Abstract: Described herein are anionic phenylene oligomers and polymers, and devices including these materials. The oligomers and polymers can be prepared in a convenient and well-controlled manner, and can be used in cation exchange 5 membranes. Also described is the controlled synthesis of anionic phenylene monomers and their use in synthesizing anionic oligomers and polymers, with precise control of the position and number of anionic groups.

Abstract: Provided is a poly(aryl-ether-ketone) (PAEK) powder suitable for use in a method for building objects layer-by-layer by electromagnetic radiation-generated sintering, which is obtained from a thermal pretreatment at a temperature between 260° C. and 290° C. and which has a melting temperature which is stable, at the build temperature, and below or equal to 330° C.

Abstract: A thermoplastic resin composition of the present invention comprises: about 5 wt % to about 35 wt % of a modified polyaryletherketone resin comprising a repeat unit represented by chemical formula 1; about 5 wt % to about 35 wt % of a polyether ether ketone resin; about 20 wt % to about 40 wt % of a polyphenylsulfone resin; and about 15 wt % to about 50 wt % of glass fibers. The thermoplastic resin composition has good properties in terms of adhesion to metals, impact resistance, and so on.

Abstract: Composite materials and structural adhesives containing particles of functionalized polymers as a toughening agent. The particles are composed of functionalized polyaryletherketone (PAEK) polymer or copolymer thereof that contain chemical functional groups capable of reacting with a thermoset resin component to form covalent bonds.

Abstract: A polyaryl ether ether composition(C) and methods of uses thereof are herein disclosed. The composition comprises a polymer blend [blend (B)] consisting of: —a first polyaryl ether ketone (PAEK-1)and —a second polyaryl ether ketone (PAEK-2), wherein the (PAEK-1) is crystalline and exhibits a melting temperature Tm of 330° C. or higher and the (PAEK-2) is either amorphous or crystalline and exhibits a melting temperature Tm of 315° C. or lower and wherein the (PAEK-1) constitutes more than 0% wt of blend (B). Composition (C) can be used in particular for the manufacture of coated metal surfaces, in particular for the coating of wires or of (part of) electronic devices.

Abstract: The present invention provides a method of preparing a polyaryletherketone copolymer (e.g. a random or block copolymer), said method comprising: polymerizing (i) a monomer system suitable for forming aryletherketone units and (ii) a comonomer in a reaction medium comprising: (a) a Lewis acid and (b) a controlling agent comprising an aromatic carboxylic acid, an aromatic sulphonic acid, or a derivative thereof; and polymers produced therefrom.

Abstract: The invention relates to a method for making a lignin component from lignin material by an acid treatment, the method comprising: forming a lignin component of lignin material by treating the lignin material by means of an acid composition in at least one acid treatment stage, and the lignin component is washed and neutralized by a pH-buffer during a filtration after the acid treatment, and pH in pH-buffer is between 4-10. Further, the invention relates to a corresponding lignin component.

Abstract: The present invention relates to polymers and copolymer including a poly(phenylene) structure, as well as a long tether. In some embodiments, the long tether facilitates a reaction between the poly(phenylene) structure and another subunit of a second polymer. In some embodiments, the tether is flexible.

Abstract: A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1) —K—R—??(1) In which K is a bond, oxygen, sulfur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.

Abstract: A process for the manufacturing of a poly(arylether sulfone)polymer comprising reacting in a solvent mixture comprising a polar aprotic solvent and in the presence of an alkali metal carbonate, a monomer mixture which contains: at least one 1,4:3,6-dianhydrohexitol selected from the group consisting of isosorbide (1), isomannide (2) and isoidide (3); at least one dihaloaryl compound of formula (S): X—Ar1—SO2—[Ar2—(T-Ar3)n—SO2]m—Ar4—X??formula (S) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5; X and X?, equal to or different from each other, are halogens selected from F, Cl, Br, I; each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom; optionally, at least one dihydroxyl compound different from the diol (AA); optionally, at least one dihaloaryl compound different from the dihalo (BB); and optionally, at leas

Abstract: Polymer composition (C) comprising a poly(aryl ether ketone) (P1) chosen from polyetheretherketones, polyetherketoneketones and polyetheretherketone-polyetherketoneketone copolymers, a polyphenylsulfone (P2), and a reinforcing fiber (F), with the exception of a polymer composition consisting of 90 wt %, based on the total weight of the polymer composition, of a polymer blend consisting of 85 parts by weight of a polyphenylsulfone and 15 parts by weight of a polyetheretherketone, and 10 wt %, based on the total weight of the polymer composition, of glass fiber.

Abstract: A polymer composition that contains a polyaryletherketone and thermotropic liquid crystalline polymer, which are melt processed in the presence of a flow modifier. The flow modifier is a functional compound that contains one or more hydroxyl functional groups.

Abstract: The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs, such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution.

Abstract: A method for preparing a sol-gel film is disclosed. The method comprises providing a sol-gel composition comprising one or more sol-gel film precursors and a crystallization aid, and processing the sol-gel composition by solution processing to form the sol-gel film. In certain embodiments, the sol-gel film comprises one or more metal oxides. A preferred crystallization aid includes triphenylphosphine oxide. A composition for making a sol-gel film, a sol-gel film, a device including a sol-gel film and a method for making such device are also disclosed.

Abstract: Briefly described, embodiments of this disclosure include articles and methods of making articles.

Abstract: Particles of an amine-functionalized polyaryletherketone polymer or copolymer thereof. The amine-functionalized polyaryletherketone polymer or copolymer thereof is selected from the group consisting of: polyaryletherketone polymer with terminal amine or protected amine functional group(s); polyaryletherketone-imide copoplymer with terminal amine or protected amine functional group(s); and polyaryletherketone-sulphone copolymer with terminal amine or protected amine functional group(s).

Abstract: An inkjet printing method includes providing an inkjet composition, which includes a radiation curable monomer or oligomer, a photo-initiator, and an inhibitor present in an amount sufficient to prevent full curing of the radiation curable monomer or oligomer during an initial exposure to a curing energy. First drops of the inkjet composition are deposited onto a substrate. The curing energy is selected such that it is sufficient to substantially consume the inhibitor. The first drops are exposed to the curing energy, whereby the first drops retain substantially a same surface tension as a liquid drop of the inkjet composition. Second drops of the inkjet composition are deposited adjacent to the first drops. The first and second drops are exposed to the curing energy, whereby the first drops are at least partially cured and the second drops retain substantially the same surface tension as a liquid drop of the inkjet composition.

Abstract: A prosthetic device comprising at least one part consisting of a polymer composition comprising at least one polyarylene (P1) and at least one polyarylether selected from the group consisting of poly(aryl ether ketone)s (P2) and poly(aryl ether sulfone)s (P3).

Abstract: A polymer composition that contains a polyaryletherketone and a liquid crystalline polymer that includes repeating units derived from naphthenic hydroxycarboxylic acids, naphthenic dicarboxylic acids, or a combination thereof in an amount of more than about 15 mol. % of the polymer is provided.

Abstract: An alkaline soluble resin, a process for preparing the same, and a photoresist composition containing the same. The alkaline soluble resin is a polyether chain-containing acrylate alkaline soluble resin. A photoresist composition comprising said alkaline soluble resin can reduce the slope angle of the film layer and prevent gaps which cause light leakage from forming in the junction between the colored film layer and the black matrix. Moreover, the coating and the rubbing effect of the orientation layer can be improved.

Abstract: A photoelectric conversion material, which acts as an electron donor for donating an electron or an electron acceptor for accepting an electron, contains a polymer having at least one structural unit selected from graphenes represented by the following general formulae (1) to (4):

Abstract: A polyaryletherketone polymeric material, for example polyetheretherketone and composite materials comprising said polymeric material are described. The polymeric material has a melt viscosity (MV) in the range 0.05 to 0.12 kNsm?2, preferably in the range 0.085 to 0.095 kNsm?2.

Abstract: A prosthetic device made of a first specific type of polyarylene, taken alone or in combination with a second specific type of polyarylene, featuring some unexpected advantages such as a very high strength and stiffness, good elongation properties, high chemical resistance, good biocompatibility as well as an outstanding impact resistance.

Abstract: The present invention provides high temperature compositions comprising blends of a first polymer, poly(aryl ether ketone phthalazinone)s, and a second polymer, selected from poly(aryl ether ketone)s, poly(aryl ketone)s, poly(ether ether ketone)s, poly(ether ketone ketone)s, or polybenzimidazoles, thermoplastic polyimides, polyetherimides, poly(aryl ether sulfone)s, poly(phenylene sulfide)s, and mixtures thereof. The compositions have improved high temperature characteristics, e.g., improved high temperature load capability and improved high temperature melt processibility.

Abstract: An efficient synthesis of polymer end-caps and poly-p-phenylene oligomers that absorb little water and provide new processing and curing strategies, and more specifically, high-performance resins and adhesives with low moisture uptake can have a two stage cure path with an unprecedented range of curing temperatures.

Abstract: The present invention relates to a process for the production of low-chlorine-content polybiphenyl sulfone polymers, to the polybiphenyl sulfone polymers obtainable in this way, to polybiphenyl sulfone polymers with less than 800 ppm content of organically bonded chlorine, to thermoplastic molding compositions and moldings, fibers, films, membranes, or foams comprising the polybiphenyl sulfone polymers mentioned, and also to their use for the production of moldings, of fibers, of films, of membranes, or of foams.

Abstract: A composition having a crosslinking compound that has the following structure (I) wherein R is OH, NH2, halide, ester, amine, ether, or amide, and x is 2-6 and A is an arene moiety having a molecular weight of less than about 10,000. A mixture including the composition and a polymer, a method for forming the mixture and a crosslinked polymer are also disclosed.

Abstract: Phase separated blends of polyaryl ether ketones, polyaryl ketones, polyether ketones, polyether ether ketones and mixtures thereof with at least one polysulfone etherimide, wherein the polysulfone etherimide has greater than or equal to 50 mole % of the polymer linkages contain at least one aryl sulfone group are described. Such blends have improved load bearing capability at high temperature. In another aspect a high crystallization temperature, especially at fast cooling rates, is achieved.

Abstract: Provided is a photosensitive alkali-soluble resin comprising a compound of formula (I), a method of preparing the same, and a color photosensitive resist containing the same, wherein n1, n2, R1, R2 and R3 are defined as herein. The photosensitive alkali-soluble resin is prepared by: copolymerizing ethylene oxide with ?-hydroxyalkyl phenyl ketone to obtain the first intermediate product, followed by copolymerizing the first intermediate product with a copolymerization product of glycerin acrylate, styrene, and maleic anhydride to obtain the second intermediate product, and oxidizing the second intermediate product to produce the photosensitive alkali-soluble resin.

Abstract: Thermoplastic polymer mixture (M) comprising at least one poly(aryl ether ketone) (P1), at least one poly(arylene sulfide) (P2), and between 0 and 25 wt. % of the total weight of the thermoplastic mixture (M), of a thermoplastic polymer material (P3) consisting of (i) at least one poly(biphenyl ether sulfone) (P3a), and/or (ii) at least one poly(ether imide) (P3b), and/or at least one poly(ether imide sulfone) (P3c), wherein: the combined weight amount of the poly(aryl ether ketone) (P1) and the poly(arylene sulfide) (P2), based on the total weight of the polymer mixture (M), is of at least 30%, and the weight amount of the poly(aryl ether ketone) (P1), based on the combined weight of the poly(aryl ether ketone) (P1) and the poly(arylene sulfide) (P2), is of at most 90%.

Abstract: An intermediate transfer member that includes a crosslinked poly(ether ether ketone) polymer, an optional conductive component, an optional polymer, and an optional release additive.

Abstract: An object of the present invention is to provide an epoxy resin composition that provides, when used for an insulation layer of a multilayer printed wiring board, a multilayer printed wiring board which is excellent in plating adhesion, heat resistance and moisture resistance reliability and capable of forming fine wiring. Another object of the present invention is to provide a resin sheet, a prepreg, a method for producing a multilayer printed wiring board, a multilayer printed wiring board and a semiconductor device. These objects are achieved by an epoxy resin composition comprising (A) an epoxy resin, (B) a phenoxy resin having a specific bisphenol acetophenone structure and (C) a curing agent, wherein the content of the phenoxy resin (B) is 10 to 30% by weight of the total solid content of the resin composition.

Abstract: A resin binder composition for the production of a fiber preform comprising an amount of at least one polyarylether thermoplast resin component and an amount of at least one thermoset resin component in weight ratio 80/20-10/90, in substantial absence of a catalyst which is active at the prevailing preform production temperature, wherein the polyarylether thermoplast has number average molecular weight (Mn) in the range 2,000-20,000, and comprises ether linked phenyl units and ether linked arylsulphone units and reactive end groups, method for producing a fiber preform using the thermally stable binder resin composition, a perform obtained with use of the method and composition, a method for injecting or infusing the preform with curable matrix resin, the curable injected or infused preform resin, a method for curing thereof and a cured composite obtained with the method.

Abstract: The present disclosure provides injectable synthetic and biodegradable polymeric biomaterials that effectively prevent seroma, a common postoperative complication following ablative and reconstructive surgeries. Provided biomaterials include physically crosslinked hydrogels that are thixotropic, display rapid chain relaxation, are easily extruded through narrow gauge needles, biodegrade into inert products, are well tolerated by soft tissues, and effectively prevent seroma in a radical breast mastectomy animal model.

Abstract: Disclosed herein is a process for preparing a linear hydroxyaryloxy-functional polydiorganosiloxanes having controlled structures. The process includes the step of reacting a linear ?,?-bisacyloxypolydiorganosiloxane with at least one bisphenolic compound, or hydroxy-functional oligomer thereof, in such a molar ratio that the phenolic groups in the bisphenolic compound or the hydroxy-functional oligomer thereof to the acyloxy groups in the ?,?-bisacyloxypolydiorganosiloxane is less than 2.0. Also disclosed are hydroxyaryloxy-functional polydiorganosiloxanes produced from the process and the polysiloxane/polyorgano block copolymers made using the hydroxyaryloxy-functional siloxanes.

Abstract: A composition having a crosslinking compound that has the following structure (I) wherein R is OH, NH2, halide, ester, amine, ether, or amide, and x is 2-6 and A is an arene moiety having a molecular weight of less than about 10,000. A mixture including the composition and a polymer, a method for forming the mixture and a crosslinked polymer are also disclosed.

Abstract: Methods are disclosed to prepare elastomeric materials by providing aromatic polymer(s) which is/are non-elastomeric at room temperature; cross-linking the aromatic polymer using a cross-linking compound to form a cross-linked aromatic polymer which is substantially cured; and heating the cross-linked aromatic polymer to a temperature at or above a glass transition temperature of the cross-linked aromatic polymer. Materials formed thereby and end products are also described which may be formed using the aromatic polymer cross-linking techniques to develop strong elastomeric materials for high temperature and/or harsh condition end applications.

Abstract: Thermoplastic polymer particles directly cross-linked together or cross-linked via a separate and independent polymer network to form an inter-penetrating network are disclosed herein, along with methods of manufacturing and use as interleaf tougheners of pre-pregs and composite articles.

Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.

Abstract: The invention provides methods for stably binding and immobilizing deoxyribonucleic acid onto objects and substrates. The method includes exposing the deoxyribonucleic acid to alkaline conditions, and contacting the deoxyribonucleic acid to the object or substrate. The alkaline conditions are produced by mixing the deoxyribonucleic acid with an alkaline solution having a pH of about 9.0 or higher, and contacting the deoxyribonucleic acid to the substrate. The immobilized DNA can be used as a taggant and can be used in combination with other detectable taggants, such as optical reporters. Methods for authentication of a DNA marked object are also provided.

Abstract: A resin having a fluorene structure, a relatively high carbon concentration in the resin, a relatively high heat resistance and a relatively high solvent solubility has a structure represented by wherein each of R3 and R4 independently denotes a benzene ring or a naphthalene ring, a carbon atom at the bridgehead of a fluorene backbone or (di)benzofluorene backbone is bonded with a carbon atom of each of other aromatic rings, and a carbon atom of each of aromatic rings of a fluorene backbone or (di)benzofluorene backbone is bonded with a carbon atom at the bridgehead of other fluorene backbone or (di)benzofluorene backbone. The resin can be applied to a wet process. Methods for producing the resin, for forming an underlayer film useful for forming a novel resist, and for pattern forming using the material, and an underlayer film excellent in heat resistance and etching resistance for multilayer resist are described.

Abstract: A polymer composition that contains at least one high performance polymer and at least one aromatic amide oligomer is provided. The oligomer can serve as a flow aid that lowers the overall viscosity of the polymer matrix under shear.

Abstract: Polymers comprising polyetheretheretherketone and polyetherdiphenyletherketone and polymers comprising polyetheretheretherketone and polyetheretherethersulphone are described which have advantageous Tn and/or Tg properties.

Abstract: An intermediate transfer member that includes a crosslinked poly(ether ether ketone) polymer, an optional conductive component, an optional polymer, and an optional release additive.

Abstract: A process for producing a solution blend of a polybenzimidazole (PBI) and a polyetherketoneketone (PEKK). The PBI is mixed with sulfuric acid at a temperature between 40° C. and 80° C. for 30 minutes to 2 hours to produce a PBI solution then cooled to room temperature to form a cooled PBI solution. Then PEKK is added to the cooled PBI solution to form a mixture and that mixture is stirred from 30 minutes to 2 hours at room temperature to form a stirred mixture. The stirred mixture is poured into an excess of water being stirred swiftly to form an aqueous mixture. The aqueous mixture is filtered to produce a blend. The blend is washed with water and dried. The resulting blend can yield a blend in all proportion from 1/99 PBI/PEKK to 99/1 PBI/PEKK.

Abstract: Disclosed are a multi-block copolymer, its producing method and an electrolyte membrane using the same. The multi-block copolymer includes a hydrophobic block having a plurality of repeating units represented as chemical formula 1; and a hydrophilic block having a plurality of repeating units represented as chemical formula 2. The multi-block copolymer is acidified, and can be used to an electrolyte membrane and a fuel cell. The use of the multi-block copolymer as an electrolyte membrane ensures excellent dimensional stability.

Abstract: Disclosed is a graft polymerization method which has solved problems involved in use of a solvent, a radical initiator and high-energy radiation when a monomer is graft-polymerized on the surface of a polymer base. The graft polymerization method is characterized in that a polymerization product is obtained by immersing a polymer base (i) having a ketone group on the surface into a reaction system containing a monomer (ii) and then irradiating the polymer base (i) with light so that polymerization of the monomer starts from the surface of the polymer base (i).

Abstract: A method and compositions are described which improve extrusion- and creep-resistance of components for use in a high temperature applications including sealing elements and seal connectors among others. The method includes providing a composition having an aromatic polymer and a crosslinking compound, and subjecting the composition to a heat molding process to form the component and crosslink the aromatic polymer.

Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.

Abstract: A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.