Abstract: A process is disclosed whereby a polymeric resin (containing ester and/or carbonate bonds) is readily converted into a resin having a modified molecular structure. Accordingly, a polycyclic carbonate (a monomer or oligomer) is transesterified with the polymer resin in the melt, preferably upon extrusion, optionally in the presence of a catalyst. Significantly, the cyclic carbonates are, by the inventive process, inserted into the structure of the polymer, effecting branching of the molecular structure, a branching which manifests itself in the modified properties of the resin.

Abstract: Poly-p-dioxanone is prepared in a process comprising:(a) heating a reaction mixture comprising p-dioxanone and an effective amount of a polymerization catalyst under conditions of temperature and pressure effective to produce a reaction product mixture comprising molten poly-p-dioxanone and unreacted p-dioxanone;(b) adding to said reaction product mixture a cyclic anhydride under conditions effective for reaction of the poly-p-dioxanone with the cyclic anhydride to form an end-capped poly-p-dioxanone;(c) exposing the reaction product mixture to a temperature within the range of about 50 to about 150.degree. C. under reduced pressure and removing unreacted p-dioxanone from the reaction product mixture; and(d) recovering the end-capped poly-p-dioxanone.The invention process permits the economical production of high molecular weight poly-p-dioxanone in the melt.

Abstract: A silicone/polyester adduct comprises between about 5 and about 30 wt % of silicone adducted to between about 70 and about 95% polyester chains formed from polyfunctional acids plus polyfunctional acids and/or anhydrides. At least about 50 mole percent of the polyfunctional acids and/or anhydrides are cycloaliphatic.

Abstract: A process is disclosed whereby a polymeric resin (containing ester and/or carbonate bonds) is readily converted into a resin having a modified molecular structure. Accordingly, a cyclic carbonate (a monomer or oligomer) is transesterified with the polymer resin in the melt, preferably upon extrusion, optionally in the presence of a catalyst. Significantly, the cyclic carbonate which may include any of a variety of functional groups may, by the inventive process, be inserted into the structure of the polymer, effecting a modification to the structure and the properties of the resin. Among the disclosed beneficial modifications thus imparted to the resin are improved thermal stability, altered rheology and optical properties.

Abstract: A single phase, compatiblized blend comprising a polycarbonate resin, a polyester resin, and no more than about 5%, by weight of the combined weight of polycarbonate and polyester, of a liquid crystalline additive as a compatibilizer.

Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.

Abstract: A thermoplastic molding composition comprising an aromatic carbonate polymer and a polyester derived from a cyclohexanedimethanol.

Abstract: The object of the present invention is the production of thermoplastically workable copolymers capable of being composted, characterized in that they consist of partially crystalline soft segments formed from aliphatic esters and also of amorphous hard segments and that the proportion of soft segments amounts to 70% to 95% by weight.

Abstract: Blends can be formed which comprise a flexible coil polymer substrate, e.g., of a poly(alkylene terephthalate), and a thermotropic, essentially liquid crystalline oligomer which comprises aromatic units and at least one linear polyalkylene spacer. These blends can be used to form fibers or molded articles.

Abstract: A release agent comprising a resin containing siloxane segments is described. The resin has been modified with a silane coupling agent containing at least one free isocyanate group and contains one or more hydrolyzable silyl groups in side chains of its molecule.

Abstract: A composition of polyester resins comprising diblock copolymers formed of two different polyester blocks joined by a bifunctional radical deriving from a dianhydride of a tetracarboxylic acid. The compositions are prepared by a reaction in the solid state of two different polyesters in the presence of a dianhydride of a tetracarboxylic acid.

Abstract: The present invention relates to a polymer blend composition for melt molding which is a composition obtained by adding a thickener to a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer, characterized in that the melt viscosity of the composition determined at a molding temperature at a shear rate of 1000 sec.sup.-1 is the same or higher than the melt viscosity of said non-liquid crystal polymer determined under the same conditions.According to the present invention, a polymer blend for melt molding having improved properties, whereby problems observed in prior arts upon molding a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer (for example, insufficient alignment of the liquid crystal polymer and difficulties in extrusion, because of excessively low melt viscosity) can be solved, is obtained.

Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.

Abstract: Disclosed is a polymer blend having excellent clarity and impact strength which is suitable for use in extrusion blow molding processes comprisinga) about 50-95 wt % of a polyester having repeat units from at least 95 mol % terephthalic acid, at least 90 mol % ethylene glycol and up to 10 mol % 1,4-cyclohexanedimethanol, the polyester having a weight average molecular weight of 75,000-85,000,b) about 40-4 wt % of recycled scrap polyester having repeat units from at least 90 mol % terephthalic acid and at least 90 mol % ethylene glycol and having a molecular weight of about 40,000-55,000, andc) about 1-10 wt % of a polymeric material containing at least 90 wt % polycarbonate and up to 10 wt % polyethylene terephthalate.

Abstract: Intimate blends of macrocyclic oligomer compositions, such as cyclic polycarbonate or poly(alkylene dicarboxylate) oligomer mixtures, are blended with linear polymers, especially addition polymers. The blends flow easily and are frequently homogeneous. The macrocyclic oligomers therein may be polymerized to produce resin blends having advantageous properties.

Abstract: A polymer composition containing a thermotropic liquid crystal polymer, polycarbonate and polyester. The polymer compositions are prepared by a two-step melt processing method which produces a unique microscopic morphology and improved toughness properties over conventional LCP blends.

Abstract: Provided are polymers containing methine linkages. Also provided are shaped or formed articles comprised of the light absorbing polymers either alone or admixed with other thermoplastic polymers to form a light absorbing thermoplastic polymer composition.

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: Disclosed is a composition of matter comprising a homogeneous blend of polyester and a polycarbonate of 4,4-isopropylidenediphenol, the composition having a Gardner b value of less than 10 and a Gardner a value of less than 4. The polyester is produced using an organic derivative of tin as catalyst.

Abstract: A method of forming a colored polymer coating on a substrate is disclosed which comprises mixing a reactive polymer, a reactive colorant, and a linking agent, and reacting the linking agent with the reactive polymer and reactive colorant under suitable conditions to form the colored polymer coating. The polymer from which the coating is formed has reactive groups which can react with the linking agent. The reactive colorant has the general formula:R-[polymeric constituent-X].sub.nwherein R is an organic dyestuff radical; the polymeric constituent is selected from polyalkylene oxides and copolymers of alkylene oxides in which the alkylene moiety of the polymeric constituent contains 2 or more carbon atoms; n is an integer from 1 to about 6; and X is a reactive moiety. The linking agent has a reactive group capable of reacting with reactive groups in the polymer and a reactive group capable of reacting with the reactive moiety of the reactive colorant.

Abstract: According to the present invention, a dental adhesive comprising glyceryl mono(meth)acrylate and a polymerizable monomer having at least one olefinic double bond and capable of copolymerizing with said glyceryl mono(meth)acrylate is provided.

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein: the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: Disclosed are clear thermoplastic molding compositions comprising an aromatic polycarbonate, a polyester of terephthalic acid and 1,4-cyclohexanedimethanol, and the copolymeric transesterification product of the polycarbonate and polyester.

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: A polymeric blend comprising a polyester and a polycarbonate, wherein:the polyester contains recurring units having the structure ##STR1## and the polycarbonate contains recurring units having the structure ##STR2##

Abstract: The invention describes a novel process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers). The process is comprised of the steps:(a) the reaction of a dihydroxy-terminated poly(aryl ether) oligomer with a high molecular weight polycarbonate, or a high molecular weight polyarylate, or a high molecular weight poly(arylate-carbonate) to yield a block copolymer; followed by(b) the coupling of the material obtained in step (a) to the required molecular weight, using a diaryl ester of carbonic acid or of a dicarboxylic acid.Both steps are performed in the presence of a catalyst. The copolymerizations can be run in bulk under vacuum in a single or twin screw extruder. Using the above conditions high molecular weight, high quality block copolymers having a combination of excellent properties are obtained in a matter of minutes.

Abstract: The invention describes a novel process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers). The process is comprised of the steps:(a) the reaction of a dihydroxy-terminated poly(aryl ether) oligomer with a high molecular weight polycarbonate, or a high molecular weight polyarylate, or a high molecular weight poly(arylate-carbonate) to yield a block copolymer; followed by(b) the coupling of the material obtained in step (a) to the required molecular weight, using a diaryl ester of carbonic acid or of a dicarboxylic acid.Both steps are performed in the presence of a catalyst. The copolymerizations can be run in bulk under vacuum in a single or twin screw extruder. Using the above conditions high molecular weight, high quality block copolymers having a combination of excellent properties are obtained in a matter of minutes.

Abstract: A process for the preparation of poly(aryl ether) block copolymers with polycarbonates and/or polyarylates comprising the steps ofa) reacting a hydroxy-terminated poly(aryl ether) with a high molecular weight aromatic polycarbonate, or a high molecular weight polyarylate, or a high molecular weight poly(arylatecarbonate) to yield a block copolymer; followed byb) coupling the material obtained in step a) under poly(aryl ether) forming conditions via the hydroxyl/activated dihalobenzenoid compound, or the hydroxyl/activated dinitrobenzenoid compound polycondensation processis described.The polymerization is preferably performed in an integrated manner starting with the poly(aryl ether)-forming monomers and using a polar aprotic solvent. Materials with an overall excellent combination of properties are obtained.

Abstract: In accordance with the present invention, there are provided polyester carbonate copolymers obtained by polymerization of a mixture of 20-80% by weight of an alkylene terephthalate oligomer [I] containing ethylene terephthalate as main structural units and having an intrinsic viscosity [.eta.], as measured at 25.degree. C. in o-chlorophenol, of less than 0.6 dl/g, and 20-80% by weight of a carbonate oligomer [II] containing 2,2-bis(4 -hydroxyphenyl)propane as main structural units and having an intrinsic viscosity [.eta.], as measured at 25.degree. C. in o-chlorophenol, of less than 0.6 dl/g, said copolymers having an intrinsic viscosity [.eta.], as measured at 25.degree. C. in o-chlorophenol, of 0.4-1.2 dl/g and a glass transition temperature (Tg) of 80.degree.-140.degree. C. with a single peak, and polyester resin compositions containing said copolymers, said resin composition being excellent in transparency, heat resistance and mechanical strength.

Abstract: Polycarbonate and polyarylate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein each R independently represents one of hydrogen or lower alkyl. The resins are reactive polycarbonates, poly(ester carbonates) and polyarylates, useful as intermediates in the preparation of block and graft copolymers, with other polymers having functional, reactive groups.

Abstract: Disclosed are blends of (a) an aromatic brominated polycarbonate; and (b) a polyphthalatecarbonate. Preferably, the blends also contain an amount of a silicone-polyimide. The blends exhibit good flame resistance and low smoke generation.

Abstract: A polyphthalatecarbonate/polycarbonate blend exhibits improved resistance to hazing and yellowing from prolonged exposure to ultraviolet radiation. The blend is useful in the production of transparent, ultraviolet radiation stable sheets and films.

Abstract: Disclosed are compositions of matter characterized by having a tensile strength of at least 13,000 psi and moldable at temperatures below 285.degree. C. comprising a blend of(a) about 10-95 weight % of a polyester containing repeating units from trans-4,4'-stilbenedicarboxylic acid 1,6-hexanediol, and(b) about 90-5 weight % of a polycarbonate of 4,4'-isopropylidenediphenol.

Abstract: Disclosed are compositions of matter characterized by having improved tensile strength comprising a blend of(a) about 30-95 weight % of a polyester containing repeating units from biphenyldicarboxylic acid 1,6-hexanediol, and(b) about 70-5 weight % of a polycarbonate of 4,4'-isopropylidenediphenol.

Abstract: Disclosed is a thermoplastic blend of a (1) polycarbonate and (2) a polyester-ether derived from 1,4-cyclohexanedicarboxylic acid, 1,4-cyclohexanedimethanol, poly(oxytetramethylene) glycol and, optionally, a polyfunctional compound. The blends possess a unique combination of properties, some of which are characteristic of compatible blends and others which are characteristic of incompatible blends.

Abstract: A clear polymer blend comprising:(1) 50-90 wt. % of a glycol copolyester having repeat units from 1,4-cyclohexanedimethanol, terephthalic acid and an alkylene glycol;(2) 45-5 wt. % of a polycarbonate resin; and(3) 5-45 wt. % of an aromatic polyester having repeat units from terephthalic acid, isophthalic acid and Bisphenol A.

Abstract: A transparent, heat resistant polyester composition having improved mechanical strength is provided, which comprises (A) 20 to 80% by weight of a polyalkylene terephthalate predominantly comprising ethylene terephthalate and having an intrinsic viscosity of from 0.6 to 1.2 dl/g, and (B) 20 to 80% by weight of a bisphenol-A polycarbonate having an intrinsic viscosity of from 0.6 to 1.2 dl/g, the composition having an intrinsic viscosity of from 0.6 to 1.2 dl/g and a single glass transition temperature of from 80.degree. to 130.degree. C. A polyester laminate may be molded as comprising a layer of the polyester composition and a layer of alkylene terephthalate. The molded polyester laminate can take any form including films and containers.

Abstract: Novel acid-functional poly(alkylene carbonate) polyahls and their salts having surfactant activities are disclosed. These polyahls have, on the average, at least about 0.05 and up to about and including one hydrophilic terminus per molecule and can be produced by the reaction of a random non-ionic poly(alkylene carbonate) polyahl obtained by reacting a monofunctional alcohol, mercaptan, carboxylic acid, primary or secondary amine, alkyl substituted phenol or alkoxylates thereof with an alkylene carbonate and/or an alkylene oxide and/or carbon dioxide and/or a poly(alkylene carbonate) polyahl, and admixing a compound capable of adding an acidic end group thereto. Novel anionic poly(alkylene carbonate) polyahls are also disclosed. Surfactant compositions comprising the acid-functional polyahls of the invention and other non-ionic surfactants are also disclosed. Moreover, surfactant compositions comprising the novel acid-functional polyahls and other anionic surfactants are also disclosed.

Abstract: A polycarbonate resin composition which comprises(i) bisphenol type aromatic polycarbonate, in admixture with(ii) 5 to 200 parts by weight of a polyester type copolymer, per 100 parts by weight of said bisphenol type aromatic polycarbonate, which is produced by adding(a) 5 to 100 parts by weight of bisphenol type aromatic polycarbonate having a viscosity-average molecular weight of not less than 5,000,to (b) 100 parts by weight of a polyester precursor having a number-average polymerization degree of 1 to 30 which is obtained from bifunctional carboxylic acid mainly composed of terephthalic acid or a derivative thereof having an ester forming ability and a diol component, and effecting polycondensation,which provides an improved fluidity and solvent cracking resistance without remarkably decreasing of the original impact resistance and transparency of polycarbonate, to eliminate the defects of polycarbonate.

Abstract: Thermoplastic copolyester-carbonate resins are described, having included in their polymer chains, a moiety of the formula: ##STR1## wherein a and b are each whole number integers of from 0 to 1; and the sum of a+b is 1.The resins are useful intermediates for branched or cross-linked molding compositions.

Abstract: A method for the preparation of polycarbonate resins bearing terminal ester groups comprises the interfacial polymerization of a dihydric phenol with a carbonyl halide in the presence of a molecular weight controlling proportion of a compound of the formula: ##STR1## wherein R represents a hydrocarbyl group amenable to beta-elimination upon thermolytic degradation. The product resins are useful as intermediates in the preparation of copolymers with, for example, polyamides.

Abstract: Novel thermoplastic elastomeric molding compositions having excellent physical properties, which comprise a blend of a polyetherimide ester elastomer and a polycarbonate resin.

Abstract: Modified poly(alkylene carbonate) polyahls comprising the residue of at least one polyahl, at least one modifier, poly(alkyleneoxy) units, poly(alkylene carbonate) units, and a plurality of active hydrogen end groups are disclosed. The modifed polyahls have an average molecular weight higher than any known polyahls containing at least the same weight percent modifier and the same poly(alkyleneoxy) and poly(alkylene carbonate) residues. Also disclosed are isocyanate-functional prepolymer compositions of these modified poly(alkylene carbonate) polyahls, which contain the residue of at least one modified poly(alkylene carbonate) polyahl of this invention and excess organic polyisocyanate units. Urethane/urea polymers formed by the reactions of the isocyanate-functional prepolymers with polyahls are also disclosed.

Abstract: Polyalkylene terephthalates which contain small quantities of aliphatic polycarbonate show improved fracture behavior, without a significant adverse effect on the strength and the flowability in the melt. Moreover, the compositions show improved behavior in hot-air ageing.

Abstract: Novel acid-functional poly(alkylene carbonate) polyahls and their salts having surfactant activities are disclosed. These polyahls have, on the average, at least about 0.05 and up to about and including one hydrophilic terminus per molecule and can be produced by the reaction of a random non-ionic poly(alkylene carbonate) polyahl obtained by reacting a monofunctional alcohol, mercaptan, carboxylic acid, primary or secondary amine, alkyl substituted phenol or alkoxylates thereof with an alkylene carbonate and/or an alkylene oxide and/or carbon dioxide and/or a poly(alkylene carbonate) polyahl, and admixing a compound capable of adding an acidic end group thereto. Novel anionic poly(alkylene carbonate) polyahls are also disclosed. Surfactant compositions comprising the acid-functional polyahls of the invention and other non-ionic surfactants are also disclosed. Moreover, surfactant compositions comprising the novel acid-functional polyahls and other anionic surfactants are also disclosed.

Abstract: Novel self-reinforced polymer composites of a base polymer with a melt processable liquid crystal polymer are prepared according to this invention. The base polymer is a flexible chain polymer, e.g. a conventional thermoplastic. Polycarbonate is a particularly suitable base polymer. The liquid crystal polymer is melt processable, that is, it has a melting point and exhibits anisotropic properties in the melt phase. Wholly aromatic copolyesters are particularly suitable. Mixing is carried out at a temperature at which both the base polymer and the liquid crystal are melt processable, i.e., at a temperature at which the base polymer flows readily and the liquid crystal polymer is above its melting point. The products of this invention comprise about 2 to 20 percent by weight of liquid crystal polymer, which is in the form of essentially unidirectionally oriented continuous fibers primarily in the range of about 1 to 10 micrometers in diameter, distributed in a matrix of the base polymer.