Metal Hydroxide Patents (Class 525/369)
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Patent number: 5082903Abstract: Acrylic elastomer obtained by copolymerization of an epoxy group-containing vinyl monomer and an .alpha.,.beta.-unsaturated carboxylic acid aryl ester can produce vulcanization products having good compression set and heat resistance when vulcanized together which (1) a cyanuric acid and (2) a quaternary ammonium salt or phosphonium salt as cross-linking agents without secondary vulcanization.Type: GrantFiled: June 26, 1990Date of Patent: January 21, 1992Assignee: Nippon Miktron LimitedInventor: Kazuma Yokoi
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Patent number: 5081195Abstract: This invention relates to a process for hydrolysing polymeric amides with a hydrolysing agent at elevated temperatures under the influence of ultrasound in a homogeneous reaction medium. The reaction is particularly suited to the production of polyacrylic acid from polyacrylamide.Type: GrantFiled: August 6, 1990Date of Patent: January 14, 1992Assignee: BP Chemicals LimitedInventors: Martin P. Atkins, Ian S. Biggin, David A. Kidd
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Patent number: 5066682Abstract: A novel process is disclosed in which a membrane of a fluorinated resin containing a pendant precursor ion exchange group represented by the formula:--SO.sub.2 Xwherein X rerpesents a halogen atom, is contacted with a aqueous solution containing specific amounts of at least one alkali metal or alkaline earth metal hydroxide and at least one specific water soluble organic compound to thereby hydrolyze the precursor group while causing a specific membrane volume increase. In the process of the present invention , since the ion exchange membrane is swelled, while being hydrolyzed, to a desired degree, the rate of hydrolysis of precursor ion exchange groups is high, so that a final ion exchange membrane is free of wrinkles formed during the hydrolysis step of a conventional process and during the electrolytic operation, thereby enabling the final membrane to ensure advantageously low cell voltage and stable, prolonged electrolytic operation.Type: GrantFiled: June 5, 1990Date of Patent: November 19, 1991Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Makoto Miyazaki, Tatsuo Hiyoshi
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Patent number: 5045578Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, a sterically hindered amine, an epoxy compound, and a salt of a fatty acid. The polymer mixtures according to the invention have a good stability against discoloring by light.Type: GrantFiled: October 13, 1988Date of Patent: September 3, 1991Assignee: General Electric Co.Inventors: Christianus A. A. Claesen, Hideo Koike
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Patent number: 5043396Abstract: A crosslinked polymer having shape memorizing property, said crosslinked polymer being obtained by thermally reversibly crosslinking a base polymer composed of a blocked copolymer of an aromatic vinyl monomer and a conjugated diene monomer, the base polymer having a glass transition temperature of 70.degree. to 140.degree. C., and the glass transition temperature being higher than the dissociation temperature of the thermally reversible crosslinkage contained in the crosslinkage polymer.Type: GrantFiled: December 28, 1989Date of Patent: August 27, 1991Assignee: Nippon Zeon Co., Ltd.Inventors: Shizuo Kitahara, Nobuo Nagata
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Patent number: 5039756Abstract: A vulcanizable epoxy group-containing elastomer composition is disclosed, which comprises:(A) an epoxy group-containing elastomer having compounded therewith(B) an organic compound having at least two linkages, per molecule, of the formula ##STR1## wherein X and Y are each oxygen atom or sulfur atom, or one of X and Y is oxygen atom and the other is sulfur atom;(C) a quaternary ammonium salt and/or a quaternary phosphonium salt;(D) a compound having one linkage, per molecule, of the formula ##STR2## wherein Z is oxygen atom or sulfur atom; and (E) calcium oxide or a combination of calcium oxide and calcium hydroxide.Type: GrantFiled: July 7, 1989Date of Patent: August 13, 1991Assignee: Sumitomo Chemical Co., Ltd.Inventors: Keisaku Yamamoto, Nobuyuki Yoshida, Masahiro Fukuyama, Masahiro Ichinose
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Patent number: 5032646Abstract: Substantially homogeneous (meth)acrylic acid/itaconic acid copolymers of number average molecular weight of 500 to 7000 are prepared by copolymerizing in aqueous solution 5 to 90 mole percent acrylic or methacrylic acid monomer with 95 to 10 mole percent itaconic acid monomer at 80.degree. to 120.degree. C. in the presence of a polymerization initiator, the acrylic or methacrylic acid monomer and at least half of the initiator being added separately and continuously to the itaconic acid monomer throughout the polymerization period. The copolymers are employed at a level of from about 0.1 to 100 ppm for prevention of alkaline calcium and magnesium scale formation, such as during seawater evaporative desalination.Type: GrantFiled: September 28, 1984Date of Patent: July 16, 1991Assignee: Pfizer Inc.Inventor: Stanley W. Walinsky
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Patent number: 5003001Abstract: Ionically crosslinked ethylene copolymers prepared by mixing a carboxyl-containing copolymer with an aqueous metal salt solution in the reaction zone of a twin-screw extruder and transferring the product to a devolatilization zone, and are used as adhesion promoters, injection molded articles or laminating films.Type: GrantFiled: June 14, 1989Date of Patent: March 26, 1991Assignee: BASF AktiengesellschaftInventors: Norbert Hasenbein, Lothar Schlemmer, Thomas Muehlenbernd, Gernot Koehler
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Patent number: 4999404Abstract: The present invention provides an ionomer resin prepared by additionally neutralizing 2 to 30% of free carboxyl groups with magnesium hydroxide. According to the present invention, physical properties of the sodium neutralized ionomer resin are improved.Type: GrantFiled: June 3, 1987Date of Patent: March 12, 1991Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Taketo Matsuki
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Patent number: 4990574Abstract: The present invention provides an ionomer resin having desired properties which is free from the above drawbacks and can readily react in an extruder. That is, the present invention provides a process for producing a modified ionomer resin which comprises mixing ionomer resin wherein 10-60% of the total carboxylic acid moieties are neutralized with sodium ions with basic zinc carbonate under molten conditions to further neutralize 10-40% of the total carboxylic acid moieties with zinc ions.Type: GrantFiled: March 2, 1989Date of Patent: February 5, 1991Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Mikio Yamada
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Patent number: 4987186Abstract: This invention provides a pressure sensitive adhesive composition comprising an acrylic copolymer component (A) which is at least in part an acetoacetyl group-containing acrylic copolymer and at least one curing component (B) selected from the class consisting of isocyanate compounds, epoxy compounds, aldehyde compounds, non-amino resin amine compounds, metal salts, metal alkoxides, metal chelate compounds, ammonium salts and hydrazine compounds.This adhesive composition is well-balanced in the triad of tack, adhesion, cohesion in adhesion technology and can be advantageously used in various applications such as adhesive tapes and labels.Type: GrantFiled: December 21, 1988Date of Patent: January 22, 1991Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Mamoru Akiyama, Takeshi Matsuyama, Yoshiyuki Yanagida, Akira Yamashita
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Patent number: 4985506Abstract: Oxidatively cross-linkable, water dilutable binders suitable for lacquers, coating compositions and sealing compounds are modified co-polymers of olefinically unsaturated compounds, having a molecular weight of 6000 to 160,000 and having for each 100 grams of solids content, a total of from60 to 250 milliequivalents of chemically incorporated carboxyl groups, of which from 10 to 100% are neutralized thereby rendering the product dilutable in water andfrom 15 to 50% by weight of chemically incorporated moieties corresponding to the formula--O--RwhereinR represents an olefinically monounsaturated or polyunsaturated aliphatic hydrocarbon having a molecular weight above 166 and containing from 12 to 22 carbon atoms, are prepared by:(a) preparing a co-polymer having a molecular weight from 5000 to 80,000, determined by gel permeation chromatography, and having intramolecular carboxylic acid anhydride units corresponding to the formula ##STR1## and an anhydride equivalent weight of from 240 to 1960 by a radically iType: GrantFiled: June 26, 1989Date of Patent: January 15, 1991Assignee: Bayer AktiengesellschaftInventors: Harald Blum, Peter Hohlein, Michael Sonntag, Wolfgang Wellner
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Patent number: 4985514Abstract: The present invention is a method for the production of a water absorbent resin, which comprises preparing a monomer component possessing an ability to form a cross-linked structure and convert itself into a hydrated gel polymer during the course of aqueous solution polymerization, possessing an acid group-containing monomer content of at least 50 mol %, and having 10 to 50 mol % of said acid group-containing monomer neutralized and subjecting said monomer component to aqueous solution polymerization within a reaction vessel having a plurality of rotary shafts each fitted with stirring blades.Type: GrantFiled: August 9, 1988Date of Patent: January 15, 1991Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Kazumasa Kimura, Takumi Hatsuda, Yoshio Irie, Tadao Shimomura
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Patent number: 4978723Abstract: Phosphate-capped polymers and a process for their preparation by contacting a silyl ketene acetal terminated polymer with vinyl phosphonates in the presence of a catalyst.Type: GrantFiled: February 27, 1990Date of Patent: December 18, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Walter R. Hertler
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Patent number: 4977192Abstract: A granular polymer composition having increased water absorption and desorption capability, resistance to photogradation and increased life span, comprising a water-insoluble but swellable cross-linked polymer material formed of at least one polymer and/or copolymer prepared from at least one unsaturated ethylene monomer having at least one carboxylic, amide, sulfuric, sulfonic, phosphoric, phosphonic, or hydroxyl functional group and at least one powdered mineral charge well dispersed in and intimately bonded to said polymer as a result of its introduction into the mixture of monomers of the same type or of a different type before their polymerization into said polymer or copolymer.Type: GrantFiled: April 28, 1988Date of Patent: December 11, 1990Assignees: Coatex S.A., Conservatome S.A.Inventors: Pierre Martineu, Christiane Saunier, Jacky Rousset, Christian Jacquemet
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Patent number: 4970268Abstract: Disclosed is a composition, a process for making the composition, and blends comprising the composition, wherein the composition comprises (a) an at least partially neutralized carboxylated ethylene-propylene rubber copolymer that is the reaction product of (i) a non-carboxylated ethylene-propylene rubber, (ii) an azidosulfonylbenzoic acid, and (iii) and a metal based neutralizing agent wherein: (1) the carboxylated copolymer is substantially free of olefinic unsaturation, and (2) the degree of neutralization of the carboxyl groups of the carboxylated copolymer is at least 50 percent, and (b) a zinc carboxylate.Type: GrantFiled: January 8, 1990Date of Patent: November 13, 1990Assignee: Shell Oil CompanyInventor: Ann C. Udding
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Patent number: 4962147Abstract: Poly(4-hydroxystyrene) is prepared by aqueous suspension polymerization of 4-acetoxystyrene monomer followed by hydrolysis with ammonium hydroxide.Type: GrantFiled: May 26, 1988Date of Patent: October 9, 1990Assignee: Hoechst Celanese CorporationInventor: Richard Vicari
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Patent number: 4959419Abstract: Polycarboxylic acids and their salts corresponding to the following general formula[X]--(NHOC--Y--COO M).sub.n (I)in whichX is the residue of a hydrophobic, linear or branched vinyl oligomer having an average molecular weight M.sub.n of from 200 to 5000 and preferably from 300 to 3000,Y is the 1,2-vinylene, 1,2-ethylene, 1,3-propylene, 1,2-phenylene, 1,2-cyclohexen-4-ylene or 1,2-cyclohexylene group,n is a number of from 1.4 to 3.0 and preferably from 1.6 to 2.3 andM is hydrogen, an alkali metal, an ammonium, C.sub.1 -C.sub.4 alkylammonium or C.sub.2 -C.sub.3 hydroxyalkylammonium group, which are useful as surfactants and emulsifiers in aqueous systems.Type: GrantFiled: December 16, 1987Date of Patent: September 25, 1990Assignee: Bayer AktiengesellschaftInventors: Adolf Schmidt, Udo W. Hendricks, Bruno Bomer, Karl H. Ott, Herbert Eichenauer, Alfred Pischtschan
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Patent number: 4957975Abstract: A composition that exhibits low tendency to foul mold cavities comprising a fluoroelastomer of vinylidene fluoride units and units of at least one other fluorine-containing monomer copolymerizable with vinylidene fluoride; a bisphenol or a polyhydroxy phenol crosslinking agent of the formula ##STR1## where R is H, alkyl or aryl and R' is alkyl or aryl; a divalent metal oxide or hydroxide; and 0.2-4 parts by weight per 100 parts by weight fluoroelastomer of a crosslinking accelerator which is a quaternary ammonium salt of the formula R".sub.4 N.sup.+ X.sup.- wherein each R" is independently an alkyl group of 2-10 carbon atoms or an aralkyl group of 7-10 carbon atoms and X.sup.- is selected from the group consisting of fluoride, dihydrogen phosphate, periodate, acetate, hydrogen sulfate, methane sulfonate, toluene sulfonate, or an anion of a bisphenol or a polyhydroxy phenol.Type: GrantFiled: March 14, 1988Date of Patent: September 18, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventors: Dana P. Carlson, Walter W. Schmiegel
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Patent number: 4952656Abstract: The inverse emulsion polymerization of a monomer of the formula ##STR1## wherein R and R.sup.1 represent hydrogen of a C.sub.1 -C.sub.4 alkyl group, using a surfactant system having a hydrophilic-lipophilic balance value from 4 to 9, an azo-type free radical initiator and certain hydrocarbon liquids to yield a water-in-oil emulsion of a homopolymer of at least 10.sup.6 average molecular weight, the emulsion having a viscosity less than 10 cps, at 15% solids, 60 rpm Brookfield and 20.degree. C.Also disclosed is the preparation of poly(vinylamines) of at least 10.sup.6 average molecular weight by acid or base hydrolysis of the homopolymer emulsion.Also disclosed are drilling mud compositions, cements for drilling holes, completion fluids, acidized fracturing fluids, and wet-end paper additives containing the poly(vinylamines) and demonstrating superior properties.Type: GrantFiled: July 12, 1989Date of Patent: August 28, 1990Assignee: Air Products and Chemicals, Inc.Inventors: Ta-Wang Lai, Bheema R. Vijayendran
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Patent number: 4943618Abstract: A method is disclosed for preparing polyacrylonitrile copolymers by Heterogeneous reaction of polyacrylonitrile aquagel. Generally, the method includes the steps of preparing a solution of polyacrylonitrile by dissolving the polyacrylonitrile in a water-miscible solvent which is capable of dissolving the polyacrylonitrile but incapable of hydrolyzing the nitrile groups of the polyacrylonitrile under the dissolution conditions. Coagulating the polyacrylonitrile solution by replacing the solvent with a coagulating fluid such as water or a water-miscible fluid incapable of dissolving polyacrylonitrile at temperatures below 80.degree. C. and incapable of reacting with the nitrile groups of the polyacrylonitrile, thus obtaining the polymer in the aquagel state. Replacing the coagulating fluid with a fluid reagent capable of reacting with the nitrile groups of the polyacrylonitrile aquagel but incapable of dissolving the polyacrylonitrile aquagel at the selected reaction temperature.Type: GrantFiled: December 18, 1987Date of Patent: July 24, 1990Assignee: Kingston Technologies Limited PartnershipInventors: Vladimir A. Stoy, George P. Stoy, Jan Lovy
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Patent number: 4929690Abstract: Metal salts of carboxyl-containing polymers are prepared by suspending carboxyl and/or carboxylic anhydride group-containing polymers in an inert solvent, reacting with a pulverulent basic metal compound, and then working up the suspension.Type: GrantFiled: October 28, 1988Date of Patent: May 29, 1990Assignee: BASF AktiengesellschaftInventors: Hans-Helmut Goertz, Walter Denzinger, Hans-Juergen Raubenheimer
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Patent number: 4921884Abstract: Articles including ophthalmic devices prepared by a process comprising the steps of thermoforming a polymer comprising units derived from an ethylenically-unsaturated monomer bearing at least one trihaloacetoxy-substituent group, by heating the polymer in a mold or in sheet-form at a temperature in the range of 100.degree. to 400.degree. C. for about 5 seconds to 15 minutes, and then cooling said polymer, to provide a shaped article, solvolyzing the resulting shaped article to provide a hydroxy-substituted polymeric shaped article, and optionally hydrating said hydroxy-substituted polymeric shaped article to provide a shaped hydrogel article. When the polymer is derived from vinyl trihaloacetate it has a syndiotactic stereochemical configuration.Type: GrantFiled: August 17, 1988Date of Patent: May 1, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventors: W. James Hammer, Ronald F. Ofstead
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Patent number: 4904739Abstract: Compositions of poly(fluoroacetylene) useful for providing electrically conductive properties to plastics by a method of dehydrofluorination of saturated fluoroethylene polymers.Type: GrantFiled: May 27, 1988Date of Patent: February 27, 1990Assignee: Pennwalt CorporationInventor: Stanley R. Sandler
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Patent number: 4900792Abstract: The present invention relates to a composition comprising crosslinkable polyethylene homopolymer, copolymer or mixture thereof. The composition includes a peroxide crosslinking agent, a crosslinking co-agent, and a metal compound having a cation selected from Group IIA and IIB of the Periodic Table of Elements. The composition is particularly useful for polymers which are formed using Ziegler-type catalysts and have complete terminal saturation. The present invention also includes a composition which has been found particularly suitable for use in critical molding processes such as rotational molding. This composition comprises a polyethylene homopolymer, copolymer, or mixture thereof. The present invention includes a method of rotational molding.Type: GrantFiled: December 16, 1988Date of Patent: February 13, 1990Assignee: Allied-Signal Inc.Inventors: Shu P. Chen, Theodore R. Engelmann, Harold D. Oltmann
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Patent number: 4877846Abstract: A polyalcohol homopolymer having the formula: ##STR1## wherein n is about 3 to about 10.Type: GrantFiled: December 23, 1988Date of Patent: October 31, 1989Assignee: Exxon Research and Engineering CompanyInventor: Tze-Chiang Chung
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Patent number: 4877843Abstract: Copolymers of p-acetoxystyrene and allyl esters of ethylenically unsaturated acids are selectively hydrolyzed to copolymers of p-vinylphenol and allyl esters of ethylenically unsaturated acids using acid or base catalysis in an alcohol or water.Type: GrantFiled: September 11, 1987Date of Patent: October 31, 1989Assignee: Hoechst Celanese CorporationInventor: Balaram Gupta
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Patent number: 4857601Abstract: Copolymers of p-acetoxystyrene and dialkyl muconates or alkyl sorbates are selectively hydrolyzed to copolymers of p-vinylphenol and dialkyl muconates or alkyl sorbates using acid or base catalysis in an alcohol or water.Type: GrantFiled: September 11, 1987Date of Patent: August 15, 1989Assignee: Hoechst Celanese Corp.Inventor: Balaram Gupta
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Patent number: 4822862Abstract: 4-Acetoxystyrene is homopolymerized and copolymerized in aqueous emulsion and, without isolation, the polymer is hydrolyzed to homopolymers and copolymers of p-vinylphenol with a base. Homopolymers and copolymers of p-vinylphenol are used as epoxy resin curing agents and in the preparation of epoxy resins by reaction with epichlorohydrin.Type: GrantFiled: August 8, 1988Date of Patent: April 18, 1989Assignee: Hoechst Celanese CorporationInventors: Raymond W. Rupp, Donna L. Keene
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Patent number: 4818795Abstract: A process for the preparation of polymaleic acid by polymerizing maleic anhydride in an aromatic hydrocarbon at from 60.degree. to 200.degree. C., using from 1 to 20% by weight, based on maleic anhydride, of peroxyesters derived from saturated or ethylenically unsaturated carboxylic acids, as the polymerization initiators and hydrolyzing the polymer, the polymaleic acid thus obtained and the use of the polymaleic acid as an agent for reducing scale formation and hard water deposits in systems through which water flows.Type: GrantFiled: September 3, 1987Date of Patent: April 4, 1989Assignee: BASF AktiengesellschaftInventors: Walter Denzinger, Heinrich Hartmann, Ulrich Goeckel, Felix Richter, Ekhard Winkler, Hans-Juergen Raubenheimer
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Patent number: 4814389Abstract: An aqueous drilling fluid having present in an amount sufficient to disperse the fluid and to provide resistance to high temperatures and solids contamination of the drilling fluid, at least one salt of a polymer or copolymer of acrylic or methacrylic acid with alkanolamine, alkylamine, mixtures of alkanolamine and alkylamine, mixtures of lithium and alkanolamine, mixtures of lithium and alkylamine and mixtures of lithium, alkanolamine and alkylamine, the polymer having a weight average molecular weight of between about 2,000 and about 15,000 and a pH of from about 6 to about 8.5 and where mixtures of lithium and alkanolamine, lithium and alkylamine or mixtures of lithium, alkanolamine and alkylamine are used, the amount of lithium is present to give from about 30% to about 70% of the desired neutralization of the polymer and the alkanolamine and/or alkylamine is present to give from about 70% to about 30% of the desired neutralization of the polymer.Type: GrantFiled: July 8, 1987Date of Patent: March 21, 1989Assignee: Diamond Shamrock Chemicals CompanyInventors: Christopher M. Garvey, Arpad Savoly, Thomas M. Weatherford
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Patent number: 4812529Abstract: A polyalcohol homopolymer having the formula: ##STR1## wherein n is about 3 to about 10.Type: GrantFiled: January 5, 1987Date of Patent: March 14, 1989Assignee: Exxon Research & Engineering Co.Inventor: Tze-Chiang Chung
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Patent number: 4801655Abstract: A hydrolyzed dye/gel polymer for use in a pH-based sensor is characterized by its chemical and optical stability with respect to dye loss with time. Preferably, the dye/gel polymer is hydrolyzed by heating in a dilute base solution for a period of time sufficient to remove weakly bonded dye molecules from the polymer, then washed to remove the base solution and loose dye.Type: GrantFiled: August 20, 1987Date of Patent: January 31, 1989Assignee: Gould, Inc.Inventors: Richard C. Murray, Jr., Mark S. Goorsky
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Patent number: 4798871Abstract: The inverse emulsion polymerization of a monomer of the formula ##STR1## wherein R and R.sup.1 represent hydrogen or a C.sub.1 -C.sub.4 alkyl group, using a surfactant system having a hydrophilic-lipophilic balance value from 4 to 9, an azo-type free radical initiator and certain hydrocarbon liquids to yield a water-in-oil emulsion of a homopolymer of at least 10.sup.6 average molecular weight, the emulsion having a viscosity less than 10 cps, at 15% solids, 60 rpm Brookfield and 20.degree. C.Also disclosed is the preparation of poly(vinylamines) of at least 10.sup.6 average molecular weight by acid or base hydrolysis of the homopolymer emulsion.Also disclosed are enhanced oil recovery compositions, drilling mud compositions, cements for drilling holes, completion fluids, acidized fracturing fluids, and wet-end paper additives containing the poly(vinylamines) and demonstrating superior properties.Type: GrantFiled: June 19, 1987Date of Patent: January 17, 1989Assignee: Air Products and Chemicals, Inc.Inventors: Ta-Wang Lai, Bheema R. Vijayendran
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Patent number: 4789709Abstract: A process for the production of a thermoplastic copolymer having excellent heat distortion resistance is disclosed. The process includes heat-treating a raw copolymer comprising a vinyl monomer unit including methacrylic and/or acrylic acid units in the presence of a specific ring-closing promoter selected from basic compounds, whereby the methacrylic and/or acrylic acid unit is converted into six-membered cyclic anhydride unit. The copolymer has excellent heat distortion resistance, transparency, mechanical properties and processability, and can produce a formed product without splash on the surface. The copolymer is useful for the production of various parts, such as automobile parts, electrical parts, industrial parts, and miscellaneous goods.Type: GrantFiled: October 30, 1986Date of Patent: December 6, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Yasuyuki Kato, Masahiro Yuyama, Masahiko Moritani, Hideaki Matsuura, Susumu Iijima, Tsuyoshi Hashimoto
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Patent number: 4785059Abstract: A hydrophilic, water-swellable graft copolymer comprising polyethylene vinyl acetate (PEVA) containing between 8 and 30 wt. % vinyl acetate units, radiation graft copolymerized with an ethylenic carboxylic acid and subsequently heat treated in an aqueous hydroxide solution at a temperature greater than the softening point of the PEVA. A process for the preparation of such a polymer by radiation induced graft copolymerization of PEVA with an ethylenic carboxylic acid and subsequent heat treatment in an aqueous hydroxide solution at a temperature greater than the softening point of the PEVA is also described. The polymers of the invention are suitable for making into devices for various applications, but are particularly useful for making surgical devices, such as laparascope tubes, urethal catheters, endovascular cannuli, for endoscopic access, and as endo-prostheses. Some examples of surgical uses of such devices using the invention are described.Type: GrantFiled: July 6, 1987Date of Patent: November 15, 1988Assignee: The Secretary of State for Defence in Her Brittanic Majesty's Government of the United Kingdon of Great Britain and Northern IrelandInventors: Peter J. Fydelor, Ronald A. Miller, Barbara J. Ringrose, Jonathan W. A. Ramsay
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Patent number: 4782120Abstract: Non-polluting thinning adjuvant for sea-water and/or fresh-water based drilling muds.Non-polluting thinning adjuvant for sea-water and/or fresh-water based drilling muds, with the aim to maintain their rheological characteristics in the extreme conditions of temperature and pressure which prevail in wells drilled at great depths. This thinning adjuvant is characterized by the fact that it is a hydrosoluble copolymer resulting from the copolymerization of ethylenic acids, acrylamides and ethylenic esters of phosphoric acid.Its general formula is: ##STR1## in which the indices m,n,p -expressed in % in mole- are chosen from the following intervals:0%<m<90%2%<n<100%0%<p<90%and where radicals R.sub.1, R.sub.2 and R.sub.4 are chosen from the group consisting of H and the alkyles, and radical R.sub.3 is chosen from the group consisting of alkylenes and alkylene-oxides and/or polyalkylene oxides.Type: GrantFiled: April 13, 1987Date of Patent: November 1, 1988Assignee: Coatex, S.A.Inventors: Jacky Rousset, Jean-Bernard Egraz, Gilles Letetour
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Patent number: 4775715Abstract: Cationic polyvinyl alcohol is prepared by blending polyvinyl alcohol under high shear conditions, at 0.degree.-100.degree. C., with a small amount of water, a small excess of base, and a quaternizing agent containing a halohydrin radical and a quaternary ammonium group. The quaternization proceeds with acceptable conversions of about 35 to well over 50%. The quaternized polyvinyl alcohol has many applications, including use as a flocculating agent, as a stabilizing colloid, and in adhesive formulations.Type: GrantFiled: July 23, 1987Date of Patent: October 4, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Aleksander Beresniewicz, Thomas Hassall, Jr.
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Patent number: 4775723Abstract: The invention relates to metal carboxylate derivatives of partially esterified .alpha.-olefin unsaturated polycarboxylic acid copolymers, the .alpha.-olefin containing 6 to 40 carbon atoms and the copolymer being esterified with an alcohol. At least 80 percent by weight of the unesterified copolymer has a molecular weight in the range from 1000 to 100,000. Preferably, the .alpha.-olefin is maleic anhydride and the alcohol contains 4 to 18 carbon atoms. The present compounds are surprisingly satisfactory internal and external lubricants for synthetic resin as PVC. Furthermore, the present compounds can be used as emulsifying and/or suspending agents, in particular when the alcohol is a polyethylene oxide glycol ether with 1 to 50 ethylene oxide units.Type: GrantFiled: November 4, 1987Date of Patent: October 4, 1988Assignee: AKZO N.V.Inventors: Helmut Kuhne, Karl-Heinz Frassek, Dieter Sonderhof, Gunther Lanzrath, Fritz Steinseifer, Heinz Beck
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Patent number: 4774285Abstract: Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C.sub.1 -C.sub.4 -alkyl vinyl ethers, the esters, nitriles and amides of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinylformamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.Type: GrantFiled: September 15, 1986Date of Patent: September 27, 1988Assignee: BASF AktiengesellschaftInventors: Sigberg Pfohl, Michael Kroener, Heinrich Hartmann, Walter Denzinger
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Patent number: 4767804Abstract: The invention provides a polymer derivative comprising the reaction product of a metal compound and a polymer having functional groups. The metal compound may be an acetate, carbonate, chloride, hydroxide, oxalate, oxide or sulphate of Al, Ba, Ca, Ce, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Mo, Na, Pb, Sn, Ti, V, Zn and Zr. The functional group may be a carboxylic acid group, a thiol group or an olefinic group.The invention includes a process for efficiently reacting a functional group on a polymer with at least one co-reagent wherein the co-reagents are rendered compatible with the polymer, for example by being dissolved in the polymer or in a solution thereof whereby the reaction is effected in a single phase. The process may be a two stage process which comprises forming a metal derivative of a polymer of relatively low molecular weight and then incorporating the metal derivative into a polymer of higher molecular weight.Type: GrantFiled: September 4, 1986Date of Patent: August 30, 1988Assignee: Rubber Bands and Plastic Research Association of Great BritainInventor: Bryan G. Willoughby
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Patent number: 4751276Abstract: The present invention relates to a process for the preparation of functional alpha-olefin homo- and copolymers by polymerization through a borane monomer intermediate.Borane monomers, derived from mono-hydroboration of appropriate dienes with dialkyl borane, have been found to be stable to Ziegler-Natta catalysts. In turn, the borane homo- and copolymers are easily converted to a variety of other functionalities; e.g., alcohols, aldehydes, amines, etc.Type: GrantFiled: July 27, 1987Date of Patent: June 14, 1988Assignee: Exxon Research and Engineering CompanyInventor: Tze-Chiang Chung
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Patent number: 4749762Abstract: Amphoteric polymers prepared by polymerization of (a) acrylic acid, (b) N,N-dimethyl- orN,N-diethylaminoethyl methacrylate and, optionally, (c) esters of methacrylic or acrylic acid prepared by (i) emulsion polymerization of (b), (c) and the methyl ester of (a), followed by basic hydrolysis, or (ii) polymerization of (a), (b) and (c) in the presence of a strong acid, and photographic emulsions comprised of said polymers in which the molar ratio of (a) to (b) is at least 2 to 1 and a silver halide.Type: GrantFiled: May 12, 1982Date of Patent: June 7, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert P. Foss
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Patent number: 4740562Abstract: A method for the surface modification of objects made from polyvinylidene fluoride by dehydrofluorinated of the surface of the objects. The dehydrofluorination is carried out with an etching solution which, in addition to a strong basic compound and a swelling agent and/or solvent for polyvinylidene fluoride, contains an auxiliary agent for the homogenization of the etching solution. The effect of etching is supported by an adhesion promoter. High resistance to shearing and good tough-elasticity in composite structure and laminates is achieved.Type: GrantFiled: May 22, 1986Date of Patent: April 26, 1988Assignee: agru Alois Gruber & Sohn oHGInventors: Klaus Menke, Klaus Wollmann, Gerhard Glink
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Patent number: 4734472Abstract: The present invention relates to a process for the preparation of functional alpha-olefin homo- and copolymers by polymerization through a borane monomer intermediate.Borane monomers, derived from mono-hydroboration of appropriate dienes with dialkyl borane, have been found to be stable to Ziegler-Natta catalysts. In turn, the borane homo- and copolymers are easily converted to a variety of other functionalities; e.g., alcohols, aldehydes, amines, etc.Type: GrantFiled: December 24, 1986Date of Patent: March 29, 1988Assignee: Exxon Research and Engineering CompanyInventor: Tze-Chiang Chung
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Patent number: 4698395Abstract: A process of purifying maleic anhydride graft polyolefin comprising the steps of adding an aqueous solution of alkali initial hydroxide to a solution of maleic anhydride graft polyolefin containing unreacted maleic anhydride which is dissolved in an organic solvent at a temperature from 80.degree. C. to 160.degree. C., thereby precipitating maleic anhydride graft polyolefin particles to make a W/O emulsion; stirring the W/O emulsion while maintaining the temperature at a same temperature as above for less than 2 hours, thereby selectively forming the alkali metal salt of unreacted maleic anhydride; adding the aqueous solution of alkali metal hydroxide to the W/O emulsion to convert the W/O emulsion into an O/W emulsion; separating the maleic anhydride draft polyolefin particles, and washing the maleic anhydride graft polyolefin particles with water.Type: GrantFiled: May 14, 1986Date of Patent: October 6, 1987Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Takayuki Inoue, Masafumi Hattori, Kazuhide Hayama, Riichiro Maruta
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Patent number: 4694046Abstract: Novel water soluble terpolymers of acrylamide, an alkali metal or ammonium salt of acrylic acid and an oil soluble or hydrophobic alkyl acrylamide monomer have been found to provide efficient viscosification of water or brine solutions. The polymers are prepared by a free radical micellar polymerization of acrylamide and alkyl acrylamide followed by base catalyzed partial hydrolysis. These terpolymers, called HRAM, impart unique and useful rheological properties to aqueous solutions. In a water or brine solution the hydrophobic groups associate to increase hydrodynamic size and enhance thickening efficiency. Solutions containing the HRAM terpolymers show increased viscosification at higher polymer concentration and reduced salt sensitivity relative to polyacrylamide based HPAM solutions.Type: GrantFiled: November 25, 1985Date of Patent: September 15, 1987Assignee: Exxon Research and Engineering CompanyInventors: Jan Bock, Donald B. Siano, S. Richard Turner
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Patent number: 4683286Abstract: The invention relates to homopolymers and copolymers of acrylonitrile with very low Fikentscher K values of 34-15 and a total content of sulfonate and sulfate end groups, which do not originate from correspondingly substituted comonomers, of 250 to 1,000 milliequivalents per kilogram of polymer, 180 to 900 milliequivalents per kilogram being in the form of sulfonate end groups, and to suitable semi-continuous or continuous precipitation polymerization processes for their preparation by means of a redox system in an aqueous medium.The resulting polymers can be extruded to shaped articles. In particular, after hydrolysis, they can be used as emulsifiers and deep bore auxiliaries.Type: GrantFiled: February 21, 1986Date of Patent: July 28, 1987Assignee: Hoechst AktiengesellschaftInventors: Tibor Krakkay, Tatjana Poggi, Ernst Schubert
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Patent number: 4678842Abstract: Compositions of poly(fluoroacetylene) useful for providing electrically conductive properties to plastics by a method of dehydrofluorination of saturated fluoroethylene polymers.Type: GrantFiled: November 29, 1984Date of Patent: July 7, 1987Assignee: Pennwalt CorporationInventor: Stanley R. Sandler
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Patent number: 4673716Abstract: Novel water soluble copolymers of acrylamide, oil soluble higher alkylacrylamide and alkali metal acrylate have been found to provide efficient viscosification of water or brine. The process for synthesizing them relies on the complete solubilization of the water insoluble monomer into an aqueous solution of the water soluble monomer(s) by means of a suitable water soluble surfactant. A redox initiator system is used in conjunction with high monomer concentration and a low reaction temperature. The surfactant chosen and its concentration is one that produces a clear, uniform, homogeneous mixture in the presence of the monomers and gives a product which remains a clear uniform, homogeneous mixture with no phase separation as the reaction proceeds toward completion. The molecular weight of the resulting polymer after isolation from the surfactant is sufficiently high that it gives an intrinsic viscosity greater than about 12 dl/g.Type: GrantFiled: November 25, 1985Date of Patent: June 16, 1987Assignee: Exxon Research and Engineering CompanyInventors: Donald B. Siano, Jan Bock