrogenated styrene polymer of the present invention includes steps of filtering, with a filter having a pore size of 0.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: October 19, 2004
    Assignees: Teijin Limited, Bayer AG
    Inventors: Kiyonari Hashizume, Nobuaki Kido, Shunichi Matsumura, Takeshi Sasaki
  • Patent number: 6794456
    Abstract: Hydrogen-plasma modification of a contact lens made from a fluorinated polymer reduces the surface chemistry of by removing fluorine, leaving behind a carbon-enriched surface that is further plasma processed into a hydrophilic surface for a lens material to be inserted into the ocular environment.
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: September 21, 2004
    Assignee: Bausch & Lomb Incorporated
    Inventor: George L. Grobe, III
  • Patent number: 6790913
    Abstract: Additive compositions comprising: (i) at least one oil-soluble hydrogenated block diene polymer, comprising at least one crystallizable block, obtainable by end-to-end polymerization of a linear diene, and at least one non-crystallizable block, the non-crystallizable block being obtainable by 1,2-configuration polymerization of a linear diene, by polymerization of a branched diene, or by a mixture of such polymerizations, (ii) at least one ethylene-unsaturated ester compound; and (iii) at least one comb polymer. The additive compositions are used to improve cold flow characteristics in fuel oils. The additive compositions are particularly effective in fuel oils having a 90-20% boiling temperature range, as measured in accordance with ASTM D-86, of more than 115° C., preferably more than 120° C., more preferably more than 130° C., and most preferably more than 140° C., and a final boiling point of more than 370° C., preferably more than 380° C.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: September 14, 2004
    Assignee: Infineum International Ltd.
    Inventors: Vincent J. P. R. Deneker, Paul Harffey
  • Patent number: 6780929
    Abstract: A valve or pump gasket for sealing a fluid dispenser device comprising a valve or a pump mounted on a fluid container, said gasket being characterized in that it comprises one or more of the following elastomer materials: a) a hydrogenated nitrile butadiene rubber (HNBR); b) an octene-ethylene copolymer (OEC); and c) a butyl or a halobutyl rubber.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: August 24, 2004
    Assignee: Valois S.A.
    Inventor: Patrice Leone
  • Patent number: 6780939
    Abstract: The present invention relates to hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art. The present invention is also related to shaped articles containing hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: August 24, 2004
    Assignee: Bayer Inc.
    Inventors: Frédéric Guérin, Sharon X. Guo, Zsolt Szentivanyi, Stephan Glander
  • Patent number: 6767969
    Abstract: A hydrogenated polymer obtained by hydrogenating a conjugated diene polymer having an average vinyl bond content of 20% by weight or more and less than 40% by weight to a degree such that 85% or more of double bond residues in the conjugated diene unit portion are hydrogenated, wherein (1) the crystallizing peak temperature and the hydrogenated vinyl bond content satisfy the formula: −2.8V+100<T<−2.8V+130 wherein T is the crystallizing peak temperature (° C.) measured by DSC; and V is the hydrogenated vinyl bond content (%), (2) the molecular weight is 60,000 to 600,000, and (3) the molecular weight distribution is 1.55 to 5.0. The hydrogenated polymer is excellent in mechanical strength, heat resistance, weatherability and processability and, when blended with other thermoplastic resins or rubbery polymers, provides molded articles with well-balanced physical properties such as impact resistance and moldability.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: July 27, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masahiro Sasagawa, Shigeru Sasaki, Shigeki Takayama, Takashi Sato
  • Patent number: 6756451
    Abstract: Process for the hydrogenation of a polymer composed of conjugated diene monomer units and a nitrile group-containing monomer units, in which hydrogenation is carried out in the presence of hydrazine, and an oxidizing compound, with the hydrogenation being carried out in the presence of a antioxidant. It is preferred for NBR to be used as polymer.
    Type: Grant
    Filed: January 7, 2002
    Date of Patent: June 29, 2004
    Assignee: DSM IP Assets B.V.
    Inventors: Johannes W. Belt, Olav M. Aagaard
  • Publication number: 20040116615
    Abstract: Use is made, for selectively hydrogenating the olefinic double bonds of block copolymers, at least one block of which comprises olefinic double bonds, using a catalyst based on a metal from Group VIII in a medium comprising an organic solvent for the copolymer and an ionic liquid as solvent for the catalyst, of a water-immiscible ionic liquid, preferably an ionic liquid for which the anion is the hexafluorophosphate anion and the cation is the 1-butyl-3-methylimidazolium (bmim+) or 1-ethyl-3-methylimidazolium (emim+) cation.
    Type: Application
    Filed: January 29, 2004
    Publication date: June 17, 2004
    Inventors: Beatrice Boussand, Philippe Bonnet, Francois Court, Michel Devic, Manuel Hidalgo, Christophe Navarro
  • Publication number: 20040082728
    Abstract: A liquid polymer suitable for use as a lubricant base oil is produced by polymerizing ethylene and at least one alpha-olefin using a metallocene catalyst to provide a polymer which is then isomerized and hydrogenated to produce the liquid polymer.
    Type: Application
    Filed: September 16, 2003
    Publication date: April 29, 2004
    Inventors: Margaret May-Som Wu, Steven P. Rucker, Richard T. Spissell, Steven Edward Donnachie
  • Publication number: 20040077795
    Abstract: The present invention relates to a hydrogenated styrene-conjugated diene-styrene copolymer having excellent toughness, heat distortion temperature, and moldability, a production process therefor, and an optical material, etc. employing the copolymer.
    Type: Application
    Filed: July 25, 2003
    Publication date: April 22, 2004
    Inventors: Kiyonari Hashizume, Nobuaki Kido, Shunichi Matsumura, Kaoru Iwata, Akihiro Aoki
  • Publication number: 20040054090
    Abstract: Disclosed is an improvement to a process for preparing coupled styrenic block copolymers wherein adding from about 0.01 to about 1.5 equivalents of a metal alkyl compound per equivalent of living polymer chain ends to the cement, during or after polymerization, improves coupling efficiencies. The resultant radial styrenic block copolymers have reduced amounts of 5+ arm oligomers which can be very desirable is certain applications, such as the modification of bitumen.
    Type: Application
    Filed: July 11, 2003
    Publication date: March 18, 2004
    Applicant: KRATON Polymers U.S. LLC
    Inventors: Robert Bening, Harvey Atwood, Marinus Pieter van Dijk, Adriana Maria Petronella Ros, Barry Moore, Carl Willis, Nikolaas Jan van Dijk
  • Patent number: 6699939
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 2, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Publication number: 20040030056
    Abstract: Polymerized oils (heat-bodied oils) were hydrogenated to make a semi-crystalline wax-like material. The process of the present invention yields hydrogenated polymerized oils that can be used as bio-renewable replacements for micro-crystalline wax and petrolatums raw materials in products that are comprised of such materials. The present invention is directed to a composition comprising a hydrogenated polymerized oil, a composition consisting essentially of a hydrogenated polymerized oil and a process of preparing a hydrogenated polymerized oil. The present invention is also directed to a composition comprising a hydrogenated blown oil, a composition consisting essentially of a hydrogenated blown oil and a process for preparing a hydrogenated blown oil.
    Type: Application
    Filed: May 2, 2003
    Publication date: February 12, 2004
    Inventor: Paul D. Bloom
  • Publication number: 20040030075
    Abstract: A method of continuously manufacturing a high viscosity polyalphaolefin product by introducing a monomer and an ionic liquid catalyst together into a reaction zone while simultaneously withdrawing from the reaction zone a reaction zone effluent that contains the high viscosity polyalphaolefin. The reaction zone is operated under reaction conditions suitable for producing the high viscosity polyalphaolefin product. The preferred high viscosity polyalphaolefin has a kinematic viscosity exceeding about 8 cSt and is the reaction product of the trimerization, oligomerization, or polymerization of an alpha olefin or a mixture of one or more product thereof. The high viscosity polyalphaolefins are useful as lubricants or lubricant additives.
    Type: Application
    Filed: April 22, 2003
    Publication date: February 12, 2004
    Inventors: Kenneth D. Hope, Donald A. Stern, Donald W. Twomey, J. Barry Collins
  • Patent number: 6686430
    Abstract: A novel alicyclic hydrocarbon copolymer having a weight average molecular weight (Mw) of 1,000-1,000,000 a comprising repeating units (a) having an alicyclic structure and repeating units (b) having a chainlike structure; the sum of repeating units (a) and repeating units (b) being at least 90 wt. % based on the copolymer, and the content of repeating units (b) being at least 1 wt. % but smaller than 10 wt. %, based on the copolymer; and the chain of repeating units (a) satisfying the formula: A≦0.3×B where A=weight average molecular weight of the chain of repeating units (a), and B=Mw of the copolymer×(number of repeating units (a)/number of the total repeating units constituting the copolymer). The copolymer exhibits low birefringence and high mechanical strength. A process for producing the copolymer is provided.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: February 3, 2004
    Assignee: Zeon Corporation
    Inventor: Tsutomu Nagamune
  • Patent number: 6683136
    Abstract: The present invention provides a process of hydrogenating a nitrile copolymer rubber, which comprises subjecting the copolymer to hydrogenation in the presence of a hydrogenation catalyst, a co-catalyst, and a proton acceptor that is non-coordinating with the metal-complex catalyst.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: January 27, 2004
    Assignee: Bayer Inc.
    Inventors: Sharon X. Guo, Paul Nguyen
  • Publication number: 20040014902
    Abstract: Disclosed is a method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising: a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends; b) terminating the living chain ends; to produce a terminated block copolymer, with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl, wherein: (i) if the polymer is terminated with an alcohol and the alcohol is a linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol: living chain end molar ratio is from 0.05 to 1.
    Type: Application
    Filed: July 22, 2003
    Publication date: January 22, 2004
    Inventors: Kimberly A Johnson, Wouter de Jong, David K Schisla
  • Publication number: 20030232928
    Abstract: Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula Rx—Si—(OR′)y, where x is 0 or 1, x+y=4, R and R′ are the same or different, R is selected from aryl hydrocarbon radicals, linear alkyl hydrocarbon radicals and branched alkyl hydrocarbon radicals, and R′ is selected from linear and branched alkyl hydrocarbon radicals, such that the resulting polymer composition contains less than about ten weight percent of uncoupled polymer diblock. The polymer compositions are subsequently selectively hydrogenated, and are useful in a variety of compounds and end use applications.
    Type: Application
    Filed: June 4, 2003
    Publication date: December 18, 2003
    Applicant: KRATON Polymers U.S. LLC
    Inventors: Harvey E. Atwood, Robert C. Bening, Mark Hageman, Dale L. Handlin, Adrie A. van der Huizen, Kimberly A. Johnson, Carl L. Willis
  • Patent number: 6653424
    Abstract: Using a polymerization catalyst comprising as a main ingredient a metal compound containing a transition metal of group 6 of the periodic table and having at least one imide group and at least two substituent (A) selected from the group consisting of an alkoxy group, an aryloxy group, an alkylamide group and an arylamide group, a polycyclic norbornene monomer is polymerized to give a ring-opened norbornene polymer having a weight average molecular weight of 500 to 1,000,000 as expressed in terms of polystyrene and a melting point of 140° C. or higher. This polymer is hydrogenated to give a hydrogenated product having a melting point of 140° C. or higher.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: November 25, 2003
    Assignee: Zeon Corporation
    Inventors: Masato Sakamoto, Daisuke Uchida, Yasuo Tsunogae, Hiroshi Kurakata
  • Patent number: 6646059
    Abstract: A process is provided for the removal of iron- and rhodium-containing residues from a solution of hydrogenated nitrile rubber. The process utilizes an ion-exchange resin having thiourea functional groups. Further, the resin is both macroporour and monodispersed. The process removes both rhodium and iron from viscous rubber solutions. In a preferred embodiment, the process is carried out in an ion-exchange column.
    Type: Grant
    Filed: November 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Bayer Inc.
    Inventors: Paul Nguyen, Harald Bender, Gilles Arsenault, Ignazio Spadola, Franz-Josef Mersmann
  • Patent number: 6635718
    Abstract: Process for the preparation of a hydrogenated polymer composed of conjugated diene monomer units and monomer units containing a nitrile group, wherein the hydrogenation is carried out in the presence of hydrazine, an oxidizing compound and a metal compound as catalyst, a metal compound containing a metal atom in an oxidation state of at least 4 being used as catalyst.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: October 21, 2003
    Assignee: DSM N.V.
    Inventors: Johannes Wilhelmus Belt, Marcus Matheus Driessen
  • Patent number: 6632890
    Abstract: The present invention relates to hydrogenated block copolymers of vinyl aromatic polymer blocks and conjugated diene polymer blocks having specific total Mn and specific block Mn's such that advantageous properties are attained. The present invention also relates to hydrogenated pentablock copolymers thereof and specifically hydrogenated pentablock copolymers useful in thin walled injection molding applications.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: October 14, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Frank S. Bates, Chin Chu, Glenn H. Fredrickson, Stephen F. Hahn, Mary Ann Jones, Jerry L. Hahnfeld
  • Publication number: 20030171499
    Abstract: Hydrogen-plasma modification of a contact lens made from a fluorinated polymer reduces the surface chemistry of by removing fluorine, leaving behind a carbon-enriched surface that is further plasma processed into a hydrophilic surface for a lens material to be inserted into the ocular environment.
    Type: Application
    Filed: January 28, 2003
    Publication date: September 11, 2003
    Applicant: Bausch & Lomb Incorporated
    Inventor: George L. Grobe
  • Patent number: 6602962
    Abstract: Disclosed herein is a process for the production of hydrogenated nitrile rubber. The appearance of corrosion in the plant equipment in which hydrogenated nitrile rubber is produced is due to the unexpected presence of relatively large amounts of HCl, generated, surprisingly, by the hydro-dehalogenation of the monochlorobenzene solvent under the reaction conditions. The addition of a compatible weakly basic additive, such as Epoxidized Soy Bean Oil (ESBO), to the reaction mixture has alleviated this serious problem.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: August 5, 2003
    Assignee: Bayer Inc.
    Inventors: Paul Nguyen, Carl Walter Von Hellens
  • Publication number: 20030144428
    Abstract: A polymer composition in solid form contains hydrogenated units of a polymer composed of diene monomer units and nitrile group containing monomer units. The hydrogenated polymer has an &agr;/&bgr; peak ratio >1, measured by 1H-NMR. The a peak is measured between 2.05 and 2.2 ppm. The &bgr; peak is measured between 1.8 and 2.05 ppm. The polymer composition has a gel content of less than 15 wt. % and a molecular weight distribution (of its soluble part) of less than 10. The polymer compositions may be used to form articles, such as automotive parts, which are less sensitive to oxidation degradation.
    Type: Application
    Filed: March 5, 2003
    Publication date: July 31, 2003
    Applicant: DSM N.V.
    Inventors: Johannes W. Belt, Jacobus A.A. Vermeulen, Nikhil K. Singha, Olav M. Aagaard, Mike Kostermann
  • Publication number: 20030139535
    Abstract: A process for producing a hydrogenation product of a ring-containing unsaturated hydrocarbon polymer, which product is low in the content of the heterogeneous catalyst used.
    Type: Application
    Filed: December 11, 2002
    Publication date: July 24, 2003
    Inventors: Hironori Haga, Masaki Takeuchi, Takeshi Muraoka, Kaoru Iwata
  • Publication number: 20030125475
    Abstract: A hydrogenated polymer obtained by hydrogenating a conjugated diene polymer having an average vinyl bond content of 20% by weight or more and less than 40% by weight to a degree such that 85% or more of double bond residues in the conjugated diene unit portion are hydrogenated, wherein
    Type: Application
    Filed: June 24, 2002
    Publication date: July 3, 2003
    Inventors: Masahiro Sasagawa, Shigeru Sasaki, Shigeki Takayama, Takashi Sato
  • Patent number: 6583230
    Abstract: The present invention is a composition comprising an alternating hydrogenated block copolymer having at least two hydrogenated vinyl aromatic polymer blocks and at least one conjugated diene polymer block, wherein the number average molecular weights (Mn) of each block can be different.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: June 24, 2003
    Assignee: The Dow Chemical Company
    Inventors: Stephen F. Hahn, Glenn H. Fredrickson, Cora M. Leibig, Molly T. Reinhardt
  • Patent number: 6583239
    Abstract: A process for producing a polymer of an &agr;-olefin which comprises polymerizing an &agr;-olefin having at least 4 carbon atoms in the presence of a catalyst for producing polymers of olefins which comprises (A) a specific metal compound and (B) at least one compound selected from (b-1) an organoaluminum oxy compound and (b-2) an ionic compound. The polymer of an &agr;-olefin is useful as a component of lubricant.
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: June 24, 2003
    Assignees: Idemitsu Petrochemical Co., Ltd., Idemitsu Kosan Co., Ltd.
    Inventors: Yutaka Minami, Tatsuya Egawa
  • Publication number: 20030096916
    Abstract: Improved amine-terminated polybutadienes (ATPBs) having one or two terminal groups of the formula —CHRNH2 wherein R is C1-C20 alkyl, are prepared by aminating a secondary hydroxyl-terminated polybutadiene having no ether groups. The ATPBs may be hydrogenated or partially hydrogenated, either prior to or after the amination, to saturate or partially saturate the polymers. Preferred ATPBs are of the formula H2NCHR-(polybutadiene)-CHRNH2 wherein R is C1-C20 alkyl.
    Type: Application
    Filed: November 20, 2002
    Publication date: May 22, 2003
    Inventors: Herbert Shin-I Chao, John Schmidhauser, Alain Robert Drexler, Nan Tian
  • Patent number: 6566549
    Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing: (i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and (ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150° C. and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: May 20, 2003
    Assignee: Rohm and Haas Company
    Inventors: Gary David Greenblatt, Barry Clifford Lange, Michael Damian Bowe, Richard Foster Merritt, Robert Wilczynski, Gary Robert Larson, Lori Marie Petrovich, David William Whitman
  • Patent number: 6566457
    Abstract: The invention relates to a process for preparing graft rubbers built up from at least one graft core and from at least one graft shell, comprising a) preparing an aqueous dispersion of at least one elastomeric polymer, b) then, to obtain the at least one graft core, selectively hydrogenating ethylenically unsaturated double bonds in the elastomeric polymer, using hydrogen, in the presence of at least one hydrogenation catalyst, where the aqueous dispersion of the elastomeric polymer comprises not more than 20% by volume of an organic solvent, and c) grafting onto the graft core at least one graft shell, and also to the corresponding graft rubbers.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: May 20, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Barghoorn, Volker Schädler, Heiko Maas, Norbert Niessner
  • Publication number: 20030092851
    Abstract: The present invention relates to a process for preparing a partially hydrogenated butadiene polymer comprising no more than 3 mol % 1,2-butadiene recurring units (A) and no more than 3 mol % ethylene recurring units (D), calculated on the total content mol/mol of recurring units, wherein a butadiene polymer comprising 1,2-butadiene recurring units (A) and 1,4-butadiene recurring units (B) is hydrogenated in the presence of hydrogen and a titanium, zirconium- and/or hafnium-based metallocene compound as hydrogenation catalyst and a cocatalyst, characterized in that: a) the hydrogenation catalyst has a reaction rate ratio of r1/r2 greater than 5, wherein r1 and r2 are the hydrogenation rates of recurring units (A) and (B) respectively at the same reaction conditions, b) the cocatalyst is an alkali metal hydride, added as such of prepared in situ, and c) hydrogenation of the conjugated diene is carried out until at least 97 % of recurring units (A) have been hydrogenated.
    Type: Application
    Filed: August 14, 2002
    Publication date: May 15, 2003
    Inventor: Wouter De Jong
  • Patent number: 6559241
    Abstract: A hydrogenated polymer is prepared by a method comprising: hydrogenating a polymer having carbon—carbon double bonds and a hydroxy group and/or a functional group which is convertible into a hydroxy group or into a hydroxymethyl group in the presence of a catalyst of palladium on a base activated carbon and/or platinum on a base activated carbon.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: May 6, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Hideharu Iwasaki, Hiroyuki Ohgi, Kikuo Arimoto