Solid Polymer Derived From Aldehyde Or Aldehyde-type Reactant And Wherein None Of The Reactants Forming The Solid Polymer Contains A Phenol-, Amine-, -n=c=x, -n-s(=o)- Or Ketone Group Or A Condensate Thereof Except When An Amine Group Appears In Hexamethylenetetramine Or A Derivative Thereof (x Is Chalcogen) Patents (Class 525/472)
  • Patent number: 5760226
    Abstract: Binders compriseA) an aminotriazine derivative in which the primary amino groups of the triazine are methylolated on average with at least one mole of formaldehyde per mole of primary amino groups, and these methylol groups are etherified on average with at least 0.5 mol of primary alcohol per mole of methylol group and the primary alcohols are a mixture containinga) 0.5-99.5 mol % of a C.sub.1 -C.sub.4 -alkanol andb) 99.5-0.5 mol % of an alcohol of the formulaR.sup.1 --O--?R.sup.2 --O!.sub.n --R.sup.3 --OH I,in which R.sup.1 is C.sub.1 -C.sub.24 -alkyl or C.sub.6 -C.sub.12 -aryl which may be unsubstituted or substituted by from one to three C.sub.1 -C.sub.8 -alkyl groups, and R.sup.2 and R.sup.3 independently of one another are C.sub.2 -C.sub.8 -alkylene and n is an integer from 1 to 100, or of a mixture of higher-boiling alcohols having a boiling point of above 120.degree. C.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: June 2, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Niessner, Wolfram Weiss, Jurgen Tropsch, Matthias Kummer, Georg Meichsner
  • Patent number: 5744504
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo?2.2.1!heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 28, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono
  • Patent number: 5710220
    Abstract: There is a provided a stable low viscosity graft polymer dispersion comprising from 25 to 60 weight percent based on the total weight of the polymer dispersion of at least three ethylenically unsaturated monomers polymerized in the presence of a reaction moderator and a free radical initiator in a polyol mixture initially containing less than 0.1 moles of induced unsaturation per mole of said polyol mixture. One of the monomers in the mixture of ethylenically unsaturated monomers is a hydroxylfunctional or aminofunctional C.sub.2 -C.sub.6 alkyl methacrylate.
    Type: Grant
    Filed: July 10, 1995
    Date of Patent: January 20, 1998
    Assignee: BASF Corporation
    Inventors: Duane A. Heyman, James A. Gallagher
  • Patent number: 5677380
    Abstract: A planarizing material comprising a resin capable of having its practical temperature for a planarizing step set at a level lower than 200.degree. C., and a melamine-type heat-curing agent and/or an epoxy-type heat-curing agent.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: October 14, 1997
    Assignee: Tosoh Corporation
    Inventors: Kosaburo Matsumura, Mitsumasa Akashi, Yoshitaka Tsutsumi, Masazumi Hasegawa
  • Patent number: 5663246
    Abstract: Cyclic acetal derivative of a resole includes the reaction product of an ortho resole compound with a carbonyl compound or a carbonyl compound derivative. The cyclic acetal derivatives of phenolic resole compounds exhibit enhanced storage stability and can be readily activated at elevated temperatures to prepare phenolic based adhesives and coatings.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: September 2, 1997
    Assignee: Lord Corporation
    Inventors: Esther Spaltenstein, Ernest B. Troughton, Jr.
  • Patent number: 5656365
    Abstract: Polyvinylbutyral useful for the production of laminated glasses containing a crosslinking agent capable of making the polyvinylbutyral very slightly meltable or nonmeltable. The material according to the invention may contain a plasticizer and is particularly resistant to fire and allows one to produce a laminated material with a good resistance to impact and to fire.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: August 12, 1997
    Assignee: Saint Gobain Vitrage
    Inventor: Daniel Dages
  • Patent number: 5648446
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 15, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5646240
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: July 8, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5646214
    Abstract: An adherent film-forming composition comprising a carbamate-functional polyester polymer or oligomer, a hydroxy functional polymer derived from ethylenically unsaturated monomers and an aminoplast crosslinking agent is disclosed. The coating composition can be used to produce clear coats in composite color plus clear coatings exhibiting good levels of acid etch resistance as well as high intercoat adhesion. Also disclosed are a method of applying a composite color plus clear coating to a substrate and the coated article prepared by such a method.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: July 8, 1997
    Assignee: PPG Industries, Inc.
    Inventor: Michael A. Mayo
  • Patent number: 5618887
    Abstract: A process for the functionalisation of polymers is disclosed. Functionalisation takes place by reacting a polymer with a peroxidant, preferably, the peroxydisulphate or monosulphate or sodium or potassium in an aqueous medium. The hydroxylated polymer can then be reacted with other materials, including biomolecules. Using the method of the inventon, products eg. Catheters or oxygenators can be produced with improved properties hitherto unobtainable.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: April 8, 1997
    Assignee: The University of Liverpool
    Inventors: Clement H. Bamford, Kadem G. Al-Lamee
  • Patent number: 5596039
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: January 21, 1997
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5569726
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: October 29, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5548032
    Abstract: A crosslinking agent suitable for acrylic rubbers, particularly for acrylic rubbers containing units of a cyanoacetic acid comonomer or a malonic acid comonomer for imparting a crosslinkability, which comprises a reaction product of formaldehyde or a polymerized formaldehyde with urea or thiourea in the presence of an acidic catalyst.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: August 20, 1996
    Assignee: Toyo Seal Kogyo Kabushiki Kaisha
    Inventors: Terumitsu Tokunaga, Michinori Kuraya
  • Patent number: 5545702
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5540663
    Abstract: Use of polyacetals containing acetaldehyde acetal units, and of mixtures of these polyacetals with fillers, for preparing compostable moldings, as coating and as adhesive, and also diapers with an outer layer comprising polyacetals containing acetaldehyde acetal units in the form of a compostable film or a compostable coating.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: July 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Karl-Heinz Schumacher, Eckehardt Wistuba
  • Patent number: 5541284
    Abstract: The subject invention relates to method for processing crude polyoxymethylene in which the isolation of unstable components from crude polyoxymethylene, such as residual monomers which are at least partly in the form of cyclic formaldehyde derivatives, is effected by treatment of the crude polyoxymethylene with an inert gaseous medium. The method of the invention is characterized in that the gaseous medium contains at least 10 volume % of water vapor, and less than 0.1 volume % of a volatile base, and/or less than 1 volume % of a volatile solvent. In an alternative variant method, the gaseous medium contains at least 10 volume % of water vapor and the treatment occurs at a temperature between 114.degree. C and the softening temperature of the crude polyoxymethylene and at a pressure of less 1.2 .multidot.10.sup.5 Pa.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: July 30, 1996
    Assignee: Dequssa Aktiengesellschaft
    Inventors: Detlef Arnoldi, Udo Gropp, Edwin Nun
  • Patent number: 5536795
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5530075
    Abstract: The instant invention pertains to a curable resin composition comprised of A) 100 parts by weight curable resin, and B) 0.1-500 parts by weight of an organopolysiloxane having organic groups that contain epoxy groups, which is expressed by the formula: ##STR1## wherein R.sup.1 is a univalent hydrocarbon group excluding alkenyl groups, R.sup.2 is a hydrogen atom or a univalent hydrocarbon group excluding alkenyl groups, R.sup.3 is an alkoxysilylalkyl group or an organic group that contains epoxy groups, a is 0 or a positive integer, b is a positive integer and c is a positive integer, where a/c has the value of 0 to 4, b/c has the value of 0.05 to 4 and (a+b)/c has the value of 0.2 to 4. The curable resin composition of the instant invention has superior flowability that produces a hardened resin with superior flexibility and adhesion.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: June 25, 1996
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Noriyasu Yokoyama
  • Patent number: 5506332
    Abstract: A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50% by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: April 9, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Graham E. McKee, Heinrich Hartmann, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5500477
    Abstract: A moulding composition based on linear polyoxymethylene copolymers and customary additives with a melt index MFI (2,16 kg, 190.degree. C.) of .ltoreq.0,8, preferably .ltoreq.0,5 and especially .ltoreq.0,2 g/10 min has an extraordinary high toughness, which eliminates an addition of elastomer modifiers. In its preparation Lewis acids or protonic acids are used as initiators.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: March 19, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Reuschel, Dietrich Fleischer, Kaoru Yamamoto, Shuichi Chino
  • Patent number: 5489448
    Abstract: A water-free, water-free reducible primer composition having a volatile organic content of less than 3 pounds per gallon yields a tough, flexible, and weatherable film when applied to metal or plastic substrates. The base resin is a polyester having an acid number of from about 50 to about 60 and a hydroxyl number of from about 160 to about 200. The polyester is the reaction product of from about 0.45 to about 0.5 mole % of adipic acid, from about 0.35 to about 0.4 mole % of neopentyl glycol, and from about 0.15 to about 0.2 mole % of trimethylolpropane.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: February 6, 1996
    Assignee: Bee Chemical Company
    Inventors: Michael L. Jackson, Frank A. Stubbs, Joseph M. Mecozzi, Dean T. Smith
  • Patent number: 5489654
    Abstract: The invention is directed to polymers containing thiuram disulfide groups and their preparation. These polymers are iniferters in radical polymerization of vinyl monomers. Macroiniferters (having one thiuram disulfide group in their main chain) and polyiniferters (having more than one thiuram disulfide group in their main chain) result respectively, in triblock copolymers PA--PB--PA and diblock copolymers. --PA--PB).sub.z, z having a value from 2 to 25.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: February 6, 1996
    Assignee: Atochem
    Inventor: Gilbert Clouet
  • Patent number: 5480947
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: January 2, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5466762
    Abstract: There are described block copolyacetals obtainable by cationically initiated polyaddition of(A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and(B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule.in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Volker Schwendemann, Heinrich Hartmann
  • Patent number: 5432240
    Abstract: A process for producing a modified phenolic resin comprises heating (a) petroleum heavy oil or pitch and (b) a formaldehyde polymer in a molar ratio of formaldehyde:oil or pitch of from 1 to 15:1 in the presence of an acid catalyst, adding phenol in a molar ratio of phenol:oil or pitch of from 0.5 to 5:1 to form a crude modified phenolic resin, and purifying by performing in optional sequence (i) a treatment with an aliphatic or alicyclic hydrocarbon to remove unreacted components and (ii) an extraction with a solvent wherein the catalyst has a solubility of 0.1 or less to remove the catalyst.
    Type: Grant
    Filed: February 3, 1994
    Date of Patent: July 11, 1995
    Assignee: Kashima Oil Co., Ltd.
    Inventors: Masahiro Tsumura, Masao Tashima, Hiromi Miyasita, Haruhiko Takeda, Tomoaki Fujii
  • Patent number: 5387655
    Abstract: Described is a composition with integral intumescence properties, the composition being obtained by combining: a) one or more aminoformaldehyde resins and b) a mixture of mono- and di- esters of orthophosphoric acid with one or more polyols, the average hydroxy-group content of the polyols being at least 40% by weight, the molar ratio of mono-ester to di-ester not exceeding 12:1 and the phosphorus content of the mixture being at least 10% by weight.
    Type: Grant
    Filed: July 28, 1993
    Date of Patent: February 7, 1995
    Assignees: Chemische Fabrik Budenheim, Rudolf A. Oetker
    Inventor: Charles D. Aslin
  • Patent number: 5376650
    Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: December 27, 1994
    Assignee: Eastman Chemical Company
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5364703
    Abstract: The present invention is directed to improving the peel strength of copper foil laminated to polyetherimide substrates which optionally are reinforced. The improvement in process comprises coating one side of the copper foil with an adhesive composition, placing the coated side of the copper foil in contact with pre-formed polyetherimide substrate, and heat-pressing the resulting build-up to form a cured laminate of improved peel strength. The adhesive composition utilized comprises a blend of a polyvinyl butyral resin; one or more resole resins, and an organic solvent. Heat-pressing conditions comprise a temperature ranging from about 450.degree. to 550.degree. F. and pressing conditions ranging from about 100 to 700 psi. Within this temperature/pressure range, the adhesive-coated copper foil mated with the pre-formed polyetherimide substrate yields desired peel strengths without inducing excessive flow of the polyetherimide substrate, i.e. maintaining a pre-desired thickness .+-.7.5%.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: November 15, 1994
    Assignee: General Electric Company
    Inventors: James E. Tracy, John T. Bartholomew
  • Patent number: 5350830
    Abstract: Provided are polyester resins containing hydroxy functionalized isophthalate ester moieties useful in coating compositions. The invention provides both solvent-borne as well as water-borne coating compositions comprised of the resins and a crosslinker such as a melamine-type crosslinker. Polyester resins of the present invention having a T.sub.g of greater than about 50.degree. C. are useful in thermosetting powder coating compositions. The coatings thus provided possess excellent acid resistance, hardness, impact resistance, and stain resistance.
    Type: Grant
    Filed: November 27, 1992
    Date of Patent: September 27, 1994
    Assignee: Eastman Chemical Company
    Inventors: Thauming Kuo, Charles H. Foster
  • Patent number: 5344874
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 6, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5306567
    Abstract: Provided are polyester resins containing hydroxy functionalized isophthalate ester moieties useful in coating compositions. The invention provides both solvent-borne as well as water-borne coating compositions comprised of the resins and a crosslinker such as a melamine-type crosslinker. Polyester resins of the present invention having a T.sub.8 of greater than about 50.degree. C. are useful in thermosetting powder coating compositions. The coatings thus provided possess excellent acid resistance, hardness, impact resistance, and stain resistance.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: April 26, 1994
    Assignee: Eastman Kodak Company
    Inventors: Thauming Kuo, Charles H. Foster, Yeong-Ho Chang
  • Patent number: 5302462
    Abstract: The reaction of less than the stoichiometric amount of a methoxymethyl aminotriazine with a linear, hydroxyl-terminated polyester in a mixture of the two wherein the polyester to triazine ratio is from about 97:3 to about 70:30 by weight affords a storage stable coating powder which forms an attractive, pin hole-free film when fused on a substrate at thicknesses of from about 3.9 to about 6.8 mils.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: April 12, 1994
    Assignee: Morton International, Inc.
    Inventors: Navin B. Shah, Andrew T. Daly
  • Patent number: 5294352
    Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 15, 1994
    Inventor: John J. Waldmann
  • Patent number: 5288804
    Abstract: A composition comprising a first component including a compound comprising at least two acetoacetate groups, and a second component including a compound comprising at least two groups which will react with an acetoacetate group, at least one of which is an aromatic aldimine group having a relatively low reactivity with water when compared with its reactivity with an acetoacetate group.The components may be premixed in water prior to application.The invention further includes a product comprising a cured blend of the two components. The product of the invention is usually a coating or film.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: February 22, 1994
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Kyu-Jun Kim, Roy C. Williams
  • Patent number: 5288559
    Abstract: Provided is a coating composition for a two-piece can containing a polyester resin (A) consisting essentially of terephthalic acid and propylene glycol and containing tri- or more functional polycarboxylic acid or polyol comonomer(s) and an alkyl-etherified aminoformaldehyde resin (B); and the coating film (C) to be obtained by reacting these (A) and (B) in the composition has larger tensile strength and elongation than the film made of only (A). The coating composition is coated on at least one surface of a metal sheet to give a coated metal sheet for a two-piece can. The coated metal sheet may be formed into a drawn and ironed can or a drawn and re-drawn can. The adhesiveness of the coated film to the metal sheet is high, and the coated film has excellent resistance to blistering and resistance to whitening and has excellent flavor preservability.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: February 22, 1994
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Masami Oka, Takao Aoki, Hiroshi Fujimoto, Hiroshi Tachika
  • Patent number: 5281675
    Abstract: Novel cyclic imino ether compositions containing one or more mesogenic moieties, when polymerized, result in products having improved properties.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: January 25, 1994
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5274070
    Abstract: The present invention relates to a magnetically active organometallic Schiff base polymer having a molecular weight of between about 4,000 and 50,000 daltons. In an additional aspect, the present invention relates to a process for the preparation of magnetically active organometallic polymer having a molecular weight of between about 4,000 and 50,000 daltons, wherein the polymer comprises a multiplicity of Schiff base tridentate chelating groups having the capacity to combine with the iron (II) or iron (III) ion of an organic salt, which process comprises:(a) combining at least one organic diamine including hydrazine with at least one organic diketone or dialdehyde in an anhydrous dipolar aprotic solvent for a time sufficient to produce to polymer at a temperature of between about 50.degree. C. and 200.degree. C.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: December 28, 1993
    Assignee: Osaka Gas Company, Ltd.
    Inventors: David B. Cotts, Louisa M. Brodrecht, Robert C. Bening, Jr.
  • Patent number: 5254665
    Abstract: Ammeline-melamine-formaldehyde resins (AMFR) containing from 5-100% ammeline were synthesized by the polymerization of the sodium salt of ammeline, which must be made in advance, melamine, and formaldehyde in basic medium (pH=9.2-10.0). In this copolymerization, it is possible to make uniform random AMFR resins with any mole ratio of ammeline salt to melamine. Preferably the AMFR resin will contain from 5-10% ammeline. As an "ionomer" or a "polyelectrolyte," both the solid and solution properties of these resins (such as melting temperature, solubility, solution stability, etc.) depended directly on the mole ratio of ammeline to melamine and formaldehyde, and/or on the pH value of the medium in which the AMFR resin was present. The pH value controlled the ammeline rings/ammeline's salt groups and also the ratio of unprotonated to protonated amino groups on both the melamine and ammeline rings.
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: October 19, 1993
    Assignee: Melamine Chemicals, Inc.
    Inventors: George M. Crews, Shen Ji, Charles U. Pittman, Jr., Ruicheng Ran
  • Patent number: 5248762
    Abstract: Cyclic polyoxymethylene having a number-average molecular weight of 500 to 5,000 is obtained by solid state cyclization reaction of an alkalidegradative linear oxymethylene homopolymer in the presence of a medium containing a cationic catalyst.The cyclization is effected at 10.degree. to 150.degree. C. for 1 to 500 minutes in an organic liquid medium.The reaction mixture obtained by the cyclization is treated with an alkaline medium to hydrolyze and remove away unreacted linear polyoxymethylene homopolymer, and isolate the cyclic polyoxymethylene.The product has a sharp molecular weight distribution and is useful as a resin improver.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: September 28, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kaoru Yamamoto, Toshio Shiwaku
  • Patent number: 5247022
    Abstract: A thermoplastic molding material based onA) from 2 to 97.5% w/w of a homopolymer or copolymer of polyoxymethyleneB) from 2 to 97.5% w/w of a polyamideC) from 0.5 to 25% w/w of a polycondensate of 2,2-di(4-hydroxyphenyl)propane and epichlorohydrinD) from 0 to 60% w/w of an impact modifier, andE) from 0 to 60% w/w of fibrous or particulate fillers or mixtures thereof.
    Type: Grant
    Filed: September 24, 1991
    Date of Patent: September 21, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham E. McKee, Walter Goetz, Siegbert Bohnet, Hartmut Zeiner
  • Patent number: 5235005
    Abstract: A curable polyimide resin is blended with (a) an organic silicon compound having a functional group selected from an epoxy group and an amino group or (b) a copolymer of an aromatic polymer and an organic silicon compound. The resulting polyimide resin composition can be cured without inducing a crack. It is suitable for the encapsulation of semiconductor devices as well as for molding and powder coating.
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: August 10, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Shiobara, Koji Futatsumori, Shinichi Jingu
  • Patent number: 5230962
    Abstract: A coating composition is disclosed comprising an acrylosilane polymer, an acrylic polyol, a polyester urethane or a copolymer thereof, an amino resin crosslinking agent, and a silsesquioxane compound. Such a composition is especially useful for providing a finish on metallic and/or non-metallic parts of automobiles and trucks. This finish has the advantage of superior etch resistance and outstanding weatherability and durability characteristics.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: July 27, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Maurice A. S. Stephenson
  • Patent number: 5223323
    Abstract: The present invention relates to a process for coating finish foils and endless edges, wherein an acid-curing aqueous coating composition, on the basis of aminoplast resin/compound containing hydroxyl groups/self-crosslinking acrylate dispersion, is applied and baked in. The coating composition used contains 5 to 20% by weight of one or more fillers of a mean particle size from 0.015 to 10 .mu.m, a maximum particle size of .ltoreq.40 .mu.m and a density of .ltoreq.2.9 g/cm.sup.3.The invention also relates to the coating compositions positions used in the process and to finish foils and endless edges produced by the process, which especially have the advantage of an extremely low formaldehyde emission, particularly as a composite with a low-formaldehyde chipboard.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: June 29, 1993
    Assignee: BASF Corporation
    Inventors: Karl-Heinz Dickerhof, Joachim Roll, Wilhelm Moss, Thomas Schwalm
  • Patent number: 5206066
    Abstract: Melamine resin prepregs or melamine resin laminates which consist of a web-like fiber reinforcement which is impregnated with melamine resins which essentially comprisea) 40-85% by weight of at least partly etherified melamine resins, which are obtainable by reaction of melamine, formaldehyde and alkanols having 1 to 8 C atoms in a molar ratio of melamine formaldehyde:alkanol of 1:(5 to 6):(4 to 6), andb) 60-15% by weight of diols consisting of 25 to 75% by weight of polyester-diols and/or polyether-diols having a molecular weight of at least 400 g/mol and 75 to 25% by weight of low molecular weight diols having 2 to 12 C atoms.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: April 27, 1993
    Assignee: Chemie Linz Gesellschaft m.b.H.
    Inventor: Heinrich Horacek
  • Patent number: 5155170
    Abstract: The instant invention involves a process for forming a low formaldehyde, essentially color-free coating composition by applying the composition preferably to a wood substrate and curing. The composition comprises a blend of a polyhydroxy-containing polymer, an hexaalkoxymethylolmelamine, a polyacetal having the formula: ##STR1## wherein R is C.sub.1 -C.sub.3 and A is C.sub.1 -C.sub.20 allyl or aryl and an acid catalyst. The coating compositions of the instant invention exhibit extremely low color and give off a significantly reduced amount of formaldehyde when cured in comparison to conventional prior art, acid catalyzed melamine/formaldehyde cured coatings.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: October 13, 1992
    Assignee: Akzo Coatings, Inc.
    Inventors: Paul R. Baukema, Milton J. Kaelin, Donald W. Waltrip, Kenneth M. Znidersic
  • Patent number: 5144005
    Abstract: Continuous process for removing unstable components from crude oxymethylene copolymer, which still contains catalysts, monomeric starting materials and unstable components, by treating the copolymer with deactivators, optionally in the presence of auxiliaries, in a pressure zone, and subsequently removing volatile components in a pressure-release zone in the presence or absence of stabilizers, in which process the crude polymer is fully melted in the absence of the deactivators and auxiliaries immediately after completion of the polymerization step, and the deactivators are subsequently incorporated, alone or together with auxiliaries, under pressure into the resultant polymer melt in at least one pressure zone.By this process, degradation is avoided and significantly better properties are obtained.
    Type: Grant
    Filed: February 4, 1988
    Date of Patent: September 1, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Sextro, Karl-Friedrich Muck, Karlheinz Burg, Eberhard Fischer
  • Patent number: 5102954
    Abstract: The instant invention involves a process for forming a low formaldehyde, essentially color-free coating composition by applying the composition preferably to a wood substrate and curing. The composition comprises a blend of a polyhydroxy-containing polymer, an hexaalkoxymethylolmelamine, a polyacetal having the formula: ##STR1## wherein R is C.sub.1 -C.sub.3 and A is C.sub.1 -C.sub.20 allyl or aryl and an acid catalyst. The coating compositions of the instant invention exhibit extremely low color and give off a significantly reduced amount of formaldehyde when cured in comparison to conventional prior art, acid catalyzed melamine/formaldehyde cured coatings.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: April 7, 1992
    Inventors: Paul R. Baukema, Milton J. Kaelin, Donald W. Waltrip, Kenneth M. Znidersic
  • Patent number: 5082891
    Abstract: The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 21, 1992
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Noriyasu Yokoyama, Keiji Yoshida
  • Patent number: 5030678
    Abstract: Disclosed are cationic aqueous emulsions containing (a) sizing composition comprising the reaction product of melamine formaldehyde compound, long chain saturated alcohol and long chain saturated or unsaturated polyethoxylated alcohol; and (b) cationic surfactant. The emulsions when used to surface size paper impart improved oil, water and polar solvent resistance thereto. The emulsions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based emulsions that are typically used to impart oil resistance to paper.
    Type: Grant
    Filed: July 2, 1990
    Date of Patent: July 9, 1991
    Assignee: PPG Industries, Inc.
    Inventors: Sai H. Hui, Mean-Jeng Hou
  • Patent number: 5026762
    Abstract: Rubber compositions for tire treads of an all-weather type are disclosed which are so designed as to exhibit high dynamic Young's modulus, sufficient resistance to snow and ice skidding, to abrasion, to cracking and to crack growth and adequate durability. A selected base rubber is combined with a selected carbon black and a selected m-cresol resin. The base rubber is a blend of two different rubbers, one being natural rubber alone or a combination with a diene rubber and the other being butadiene rubber. The carbon black has specified absorptivity of iodine and dibutyl phthalate. The m-cresol resin is a novolak condensate.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: June 25, 1991
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Masashi Kida, Shingo Midorikawa, Ichiro Suzuki, Yoshihiko Suzuki, Youichi Yamaguchi