Abstract: The present invention relates to a microfluidic flow process for making monomers, monomers made by such processes, and methods of using such monomers. In such process, microfluidic reaction technology is used to synthesize cyanation reaction products orders of magnitude faster than is possible in batch and continuous syntheses. The aforementioned process does require strictly regulated, highly toxic cyanogen chloride. Thus the aforementioned process is more economically efficient and reduces the environmental impact of thermosetting resin monomer production, and produces thermosetting resin monomers in greater purity than obtained through typical processes.

Abstract: The present invention provides an epoxy resin including a reaction product of 1,2,4-trihydroxybenzene and an epihalohydrin, the epoxy resin containing a cyclic compound that has a cyclic structure containing, as constitutional atoms, oxygen atoms at 1-position and 2-position derived from 1,2,4-trihydroxybenzene, the cyclic compound being contained in an amount of 0.003 to 0.070 mol based on 100 g of the epoxy resin. The epoxy resin is liquid and is excellent in pyrolysis resistance.

Abstract: A coating composition is described that has good film forming and blocking properties in a composition that also has low or no VOCs. The coating compositions herein include functionalized urethane (meth)acrylate polymers that allow better film formation and particle coalescence while maintaining the low or no VOC levels. In one aspect, the coating compositions include functionalized polymers with a higher glass transition temperature (Tg) to aid in achieving good block resistance but a low minimum film forming temperature (MFFT) to achieve good particle coalescence and film formation all while being substantially free of co-solvents, coalescent aid and/or plasticizers.

Abstract: A toughened epoxy resin composition includes an end-capped polyalkylene oxide (A), an epoxy resin (B), an epoxy curing agent (C), and a core shell polymer (D). The end-capped polyalkylene oxide (A) has a number average molecular weight of 1500 to 5000, and 40% or more of a total number of ends of the end-capped polyalkylene oxide (A) are capped with at least one selected from the group consisting of an alkyl group, an allyl group, and an aryl group. A weight ratio of the end-capped polyalkylene oxide (A) to the core shell polymer (D) is 10/90 to 90/10. The core shell polymer (D) comprises a core layer in an amount of 70 to 95% by weight and the core layer is one or more selected from the group consisting of diene rubber, (meth)acrylate rubber, organosiloxane rubber, styrene polymer, and (meth)acrylate polymer.

Abstract: The present invention relates to vinyl polymers having certain characteristics which confer flame-retardant properties to the polymer and their polymeric compositions with other vinyl polymers.

Abstract: Disclosed is a block copolymer having a first polymer block including a first primary monomer that is a 1,1-disubstituted alkene compound, wherein the first primary monomer is present at a concentration of about 50 weight percent or more, based on the total weight of the first polymer block, the first polymer block covalently bonded to a second polymer block including a second primary monomer different from the first primary monomer, wherein the second primary monomer is present at a concentration of about 50 weight percent or more, based on the total weight of the second polymer block. Also disclosed is a polymer comprising at least one monomer of a 1,1-disubstituted alkene compound having a weight average molecular weight of about 3000 daltons or more, wherein the polymer is substantially free of a melting temperature and is substantially free of a glass transition temperature of about 15° C. or more.

Abstract: An object of the present invention is to provide curing agent composite particles for epoxy resin, which are less likely to aggregate, and are excellent in storage stability and solvent resistance. Coated particles of the present invention comprise (A) curing agent particles for epoxy resin, and (B) an alkoxy oligomer, wherein the surfaces of the curing agents for epoxy resin particle are coated with the alkoxy oligomer.

Abstract: Disclosed herein is a process for forming a multilayer construction, and the multilayer constructions including at least one layer of an elastic meltblown fabric, the process comprising extruding one or more polyolefin polymer (e.g., a propylene-?-olefin copolymer) having a MFR from less than 90 dg/min through at least one die having a plurality of nozzles to form a plurality of continuous fibers, at least one die operating at a melt pressure from greater than 500 psi (3.45 MPa) to form at least one elastic meltblown fabric, and adhering the at least one elastic meltblown fabric to at least one extensible fabric.

Abstract: A material comprising crosslinked polyrotaxanes which exhibits desired viscoelasticity, particularly stress-strain characteristics with a wide low-stress region, in spite of being free from solvent; and a process for production of the same. The material comprises a first polyrotaxane bearing first cyclic molecules and a second polyrotaxane bearing second cyclic molecules, and the first and second polyrotaxanes are crosslinked via the first and second cyclic molecules. The material is free from solvent and exhibits a stress of 2.0 MPa or below at 50% strain.

Abstract: A method of producing cross-linked rubber including a step of reacting a polyether rubber composition at 130 to 200° C., the polyether rubber composition containing 100 parts by weight of epihalohydrin monomer units, 0.1 to 100 parts by weight of a five-membered ring or six-membered ring nitrogen atom-containing aromatic heterocyclic type compound, and 0.1 to 10 parts by weight of at least one cross-linking agent which is selected from sulfur, a sulfur-containing compound, and triazine-based compound.

Abstract: Provided is a polymer-based detergent builder which is capable of effectively suppressing deposition of a surfactant, and effectively preventing soil re-deposition, even in washing using high hardness water.

Abstract: A composition including at least one curable structural adhesive, and at least one chemically cross-linked elastomer, wherein the chemically cross-linked elastomer is present in the structural adhesive as penetrating polymer network. Such a composition constitutes a so-called shape memory material and is suitable for reinforcing cavities in structural components, such as, for example, in automobile bodies.

Abstract: The invention relates to polymers that can be obtained by polymerizing the monomers (A), (B), and (D), and optionally (C), where (A) is a monomer of formula (I), wherein A stands for C2 to C4 alkylene, B stands for a C2 to C4 alkylene different from A, R stands for hydrogen or methyl, m stands for a number from 1 to 500, n stands for a number from 1 to 500, (B) is an ethylenically unsaturated monomer that contains at least one carboxylic acid function, (C) is optionally a further ethylenically unsaturated monomer different from (A) and (B), (D) is a monomer of formula (II), wherein D stands for C2 to C4 alkylene, E stands for a C2 to C4 alkylene group different from D, F stands for a C2 to C4 alkylene group different from E, R stands for hydrogen or methyl, o stands for a number from 1 to 500, p stands for a number from 1 to 500, q stands for a number from 1 to 500, and wherein the weight fraction of the monomers is 35 to 99% for the macromonomer (A), 0.

Abstract: The invention relates to the use of polymers, containing between 1 and 100 mol % of structural units of the formula (1), wherein R1 means hydrogen or C1-C6 alkyl, A means C2-C4 alkylene groups, and B means C2-C4 alkylene groups, with the stipulation that A is different from B, and x and y mean an integer from 1 to 100 independent of each other, in amounts of 0.01 to 2 wt % relative to the water phase, as gas hydrate inhibitors.

Abstract: The invention provides for the use of copolymers comprising 1 to 99 mol % of structural units of the formula (1) in which R1 is hydrogen or C1-C6-alkyl, A is C2-C4-alkylene groups and B is C2-C4-alkylene groups, with the proviso that A is different than B, and x, y are each independently an integer of 1-100, and 1 to 99 mol % of structural units of the formula (3) in which R6 is hydrogen or C1-C6-alkyl, D is C2-C4-alkylene groups and z is an integer of 1-50, in amounts of 0.01 to 2% by weight, based on the water phase, as gas hydrate inhibitors.

Abstract: There are provided a radical polymerizable composition having a low viscosity suitable for coating and a cured product and a plastic lens each obtained by curing the composition, the cured product having a high refractive index, good adhesiveness to a plastic film substrate, and good adhesiveness kept even under high-temperature and high-humidity conditions. The radical polymerizable composition includes phenylbenzyl (meth)acrylate (A), an epoxy (meth)acrylate (X) having an aromatic ring in its molecular structure, and a radical polymerization initiator (Y) as essential components.

Abstract: An interpenetrating polymer network (IPN) adhesive comprises an acrylated polymer system curable by radiation, and a flexible epoxy system thermally curable after the acrylated polymer system is cured.

Abstract: The present invention is directed to conjugates of hydrolytically stabilized maleimide-functionalized water soluble polymers and to methods for making and utilizing such polymers and their precursors.

Abstract: There is provided an oil-in-water emulsion composition whose continuous phase is an aqueous phase, but which has a high moisture evaporation suppressing effect and is also superior in feeling, and a method for producing the same. An oil-in-water emulsion composition containing an oily component having an inorganic value of 2500 or less, an organic value of 5000 or less and an IOB value of 0.3 to 0.5, the oil-in-water emulsion composition containing the following components (A) to (C) in an aqueous phase. (A) a polyoxyethylene alkyl or alkenyl ether having alkyl group or alkenyl group having 20 to 24 carbon atoms and an average molar number of ethylene oxide added of 1.5 to 4 (B) a polyhydric alcohol (C) a water-soluble polymer.

Abstract: A material comprising crosslinked polyrotaxanes which exhibits desired viscoelasticity, particularly stress-strain characteristics with a wide low-stress region, in spite of being free from solvent; and a process for production of the same. The material comprises a first polyrotaxane bearing first cyclic molecules and a second polyrotaxane bearing second cyclic molecules, and the first and second polyrotaxanes are crosslinked via the first and second cyclic molecules. The material is free from solvent and exhibits a stress of 2.0 MPa or below at 50% strain.

Abstract: A composition for a semiconductive rubber, comprising an epichlorohydrin-based rubber (a), an ethylene oxide-modified (meth)acrylate (b), and at least one kind of a crosslinking agent (c) selected from the group consisting of a sulfur-based crosslinking agent, a quinoxaline-based crosslinking agent and a triazine-based crosslinking agent.

Abstract: Room temperature curing epoxy adhesives that show good adhesion to plastic substrates are described. The adhesives contain an epoxy resin component comprising a first epoxy resin and a second epoxy resin; a first amine curing agent having an equivalent weight of at least 50 grams per mole of amine equivalents; a second amine curing agent having an equivalent weight of no greater than 45 grams per mole of amine equivalents; an acetoacetoxy-functionalized compound; a metal salt catalyst; and a multifunctional acrylate.

Abstract: Piezoelectric compositions are provided wherein mechanical and piezoelectric properties can be separately modulated. Preferred compositions include resin blends that comprise: (a) a piezoelectrically active polymer and (b) a matrix polymer, methods of making, and use of such resin blends. Advantages of preferred resin blends of the invention can include high piezoelectricity, mechanical strength and flexibility, convenient fabrication process, and high sensitivity at high temperatures.

Abstract: A polymer comprises units derived from ethylene and poly(alkoxide) the polymer having at least 0.15 units of amyl groups per 1000 carbon atoms as determined by 13C Nuclear Magnetic Resonance (NMR).

Abstract: A resin component for a one- or two-component adhesive, a matrix resin, or a structural foam, comprising: C1) at least one epoxy resin, having an average of more than one epoxy group per molecule, that does not correspond to the definition of component C2); C2) at least one oligomeric or polymeric urethane-group-free polyether compound. A one- or two-component epoxy adhesive, structural foam, or matrix material for composites, comprising the aforesaid resin components.

Abstract: The invention relates to a copolymer comprising i) 3 to 40 mol % of an isoprenolpolyether derivative structural unit ? ii) 3 to 40 mol % of a vinyloxypolyether derivative structural unit ? and iii) 35 to 93 mol % of an acid structural unit ?, the structural units of the copolymer which belong to the vinyloxypolyether derivative structural unit ? having longer side chains than the structural units which belong to the isoprenolpolyether derivative structural unit ?.

Abstract: A high-efficiency light diffusing polymeric film comprises a first polymer which is a light transmissible medium, and a second polymer which forms light scattering particles, wherein the polymers are immiscible and have a refractive index difference of about 0.001 to about 0.5, and the polymeric film comprises about 30 about to 70 parts by weight of the second polymer with respect to 100 parts by weight of the first polymer. A method for manufacturing a high-efficiency polymeric film is carried out such that a first polymer forms a continuous phase and a second polymer forms a dispersed phase through coating or extrusion.

Abstract: Amphiphilic graft polymers based on water-soluble polyalkylene oxides (A) as a graft base and side chains formed by polymerization of a vinyl ester component (B), said polymers having an average of ?1 graft site per 50 alkylene oxide units and mean molar masses Mw of from 3000 to 100 000.

Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.

Abstract: A polyether rubber comprising units expressed by the following general formula (1) in 0.1 mol % or more but less than 30 mol % is provided. (wherein in the above general formula (1), A+ is a group which contains a cationic nitrogen-containing aromatic heterocyclic ring. Said group which contains a cationic nitrogen-containing aromatic heterocyclic ring is bonded with the carbon atom at the “2” position which is shown in the above general formula (1) through a nitrogen atom which forms said cationic nitrogen-containing aromatic heterocyclic ring. X? is arbitrary counter anion.

Abstract: Methods for fabricating a random graft PS-r-PEO copolymer and its use as a neutral wetting layer in the fabrication of sublithographic, nanoscale arrays of elements including openings and linear microchannels utilizing self-assembling block copolymers, and films and devices formed from these methods are provided. In some embodiments, the films can be used as a template or mask to etch openings in an underlying material layer.

Abstract: A polyol composition comprising a polyol (a) and resin fine particles (b) dispersed in the polyol (a), and a method for producing the polyol composition are provided, wherein the resin fine particles (b) are particles such that an arithmetic standard deviation by volume of a particle size distribution of the particles, derived from respective values in 85 divisions of a range of 0.020 to 2000 ?m determined by a laser diffraction/scattering particle size distribution analyzer, is not more than 0.6. A resin fine particle-dispersed polyol composition that, even if the resin particles dispersed in the polyol have a small particle diameter, allows the production of a polyurethane resin having an excellent mechanical strength such as elongation at break, and a method for producing the same, are provided.

Abstract: Methods for fabricating a random graft PS-r-PEO copolymer and its use as a neutral wetting layer in the fabrication of sublithographic, nanoscale arrays of elements including openings and linear microchannels utilizing self-assembling block copolymers, and films and devices formed from these methods are provided. In some embodiments, the films can be used as a template or mask to etch openings in an underlying material layer.

Abstract: A polyol composition comprising a polyol (a) and resin fine particles (b) dispersed in the polyol (a), and a method for producing the polyol composition are provided, wherein the resin fine particles (b) are particles such that an arithmetic standard deviation by volume of a particle size distribution of the particles, derived from respective values in 85 divisions of a range of 0.020 to 2000 ?m determined by a laser diffraction/scattering particle size distribution analyzer, is not more than 0.6. A resin fine particle-dispersed polyol composition that, even if the resin particles dispersed in the polyol have a small particle diameter, allows the production of a polyurethane resin having an excellent mechanical strength such as elongation at break, and a method for producing the same, are provided.

Abstract: A method for preparing high-purity polyethyleneglycol-alkylenealdehydes and derivatives thereof is provided.

Abstract: The present invention is aimed to provide a thermosetting resin composition which is easily produced, has excellent storage stability and thermal stability while maintaining high transparency and preventing formation of voids on the occasion of semiconductor chip bonding, and gives a cured product having excellent heat resistance, a flip-chip mounting adhesive containing the thermosetting resin composition, a method for producing a semiconductor device using the flip-chip mounting adhesive, and a semiconductor device produced by the method for producing a semiconductor device. The present invention is a thermosetting resin composition including an epoxy resin, an acid anhydride having a bicycle skeleton, and an imidazole curing accelerator that is in a liquid form at an ordinary temperature.

Abstract: The invention relates to a method for the fluid-phase synthesis of a polymer formed from n monomers.

Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.

Abstract: A curing agent for epoxy resin has one or more five- or six-membered aromatic rings, and substituted on the one or more five- or six-membered rings at least two functionalities reactive with the epoxy selected from the group consisting of hydroxyl, amine, imidazole, azine, hydrazide, anhydride, and Lewis acid groups. Choice of functionality can provide a mixed polymer network, one with a more densely cross-linked polymer structure having a high Tg, and the other with a more linear polymer structure to contribute to stress reduction.

Abstract: A polyester block terpolymer comprising an amorphous block comprising a polystyrene dicarboxylate; a crystallizable block comprising a polyethylene glycol; and an aliphatic diol block; wherein the amorphous block is a continuous phase and the crystallizable block is a dispersed phase, and wherein the dispersed phase is less than about 200 nanometers in size.

Abstract: A composition for a semiconductive rubber, comprising an epichlorohydrin-based rubber (a), an ethylene oxide-modified (meth)acrylate (b), and at least one kind of a crosslinking agent (c) selected from the group consisting of a sulfur-based crosslinking agent, a quinoxaline-based crosslinking agent and a triazine-based crosslinking agent.

Abstract: A composition includes an elastomeric composition. The elastomeric composition can include an epichlorohydrin composition, and the elastomeric composition can be substantially free of a fluoroelastomer composition. The composition can further include a filler material which includes a reinforcement-grade carbon black. The composition can further include a peroxide curative.

Abstract: A resin component for a one- or two-component adhesive, a matrix resin, or a structural foam, comprising: C1) at least one epoxy resin, having an average of more than one epoxy group per molecule, that does not correspond to the definition of component C2); C2) at least one oligomeric or polymeric urethane-group-free polyether compound. A one- or two-component epoxy adhesive, structural foam, or matrix material for composites, comprising the aforesaid resin components.

Abstract: Disclosed are toughened, antistatic resin composition and an article comprising the composition wherein the composition comprises or consists essentially of poly(hydroxyalkanoic acid), such as polylactic acid; an impact modifier comprising an ethylene copolymer; and an ion conducting polymer.

Abstract: An interpenetrating polymer network (IPN) adhesive comprises an acrylated polymer system curable by radiation, and a flexible epoxy system thermally curable after the acrylated polymer system is cured.

Abstract: Non water-soluble polymers with a comb structure and a (meth)acrylic skeleton on which are grafted side chains containing at least one hydrophobic monomer of the styrene or (meth)acrylic ester type on C1 to C4, and at least one hydroxy or methoxy polylakylene glycol monomer. The levels of monomers are such that the polymer is amphiphilic because it is both rich in hydrophobic monomer and polylakylene glycol monomer. These products, used in paper coating dispersions, enable an increase in their Brookfield™ viscosity, a reduction in their ACAV viscosity, and an improvement in their water retention, which makes them particularly well suited for dry extract and/or high deposit speed coatings.

Abstract: The invention relates to graft polyols with a bimodal particle size distribution and a total solid content of between 5 and 65 wt. %. Said polyols contain small particles with a particle diameter of between 0.05 and 0.7 ?m and large particles with a particle diameter of between 0.4 and 5.0 ?m, whereby the peaks of the large and small particles measured during a representation according to the light-scattering analysis method do not overlap. The total solid content with the defined particle sizes consists of a volumetric fraction of between 5 and 45% small particles and a volumetric fraction of between 95 and 55% large particles, said volumetric fractions totalling 100%. The invention also relates to a method for producing graft polyols of this type and to the use thereof for producing polyurethanes.

Abstract: Methods for preparing polymeric reagents bearing a maleimide are provided. Also provided are related compositions.

Abstract: Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one ?,?-unsaturated monocarboxylic acid and/or at least one ?,?-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.

Abstract: Methods for fabricating a random graft PS-r-PEO copolymer and its use as a neutral wetting layer in the fabrication of sublithographic, nanoscale arrays of elements including openings and linear microchannels utilizing self-assembling block copolymers, and films and devices formed from these methods are provided. In some embodiments, the films can be used as a template or mask to etch openings in an underlying material layer.