Mixed With O-c(=o)-o-, Hal-c(=o)-o-, Or Hal-c(=o)-hal Containing Reactant Or Polymer Derived Therefrom; Or Wherein Solid Polymer Is Derived From A Hal-c(=o)-hal, O-c(=o)-o-, Or Hal-c(=o)-o-, A Polycarboxylic Acid Or Derivative And A Polyhydroxy Reactant Patents (Class 525/439)
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Publication number: 20130310490Abstract: A heat-shrinkable film comprising an aliphatic polycarbonate, wherein the film is uniaxially or biaxially oriented, and exhibits a heat-shrinkage of at least 30% in at least one direction when treated with hot air at 70° C. for 10 min, has an improved transparency and good heat-shrinkability which can be used for various purposes such as a label or wrapping material.Type: ApplicationFiled: November 21, 2011Publication date: November 21, 2013Applicant: SKC CO., LTDInventors: Deuk-Young Lee, Sang Il Kim
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Patent number: 8586183Abstract: A laser composition comprises a combination of: (a) from more than 45 to less than 94 weight percent of a crystalline or semi-crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers poly(ethylene terephthalate) copolymers, and combinations thereof; (b) from greater than 6 to less than 25 weight percent of an amorphous thermoplastic poly(ester) copolymer, poly(ester-carbonate), or combination thereof; (c) optionally, from 1 to 30 weight percent of a filler; and (d) optionally, from 0.01 to 5 weight percent of an antioxidant, mold release agent, colorant, stabilizer, or a combination thereof; wherein an article having a 2 mm thickness and molded from the composition has (i) a near infrared transmission at 960 nanometers of greater than 30 percent and (ii) a Vicat softening temperature of at least 170° C.Type: GrantFiled: January 13, 2011Date of Patent: November 19, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Tony Farrell, Johannes Hubertus G. M. Lohmeijer
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Publication number: 20130303692Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 80 to 100 mole % terephthalic acid residues; optionally, 0 to 20 mole % aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 20 to 30 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 70 to 80 mole % 1,4-cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: ApplicationFiled: July 12, 2013Publication date: November 14, 2013Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Publication number: 20130303698Abstract: A polyetherimide having an OH content that is greater than 0 and equal or less than 100 ppm; and a chlorine content that is greater than 0 ppm is disclosed herein. A method for preparing the polyetherimide is also disclosed.Type: ApplicationFiled: July 19, 2013Publication date: November 14, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Hendrich Chiong, Thomas Link Guggenheim, Farid Fouad Khouri, Matthew L. Kuhlman, Miguel Angel Navarro de Castro, Roy Ray Odle, Brennan Alexander Smith
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Publication number: 20130289220Abstract: The present invention comprises a stent comprising a blend formed from a polymer. The polymer comprises poly-L-lactide, poly-D-lactide or mixtures thereof and a copolymer moiety comprising poly-L-lactide or poly-D-lactide linked with ?-caprolactone or trimethylcarbonate. The poly-L-lactide or poly-D-lactide sequence in the copolymer moiety is random with respect to the distribution of ?-caprolactone or trimethylcarbonate and the copolymer moiety molecular weight ranges from about 1.2 IV to about 4.8 IV. The meandering elements may be stretched to a modulus ranging from about 250000 PSI to about 550,000 PSI. One, two, three, n or all segments of the meandering element may have a decreased cross-sectional area and may have a wide-angle X-ray scattering (WAXS) 2? values of ranging from about 1 to about 35 after stretching.Type: ApplicationFiled: October 25, 2012Publication date: October 31, 2013Applicant: OrbusNeich Medical, Inc.Inventor: OrbusNeich Medical, Inc.
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Publication number: 20130245206Abstract: The bioabsorbable polymers and compositions of the present invention may be formed into medical devices such as stents that can be crimped onto a catheter system for delivery into a blood vessel. The properties of the bioabsorbable polymers allow for both crimping and expansion of the stent. The crystal properties of the bioabsorbable polymers may change during crimping and/or expansion allowing for improved mechanical properties such as tensile strength and slower degradation kinetics. Typically, bioabsorbable polymers comprise aliphatic polyesters based on lactide backbone such as poly L-lactide, poly D-lactide, poly D,L-lactide, mesolactide, glycolides, lactones, as homopolymers or copolymers, as well as formed in copolymer moieties with co-monomers such as, trimethylene carbonate (TMC) or ?-caprolactone (ECL).Type: ApplicationFiled: April 11, 2013Publication date: September 19, 2013Applicant: OrbusNeich Medical, Inc.Inventors: G. Lawrence Thatcher, Robert J. Cottone
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Patent number: 8536282Abstract: A polycarbonate polymer or copolymer comprising pendant silylated dihydroxy aromatic compound of the formula (1a); wherein Ga and Gb are each independently C1-12 alkyl, —OSi(C1-12 alkyl)3, C1-12 arylalkyl, or —OSi(C1-12 arylalkyl)3; Za and Zb are each independently a straight or branched C2-18 is alkylene, a C8-18 arylalkylene, or a C8-18 alkylarylene, Xa is a direct bond, a heteroatom-containing group, or a C1-18 organic group, and r and s are each independently 1 or 2 is disclosed.Type: GrantFiled: September 8, 2009Date of Patent: September 17, 2013Assignee: Momentive Performance Materials Inc.Inventors: Jan Pleun Lens, Tilak Thulasi Raj, Binod Behari Sahoo, Arakali Srinivasarao Radhakrishna
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Publication number: 20130217830Abstract: The present invention relates to a clear, semicrystalline article comprising a polyester comprising terephthalic acid residues as the dicarboxylic acid component, and 1 to 15 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 85 to 99 mole % of 1,4-cyclohexanedimethanol residues as the glycol component. The article may be in the form of a film or sheet, a bottle, or a fiber. The article, when produced by a process involving strain-induced crystallization, is characterized with high crystallinity.Type: ApplicationFiled: February 16, 2012Publication date: August 22, 2013Applicant: EASTMAN CHEMICAL COMPANYInventors: Emmett Dudley Crawford, Michael Eugene Donelson
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Publication number: 20130217835Abstract: A polyester/polycarbonate blend having superior thermal stability and superior color stability is disclosed. The polyester/polycarbonate blend comprises: (a) P(ET-CT) (poly(ethylene terephthalate-co-1,4-cyclohexylene dimethylene terephthalate) which is copolymerized with 1,4-cyclohexanedimethanol (CHDM) of 40 to 90 mol % with respect to total diol components; (b) polyethylene terephthalate (PET); (c) polycarbonate (PC); and (d) germanium of 1 to 100 ppm (weight ratio) with respect to total polyester/polycarbonate blend, wherein with respect to total polyester/polycarbonate blend, the amount of the P(ET-CT) and PET is 50 to 90 weight %, the amount of the PET is 1 to 6 times in weight ratio with respect to the P(ET-CT), and the amount of the PC is 10 to 50 weight %.Type: ApplicationFiled: October 28, 2011Publication date: August 22, 2013Applicant: SK CHEMICALS CO., LTD.Inventors: Dong-June Hwang, Jeoung-Jun Hwang, Jae-Bong Lim, Tae-Young Kim, Sung-Su Bae
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Publication number: 20130206636Abstract: An amorphous copolyester comprising the reaction product of: (a) a monomer of formula I wherein R1, R2, R3, and R5 are each independently hydrogen or a C1-3 alkyl group, a is 0-1, b is 0-4, c is 0-4 and d is 0-3, and each R4 is independently hydrogen or a C1-3 alkyl group; (b) a virgin monomer selected from terephthalic acid, a di(C1-3 alkyl) terephthalate, and combinations thereof, and (c) 1,4-cyclohexane dimethanol; wherein the residue of monomer (a) is present in an amount from 7 to less than 12 mole % of the copolyester based on moles of repeat units in the polyester; and the copolyester has a glass transition temperature of at least 107° C., an intrinsic viscosity of at least 0.7 dl/g, and a molded sample has a Notched Izod value of at least 290 J/m determined in accordance with ASTM D256.Type: ApplicationFiled: February 15, 2012Publication date: August 15, 2013Inventors: Navinchandra S. ASTHANA, Ganesh KANNAN
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Patent number: 8507638Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters have a desirable combination of inherent viscosity and glass transition temperature (“Tg”). The polyesters can have an inherent viscosity from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C. and a Tg of 85 to 115° C. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: August 23, 2011Date of Patent: August 13, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8507644Abstract: Methods of making metal-terephthalate polymers from a polyester ethylene terephthalate or terephthalic acid produces high yield and high purity reaction products for a range of metals. Among the preferred metal compounds employed in the processes are metal oxides and metal hydroxides. The methods are preferably carried out at a low pressure and can produce metal-terephthalate polymer powders containing small crystals which can be employed to enhance properties of polymers or disperse metals in specific applications by thermal decomposition of metal-terephthalate polymers.Type: GrantFiled: March 29, 2011Date of Patent: August 13, 2013Assignee: Chem Engineering EnergyInventors: Daniel Eric Steinmeyer, Jonathan Lyle Wistrom
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Patent number: 8501287Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.Type: GrantFiled: September 23, 2010Date of Patent: August 6, 2013Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips, Robert Ellis McCrary
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Publication number: 20130150504Abstract: Disclosed herein is a composition comprising a polyphenylene ether sulfone and a resorcinol based silicone aryl polyester carbonate copolymer wherein greater than or equal to 50 mol % of copolymer repeating units are ester units derived from resorcinol, based on the total molar amount of all repeating units in the polymer and wherein the blend has less than 1 weight percent polycarbonate, based on the total weight of the composition, has FAR 25.853 peak heat release of less than 60 KW/m2 and time to peak heat release of greater than or equal to 120 seconds.Type: ApplicationFiled: December 9, 2011Publication date: June 13, 2013Applicant: SABIC Innovative Plastics IP B.V.Inventors: Robert Russell Gallucci, Paul Dean Sybert
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Publication number: 20130150507Abstract: Disclosed herein is a miscible, high flow composition comprising 80 to 99 wt % of a polyphenylene ether sulfone and 1 to 20 wt % of an aryl polyester carbonate copolymer, based on the combined weight of the polyphenylene ether sulfone and the aryl polyester carbonate copolymer.Type: ApplicationFiled: December 9, 2011Publication date: June 13, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Robert Russell Gallucci, Paul Dean Sybert
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Patent number: 8445581Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.Type: GrantFiled: August 2, 2007Date of Patent: May 21, 2013Assignee: Polynovo Biomaterials Pty LimitedInventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
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Patent number: 8445107Abstract: Process for production of multicomponent moldings, which comprises producing a molding of which at least one layer is composed of a thermoplastic molding composition composed of A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.Type: GrantFiled: June 13, 2006Date of Patent: May 21, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Carsten Weiss, Mark Voelkel, Bernhard Rosenau, Christophe Ginss, Kurt Hofli
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Patent number: 8440769Abstract: A copolyester composition comprising units of residues of a) about 1-40 mole % of trans 3,3?, trans 4,4? stilbene dicarboxylic acid and the combination thereof, b) about 99-60 mole % of cis,trans, and the combination thereof of 1,4 cyclohexane dicarboxylic acid, and c) about 50-100 mole % of cis, trans, and the combination thereof of 1,4-cyclohexane dimethanol. The resulting copolyester may be characterized by its clarity, as well as enhanced heat performance due to the presence of the stilbene moiety.Type: GrantFiled: August 11, 2006Date of Patent: May 14, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ganesh Kannan, Steven James Montgomery
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Publication number: 20130095269Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues and ethylene glycol residues. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.Type: ApplicationFiled: October 10, 2012Publication date: April 18, 2013Applicant: EASTMAN CHEMICAL COMPANYInventor: EASTMAN CHEMICAL COMPANY
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Publication number: 20130096262Abstract: A compound includes a polymer where the polymer includes a pendant dioxirane moiety. Cost-effective, facilitated generation of a polymer including a pendant dioxirane moiety allows for the compound to be disposable or be easily recycled. The compound can be used in air purification and liquid purification to not only remove particulate matter, but also to destroy microorganisms and remove volatile organic compounds.Type: ApplicationFiled: April 12, 2012Publication date: April 18, 2013Inventors: Angele Sjong, Kraig Anderson
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Publication number: 20130095272Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and ethylene glycol. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.Type: ApplicationFiled: October 10, 2012Publication date: April 18, 2013Applicant: EASTMAN CHEMICAL COMPANYInventor: EASTMAN CHEMICAL COMPANY
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Patent number: 8415450Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-l,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity of said polyester is from 0.55 to 0.68 dL/g as determined in 60/40(wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a Tg from 110 to 160° C.; wherein the polyester composition comprises no polycarbonate; wherein the melt viscosity of the polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.; and wherein the polyester has a notched Izod impact strength, of at least 7.5 ft-lb/in.ch at 23° C. according to ASTM D256 with a 10-mil notch in a ? inch thick bar. The polyesters may be manufactured into articles of manufacture as fibers, films, bottles or sheets.Type: GrantFiled: January 12, 2012Date of Patent: April 9, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8410227Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.Type: GrantFiled: May 29, 2012Date of Patent: April 2, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Dietrich Scherzer, Jean-Francois Stumbe, Carsten Weiβ, Freddy Gruber
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Patent number: 8389662Abstract: Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.Type: GrantFiled: September 29, 2010Date of Patent: March 5, 2013Assignee: SABIC Innovative Plastics IP B.V.Inventors: Hans de Brouwer, Robert Dirk van de Grampel, Jan Henk Kamps, Jan-Pleun Lens, Hendrik Theodurus van de Grampel
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Publication number: 20130053461Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions through an in situ phosphorus containing titanium based catalyst and articles made from the compositions.Type: ApplicationFiled: August 30, 2011Publication date: February 28, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Husnu Alp ALIDEDEOGLU, Hareesh Shamroa DESHPANDE, Belinda DUCKWORTH, Tukaram GUNALE, Darshan JAYANNA, Ganesh KANNAN
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Publication number: 20130034740Abstract: Using nano-particles to topographically enhance the reacting surface of an inorganic fiber used as a reinforcement medium in an embedding matrix is described.Type: ApplicationFiled: September 9, 2011Publication date: February 7, 2013Applicant: Apple Inc.Inventors: Marta M. GIACHINO, Michael K. Pilliod
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Patent number: 8362136Abstract: A thermoplastic molding composition, comprising 10 to 98.99% of a thermoplastic polyester, 0.01 to 20% of a hyperbranched polycarbonate, and/or hyperbranched AxBy polyester, wherein Ax and By are different monomers and indices x and y are functional groups in A and B, x is at least 1.1 and y at least 2.1; 1 to 60% of a graft polymer comprising 20 to 80% of a graft base comprising an elastomeric polymer based on alkyl acrylates, 20 to 80% of a graft of 60 to 95% of styrene or of substituted styrenes of formula 1 R is an alkyl radical or hydrogen, R1 is an alkyl radical, n is 1-3, and 5 to 40% by weight of an unsaturated nitrite, 0 to 60% of a copolymer comprising, 60 to 95 of styrene and/or substituted styrenes of formula 1, 5 to 40% of an unsaturated nitrile, 0 to 60% of other additives.Type: GrantFiled: August 2, 2005Date of Patent: January 29, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Carsten Weiβ, Jean-Francois Stumbe
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Patent number: 8354491Abstract: Described are container(s) comprising polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 15 to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 50 to 85 mole % 1,4-cyclohexanedimethanol residues; wherein the total mole % of said dicarboxylic acid component is 100 mole %, and the total mole % of said glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a 1/8-inch thick bar; and wherein the melt viscosity of said polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.Type: GrantFiled: January 28, 2011Date of Patent: January 15, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Publication number: 20130012666Abstract: A composition comprising from 10 to 90 weight percent of a copolyetherester elastomer comprising: a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate, polyethylene terephthalate copolymers, and combinations thereof; and that contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that is derived from the polyethylene terephthalate component and a polyalkylene oxide glycol, and that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component; from 10 to 90 weight percent of a polycarbonate; and from 0 to 60 weight percent of a polyester.Type: ApplicationFiled: September 14, 2012Publication date: January 10, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Peter H. Vollenberg, Dhaval Shah, Kenneth F. Miller
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Patent number: 8349972Abstract: Disclosed herein is a paint composition comprising a hydroxyl group containing resin (A), comprising structural units based on 2,2-dimethylolalkanoic acid, having a hydroxyl group value of from 200 to 400 mgKOH/g, and comprising less than 25 weight % in the resin solid fraction of structural units based on a lactone compound; a hydroxyl group containing resin (B), having a hydroxyl group value from 50 to 200 mgKOH/g, and comprising from 25 to 75 weight % in the resin solid fraction of structural units based on a lactone compound; and a crosslinking agent (C) comprising at least two OH-reactive functional groups per molecule; wherein the resin solid fraction weight ratio (A)/(B) of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B) is from 90/10 to 10/90.Type: GrantFiled: November 1, 2006Date of Patent: January 8, 2013Assignee: BASF Coatings Japan Ltd.Inventors: Tetsu Konishi, Shinji Mitsumune, Hiroyuki Tagkagi, Takehito Ito, Rui Niimi
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Publication number: 20120289655Abstract: The present invention seeks to provide a resin composition which contains an aromatic polycarbonate resin and a polyester resin and which has excellent mechanical strength, flowability and thermal stability and also has excellent moist heat resistance together. The present invention is a resin composition containing 50 to 99 parts by weight of an aromatic polycarbonate resin (component A) and 1 to 50 parts by weight of a polyester resin (component B), the component B being a polyester resin polymerized in the presence of a titanium-phosphorus catalyst obtained by reacting titanium tetrabutoxide, etc., with monolauryl phosphate, etc.Type: ApplicationFiled: January 13, 2011Publication date: November 15, 2012Inventors: Atsushi Sumita, Daisuke Takahashi, Fumihiro Togashi, Tomoyuki Hirano
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Patent number: 8299204Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbons atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: October 30, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8287970Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.Type: GrantFiled: November 20, 2008Date of Patent: October 16, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips
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Patent number: 8287972Abstract: The invention relates the use of a copolyester elastomer comprising hard blocks comprising polyester segments, polymeric soft blocks and urethane linkages, in applications with a thermal overload requirement specifying a thermal overload temperature above the melting temperature of the copolyester elastomer. The invention also relates to films as well as tubes and electrical cables, such as convoluted tubes and electrical cables for use in cable harness systems. The invention more further relates to polymeric materials with high heat properties that can be used in the tubes and cables and to tubes and cables at least comprising a layer consisting of the polymeric materials.Type: GrantFiled: November 11, 2008Date of Patent: October 16, 2012Assignee: DSM IP Assets B.V.Inventors: Hendricus F. Aussems, Atze J. Nijenhuis, Beert J. Keestra
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Publication number: 20120252985Abstract: Provided herein are polycarbonate blend compositions, methods for making polycarbonate blend compositions and articles containing the polycarbonate blend composition, wherein the polycarbonate blend composition comprises a first polycarbonate and a second polycarbonate wherein the polycarbonate blend has a glass transition temperature (Tg) between 148° C. and 155° C. as measured using a differential scanning calorimetry method; a percent (%) haze of less than 3.5% and a % transmission of greater than 80% as measured using a method of ASTM D 1003-07, and wherein the blend composition possesses 80% or greater ductility in a notched izod test at ?20° C. at a thickness of 0.125 inches according to ASTM D256-10.Type: ApplicationFiled: March 31, 2011Publication date: October 4, 2012Inventors: Niles Rosenquist, Srinivas Siripurapu
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Publication number: 20120251750Abstract: A poly(siloxane) copolymer composition comprising: a first polymer comprising a first repeating unit, and a poly(siloxane) block unit, a second polymer different from the first polymer and comprising of bromine; and optionally, one or more third polymers different from the first polymer and second polymer; wherein siloxane units are present in the composition in an amount of at least 0.3 wt %, and bromine is present in the composition in an amount of at least 7.8 wt %, each based on the sum of the wt % of the first, second, and optional one or more third polymers; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, and an E662 smoke test Dmax value of less than 200.Type: ApplicationFiled: September 30, 2011Publication date: October 4, 2012Inventors: Paul D. Sybert, Laura G. Shultz Hume, James F. Hoover, Thomas L. Evans
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Light diffusion member, back light assembly including the same and display device including the same
Patent number: 8268441Abstract: The light diffusion member includes a light diffusing body and a light diffusing layer. The light diffusing body includes a polymer mixture obtained by uniformly blending a first polymer having a first glass transition temperature and a second polymer having a second transition temperature higher than the first transition temperature. Alternatively, the light diffusing body includes a copolymer prepared from the first and the second polymer. The light diffusing body diffuses an incident light through a light exiting surface. The light diffusing layer is formed on the light exiting surface of the light diffusing body and includes a binder resin having beads. A back light assembly including the light diffusion member and a liquid crystal display device including the light diffusion member exhibit an improved luminance and an improved light diffusing efficiency.Type: GrantFiled: April 4, 2011Date of Patent: September 18, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Geun-Hyung Kim, Jong-Dae Park, Tae-Seok Kim -
Publication number: 20120232212Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.Type: ApplicationFiled: May 29, 2012Publication date: September 13, 2012Applicant: Basf SEInventors: Andreas Eipper, Bernd Bruchmann, Dietrich Scherzer, Jean-Francois Stumbe, Carsten Weiß, Freddy Gruber
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Publication number: 20120220680Abstract: The present invention relates to biodegradable aliphatic-aromatic polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids and diols, wherein the polyfunctional aromatic acids are constituted by mixtures of acids of renewable and synthetic origin.Type: ApplicationFiled: November 5, 2010Publication date: August 30, 2012Applicant: Novamont S.P.A.Inventors: Catia Bastioli, Giampietro Borsotti, Luigi Capuzzi, Gian Tomaso Masala, Tiziana Milizia, Roberto Vallero
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Patent number: 8252868Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.Type: GrantFiled: November 4, 2011Date of Patent: August 28, 2012Assignee: Techno Polymer Co., Ltd.Inventors: Masaaki Mawatari, Tatsuya Toneri
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Publication number: 20120214914Abstract: A dimethyl terephthalate residual composition comprising a. dimethyl terephthalate derived from a terephthalic-containing polyester homopolymer, terephthalic-containing polyester copolymer, or a combination thereof and b. from more than 0 to less than 3.6 wt. % of a residual component selected from dimethyl isophthalate, cyclohexane dimethanol, diethylene glycol, triethylene glycol, and combinations thereof.Type: ApplicationFiled: February 22, 2011Publication date: August 23, 2012Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Philip Wesley BELL, Dhaval SHAH
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Patent number: 8236905Abstract: Hyperbranched polyesters containing ethylenically unsaturated groups and obtainable by reacting (c) at least one compound having at least one ethylenic double bond with at least one hyperbranched polyester obtainable by condensing (a) at least one dicarboxylic acid or derivative thereof with at least one at least trifunctional alcohol or (b) at least one tricarboxylic or higher polycarboxylic acid or derivative thereof with at least one diol.Type: GrantFiled: October 8, 2004Date of Patent: August 7, 2012Assignee: BASF AktiengesellschaftInventors: Jean-Francois Stumbe, Bernd Bruchmann, Dietmar Haering, Yvonne Heischkel
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Publication number: 20120184687Abstract: The clear blends of this invention are unique compositions of matter and are prepared by blending polyesters prepared from terephthalic acid, 40 to 5 mole % 2,2,4,4-tetramethy-1,3-cyclobutanediol and 60 to 95 mole % 1,4-cyclohexanedimethanol with a copolyestercarbonate comprising a bisphenol A diol component and 50-90 mole % isophthalic acid and 0-60 mole % terephthalic acid and 0 to 60 mole % carbonic acid. The composition of the blend includes up to about 95 weight % the copolyestercarbonate. These blends have a combination of clarity and toughness making the materials particularly useful in engineering molding plastics and packaging.Type: ApplicationFiled: April 29, 2011Publication date: July 19, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Wesley Raymond Hale, Gary Michael Stack
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Publication number: 20120165460Abstract: The present invention discloses a polycarbonate resin composition which includes a polycarbonate resin (A), a polycarbonate-polysiloxane copolymer (B), and a siloxane copolyester (C), wherein the siloxane copolyester (C) is present in an amount of about 0.1 to about 6 wt % based on 100 wt % of a base resin including the polycarbonate resin (A), polycarbonate-polysiloxane copolymer (B), and siloxane copolyester (C). The composition can have excellent mold release properties and appearance.Type: ApplicationFiled: September 22, 2011Publication date: June 28, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Hwan Seok PARK, Jin Seong LEE, Jong Tae YOON, Yun Ku NAM, Min Jung KANG, Seung Shik SHIN, Woo Jung KIM, Kyuong Sik CHIN
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Publication number: 20120157604Abstract: Described as one aspect of the invention are polymer blends comprising at least one polyester wherein the polymer blend comprises: (A) a polyester composition comprising (I) at least one polyester (Polymer A) which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) about 10 to about 90 mole % of ethylene glycol residues; and (ii) about 90 to about 10 mole % of cyclohexanedimethanol residues; (II) residues of at least one titanium compound; and (III) at least one chelating phosphorus species, reaction products thereof, or mixtures thereof, represented by the structure: wherein: n=an integer from 1 to 4; R can be hydrogen or C1-C22-alkyl; and R1 and R2 each can be hydrogen, C1-C22-alkyl, hydroxyl, or aryl; whType: ApplicationFiled: December 20, 2010Publication date: June 21, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Jason Christopher Jenkins, Dennis Edward Brickey, Michael Eugene Donelson
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Patent number: 8193302Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: June 5, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Publication number: 20120136124Abstract: The present invention discloses a process for preparing di-, tri, or multi-block polyester/polycarbonate (co)polymers by ring-opening polymerisation in the presence of a non-toxic catalyst system in combination with either a linear monohydroxy HO—PC—OR, or a linear telechelic dihydroxy HO—PC—OH, or a star polyhydroxy R—(PC—OH)n end-capped polyester/polycarbonate.Type: ApplicationFiled: November 30, 2009Publication date: May 31, 2012Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Jean-François Carpentier, Sophie Guillaume, Marion Helou, Abbas Razavi
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Patent number: 8188185Abstract: A biodegradable packaging film is provided. The film is formed from a blend that contains a thermoplastic starch and polylactic acid. Starch is a relatively inexpensive natural polymer that is also renewable and biodegradable. Polylactic acid is likewise an inexpensive synthetic polymer that is biodegradable and renewable, yet also capable of providing increased tensile strength to the film. Although providing a good combination of biodegradability/renewability and increased tensile strength, the polylactic acid is also relatively rigid and can result in films having a relatively high stiffness (e.g., high modulus of elasticity) and low ductility. While more ductile than polylactic acid, the thermoplastic starch is often difficult to melt process in film forming processes and very sensitive to moisture and water vapor, reducing its ability to be used as a stand alone packaging film.Type: GrantFiled: June 30, 2008Date of Patent: May 29, 2012Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James H. Wang, Sara A. Funk
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Publication number: 20120068115Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.Type: ApplicationFiled: September 16, 2011Publication date: March 22, 2012Applicants: BAYER MATERIAL SCIENCE AG, FRX POLYMERS, INC.Inventors: Dieter FREITAG, Pin GO, Lawino KAGUMBA, Stephan KONRAD, Helmut-Werner HEUER, Berit KRAUTER, Pieter OOMS, Michael PREIN, Johann RECHNER
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Patent number: 8133967Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: October 7, 2010Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell