Mixed With -n=c=x Reactant Or Polymer Therefrom Patents (Class 525/457)
  • Patent number: 6037440
    Abstract: Polyurethanes with reactive 2-cyanoacetamido moieties are cross-linked with selected electrophiles to give polyurethanes with increased network density.
    Type: Grant
    Filed: February 11, 1998
    Date of Patent: March 14, 2000
    Assignee: Eastman Kodak Company
    Inventors: John C. Wilson, William B. Vreeland
  • Patent number: 6018005
    Abstract: Urethane resins are made by reacting selected nucleophiles, including alcohols, with an isocyanate. The order of addition of the isocyanate and the different nucleophiles can tailor the distribution of di-urethane and mixed urethane/urea molecules in the final resin product. The isocyanate-derived resin materials are useful as ingredients as phase change ink carrier compositions used to make phase change ink jet inks.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: January 25, 2000
    Assignee: Tektronix, Inc.
    Inventors: Jeffery H. Banning, Wolfgang G. Wedler, Clifford R. King, Donald R. Titterington
  • Patent number: 6001214
    Abstract: In one aspect, this invention is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a weight average molecular weight of at least about 2,000; and (2) a catalytic amount of (a) a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound, (b) a mixture of a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound and a second organometallic compound, or (c) a mixture of an organometallic compound with dimorpholinodialkyl ether or an dialkylmorpholinodialkyl ether.
    Type: Grant
    Filed: August 6, 1998
    Date of Patent: December 14, 1999
    Assignee: Essex Specialty Products, Inc.
    Inventors: Harry W. Hsieh, Syed Z. Mahdi
  • Patent number: 6001936
    Abstract: An interpenetrating polymer network (IPN) or semi-interpenetrating polymer network (semi-IPN) comprises a first phase which is continuous and comprises a flexible polymer and a second phase which is a fluorescent or nonfluorescent durable dispersed or continuous phase and comprises a dye and a polymer, wherein the polymer enhances durability of the dye. Such networks are particularly useful in fluorescent traffic signs or safety devices or in pavement marking tape or paint.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: December 14, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: Denise A. Barrera, Roberta E. Harelstad, William D. Joseph, Lee A. Pavelka
  • Patent number: 5977245
    Abstract: Low VOC automotive sealer compositions containing reactive urea/urethane compounds are disclosed. Sealers and tintable sealers utilyzing the reactive urea/urethane compounds have improved physical properties with a faster dry times without sacrificing other desirable properties. These compositions are found to be useful for automotive refinish according to this invention.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: November 2, 1999
    Assignee: BASF Corporation
    Inventors: Rajnikant P. Shah, Sudhakar Dantiki, Stewart Shepler
  • Patent number: 5976669
    Abstract: A retroreflective article (10) has retroreflective elements (12) partially embedded in a binder layer (14) that contains a solid polyurethane. The polyurethane includes soft segments, hard segments, silicon moieties, and urethane moieties. The specific chemical identities and relative amounts of the segments and moieties are sufficient to impart desired high elongation and low modulus to the polymer. The inventive retroreflective article is capable of demonstrating extraordinary laundering durability under industrial wash conditions and tumble and tunnel drying.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: November 2, 1999
    Assignee: 3M Innovative Properties Company
    Inventor: Robert J. Fleming
  • Patent number: 5972158
    Abstract: A process of bonding a plastic is provided. The process comprises applying to a plastic surface an aqueous dispersion of a hydroxyl-functional polyurethane prepolymer obtained by:(1) reaction of:a polyol component containing a polyester polyol,a compound selected from the group of compounds containing groups capable of salt formation and at least two isocyanate-reactive groups,an isocyanate component in a stoichiometric excess, at least 20% by weight of said component consisting of tetramethyl xylylene diisocyanate, and(2) subsequent dispersion in water and at least partial reaction of the remaining NCO groups with an aminoalcohol and, optionally, subsequent chain extension. The process further comprises drying said applied aqueous dispersion to form a primer and bonding said plastic surface having said primer to a part to be joined thereto. The process is particularly useful for priming plastics such as polyvinyl chloride.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: October 26, 1999
    Assignee: Kenkel Kommanditgeselschaft auf Aktien
    Inventors: Horst Hoffmann, Hans-Georg Kinzelmann, Hans-Peter Kohlstadt
  • Patent number: 5973072
    Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
  • Patent number: 5955534
    Abstract: Polymer polyols and polymer-modified polyols having substantially no transition metal content in the polyol continuous phase may be prepared from encapsulative double metal cyanide complex-catalyzed polyoxy-alkylene polyether base polyols without substantial removal of double metal cyanide complex catalyst residues from the base polyol and subsequent in situ polymerization of one or more polymerizable monomers.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: September 21, 1999
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Donald W. Simroth, Xinhua Zhou, Charles V. Rose
  • Patent number: 5939488
    Abstract: The subject invention provides reactive hot melt adhesive compositions comprising polyurethane prepolymers which have an isocyanate index greater than one and which are prepared from a low hydroxyl number composition comprising high molecular weight polyester diols which have a relatively low melting point. These reactive hot melt adhesive compositions have a faster setting speed than conventional reactive hot melt adhesive compositions. The subject invention also provides a method for bonding articles together which uses such reactive hot melt adhesive compositions and articles which comprise the reactive hot melt adhesive compositions.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: August 17, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: James W. Nowicki, Robert S. Wallach
  • Patent number: 5925409
    Abstract: A method of lining a surface of a substrate comprises providing a reactive mixture which comprises (1) a resin containing active hydrogens; (2) a polycarbodiimide; and (3) an organic diluent; reacting the resin containing active hydrogens and the polycarbodiimide to chemically bind the resin and the polycarbodiimide; applying the chemically bound resin and polycarbodiimide to the surface of the substrate; and curing the chemically bound resin and polycarbodiimide in the presence of an initiator to form a cured resin material which lines the surface of the substrate.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: July 20, 1999
    Assignee: Reichhold, Inc.
    Inventor: Hildeberto Nava
  • Patent number: 5919568
    Abstract: A power coating and a substrate coated with the coating are provided, wherein the coating contains a mixture ofA) a pulverulent polyisocyanate component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C., of the formula I ##STR1## where R, R.sup.1 and n are as described herein, and B) a pulverulent, organic polyhydroxy component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C. and having a ratio of secondary to primary OH groups of at least 3.1,wherein components A and B are present in a ratio of equivalents of NCO:OH groups of from 0.5:1 to 1.3:1,and wherein component B is selected from the group consisting of bisphenol A-containing epoxy resin, oligoamides containing secondary hydroxyl groups, and mixtures thereof.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: July 6, 1999
    Assignee: Huels Aktiengesellschaft
    Inventor: Elmar Wolf
  • Patent number: 5894071
    Abstract: Two-component adhesive-, sealing- or coating compositions are being described which are separately packed, and comprise the component A and the component D, whereby the component A is curing as soon as it gets in touch with water or the component D which contains the curing agent for the component A.The component D can be, or a component B containing an ingredient which is curing at the contact of water, or, possibly, at the contact with the component A, orthe component D can also be a mixture of solid matter and a volatile ingredient which is causing the cross-linking of the component A.The advantage of the novel two-component systems is that the component D is working as a curing agent for the component A, however, a surplus thereof is, or self-curing, or it does not leave a nuissance residue in the cured composition.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: April 13, 1999
    Assignee: Sika AG, vorm. Kaspar Winkler & Co.
    Inventors: Peter Merz, Norman E. Blank, Hans-Peter Tschan, Reinhard Ernst Wappmann, Lutz Zabel
  • Patent number: 5872182
    Abstract: A water-based sulfonated polyurethane composition and footwear manufactured using the composition as as an adhesive, coating and primer. The sulfonated polyurethane is a reaction product ofa) at least one polyisocyanate;b) at least one alkylene diol;c) at least one sulfonated polyester polyol wherein the sulfo groups thereof are present as alkali metal salts; andd) at least one dihydroxy carboxylic acid, or salt thereof. The composition may also be modified to include a dispersed polymer or copolymer of an ethylenically unsaturated monomer. Such mofified compositions may be obtained by preparing the sulfonated polyurethane in the presence of an ethylenically unsaturated monomer and subsequently subjecting the mixture to free-radical polymerization conditions.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: February 16, 1999
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler, Jillian H. Ierien, Brian L. Marty
  • Patent number: 5861470
    Abstract: The invention discloses two-component water-based laminating adhesives, comprising aqueous polyurethane dispersions and water dispersible polyisocyanates based on the isocyanurates of hexamethylene diisocyanate, having enhanced machining characteristics. The invention further discloses a method for the preparation of dry-bond laminates having enhanced properties including dry-bond clarity and water resistance.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: January 19, 1999
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Peter A. Voss, Thomas E. Rolando
  • Patent number: 5852137
    Abstract: In one aspect, this invention is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a weight average molecular weight of at least about 2,000; and (2) a catalytic amount of (a) a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound, (b) a mixture of a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound and a second organometallic compound, or (c) a mixture of an organometallic compound with dimorpholinodialkyl ether or an dialkylmorpholinodialkyl ether.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: December 22, 1998
    Assignee: Essex Specialty Products
    Inventors: Harry W. Hsieh, Syed Z. Mahdi
  • Patent number: 5840812
    Abstract: The present invention relates to waterproof but breathable flat materials prepared from the melt from polymer resin mixtures consisting of at least two different melt processable polyurethanes, wherein the different thermoplastic polyurethanes have soft segments with different chemical constitutions, wherein the thermoplastic polyurethane which forms the matrix is a polyurethane with a ether based soft segment, wherein the ether segment has a carbon/oxygen atomic ratio of at least two and at most three and is present at a rate of 70-95 wt. % with reference to the total weight of thermoplastic polyurethanes used for melt processing to produce a flat material, and wherein the flat materials according to the invention have a higher permeability to water vapour, determined according to DIN 53 122, and a lower water absorption, determined according to DIN 53 495, method C, than flat materials made from one of the polyurethanes used for the polymer resin mixture.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: November 24, 1998
    Assignee: Wolff Walsrode AG
    Inventor: Dirk Schultze
  • Patent number: 5840806
    Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
  • Patent number: 5804648
    Abstract: A TDI residue generated from the phosgenation of toluene diamine having an ortho-isomer content of less than 0.5% is used to produce a urethane-filled hydroxyl compound. The TDI residues useful in this invention must contain at least 10% monomeric TDI and have a total NCO content of at least 20%. These TDI residues are reacted with a monofunctional alcohol in an amount such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The resultant composition may then be dissolved in a polyhydroxyl compound to produce a urethane-filled polyhydroxyl compound. This urethane-filled polyhydroxyl compound may then be reacted with a polyisocyanate to produce a polyurethane.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: September 8, 1998
    Assignee: Bayer Corporation
    Inventor: William E. Slack
  • Patent number: 5789493
    Abstract: The invention relates to a process for preparing a composition contains a polymer and a crosslinking agent which comprises mixing a polymer that is solid at room temperature with a crosslinking agent, the polymer and the crosslinker having complementary reactive groups, at a temperature at which the viscosity of the polymer (measured according to Emila) is less than 5000 dpas, in a means for achieving a homogeneous composition in such a short time that less than 20% of the reactive groups of one of either the polymer or crosslinking agent has reacted, and subsequently cooling and comminuting the composition.The mixing is preferably effected in a static mixer at a temperature higher than 140.degree. C.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: August 4, 1998
    Assignee: DSM N.V.
    Inventors: Josephus M. Van Aaken, Guillaume F. M. Hoedemakers, Johannes S. Van Der Bas, Adrianus J. Van De Werff
  • Patent number: 5789494
    Abstract: Methods and compositions for encapsulated polymeric gels swollen with nonaqueous reactive materials are provided. The methods include gel synthesis, swelling of a gel precursor with a first nonaqueous reactive material, and encapsulation of the swollen gel with a second nonaqueous reactive material. Gels precursors may be synthesized from crosslinking polymers, or alternatively, may be formed by crosslinking and polymerizing a monomer starting material. An accelerator may be utilized to facilitate swelling of the gel precursor with the first nonaqueous reactive material. Foams and composites may also be swollen with the first nonaqueous reactive material. The swollen gel is then contacted with a second nonaqueous reactive material such that an encapsulation layer is formed thereby. The encapsulated gels may be stored for subsequent use.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 4, 1998
    Assignee: Medlogic Global Corporation
    Inventors: Barry Joseph Hand, E. C. Lupton, Jr., Lev Bromberg, Xiaohong Yu
  • Patent number: 5789513
    Abstract: A coating composition comprising an alkyd or urethane resin and a polyfluorourethane of Formula II(R.sub.f --X--O--CO--NH).sub.m --A--(NH--CO--O--R).sub.(p-m) IIwhereinR.sub.f is a C.sub.2 -C.sub.20 linear or branched fluorocarbon,X is --(CH.sub.2).sub.n --, --(CH.sub.2).sub.g SO.sub.z (CH.sub.2).sub.t --, or --SO.sub.2 N(R.sub.1)CH.sub.2 CH.sub.2 --wherein n is 1 to about 20; g and t are each independently 1 to about 3; z is 0, 1 or 2; and R.sub.1 is an alkyl of 1 to about 4 carbon atoms;A is an aliphatic, cycloaliphatic, aromatic, or heterocyclic radical;R is a C.sub.3 -C.sub.20 linear, branched, or cyclic aliphatic group containing at least one ethylenically unsaturated double bond and optionally at least one phenyl or phenyl substituted with C.sub.1 -C.sub.6 alkyl or halogen;p is 2 to 3; andm is from about 0.8 to about 1.25 when p is 2, and m is from about 1 to about (p-1) when p is greater than 2 is disclosed.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jack Robert Kirchner
  • Patent number: 5760133
    Abstract: A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: June 2, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Heidingsfeld, Willi Meister, Bernhard Schulte, Wolfgang Brauer, Friedemann Muller, Hans-Georg Hoppe, Hans-Georg Wussow, Jurgen Winkler
  • Patent number: 5756636
    Abstract: A substantially solid free isocyanate prepolymer is made by reacting an isocyanate mixture which is made up of a toluene diisocyanate residue containing monomeric toluene diisocyanate and optionally, additional monomeric toluene diisocyanate in an amount such that the total NCO content is at least 37% with a polyether polyol having an ethylene oxide content of at least 30%. The polyether polyol has a molecular weight of from about 200 to about 6,000 and a functionality of from 2 to 6. The product prepolymers are particularly useful in the production of polyurethanes.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: May 26, 1998
    Assignee: Bayer Corporation
    Inventors: William E. Slack, Jyothi S. Pisipati
  • Patent number: 5753749
    Abstract: Urethane-filled compositions are produced by reacting a dicyclohexylmethane diisocyanate residue or a dicyclohexylmethane diisocyanate residue containing mixture with a monofunctional alcohol containing at least one ether group in an amount such that the equivalent ratio isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The diisocyanate residue or residue-containing mixture must contain at least 20% by weight monomeric diisocyanate and have a total NCO content of at least 10%. The diisocyanate residue is produced by phosgenating dicyclohexylmethane diamine in which less than 20% polymeric diamine is present. The urethane filled compositions produced in this manner may then be dissolved in either a polyol or a polyisocyanate and subsequently used to produce polyurethanes in known manner.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: May 19, 1998
    Assignee: Bayer Corporation
    Inventor: William E. Slack
  • Patent number: 5753750
    Abstract: TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: May 19, 1998
    Assignee: Bayer Corporation
    Inventors: William E. Slack, Jyothi S. Pisipati
  • Patent number: 5747627
    Abstract: A room temperature curing polyurethane composition comprises a polyisocyanate compound or polyurethane prepolymer (A), an oxazolidine compound (B) having at least one oxazolidine ring, a compound (C) for accelerating the opening of the oxazolidine ring, and optionally a modified carbodiimide (D). The inventive polyurethane composition excels in storage stability and freedom of foaming when curing.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: May 5, 1998
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kazushi Kimura, Toshimitsu Takeda, Hiroyuki Hosoda, Kazunori Ishikawa, Hiroyuki Okuhira
  • Patent number: 5747581
    Abstract: An adhesive and sealing material contains a) at least one reactive prepolymer which is liquid at room temperature and b) at least one further component which is solid at room temperature, liquid at a slightly raised temperature and at least partially incompatible with the liquid prepolymer(s). Component b) is preferably liquid at a temperature of max. 50.degree. C.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: May 5, 1998
    Inventors: Manfred Proebster, Manfred Schumann
  • Patent number: 5739207
    Abstract: Urethane-filled polyisocyanates are produced by (a) reacting a hexamethylene diisocyanate-containing residue having less than 10% by weight monomeric hexamethylene diisocyanate and a total NCO content of at least 25% with an alcohol containing at least one ether linkage in an equivalent ratio of isocyanate to hydroxyl groups of from about 0.9:1 to about 1.0:0.9 and (b) dissolving the product of (a) in a polyisocyanate. These urethane-filled polyisocyanates are particularly useful in the production of polyurethanes.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: April 14, 1998
    Assignee: Bayer Corporation
    Inventor: William E. Slack
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5710117
    Abstract: Detergent formulation for washing laundry characterized in that it comprises:from about 10 to 80% of its weight of at least one hydrated zeolite (z) of formulaxNa.sub.2 O.yAl.sub.2 O.sub.3.zSiO.sub.2.wH.sub.2 Oin which, if y=1, x is from about 0.7 to 1.1, z is from about 1.3 to 3.3 and w is from about 10 to 264from about 0.005 to 5%, of its weight of a least one polyalkylene terephthalate-polyoxyalkylenebisurethane (PET-UPOEU) copolymeric nonionic or anionic anti-soiling agent, said copolymer being obtained by reaction of a polyalkylene terephthalate (PET) and a polyoxyalkylnebisurethane (UPOEU), the molar ratio of the NCO functions to all of the OH functions or OH function equivalents being from about 0.5 to 1,from about 3 to 40%, of its weight of a least one saturated C.sub.5 -C.sub.24, aliphatic or hydroxyaliphatic alkyl sulphate anionic surfactant (FAS) optionally condensed with approximately 0.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: January 20, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Claire David, Etienne Fleury
  • Patent number: 5703159
    Abstract: Resins having a group reactive with an isocyanate group on a side chain are modified with isocyanatosiloxanes. In one form, the isocyanatosiloxane is a single end isocyanatosiloxane obtained by effecting addition reaction between a single end hydrogenosiloxane and an isocyanate group-containing organic silicon compound having one isocyanate group and at least one aliphatic unsaturated hydrocarbon group. A single end isocyanatosiloxane obtained by introducing an isocyanate group into a single end primary aminosiloxane is also useful. In another form, the isocyanatosiloxane is a polyfunctional isocyanatosiloxane which is obtained by effecting addition reaction between a hydrogenosiloxane having at least two SiH groups and an isocyanate group-containing organic silicon compound having one isocyanate group and one aliphatic unsaturated hydrocarbon group.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: December 30, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Shoji Ichinohe, Toshio Yamazaki, Akira Yamamoto
  • Patent number: 5703158
    Abstract: Sulfonated polyester polyols and mixtures of sulfonated polyester polyols and hydroxy carboxylic acids are used to prepare improved aqueous anionic poly(urethane/urea) dispersions with a high crystallization rate, low heat activation temperature, high green strength, stability at low pH, which show good compatibility with other water based polymers and with crosslinkers. The aqueous anionic poly(urethane/urea) dispersions have high heat resistance after curing or blending with a crosslinker.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: December 30, 1997
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Michael J. Dochniak, Sonja Stammler
  • Patent number: 5698656
    Abstract: A moisture-curing urethane adhesive composition of a urethane prepolymer resulting from the reaction of a mixture of a polyether diol and a polyether triol with a diisocyanate compound, and a polyurethane compound resulting from the reaction of a mixture of a polyester polyol and a polypropyleneether polyol with a hexamethylene diisocyanate compound with addition of a monoalcohol. A modified moisture-curing urethane adhesive composition of a urethane prepolymer resulting from the reaction of a mixture of a polyether diol and a polyether triol with a diisocyanate compound, a first polyurethane compound resulting from the reaction of a copolymeric polyol consisting of propylene oxide and .epsilon.-caprolactone with a hexamethylene diisocyanate compound with addition of a monoalcohol, and a second polyurethane compound resulting from the reaction of a polyester polyol with a hexamethylene diisocyanate compound with addition of a monoalcohol.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: December 16, 1997
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Yoshinobu Ohashi, Hideyuki Matsuda, Eiji Nishi, Tsuyoshi Nishida
  • Patent number: 5681896
    Abstract: This invention is a quaternary ammonium/isocyanate compound having the formulaOCN-Z-Q.sup.+ A.sup.-,whereinZ is a divalent organic moiety;Q is a quaternary ammonium moiety; andA is a monovalent anionic counterion.Use of this quaternary ammonium/isocyanate compound or its amine/isocyanate compound enables one to convert any hydroxy containing binder into a self-wetting binder.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: October 28, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ravindra L. Arudi
  • Patent number: 5679756
    Abstract: A process for making thermoplastic thiourethane-urethane copolymers for use in making optical products preferably comprising reacting an aliphatic diisocyanate with a dithiol under polymerization conditions to form a thiourethane prepolymer which is then reacted with a diisocyanate such as methylene bis(phenyl isocyanate) and a polyol such as a diaromatic containing diol such as ethoxylated Bisphenol A or an aliphatic isocyanate reactive monomer such as tricyclodecane dimethanol or 1,4-dimethanol cyclohexane to form the copolymer product. The polymers have a combination of high refractive index and high Abbe No. The polymers also have high impact strength, high hardness and Tg's above 100.degree. C. It is preferred to make the polymer in an extruder.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: October 21, 1997
    Assignee: Optima Inc.
    Inventors: Zhenya Zhu, Brian G. Risch, Zhou Yang, Yin-Nian Lin
  • Patent number: 5679418
    Abstract: A polyurethane composition suitable for producing leather-like sheets having a soft hand and excellent durability and being dyeable with acid dyes comprising a mixture of:a first polyurethane (a) obtained by reacting:an intermediate product diol (D) with both ends thereof substantially being OH and obtained by reacting a tertiary amino group-containing diol (A), a polymer diol (B) having a number average molecular weight of 500 to 3,000 selected from the group consisting of polyesters, polycarbonates, polylactones and polyethers and an organic diisocyanate (C1), in such stoichiometric amounts as to make the molar ratio of NCO/OH 0.5 to 0.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: October 21, 1997
    Assignee: Kuraray Co., Ltd.
    Inventor: Toshiyuki Akasawa
  • Patent number: 5663274
    Abstract: The present invention relates to heat-curable, cyclic isocyanate addition productsi) which are the reaction products ofa) a polyisocyanate component having an average isocyanate functionality of two or more and a uretdione group content (calculated as N.sub.2 C.sub.2 O.sub.2, MW 84) of 1 to 30%, based on the weight of the polyisocyanate component, withb) a compound containing two or more isocyanate-reactive groups andii) in which at least 10% by weight of the reaction products are in the form of cyclic groups containing urea and/or urethane groups. The present invention also relates to a process for the preparation of these cyclic isocyanate addition products and to the products obtained by curing these compositions, optionally in the presence of other isocyanate-reactive compounds, at elevated temperatures, e.g., coatings, adhesives, molded articles, elastomers and foams.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: September 2, 1997
    Assignee: Bayer Corporation
    Inventors: Sze-Ming Lee, Philip E. Yeske, Duane B. Priddy, Jr., Robert J. Kumpf, Douglas A. Wicks
  • Patent number: 5663244
    Abstract: A flexible, aminoplast-curable film-forming composition and a process for preparing multi-layered coated articles coated with a pigmented or colored base coat and a transparent or clear topcoat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent topcoat to the base coat. The transparent topcoat composition is a flexible, curable film-forming composition comprising (1) a polyether polymer containing a plurality of terminal or pendant carbamate groups of the structure: ##STR1## and (2) an aminoplast crosslinking agent. The topcoat composition provides a flexible composite coating with improved acid etch resistance, making the composite coating particularly useful as a topcoat for plastic automotive parts.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: September 2, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Steven V. Barancyk, Christopher A. Verardi, William A. Humphrey
  • Patent number: 5658672
    Abstract: A one-part, solvent free in-mold coating composition exhibiting good hardness, good crack resistance, and good adhesion to fiber reinforced plastic substrates includes a blend of a urethane polyacrylate compound having three or more (meth)acrylate groups, a urethane diacrylate or urethane divinyl compound, one or more adhesion promoters, and one or more ethylenically unsaturated copolymerizable monomers.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: August 19, 1997
    Assignee: GenCorp Inc.
    Inventors: Gerd M. Lenke, Earl G. Melby, H. William Cocain
  • Patent number: 5637639
    Abstract: A process for preparing poly(urethane/urea) prepolymers and aqueous poly(urethane/urea) dispersions (PUDs) therefrom, the poly(urethane/urea) polymers having high heat resistance and good water resistance. The method employs a water soluble volatile organic solvent, such as acetone, at a level of 0.1-5%, based on final dispersion weight, a level which does not require removal for purposes of flash point considerations.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: June 10, 1997
    Assignee: H.B. Fuller Licensing and Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler
  • Patent number: 5610232
    Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and water. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, and optionally,a low molecular weight aliphatic diol having a molecular weight of from 60 to 400a non-sulfonated polyol,and the diisocyanate component being selected from the group consisting of aromatic diisocyanates, isopherone diisocyanate, hexamethylene diisocyanate and mixtures thereof.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler, Scott Rhein, Lowell Lindquist
  • Patent number: 5608000
    Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and a chain extender. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, anda low molecular weight aliphatic diol having a molecular weight of from 60 to 400.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: March 4, 1997
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler
  • Patent number: 5574114
    Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: November 12, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
  • Patent number: 5574102
    Abstract: An impact-resistant composition is disclosed, comprising(A) a modified polyisocyanate in which the active isocyanate groups have been blocked, obtained from a polycaprolactone-modified diol and an isocyanate compound, and(B) a hydroxyl group-containing resin containing two or more hydroxyl groups per molecule. The composition is useful as a coating composition for forming a chipping-resistant coated film.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: November 12, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hajime Tanigami, Hiroshi Mashima, Makoto Ozaki
  • Patent number: 5558941
    Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: September 24, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
  • Patent number: 5559196
    Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: September 24, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
  • Patent number: 5554692
    Abstract: The present invention concerns blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings. More particularly, the invention pertains to thermosetting protective coatings containing a coreactive binder polymer comprising a hydroxyl functional matrix polymer adapted to coreact with a blocked isocyanate comprising pentaerythritol reacted with excess equivalents of isocyanate where excess isocyanate groups are blocked with a blocking agent. Pentaerythritol comprises between about 20% and 100% by weight of the polyol reactants reacted with excess isocyanate groups while the blocked crosslinker comprises between about 10% and 50% by weight of the thermosetting binder components. The preferred thermosetting coating is powder coating.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: September 10, 1996
    Assignee: Ferro Corporation
    Inventor: Alistair J. Ross
  • Patent number: 5552496
    Abstract: An aqueous coating composition which is self-drying or is crosslinked by external agents, processes and dispersions for its preparation and its use.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: September 3, 1996
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Bettina Vogt-Birnbrich, Hans-Peter Patzschke, Werner Lenhard, Walter Schubert
  • Patent number: 5538717
    Abstract: Colored or colorless aqueous nail polish containing particles of polyester-polyurethane which are anionic in dispersion, and in which the particle size is between 2 and 40 nm, and the hardness (as measured using a Persoz' clock) of the film produced after drying for 24 hours at 30.degree. C. and 50% relative humidity from a 300 .mu.m-thick layer of an aqueous dispersion of said particles containing 28% dry matter is between 50 and 300 seconds.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: July 23, 1996
    Assignee: L'Oreal
    Inventor: Val erie de La Poterie