Solid Polymer Derived From Silicon-containing Reactant Patents (Class 525/474)
  • Publication number: 20120329915
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Application
    Filed: September 5, 2012
    Publication date: December 27, 2012
    Applicants: Dow Agroscienses LLC, Kroff Chemical Company
    Inventors: Paul Rey, Steven P. Ceplecha, David M. Sunderlik
  • Publication number: 20120329961
    Abstract: A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.
    Type: Application
    Filed: June 27, 2011
    Publication date: December 27, 2012
    Inventors: Alvaro Carrillo, Hua Guo
  • Publication number: 20120320535
    Abstract: Methods and systems are provided for a dry silicone gel in a closure or interconnect system. The dry silicone gel may be made by reacting a crosslinker, a chain extender, and a vinyl-terminated polydimethylsiloxane. The reaction may be conducted in the presence of a catalyst. In certain embodiments, the dry silicone gel may comprise: (1) a hardness between 100 g and 300 g, (2) a stress relaxation between 30% and 60% when subjected to a deformation of 50% of the original size of the gel, (3) a compression set between 4% and 20% after 50% strain has been applied to the gel for 1000 hours at 70° C., and/or (4) less than 10% oil bleed out under compression of 1.2 atm after 60 days at 60° C.
    Type: Application
    Filed: June 20, 2011
    Publication date: December 20, 2012
    Inventors: Stephane J.G. Berghmans, Michael A. Oar, Miguel A. Morales, Gary W. Adams, Anne-Marie Prins, Nathalie Hendrickx, Guenter Feldmeier, Rudi Kraemer, Bert Bergmer, Kristof Vastmans
  • Publication number: 20120315229
    Abstract: There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals optionally containing heteroatoms, carbonyl groups, and hydroxyl groups, each independently having from about 1 to about 20 carbon atoms; RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(?O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at le
    Type: Application
    Filed: June 9, 2011
    Publication date: December 13, 2012
    Applicant: Momentive Performance Materials Inc.
    Inventors: Benjamin FALK, Sigfredo Gonzalez
  • Patent number: 8329830
    Abstract: A surface treatment process comprises (a) providing at least one substrate having at least one major surface; (b) combining (1) at least one curable oligomeric or polymeric polysilazane comprising at least one chemically reactive site, and (2) at least one fluorochemical compound comprising (i) at least one organofluorine or heteroorganofluorine moiety that comprises at least about six perfluorinated carbon atoms, and (ii) at least one functional group that is capable of reacting with the polysilazane through at least one of the chemically reactive sites; (c) allowing or inducing the polysilazane and the fluorochemical compound to react to form at least one curable organofluorine-modified polysilazane; (d) applying the curable organofluorine-modified polysilazane or its precursors to at least a portion of at least one major surface of the substrate; and (e) curing the curable organofluorine-modified polysilazane to form a surface treatment.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: December 11, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Yu Yang, George G. I. Moore, Thomas P. Klun
  • Publication number: 20120308494
    Abstract: Linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups, obtainable by the reaction of organopolysiloxanes functionalized with secondary aminoalkyl groups with the reaction products formed from compounds containing epoxy groups and amines, the use thereof and process for preparation thereof.
    Type: Application
    Filed: December 29, 2010
    Publication date: December 6, 2012
    Inventors: Frank Schubert, Wilfried Knott, Michael Ferenz, Klaus-Dieter Klein, Tobias Maurer, Ralph Scheurmann, Bernhard William Kluesener, Rajan Keshav Panandiker
  • Patent number: 8324324
    Abstract: A composition for preparing curable organofluorine-modified polysilazanes comprises (a) at least one curable oligomeric or polymeric polysilazane comprising at least one chemically reactive site; and (b) at least one fluorochemical compound comprising (1) at least one organofluorine or heteroorganofluorine moiety, and (2) at least one functional group that is capable of reacting with the curable oligomeric or polymeric polysilazane through at least one of the chemically reactive sites of the polysilazane. The curable organofluorine-modified polysilazanes can be prepared by combining the components of the composition and allowing or inducing the components to react.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: December 4, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Yu Yang, George G. I. Moore, Thomas P. Klun
  • Publication number: 20120302705
    Abstract: A method of producing an organopolysiloxane compound in which a poly(N-acylalkyleneimine) segment comprising repeating units represented by formula (1): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, is bonded to a terminal end and/or a side chain of an organopolysiloxane segment, the method comprising: a step (a) of subjecting a cyclic imino ether compound represented by formula (I): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, to ring opening polymerization in a solvent, thereby preparing a terminal reactive poly(N-acylalkyleneimine) solution; a step (b) of mixing a modified organopolysiloxane having an amino group at a terminal end and/or a side chain of its molecular chain and a solvent, thereby preparing a modified organopolysiloxane solution; a step (c) of mixing the terminal reactive poly(N-acylalkyleneimine) solution obt
    Type: Application
    Filed: December 14, 2010
    Publication date: November 29, 2012
    Applicant: KAO CORPORATION
    Inventors: Takashi Kodate, Katsuhiko Rindo, Osamu Takiguchi
  • Publication number: 20120302700
    Abstract: The present invention includes a method for preparing a nanoparticle filled nanocomposite material, the method including the steps of providing a plurality of nanoparticles. attaching a first layer of organic ligand to the nanoparticle via a phosphate or phosphonate linkage, covalently attaching a second layer of matrix compatible polymer to said first layer of organic ligand to produce modified nanoparticles, providing a polymer matrix and dispersing the modified nanoparticles in the polymer matrix, wherein the dispersement of the modified nanoparticles into the polymer matrix results in a nanocomposite material, and wherein the modified nanoparticles are modified such that the first layer is proximal to the nanoparticle and the second layer is distal to the nanoparticle. Also within the scope of the invention are modified nanoparticles, alternative nanocomposite materials and methods of making the same.
    Type: Application
    Filed: January 27, 2011
    Publication date: November 29, 2012
    Applicants: UNIVERSITY OF SOUTH CAROLINA, RENSSELAER POLYTECHNIC INSTITUTE
    Inventors: Peng Tao, Li Yu, Brian Benicewicz, Richard W. Siegel, Linda S. Schadler, Anand Viswanath
  • Publication number: 20120296052
    Abstract: A method of producing an organopolysiloxane compound in which a poly(N-acylalkyleneimine) segment comprising repeating units represented by formula (1): is bonded to a terminal end and/or a side chain of an organopolysiloxane segment, the method comprising: a step (a) of subjecting a cyclic imino ether compound represented by formula (I): to ring opening polymerization in a solution thereof which is obtained by mixing the cyclic imino ether compound and a solvent, thereby preparing a solution of a terminal reactive poly(N-acylalkyleneimine); a step (b) of dehydrating a solution which is obtained by mixing a modified organopolysiloxane having an amino group at a terminal end and/or a side chain of its molecular chain and a solvent, such that a water concentration of a mixed solution to be obtained by mixing the solution of the terminal reactive poly(N-acylalkyleneimine) obtained in step (a) and the resultant solution of the modified organopolysiloxane is regulated to be 150 mg/kg or less; and
    Type: Application
    Filed: December 14, 2010
    Publication date: November 22, 2012
    Applicant: KAO CORPORATION
    Inventors: Takashi Kodate, Katsuhiko Rindo, Osamu Takiguchi
  • Patent number: 8314190
    Abstract: A fluoropolyether base rubber composition comprising (a) a linear fluoropolyether compound containing at least two ester groups in a molecule and a divalent perfluoroalkyl ether structure in its backbone, and having a Mn of 3,000-100,000, and (b) a siloxane polymer containing at least three amino groups in a molecule cures at room temperature into a product having heat resistance, low-temperature performance, chemical resistance, solvent resistance and oil resistance.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: November 20, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuo Muto, Takashi Matsuda, Mikio Shiono
  • Patent number: 8309664
    Abstract: Process for the preferential alkoxylation of silicone-polyether copolymers either alone or in compositions thereof containing, for example, excess polyether by use of double metal cyanide catalysts.
    Type: Grant
    Filed: October 26, 2009
    Date of Patent: November 13, 2012
    Assignee: Evonik Goldschmidt GmbH
    Inventors: Wilfried Knott, Frank Schubert, Frauke Henning
  • Patent number: 8309637
    Abstract: The present disclosure relates to a composition with improved flame resistance, to articles made from the composition, and to methods that include processing the composition. The composition can include from 15 to 85 percent by weight of a polyetherimide (PEI), from 15 to 85 percent by weight of a polyphenylsulfone (PPSU), a polyetherimide-siloxane copolymer in an amount up to 12 percent by weight, and from 0 to 0.30 percent by weight of a stabilizer.
    Type: Grant
    Filed: August 11, 2011
    Date of Patent: November 13, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Mark Sanner, Robert Russell Gallucci, Rajendra K. Singh
  • Patent number: 8308699
    Abstract: Substrates, optionally coated with an undercoating, having grafted thereto one or more non-fouling materials are described herein. The non-fouling, polymeric material can be grafted to a variety of functionalized substrate materials, particularly polymeric substrates and/or polymeric undercoatings immobilized on a substrate. The compositions described herein are highly resistant protein absorption, particularly in complex media and retain a high degree of non-fouling activity over long periods of time. The compositions described herein may also demonstrate antimicrobial and/or anti-thrombogenic activity. The non-fouling material can be grafted to a functionalized substrate, or optionally from an undercoating on the substrate, preferably without significantly affecting the mechanical and/or physical properties of the substrate material.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: November 13, 2012
    Assignee: Semprus Biosciences Corp.
    Inventors: Zheng Zhang, Chad Huval, William Shannan O'Shaughnessey, Michael Hencke, Trevor Squier, Jun Li, Michael Bouchard, Christopher R. Loose
  • Patent number: 8309649
    Abstract: The present invention relates to silylated amino resins, to processes for preparing them, to their use, and to coating compositions comprising them.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: November 13, 2012
    Assignee: BASF SE
    Inventors: Bastian Martin Noller, Reinhold Schwalm, Christine Roesch, Thomas Breiner, Jean-Francois Stumbe, Christina Haaf
  • Publication number: 20120283393
    Abstract: The present invention is a polycarbonate-polyorganosiloxane copolymer (A-1) comprising a polycarbonate block composed of a specific structural unit and a polyorganosiloxane block composed of a specific structural unit, wherein (1) the content of the polyorganosiloxane block portion is 1 to 30% by mass, (2) the average number of the repeating structural units represented by the general formula (II) is 70 to 1000, (3) the viscosity-average molecular weight of the copolymer is 13000 to 26000, and (4) the content of the phenol residue having an allyl group in the copolymer is 400 ppm by mass or less, the copolymer providing a molded article having excellent thermal stability and excellent color tone after even when the molding is carried out at high temperature; a process for production of the copolymer; and a polycarbonate resin using the polycarbonate-polyorganosiloxane copolymer.
    Type: Application
    Filed: December 9, 2010
    Publication date: November 8, 2012
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventor: Yasuhiro Ishikawa
  • Publication number: 20120273145
    Abstract: The present invention relates to a drainage aid composition and its use in pulp washing process. More particulary, this invention relates to drainage aid composition of silicone polyethers prepared via zinc catalized dehydrogenative coupling of alcohol terminated polyethers with silicone oligomers and polymers comprising of at least one silicon bonded hydrogen. The compostion of this invention exhibit excellent drainage properties.
    Type: Application
    Filed: April 25, 2012
    Publication date: November 1, 2012
    Applicant: HERCULES INCORPORATED
    Inventors: Zoha Al-badri, Todd S. Bolton
  • Publication number: 20120277339
    Abstract: Provided are inorganic-organic block copolymers that self assemble without the addition of a precursor. The inorganic block of the polymers includes silicon and the organic block may be any organic polymer. The inorganic-organic block copolymers self assemble to form a material in which the inorganic polymer block may be crosslinked to produce an organosilicate and/or silica matrix, and further thermal curing of the matrix results in the formation of a porous nanostructured film.
    Type: Application
    Filed: April 29, 2011
    Publication date: November 1, 2012
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Krishna M. Bajjuri, Qiu Dai, Alshakim Nelson, Jitendra S. Rathore
  • Publication number: 20120269994
    Abstract: A marine vehicle component wherein the component is a partition or a light cover, and wherein the marine vehicle component is molded or formed from a thermoplastic polymer composition comprising a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 25, 2012
    Inventors: Paul Dean Sybert, James Franklin Hoover, Thomas L. Evans
  • Publication number: 20120267480
    Abstract: An aircraft component wherein the component is a partition or a light cover, and wherein the aircraft component is molded or formed from a thermoplastic polymer composition including: a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 25, 2012
    Inventors: Paul Dean Sybert, James Franklin Hoover, Laura G. Schultz Hume
  • Publication number: 20120271010
    Abstract: A hydrophilic polymer compound includes a polymer compound which inhibits platelet adhesion, and a compound that inhibits blood coagulation reaction, bound to the polymer compound.
    Type: Application
    Filed: December 22, 2010
    Publication date: October 25, 2012
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Hirokazu Sakaguchi, Yuka Sakaguchi, Kazuhiro Tanahashi
  • Patent number: 8293848
    Abstract: Curable compositions are disclosed, containing at least one organopolysiloxane, which contains at least one hydroxyl group and/or group which can be hydrolyzed, in aqueous dispersion, i) at least one oganopolysiloxane having a dynamic viscosity of 0.05 to 7 (measured according to Brookfield DV-II+, spindle 3, 23° C.), which is free of hydroxyl groups and/or groups which can be hydrolyzed, in aqueous dispersion, at least one cross-linking agent, at least one emulsifier, at least one cross-linking catalyst, at least one aqueous silicon-free polymer dispersion, at least one filler, and optionally water. The compositions are suitable as sealants, adhesives, or coating agents for application in the construction field, in particular in the sanitary field and in the kitchen field. They are characterized in relation to aqueous silicone preparations known up to this point by an improved adhesion spectrum, in particular on plastic substrates.
    Type: Grant
    Filed: May 24, 2010
    Date of Patent: October 23, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Thomas Plantenberg, Klaus Helpenstein, Ralf Dunekake, Johann Klein
  • Publication number: 20120264890
    Abstract: Copolymers containing at least one perfluoropolyether segment and at least one polydiorganosiloxane segments are described. The copolymers further contain multiple aminooxalylamino groups that link the various segments together. Methods of making the copolymers are also described.
    Type: Application
    Filed: December 22, 2010
    Publication date: October 18, 2012
    Inventors: Richard G. Hansen, Miguel A. Guerra, David S. Hays, Suresh S. Iyer, Ramesh C. Kumar, George G.I. Moore, Yu Yang
  • Publication number: 20120259064
    Abstract: The invention provides new polymeric or oligomeric active agents with a biocidal effect. Such particularly advantageous polymeric or oligomeric active agents with a biocidal effect are obtainable via polycondensation of a guanidine acid addition salt with an amine mixture comprising at least one diamine and/or one triamine, wherein at least one amine is selected from the group comprising i) diamine, comprising at least one cycloaliphatic residue, and ii) dialkylenetriamine. At least one amine is hereby preferably selected from 4,4?-methylenebis(cyclohexylamine) and diethylenetriamine. Furthermore, it is favorable if the guanidine acid addition salt is guanidinehydrochloride.
    Type: Application
    Filed: November 12, 2010
    Publication date: October 11, 2012
    Inventors: Andreas Greiner, Seema Agarwal, Claudia Mattheis
  • Patent number: 8278400
    Abstract: Polyamine cross-linked polysiloxanes, such as functionalized polysiloxane cross-linked with a polyalkylenepolyamine are described herein. The polyamine cross-linked polysiloxanes may be used in an antifouling composition to prevent biological fouling in marine environments.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: October 2, 2012
    Assignee: NDSU Research Foundation
    Inventors: Bret Ja Chisholm, Philip Boudjouk, Johnson Thomas, David Allen Christianson, Shane Jeremy Stafslien
  • Patent number: 8278399
    Abstract: Processes for preparing siloxane-modified polyisocyanates, the processes comprising: providing a polyisocyanate reactant; and reacting the polyisocyanate reactant with a hydroxyl-containing siloxane having a number-average molecular weight of 200 to 3000 g/mol and an average OH functionality of greater than or equal to 1.8, and corresponding to the general formula (I): wherein X represents an aliphatic, unbranched or branched C1 to C20 radical optionally containing ether groups; R represents a hydroxyl-functional radical; R1 represents a hydrogen or an optionally heteroatom-containing C1 to C20 hydrocarbon radical; and n is 1 to 40; siloxane-modified polyisocyanates prepared thereby, and uses therefor.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: October 2, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Arno Nennemann, Markus Mechtel, Thomas Klimmasch, Meike Niesten
  • Publication number: 20120238669
    Abstract: Inventive composite materials are provided. The composite is preferably a nano-composite, and comprises an asphaltene, or a mixture of asphaltenes, blended with a polymer. The polymer can be any polymer in need of altered properties, including those selected from the group consisting of epoxies, acrylics, urethanes, silicones, cyanoacrylates, vulcanized rubber, phenol-formaldehyde, melamine-formaldehyde, urea-formaldehyde, imides, esters, cyanate esters, allyl resins.
    Type: Application
    Filed: March 16, 2012
    Publication date: September 20, 2012
    Applicant: Honeywell Federal Manufacturing & Technologies, LLC
    Inventor: Daniel E. Bowen, III
  • Patent number: 8268926
    Abstract: Particle-toughened polymer compositions include a base polymer formulation and a plurality of toughening particles. In certain embodiments, the base polymer formulation includes bismaleimides or other polymer resins capable of high temperature service. A first plurality of toughening particles may include core shell rubbers. A second plurality of toughening particles may be selected from a variety of polymer compositions, including polyimides, polyether ketone (PEK), polyether ether ketone (PEEK), polyether ketone ketone (PEKK), polyether imide, polyether sulfones, and polyphenylene oxide. It is found that increasing concentration of the core shell rubbers may improve the toughness of the composition while preserving thermal properties of the composition, such as glass transition temperature.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: September 18, 2012
    Assignee: Cytec Technology Corp.
    Inventors: Mark Richard Bonneau, Jack Douglas Boyd, Gordon T. Emmerson, Scott D. Lucas, Stephen J. Howard, Spencer Donald Jacobs
  • Publication number: 20120232227
    Abstract: A compound having the formula below. Each R is methyl or phenyl; R2 comprises one or more of silane, siloxane, and aromatic groups; n is a nonnegative integer; and m is 1 or 2. The dashed bond is a single bond and the double dashed bond is a double bond, or the dashed bond is a double bond and the double dashed bond is a triple bond. A polymer made by a hydrosilation reaction of a polyhedral oligomeric silsesquioxane having pendant siloxane groups with an acetylene- and silicon-containing compound having at least two vinyl or ethynyl groups, and a crosslinked polymer thereof. The reaction occurs between the pendant siloxane groups and the vinyl or ethynyl groups.
    Type: Application
    Filed: May 24, 2012
    Publication date: September 13, 2012
    Applicant: The Government of the United States of America, as represented by the Secretary of the Navy
    Inventors: Manoj K. Kolel-Veetil, Teddy M. Keller
  • Patent number: 8263717
    Abstract: The present invention provides a polysilazane-containing composition capable of forming a dense siliceous film more rapidly and at a lower temperature than known polysilazane-containing composition. In a process for forming the siliceous film, the composition comprising a polysilazane compound, a particular amine compound and a solvent is coated on a substrate and converted into a siliceous substance. The particular amine compound preferably contains two amine groups separated from each other at the distance corresponding to five C—C bonds or more, and the amine groups preferably have hydrocarbon substituent groups.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: September 11, 2012
    Assignee: AZ Electronic Materials USA Corp.
    Inventor: Yuki Ozaki
  • Patent number: 8263724
    Abstract: The purpose of the present invention is to provide a surface treating agent which provides a surface where stain does not easily adhere, does not stand out and is easily wiped off. The present invention is a perfluoropolyether group-containing polyorganosiloxane represented by the following formula (1) and a surface treating agent comprising the same, Ak(R)nZ-Q-Rf-Q-Z(R)nAk??(1) wherein Rf is a divalent perfluoropolyether group; Q is a divalent group linking Rf with Z; Z is a polyorganosiloxane group having at least three siloxane bonds with its valency being trivalent to undecavalent; R is a monovalent organic group having 8 to 40 carbon atoms, n is an integer of from 1 to 8; A is a group represented by the following formula (2); and k is an integer of from 1 to 9, provided that a total of n+k=the valency of Z?1 wherein R? is an alkyl group having 1 to 4 carbon atoms or a phenyl group; X is a hydrolysable group, a is 2 or 3; and b is an integer of from 2 to 10.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: September 11, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yuji Yamane, Noriyuki Koike, Hirofumi Kishita
  • Patent number: 8263312
    Abstract: Antireflective coatings comprising (i) a silsesquioxane resin having the formula (PhSiO(3-x)/2(OH)x)mHSiO(3-x)/2(OH)x)n(MeSiO(3-x)/2(OH)x)p where Ph is a phenyl group, Me is a methyl group, x has a value of 0, 1 or 2; m has a value of 0.01 to 0.99, n has a value of 0.01 to 0.99, p has a value of 0.01 to 0.99, and m+n+p=1; (ii) a polyethylene oxide fluid; and (iii) a solvent; and a method of forming said antireflective coatings on an electronic device.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: September 11, 2012
    Assignee: Dow Corning Corporation
    Inventors: Peng-Fei Fu, Eric Scott Moyer
  • Publication number: 20120201765
    Abstract: The present invention relates to silicone compounds which have photoprotective properties and personal care compositions comprising the same. The present inventors, in developing a sunscreen that gives protection against both UV radiation and visible radiation, found that when certain moieties generally occurring in nature e.g. curcuminoids, polyphenols or flavonoids having uv-visible absorption activity are attached to cross-linked silicone polymers, they provide not only the desired photoprotection but also excellent spreadability on skin.
    Type: Application
    Filed: September 21, 2010
    Publication date: August 9, 2012
    Applicant: Unilever NV
    Inventors: Ashish Anant Vaidya, Nilmoni Ghosh, Balu Kunjupillai
  • Patent number: 8236902
    Abstract: The present invention discloses a method for making blended polymers by utilizing fluorophilic inter-polymer associative interactions between perfluorocarbon functional groups attached on the constituent polymers. The method of the present invention is capable of forming blended polymers from otherwise incompatible polymers. Also disclosed are blended polymers obtained by the method thereof. Methods and devices utilizing novel blended polymer of the present invention including chromatography, catalysis, photonic and sensor applications are also provided.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: August 7, 2012
    Assignee: University of Southern California
    Inventors: Thieo Hogen-Esch, Jingguo Shen
  • Patent number: 8236342
    Abstract: The invention provides a multi-polymer hydrogel article having a first polymeric, water-swellable material and a second polymeric material, organized such that a first region substantially comprises the first polymeric, water-swellable material, a second region adjacent the first region comprises a mixture of the first polymeric, water-swellable material and the second polymeric material, and a third region adjacent the second region substantially comprises the second polymeric material. The article exhibits an increasing concentration gradient of the second polymeric material moving from the first region, through the second region, to the third region.
    Type: Grant
    Filed: April 26, 2010
    Date of Patent: August 7, 2012
    Assignee: Zimmer, Inc.
    Inventors: Brian Thomas, Kai Zhang
  • Patent number: 8232363
    Abstract: A polymeric material with a variable modulus of elasticity is described herein. The polymeric material described herein is useful for forming implantable medical devices (e.g. ophthalmic lenses, breast implants, and body augmentation devices). In addition, medical devices formed from the polymer material can be used to controllably release a therapeutic agent. Also, the polymeric material may be used to prepare topical compositions or other applications or devices where control of a mechanical property such as material modulus is important.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: July 31, 2012
    Assignee: Abbott Medical Optics Inc.
    Inventors: Can B. Hu, Thuy B. Mai
  • Publication number: 20120187046
    Abstract: Sulfur contaminants, such as elemental sulfur (S8), hydrogen sulfide and other sulfur components in fluids (e.g., air, natural gas, and other gases, as well as water and other liquids) are removed using a silicone-based chemical filter/bath. In one embodiment, a silicone-based chemical filter includes a membrane having a cross-linked silicone that is a reaction product of an olefin and a polyhydrosiloxane. For example, sulfur contaminants in air may be removed by passing the air through the membrane before the air enters a data center or other facility housing computer systems. In another embodiment, a silicone-based chemical bath includes a housing having an inlet port, an outlet port, and a chamber containing a silicone oil. For example, sulfur contaminants in air may be removed by passing the air through the silicone oil in the chamber before the air enters a data center or other facility housing computer systems.
    Type: Application
    Filed: January 21, 2011
    Publication date: July 26, 2012
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III, Timothy J. Tofil
  • Publication number: 20120178859
    Abstract: Optical devices of excellent optical and physical properties produced from cured resins are disclosed. The resins and/or the cured hybrid polymer material made with the resins are characterized by a high level of cycloaliphatic-containing groups. Specific additives that can participate in crosslinking the curable polysiloxane provide additional physical property advantages.
    Type: Application
    Filed: January 20, 2012
    Publication date: July 12, 2012
    Applicant: DIGITALOPTICS CORPORATION EAST
    Inventors: Daniel Roitman, Dileep Goyal
  • Patent number: 8217130
    Abstract: Disclosed herein is a curable composition excellent in workability, adhesion properties, rubber-like properties, storage stability, and quick curability. The curable composition comprises (A) a crosslinkable silyl group-containing organic polymer and (B) a (meth)acrylic polymer obtained by polymerizing a (meth)acrylic monomer having a polymerizable unsaturated bond in the presence of a metallocene compound and a crosslinkable silyl group-containing thiol compound, at least one end of the (meth)acrylic polymer being bonded to a residue, —S—R3 (where R3 represents a group having a crosslinkable silyl group) obtained by removing a hydrogen atom from the crosslinkable silyl group-containing thiol compound.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: July 10, 2012
    Assignee: Cemedine Co., Ltd.
    Inventors: Atsushi Saito, Tomonori Saito, Naomi Okamura
  • Patent number: 8216673
    Abstract: Glass fiber-treating agent which includes: (A) 5-95% by weight of an acetylene glycol or an ethylene oxide and/or a propylene oxide adduct of an acetylene glycol; and (B) 5-95% by weight of a silicone surfactant which may be polyoxyalkylene-modified. The glass fiber-treating agent reduces dynamic and static surface tension and contact angle. The glass fiber-treating agent provides excellent wetting, penetration, and antifoaming properties when glass fibers are treated therewith.
    Type: Grant
    Filed: August 2, 2006
    Date of Patent: July 10, 2012
    Assignees: Nissin Chemical Industry Co., Ltd., Shin-Etsu Chemical Co., Ltd.
    Inventors: Toru Mizusaki, Shuichiro Shinohara, Akira Yamamoto, Masaki Tanaka
  • Patent number: 8216321
    Abstract: Crosslinkable liquid composition which can crosslink to give a hydrophobic and/or oleophobic silicone elastomer coating, comprising a polyorganosiloxane (POS) resin A exhibiting, per molecule, on the one hand, at least two different siloxyl units chosen from those of M, D, T and Q types, one of the units being a T unit or a Q unit, and, on the other hand, at least three hydrolysable/condensable groups of OH and/or OR1 types, where R1 is a linear or branched C1 to C6, preferably C1 to C3, alkyl radical, a system for promoting attachment B and a polyfluoroacrylate F. Use of this composition to form a silicone elastomer sheath around the constituent yarns, fibers and/or filaments of a textile material and to confer long-lasting oleophobicity and/or hydrophobicity properties.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: July 10, 2012
    Assignee: Bluestar Silicones France, SAS
    Inventors: Martial Deruelle, Yves Giraud
  • Publication number: 20120172472
    Abstract: A silicone composition is described that includes components having SiH/SiOH group and that can be polymerized/cross-linked by a dehydrocondensation reaction in the presence of a catalyst such as an iron-based complex or salt, requiring a low activation temperature.
    Type: Application
    Filed: June 15, 2010
    Publication date: July 5, 2012
    Applicant: BLUESTAR SILICONES FRANCE
    Inventor: Christian Maliverney
  • Publication number: 20120172543
    Abstract: Silicone pressure sensitive adhesive (PSA) compositions and methods for their preparation are provided. In one embodiment, PSAs are formed from a silicone polymer mixture by condensation polymerization of low viscosity polyorganosiloxanes in inert solvents and/or silicone fluids, and optionally adding a silicone resin (MQ) during polymerization. The silicone polymer mixture formed may also be mixed with a silicone resin (MQ) and bodying catalyst, and bodying is allowed to continue until the desired reaction product is formed.
    Type: Application
    Filed: August 24, 2010
    Publication date: July 5, 2012
    Inventors: Stephen Edward Cray, Delphine Davio, Robert Alan Ekeland, Andreas Stammer
  • Publication number: 20120172473
    Abstract: A silicone composition is described that includes components having SiH/SiOH groupings and that can be polymerized/cross-linked by a dehydrogenative condensation reaction in the presence of a non-metal tri- or tetrasubstituted non-silylated guanidine catalyst and requiring a low activation temperature.
    Type: Application
    Filed: June 15, 2010
    Publication date: July 5, 2012
    Applicant: BLUESTAR SILICONES FRANCE
    Inventor: Christian Maliverney
  • Publication number: 20120172483
    Abstract: Provided is a process for production of a cured molded article capable of readily producing a transparent and discoloration-free cured molded article that exhibits a low shrinkage ratio and an excellent heat resistance, abrasion resistance, and mold release behavior. Also provided is a cured molded article that is useful in a variety of applications, for example, as an optical member. The process for production of a cured molded article from a curable resin composition that comprises a condensable inorganic compound, a curable organic compound, and a curing agent is a process for production of a cured molded article including a first step composed of a step of thermally curing the curable resin composition at 80 to 200° C. and/or a step of curing the curable resin composition by exposure to active-energy radiation, and a second step of subjecting the cured material obtained in the first step to a thermal cure at above 200° C. but not more than 500° C.
    Type: Application
    Filed: September 16, 2010
    Publication date: July 5, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD
    Inventors: Jun-Ichi Nakamura, Ai Matsumoto
  • Patent number: 8207245
    Abstract: The present invention relates to silicon-containing biostable gels and processes for their preparation. The gels possess properties which make them useful in the manufacture and repair of biomaterials and medical devices, articles or implants, in particular the manufacture of soft tissue implants such as breast implants and the repair of orthopaedic joints such as spinal discs.
    Type: Grant
    Filed: September 28, 2005
    Date of Patent: June 26, 2012
    Assignee: Aortech International plc
    Inventors: Ajay Padsalgikar, Trang Thanh Nhan, Sriram Venkataramani, Mansour Mehrabi, Mark Bown
  • Publication number: 20120157567
    Abstract: The disclosure is directed to a silicone composition. The silicone composition includes a silicone matrix component, an adhesion promoter, and a quaternary ammonium salt containing polymer, wherein the quaternary ammonium salt containing polymer is in an amount to provide a bactericidal effect to the silicone composition. The disclosure is further directed to an article made thereof and to methods for making the article.
    Type: Application
    Filed: December 16, 2011
    Publication date: June 21, 2012
    Applicant: SAINT-GOBAIN PERFORMANCE PLASTICS CORPORATION
    Inventors: Duan Li Ou, Heidi Sardinha, Mark W. Simon
  • Publication number: 20120153219
    Abstract: An electrode includes a binder and an electroactive material, wherein the binder includes a polymer including a linear polysiloxane or a cyclic polysiloxane.
    Type: Application
    Filed: December 20, 2011
    Publication date: June 21, 2012
    Inventors: Zhengcheng Zhang, Jian Dong, Khalil Amine
  • Patent number: 8202939
    Abstract: A formable curable elastomer composition comprising a dispersion of a cured organic elastomer, such as EPDM, butyl rubber and hydrogenated nitrile butyl rubber, is provided in an uncured silicone elastomer. The organic elastomer is cured by a phenol-formaldehyde resin. These compositions can generally be used in applications where silicone rubber is used, and in particular where the cured rubber is liable to be exposed to temperatures of 150-200° C. Examples of such uses include tyre bladders used in the moulding of tyres, spark plug boots for internal combustion engines, wire and cable coatings designed to be used at high temperatures and ceramifiable wire and cable coatings used in safety critical applications such as emergency lighting systems.
    Type: Grant
    Filed: September 19, 2007
    Date of Patent: June 19, 2012
    Assignee: Dow Corning Corporation
    Inventors: Robert Moore, Michael Proctor
  • Publication number: 20120148774
    Abstract: The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties.
    Type: Application
    Filed: December 12, 2011
    Publication date: June 14, 2012
    Applicant: Interface Biologics Inc.
    Inventors: Sanjoy MULLICK, Weilun CHANG, Alexandra PIOTROWICZ, Jeannette HO, Richard WITMEYER