Solid Polymer Derived From Ketone Reactant And Wherein None Of The Reactants Forming The Solid Polymer Contains An Aldehyde Group Or Is An Aldehyde-type Reactant Or Polymer Derived Therefrom Patents (Class 525/471)
  • Patent number: 4987171
    Abstract: Poly(ether ketone ketones), which are important engineering resins, are thermally stabilized by being contacted for at least 15 minutes above their glass transition temperature with an organic hydroperoxide containing at least 0.1 mg of active oxygen per gram, having a boiling point above about 130.degree. C., and degradable between 130.degree. C. and the contacting temperature, the hydroperoxide being made from a precursor comprising at least one benzylic or allylic hydrogen in its molecule.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: January 22, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward G. Brugel
  • Patent number: 4980114
    Abstract: Disclosed herein are stretched poly(arylene thioether) block copolymer films and a production processes thereof, said block copolymer film comprising a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 100 parts by weight of at least one other thermoplastic resin, and (C) up to 15 parts by weight of at least one filler.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: December 25, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4977235
    Abstract: Novel polyarylate polymers comprise alternating moieties derived from an aromatic dicarboxylic acid halide, with moieties derived from a hydroxyaryl-substituted 1,6-diaza [4.4] spirodilactam compound and, optionally, with moieties derived from a di(hydroxyphenyl) compound. The polyarylate polymers are thermoplastic polymers characterized by relatively high glass transition temperatures.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: December 11, 1990
    Assignee: Shell Oil Company
    Inventor: Pen-Chung Wang
  • Patent number: 4977224
    Abstract: A process for preparation of a copoly(arylene sulfide) which has a decreased amount of disulfide radicals and corresponds to the structure ##STR1## wherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.45 to 0 and n is at least 50,comprising contacting a copoly(arylene sulfide) corresponding to the structure ##STR2## wherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.50 to 0.001 and n is at least 25,in the melt phase with a diiodoaromatic compound corresponding to the structureI-A-IwhereinA is a divalent substituted or unsubstituted aromatic radical.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: December 11, 1990
    Assignee: Eastman Kodak Company
    Inventors: Joseph J. Watkins, David R. Fagerburg, Paul B. Lawrence, Mark Rule
  • Patent number: 4975470
    Abstract: Blends comprising from about 1 to about 99 percent by weight of a poly(aryl ether ketone co-carbonate) and from about 99 to about 1 percent by weight of a thermoplastic polymer selected from the group of a poly(aryl ether ketone), a poly(arylene sulfide), a poly(ether imide) or a poly(aryl ether).
    Type: Grant
    Filed: June 6, 1989
    Date of Patent: December 4, 1990
    Assignee: Amoco Corporation
    Inventors: Markus Matzner, Barry D. Dean, Donald M. Papuga
  • Patent number: 4975479
    Abstract: Disclosed herein are melt-stable thermoplastic resin compositions comprising (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) --400 parts by weight of at least one of thermoplastic resins, and (C) 0-400 parts by weight of at least one filler per 100 parts by weight of the resin components. At least either one of Component (B) and Component (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of Component (A). The poly(arylene thioether) block copolymer alternately comprise at least one poly(arylene thioether-ketone) block having predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other and at least one poly(arylene thioether) block having predominant recurring units of the formula ##STR2## Also disclosed are compositions obtained by stabilizing by the melt-stable thermoplastic resin compositions with a basic compound and products molded or formed product from these compositions.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: December 4, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4973646
    Abstract: Disclosed are thermosetting, powder coating compositions comprised of semi-crystalline polyesters and .epsilon.-caprolactam-blocked bis(1-cyanato-1-methylethyl) benzene compounds which are readily curable at relatively-mild temperatures and using cure times commonly used to cure (cross-link) powder coatings. When using equivalent curing conditions, the disclosed coating compositions exhibit a higher degree of cross-linking than do combinations of amorphous polyesters and the .epsilon.-caprolactam-blocked bis(1-cyanato-1-methylethyl)-benzene compounds.
    Type: Grant
    Filed: April 9, 1990
    Date of Patent: November 27, 1990
    Assignee: Eastman Kodak Company
    Inventors: Jonathan S. Witzeman, Yeong-Ho Chang
  • Patent number: 4973631
    Abstract: Epoxy resins can be cured or crosslinked with triphenyl phosphine oxide compounds having epoxy-reactive (active hydrogen) substituents either alone or in combination with amine-terminated polyarylene ethers (e.g., amine-terminated polysulfone oligomers or high polymers.
    Type: Grant
    Filed: October 6, 1989
    Date of Patent: November 27, 1990
    Assignee: Virginia Tech Intellectual Properties Inc.
    Inventors: James E. McGrath, Attila Gungor
  • Patent number: 4968758
    Abstract: Novel poly(aryl ether sulfone)-poly(aryl ether ketone) block copolymers are described. They are prepared by the nucleophilic polycondensation of a hydroxy- or halo-terminated poly(aryl ether ketone) oligomer with the poly(aryl ether sulfone) forming reagents; alternatively, a preformed poly(aryl ether sulfone) block may be used.The novel copolymers are tough materials with excellent heat, solvent, and stress-crack resistanced. They display high HDT's (heat distortion temperatures) and are useful in molding, extrusion and composites applications.
    Type: Grant
    Filed: August 22, 1988
    Date of Patent: November 6, 1990
    Assignee: Amoco Corporation
    Inventors: Markus Matzner, James H. Botkin, Paul A. Winslow
  • Patent number: 4962143
    Abstract: Disclosed herein are poly(arylene thioether) block copolymer fibers formed by melt-spinning a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 50 parts by weight of at least one other thermoplastic resin and (C) up to 10 parts by weight of at least one filler.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: October 9, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4962162
    Abstract: The resin composition which contains thermosetting resin as Component (A), a thermoplastic resin as Component (B), and at least one compound selected from the group consisting of an epoxy resin capable of dissolving the thermoplastic resin and a reactive diluent possessing at least one epoxy group as Component (C) in a ratio such that the proportions of Components (A), (B), and (C) fall respectively in the ranges of 30 to 96% by weight, 2 to 50% by weight, and 2 to 49% by weight, based on the total weight of the resin composition. The resin composition is capable of producing a molded article combining the highly satisfactory mechanical and thermal properties of a thermosetting resin and the highly satisfactory toughness of a thermoplastic resin.
    Type: Grant
    Filed: September 30, 1987
    Date of Patent: October 9, 1990
    Assignee: Toho Rayon Co., Ltd.
    Inventors: Hiroyuki Kosuda, Yasuhisa Nagata, Masato Andoh
  • Patent number: 4960555
    Abstract: Disclosed herein are poly(arylene thioether) block copolymer fibers formed by melt-spinning a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 50 parts by weight of at least one other thermoplastic resin and (C) up to 10 parts by weight of at least one filler.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: October 2, 1990
    Assignee: Kureha Kagaku Kogho K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4960806
    Abstract: Disclosed herein are stretched poly(arylene thioether) block copolymer films and production processes thereof, said block copolymer film comprising a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 100 parts by weight of at least one other thermoplastic resin, and (C) up to 15 parts by weight of at least one filler.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: October 2, 1990
    Assignee: Kureha Kagaku Kagyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4959423
    Abstract: Described herein are blends having increased crystallization rates comprising (a) at least 98 percent by weight of a poly(aryl ether ketone) having a melting point no more than about 390.degree. C., and (b) 2 percent by weight or less of another poly(aryl ether ketone) having a melting point higher than about 400.degree. C. The blends retain their attractive crystallization behavior even after prolonged treatment in the melt. The blends of this invention may be fabricated into any desired shape, for example, moldings, coatings, films, fibers, and particularly, for use as electrical insulation for electrical conductors.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: September 25, 1990
    Assignee: Amoco Corporation
    Inventors: James E. Harris, Paul A. Winslow
  • Patent number: 4959424
    Abstract: Described herein are novel amino-terminated poly(aryl ether ketone) oligomers and methods for their production. These amino-terminated poly(aryl ether ketone) oligomers are used as building blocks for a variety of polymers and copolymers.
    Type: Grant
    Filed: July 25, 1986
    Date of Patent: September 25, 1990
    Assignee: Amoco Corporation
    Inventors: Markus Matzner, Donald M. Papuga
  • Patent number: 4957995
    Abstract: A low viscosity epoxy resin, i.e., a low viscosity polyglycidyl derivative, of an aminophenol having at least one alkyl group on its aromatic ring of which viscosity is 15 poises or below as measured at 25.degree. C., a resin composition containing said resin, and a fiberreinforced composite material containing as matrix a cured product of said epoxy resin composition and a fiber as reinforcing material.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: September 18, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuhisa Saito, Katsuya Watanabe, Kohichi Okuno, Kunimasa Kamio, Akira Morii
  • Patent number: 4957962
    Abstract: Fiber composite useful in automotive construction and the aerospace industry are composed of a plastics matrix and reinforcing fibers, this plastics matrix comprising a mixture of from 90 to 40% by weight of polyether sulfone and 10 to 60% by weight of polyether ketone.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: September 18, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Winkler, Peter Ittemann, Gerhard Heinz
  • Patent number: 4942216
    Abstract: Polyaryl ether ketones essentially consist of(A) 55-95 mol % of repeating units of the general formula ##STR1## where s and t are each 0, 1, 2 or 3 and Q and T are each --O-- or --CO--, or their C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 alkoxy, aryl, chlorine or fluorine derivatives substituted in the nucleus, and(B) 5-45 mol % of repeating units of the general formula II ##STR2## where Ar.sup.1, Ar.sup.2, Ar.sup.3, ar.sup.4 and Ar.sup.5 independently of one another are each a phenylene, biphenylene or naphthylene group or a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl, chlorine or fluorine derivative of this group, Q' and T' are each --O--or --CO-- and s' and t' are each 0, 1, 2 or 3, with the proviso that one or more of the groups Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4 and Ar.sup.5 are a biphenylene or naphthylene group or a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl, chlorine or fluorine derivative of such a group and, if Ar.sup.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: July 17, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Heinz, Robert R. Lieder, Juergen Koch
  • Patent number: 4929665
    Abstract: A resin composition comprising (a) 100 parts by weight of a block copolymer composed of polyphenylene sulfide segments and polyphenylene sulfide sulfone segments and (b) 0.01 to 20 parts by weight of at least one compound selected from the group consisting of epoxy resins, maleimide compounds, N,N'-diarylcarbodiimide compounds and organosilane compounds and as required, (c) an organic filler.
    Type: Grant
    Filed: January 19, 1988
    Date of Patent: May 29, 1990
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Toshio Inoue, Takayuki Mine, Hitoshi Izutsu, Toshihide Yamaguchi, Fumihiro Kobata, Juheiji Kawabata
  • Patent number: 4921889
    Abstract: Thermoplastic molding materials contain, as essential components,(A) from 2 to 97.9% by weight of a nylon,(B) from 2 to 97.9% by weight of a polyaryl ether ketone and(C) from 0.1 to 30% by weight of a polymeric component containing hydroxyl groupsand in addition(D) from 0 to 50% by weight of an impact-modifying rubber and(E) from 0 to 60% by weight of fibrous and/or particulate fillers.
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: May 1, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietrich Lausberg, Erhard Seiler
  • Patent number: 4914176
    Abstract: Novel thermoplastic polymers of relatively high glass transition temperatures are characterized by five-carbon moieties having a keto group in the 3-position alternating with bis(benzoheterocyclic) moieties. The polymers are produced by reaction of a keto-C.sub.5 source, selected from 4-oxoheptanedioic acid compounds or a 1,6-dioxa [4.4] spirodilactone, with a bis(ortho-phenylene amine) compound. Further cyclization of the initial polymer product or reaction of a bis(ortho-phenylenediamine) provides a polymer having a hexacyclic repeating unit.
    Type: Grant
    Filed: March 17, 1989
    Date of Patent: April 3, 1990
    Assignee: Shell Oil Company
    Inventor: Pen C. Wang
  • Patent number: 4910289
    Abstract: Described herein are miscible poly(aryl ether ketone) blends possessing increased crystallization rates. The novel compositions contain (a) from about 98 to about 99.9 percent by weight of a miscible poly(aryl ether ketone) blend, and (b) from about 0.1 to about 2 percent by weight of a poly(phenylene sulfide) or a copolymer thereof. The compositions of the instant invention retain their attractive crystallization behavior even after prolonged treatment in the melt. Moreover, these compositions display excellent mechanical properties as well as excellent chemical and heat resistance.
    Type: Grant
    Filed: July 27, 1987
    Date of Patent: March 20, 1990
    Assignee: Amoco Corporation
    Inventor: James E. Harris
  • Patent number: 4908427
    Abstract: A polymer composition containing a polyaryletherketone and a polysulphone, where the polysulphone contains the repeating units--Ph--SO.sub.2 --Ph--Ph--SO.sub.2 --Ph--and--Ar--linked through ether linkages. The polysulphone contains 50 to 75% molar of the units --Ar--, and Ar may contain more than one aromatic group linked by aliphatic hydrocarbon groups, or by --SO--, --SO.sub.2 -- or --CO--.A composition containing a high proportion of the polyaryletherketone shows a reduced shrinkage compared to the polyaryletherketone alone. A composition containing a high proportion of the polysulphone has improved solvent resistance and stress crack resistance compound to the polysulphone alone. The composition can be used for production of film or fibre or for wire coating or may include other additives such as fillers or fibrous reinforcing agents, e.g. glass or carbon fibre.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: March 13, 1990
    Assignee: Imperial Chemical Industries PLC
    Inventor: Shamsedin Rostami
  • Patent number: 4906500
    Abstract: Described herein are blends of a particular poly(aryl ether), a poly(alkylene terephthalate), and a nucleating agent. These blends are suitable for molding into electrical connectors which do not blister when subjected to vapor phase reflow and infrared reflow applications.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: March 6, 1990
    Assignee: Amoco Corporation
    Inventor: Lawrence A. McKenna
  • Patent number: 4900848
    Abstract: A low viscosity epoxy resin, i.e., a low viscosity polyglycidyl derivative, of an aminophenol having at least one alkyl group on its aromatic ring of which viscosity is 15 poises or below as measured at 25.degree. C., a resin composition containing said resin, and a fiber-reinforced composite material containing as matrix a cured product of said epoxy resin composition and a fiber as reinforcing material.
    Type: Grant
    Filed: March 29, 1988
    Date of Patent: February 13, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuhisa Saito, Katsuya Watanabe, Kohichi Okuno, Kunimasa Kamio, Akira Morii, Hiroshi Nakamura
  • Patent number: 4897238
    Abstract: Disclosed herein is a stretched poly(arylene thioether-ketone) film made of a thermoplastic material which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g and a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C., and a reduced viscosity of 0.3-2 dl/g as determined by viscosity measurement at 25.degree. C. and a polymer concentration of 0.5 g/dl in 98 percent by weight sulfuric acid; and optionally, (B) up to 100 parts by weight of at least one of thermoplastic resins and/or up to 15 parts by weight of at least one of fillers. Its production process is also disclosed.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: January 30, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki, Yoshikatsu Satake, Toshiya Mizuno, Yo Iizuka
  • Patent number: 4895913
    Abstract: A wire coating resin composition comprising 25 to 95% by weight of a polyetherketone and 75 to 5% by weight of an aromatic polysulfone, which is characterized by the intrinsic viscosity (y) of the polyetherketone complying with the condition0.83.ltoreq.y.ltoreq.0.01x+0.65,wherein x represents weight percentage of the polyetherketone in the wire coating resin composition.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: January 23, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruo Saito, Kuniaki Asai, Yasurou Suzuki
  • Patent number: 4895924
    Abstract: Disclosed herein are poly(arylene thioetherketone) fibers obtained by melt-spinning a thermoplastic material which comprises 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and optionally, up to 50 parts by weight of at least one of thermoplastic resins. The PTK has predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other, and has a melting point, Tm of 310-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C., and a reduced viscosity of 0.3-2 dl/g as determined by viscosity measurement at 25.degree. C. and a polymer concentration of 0.5 g/dl in 98 percent by weight sulfuric acid. The PTK fibers of this invention have high heat resistance and strength.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: January 23, 1990
    Assignee: Kureha Kagaku Kogyo K. K.
    Inventors: Yoshikatsu Satake, Yo Iizuka, Hiroyuki Endo, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki
  • Patent number: 4895892
    Abstract: Disclosed herein is a melt-stable poly(arylene thioether-ketone) composition, which comprises:(A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C. and a reduced viscosity of 0.2-2 dl/g;(B) 0-400 parts by weight of at least one of thermoplastic resins; and(C) at least one of fibrous fillers and/or at least one of inorganic fillers in a proportion of 0-400 parts by weight per 100 parts by weight of the sum of said components (A) and (B).At least either one of the components (B) or (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of the component (A).
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: January 23, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Takashi Kaneko, Yutaka Kobayashi, Yo Iizuka, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki
  • Patent number: 4895893
    Abstract: Heat-resistant resin composition comprising (A) 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure containing 50% by weight or higher of recurring units of the formula ##STR1## and a logarithmic viscosity number of 0.1 to 1.0 dl/g; (B) from 0.01 to less than 25 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR2## wherein the --CO-- and --S-- are in the para position to each other, and having a melting point of 310.degree.-380.degree. C., a residual melt crystallization enthalpy of at least 10 J/g, a melt crystallization temperature of at least 210.degree. C. and a reduced viscosity of 0.2 to 2 dl/g; and (C) at least one of fibrous fibers and/or at least one of inorganic fillers in a proportion of 0 to 400 parts by weight per 100 parts by weight of the resin component comprising said poly(arylene sulfide) and said poly(arylene thioether-ketone).
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: January 23, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Takashi Kaneko, Yutaka Kobayashi, Yukio Ichikawa, Yo Iizuka, Makoto Fukuda, Toshio Enoki, Takayuki Katto, Yasuo Sakaguchi, Zenya Shiiki
  • Patent number: 4895912
    Abstract: Disclosed herein is a stretched poly(arylene thioether-ketone) film made of a thermoplastic material which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g and a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C., and a reduced viscosity of 0.3-2 dl/g as determined by viscosity measurement at 25.degree. C. and a polymer concentration of 0.5 g/dl in 98 percent by weight sufuric acid; and optionally, (B) up to 100 parts by weight of at least one of thermoplastic resins and/or up to 15 parts by weight of at least one of fillers. Its production process is also disclosed.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: January 23, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Yo Iizuka, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki, Toshiya Mizuno
  • Patent number: 4883845
    Abstract: The invention relates to curable compositions comprising(a) a copolyether resin having end groups --OR.sup.1 linked direct to phenyl nuclei and containing 1 to 50 mol % of repeating structural units of formula I ##STR1## and 99 to 50 mol % of repeating structural units of formula II ##STR2## wherein R.sup.1 is hydrogen, a phenylene radical substituted by amino agroups or ethylenically unsaturated radicals or is a 2,3-epoxypropyl radical, R.sup.2 is a direct C--C bond or a group of formula --C.sub.r H.sub.2r --, --O--, --S--, --CO-- or --SO.sub.2 --, r is 1 to 20, R.sup.3 is hydrogen or methyl, R.sup.4, R.sup.5 and R.sup.7 are inert substituents, m, n and o are each independently 0, 1 or 2, p is 1 or 2, R.sup.6 is a radical of a bisphenol, X and Y are --SO.sub.2 -- or --CO--, and(b) at least one compound of formula VIII, IX or X ##STR3## wherein A forms a maleimidyl, nadicimidyl, allylnadicimidyl or methallylnadicimidyl system, and R.sup.14 and R.sup.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: November 28, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Friedrich Stockinger, Werner Stauffer
  • Patent number: 4883855
    Abstract: The invention relates to copolyether resins having end groups --OR.sup.1 linked direct to phenyl nuclei and containing 1 to 50 mol % of repeating structural units of formula I ##STR1## and 99 to 50 mol % of repeating structural units of formula II ##STR2## wherein R.sup.1 is hydrogen, a phenylene radical substituted by amino groups or ethylenically unsaturated radicals or is a 2,3-epoxypropyl radical, R.sup.2 is a direct C--C bond or a group of formula --C.sub.r H.sub.2r --, --O--, --S--, --CO-- or --SO.sub.2 --, r is 1 to 20, R.sup.3 is hydrogen or methyl, R.sup.4, R.sup.5 and R.sup.7 are inert substituents, m, n and o are each independently 0, 1 or 2, p is 1 or 2, R.sup.6 is a radical of a bisphenol, X and Y are --SO.sub.2 -- or --CO--.The compounds can be used in particular in conjunction with unsaturated imides as matrix resins for the preparation of fibrous composite structures.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: November 28, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Friedrich Stockinger
  • Patent number: 4882397
    Abstract: Described herein is process for preparing polyaryletherketones from a polyketal by converting the polyketal to a polyaryletherketone in the presence of a Group IIA, IIB, IVA, VIIB, IIIA, IVB, IB or VIII metal salt.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: November 21, 1989
    Assignee: Amoco Corporation
    Inventor: Donald R. Kelsey
  • Patent number: 4877850
    Abstract: In one embodiment, a process is provided for treating virgin arylene sulfide resins, wherein a heated polymer slurry, comprising a virgin arylene sulfide resin and water, is contacted by a buffer solution having a pH less than about 9.35 but greater than that necessary to result in at least a partial curing of the virgin arylene sulfide resin. In a further embodiment, a process is provided for treating a virgin arylene sulfide resin, wherein a virgin arylene sulfide resin is slurried in a buffer solution having a pH less than about 9.35 but greater than that necessary to result in at least a partial curing of the virgin arylene sulfide resin. The treating process of this invention is conducted at an elevated temperature, below the melting point of the virgin arylene sulfide resin, while in the substantial absence of a gaseous oxidizing atmosphere. The treated arylene sulfide resins are recovered from the polymer slurry in a manner which does not result in at least a partial curing of the treated resin.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: October 31, 1989
    Assignee: Phillips Petroleum Company
    Inventors: Jon F. Geibel, Afif Nesheiwat
  • Patent number: 4873283
    Abstract: Disclosed herein is a molded or formed poly(arylene thioether-ketone) article made of a thermoplastic material which comprises 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and if desired, up to 100 parts by weight of at least one of thermoplastic resins and/or up to 300 parts by weight of at least one of fibrous fillers and/or least one of inorganic fillers. The PTK has predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other, and has a melting point, Tm of 310.degree.-380.degree. C., a residual melt cyrstallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C., and a reduced viscosity of 0.2-2 dl/g as determined by viscosity measurement at 25.degree. C. and a polymer concentration of 0.5 g/dl in 98 percent by weight sulfuric acid.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: October 10, 1989
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Yo Iizuka, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki
  • Patent number: 4868240
    Abstract: The present invention discloses a polyarylene thioether of high crystallizing rate having a necessary time for 50% crystallization of not more than 50 seconds upon crystallization of a molten polymer at 250.degree. C. as well as a production process therefor.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: September 19, 1989
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yukio Ichikawa, Takayuki Katto, Zenya Shiiki
  • Patent number: 4857607
    Abstract: The invention relates to polycycloacetals of formula I ##STR1## wherein n is an integer from 1 to 500, x and y are each independently of the other 0 or 1, R.sup.1 is a carbon atom or a tetravalent hydrocarbon radical having a molecular weight not greater than 1000 and which can additionally contain ether oxygen atoms or oxygen atoms in hydroxyl, carbonyl or epoxy groups, and R.sup.2 is a tetravalent hydrocarbon radical derived from a dialdehyde or a diketone.The polycycloacetals can be used together with conventional hardeners and/or curing catalysts for epoxy resins for the fabrication of cross-linked (cured) products having good properties, especially having excellent fastness to solvents, light and weathering.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: August 15, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Jacques-Alain Cotting, Alfred Renner
  • Patent number: 4853442
    Abstract: Novel sulfur containing polyarylene polyether oligomers are disclosed. The oligomers are prepared through condensing salts of hydroxy and/or thio aromatic compounds, halobenzenoid compounds bearing two replaceable halogens and metal or ammonium sulfides following by end capping the resultant oligomer intermediate with a salt of a hydroxy and/or thio aromatic compound.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: August 1, 1989
    Assignee: Hercules Incorporated
    Inventor: Tuyen T. Nguyen
  • Patent number: 4853443
    Abstract: Disclosed is a novel polymer of this invention which comprises having a recurring unit represented by the formula: ##STR1## and having a reduced viscosity (.eta.sp/c) of 0.2 dl/g or more at 60.degree. C. in a solution of a concentration of 0.2 g/dl in p-chlorophenol as a solvent, a method for preparing the same which comprises reacting a dihalogenobenzonitrile represented by the formula: ##STR2## wherein X represents a halogen atom, with an alkali metal salt of resorcin represented by the formula: ##STR3## wherein M represents an alkali metal, in the presence of a solvent; and then treating the reaction product obtained by water or alcohol, and molding materials and molded products employing the polycyanoaryl ether.
    Type: Grant
    Filed: November 9, 1987
    Date of Patent: August 1, 1989
    Assignee: Idemitsu Kosan Company, Limited
    Inventors: Shigeru Matsuo, Tomoyoshi Murakami, Thoru Bando, Kikuo Nagatoshi
  • Patent number: 4839411
    Abstract: Virgin poly(arylene sulfide) resins are oxidatively cured by heat treatment at an elevated temperature below the melting point of the resin, under an oxidizing atmosphere comprising less than a 20 volume % oxygen concentration. The resulting polymer exhibits drastically improved thermal stability with no apparent sacrifice in physical properties.
    Type: Grant
    Filed: September 22, 1987
    Date of Patent: June 13, 1989
    Assignee: Phillips Petroleum Company
    Inventors: Kenneth C. Hoover, Fred T. Sherk, Joseph E. Figard
  • Patent number: 4837284
    Abstract: Described herein are novel block copolymers wherein one block is a poly(aryl ether ketone) oligomer and other block is a liquid crystalline polyester oligomer. Processes for the preparation of the subject copolymers are also described. The novel block copolymers display excellent mechanical properties, good high temperatures stability and excellent solvent and chemical resistance.
    Type: Grant
    Filed: March 31, 1987
    Date of Patent: June 6, 1989
    Assignee: Amoco Corporation
    Inventors: Markus Matzner, Donald M. Papuga
  • Patent number: 4826906
    Abstract: Disclosed herein is a poly(arylene thioether-ketone) composition improved in melt stability and crystallinity, which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and (B) 0.1-30 parts by weight of at least basic compound selected from the group consisting of the hydroxides, oxides and aromatic carboxylic acid salts of Group IIA metals of the periodic table other than magnesium and the hydrocarbyl oxides, aromatic carboxylic acid salts, carbonates, hydroxides, phosphates and borates of Group IA metals of the periodic table. The phosphates and borates include condensation products. The PTK has predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization peak-temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C. and a reduced viscosity of 0.2-2 dl/g.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: May 2, 1989
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Ken Kashiwadate, Yo Iizuka, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki
  • Patent number: 4824920
    Abstract: The resins resulting from converting dicyclopentadiene-phenol adducts to their corresponding vinylbenzyl ethers are an excellent matrix in which to embed fibers to produce a composite. Such resins, especially as a blend of materials with varying molecular weight distribution, are amorphous materials whose glass transition temperature is well under the curing temperature, and whose solubility permits solutions with high solids content so as to afford coatings with high resin content. The extensively crosslinked polymer resulting from therma, photochemical, or free radical initiated polymerization has excellent thermal and electrical properties for use in multilayer circuit boards.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: April 25, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Joseph J. Zupancic, Jeffrey P. Conrad, James A. Wrezel, Andrew M. Zweig, Jean M. J. Frechet
  • Patent number: 4804721
    Abstract: The resins resulting from converting the phenol-formaldehyde type condensation products of dicyclopentadiene-phenol adducts with selected aldehydes and ketones to their corresponding vinylbenzyl ethers are an excellent matrix in which to embed fibers to produce a composite. Such resins, especially as a blend of materials with varying molecular weight distribution, are amorphous materials whose glass transition temperature is well under the curing temperature, and whose solubility permits solutions with high solids content so as to afford coatings with high resin content. The extensively crosslinked polymer resulting from thermal, photochemical, or free radical initiated polymerization has excellent thermal and electrical properties for use in multilayer circuit boards.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: February 14, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Joseph J. Zupancic, Jeffrey P. Conrad
  • Patent number: 4804724
    Abstract: Described are blends of a biphenyl containing poly(acryl ether sulfone) and a poly(acryl ether ketone). These blends exhibit improved mechanical properties and environmental stress rupture resistance.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: February 14, 1989
    Assignee: Amoco Corporation
    Inventors: James E. Harris, Lloyd M. Robeson
  • Patent number: 4801657
    Abstract: Two step process for preparing high molecular weight, high melting polyarylethers by polycondensing an alkyl-substituted dihydric phenol and an aromatic dihalide, and thereafter dealkylating the polycondensation product.
    Type: Grant
    Filed: April 2, 1987
    Date of Patent: January 31, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Wilhelm K. Risse
  • Patent number: 4786694
    Abstract: Described are crystalline block copolymers displaying high glass transition temperatures, excellent mechanical properties, excellent chemical and thermal stability, and good melt processability. These block polymers contain segments of crystalline poly(aryl ether ketones).
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: November 22, 1988
    Assignee: Amoco Corporation
    Inventors: Robert A. Clendinning, James E. Harris, George T. Kwiatkowski, Lee P. McMaster, Markus Matzner, Paul A. Winslow
  • Patent number: 4774296
    Abstract: Described herein are crystalline block polymers and chain extended polymers containing blocks of crystalline poly(aryl ether ketones). Also, described herein are monomers and oligomers suitable for preparing the crystalline block polymers and chain-extended polymers. Further, described herein are methods for producing the crystalline block and chain-extended polymers, as well as the monomers and oligomers.
    Type: Grant
    Filed: May 2, 1985
    Date of Patent: September 27, 1988
    Assignee: Amoco Corporation
    Inventors: Robert A. Clendinning, James E. Harris, Donald R. Kelsey, Markus Matzner, Lloyd M. Robeson, Paul A. Winslow, Louis M. Maresca
  • Patent number: H732
    Abstract: Non-miscible blends comprising, as a major component, a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and, as a minor component, an oligomer derived from an epihalohydrin and a hydroxyphenylalkane, demonstrate improved processability.
    Type: Grant
    Filed: June 20, 1988
    Date of Patent: February 6, 1990
    Assignee: Shell Oil Company
    Inventor: Robert G. Lutz