Abstract: Disclosed herein is a method of preparing a polycarbonate composition comprising melt blending a first polycarbonate prepared by interfacial polymerization and having hydroxy end groups that are capped with endcapping groups, with a second polycarbonate prepared by melt polymerization and having hydroxy end groups that are capped with endcapping groups, wherein the second polycarbonate has a lower mole percent of endcapping groups than that of the first polycarbonate; wherein an article having a thickness of 3.2 mm and molded from the polycarbonate composition has a haze of less than 3 according to ASTM D1003-00; and wherein a flat article molded from the polycarbonate composition has a surface charge of ?2 to +2 kV. A polycarbonate composition and complex article prepared according to the method are also disclosed.

Abstract: Processes for preparing polyestercarbonates are disclosed. The processes allow for the consistent incorporation of adipic acid into a polymer generated from a dihydroxy compound, such as bisphenol-A, at levels greater than 99%. The polyestercarbonates so produced, as well as articles formed from the polyestercarbonates, are also disclosed herein.

Abstract: A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.

Abstract: Embodiments of the present invention provide various multipolymers and permselective membranes for use with biosensors and other implantable medical devices and prostheses. Embodiments of the present invention may provide structural strength and integrity, and further may control the influx of glucose, oxygen and/or water. Embodiments of the present invention may, for example, minimize or reduce the influx of glucose by minimizing the percentage of hydrophilic segments, which in turn minimizes the percentage of water uptake and the degree of glucose transport.

Abstract: The present invention relates to a miscible transparent polymer blend, specifically, a polycarbonate blend which comprises homopolycarbonates and/or copolycarbonates. In particular, high aspect ratio monomers confer unique miscibility properties on polycarbonates. Miscible, transparent blends have been found to form from polycarbonate mixtures containing as components of the mixture (1) polycarbonates of bisphenol A monomers copolymerized with a variety of bisphenols, and (2) polycarbonates containing high aspect ratio monomers.

Abstract: The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.

Abstract: A method for producing a PC copolymer with improved productivity is provided. The PC copolymer has a specific structure and the method uses a diester diol-containing monomer as a raw material. The polycarbonate copolymer is produced by reacting a diester diol-containing monomer, a divalent phenol, and a carbonate precursor by interfacial polymerization, wherein the diester diol-containing monomer is a product of reaction between a hydroxybenzoic acid or an esterified product thereof and a polyalkylene glycol, wherein the esterification degree of hydroxyl groups of the polyalkylene glycol is 50 to 90 mol %.

Abstract: A method for producing a high quality aromatic polycarbonate, which comprises subjecting to molten state polymerization a mixture of an aromatic dihydroxy compound and a diaryl carbonate in the presence of a catalyst, the mixture of the aromatic dihydroxy compound and the diaryl carbonate being obtained by a mixing step in which an aromatic dihydroxy compound and a catalyst, each being in a solid state and/or a liquid state, are added to a diaryl carbonate in a molten state in the presence of an inert gas, thereby dissolving the aromatic dihydroxy compound and the catalyst in the molten diaryl carbonate.

Abstract: A high-functionality, highly branched or hyperbranched polycarbonate that has a weight average molecular weight of between 3,300 and 150,000, a degree of crosslinking of less than 15%, and a degree of branching ranging from 10% to 99.9%; the polycarbonate being made by a process comprising preparing one or more condensation products (K), and intermolecularly reacting the one or more condensation products (K) to form the polycarbonate.

Abstract: Compositions including poly(block-phophonato-esters) or poly(block-phosphonato-carbonate) and a process for making them from oligomeric phosphonates and/or polyphosphonates and polyester and/or polycarbonates are disclosed. The compositions provide tough flame retardant materials and coatings.

Abstract: Polymers, compositions, and medical devices useful for delivering (e.g., by local and/or sustained delivery) a haloacetate (e.g., dichoroacetate) to a tissue are disclosed herein. Such methods can be useful for treatment of diseases such as cancer.

Abstract: A blend of a first polycarbonate polymer comprising at least about 85% dimethyl bisphenol cyclohexane (DMBPC) units with a second polycarbonate polymer is disclosed. The blend has a combination of high scratch resistance and good ductility.

Abstract: A thermoplastic composition comprises a sulfonate end-capped polycarbonate of formula: Z-S(O)2—O-(-L-)m-O—S(O)2-Z wherein each Z is independently an alkyl or aryl group, wherein -(-L-)m- is a polycarbonate linking group with m units of linking unit L, and wherein m is at least one. Methods of making the sulfonate end-capped polycarbonate and thermoplastic composition, and articles prepared therefrom, are also disclosed.

Abstract: This invention relates to thermoplastic elastomer compositions comprising blends of polyether ester elastomers and crosslinkable poly(meth)acrylate rubbers, and the manufacture and use thereof in, for example, shaped or molded rubber articles.

Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.

Abstract: A polycarbonate copolymer comprising 90 to 100 mol % of units derived from a cyclohexylidene bisphenol of the formula wherein Ra? and Rb? are each independently C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4; 2 to 35 wt % of units derived from a polysiloxane diol of the formulas or a combination thereof, wherein Ar is a substituted or unsubstituted C6-36 arylene group, each R is the same or different C1-13 monovalent organic group, each R6 is the same or different divalent C1-C30 organic group, and E is an integer from 2 to 100; and 0 to 10 mol % of units derived from a dihydroxy aromatic compound of formula (3) wherein Ra and Rb are each independently halogen, p and q are each independently integers of 0 to 4, and the dihydroxy aromatic compound of formula (3) is not the same as the cyclohexy

Abstract: High-functionality, highly branched or hyperbranched polycarbonates based on dialkyl or diaryl carbonates or phosgene, diphosgene or triphosgene and on aliphatic, aliphatic/aromatic, and aromatic diol or polyols, and their use for producing paint systems.

Abstract: A polymer blend consisting essentially of at least one thermoplastic polymer, and a polymer comprising structural units derived from a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine is disclosed.

Abstract: The present invention relates to a miscible transparent polymer blend, specifically, a polycarbonate blend which comprises homopolycarbonates and/or copolycarbonates. In particular, high aspect ratio monomers confer unique miscibility properties on polycarbonates. Miscible, transparent blends have been found to form from polycarbonate mixtures containing as components of the mixture (1) polycarbonates of bisphenol A monomers copolymerized with a variety of bisphenols, and (2) polycarbonates containing high aspect ratio monomers.

Abstract: The present invention relates to a curable thermoplastic elastomeric composition based on a polytrimethylene ether ester elastomer and a crosslinkable poly(meth)acrylate rubber system; and a melt processible thermoplastic elastomeric compositions based on a continuous phase comprising of a polytrimethylene ether ester elastomer and a disperse phase of a crosslinked poly(meth)acrylate rubber. A process for manufacturing such a melt processible thermoplastic elastomeric composition, and a shaped article (e.g. an extruded or molded article) made thereform, are also disclosed.

Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These elastomer compositions comprise reaction products of polyisocyanates and telechelic polymers having isocyanate-reactive end-groups such as hydroxyl groups and/or amine groups. These elastomer compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.

Abstract: A biocompatible multipolymer, having a backbone comprising about 10 to 45 wt % of at least one hard segment and about 55 to 90 wt % of soft segments. The soft segments are divided into three groups, 5 to 25 wt %, of total soft segment weight, of an oxygen permeable soft segment; 5 to 25 wt %, of total soft segment weight, of a hydrophilic soft segment; and 50 to 90 wt %, of total soft segment weight, of a biostable, relatively hydrophobic soft segment.

Abstract: The invention relates to novel absorbable polyesters, produced by ring-opening polymerisation of hydroxycarboxylic acids in the presence of a polyol containing an electrolyte, in an extruder. In particular, the invention relates to novel polylactide glycolide polyesters which are essentially free of dextran sulphate and which are produced by ring-opening polymerisation of lactide and glycolide in the presence of dextran sulphate in the extruder; to the production of the same and to their use in depot medicaments.

Abstract: A regenerated resin composition comprising (I) a molded article pulverized material (Component A) that satisfies conditions (1) that the molded article pulverized material is a pulverized material of a molded article having an aromatic polycarbonate resin content of 30 to 98% by weight, (2) that the pulverized material has a viscosity average molecular weight of 17,000 to 30,000, and (3) that the pulverized material has a wet heat retention ratio of at least 60%, and (II) an aromatic polycarbonate resin (Component B). According to the present invention, there is provided a regenerated resin composition that comprises a pulverized material from a molded article made of an aromatic polycarbonate resin and that is excellent in the property of retaining physical properties for a long period of time and excellent in mechanical strength.

Abstract: A fluorescent article is disclosed comprising a polymer matrix comprising a polymer having in its backbone repeating units of a U.V. light absorbing moiety, or a moiety capable of being transformed by photo-Fries rearrangement into a U.V. light absorbing moiety, the matrix further comprising a fluorescent dye. The matrix affords surprisingly improved fluorescence protection as compared to prior fluorescent articles having only U.V. light absorbing additives.

Abstract: The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as ?-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.

Abstract: The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as ?-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.

Abstract: A coil coating composition producing a coil coating with excellent properties at a lower peak metal temperature includes (a) a first, branched polyester prepared by condensation of a polyol component consisting essentially of a flexibilizing diol, 2-methyl-1,3-propanediol, and a polyol having at least three hydroxyl groups and an acid component consisting essentially of isophthalic acid; (b) a second, essentially linear polyester prepared by condensation of a polyol component consisting essentially of a flexibilizing diol and 2-methyl-1,3-propanediol and an acid component consisting essentially of isophthalic acid; and (c) a crosslinking agent.

Abstract: A polycarbonate composition excellent in both antistatic property and coloring matter coatability containing (a) a polycarbonate obtained by an ester exchange process, and (b) a compound having a molecular weight of from 300 to 8,000 and having any of ester bond, carbonate bond, amide bond and urethane bond in its molecule and an aromatic hydrocarbon group substituted by at least one alkyl group at the molecular end thereof, a write once read many optical disc substrate and a write once read many optical disc using the same and a process for the production of a write once read many optical disc are described.

Abstract: A thermoplastic molding composition comprising polycarbonate and 50 ppm to 300 ppm, in relation to the weight of the composition, of diphenyl carbonate is disclosed. The composition is especially suitable for the preparation of extruded sheets, in particular coextruded.

Abstract: A low VOC clear coat composition which comprises an epoxy compound, a melamine component and an aliphatic polyisocyanate having an average of 2 to 6 isocyanate functionalities, and optionally contains a catalyst (e.g., organotin catalysts, acid catalysts and combinations); a polyhydroxyl functional compound (e.g., polycarbonate polyol); or other additives (e.g., light absorbers and light stabilizers). Also disclosed is an article coated with the clear coat composition, a process of making the composition, and a process of applying the composition to, for example, an automobile body.

Abstract: Copolymers of polycarbonates or polyarylates with polyether polymers such as polyethersulfones, polyetherketones, and polyetherimides are prepared by reaction of the polyether polymer-forming reagents, e.g., bisphenol A disodium salt and bis(4-chlorophenyl) sulfone, in the presence of the polycarbonate or polyarylate. The reaction may take place in a dipolar aprotic solvent, or in a water-immiscible aromatic solvent in the presence of a phase transfer catalyst, preferably a hexaalkylguanidinium halide. Hydroxy-terminated polyether oligomers may be produced from the copolymers by saponification of carbonate or ester groups.

Abstract: Thermally stable block copolyestercarbonates comprising chain members derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polyester chain segments, are prepared by a method comprising the steps of: (a) preparing a hydroxy-terminated polyester intermediate comprising structural units derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety; and (b) conducting a reaction of the polyester intermediate with phosgene in a reaction mixture comprising water, a substantially water-immiscible organic solvent, and a base, wherein base and phosgene are added simultaneously to the reaction mixture at a substantially constant molar ratio of base to phosgene for a time period of at least about 60% of the total amount of phosgene added.

Abstract: In the present invention, a retardation film is produced by adjusting the mixing ratio of at least two kinds of mutually compatible polymers A and B and by forming the resulting mixture into the film. The polymers A and B are copolymers comprising respective two common repeating units and different in copolymerization composition. According to the present invention, the retardation film having the desired wavelength dispersion can industrially and simply be produced. Furthermore, there can be provided the high-quality retardation film capable of controlling the wavelength dispersion of the retardation at a high level.

Abstract: Polyamide elastomer comprising a hard segment derived from polyamide having no divalent aromatic group and a soft segment derived from polycarbonate diol having no divalent aromatic group has high flexibility and high heat resistance in addition to good physical characteristics of the known polyamide elastomers.

Abstract: A method of preparing block copolymers by solid state polymerization is described. A mixture of a partially crystalline polycarbonate having activated terminal aryloxy groups, for example terminal methyl salicyl groups, when heated together with an oligomeric polyester having reactive terminal hydroxy groups under solid state polymerization conditions affords block copolymers. The activated terminal aryloxy groups play a key role in preserving the block lengths of the starting materials. A control sample in which the partially crystalline polycarbonate lacks activated terminal aryloxy groups, for example polycarbonates substituted by phenol, affords a much lower molecular weight, more highly randomized copolymer product. The product block copolymers are useful as “weatherable” plastic materials.

Abstract: A thermoplastic molding composition suitable for making articles having good combination of properties is disclosed. The composition contains (A) a copolycarbonate derived from compounds of formula (I) wherein R1 to R4 independently of one another represent H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and compounds of formula (II) wherein R5 to R8 independently of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene, and (B) a homopolycarbonate derived from bisphenol A. The composition that features resistance to stress cracking and good low-temperature properties is suitable for automotive construction and exterior applications.

Abstract: A thermoplastic molding composition that features improved low-temperature properties and is thus suitable for application in exterior automotive parts is disclosed. The composition contains (A) 80 to 60 percent of a copolycarbonate wherein 65 to 75 mole percent of its structural units are derived from compounds of formula (I) wherein R1, R2, R3 and R4 independently of one another represents H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and wherein 25 to 35 mole percent of its structural units are derived from compounds of formula (II) where R5, R6, R7 and R8 independently one of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene and (B) 20 to 40 percent of a homopolycarbonate of bisphenol A having a melt flow rate, determined in accordance with ASTM D-1238 under 1.2 kg loading at 300° C. of 3 to 12 gm/10 minutes.

Abstract: A bioabsorbable material such as a terpolymer of poly-(L-lactide/D-lactide/glycolide). The material may consist of 85 molar percent L-lactide, 5 molar percent D-lactide, and 10 molar percent glycolide. The material may have a heat of fusion of about 15-25 J/G, tensile strength retention at 26 weeks of incubation of at least about 50%, and tensile strength retention at 52 weeks of incubation of at most about 25%. The material may be used in implantable devices such as bone fixation devices.

Abstract: Solid particles containing 10 to 90 parts by weight of a dihydroxy compound and 10 to 90 parts by weight of a carbonic acid ester are disclosed. Also disclosed is a process for the production of these particles, an apparatus suitable for the process and a method for their use in production of polycarbonate by transesterification of carbonic acid esters with dihydroxy compounds.

Abstract: By heating at above the melting point and/or glass transition point of the polycondensate and adding an aromatic dicyanate; or adding a mixture comprising an aromatic dicyanate and a polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary aromatic amines; or adding a mixture comprising (i) an aromatic dicyanate, (ii) at least one polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary amines, and (iii) a difunctional epoxide, it is possible to bring about an increase in the molecular weight and/or viscosity of virgin polycondensate and polycondensate recyclates.

Abstract: A thermoplastic composition is described, based on a copolycarbonate which includes at least two structural units. Structure I is usually a conventional carbonate based on bisphenol A, while structure II is a bisphenol carbonate which includes branched or linear groups extending from a bridging carbon atom or carbon group which connects two aromatic rings. The compositions exhibit very good melt flow, along with enhanced shear-thinning behavior. These characteristics are important for optical disc applications. Thus, related articles are described, along with processes for preparing such articles.

Abstract: The present invention provides an article of manufacture having a coating or is otherwise surrounded in large measure by a second polymer which has non-blocking characteristics. In a preferred embodiment, the article possesses a core polymer which has a Tg of less than 25° C. which is coated with or otherwise surrounded by a second polymer which has a Tg of greater than 25° C., but less than 230° C. Further, preferred core polymers have a number average molecular weight of about 3000 to about 100,000. A further feature of the articles of the present invention is that when heated to temperatures of about 100 to 300° C., they undergo an ester exchange reaction to provide a substantially homogeneous polymer product useful in hot melt adhesive applications.

Abstract: The present invention is a polyester resin composition comprising an inorganic filler such as a swellable, lamellar silicate organized by an organizing agent, polyetherimide, and a polymer containing polyethylene naphthalate in a constituent unit thereof, which polymer is preferably a copolymer containing polyethylene terephthalate and polyethylene naphthalate as copolymerized components.

Abstract: This invention relates to polymeric thermoplastic moldable compositions comprising poly(alkylene carbonates), which are useful in manufacturing of articles which may be manipulated and shaped by their user, but regain their shape after distortion. These compositions are free from toxic compounds and have a glass transition temperature from about 15° C. to about 132° C. These compositions are useful in manufacturing of articles such as toys, utensils to convey solids or liquids to the mouth, soothing articles (i.e., teething rings and pacifiers) and articles which support food (i.e., candy/confection sticks or holders.) They are most useful in manufacturing of children's toys and products.

Abstract: A thermoplastic molding composition that features improved low-temperature properties and is thus suitable for application in exterior automotive parts is disclosed.

Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.

Abstract: Block copolymers based on poly(ortho esters) containing amine groups. These block copolymers have both hydrophilic and hydrophobic blocks. They form micelles in aqueous solution, making them suitable for encapsulation or solubilization of hydrophobic or water-insoluble materials; and they also form bioerodible matrices for the sustained release of active agents.

Abstract: A flame-retardant resin composition comprising a phosphazene flame retardant and a polyester resin, wherein the flame retardant is bonded to the molecules of the polyester resin via the ester group thereof, can retain a high flame retardance for a prolonged term with little or no vaporization with time and is excellent in flame retardance, impact resistance, properties and processability.

Abstract: An injection blow-molded disposable tumbler is formed from a polymeric material and includes a fortified upper rim having a thickness greater than the adjacent sidewall. The tumbler may be formed of a variety of resinous materials and exhibits improved toughness and crush resistance as well as aesthetic qualities particularly desired by consumers. In a particularly preferred embodiment, thick-walled polycarbonate tumblers are prepared from hydrolysis-stabilized polycarbonate compositions while minimizing molded-in stress. In still further embodiments, nanocomposites compositions are used to form the containers of the invention.