Oxygen Compound Contains At Least One Alcohol Group Patents (Class 525/384)
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Publication number: 20110301560Abstract: There is provided an absorbent resin particle having an absorption rate pattern where the rate is slow in the initial stage, moderate in the middle stage, and fast in the late stage, and there is also provided an absorbent article free from problems such as skin irritation by using the absorbent resin particle. The present invention relates to an absorbent resin particle comprising a crosslinked polymer (A1) including, as an essential constituent unit, a water-soluble vinyl monomer (a1) and/or a hydrolyzable vinyl monomer (a2), and a crosslinking agent (b), wherein, in a measurement method of swelled volume per 1 g of the absorbent resin particle against physiological saline, a ratio (t2/t1) of the time (t2) until swelled volume reaches 40 ml to the time (t1) until the swelled volume reaches 5 ml is 5 to 20.Type: ApplicationFiled: December 24, 2009Publication date: December 8, 2011Applicant: SAN-DIA POLYMERS, LTD.Inventors: Takashi Fujimura, Hidenobu Ishida
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Publication number: 20110301303Abstract: The present invention relates to a process for preparing a water absorbent resin, particularly to a process for preparing a water absorbent resin which can resolve the uneven size of the fine pulverized gel-type resin and long pulverizing time those are the problems of prior process for preparing the water absorbent resin, by carrying out the pulverizing process of the gel-type resin divided into the coarse pulverizing process which is carried out with the internal cross-linking polymerization, and the fine pulverizing process. According to the preparation process, it is possible to mass-produce the water absorbent resin showing excellent absorption under pressure and low extractable content.Type: ApplicationFiled: June 7, 2011Publication date: December 8, 2011Applicant: LG CHEM, LTD.Inventors: Jun-Kyu KIM, Jong-Hyuk KWON, Young-Jae HUR, Yun-Kyung DO
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Patent number: 8071676Abstract: A primary modified polymer composed of (1) a hydrogenated polymer obtained by hydrogenating at least one non-hydrogenated polymer selected from the group consisting of polymers comprising conjugated diene monomer units and copolymers comprising conjugated diene monomer units and vinyl aromatic monomer units and (2) groups of a primary modifier having a functional group which are bonded to the polymer (1), which has a specific vinyl aromatic monomer unit content, a specific vinyl aromatic polymer block content, a specific weight-average molecular weight, and a specific degree of hydrogenation of the double bonds of conjugated diene monomer units; a secondary modified polymer obtained by reacting a primary modified polymer composed of (?) a base polymer and (?) groups of a primary modifier having a functional group which are bonded to the polymer (?) with a secondary modifier; and compositions comprising the primary or secondary modified polymer and at least one other component.Type: GrantFiled: December 22, 2008Date of Patent: December 6, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki, Shigeo Nakajima, Yasuhiro Kusanose
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Patent number: 8063151Abstract: The copolymers include a hydrophobic monomer and an acryloyl or methacryloyl ester of a propylene glycol monomethyl ether, also referred to as 1-methyl-2-methoxyethyl acrylate (“MMOEA”). The combination of the hydrophobic monomer and the MMOEA monomer advantageously provides desired mechanical strength, biocompatibility, and drug permeability in the copolymers. The copolymers can advantageously be used on medical devices.Type: GrantFiled: November 19, 2007Date of Patent: November 22, 2011Assignee: Abbott LaboratoriesInventor: Stephen Pacetti
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Patent number: 8058355Abstract: The present invention provides solvent- and water-based primer compositions that include at least one chlorinated carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The chlorinated carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof then chlorinated. The chlorinated carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified chlorinated carboxylated polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified chlorinated carboxylated polyolefins water-dispersible.Type: GrantFiled: August 31, 2005Date of Patent: November 15, 2011Assignee: Eastman Chemical CompanyInventors: Robert Lee Eagan, Kevin Alan Williams, Allen Morgan Cheek
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Patent number: 8058354Abstract: The present invention provides solvent- and water-based primer compositions that include at least one carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof. The carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.Type: GrantFiled: June 30, 2003Date of Patent: November 15, 2011Assignee: Eastman Chemical CompanyInventors: Kevin Alan Williams, Robert Lee Eagan, Lisa Kay Templeton, Richard Leon McConnell
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Publication number: 20110257306Abstract: Composition comprising at least one vinyl halide polymer and 0.1 to 5% by weight, relative to the weight of the vinyl halide polymer, of at least one polymer of at least one acrylic ester obtained by polymerization in solution in a liquid medium comprising at least one chain transfer agent chosen among the C3-C20 hydrocarbons containing at least one secondary alcohol function. Process for its manufacture, article obtained starting from this composition and use of this composition for manufacturing sheets and films via calendaring or for manufacturing profiles by extrusion. Process for the manufacture of a polymer of at least one acrylic ester which can be used in the composition.Type: ApplicationFiled: October 12, 2009Publication date: October 20, 2011Applicant: SOLVAY SAInventors: Vincent Bodart, Claudine Bloyaert, Dirk Dompas
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Publication number: 20110257340Abstract: A process for producing water-absorbing polymer particles by polymerizing a monomer solution or suspension comprising an ethylenically unsaturated monomer bearing acid groups, an ethylenically unsaturated monomer, a crosslinker and an initiator.Type: ApplicationFiled: April 18, 2011Publication date: October 20, 2011Applicant: BASF SEInventors: Norbert Herfert, Thomas Daniel, Thomas Gieger
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Patent number: 8030412Abstract: The present invention relates to an active-energy-ray-curable coating composition containing, as essential components, a radical-polymerizable resin (I) containing a polymer structure (?) of a radical-polymerizable unsaturated monomer and a poly(perfluoroalkylene ether) chain (?), and having a resin structure in which a plurality of the polymer structures (?) are linked to each other with the poly(perfluoroalkylene ether) chain (?) therebetween and the polymer structures (?) each have a radical-polymerizable unsaturated group at a side chain thereof; and a polymerization initiator (II). The active-energy-ray-curable coating composition can be used as a coating material that imparts surface properties such as stain-proof properties.Type: GrantFiled: April 15, 2009Date of Patent: October 4, 2011Assignee: DIC CorporationInventors: Hideya Suzuki, Shin Sasamoto
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Publication number: 20110237754Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises thermal postcrosslinking in the presence of steam.Type: ApplicationFiled: March 23, 2011Publication date: September 29, 2011Applicant: BASF SEInventors: Thomas Daniel, Marco Krüger, Karin Flore, Stefan Blei, Uwe Stueven, Norbert Herfert, Michael A. Mitchell
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Patent number: 8026315Abstract: The present invention relates to a process for producing water-absorbing polymeric particles by polymerizing a monomer solution, which comprises removing the polymer gel from the reactor when the gel temperature is at least 50° C. and the monomer conversion is not more than 90 mol %, and also to a process for producing hygiene articles.Type: GrantFiled: March 28, 2006Date of Patent: September 27, 2011Assignee: Basf AktiengesellschaftInventors: Ulrich Riegel, Thomas Daniel, Dieter Hermeling, Mark Elliott
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Patent number: 8026309Abstract: A process is provided for producing a compatibilized polymeric blend. A first thermoplastic polymer and a reactive moiety are provided to a progressive melt kneading apparatus. The reactive moiety comprises a first reactive group capable of reacting with the first thermoplastic polymer but not a second polymer and a second reactive group capable of reacting with the second polymer but not the first polymer. The first thermoplastic polymer and the reactive moiety are then melt kneaded so that the first reactive group reacts with the first thermoplastic polymer and the second reactive group is grafted to the first thermoplastic polymer, forming a molten self-compatibilizer. A molten second polymer is then provided. The molten self-compatibilizer is melt kneaded with the molten second polymer so that the second reactive group reacts with the second polymer to form a compatibilized polymeric blend. Also provided are articles formed from the compatibilized polymer blend.Type: GrantFiled: February 29, 2008Date of Patent: September 27, 2011Assignee: PRS Mediterranean Ltd.Inventors: Izhar Halahmi, Oded Erez, Adi Erez
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Publication number: 20110224375Abstract: The instant invention pertains to the preparation of polymers or copolymers wherein in a first step a controlled free radical polymerization process is carried out and in a second step the resulting polymer is modified by transesterification reactions. The final modified polymer or copolymer is useful as a dispersant for pigments. Further aspects of the invention are the thus prepared polymers or copolymers, a pigment concentrate containing the polymer or copolymer and a coating material containing the pigment concentrate.Type: ApplicationFiled: May 20, 2011Publication date: September 15, 2011Inventors: Ralf KNISCHKA, Ernst Eckstein, Clemens Auschra, Akira Matsumoto
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Patent number: 8008430Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.Type: GrantFiled: August 17, 2006Date of Patent: August 30, 2011Assignee: Nalco CompanyInventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
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Patent number: 7994259Abstract: The invention relates to a method for the production of a polymer (P) comprising amide and ester groups, whereby, in a first step, a homo- or co-polymer (P1) of (meth)acrylic acid is reacted with a monohydroxy compound (E) at a temperature of up to 200° C., such that, in addition to ester groups, anhydride groups are formed and, in a second step, the anhydride groups formed in the first step are reacted with a monoamine compound (A) at temperatures significantly below 100° C. The invention further relates to polymers produced by the above method, the use thereof in hydraulic-setting compositions and said hydraulic-setting compositions before and after hardening by addition of water.Type: GrantFiled: March 18, 2005Date of Patent: August 9, 2011Assignee: Sika Technology AGInventors: Ueli Sulser, Irene Schober, Ulf Velten, Anna Krapf
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Publication number: 20110178208Abstract: Polymers P as dispersants, in particular as liquefiers, for hydraulically setting systems, and hydraulically setting systems including the polymer P. The polymer P includes at least one acid unit, at least one ester unit, and at least one unit containing terephthalate or naphthalate.Type: ApplicationFiled: October 29, 2008Publication date: July 21, 2011Applicant: SIKA TECHNOLOGY AGInventors: Christina Hampel, Ulf Velten, Ueli Sulser, Jabbar Al Shemari, Norman Blank
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Patent number: 7981969Abstract: The invention concerns a process for producing water-absorbing polymer, which comprises a base polymer A being mixed with a first aqueous solution B of at least one surface postcrosslinker and a second aqueous solution C of at least one polyvalent cation and thermally treated, wherein said base polymer A is based on at least 50% neutralized acid-functional monomer and said solutions B and C are metered wholly or partly concurrently through separate nozzles whereby a water-absorbing polymer having a high saline flow conductivity value is obtained.Type: GrantFiled: February 18, 2005Date of Patent: July 19, 2011Assignee: BASF AktiengesellschaftInventors: Ulrich Riegel, Thomas Daniel, Matthias Weismantel, Mark Elliott, Dieter Hermeling
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Publication number: 20110166300Abstract: A method for the production of a water-absorbing resin is to be provided which permits enhancement and stabilization of property, for example, liquid permeability, of a water-absorbing resin by a simple and convenient method without requiring change of raw materials or expensive facility investment. The method comprises a polymerization step for polymerizing an aqueous solution of acrylic acid (or salt thereof) to obtain a hydrogel cross-linked polymer; a drying step for drying the hydrogel cross-linked polymer to obtain a water-absorbing resin powder; a classification step for classifying the water-absorbing resin powder; and a surface cross-linking step for surface cross-linking the water-absorbing resin powder before or after the classification step, wherein electricity is eliminated in the classification step.Type: ApplicationFiled: September 11, 2009Publication date: July 7, 2011Applicant: Nippon Shokubai Co. LtdInventors: Yorimichi Dairoku, Kozo Nogi, Syuji Kanzaki, Kunihiko Ishizaki, Koji Matsumoto, Yoshiro Mitsukami
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Patent number: 7964673Abstract: A proton-conducting polymer comprises a main chain and a plurality of branched side chains extending radially therefrom. The branched side chains are each bonded to a proton-conducting salt at the end. In the proton-conducting polymer, the salts can be circumscribed by a virtual circle having a center on the cross-sectional center of the main chain such that a radial direction of the virtual circle is perpendicular to a longitudinal direction of the main chain. Thus, the proton-conducting polymer has a substantially cylindrical structure, and the salts are located on the peripheral wall of the substantially cylindrical structure. Protons are transferred between the adjacent salts, so that a conduction channel is formed on the peripheral wall of the cylindrical structure.Type: GrantFiled: January 22, 2008Date of Patent: June 21, 2011Assignee: Honda Motor Co., Ltd.Inventors: Tadahiro Shiba, Hitoshi Iwadate
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Publication number: 20110144262Abstract: The invention provides a process for producing spiral polymers controlled in the direction of spiral winding easily from inexpensive general-purpose polymers; and spiral polymers controlled in the direction of spiral winding. The invention relates to a process for the production of syndiotactic polymethacrylate- or polyacrylate-type spiral polymers controlled in the direction of spiral winding which comprises dissolving a syndiotactic polymethacrylate- or polyacrylate-type polymer and a chiral compound in a solvent preferably under heating, subjecting the obtained solution to cooling or concentration to form a solid matter, and separating the solid matter; and so on.Type: ApplicationFiled: March 18, 2008Publication date: June 16, 2011Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCYInventors: Takehiro Kawauchi, Jiro Kumaki, Eiji Yashima
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Publication number: 20110136954Abstract: The present invention relates to an acrolein polymer containing a carbon biosourced according to the ASTM D6866-06 standard, and to the preparation method thereof including a first step for dehydrating glycerol from a glycerol aqueous solution in the presence of an acid catalyst, followed by a polymerization of the obtained substance in the presence of an ionic catalyst or a free radical initiator. The polymer according to the invention has numerous uses in the fields of animal health, antibiotics, disinfection and sterilization, cosmetics, drilling sludge, paints and inks, and the paper and textile industries, and responds to certain sustainable development concerns.Type: ApplicationFiled: June 19, 2009Publication date: June 9, 2011Applicant: ARKEMA FRANCEInventor: Jean-Luc Dubois
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Patent number: 7956130Abstract: A rubber composition for a tire superior in grip performance and abrasion resistance and a tire prepared by using the same are provided. The rubber composition for a tire comprises 3 to 200 parts by weight of an aromatic vinyl polymer having an end modified with —OH, —SH, —COOH, —CSSH, —SO3H, —(COO)xM, —(SO3)xM or —CO—R (M is a cation, x is an integer of 1 to 3 depending on the valency of M and R is an alkyl group) and having a weight average molecular weight of 300 to 10,000, based on 100 parts by weight of a diene rubber, and the tire is prepared by using the rubber composition.Type: GrantFiled: July 20, 2007Date of Patent: June 7, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kazuyuki Nishioka, Katsumi Terakawa
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Publication number: 20110105739Abstract: The invention relates to functionalized matrix materials or matrices that have structures of general formula (I) T-(C?O)O—B-D, methods for the production thereof, and the use thereof in methods for purifying and isolating biomolecules.Type: ApplicationFiled: February 20, 2009Publication date: May 5, 2011Inventors: Roland Fabis, Ralf Hammelreich
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Publication number: 20110100916Abstract: Articles that contain a solid support with a grafted chain extending from the solid support, methods of making these articles, and various uses of the articles are described. More specifically, the grafted chain has a functional group that can react with or interact with target compound. Alternatively, the functional group on the grafted chain can react with a modifying agent to provide another group that can react with or interact with the target compound. The grafted chains are attached to the solid support through a ring-opened azlactone group. The articles can be used to purify the target compound or to separate the target compound from other molecules in a sample.Type: ApplicationFiled: May 11, 2009Publication date: May 5, 2011Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Simon K. Shannon, Catherine A. Bothof, Babu N. Gaddam, Jerald K. Rasmussen, Richard B. Ross
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Patent number: 7928166Abstract: There is disclosed a polyvinyl alcohol having a 1,2-glycol bond in a side chain, and a process for preparing the polyvinyl alcolnol wherein there is no generation of dimethyl carbonate hence no need of a process of eliminating dimethyl carbonate in the recovering process of waste liquid after hydrolysis. Also, even when an introduction amount of 1,2-glycol bonds is increased, there is no deterioration of solubility in a hydrolyzing solution (methanol) of a copolymer (paste) before hydrolysis. Further, water-insolubility is not lowered even in experiencing thermal history. Specifically, there is provided a polyvinyl alcohol having a 1,2-glycol bond in a side chain obtained by hydrolyzing a copolymer of a vinyl ester monomer and a compound shown in the formula (1) wherein the hydrolysis degree of the polyvinyl alcohol is at least 60% by mol.Type: GrantFiled: August 18, 2004Date of Patent: April 19, 2011Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventor: Mitsuo Shibutani
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Patent number: 7919564Abstract: The present invention provides a method for manufacturing a particulate water-absorbing agent which has excellent liquid diffusibility and liquid permeability, and whose amount of residual monomers is reduced. The method for manufacturing the particulate water-absorbing agent of the present invention includes a step of surface-crosslinking, in the presence of an organic crosslinking agent, water-absorbing resin particles obtained through at least a step of polymerizing an aqueous solution of unsaturated monomers, and in or after the polymerizing step, a reaction system is mixed with peroxide. Thus, it is possible to obtain the particulate water-absorbing agent which has excellent liquid diffusibility and liquid permeability and whose amount of residual monomers is small, that is, it is possible to obtain the particulate water-absorbing agent which is highly functional and highly safe.Type: GrantFiled: September 28, 2006Date of Patent: April 5, 2011Assignee: Nippon Shokubai Co., Ltd.Inventors: Hirofumi Shibata, Kazushi Torii
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Patent number: 7906591Abstract: A method for preparing acid-containing polymers by reacting them in the presence of end-capped polyols or amines in the presence of phosphorous-containing compounds.Type: GrantFiled: November 25, 2008Date of Patent: March 15, 2011Assignee: Rohm and Haas CompanyInventors: Barry Weinstein, Kenneth Bruce Laughlin, William C. Finch
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Patent number: 7897677Abstract: This invention provides a water-based primer composition comprising (A) an aqueous dispersion of modified polyolefin, which is prepared by dispersing a modified polyolefin (a) in an aqueous medium, the polyolefin (a) being produced by modifying an unsaturated carboxylic acid- or acid anhydride-modified polyolefin (i) having a melting point not higher than 120° C. and an weight-average molecular weight within a range of 30,000-200,000, further with a compound having polyoxyalkylene chain; (B) at least one kind of aqueous resin selected from aqueous urethane resin, aqueous acrylic resin and aqueous polyester resin; and (C) pigment; the solid weight ratio of the component (A)/component (B) being within a range of 20/80-85/15, and containing the component (C) in an amount within a range of 0.5-200 parts by weight per 100 parts by weight of the total solid resin content of the composition.Type: GrantFiled: April 5, 2007Date of Patent: March 1, 2011Assignee: Kansai Paint Co., Ltd.Inventors: Yasuyuki Kataoka, Toshiaki Nagano, Minoru Ishikura, Terutaka Takahashi, Hideo Sugai
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Publication number: 20110045030Abstract: The present invention pertains to crosslinkable and crosslinked polyisobutylene-based polymers, to compositions that contain such polymers, and to medical devices that are formed using such polymers. According to one aspect, the present invention pertains to crosslinkable and crosslinked compositions that comprise a copolymer that comprises a polyisobutylene segment and two or more reactive groups. According to another aspect, the present invention pertains to medical devices that contain such compositions. According to another aspect, the present invention pertains to methods of making medical devices using such compositions.Type: ApplicationFiled: August 20, 2010Publication date: February 24, 2011Applicant: CARDIAC PACEMAKERS, INC.Inventors: Shrojalkumar Desai, Mark Boden
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Patent number: 7893168Abstract: To provide a hydrophobic linear polyrotaxane molecule which is soluble in an organic solvent, and a crosslinked polyrotaxane using the same. A hydrophobic linear polyrotaxane molecule has a cyclic molecule, a linear molecule including the cyclic molecule with piercing through the cyclic molecule, and blocking groups placed at both end terminals of the linear molecule to prevent the cyclic molecule from leaving from the linear molecule. The linear molecule is hydrophobic. The linear molecule is polycaprolactone and has a molecular weight ranging from 5,000 to 100,000. The cyclic molecule is ?-cyclodextrin, ?-cyclodextrin or ?-cyclodextrin. A crosslinked polyrotaxane is formed by combining the hydrophobic linear polyrotaxane molecule and a polymer through the cyclic molecule.Type: GrantFiled: August 23, 2006Date of Patent: February 22, 2011Assignees: Nissan Motor Co., Ltd., The University of TokyoInventors: Kohzo Ito, Jun Araki, Tatsuya Suzuki, Masahiko Yamanaka, Kentarou Watanabe
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Publication number: 20110040044Abstract: The present invention provides a surface treatment method for a water-absorbing resin comprising three steps of: 1) a humidifying and mixing step for mixing a base polymer and a surface cross-linking agent solution to obtain a “humidified substance”; 2) a pretreatment step for raising temperature of said humidified substance to obtain a “pretreated substance”; and 3) a surface cross-linking reaction step for cross-linking said pretreated substance to obtain a surface cross-linked “water-absorbing resin”; wherein dew point in the pretreatment step of the above 2) is from 50° C. to 95° C., and temperature of said humidified substance is raised from temperature below the dew point up to a temperature of 10° C. higher than the dew point.Type: ApplicationFiled: April 10, 2009Publication date: February 17, 2011Applicant: Nippon Shokubai Co., Ltd.Inventors: Atsushi Motoyama, Seiji Kato, Makoto Matsumoto, Takaaki Kawano, Yoshio Irie
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Patent number: 7887926Abstract: The invention provides novel polymers, including triblock polymers, as well as methods of preparing the polymers, and compositions that include such polymers. The polymers can include at least three blocks, the first block that includes poly(styrene), the second block that includes a random arrangement of poly(ethylene) and poly(butylene), and a third block that includes functionalized poly(isoprene). Units of the functionalized poly(isoprene) block can include hydroxyl groups and one or more ether linked side chains comprising R1, R2, R3, R4, R5, R6, as defined herein, or a combination thereof. The polymers can be used to provide antifouling coatings, for example, for marine ship hulls.Type: GrantFiled: March 4, 2009Date of Patent: February 15, 2011Assignees: Cornell University, Kraton PolymersInventors: Christopher K. Ober, Craig Jonathan Weinman, Daewon Park, Dale L. Handlin, Carl Lesley Willis
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Patent number: 7868099Abstract: This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated tin containing compound to produce a polymer which is terminated with halogenated tin moieties, wherein the halogenated tin containing compound is of the structural formula: wherein X represents a halogen atom, wherein Z1 groups can be the same or different and are selected from alkyl groups containing from 1 to 8 carbon atoms, wherein x represents an integer from 1 to 20, wherein the molar ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated tin containing compound is within the range of 2:n to (n?1):n, wherein n represents the number of halogen atoms that are bonded directly to tin atoms in the halogenated tin containing compound; (b) reacting the polymer which is terminated with halogenated tin moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy tin moietieType: GrantFiled: July 28, 2010Date of Patent: January 11, 2011Assignee: The Goodyear Tire + Rubber CompanyInventors: Adel Farhan Halasa, Wen-Liang Hsu, Chad Aaron Jasiunas
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Patent number: 7863390Abstract: Esterified polyalkene/UAR copolymer reaction products useful as (1) a friction modifier for lubricating oils such as automatic transmission fluids to improve torque capacity and anti-shudder durability and for continuous variable transmissions (CVTs), (2) a friction modifier for fuels or (3) a cold flow improver for diesel fuels are provided. The esterified copolymer reaction product may be used as is or can be further derivatized (e.g., by post treatment of the esterified copolymer reaction product with, for example, ethylene carbonate or boric acid).Type: GrantFiled: March 17, 2009Date of Patent: January 4, 2011Assignee: Chevron Oronise Company LLCInventor: Kenneth D. Nelson
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Publication number: 20100317808Abstract: To provide a novel fluorinated compound, a fluoropolymer and a method for producing the compound. A compound represented by the formula CF2?CFCF2C(X)(C(O)OZ)(CH2)nCR?CHR (wherein X is a hydrogen atom, a cyano group or a group represented by the formula —C(O)OZ, Z is a hydrogen atom or a C1-20 monovalent organic group, n is 0, 1, or 2, and R is a hydrogen atom or a C1-20 monovalent organic group), a method for producing it, and a fluoropolymer obtained by polymerizing the compound.Type: ApplicationFiled: August 18, 2010Publication date: December 16, 2010Applicant: Asahi Glass Company, LimitedInventors: Koichi MURATA, Naoko SHIROTA, Osamu YOKOKOJI, Yoko TAKEBE
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Publication number: 20100301258Abstract: that are made up of oriented polymer chains are provided. Chains of polymer may be oriented or substantially aligned in one or more directions exhibiting enhanced thermal conductivity along the direction of orientation. Orientation of polymers within sheets may lead to a wide range of thermally relevant applications.Type: ApplicationFiled: April 17, 2008Publication date: December 2, 2010Applicant: Massachusetts Institute of TechnolohyInventors: Gang Chen, Erik Skow, Xiaoyuan Chen
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Publication number: 20100292352Abstract: The composition and the preparation of a chain-extending concentrate for production of foamed cellular materials of aromatic polyesters is disclosed in this invention. The chain-extending concentrate includes an ethylene-acrylate copolymer, a high-temperature thermoplastic and a multifunctional compound. The preparation process includes two steps: 1) Mixing and melt blending the multifunctional compound and the HT thermoplastic resin into the matrix of the ethylene-acrylate copolymer in an internal mixer and 2) extrusion of the mixture at a temperature below the melting point or reaction temperature of the multifunctional compound.Type: ApplicationFiled: May 18, 2010Publication date: November 18, 2010Applicant: ARMACELL ENTERPRISE GMBHInventors: Jie LI, Horst GRATER, Mika MELLER
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Patent number: 7812097Abstract: An improved curable formaldehyde-free binding composition is provided. Such curable composition comprises the reaction product of a polyanhydride and a polyol crosslinker and a lower molecular weight anhydride. Initially, the polyanhydride is modified through reaction with a polyol (e.g., a glycol or an alkanolamine) and subsequently is grafted with the lower molecular weight anhydride (e.g., maleic anhydride) to form a water-soluble or water-dispersible curable reaction product. The composition is well suited for binding fibrous materials (e.g., a mat of glass fibers) or for bonding together non-fibrous materials. The binder composition displays an advantageous viscosity so as to facilitate a flowable application with ease combined with an adequately high molecular weight to satisfactorily undergo service as a binder following curing even when harsh environmental conditions (e.g., hot humid air) are encountered for a prolonged period of time.Type: GrantFiled: September 22, 2009Date of Patent: October 12, 2010Assignee: Johns ManvilleInventor: Kiarash Alavi Shooshtari
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Publication number: 20100256309Abstract: A heat-shrinkable polyester film is provided which exhibits a high shrinkability in a high-temperature range with a main shrinking direction oriented in a longitudinal direction thereof, though not shrinking in the longitudinal direction in a low-temperature range, possesses an extremely high mechanical strength in a transverse direction orthogonal to the main shrinking direction, and, in particular, can be utilized suitably as a film for forming a jacket label of a battery or in similar applications.Type: ApplicationFiled: December 11, 2008Publication date: October 7, 2010Applicants: TOYO BOSEKI KABUSHIKI KAISHA, FUJI SEAL INTERNATIONAL INC.Inventors: Takuro Endo, Masatoshi Hashimoto, Katsuhiko Nose
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Publication number: 20100256293Abstract: A formaldehyde-free coating for a fibrous substrate is provided. The coating includes a thermoset binder system having a polymer binder and a crosslinker, wherein the thermoset binder system is waterborne and has an alkali pH from about 7 to about 10. The coating has a high modulus and the ability to hygroscopically expand.Type: ApplicationFiled: April 1, 2010Publication date: October 7, 2010Inventor: Lida Lu
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Patent number: 7803879Abstract: An aqueous, formaldehyde-free binder composition comprising a modified copolymer of maleic anhydride and a vinyl aromatic compound such as styrene, the copolymer being modified by reaction with a primary alkanolamine, such as monoethanolamine (MEA), to produce a modified copolymer that is self-curing and cures as a consequence of cross-linking, esterification reactions between pendant carboxyls and hydroxyl groups on the solubilized (hydrolyzed) modified copolymer chains; the invention also relates to the corresponding method of using the binder composition for making fiber products, especially fiberglass insulation.Type: GrantFiled: June 16, 2006Date of Patent: September 28, 2010Assignee: Georgia-Pacific Chemicals LLCInventors: Ramji Srinivasan, Kurt Gabrielson, John B. Hines, Cornel Hagiopol
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Publication number: 20100239521Abstract: The various embodiments herein provide a method for producing a carrier system for the encapsulation or entrapment of a bioactive agent. According to one embodiment herein, producing a carrier complex of a bioactive ingredient disposed within a carrier material, the method comprising the steps of: (a) providing a complexation zone supplied with an aqueous medium containing the carrier material; (b) simultaneously stirring and heating the aqueous medium; (c) adding the bioactive ingredient to the aqueous medium and maintaining the complexation zone under conditions of temperature effective to facilitate complexation of the bioactive ingredient by the carrier material; and (d) recovering from the complexation zone a carrier complex of the bioactive ingredient.Type: ApplicationFiled: June 1, 2010Publication date: September 23, 2010Inventor: MOHAMMAD REZA MOZAFARI
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Publication number: 20100234531Abstract: Among other things, a process for producing an agglomerated superabsorbent polymer particle and an agglomerated superabsorbent polymer particle are disclosed. The process comprises the steps of: (A) bringing superabsorbent polymer fine particles having at least about 40 wt. %, a particle size of less than about 150 ?m into contact with a fluid comprising to more than about 10 wt. % a cross-linkable, uncrosslinked polymer based on polymerized, ethylenically unsaturated, acid group-bearing monomers or salts thereof; and (B) cross-linking the uncrosslinked polymer by heating the superabsorbent polymer fine particles and the fluid to a temperature from about 20 to about 300° C., so that the cross-linkable, uncrosslinked polymer at least partially crosslinks.Type: ApplicationFiled: May 28, 2010Publication date: September 16, 2010Inventor: Markus FRANK
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Patent number: 7795354Abstract: An aqueous binder composition, useful for making fiber products, especially fiberglass insulation, comprising an aqueous substantially alkaline (pH of at least 5.0) solution of a polyol and a hydrolyzed (solubilized) copolymer of maleic anhydride and a vinyl aromatic compound, preferably styrene (i.e., a SMA copolymer); the copolymer is solubilized using ammonia, a secondary alkanolamine (preferably diethanolamine (DEA)), a tertiary alkanolamine (preferably triethanolamine (TEA)), or a mixture thereof and the binder composition is cured as a consequence of cross-linking, esterification reactions between pendant carboxyls on the solubilized (hydrolyzed) copolymer (SMA) chains and hydroxyl groups of the polyol, including the diethanolamine and/or triethanolamine preferably used in the solubilization of the SMA.Type: GrantFiled: June 16, 2006Date of Patent: September 14, 2010Assignee: Georgia-Pacific Chemicals LLCInventors: Ramji Srinivasan, Kurt Gabrielson, John B. Hines, Cornel Hagiopol
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Patent number: 7781536Abstract: It is an object of the present invention to provide an ocular lens superior in the wettability of the surface thereof, hydrating properties, oxygen permeability, flexibility, elasticity, transparency and shape recoverability though it has a composition using a silicone-containing monomer. The present invention relates to a highly oxygen-permeable hydrated ocular lens obtained by saponifying a copolymer prepared from a specific both-terminal (meth)acryl polydimethylsiloxane, a vinyl carboxylate, a (meth)acrylamide type monomer, a vinyl type crosslinking agent, one or both of a (meth)acrylate having a tertiary structure and a (meth)acrylate having a cyclic structure as (meth)acrylates each having a bulky structure at its side chain and a monomer copolymerizable with these compounds.Type: GrantFiled: September 15, 2005Date of Patent: August 24, 2010Assignee: Seed Co., Ltd.Inventors: Takehisa Kamiya, Kazunori Kobayashi, Kenji Uno
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Patent number: 7767766Abstract: A method of manufacture of soluble, microbiologically active and stable acrolein polymer comprising: (a) polymerising acrolein in the presence of base to form a polymer of acrolein; (b) dissolving the polymer of acrolein in an alcohol selected from monoalcohols and polyols optionally with addition of water to form an alcohol solution of the polymer of acrolein; (c) heating the alcohol solution of the polymer of acrolein; and (d) mixing base with the polymer of acrolein.Type: GrantFiled: November 5, 2004Date of Patent: August 3, 2010Assignee: Chemeq Ltd.Inventor: Matthew Tilbrook
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Publication number: 20100184920Abstract: A method comprising preparing a reaction mixture comprising a styrene monomer, an antioxidant, and a reaction rate improving additive, contacting the reaction mixture with an antioxidant reactive compound, and placing the reaction mixture under conditions suitable for polymerization of the styrene monomer to a styrenic polymer wherein the polymerization occurs at an overall reaction rate that is increased by equal to or less than 20% when compared to an otherwise similar polymerization process carried out in the absence of the reaction rate improving additive A method comprising preparing a reaction mixture comprising a styrene monomer, an elastomer, an antioxidant, a sodium or calcium salt of an organic acid, and an initiator; and placing the reaction mixture under conditions suitable for polymerization of the styrene monomer to a styrenic polymer, wherein the sodium or calcium salt of an organic acid protects the initiator such that the polymerization is carried out at a reaction rate greater than would othType: ApplicationFiled: January 22, 2009Publication date: July 22, 2010Applicant: Fina Technology, Inc.Inventor: David Knoeppel
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Patent number: 7745542Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound and with at least one aromatic amine.Type: GrantFiled: July 27, 2006Date of Patent: June 29, 2010Assignee: Chevron Oronite Company LLCInventors: William R. Ruhe, Jr., Casey D. Stokes, James A. Gray
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Patent number: 7745537Abstract: The present invention provides a particulate water absorbing agent for absorbent cores which is excellent in powder conveying property, and achieves sufficient absorption performances for use in absorbent cores in particulate water absorbing agents including a water absorbing resin as a principal component, and which further is suitable for practical applications. In the present invention, characteristics that had not been known conventionally at all, i.e., “permeability potential under pressure (PPUP)” and “frictional charge being a positive charge” of the particulate water absorbing agent are regulated at a time, and furthermore, regulation of the “moisture content of 2 to 10% by weight” is perfected. Also, the particulate water absorbing agent including (A) a water-swelling crosslinked polymer having a constitutional unit derived from an unsaturated monomer containing an acid group and/or a salt thereof; and (B) water fulfills certain requirements.Type: GrantFiled: April 6, 2006Date of Patent: June 29, 2010Assignee: Nippon Shokubai Co., Ltd.Inventors: Yasuhisa Nakashima, Toshihiro Takaai, Katsuyuki Wada
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Patent number: RE42299Abstract: The present invention is related to a polymer comprising terminal sulfonic acid groups, which has a high ionic conductivity and good structural stability, does not decompose even under low humidity conditions, and is inexpensive to produce. Furthermore, the present invention is related to a polymer electrolyte and a fuel cell using the same. The polymer of the present invention has a substituent comprising a terminal sulfonic acid group comprising Formula (1) at a side chain: where n may be a number in the range of about 1 to about 5.Type: GrantFiled: May 26, 2010Date of Patent: April 19, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Do-yun Kim, Min-ju Jeong, Myung-sup Jung, Bong-Seok Moon