Mixed With -n=c=x Reactant Or Polymer Therefrom Patents (Class 525/457)
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Patent number: 6037440Abstract: Polyurethanes with reactive 2-cyanoacetamido moieties are cross-linked with selected electrophiles to give polyurethanes with increased network density.Type: GrantFiled: February 11, 1998Date of Patent: March 14, 2000Assignee: Eastman Kodak CompanyInventors: John C. Wilson, William B. Vreeland
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Patent number: 6018005Abstract: Urethane resins are made by reacting selected nucleophiles, including alcohols, with an isocyanate. The order of addition of the isocyanate and the different nucleophiles can tailor the distribution of di-urethane and mixed urethane/urea molecules in the final resin product. The isocyanate-derived resin materials are useful as ingredients as phase change ink carrier compositions used to make phase change ink jet inks.Type: GrantFiled: February 13, 1998Date of Patent: January 25, 2000Assignee: Tektronix, Inc.Inventors: Jeffery H. Banning, Wolfgang G. Wedler, Clifford R. King, Donald R. Titterington
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Patent number: 6001214Abstract: In one aspect, this invention is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a weight average molecular weight of at least about 2,000; and (2) a catalytic amount of (a) a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound, (b) a mixture of a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound and a second organometallic compound, or (c) a mixture of an organometallic compound with dimorpholinodialkyl ether or an dialkylmorpholinodialkyl ether.Type: GrantFiled: August 6, 1998Date of Patent: December 14, 1999Assignee: Essex Specialty Products, Inc.Inventors: Harry W. Hsieh, Syed Z. Mahdi
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Patent number: 6001936Abstract: An interpenetrating polymer network (IPN) or semi-interpenetrating polymer network (semi-IPN) comprises a first phase which is continuous and comprises a flexible polymer and a second phase which is a fluorescent or nonfluorescent durable dispersed or continuous phase and comprises a dye and a polymer, wherein the polymer enhances durability of the dye. Such networks are particularly useful in fluorescent traffic signs or safety devices or in pavement marking tape or paint.Type: GrantFiled: October 24, 1997Date of Patent: December 14, 1999Assignee: 3M Innovative Properties CompanyInventors: Denise A. Barrera, Roberta E. Harelstad, William D. Joseph, Lee A. Pavelka
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Patent number: 5977245Abstract: Low VOC automotive sealer compositions containing reactive urea/urethane compounds are disclosed. Sealers and tintable sealers utilyzing the reactive urea/urethane compounds have improved physical properties with a faster dry times without sacrificing other desirable properties. These compositions are found to be useful for automotive refinish according to this invention.Type: GrantFiled: February 25, 1997Date of Patent: November 2, 1999Assignee: BASF CorporationInventors: Rajnikant P. Shah, Sudhakar Dantiki, Stewart Shepler
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Patent number: 5976669Abstract: A retroreflective article (10) has retroreflective elements (12) partially embedded in a binder layer (14) that contains a solid polyurethane. The polyurethane includes soft segments, hard segments, silicon moieties, and urethane moieties. The specific chemical identities and relative amounts of the segments and moieties are sufficient to impart desired high elongation and low modulus to the polymer. The inventive retroreflective article is capable of demonstrating extraordinary laundering durability under industrial wash conditions and tumble and tunnel drying.Type: GrantFiled: December 20, 1996Date of Patent: November 2, 1999Assignee: 3M Innovative Properties CompanyInventor: Robert J. Fleming
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Patent number: 5972158Abstract: A process of bonding a plastic is provided. The process comprises applying to a plastic surface an aqueous dispersion of a hydroxyl-functional polyurethane prepolymer obtained by:(1) reaction of:a polyol component containing a polyester polyol,a compound selected from the group of compounds containing groups capable of salt formation and at least two isocyanate-reactive groups,an isocyanate component in a stoichiometric excess, at least 20% by weight of said component consisting of tetramethyl xylylene diisocyanate, and(2) subsequent dispersion in water and at least partial reaction of the remaining NCO groups with an aminoalcohol and, optionally, subsequent chain extension. The process further comprises drying said applied aqueous dispersion to form a primer and bonding said plastic surface having said primer to a part to be joined thereto. The process is particularly useful for priming plastics such as polyvinyl chloride.Type: GrantFiled: October 15, 1996Date of Patent: October 26, 1999Assignee: Kenkel Kommanditgeselschaft auf AktienInventors: Horst Hoffmann, Hans-Georg Kinzelmann, Hans-Peter Kohlstadt
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Patent number: 5973072Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.Type: GrantFiled: March 21, 1996Date of Patent: October 26, 1999Assignee: Exxon Chemical Patents, Inc.Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
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Patent number: 5955534Abstract: Polymer polyols and polymer-modified polyols having substantially no transition metal content in the polyol continuous phase may be prepared from encapsulative double metal cyanide complex-catalyzed polyoxy-alkylene polyether base polyols without substantial removal of double metal cyanide complex catalyst residues from the base polyol and subsequent in situ polymerization of one or more polymerizable monomers.Type: GrantFiled: August 20, 1997Date of Patent: September 21, 1999Assignee: ARCO Chemical Technology, L.P.Inventors: Donald W. Simroth, Xinhua Zhou, Charles V. Rose
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Patent number: 5939488Abstract: The subject invention provides reactive hot melt adhesive compositions comprising polyurethane prepolymers which have an isocyanate index greater than one and which are prepared from a low hydroxyl number composition comprising high molecular weight polyester diols which have a relatively low melting point. These reactive hot melt adhesive compositions have a faster setting speed than conventional reactive hot melt adhesive compositions. The subject invention also provides a method for bonding articles together which uses such reactive hot melt adhesive compositions and articles which comprise the reactive hot melt adhesive compositions.Type: GrantFiled: October 15, 1997Date of Patent: August 17, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: James W. Nowicki, Robert S. Wallach
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Patent number: 5925409Abstract: A method of lining a surface of a substrate comprises providing a reactive mixture which comprises (1) a resin containing active hydrogens; (2) a polycarbodiimide; and (3) an organic diluent; reacting the resin containing active hydrogens and the polycarbodiimide to chemically bind the resin and the polycarbodiimide; applying the chemically bound resin and polycarbodiimide to the surface of the substrate; and curing the chemically bound resin and polycarbodiimide in the presence of an initiator to form a cured resin material which lines the surface of the substrate.Type: GrantFiled: August 27, 1997Date of Patent: July 20, 1999Assignee: Reichhold, Inc.Inventor: Hildeberto Nava
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Patent number: 5919568Abstract: A power coating and a substrate coated with the coating are provided, wherein the coating contains a mixture ofA) a pulverulent polyisocyanate component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C., of the formula I ##STR1## where R, R.sup.1 and n are as described herein, and B) a pulverulent, organic polyhydroxy component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C. and having a ratio of secondary to primary OH groups of at least 3.1,wherein components A and B are present in a ratio of equivalents of NCO:OH groups of from 0.5:1 to 1.3:1,and wherein component B is selected from the group consisting of bisphenol A-containing epoxy resin, oligoamides containing secondary hydroxyl groups, and mixtures thereof.Type: GrantFiled: December 12, 1996Date of Patent: July 6, 1999Assignee: Huels AktiengesellschaftInventor: Elmar Wolf
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Patent number: 5894071Abstract: Two-component adhesive-, sealing- or coating compositions are being described which are separately packed, and comprise the component A and the component D, whereby the component A is curing as soon as it gets in touch with water or the component D which contains the curing agent for the component A.The component D can be, or a component B containing an ingredient which is curing at the contact of water, or, possibly, at the contact with the component A, orthe component D can also be a mixture of solid matter and a volatile ingredient which is causing the cross-linking of the component A.The advantage of the novel two-component systems is that the component D is working as a curing agent for the component A, however, a surplus thereof is, or self-curing, or it does not leave a nuissance residue in the cured composition.Type: GrantFiled: December 6, 1996Date of Patent: April 13, 1999Assignee: Sika AG, vorm. Kaspar Winkler & Co.Inventors: Peter Merz, Norman E. Blank, Hans-Peter Tschan, Reinhard Ernst Wappmann, Lutz Zabel
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Patent number: 5872182Abstract: A water-based sulfonated polyurethane composition and footwear manufactured using the composition as as an adhesive, coating and primer. The sulfonated polyurethane is a reaction product ofa) at least one polyisocyanate;b) at least one alkylene diol;c) at least one sulfonated polyester polyol wherein the sulfo groups thereof are present as alkali metal salts; andd) at least one dihydroxy carboxylic acid, or salt thereof. The composition may also be modified to include a dispersed polymer or copolymer of an ethylenically unsaturated monomer. Such mofified compositions may be obtained by preparing the sulfonated polyurethane in the presence of an ethylenically unsaturated monomer and subsequently subjecting the mixture to free-radical polymerization conditions.Type: GrantFiled: November 21, 1995Date of Patent: February 16, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler, Jillian H. Ierien, Brian L. Marty
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Patent number: 5861470Abstract: The invention discloses two-component water-based laminating adhesives, comprising aqueous polyurethane dispersions and water dispersible polyisocyanates based on the isocyanurates of hexamethylene diisocyanate, having enhanced machining characteristics. The invention further discloses a method for the preparation of dry-bond laminates having enhanced properties including dry-bond clarity and water resistance.Type: GrantFiled: March 7, 1997Date of Patent: January 19, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Peter A. Voss, Thomas E. Rolando
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Patent number: 5852137Abstract: In one aspect, this invention is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a weight average molecular weight of at least about 2,000; and (2) a catalytic amount of (a) a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound, (b) a mixture of a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound and a second organometallic compound, or (c) a mixture of an organometallic compound with dimorpholinodialkyl ether or an dialkylmorpholinodialkyl ether.Type: GrantFiled: January 29, 1997Date of Patent: December 22, 1998Assignee: Essex Specialty ProductsInventors: Harry W. Hsieh, Syed Z. Mahdi
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Patent number: 5840812Abstract: The present invention relates to waterproof but breathable flat materials prepared from the melt from polymer resin mixtures consisting of at least two different melt processable polyurethanes, wherein the different thermoplastic polyurethanes have soft segments with different chemical constitutions, wherein the thermoplastic polyurethane which forms the matrix is a polyurethane with a ether based soft segment, wherein the ether segment has a carbon/oxygen atomic ratio of at least two and at most three and is present at a rate of 70-95 wt. % with reference to the total weight of thermoplastic polyurethanes used for melt processing to produce a flat material, and wherein the flat materials according to the invention have a higher permeability to water vapour, determined according to DIN 53 122, and a lower water absorption, determined according to DIN 53 495, method C, than flat materials made from one of the polyurethanes used for the polymer resin mixture.Type: GrantFiled: November 22, 1995Date of Patent: November 24, 1998Assignee: Wolff Walsrode AGInventor: Dirk Schultze
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Patent number: 5840806Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).Type: GrantFiled: January 7, 1997Date of Patent: November 24, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
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Patent number: 5804648Abstract: A TDI residue generated from the phosgenation of toluene diamine having an ortho-isomer content of less than 0.5% is used to produce a urethane-filled hydroxyl compound. The TDI residues useful in this invention must contain at least 10% monomeric TDI and have a total NCO content of at least 20%. These TDI residues are reacted with a monofunctional alcohol in an amount such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The resultant composition may then be dissolved in a polyhydroxyl compound to produce a urethane-filled polyhydroxyl compound. This urethane-filled polyhydroxyl compound may then be reacted with a polyisocyanate to produce a polyurethane.Type: GrantFiled: December 27, 1996Date of Patent: September 8, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5789493Abstract: The invention relates to a process for preparing a composition contains a polymer and a crosslinking agent which comprises mixing a polymer that is solid at room temperature with a crosslinking agent, the polymer and the crosslinker having complementary reactive groups, at a temperature at which the viscosity of the polymer (measured according to Emila) is less than 5000 dpas, in a means for achieving a homogeneous composition in such a short time that less than 20% of the reactive groups of one of either the polymer or crosslinking agent has reacted, and subsequently cooling and comminuting the composition.The mixing is preferably effected in a static mixer at a temperature higher than 140.degree. C.Type: GrantFiled: August 1, 1997Date of Patent: August 4, 1998Assignee: DSM N.V.Inventors: Josephus M. Van Aaken, Guillaume F. M. Hoedemakers, Johannes S. Van Der Bas, Adrianus J. Van De Werff
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Patent number: 5789494Abstract: Methods and compositions for encapsulated polymeric gels swollen with nonaqueous reactive materials are provided. The methods include gel synthesis, swelling of a gel precursor with a first nonaqueous reactive material, and encapsulation of the swollen gel with a second nonaqueous reactive material. Gels precursors may be synthesized from crosslinking polymers, or alternatively, may be formed by crosslinking and polymerizing a monomer starting material. An accelerator may be utilized to facilitate swelling of the gel precursor with the first nonaqueous reactive material. Foams and composites may also be swollen with the first nonaqueous reactive material. The swollen gel is then contacted with a second nonaqueous reactive material such that an encapsulation layer is formed thereby. The encapsulated gels may be stored for subsequent use.Type: GrantFiled: June 7, 1995Date of Patent: August 4, 1998Assignee: Medlogic Global CorporationInventors: Barry Joseph Hand, E. C. Lupton, Jr., Lev Bromberg, Xiaohong Yu
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Patent number: 5789513Abstract: A coating composition comprising an alkyd or urethane resin and a polyfluorourethane of Formula II(R.sub.f --X--O--CO--NH).sub.m --A--(NH--CO--O--R).sub.(p-m) IIwhereinR.sub.f is a C.sub.2 -C.sub.20 linear or branched fluorocarbon,X is --(CH.sub.2).sub.n --, --(CH.sub.2).sub.g SO.sub.z (CH.sub.2).sub.t --, or --SO.sub.2 N(R.sub.1)CH.sub.2 CH.sub.2 --wherein n is 1 to about 20; g and t are each independently 1 to about 3; z is 0, 1 or 2; and R.sub.1 is an alkyl of 1 to about 4 carbon atoms;A is an aliphatic, cycloaliphatic, aromatic, or heterocyclic radical;R is a C.sub.3 -C.sub.20 linear, branched, or cyclic aliphatic group containing at least one ethylenically unsaturated double bond and optionally at least one phenyl or phenyl substituted with C.sub.1 -C.sub.6 alkyl or halogen;p is 2 to 3; andm is from about 0.8 to about 1.25 when p is 2, and m is from about 1 to about (p-1) when p is greater than 2 is disclosed.Type: GrantFiled: February 26, 1997Date of Patent: August 4, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Jack Robert Kirchner
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Patent number: 5760133Abstract: A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed.Type: GrantFiled: April 17, 1996Date of Patent: June 2, 1998Assignee: Bayer AktiengesellschaftInventors: Herbert Heidingsfeld, Willi Meister, Bernhard Schulte, Wolfgang Brauer, Friedemann Muller, Hans-Georg Hoppe, Hans-Georg Wussow, Jurgen Winkler
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Patent number: 5756636Abstract: A substantially solid free isocyanate prepolymer is made by reacting an isocyanate mixture which is made up of a toluene diisocyanate residue containing monomeric toluene diisocyanate and optionally, additional monomeric toluene diisocyanate in an amount such that the total NCO content is at least 37% with a polyether polyol having an ethylene oxide content of at least 30%. The polyether polyol has a molecular weight of from about 200 to about 6,000 and a functionality of from 2 to 6. The product prepolymers are particularly useful in the production of polyurethanes.Type: GrantFiled: December 27, 1996Date of Patent: May 26, 1998Assignee: Bayer CorporationInventors: William E. Slack, Jyothi S. Pisipati
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Patent number: 5753749Abstract: Urethane-filled compositions are produced by reacting a dicyclohexylmethane diisocyanate residue or a dicyclohexylmethane diisocyanate residue containing mixture with a monofunctional alcohol containing at least one ether group in an amount such that the equivalent ratio isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The diisocyanate residue or residue-containing mixture must contain at least 20% by weight monomeric diisocyanate and have a total NCO content of at least 10%. The diisocyanate residue is produced by phosgenating dicyclohexylmethane diamine in which less than 20% polymeric diamine is present. The urethane filled compositions produced in this manner may then be dissolved in either a polyol or a polyisocyanate and subsequently used to produce polyurethanes in known manner.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5753750Abstract: TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: Bayer CorporationInventors: William E. Slack, Jyothi S. Pisipati
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Patent number: 5747627Abstract: A room temperature curing polyurethane composition comprises a polyisocyanate compound or polyurethane prepolymer (A), an oxazolidine compound (B) having at least one oxazolidine ring, a compound (C) for accelerating the opening of the oxazolidine ring, and optionally a modified carbodiimide (D). The inventive polyurethane composition excels in storage stability and freedom of foaming when curing.Type: GrantFiled: August 19, 1996Date of Patent: May 5, 1998Assignee: The Yokohama Rubber Co., Ltd.Inventors: Kazushi Kimura, Toshimitsu Takeda, Hiroyuki Hosoda, Kazunori Ishikawa, Hiroyuki Okuhira
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Patent number: 5747581Abstract: An adhesive and sealing material contains a) at least one reactive prepolymer which is liquid at room temperature and b) at least one further component which is solid at room temperature, liquid at a slightly raised temperature and at least partially incompatible with the liquid prepolymer(s). Component b) is preferably liquid at a temperature of max. 50.degree. C.Type: GrantFiled: December 21, 1995Date of Patent: May 5, 1998Inventors: Manfred Proebster, Manfred Schumann
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Patent number: 5739207Abstract: Urethane-filled polyisocyanates are produced by (a) reacting a hexamethylene diisocyanate-containing residue having less than 10% by weight monomeric hexamethylene diisocyanate and a total NCO content of at least 25% with an alcohol containing at least one ether linkage in an equivalent ratio of isocyanate to hydroxyl groups of from about 0.9:1 to about 1.0:0.9 and (b) dissolving the product of (a) in a polyisocyanate. These urethane-filled polyisocyanates are particularly useful in the production of polyurethanes.Type: GrantFiled: December 27, 1996Date of Patent: April 14, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5733538Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.Type: GrantFiled: June 7, 1995Date of Patent: March 31, 1998Assignee: Thoratec Laboratories, Inc.Inventor: Judy S. Riffle
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Patent number: 5710117Abstract: Detergent formulation for washing laundry characterized in that it comprises:from about 10 to 80% of its weight of at least one hydrated zeolite (z) of formulaxNa.sub.2 O.yAl.sub.2 O.sub.3.zSiO.sub.2.wH.sub.2 Oin which, if y=1, x is from about 0.7 to 1.1, z is from about 1.3 to 3.3 and w is from about 10 to 264from about 0.005 to 5%, of its weight of a least one polyalkylene terephthalate-polyoxyalkylenebisurethane (PET-UPOEU) copolymeric nonionic or anionic anti-soiling agent, said copolymer being obtained by reaction of a polyalkylene terephthalate (PET) and a polyoxyalkylnebisurethane (UPOEU), the molar ratio of the NCO functions to all of the OH functions or OH function equivalents being from about 0.5 to 1,from about 3 to 40%, of its weight of a least one saturated C.sub.5 -C.sub.24, aliphatic or hydroxyaliphatic alkyl sulphate anionic surfactant (FAS) optionally condensed with approximately 0.Type: GrantFiled: April 4, 1996Date of Patent: January 20, 1998Assignee: Rhone-Poulenc ChimieInventors: Claire David, Etienne Fleury
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Patent number: 5703159Abstract: Resins having a group reactive with an isocyanate group on a side chain are modified with isocyanatosiloxanes. In one form, the isocyanatosiloxane is a single end isocyanatosiloxane obtained by effecting addition reaction between a single end hydrogenosiloxane and an isocyanate group-containing organic silicon compound having one isocyanate group and at least one aliphatic unsaturated hydrocarbon group. A single end isocyanatosiloxane obtained by introducing an isocyanate group into a single end primary aminosiloxane is also useful. In another form, the isocyanatosiloxane is a polyfunctional isocyanatosiloxane which is obtained by effecting addition reaction between a hydrogenosiloxane having at least two SiH groups and an isocyanate group-containing organic silicon compound having one isocyanate group and one aliphatic unsaturated hydrocarbon group.Type: GrantFiled: December 11, 1995Date of Patent: December 30, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Shoji Ichinohe, Toshio Yamazaki, Akira Yamamoto
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Patent number: 5703158Abstract: Sulfonated polyester polyols and mixtures of sulfonated polyester polyols and hydroxy carboxylic acids are used to prepare improved aqueous anionic poly(urethane/urea) dispersions with a high crystallization rate, low heat activation temperature, high green strength, stability at low pH, which show good compatibility with other water based polymers and with crosslinkers. The aqueous anionic poly(urethane/urea) dispersions have high heat resistance after curing or blending with a crosslinker.Type: GrantFiled: November 22, 1994Date of Patent: December 30, 1997Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Michael J. Dochniak, Sonja Stammler
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Patent number: 5698656Abstract: A moisture-curing urethane adhesive composition of a urethane prepolymer resulting from the reaction of a mixture of a polyether diol and a polyether triol with a diisocyanate compound, and a polyurethane compound resulting from the reaction of a mixture of a polyester polyol and a polypropyleneether polyol with a hexamethylene diisocyanate compound with addition of a monoalcohol. A modified moisture-curing urethane adhesive composition of a urethane prepolymer resulting from the reaction of a mixture of a polyether diol and a polyether triol with a diisocyanate compound, a first polyurethane compound resulting from the reaction of a copolymeric polyol consisting of propylene oxide and .epsilon.-caprolactone with a hexamethylene diisocyanate compound with addition of a monoalcohol, and a second polyurethane compound resulting from the reaction of a polyester polyol with a hexamethylene diisocyanate compound with addition of a monoalcohol.Type: GrantFiled: November 7, 1995Date of Patent: December 16, 1997Assignee: The Yokohama Rubber Co., Ltd.Inventors: Yoshinobu Ohashi, Hideyuki Matsuda, Eiji Nishi, Tsuyoshi Nishida
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Patent number: 5681896Abstract: This invention is a quaternary ammonium/isocyanate compound having the formulaOCN-Z-Q.sup.+ A.sup.-,whereinZ is a divalent organic moiety;Q is a quaternary ammonium moiety; andA is a monovalent anionic counterion.Use of this quaternary ammonium/isocyanate compound or its amine/isocyanate compound enables one to convert any hydroxy containing binder into a self-wetting binder.Type: GrantFiled: January 11, 1996Date of Patent: October 28, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventor: Ravindra L. Arudi
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Patent number: 5679756Abstract: A process for making thermoplastic thiourethane-urethane copolymers for use in making optical products preferably comprising reacting an aliphatic diisocyanate with a dithiol under polymerization conditions to form a thiourethane prepolymer which is then reacted with a diisocyanate such as methylene bis(phenyl isocyanate) and a polyol such as a diaromatic containing diol such as ethoxylated Bisphenol A or an aliphatic isocyanate reactive monomer such as tricyclodecane dimethanol or 1,4-dimethanol cyclohexane to form the copolymer product. The polymers have a combination of high refractive index and high Abbe No. The polymers also have high impact strength, high hardness and Tg's above 100.degree. C. It is preferred to make the polymer in an extruder.Type: GrantFiled: December 22, 1995Date of Patent: October 21, 1997Assignee: Optima Inc.Inventors: Zhenya Zhu, Brian G. Risch, Zhou Yang, Yin-Nian Lin
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Patent number: 5679418Abstract: A polyurethane composition suitable for producing leather-like sheets having a soft hand and excellent durability and being dyeable with acid dyes comprising a mixture of:a first polyurethane (a) obtained by reacting:an intermediate product diol (D) with both ends thereof substantially being OH and obtained by reacting a tertiary amino group-containing diol (A), a polymer diol (B) having a number average molecular weight of 500 to 3,000 selected from the group consisting of polyesters, polycarbonates, polylactones and polyethers and an organic diisocyanate (C1), in such stoichiometric amounts as to make the molar ratio of NCO/OH 0.5 to 0.Type: GrantFiled: November 7, 1995Date of Patent: October 21, 1997Assignee: Kuraray Co., Ltd.Inventor: Toshiyuki Akasawa
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Patent number: 5663274Abstract: The present invention relates to heat-curable, cyclic isocyanate addition productsi) which are the reaction products ofa) a polyisocyanate component having an average isocyanate functionality of two or more and a uretdione group content (calculated as N.sub.2 C.sub.2 O.sub.2, MW 84) of 1 to 30%, based on the weight of the polyisocyanate component, withb) a compound containing two or more isocyanate-reactive groups andii) in which at least 10% by weight of the reaction products are in the form of cyclic groups containing urea and/or urethane groups. The present invention also relates to a process for the preparation of these cyclic isocyanate addition products and to the products obtained by curing these compositions, optionally in the presence of other isocyanate-reactive compounds, at elevated temperatures, e.g., coatings, adhesives, molded articles, elastomers and foams.Type: GrantFiled: June 5, 1996Date of Patent: September 2, 1997Assignee: Bayer CorporationInventors: Sze-Ming Lee, Philip E. Yeske, Duane B. Priddy, Jr., Robert J. Kumpf, Douglas A. Wicks
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Patent number: 5663244Abstract: A flexible, aminoplast-curable film-forming composition and a process for preparing multi-layered coated articles coated with a pigmented or colored base coat and a transparent or clear topcoat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent topcoat to the base coat. The transparent topcoat composition is a flexible, curable film-forming composition comprising (1) a polyether polymer containing a plurality of terminal or pendant carbamate groups of the structure: ##STR1## and (2) an aminoplast crosslinking agent. The topcoat composition provides a flexible composite coating with improved acid etch resistance, making the composite coating particularly useful as a topcoat for plastic automotive parts.Type: GrantFiled: May 23, 1995Date of Patent: September 2, 1997Assignee: PPG Industries, Inc.Inventors: Steven V. Barancyk, Christopher A. Verardi, William A. Humphrey
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Patent number: 5658672Abstract: A one-part, solvent free in-mold coating composition exhibiting good hardness, good crack resistance, and good adhesion to fiber reinforced plastic substrates includes a blend of a urethane polyacrylate compound having three or more (meth)acrylate groups, a urethane diacrylate or urethane divinyl compound, one or more adhesion promoters, and one or more ethylenically unsaturated copolymerizable monomers.Type: GrantFiled: May 8, 1995Date of Patent: August 19, 1997Assignee: GenCorp Inc.Inventors: Gerd M. Lenke, Earl G. Melby, H. William Cocain
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Patent number: 5637639Abstract: A process for preparing poly(urethane/urea) prepolymers and aqueous poly(urethane/urea) dispersions (PUDs) therefrom, the poly(urethane/urea) polymers having high heat resistance and good water resistance. The method employs a water soluble volatile organic solvent, such as acetone, at a level of 0.1-5%, based on final dispersion weight, a level which does not require removal for purposes of flash point considerations.Type: GrantFiled: September 15, 1995Date of Patent: June 10, 1997Assignee: H.B. Fuller Licensing and Financing, Inc.Inventors: Youlu Duan, Sonja Stammler
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Patent number: 5610232Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and water. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, and optionally,a low molecular weight aliphatic diol having a molecular weight of from 60 to 400a non-sulfonated polyol,and the diisocyanate component being selected from the group consisting of aromatic diisocyanates, isopherone diisocyanate, hexamethylene diisocyanate and mixtures thereof.Type: GrantFiled: June 7, 1995Date of Patent: March 11, 1997Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler, Scott Rhein, Lowell Lindquist
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Patent number: 5608000Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and a chain extender. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, anda low molecular weight aliphatic diol having a molecular weight of from 60 to 400.Type: GrantFiled: September 9, 1994Date of Patent: March 4, 1997Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler
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Patent number: 5574114Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.Type: GrantFiled: June 2, 1995Date of Patent: November 12, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
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Patent number: 5574102Abstract: An impact-resistant composition is disclosed, comprising(A) a modified polyisocyanate in which the active isocyanate groups have been blocked, obtained from a polycaprolactone-modified diol and an isocyanate compound, and(B) a hydroxyl group-containing resin containing two or more hydroxyl groups per molecule. The composition is useful as a coating composition for forming a chipping-resistant coated film.Type: GrantFiled: May 19, 1993Date of Patent: November 12, 1996Assignee: Nippon Paint Co., Ltd.Inventors: Hajime Tanigami, Hiroshi Mashima, Makoto Ozaki
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Patent number: 5558941Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.Type: GrantFiled: June 2, 1995Date of Patent: September 24, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
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Patent number: 5559196Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.Type: GrantFiled: June 2, 1995Date of Patent: September 24, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
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Patent number: 5554692Abstract: The present invention concerns blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings. More particularly, the invention pertains to thermosetting protective coatings containing a coreactive binder polymer comprising a hydroxyl functional matrix polymer adapted to coreact with a blocked isocyanate comprising pentaerythritol reacted with excess equivalents of isocyanate where excess isocyanate groups are blocked with a blocking agent. Pentaerythritol comprises between about 20% and 100% by weight of the polyol reactants reacted with excess isocyanate groups while the blocked crosslinker comprises between about 10% and 50% by weight of the thermosetting binder components. The preferred thermosetting coating is powder coating.Type: GrantFiled: January 6, 1994Date of Patent: September 10, 1996Assignee: Ferro CorporationInventor: Alistair J. Ross
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Patent number: 5552496Abstract: An aqueous coating composition which is self-drying or is crosslinked by external agents, processes and dispersions for its preparation and its use.Type: GrantFiled: February 27, 1995Date of Patent: September 3, 1996Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Bettina Vogt-Birnbrich, Hans-Peter Patzschke, Werner Lenhard, Walter Schubert
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Patent number: 5538717Abstract: Colored or colorless aqueous nail polish containing particles of polyester-polyurethane which are anionic in dispersion, and in which the particle size is between 2 and 40 nm, and the hardness (as measured using a Persoz' clock) of the film produced after drying for 24 hours at 30.degree. C. and 50% relative humidity from a 300 .mu.m-thick layer of an aqueous dispersion of said particles containing 28% dry matter is between 50 and 300 seconds.Type: GrantFiled: October 14, 1994Date of Patent: July 23, 1996Assignee: L'OrealInventor: Val erie de La Poterie