Mixed With Ethylenically Unsaturated Reactant Or Polymer Derived Therefrom Patents (Class 525/401)
  • Patent number: 11903380
    Abstract: The invention relates to a mixture of polyoxymethylene dialkyl ethers (POM) having a specific molecular distribution of n as well as its preparation method. The invention also relates to a composition comprising: a) a mixture of polyoxymethylene dialkyl ethers (POM) having a restricted specific molecular distribution b) at least one biocidal agent c) at least one pro-penetrating agent d) at least one dye e) optionally, another additive and water as diluent, It also relates to a non-therapeutic method of preserving and/or embalming a dead human or animal body using the composition, such as the use of this composition for anatomopathological purposes.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: February 20, 2024
    Assignee: ARKEMA FRANCE
    Inventors: Jean-Luc Dubois, Jean-Luc Couturier, Didier Belluard, Christian Haroux
  • Patent number: 11807720
    Abstract: In some aspects, the present disclosure pertains to a multi-arm polymer comprising a core and a plurality of polyoxazoline segments (or arms) having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.
    Type: Grant
    Filed: August 21, 2020
    Date of Patent: November 7, 2023
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Joseph T. Delaney, Jr., Paul V. Grosso, John Kummailil, Tatyana Dyndikova, Carey Rehder
  • Patent number: 11015010
    Abstract: Provided is a block copolymer that makes it possible to produce inorganic nanoparticles that can be dispersed in an organic solvent, the inorganic nanoparticles being of uniform size and a reducing agent not having to be used. A block copolymer including a catechol segment represented by formula (1).
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: May 25, 2021
    Assignee: JAPAN SCIENCE AND TECHNOLOGY AGENCY
    Inventors: Hiroshi Yabu, Yuta Saito
  • Patent number: 9982123
    Abstract: The invention relates to a process for producing molding compositions containing: a) from 55 to 85% by weight of copolymer A composed of vinylaromatic monomer A1 and a,B-unsaturated monomer A2; b) from 15 to 45% by weight of graft copolymer B with particle size from 50 to 550 nm composed of: B1: from 60 to 80% by weight of rubbery graft base B1 composed of: B11: from 80 to 99% by weight of at least one C2-C8-alkyl acrylate, B12: from 0.5 to 2.5% by weight of cyclic crosslinking agent, B13: from 0 to 2% by weight of non-cyclic crosslinking agent, B2: from 20 to 40% by weight of at least one graft shell B2 composed of: B21: from 60 to 75% by weight of a styrene, B22: from 25 to 40% by weight of acrylonitrile, c) from 0 to 10% by weight of additives C; where the reaction time of the polymerization for producing the graft base B1 is in the range from 2 to 5 h, and the addition of the starting materials takes place over at least two chronological segments.
    Type: Grant
    Filed: April 1, 2015
    Date of Patent: May 29, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Jordan Kopping, Philipp Boeckmann, Norbert Niessner, Lydia Behring
  • Patent number: 8877873
    Abstract: The invention relates to a hybrid resin, which is suitable in particular for impregnating paper webs. The hybrid resin according to the invention can be advantageously used for improving the mechanical properties of counteracting layers in multilayer boards.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: November 4, 2014
    Assignee: Kaindl Decor GmbH
    Inventor: Paul Leitner
  • Publication number: 20140275435
    Abstract: The present invention pertains to bio-based block polymers synthesized from functionalized lignin-based molecules (A-monomer) and functionalized fatty acids or fatty alcohols (B-monomer) derived from plant or animal oils, waxes or fats. The block polymers can be synthesized via numerous polymerization techniques, such as reversible addition-fragmentation chain transfer (RAFT). Most importantly, this class of bio-based block polymers shows promise as providing sustainable yet scalable and tunable thermoplastic elastomers and pressure-sensitive adhesives, among other applications.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 18, 2014
    Applicant: University of Delaware
    Inventors: Thomas H. Epps, III, Angela L. Holmberg, Joseph F. Stanzione, Richard Wool
  • Patent number: 8802791
    Abstract: An abrasive product includes a plurality of abrasive particles and a resin cured with a polythiol group. A method of preparing the abrasive product includes contacting the plurality of abrasive particles with a curable composition that includes a resin and a polythiol group, and curing the curable composition to produce the abrasive product. A method of abrading a work surface includes applying an abrasive product to a work surface in an abrading motion to remove a portion of the work surface. A curable composition includes a formaldehyde resin and a polythiol group. A formaldehyde resin is crosslinked by a polythiol group. A method of crosslinking the formaldehyde resin includes reacting the polythiol group with the formaldehyde resin.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: August 12, 2014
    Assignees: Saint-Gobain Abrasives, Inc., Saint-Gobain Abrasifs
    Inventors: Anthony C. Gaeta, William C. Rice
  • Patent number: 8329829
    Abstract: A thermoplastic polyurethane composition includes thermoplastic polyurethane (TPU), a polysiloxane, an acetal polymer, and an acrylonitrile-butadiene-styrene (ABS) copolymer. A method of forming the TPU composition includes the step of combining the TPU, the polysiloxane, the acetal polymer, and the ABS copolymer. The thermoplastic polyurethane composition is also used to form an article. The TPU composition has an increased abrasion resistance and decreased coefficient of friction as compared to existing TPUs.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: December 11, 2012
    Assignee: BASF SE
    Inventor: Gulay Serhatkulu
  • Patent number: 8106098
    Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: January 31, 2012
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 7915350
    Abstract: Compositions are described comprising a) polyoxymethylene, b) thermoplastic elastomer having active hydrogen atoms, c) polyoxymethylene which differs from component a) and contains active hydrogen atoms, d) reagent for covalent coupling of components b) and c), and e) if appropriate, another impact modifier, which differs from component b). The compositions feature improved toughness and can be used for production of moldings.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: March 29, 2011
    Assignee: Ticona GmbH
    Inventors: Holger Schmalz, Christine Köstler, Klaus Kurz
  • Patent number: 7906594
    Abstract: The invention relates to a process for preparation of polymer blends comprising at least one polyoxymethylene and at least one thermoplastic elastomer, where the thermoplastic elastomer is micropelletized by a pelletizing process and the pellets obtained in a) are dispersed in the polyoxymethylene matrix via melting of the components and mixing of these at low shear forces, and also to the use of micropelletized thermoplastic elastomers for preparation of polyoxymethylenes with low formaldehyde emission.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: March 15, 2011
    Assignee: Ticona GmbH
    Inventors: Karl-Friedrich Mück, Ernst Hofmann, Michael Hoffmockel
  • Patent number: 7795357
    Abstract: Multiblock copolymers are described and contain the structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—X-D-X—(CO—R2)m—CO—X—??(I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical-having at least two carbon atoms or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, X is selected from —O—, —S—, or —NH—, D is a divalent radical B which is a radical of a hydroxy-terminated, mercaptan-terminated, or amino-terminated polymer which derives from polyalkylene glycols, polyvinyl ethers, polyvinyl ether-alkene copolymers, polyvinyl esters, polyvinyl ester-alkene copolymers, polyvinyl alcohols, polyvinyl alcohol-alkene copolymers, polyvinylaromatics, polyacrylates, polymethacrylates, polyacetals, polycarbonates, polyesters, polyamides, polyimines, polyetherester elastomers, polyetheramide elastomers, polyalkadienes, polyurethanes, polyureas, polysiloxanes, or a triblock copolymer radical -PAO-B-PAO-, wh
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: September 14, 2010
    Assignee: Ticona GmbH
    Inventors: Dirk Zierer, Klaus Kurz, Jens Schiebisch, Karl-Friedrich Mück, Holger Schmalz
  • Patent number: 7199166
    Abstract: Radiation-curable resins containing a carbonyl-hydrogenated ketone-aldehyde and/or a ring-hydrogenated phenyl-aldehyde resins, and a process for preparing them.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: April 3, 2007
    Assignee: Degussa AG
    Inventors: Patrick Gloeckner, Lutz Mindach, Peter Denkinger
  • Patent number: 7160924
    Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: January 9, 2007
    Assignees: The General Hospital Corporation, Amgen, Inc.
    Inventors: Olaf B. Kinstler, David L. Ladd, Mikahil I. Papisov
  • Patent number: 6780940
    Abstract: The present invention relates to an adhesive resin composition comprising a heat-generating material (A) which generates heat when subjected to high frequency induction and a thermoplastic resin (B) modified with a monomer having a functional group which reacts with an inorganic, the thermoplastic resin (B) having a melting point ranging from 90° C. to 200° C. The present invention also relates to a method for separating a bonded article into adherends, the method comprising detaching by induction heating the bonded portions of adherends bonded together by the thermoplastic resin composition comprising a heat-generating material (A) which generates heat when subjected to high frequency induction and a thermoplastic resin (B) modified with a monomer having a functional group which reacts with an inorganic substance and has a melting point ranging from 90° C. to 200° C.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: August 24, 2004
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Nori Yoshihara, Kenji Ohama, Satoshi Sakai, Hitoshi Kosugi, Koji Nakanishi
  • Patent number: 6777487
    Abstract: The present invention relates to a polyacetal ABA type block copolymer having a liquid hydrogenated polybutadiene block hydroxyalkylated at both end having a specific monomer structure in the main chain and a polyacetal resin composition comprising the block copolymer and a specific polymer compound or an inorganic filler. The block copolymer and the resin composition can satisfy 4 characteristics necessary for materials for large-diameter gears, i.e. (1) high cycle capability (high productivity), (2) high roundness, (3) distinguished dimensional stability and (4) distinguished durability at the same time and provide useful materials for large-diameter gears having a pitch circle diameter of 60 mm or more.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: August 17, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masahiko Niino, Hideki Nakamura, Sumio Komatsu
  • Patent number: 6599446
    Abstract: Inclusion of relatively small amounts of organic ionic species, such as calcium stearate, in the preparation of an electrically conductive polymer composite composition provides a composition having enhanced electrical properties relative to the composite composition lacking the added organic ionic species. As a result of this enhancement, normally insulating materials which rely upon a conductive filler to render them electrically conductive, can be made to achieve a given level of conductivity using less of the conductive filler than would otherwise be required. As a result, the adverse effects of the conductive filler on the polymer's physical properties can be minimized while maintaining a high level of electrical conductivity.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: July 29, 2003
    Assignee: General Electric Company
    Inventors: Michael Leslie Todt, David Ernest Rodrigues, Sai-Pei Ting
  • Patent number: 6576714
    Abstract: The present invention provides a production process for a terminal-end-stabilized glyoxylic acid (salt)-based polymer, which process enables to reduce the amount of the polymerization solvent, as recovered or removed after the end of the polymerization (before the start of the hydrolysis) or after the end of the hydrolysis, without lowering the production efficiency. The production process for a terminal-end-stabilized glyoxylic acid (salt)-based polymer comprises the step of polymerizing a monomer component including a glyoxylic acid ester in order to produce the terminal-end-stabilized glyoxylic acid (salt)-based polymer, wherein a terminal end stabilizer is used as a reaction medium of the polymerization.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: June 10, 2003
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takuya Saeki, Akihiko Kanzaki, Junichi Nakamura, Yoshikazu Fujii, Shigeru Yamaguchi
  • Patent number: 6506835
    Abstract: A novel composition is disclosed which comprises polyvinyl chloride, an ethylene-based copolymer as a compatibilizer, inorganic fillers and from about 5 to 95 percent by weight of either virgin or recycled/recovered polyvinyl butyral. A process for preparing this novel composition is also provided.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: January 14, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: George Henry Hofmann
  • Patent number: 6506838
    Abstract: Modified oxymethylene polymers comprising a linear polymer of oxymethylene repeat units, blocked at one end by at least one terminal group selected from the group consisting of an alkylene oxide as an adduct to alcohol and an alkylene oxide as an adduct to carboxylic acid, the linear polymer excluding the terminal group having a number average molecular weight of 10,000-500,000 and the modified oxymethylene polymer having a molecular weight distribution (Mw/Mn) of not more than 2.5, obtained by anionic polymerization of formaldehyde and the alkylene oxide as an adduct to alcohol and/or carboxylic acid. The present modified oxymethylene polymers can give moldings with improved repeated impact resistance at the welded parts and controlled smell generation, and improved sliding characteristics, wherein the sliding characteristics are further improved upon combination with an olefinic polymer.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: January 14, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Toshiharu Seyama
  • Publication number: 20020137876
    Abstract: A process for producing amino resin particles includes: a reaction process for obtaining a reaction solution containing an amino resin precursor which is obtained by a reaction of an amino compound with formaldehyde, and having a viscosity in a range of from 2×10−2 Pa.s to 5.8×10−2 Pa.s at a temperature in a range of from 95° C. to 98° C.; an emulsion process for obtaining an emulsion by emulsifying the reaction solution; and a curing process for curing the amino resin precursor in the emulsion state by adding a catalyst to the emulsion. With this producing process, it is possible to readily produce amino resin particles with an essentially uniform particle size (narrow particle size distribution).
    Type: Application
    Filed: December 28, 2001
    Publication date: September 26, 2002
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Yasuhiro Yamamoto, Shuji Shimizu, Masafumi Inoue, Hideki Oishi
  • Patent number: 6426393
    Abstract: To provide polyacetal which has excellent shock resistance, rigidity and creep resistance as essential properties of the polymer and makes a high flowability and an excellent molding property upon molding possible by improving the thermal stability. In the manufacture of a polyacetal copolymer by a copolymerization of 100 parts by weight of trioxane (a) with 0.05-20 parts by weight of a cyclic ether compound (b) which is copolymerizable with trioxane and 0.001-10 parts by weight of a mono-functional glycidyl compound (c), the mono-functional glycidyl compound (c) having a chlorine content of not more than 0.3% by weight is used.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: July 30, 2002
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshihisa Tajima, Hidetoshi Okawa
  • Patent number: 6362263
    Abstract: Impact modified, compatibilized poly(phenylene ether)-polyamide compositions containing either a polybutene or an organosiloxane mixture give molded parts with good surface appearance, improved flow at high shear rate, and improved low temperature impact strength in comparison to control blends without added organosiloxane mixture or polybutene.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: March 26, 2002
    Assignee: General Electric Company
    Inventors: Sterling Bruce Brown, Norberto Silvi, Mark Howard Giammattei, Navjot Singh, Farid Fouad Khouri
  • Patent number: 6260949
    Abstract: Disclosed is a composition comprising a blend of (a) a thermally reactive polymer selected from the group consisting of resoles, novolacs, thermally reactive polyarylene ethers, and mixtures thereof; and (b) a photoreactive epoxy resin that is photoreactive in the absence of a photocationic initiator.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: July 17, 2001
    Assignee: Xerox Corporation
    Inventors: Thomas W. Smith, David J. Luca, Kathleen M. McGrane
  • Patent number: 6139920
    Abstract: Disclosed is a composition comprising a blend of (a) a thermally reactive polymer selected from the group consisting of resoles, novolacs, thermally reactive polyarylene ethers, and mixtures thereof; and (b) a photoreactive epoxy resin that is photoreactive in the absence of a photocationic initiator.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: October 31, 2000
    Assignee: Xerox Corporation
    Inventors: Thomas W. Smith, David J. Luca, Kathleen M. McGrane
  • Patent number: 5977254
    Abstract: A molding material contains, based on the sum of the components A and B, and, if required, C, D and/or E,A: 1-99% by weight of a particulate microemulsion polymer having a glass transition temperature below 0.degree. C. and a median particle size of less than 50 nm,B: 1-99% by weight of a semicrystalline polymer B, in particular selected from at least one polymer from semicrystalline polyamides, partly aromatic copolyamides, polyolefins, ionomers, polyesters, polyetherketones, polyoxyalkylenes and polyarylene sulfides,C: 0-50% by weight of a polymer selected from a particulate graft copolymer having a median particle size of from 60 to 10,000 nm, a thermoplastic polyurethane, a thermoplastic elastomer and an acrylate, diene, EP, EPDM or silicone rubber,D: 0-50% by weight of polycarbonates andE: 0-50% by weight of fibrous or particulate fillers or of a mixture thereof.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Norbert Niessner, Herbert Fisch
  • Patent number: 5973081
    Abstract: A modified polyacetal is obtainable by heating 0.1 to 30 parts by weight of (B) a polymerizable compound having a modifying group such as an epoxy group, a carboxyl group or an acid anhydride group relative to 100 parts by weight of (A) a base polyacetal and introducing the modifying group of the polymerizable compound to the base polyacetal. The base polyacetal (A) includes (A1) a polyacetal selected from polyoxymethylene homopolymers and copolymers, and (A2) a polymerizable polyacetal having a functional group comprising a polymerizablly unsaturated bond. The introduction efficiency of the modifying group can be enhanced by adding 0.01 to 2.5 parts by weight of (C) a free-radical initiator relative to 100 parts by weight of the total amount of the components (A) and (B), and mixing the resultant mixture under a molten state of the polyacetal. According to such method, the affinity of the polyacetal is improved by introducing the modifying group to the base polyacetal with ease and high efficiency.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: October 26, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hiroyuki Kanai, Hajime Serizawa, Katsuhei Ohnishi, Eiji Masuda, Kaoru Yamamoto
  • Patent number: 5969054
    Abstract: The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: October 19, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Michael Sonntag, Dieter Margotte
  • Patent number: 5958398
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: September 28, 1999
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5891960
    Abstract: Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: April 6, 1999
    Assignee: PPG Industries, Inc.
    Inventors: James A. Claar, Karl F. Schimmel, Shanti Swarup, Bruce A. Connelly
  • Patent number: 5863963
    Abstract: Disclosed is a process which comprises the steps of (a) providing a polymer containing at least some monomer repeat units with halomethyl group substituents which enable crosslinking or chain extension of the polymer upon exposure to a radiation source which is electron beam radiation, x-ray radiation, or deep ultraviolet radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several groups as specified in the claims, B is one of several groups as specified in the claims, and n is an integer representing the number of repeating monomer units, and (b) causing the polymer to become crosslinked or chain extended through the photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead by the aforementioned curing process.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: January 26, 1999
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 5811510
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: September 22, 1998
    Assignee: General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5804664
    Abstract: The synthesis and characterization of novel linear polymers and multi-arm star polymers comprising polyisobutylene arms connected to a well-defined calixarene core are described. The synthesis has been achieved using the "core first" method wherein multifunctional calix?n!arene (where n=4 to 16) derivatives or their monofunctional analogues are used as initiators which, in conjunction with certain Freidel-Crafts acids as co-initiators, induce the living polymerization of isobutylene or a similar carbocationic polymerizable monomer to form star polymers or block copolymers. Novel initiators suitable for inducing the polymerization are also described.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: September 8, 1998
    Inventors: Joseph P. Kennedy, Istvan J. Majoros, Sunny Jacob
  • Patent number: 5767205
    Abstract: A polyacetal resin is blended with a copolymer of styrene with 1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl)benzene to prepare a resin composition which does not cause phase separation, has an excellent extrusion stability, and provides excellent surface appearance and physical properties for a molding thereof.
    Type: Grant
    Filed: September 28, 1995
    Date of Patent: June 16, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Mitsuteru Mutsuda, Kenji Nakama
  • Patent number: 5760138
    Abstract: Polyacetal resin compositions characterized in that they are polyacetal resin compositions essentially consisting of a polyacetal resin, an olefin polymer containing a glycidyl group on the side chain and a styrene polymer having an oxazolyl group, the total content of the said olefin polymer having a glycidyl group on the side chain and the said styrene polymer having an oxazolyl group is 0.1-15 weight % with respect to the said polyacetal resin composition, and the content of the said styrene polymer having an oxazolyl group is 50-200 weight parts with respect to 100 weight parts of the said olefin polymer containing a glycidyl group on the side chain.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: June 2, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Kenichi Shinohara
  • Patent number: 5756594
    Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
  • Patent number: 5679743
    Abstract: The disclosure describes a polyacetal resin composition comprising 100 parts by weight of a polyacetal resin (A), 0.3 to 10 parts by weight of an olefin copolymer (B) composed of 30 to 70 wt % of ethylene-propylene-diene rubber (B.sub.1), 30 to 70 wt % of an ethylene-vinyl acetate copolymer (B.sub.2) with a vinyl acetate content of 18 to 40 wt % and 1 to 25 wt % of an ethylene-(C.sub.4-6)olefin-1 copolymer (B.sub.3), and 0.1 to 10 parts by weight of a styrene-based thermoplastic elastomer (C) having a functional group.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: October 21, 1997
    Assignee: Oiles Corporation
    Inventors: Kazuo Hirai, Kingo Miyasaka, Masayuki Rokugawa, Katsumi Minou
  • Patent number: 5656365
    Abstract: Polyvinylbutyral useful for the production of laminated glasses containing a crosslinking agent capable of making the polyvinylbutyral very slightly meltable or nonmeltable. The material according to the invention may contain a plasticizer and is particularly resistant to fire and allows one to produce a laminated material with a good resistance to impact and to fire.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: August 12, 1997
    Assignee: Saint Gobain Vitrage
    Inventor: Daniel Dages
  • Patent number: 5646214
    Abstract: An adherent film-forming composition comprising a carbamate-functional polyester polymer or oligomer, a hydroxy functional polymer derived from ethylenically unsaturated monomers and an aminoplast crosslinking agent is disclosed. The coating composition can be used to produce clear coats in composite color plus clear coatings exhibiting good levels of acid etch resistance as well as high intercoat adhesion. Also disclosed are a method of applying a composite color plus clear coating to a substrate and the coated article prepared by such a method.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: July 8, 1997
    Assignee: PPG Industries, Inc.
    Inventor: Michael A. Mayo
  • Patent number: 5618887
    Abstract: A process for the functionalisation of polymers is disclosed. Functionalisation takes place by reacting a polymer with a peroxidant, preferably, the peroxydisulphate or monosulphate or sodium or potassium in an aqueous medium. The hydroxylated polymer can then be reacted with other materials, including biomolecules. Using the method of the inventon, products eg. Catheters or oxygenators can be produced with improved properties hitherto unobtainable.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: April 8, 1997
    Assignee: The University of Liverpool
    Inventors: Clement H. Bamford, Kadem G. Al-Lamee
  • Patent number: 5580931
    Abstract: A method for property modification of bulk polymers, by initially treating a short chain monomeric organic acid, having a carboxylic group (with dissociation constant between 10.sup.-2 to 10.sup.-6 cm.sup.-1, and less than 8 carbons); with a Group IA, IIA or IIB metal, metal oxide, peroxide, hydroxide, or halogens, for forming a metal ligand or complex metal salt of the acid. The bulk polymers are mixed with the complex metal salts and free radicals are introduced into the mixture by means of oxidizing materials, to functionalize the bulk polymer with ionic polymerization sites. A copolymer formation is effected between the monomeric organic metal salt anion and the bulk polymer, as catalyzed by the metal cation, at such sites. The polymerization is a substantially non-cross linked ionic one resulting from the dissociation parameters and the short chain length of the complex metal salt, which is maintained prior to copolymer formation.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: December 3, 1996
    Assignee: Nathaniel H. Garfield
    Inventor: Juan E. Aguirre
  • Patent number: 5559180
    Abstract: A polyacetal composition is provided for use in plastic-plastic wear applications, said composition containing about 85 to 99 weight percent polyacetal, about 0 to 5 weight percent polytetrafluoroethylene fibers, about 0.5 to 5 weight percent ethylene methyl acrylate copolymer, and about 0.5 to 5 weight percent of at least one lubricant. The compositions are particularly useful in forming shaped articles for use especially in conveyor chain applications and gear applications.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: September 24, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tatsuhiro Takahashi, Edmund A. Flexman, Robert J. Kassal
  • Patent number: 5408002
    Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: April 18, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
  • Patent number: 5346737
    Abstract: Incorporation of at least one lubricant and an ethylene-based polymer of the formula E/X/Y wherein E is ethylene, X is methyl acrylate, butyl acrylate, or ethyl acrylate, and Y is glycidyl methacrylate, glycidyl acrylate, or glycidyl vinyl ether into polyacetal compositions results in compositions having good wear resistance and good melt processing thermal stability. The compositions are useful, for example, when molded into parts to be used in sliding applications, such as gears, cams, and conveyor chains.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: September 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tatsu-Hiro Takahashi, Toshikazu Kobayashi
  • Patent number: 5344875
    Abstract: The present invention provides a polyoxymethylene resin composition which is excellent in wear resistance and is suitable as materials for various sliding parts. The composition comprises (A) 65-98.8% by weight of a polyoxymethylene resin, (B) 0.2-5.0% by weight of a polyfunctional isocyanate compound, (C) 0.5-20% by weight of an olefin polymer containing 30% by weight or more of ethylene and a functional group containing an active hydrogen, and (D) 0.2-10% by weight of polyethylene.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: September 6, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Masahiko Niino
  • Patent number: 5310828
    Abstract: Novel polymeric compositions are provided for polyamide fibers or fibers having terminal amino groups that impart stain resistance and are resistant to discoloration.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: May 10, 1994
    Assignee: Peach State Labs, Inc.
    Inventors: Michael S. Williams, Thomas H. Moss, III
  • Patent number: 5294670
    Abstract: The present invention relates to a polyacetal copolymer comprising a polyoxymethylene group (A) and a vinyl polymer group (B), the copolymer having a structure of the formula (I):A.sub.n --X--B (I)wherein X is a terminal group of B and represents a binding group derived from a compound having at least two carbon atoms and 1 to 4 groups selected from hydroxyl, carboxyl, ester, amino and alkoxy groups, and A.sub.n means that A is present in the quantity of n times in number, and bonds to X, in which n=1 to 4, and the copolymers has a number average molecular weight of 10,000 to 500,000; a process for the production of said copolymer; and a composition comprising said copolymer and a polyvinyl polymer and/or polyoxymethylene.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: March 15, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tadashige Hata, Kazuhiko Matsuzaki
  • Patent number: 5286808
    Abstract: Crosslinked elastomeric acetal polymers are made by the copolymerization of 1,3-dioxolane with a smaller amount of one or more bifunctional monomers. The two functional groups of the bifunctional monomer react under the same cationic polymerization conditions as the 1,3-dioxolane. The elastomeric acetal polymer does not crystallize even when the temperature is as low as -50.degree. C. The elastomeric acetal polymer is particularly useful for blending with crystalline acetal polymers to yield a composition with improved impact resistance.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: February 15, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: George L. Collins, William M. Pleban, Paul Zema
  • Patent number: 5266633
    Abstract: The invention relates to a mixture composed essentially of polyoxymethylene (component A), a rubber-elastic graft copolymer in which the particles have been formed from a rubber-elastic, single-phase core based on polydiene and a hard graft shell (component B) and, if appropriate, a polymeric third component (component C). The invention also relates to a three-component mixture of the components A, B' and C, the core, in the case of B', being preponderantly or entirely composed of poly(meth)acrylic acid ester or silicone rubber instead of polydiene.The shaped articles produced from these mixtures are particularly distinguished by good low-temperature impact strength.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: November 30, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karlheinz Burg, Harald Cherdron, Friedrich Kloos, Helmut Schlaf
  • Patent number: 5260378
    Abstract: The invention relates to a block copolymer according to the general formula A-b-B on the basis of a furan derivative as binding group (b) and the process for the preparation hereof. The furan derivative as binding group (b) is a compound according to formula (I). ##STR1## The block copolymer can simply be prepared in one single reactor and is suitable for use as compatibilizer.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: November 9, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Alessandro Gandini, Marie C. Salon