Contains Polyhydroxy Reactant; Or Additional Polymer Derived From -n=c=x And Polyhydroxy Reactant Patents (Class 525/458)
  • Patent number: 5525681
    Abstract: Polyurea polymers prepared from formulations including a polyisocyanate, a polyamine and a polyepoxide can have good heat stability and good physical properties in the substantial absence of uretidine diones and isocyanurates. The polymers can be prepared in one step of admixing and heating at greater than 150.degree. C. or in a two step process by first admixing the components at less than 130.degree. C. and then postcuring the product at greater than 150.degree. C. The polyurea polymer, after postcuring, can have substantially no residual epoxy or oxazolidinone groups. These polymers were particularly useful for applications which require the exposure of the polyurea polymers to both intermittent high temperatures and high humidity. The polyurea polymers of the present invention can withstand higher temperatures than conventional polyurea polymers without blistering.
    Type: Grant
    Filed: April 13, 1995
    Date of Patent: June 11, 1996
    Assignee: The Dow Chemical Company
    Inventors: Benny G. Barron, Shenghong Dai, James R. Porter
  • Patent number: 5523344
    Abstract: Adhesive formulations are blends of aqueous polymer dispersions and a hydrophobic plasticizer. The blended dispersed polymers include at least one hard sulfonated polyester urethane, at least one soft non-sulfonated polyester urethane, and at least one polar non-polyurethane water-based polymer or copolymer. A high molecular weight elastomeric non-sulfonated polyurethane polymer and a crosslinker are optional further components in the blend. The formulations are useful as non-heat activating, one-component adhesives which generate excellent green strength, water and heat resistant bonds.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 4, 1996
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Mike Maksymkiw, Gray Haider, Michael Dochniak, Leonard Jannusch, Paul Wade
  • Patent number: 5516857
    Abstract: Thermoplastic urethane elastomeric alloys are obtained by melt compounding at least one first component that is a polyurethane elastomer having at least one plasticizer reacted therein, this first component being formed by heating a reaction mixture comprising at least one isocyanate having a functionality of less than about 2.2, at least one long chain polyol, at least one chain extender and at least one plasticizer in specified amounts at a temperature of at least about 330.degree. F. (165.6.degree. C.), with at least one second component that is another thermoplastic elastomer not within the definition of the first component.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 14, 1996
    Assignee: REFAC International, Ltd.
    Inventor: William H. Mann
  • Patent number: 5514747
    Abstract: A method for preparing a polyamide-imide-modified polyurethane varnish composition for coating a conductive wire to form a varnished wire. The method comprises the steps of: (a) preparing a first intermediate reaction product, which is an isocyanate compound, (b) preparing a second intermediate reaction product, which is a hydroxy compound, and (c) mixing the first and second intermediate reaction products with a diluent to form the polyamide-imide-modified polyurethane varnish composition. The first intermediate reaction comprises the steps of: (I) preparing a first reaction mixture containing a phenol or a derivative of phenol, a diisocyanate, and a dihydroxy compound in a first organic solvent, and reacting the first reaction mixture at room temperature; (ii) adding a diacid compound or trimellitic anhydride or mixture thereof to the first reaction mixture, and reacting at 100.degree..about.140.degree. C.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: May 7, 1996
    Assignee: Industrial Technology Research Institute
    Inventors: Sheng Yaw Hsu, Tzong-Ming Lee
  • Patent number: 5498782
    Abstract: Distortion control additives are disclosed which comprise a polyisocyanate, a polyol or polyol blend having a hydroxyl functionality of 2 to 3 hydroxyl groups per molecule and an average molecular weight of at least about 500 grams per gram mole, a diol chain extender having from about 2 to 35 carbon atoms per molecule and an acrylate or methacrylate having an acrylate functionality of from 1 to 5 acrylate groups per molecule. Ultraviolet-curable liquid compositions comprising an unsaturated polymeric resin, a monomer and the distortion control additives of the present invention are also disclosed. The distortion control additives can provide substantial reductions in distortion, e.g., shrinkage, of objects produced by ultraviolet curing, e.g., stereolithography.
    Type: Grant
    Filed: September 8, 1993
    Date of Patent: March 12, 1996
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Gary C. Rex
  • Patent number: 5484853
    Abstract: A two-part adhesive composition having superior adhesive strength at cryogenic temperatures contains a urethane resin composition part and a hardener part. The urethane resin composition part comprises 50 to 99% by weight of a modified polyurethane prepolymer having an epoxy group at each of its respective ends and 1 to 50% by weight of a modified urethane compound having substantially no ether cyanate (NCO) groups and at least two epoxy groups per molecule and a molecular weight of less than 800 daltons. The hardener part is a polyamine containing primary or secondary amine groups. The equivalent ratio of the amine groups of the polyamine to the epoxy groups of the urethane resin composition part is 0.5 to 2.0.
    Type: Grant
    Filed: July 28, 1993
    Date of Patent: January 16, 1996
    Assignee: China Technical Consultants, Inc.
    Inventors: Der-Shyang Chen, Hung-Chung Hsia, Chen-Chi M. Ma, Wang-Nang Wang
  • Patent number: 5458935
    Abstract: The invention provides a thermoplastic polyurethane elastomer which contains a blend of polyurethane resins and is suitable for use in the form of tubing. The blend has a tensile strength of more than 7000 psi and an ultimate elongation greater than 200%. The blend contains about 50% to about 80% by weight of an elastomeric polyurethane resin having a hardness in the range of about 60 to 70 Shore D units. The blend additionally contains about 20% to about 50% of a relatively rigid polyurethane resin having a hardness of about 10 units more than the elastomeric resin. The invention also provides methods for using and methods for manufacturing tubing fabricated from the thermoplastic polyurethane elastomer. Preferred extrusion conditions are described.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: October 17, 1995
    Assignee: Abbott Laboratories
    Inventor: Bernard G. Alzner
  • Patent number: 5436302
    Abstract: A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: July 25, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles W. Stobbie, IV, John C. Tangen, Lani S. Kangas
  • Patent number: 5422385
    Abstract: An isocyanate-based elastomer containing a filler material, the filler material being present at a level in the range of from about 30% to about 90% by weight of the elastomer and having a specific gravity of less than about 2.0. A process for producing the isocyanate-based elastomer is also disclosed. The process comprises the steps of: providing a first mixture comprising a catalyst and a filler material, the filler material being wetted by the catalyst; providing a second mixture comprising an isocyanate and an active hydrogen-containing compound; mixing the first mixture and the second mixture to provide a reaction mixture; allowing the reaction mixture to react to produce the isocyanate-based elastomer.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: June 6, 1995
    Assignee: Woodbridge Foam Corporation
    Inventor: Paul V. Farkas
  • Patent number: 5415799
    Abstract: A cleaning composition for removing reactive polyurethane (PUR) hot melt adhesives from production and processing devices, machines and equipment which includes at least one reactive monofunctional hydroxyl compound which can react with the reactive isocyanate groups of the hot melt adhesive. The monohydroxy functional compound of the invention's clean composition completely saturates the remaining NCO groups of the hot melt adhesive to be removed, converting the adhesive into non-reactive, meltable compounds which are soluble in the cleaning composition.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: May 16, 1995
    Assignee: H. B. Fuller Company
    Inventor: Franz Maitz
  • Patent number: 5410001
    Abstract: The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by(I) reacting, in a first stage,(a) diphenylmethane diisocyanate and(b) a monoalcohol or a mixture of monoalcohols to give an intermediate product (A) containing isocyanate groups, and(II) reacting this intermediate product (A) in a second stage with(c) a polyol or a mixture of polyols to give an intermediate product (B) containing hydroxyl groups which(III) is reacted in a third stage either with(d) a cycloaliphatic, aliphatic or araliphatic polyisocyanate or a mixture of such polyisocyanates and(e) a monofunctional masking agent or a mixture of such masking agents or with(f) a partially-masked polyisocyanate prepared from (d) and (e)to give a crosslinking agent which is free from isocyanate groups.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: April 25, 1995
    Assignee: BASF Lacke & Farben Aktiengesellschaft
    Inventors: Gunther Ott, Ulrich Heimann, Walter Jouck, Udo Reiter, David J. Santure
  • Patent number: 5367036
    Abstract: A moisture-curable urethane-based sealing composition is made up of an urethane prepolymer and a polyurethane compound blended together in specified amounts. The urethane prepolymer is derivable by reacting a selected class of polyether polyols with a selected class of polyisocyanate compounds. The polyurethane compound is available by reacting a selected class of polyether or polyester polyols with a selected class of polyisocyanate compounds, followed by reaction of the resulting prepolymer with a selected class of monoalcohols to thereby binder all isocyanate groups in the prepolymer. The ultimate sealant is adequate in initial adhesion strength, low in glass transition temperature and resistant to moist heat.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: November 22, 1994
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Hitoshi Saito, Tetsuji Kitamura, Hideyuki Matsuda, Masamichi Danjo, Eiji Nishi
  • Patent number: 5350811
    Abstract: An adhesive composition comprising (a) an epoxy resin obtained by reacting a 1,3-bis(dicarboxyphenyl)-1,1,3,3-tetrasubstituted disiloxane dianhydride with an alcohol or alcohol derivative, followed by reaction with an epoxy compound having two or more epoxy groups, or an epoxy resin obtained by reacting a 1,3-bis(dicarboxyphenyl)-1,1,3,3-tetrasubstituted disiloxane with an epoxy compound having two or more epoxy groups and (b) a curing agent is suitable for bonding semiconductor chips to a copper frame with a small warpage of the chips.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: September 27, 1994
    Assignee: Hitachi Chemical Co. Ltd.
    Inventors: Nobuo Ichimura, Mitsuo Yamazaki, Kohei Fujita, Hidetaka Satou, Yasuo Miyamoto, Masao Kawasumi, Tohru Kikuchi
  • Patent number: 5342873
    Abstract: A reactive, after cooling still viscous-plastic moldable hot-melt adhesive contains a mixture ofat least one thermoplastic material,at least one binder on isocyanate basis, andat least one thixotropic agent,and the isocyanate content, referred to the total of the hot-melt adhesive, is in the range from 0.01 to 10 percent by weight.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: August 30, 1994
    Assignee: Sika AG, vorm. Kaspar Winkler & Co.
    Inventors: Peter W. Merz, Lutz Zabel, Christian Fischer
  • Patent number: 5342889
    Abstract: The present invention relates to electrostatic dissipative polymeric compositions comprising an effective amount of a chain extended polymer and a matrix polymer or matrix polymer blend. The chain extended polymer of the subject invention has electrostatic dissipative properties and is formed from low molecular weight polyethers which are reacted with a chain extender to furnish a useful additive.
    Type: Grant
    Filed: July 10, 1991
    Date of Patent: August 30, 1994
    Assignee: The B. F. Goodrich Company
    Inventors: Francis R. Sullivan, Elaine A. Mertzel, Edmond G. Kolycheck
  • Patent number: 5338763
    Abstract: Compounds containing alcoholic hydroxyl groups suitable as a starting material for the isocyanate polyaddition process by the alcoholysis of polyisocyanate polyaddition products are produced. Polyurethane urea or polyurea waste products having a molar ratio of urea groups to urethane groups of from 1:20 to 1:0 are heated in size reduced form to temperatures of from 120.degree. to 250.degree. C. together with B) polyhyhdric alcohols in the molecular weight range of from 62 to 250 in a ratio by weight of A:B of from 3:1 to 1:10. At least 10% of the polyhydric alcohol B put into the process is subsequently removed by distillation under reduced pressure. A total of up to 1000% by weight, based on the weight of polyurethane urea or polyurea waste A, of one or more polyhydroxy compounds having a molecular weight above 250 which is (are) not volatile under the distillation conditions may optionally be added to the mixture before and/or after removal of the excess alcohol B by distillation.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: August 16, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Munzamy, Werner Rasshofer, Karl-Heinz Dorner, Ulrich Limna
  • Patent number: 5334689
    Abstract: Process for preparing a flexible foam by reacting an isocyanate prepolymer having a free NCO content of 2-15% by weight, an isocyanate prepolymer having a free content of 25-31% by weight and an isocyanate-reactive composition comprising water.
    Type: Grant
    Filed: January 12, 1994
    Date of Patent: August 2, 1994
    Assignee: Imperial Chemical Industries PLC
    Inventors: Louis Muller, Gabriel Verhelst
  • Patent number: 5331044
    Abstract: The present invention deals with low temperature impact resistant, easily flowing, thermoplastic polyurethane elastomer compositions, comprising:A) 5-95 parts by weight of at least one thermoplastic polyurethane elastomer (A) having a Shore A hardness less hah 95; andB) 95-5 parts by weight of at least one thermoplastic polyurethane elastomer (B) having a Shore A hardness greater than 98, whereby the parts by weight of (A) and (B) total 100 parts by weight; andC) 0-60 weight percent based on the weight of (A) and (B) of a reinforcing filler.The products are prepared by melting together polyurethane elastomers (A) and (B) at temperatures of from 140.degree.-250.degree. C., preferably in an extruder, and are most preferred for the preparation of ski boots and injection molded articles for motor vehicles.
    Type: Grant
    Filed: February 7, 1990
    Date of Patent: July 19, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Deitrich Lausberg, Rolf Steinberger, Walter Heckmann, Harald Schulz
  • Patent number: 5283298
    Abstract: The present invention is directed to a hydrophilic composition which is the reaction product of a polyvinylpyrrolidone, an organic monoisocyanate, and an oxyalkylene group containing mono- or di- hydroxyl compound.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: February 1, 1994
    Assignee: Miles Inc.
    Inventors: Ashok M. Sarpeshkar, Peter H. Markusch, Charles S. Gracik
  • Patent number: 5281677
    Abstract: A thermoplastic polyurethane chain extended with an alkylenediol is blended with a thermoplastic polyurethane chain extended with an oxyalkylene qlycol oligomer. The blend is extruded into a catheter tubing having sufficient initial stiffness for satisfactory insertion in a patient and a high degree of softening for safe positioning and long term catheterization procedures without the risk of vessel wall perforation.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: January 25, 1994
    Assignee: Becton, Dickinson and Company
    Inventors: Theo O. Onwunaka, Fidelis C. Onwumere, James M. Lambert
  • Patent number: 5281654
    Abstract: This invention is directed to a polyurethane mixture. More particularly, there is provided a mixture polyurethanes comprising a first polyurethane with at least two end groups, where each end group comprises a terminal isocyanate and a polyether; a second polyurethane with at least two end groups, where each end group comprises a terminal isocyanate group and a non-functional group; and a third polyurethane with at least two end groups, where one end group comprises a terminal isocyanate and a polyether and one other end group comprises a terminal isocyanate and a non-functional group. A method for improving the sag resistance of an aqueous composition is also provided. This method permits the formulation of aqueous compositions which resist the tendency to sag. The polyurethane mixture of this invention is useful for thickening aqueous compositions such as paints, coatings, cosmetics, personal care items, hair shampoos and conditioners, cleaners, and the like.
    Type: Grant
    Filed: January 14, 1993
    Date of Patent: January 25, 1994
    Assignee: Rohm and Haas Company
    Inventors: Eric K. Eisenhart, Paul R. Howard, Rodney L. Randow, Rafael G. Aviles
  • Patent number: 5270348
    Abstract: Process for preparing a flexible foam by reacting an isocyanate prepolymer having a free NCO content of 2-15% by weight, an isocyanate prepolymer having a free content of 25-31% by weight and an isocyanate-reactive composition comprising water.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: December 14, 1993
    Assignee: Imperial Chemical Industries plc
    Inventors: Louis Muller, Gabriel Verhelst
  • Patent number: 5252671
    Abstract: The present invention relates to coating compositions containing(A) 70 to 98% by weight, based on the sum of components (A) and (B), of(a) isocyanate-free polymers of ethylenically unsaturated monomers and/or polyurethanes or blocked isocyanate prepolymers, and(b) optional organic solvents,wherein component (A) contains no significant quantities of groups capable of reacting with component (B) or starting materials thereof and has a viscosity (at 23.degree. C.) of 2000 to 100,000 mPa.s;(B) 2 to 30% by weight, based on the sum of components (A) and (B), of a polyaddition product prepared in and dispersed in component (A), wherein the polyaddition product is a polyurethane, polyurethane urea, polyurea, or mixture thereof, containing ionic groups and/or potentially ionic groups in a quantity corresponding to from 0.
    Type: Grant
    Filed: May 21, 1992
    Date of Patent: October 12, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef Pedain, Klaus Noll, Wilhelm Thoma, Detlef-Ingo Schutze
  • Patent number: 5252683
    Abstract: A coating composition useful for shatter-proofing glass, capable of forming a film which allows an elongation of at least 400%. The coating composition includes (A) a polyurethane compound obtained by reaction of (a) a polycarbonate diol and/or (b) an aliphatic polyester diol, (c) an organic diisocyanate and (d) a chain extender possessing an active hydrogen-containing group in amounts to give an isocyanate group/active hydrogen-containing group equivalent ratio not exceeding 1.0, (B) an organic polyisocyanate compound and (C) a reactive silicone oil.
    Type: Grant
    Filed: March 29, 1991
    Date of Patent: October 12, 1993
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Murata, Masami Oka, Hiroshi Fujimoto
  • Patent number: 5248731
    Abstract: Thermoplastic synthetic polymeric compositions of certain polyurethanes, polyamides or chlorinated polyolefins, having processing temperatures in the range of about 150.degree. to 325.degree. F., can be modified by the addition of a millable thermoplastic polyurethane elastomer thereto to lower the processing temperature by 10.degree. to 30.degree. F. or more. This modification enables the thermoplastic composition to be processed on conventional calendering or extrusion equipment with a lesser amount of energy or with better performance. Also, coated fabrics of such thermoplastic compositions and a fiber reinforcement.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: September 28, 1993
    Assignee: Reeves Bros. Inc.
    Inventors: Fred N. Teumac, John R. Damewood, Jill R. Menzel
  • Patent number: 5238999
    Abstract: A one component composition suitable for coating a substrate, including at least one crosslinker having a functionality thereon that is reactive with a functionality on at least one film forming polymer. The crosslinker includes at least one member selected from the group consisting of: blocked isocyanurates of isophorone diisocyanate; derivatives of blocked isocyanurates of isophorone diisocyanate; blocked biurets of isophorone diisocyanate; derivatives of blocked biurets of isophorone diisocyanate. The composition preferably includes a blend of this crosslinker with a second crosslinker, wherein the second crosslinker is at least one member selected from the group consisting of: blocked isocyanurates of hexamethylene diisocyanate; derivatives of blocked isocyanurates of hexamethylene diisocyanate; blocked biurets of hexamethylene diisocyanate; and derivatives of blocked biurets of hexamethylene diisocyanate.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: August 24, 1993
    Assignee: BASF Corporation
    Inventors: Vincent C. Cook, James R. Eshelman, Edward A. Guerrini
  • Patent number: 5234996
    Abstract: A two-part polyurethane adhesive which comprises a main component comprising a hydroxyl-terminated saturated polyester resin or a polyester urethane rubber prepared by reacting said hydroxyl-terminated saturated polyester resin with a diisocyanate compound, and a curing agent comprising a urethane prepolymer having an active isocyanate group which is prepared by reacting a hydrogenated hydroxyl-terminated polybutadiene with an excess amount of a polyisocyanate. Said polyurethane adhesive is useful for adhering a polyolefin base material and a covering material for the production of automobile interior parts.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: August 10, 1993
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Masahito Mori, Kousuke Torii, Hirokazu Okamoto
  • Patent number: 5194503
    Abstract: A non-isocyanate flexibilizer additive is provided which finds utility in coating systems such as alkyds, polyesters, acrylic/polyester, alkyd/acrylic, carboxy/epoxy, polyether/urethane, epoxy/polyester, other epoxy, and urea and melamine formaldehyde systems. The non-isocyanate functional flexibilizer has the formula; B--C(O)--NW--A--NX--C(O)--K wherein A is selected from the group consisting fundamentally of polyesters, polyamides, polyureas, polyurethanes, acrylics; biuret, allophonate and urethane extended polyesters; wherein B and K are selected from the group consisting of --OR and --Z--R'--SiOR".sub.(3-n) R"".sub.n wherein R' is a divalent lower alkyl radical of from 1 to 18 carbon atoms, R is a lower alkyl radical of from 1 to 18 carbon atoms, Z is a member selected from the group consisting of S and NR", W and X are selected from H and lower alkyl radicals of from 1 to 10 carbon atoms, wherein R", R" and R"" are H or a lower alkyl radical of from 1-18 carbon atoms, and wherein n is 0, 1 or 2.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: March 16, 1993
    Assignee: BASF Corporation
    Inventors: Gerald L. Bajc, Thomas E. Noseworthy, James M. Cameron
  • Patent number: 5173538
    Abstract: A quick-setting, moisture-curing hot-melt polyurethane composition having a first polyether-based polyurethane prepolymer having a Tg above room temperature and a second polyurethane prepolymer with a Tg below room temperature, the first prepolymer being prepared from a low molecular weight polyether; preferably the second prepolymer is also polyether based and prepared from a high molecular weight polyether.
    Type: Grant
    Filed: October 17, 1989
    Date of Patent: December 22, 1992
    Assignee: Bostik, Inc.
    Inventors: Heinz G. Gilch, Walter Rath
  • Patent number: 5162457
    Abstract: This invention relates to crystalline, isocyanate group-containign hot melt adhesives based onfrom 70-95% by weight of a prepolymer A based on polyester diols having a molecular weight of from 1500 to 10,000 and melting points of from 50.degree. to 90.degree. C. and diisocyanates in a ratio of isocyanate groups of the diisocyanate to the hydroxyl groups of the polyester diol of from 3:1 to 1.2:1 andfrom 5-30% by weight of a component B having a molecular weight of from 1000 to 10,000 based on polyesters having melting points of from 60.degree. to 150.degree. C., in which component B contains at most 0.5 Zerewitinow active groups per molecule.
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: November 10, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eduard Hansel, Walter Meckel, Klaus Konig, Otto Ganster, Horst Stepanski
  • Patent number: 5143987
    Abstract: The present invention is directed to a polyurethane reactive adhesive compound comprising:A) one or more polyisocyanates having an inactivated particle surface,B) at least one isocyanate reactive compound having a molecular weight MG.sub.w greater than 400, andC) finely dispersed polymer particles, wherein the polymer is solid at temperatures below 70.degree. C. and has a molecular weight MG.sub.w of at least 3000.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: September 1, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eduard Hansel, Heinrich Hess, Gunter Arend, Gerhard Grogler, Richard Kopp
  • Patent number: 5137972
    Abstract: A two component composition suitable for coating a substrate comprises at least one crosslinker having a functionality thereon which is reactive with a functionality on at least one film forming polymer present in a separate component of the composition. The crosslinker comprises at least one member selected from the group consisting of: (1) an isocyanurate of isophorone diisocyanate; (2) a derivative of an isocyanurate of isophorone diisocyanate; (3) a biuret of isophorone diisocyanate; and (4) a derivative of a biuret of isophorone diisocyanate. The composition preferably comprises a blend of the this crosslinker with a second crosslinker, wherein the second crosslinker is at least one member selected from the group consisting of: (1) an isocyanurate of hexamethylene diisocyanate; (2) a derivative of an isocyanurate of hexamethylene diisocyanate; (3) a biuret of hexamethylene diisocyanate; and (4) a derivative of a biuret of hexamethylene diisocyanate.
    Type: Grant
    Filed: August 29, 1991
    Date of Patent: August 11, 1992
    Assignee: BASF Corporation
    Inventor: Vincent C. Cook
  • Patent number: 5130384
    Abstract: The processing temperature of linear thermoplastic polyurethane elastomers prepared from a polycarbonate polyol, a polyether polyol, an extender and a disocyanate compound which has been modified by reaction with a low molecular weight diol to form a modified diisocyanate compound prior to reaction with the other components of the elastomer, can be reduced by adding a millable thermoplastic linear polyurethane elastomer thereto. These materials possess an optimum combination of hydrolytic stability, toughness, flexibiity and low temperature processing characteristics.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: July 14, 1992
    Assignee: Reeves Brothers, Inc.
    Inventors: John R. Damewood, Jill R. Menzel, Fred N. Teumac, Bert A. Ross
  • Patent number: 5089571
    Abstract: High molecular weight thermoplastic polyurethane resins with narrow molecular weight distribution and good physical properties are prepared by regenerating thermally degraded and/or off-grade thermoplastic polyurethane resins. The regenerated high molecular weight thermoplastic polyurethane resins do not present any processing difficulties inherent to high molecular weight resins.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: February 18, 1992
    Assignee: The Dow Chemical Company
    Inventors: Henry W. Bonk, Augustin T. Chen, Benjamin S. Ehrlich
  • Patent number: 5068280
    Abstract: Polyurethane and/or polyurea dispersions are prepared by reacting certain coreactants with a polyisocyanate in the presence of a preformed polyurethane and/or polyurea dispersion. The resulting products are epsecially useful to prepare flexible polyurethane foams which exhibit low shrinkage. In addition, polyurethane and/or polyurea dispersions having a bimodal particle size distribution are disclosed.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: November 26, 1991
    Assignee: The Dow Chemical Company
    Inventors: Jack M. Pal, James P. Cosman, Karen Tan
  • Patent number: 5066733
    Abstract: Disclosed is a liquid coating composition, useful for making a chip resistant coating, comprising a binder of: a first and a second urethane resin each containing terminal, reactive ethylenically unsaturated groups. Each urethane resin is prepared by reacting components comprising (A) an isocyanate-terminated prepolymer which is the product of reacting an organic polyisocyanate with an organic polyol with (B) an isocyanate reactive group-containing unsaturated monomer selected from hydroxyalkyl acrylates, hydroxyalkyl methacrylates and hydroxyalkyl acrylamides. The organic polyol for the first urethane resin has a hydroxyl functionality of 3 or more; the organic polyol for the second urethane resin has a hydroxyl functionality of less than three; and the average functionality of the polyols utilized for the first and second urethane resins is less than three.Also disclosed is a method of making a cured chip resistant, coating.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: November 19, 1991
    Assignee: PPG Industries, Inc.
    Inventors: Jonathan T. Martz, Thomas W. Kelly, Rostyslaw Dowbenko, James A. Meier, Anthony C. Palermo
  • Patent number: 5028642
    Abstract: An improved spandex polymer composition provides fibers or films of the composition with increased heat set efficiency and greater discoloration resistance. The composition contains zinc oxide and a polyhydroxy additive selected from certain sugars, reduced sugars and/or polyhydroxy urethanes formed from these sugars or reduced sugars and an organic diisocyanate.
    Type: Grant
    Filed: February 9, 1990
    Date of Patent: July 2, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Charles W. Goodrich, William L. Evans
  • Patent number: 5021520
    Abstract: The present invention relates to crosslinked polyurethane-polyurea powders which are prepared by a process which comprises dispersing NCO semiprepolymers in an aqueous medium, forming powders and isolating the powders from the aqueous medium, the NCO semiprepolymers having an NCO content of 10 to 20%, being liquid at room temperature and/or dissolved in isocyanate-inert, water-soluble solvents and based on the reaction product of(a) a polyisocyanate component based on at least one organic polyisocyanate with a polyol component having an average hydroxyl functionality of 2.3 to 4.0 and containing(b) a hydrophobic polyol component containing less than 25% by weight of ethylene oxide units, --CH.sub.2 --CH.sub.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: June 4, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Reiff, Dieter Dieterich, Rene Stepanek
  • Patent number: 4999407
    Abstract: Quick-setting hot-melt adhesive compositions comprising a mixture of at least two polyurethane prepolymer, each providing a different glass transition point to said composition. Preferably one prepolymer has a tg above room temperature and one prepolymer has a tg below room temperature. These adhesive mixtures show an attractive blend of properties, giving quick setting bonds which are flexible immediately after bonding and which after curing have excellent heat stability and resistance to hydrolytic and chemical attack.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: March 12, 1991
    Assignee: Bostik, Inc.
    Inventors: Heinz G. Gilch, Karl-Heinz Albert
  • Patent number: 4957959
    Abstract: Prepolymer composition which comprises 10 to 95% by weight of a first isocyanate-group-containing prepolymer (A) obtained by reacting an excess equivalent of an aromatic diisocyanate (c) containing an isocyanate group directly bonded to the aromatic nucleus with an oxyethylene-group-containing polyoxyalkylene polyol (a) of a relatively high molecular weight; 90 to 5% by weight of a second isocyanate-group-containing prepolymer (B) obtained by reacting an excess equivalent of an organic diisocyanate (d) not containing an isocyanate group directly bonded to the aromatic nucleus with an oxyethylene-group-containing polyoxyalkylene polyol (b) of a relatively high molecular weight; and, as the case may be, an unreacted substance of diisocyanate which has been used in the production of the respective prepolymers (A) and (B), the prepolymer composition containing the isocyanate group in a range of from 3 to 15% by weight, wherein the polyoxyalkylene polyol (a) and the polyoxyalkylene polyol (b) are either same or di
    Type: Grant
    Filed: April 26, 1989
    Date of Patent: September 18, 1990
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Yukio Matsumoto, Nobuaki Kunii
  • Patent number: 4946910
    Abstract: This invention, therefore, relates to the field of polyurethane coatings for use in automobile basecoat/clearcoat systems. In particular, this invention relates to water-dispersible polyurethane resins having polyether sidechains which may be utilized in basecoat compositions as principal resins or grind resins. These polyurethane resins may be laterally stabilized or terminally stabilized. The terminally stabilized resins of this invention are preferably employed as principal resins in basecoat compositions.
    Type: Grant
    Filed: December 22, 1988
    Date of Patent: August 7, 1990
    Assignee: BASF Corporation, Inmont Division
    Inventors: Thomas G. Savino, Thomas C. Balch, Alan L. Steinmetz, Sergio E. Balatin, Nicholas Caiozzo
  • Patent number: 4942212
    Abstract: A polyurethane resin is composed of a polyol component, a polyisocyanate component and optionally, a chain extender component. At least a portion of the polyol component or chain extender component is a siloxane polyol component represented by the following formula (1) and/or formula (2): ##STR1## wherein R means an alkyl group, R' denotes a hydrogen atom or C.sub.1-5 alkyl group, k, l and m stand for 1-250, 0-5 and 0-50 respectively, and n is an integer of 1-3 in the formula (1) and an integer of 2-3 in the formula (2). A thermal recording material containing the polyurethane resin as a heat-resistant layer is also disclosed.
    Type: Grant
    Filed: December 6, 1988
    Date of Patent: July 17, 1990
    Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Colour & Chemicals Mfg. Co., Ltd.
    Inventors: Kazuyuki Hanada, Kohichi Kuroda, Iwao Misaizu, Masashi Kashimura, Tomoko Goto, Katsumi Kuriyama
  • Patent number: 4929667
    Abstract: A urethane prepolymer composition is provided comprising (a) a terminal isocyanate group-containing urethane prepolymer derived from a polytetramethylene glycol having a specific molecular weight of 700 to 1500 and an aliphatic and/or alicyclic diisocyanate and (b) a terminal isocyanate group-containing urethane prepolymer derived from a polycaprolactone diol and/or polyol having a specific molecular weight of 500 to 1500 and an aliphatic and/or alicyclic diisocyanate, the weight ratio of (a) to (b) being in the range of 80/20 to 20/80. This composition has excellent compatibility with a diol compound and/or a polyol compound, and can be formulated together with the diol compound and/or the polyol compound into a polyurethane coating composition system which forms a coating film having not only excellent weathering resistance, elastic recovery and transparency but also excellent low-temperature physical properties such as mechanical strength, flexibility and impact resistance at low temperatures, e.g., -30.
    Type: Grant
    Filed: February 1, 1989
    Date of Patent: May 29, 1990
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kazuki Ban, Norio Oyabu
  • Patent number: 4920173
    Abstract: PUR powder paints with matt surfaces that level well after baking are obtained when polymers containing hydroxyl groups with more than 2 OH groups in the molecule are reacted with blocked polyisocyanate-urea adducts of polyisocyanates and polyamines with an NCO content of 8 to 15 wt. % and a free NCO content of up to 4 wt. %.
    Type: Grant
    Filed: September 15, 1988
    Date of Patent: April 24, 1990
    Assignee: Huels Aktiengesellschaft
    Inventor: Rainer Gras
  • Patent number: 4889915
    Abstract: High green strength curable urethane adhesive compositions of a polyol, an organic isocyanate compound, a thermoplastic polyurethane which is soluble in methyl ethyl ketone to at least 1 weight percent for imparting tack and green strength properties to the composition, and, optionally, a solvent for controlling the percent solids and viscosity of the composition.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: December 26, 1989
    Assignee: CasChem, Inc.
    Inventors: Melvin Brauer, Clayton C. Crawford
  • Patent number: 4885348
    Abstract: A dispersion in an aromatic polyisocyanate of a reaction product of the polyisocyanate and an amine having the formula: ##STR1## wherein Q represents hydrogen or hydrocarbyl and R represents a hydrocarbyl radical selected from radicals of the formulae: ##STR2## or wherein R and Q together with the attached nitrogen atom form a piperidine, morpholine or pyrolidine ring bearing a hydrocarbyl radical on at least one of the carbon atoms adjacent to the nitrogen atom.
    Type: Grant
    Filed: August 19, 1988
    Date of Patent: December 5, 1989
    Assignee: Imperial Chemical Industries PLC
    Inventors: James P. Brown, Ernst O. Duber, Mark Loenders
  • Patent number: 4882408
    Abstract: One-component polyurethane systems contain reaction products prepared in situ from(A) monoamines and/or polyamines and/or polymeric substances having one or more amino groups and(B) mono- and/or polyisocyanates and/or polymeric substances having one or more isocyanate groupsas viscosity-regulating substances.
    Type: Grant
    Filed: July 11, 1988
    Date of Patent: November 21, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Rainer Blum
  • Patent number: 4829123
    Abstract: An drying resin composition comprises (A) at least one radical curable resin selected from the group consisting of an unsaturated polyester resin, an urethane-acrylic resin, a polyester-acrylic resin and an epoxy-acrylic resin, (B) an urethane-acrylic oligomer having 1.0 to 10.0 mmole/g of allyl ether groups and 0.2 to 5 mmole/g of (meth)acryloyl groups, (C) and ethylenically unsaturated monomer and (D) an initiator. The composition has an improved drying property and provides a coating film having improved flexibility, weatherability and water resistance.
    Type: Grant
    Filed: June 22, 1988
    Date of Patent: May 9, 1989
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Sadao Shigematsu, Mamoru Akiyama
  • Patent number: 4806598
    Abstract: A stable, nonreactive, thermoplastic polymer blend comprising from about 10 to about 95 percent by weight of a superabsorbent, thermoplastic polymeric composition and from about 90 to about 5 percent by weight of at least one thermoplastic polymer.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: February 21, 1989
    Assignee: Kimberly-Clark Corporation
    Inventor: Michael T. Morman
  • Patent number: 4798876
    Abstract: Water absorptive polyurethane composition, having high mechanical strength, is formed of A. about 25% to about 75% of a hydrophilic polyether polyurethane which is the reaction product of diethylene glycol and a polyoxyethylene glycol having a molecular weight of about 1000 to about 8000 with a polyisocyanate and B. about 75% to about 25% of a hydrophobic polyester polyurethane which is the reaction product of a polyfunctional polyester derived from the condensation of a polyol with a polybasic acid with a polyisocyanate.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: January 17, 1989
    Assignee: Tyndale Plains-Hunter Ltd.
    Inventors: Francis E. Gould, Ellen K. Morgan, Stephen D. Reduker