Mixed With Ethylenically Unsaturated Reactant Or Polymer Derived Therefrom Patents (Class 525/479)
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Patent number: 6262188Abstract: Compositions, comprising functionalized resins having the formula MxHMyRQ (I) wherein x+y is in the range from 0.Type: GrantFiled: December 3, 1999Date of Patent: July 17, 2001Assignee: General Electric CompanyInventors: Frank S. Burkus, II, Slawomir Rubinsztajn, Jacek Gulinski, Bogdan Marciniec
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Patent number: 6258914Abstract: Alkoxy silane oligomers which have a non-hydrolyzable carbon bridged bond to another silane functionality are taught herein, as well as their manufacture and utility.Type: GrantFiled: October 15, 1999Date of Patent: July 10, 2001Assignee: C. K. Witco CorporationInventors: Shiu-Chin Huang Su, Herbert E. Petty, Fredrick D. Osterholtz
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Publication number: 20010006760Abstract: The present invention relates to a novel photosensitive resin which can be developed in water and which can be used as a photosensitive resin composition. More specifically, the present invention relates to a composition which is useful as a photosensitive soldering resist for printed circuit board.Type: ApplicationFiled: February 14, 2001Publication date: July 5, 2001Applicant: Ajinomoto Co., Inc.Inventors: Shigeo Nakamura, Tadahiko Yokota
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Patent number: 6252030Abstract: A method for manufacturing an organic solvent-soluble hydrogenated octasilsesquioxane-vinyl group-containing compound copolymer comprising reacting 1 mol of (A) a hydrogenated octasilsesquioxane described by formula I with 0.2 to less than 3 mol of (B) a divinyl group-containing compound described by formula (2) CH2═CH—L—CH═CH2 Formula 2 where L is selected from the group consisting of (a) a divalent hydrocarbon group comprising 3 to 10 carbon atoms and (b) —(SiR2O)m—SiR2—, where each R is independently selected from the group consisting of alkyls comprising 1 to 6 carbon atoms and aryls comprising 6 to 9 carbon atoms and 1≦m≦10; in the presence of a hydrosilylation catalyst.Type: GrantFiled: March 9, 2000Date of Patent: June 26, 2001Assignee: Dow Corning Asia, Ltd.Inventors: Gregg Alan Zank, Michitaka Suto
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Patent number: 6251965Abstract: A process for forming a surface modification on a polymer substrate and polymer substrates having such surface modifications. The process comprises the steps of absorbing a swelling monomer into the polymer substrate for a period of time in order to swell the polymer substrate; removing the swollen polymer from the swelling monomer; transferring the swollen polymer to a reaction mixture containing at least one functional monomer; polymerizing the functional monomer in the reaction mixture containing the swollen polymer substrate for a period of time; and removing the polymer from the reaction mixture. Because the surface modification produced by the process is a surface interpenetrating polymer network, the process is not sensitive to the reactive groups located on the surface of the polymer substrate. Further, the surface interpenetrating network bonds to the polymer substrate through caternary connections or other forms of chain entanglement and thus is quite stable.Type: GrantFiled: May 3, 1999Date of Patent: June 26, 2001Assignee: Pharmacia ABInventors: Yading Wang, Robert van Boxtel, Stephen Q. Zhou
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Patent number: 6252028Abstract: Curable organopolysiloxane compositions comprising (D) a platinum catalyst selected from the class consisting of where R2 is an unsubstituted or substituted diene bonded to platinum via at least one &pgr; bond, having an unbranched or branched chain of from 4 to 12 carbon atoms or a ring of from 6 to 18 carbon atoms, R3 are identical or different and are a hydrogen atom, halogen atom or a monovalent, unsubstituted or halogen- or cyano-substituted hydrocarbon radical having from 1 to 24 carbon atoms, R4 are identical or different bivalent, unsubstituted or substituted hydrocarbon radicals having from 1 to 24 carbon atoms, R5 are identical or different bivalent, unsubstituted or substituted hydrocarbon radicals having from 1 to 12 carbon atoms, silane radicals or siloxane radicals, R6 are identical or different and are a hydrogen atom or a monovalent hydrocarbon radical having from 1 to 20 carbon atoms, e is an integer greater than or equal to 1, and f is 0 or 1.Type: GrantFiled: October 7, 1999Date of Patent: June 26, 2001Assignee: Wacker-Chemie GmbHInventors: Armin Fehn, Frank Achenbach
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Patent number: 6251993Abstract: A novel moisture curable polymer combination comprising, a member selected from the group consisting of a polydiolefin polymer containing olefinic unsaturation in either the main polymer backbone or in pendent side chains; and a loop polymer having a polymeric backbone and a plurality of olefinic groups which have been converted to closed loops by reaction with difunctional organic compounds reactive with said olefinic groups, said olefinic groups from which the loops are formed may either be present within the backbone and/or pendent from the polymeric backbone; and a silicon cross-linking compound containing at least one easily hydrolyzed substituent.Type: GrantFiled: July 28, 1999Date of Patent: June 26, 2001Assignee: Fluorochem, Inc.Inventors: Kurt Baum, Wen-Huey Lin
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Patent number: 6231990Abstract: A low VOC primer composition suitable for use with room temperature vulcanizable silicones, comprising a polyorganosiloxane resin, an acrylic resin, an organotitanate, a silane or partial hydrolyzate thereof and an organic liquid in amount effective to dissolve the other components of the primer composition that provides improved adhesion to diverse substrates.Type: GrantFiled: June 21, 1999Date of Patent: May 15, 2001Assignee: General Electric CompanyInventors: Chiu-Sing Lin, Brian P. Bayly, Timothy J. Fahrenkopf, Gary M. Lucas
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Patent number: 6225370Abstract: An ink composition comprises a colorant and an additive. The additive is selected from the group consisting of first dispersants synthesized from an aromatic mercaptan, a hydrophilic monomer, a hydrophobic polymeric reactant having a siloxyl substituent and a first stabilizing reactant; second dispersants synthesized from a non-aromatic mercaptan, a hydrophilic monomer, a hydrophobic polymeric reactant having a siloxyl substituent, and a second stabilizing reactant selected from the group consisting of nonylphenoxy (PEG)4-6 methacrylate, nonylphenoxy (PPG)4-6 methacrylate, nonylphenoxy (PEG)4 6 acrylate, nonylphenoxy (PPG)4-6 acrylate and mixtures thereof; humectant mixtures comprising a bis-hydroxy terminated thioether, a lactam, and a compound selected from the group consisting of polyalkylene glycols, polyol/alkylene oxide condensates and mixtures thereof; and mixtures thereof.Type: GrantFiled: July 26, 1999Date of Patent: May 1, 2001Assignee: Lexmark International, Inc.Inventors: Ajay Kanubhai Suthar, Bradley Leonard Beach, Kathryn Dowlen Mullins, Jing X. Sun, Robin Gnerlich Baskette
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Patent number: 6225409Abstract: A method of making a polymeric composition comprising a fluorocarbon-silicone interpenetrating network, comprising the steps of: a) mechanically compounding a fluorocarbon copolymer and metal oxide or hydroxide acid acceptor to form a homogenous mixture; and b) dispersing in solvent the mixture formed by step a) with a polymer selected from a curable polyfunctional poly(C(1-6) alkyl)siloxane polymer; a curable polyfunctional poly(C(1-6) alkyl)arylsiloxane polymer; and combinations thereof, and c) solution milling the dispersion of b) to form a homogeneous blend.Type: GrantFiled: September 18, 1998Date of Patent: May 1, 2001Assignee: Eastman Kodak CompanyInventors: Stephen V. Davis, Jiann-Hsing Chen, Nataly Boulatnikov
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Patent number: 6221940Abstract: A thermoplastic resin composition containing a polyetherimide resin, a glycidyl ester impact modifier and a organometallic compound exhibits improved impact strength and ductility.Type: GrantFiled: December 23, 1997Date of Patent: April 24, 2001Assignee: General Electric CompanyInventors: Robert Puyenbroek, James Fishburn
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Patent number: 6221972Abstract: The present invention relates to a novel photosensitive resin which can be developed in water and which can be used as a photosensitive resin composition. More specifically, the present invention relates to a composition which is useful as a photosensitive soldering resist for printed circuit board.Type: GrantFiled: September 10, 1997Date of Patent: April 24, 2001Assignee: Ajinomoto Co., Inc.Inventors: Shigeo Nakamura, Tadahiko Yokota
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Patent number: 6214937Abstract: The synthesis and characterization of novel multi-arm, polyisobutylene-based star-block polymers comprising a plurality of polyisobutylene-containing, diblock arms radiating from a siloxane core are described. The synthesis has been achieved by cationically polymerizing a monomer, such as styrene, and isobutylene to form diblock prearms and then hydrosilating the unsaturation-functionalized polyisobutylene with siloxanes carrying a plurality of Si—H groups via hydrosilation. The resultant star-block polymers may be thermoplastic elastomers characterized as having superior tensile strength and processing properties as compared to linear triblock polymers of similar hard/soft segments.Type: GrantFiled: March 26, 1999Date of Patent: April 10, 2001Assignee: The University of AkronInventors: Joseph P. Kennedy, Jung S. Shim
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Patent number: 6211322Abstract: The invention relates to organopolysiloxanes comprising (meth)acrylate groups, to a process for their preparation and to their use as radiation-curing coating materials.Type: GrantFiled: March 1, 1999Date of Patent: April 3, 2001Assignee: Th. Goldschmidt AGInventors: Hardi Döhler, Thomas Ebbrecht, Stefan Stadmüller
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Patent number: 6207769Abstract: A polymer composition comprises a polymer matrix and a siloxane-containing additive which is substantially incompatible with the polymer matrix, wherein the siloxane of the additive has a hydroxy, alkoxy or epoxy functionality, and a functionality which is capable of bonding with a silicone elastomer-forming composition which is curable by a hydrosilylation reaction. The polymer matrix preferably comprises polyphenylenesulphide, and the additive preferably comprises hydroxy-terminated methylvinyl siloxane. The composition is capable of forming plastics articles to which cured silicone elastomers can adhere.Type: GrantFiled: June 30, 1999Date of Patent: March 27, 2001Assignee: Dow Corning GmbHInventors: Ernst Gerlach, Edouard Joseph, Klaus Kunz, Dieter Zaulig
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Patent number: 6201057Abstract: A stain/topcoat system for non-porous thermoset and/or thermoplastic articles comprises a pigmented stain, and a topcoat comprising one or more non-siloxane film-forming polymers, an emulsion of one or more curable organopolysiloxanes, a weatherability agent having a functional group that is reactive with carboxylate functional sites and water. The topcoat displays exceptional adhesion and weatherability to pigmented stained surfaces.Type: GrantFiled: February 23, 1998Date of Patent: March 13, 2001Assignee: Therma-Tru CorporationInventor: Cem A. Porter
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Patent number: 6187890Abstract: Curable organopolysiloxane compositions comprising a platinum catalyst selected from the group consisting of (PR23)2Pt(—C≡C—R3)2 (III), (R22P—R4—PR22)Pt(—C≡C—R3)2 (IV) and H—C≡C—R5—C≡C—[—Pt(PR23)2—C≡C—R5—C≡C—]e—H (V) where R2, R3, R4, R5 and e are as defined in claim 1.Type: GrantFiled: August 13, 1999Date of Patent: February 13, 2001Assignee: Wacker-Chemie GmbHInventors: Armin Fehn, Frank Achenbach, Stefan Dietl
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Patent number: 6184284Abstract: A composition is comprised of the following: a) a hydrolyzed or partially hydrolyzed alkoxysilane; b) a solvent consisting of an organic liquid or mixture of two or more organic liquids in which component (a) and component (c) are soluble and c) a cross linking prepolymer, oligomer, resin or mixtures thereof that forms a low dielectric constant crosslinked polymer. Preferred crosslinked polymers are of a arylcyclobutene or polyphenylene prepolymer, oligomer, resin or mixtures thereof. A coating may be made using the composition wherein the coating is comprised of a crosslinked polymer of a low dielectric crosslinking prepolymer, oligomer, resin or mixture thereof and a hydrolyzed or partially hydrolyzed alkoxysilane, said coating being adhered to a surface of a substrate wherein said surface is comprised of a first material that is a metal, ceramic or polymer and a second material that is (i) a metal, ceramic, or polymer and (ii) different than the first material.Type: GrantFiled: August 24, 1998Date of Patent: February 6, 2001Assignee: The Dow Chemical CompanyInventors: Theodore M. Stokich, Jr., Brian B. Martin, Paul H. Townsend, III
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Patent number: 6180741Abstract: A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.Type: GrantFiled: October 7, 1999Date of Patent: January 30, 2001Assignees: DSM N.V., JSR CorporationInventors: Yoshikazu Yamaguchi, Zen Komiya, Takashi Ukachi
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Patent number: 6180690Abstract: Aqueous ink jet ink compositions comprising an aqueous vehicle, a colorant, and an alkoxysilane binder additive, have excellent water and smear fastness and print quality.Type: GrantFiled: November 4, 1998Date of Patent: January 30, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Joseph Harry Spinelli
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Patent number: 6174977Abstract: Disclosed is a cold curable resin composition comprising at least a block copolymer in which a polymer portion having an epoxy group, a hydroxyl group and a hydrolytic silyl group and a polyorganosiloxane portion exist in the same molecular chain. A base material coated with the curable resin composition is also disclosed herein. The resin composition of the present invention has high performance in application to, for instance, an inorganic base material such as a plastic plate, e.g., an acrylic plate and glass, and has excellent cold curing properties, possesses high de-staining ability and excellent adhesive properties, and further can form a smooth and transparent coating film.Type: GrantFiled: October 25, 1999Date of Patent: January 16, 2001Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Yasushi Ariyoshi, Takehiro Suzuki
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Patent number: 6169142Abstract: Silicone rubber parts having a high thermal conductivity and low hardness are obtained by molding and curing a composition comprising (A) 100 parts by weight of an alkenyl-bearing organopolysiloxane having a viscosity of up to about 500,000 centistokes at 25° C., (B) 300-1,200 parts by weight of aluminum oxide powder, (C) 0.05-10 parts by weight of an alkoxysilane of the formula: R1aSi(OR2)(4−a) wherein R1 is a monovalent C6-20 hydrocarbon group, R2 is a C1-6 alkyl group, and a=1, 2 or 3, (D) a platinum group metal catalyst, and (E) an organohydrogenpolysiloxane containing at least two SiH groups in a molecule. The composition is formulated so as to suppress the viscosity increase of a liquid silicone rubber composition due to heavy loading of aluminum oxide.Type: GrantFiled: June 17, 1999Date of Patent: January 2, 2001Assignee: Shin Etsu Chemical Co., Ltd.Inventors: Akio Nakano, Takeshi Hashimoto
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Patent number: 6169149Abstract: Melt extrudable grafts of emulsion polymerized silicone rubber and polyacrylate rubber hybrids have been found to be valuable impact modifiers for organic thermoplastic polymeric materials. Optimum impact modifier properties are achieved by employing as a source material, an emulsion polymerized silicone rubber made under semi-continuous, low shear process conditions.Type: GrantFiled: December 4, 1998Date of Patent: January 2, 2001Assignee: General Electric CompanyInventors: Daniel Horace Craig, Rong Hu
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Patent number: 6166120Abstract: The present invention relates to a flame retardant composition comprising (A) a polymer which includes a copolymer of ethylene and at least one other comonomer including a vinyl unsaturated polybishydrocarbylsiloxane; and (B) an inorganic filler comprising at least one member selected from the group consisting of oxides, hydroxides and carbonates of aluminium, magnesium, calcium and barium. It also relates to a cable or wire comprising such a composition.Type: GrantFiled: March 4, 1999Date of Patent: December 26, 2000Assignee: Borealis Technology OyInventors: Bernt-.ANG.ke Sultan, Matti Hirvensalo, Jussi Laurell
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Patent number: 6162888Abstract: The present invention relates to a method of making a silicone polyether comprising (I) reacting a mixture comprising an olefin functional polyether, an organohydrogensiloxane, and a homogeneous transition metal hydrosilylation catalyst, and (II) subjecting the product of (I) to hydrogen gas. The method of this invention reduces the amount of olefinic species present which are precursors to odorous compounds. Thus the method of this invention reduces the amount of odor in the silicone polyether product. These odors are objectionable, particularly in personal care applications.Type: GrantFiled: May 17, 1999Date of Patent: December 19, 2000Assignee: Dow Corning CorporationInventors: Kenneth Michael Lee, Lenin James Petroff, William James Schulz, Jr.
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Patent number: 6147142Abstract: Previously cross-linked silicone elastomer particles with an organic-polymer shell are used as constituents for formulating aqueous coating compositions based on water-soluble or water-dilutable binders. The silicone elastomer particles contain: (a) 5 to 95% by weight, with respect to the total weight of the copolymer, of a nuclear polymer of general formula (R.sub.2 SiO.sub.2/2).sub.x (RSiO.sub.3/2).sub.y (SiO.sub.4/2).sub.z, in which x=5 to 99.5% by mole, y=0.5 to 95% by mole, z=0 to 30% by mole, and (b) 5 to 95% by weight, with respect to the total weight of the copolymer of a shell made of an organopolymer from mono- or poly-ethylenically unsaturated monomers; and R stands for the same or different monovalent alkyl or alkenyl radicals with 1 to 6 carbon atoms, aryl radicals or substituted hydrocarbon radicals.Type: GrantFiled: September 28, 1998Date of Patent: November 14, 2000Assignee: Wacker-Chemie GmbHInventors: Michael Geck, Walter Goeblmeier, Bernward Deubzer, Ekkehard Patrick, Helmut Oswaldbauer
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Patent number: 6127504Abstract: A linear polyfluoro compound having at least two alkenyl groups as a base component is blended with a linear polyfluoro compound having one alkenyl group and a hydrosilyl-bearing linear polysiloxane having fluoroalkyl substituents in side chains and at ends thereof. With a platinum catalyst added, there is obtained a curable composition having improved storage stability which will quickly cure into satisfactory gel products.Type: GrantFiled: December 24, 1998Date of Patent: October 3, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kenichi Fukuda, Yasuo Tarumi
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Patent number: 6114449Abstract: A curable rubber composition comprises of a silicone rubber (A) and an ethylene-.alpha.-olefin-polyene amorphous copolymer (B) containing as the polyene component a norbornene compound having at least one kind of vinyl terminal group represented by 5-vinyl-2-norbornene or 5-methylene-2-norbornene. The rubber composition is speedily cured, if said components (A) and (B) are mixed by the A/B mixing ratio of 98/2-2/98 (% by weight) and kneaded in the presence of an organic peroxide. A vulcanizate rubber excelling in mechanical strength, water resistance and thermal aging resistance can be manufactured from said composition, since its crosslink density can be enhanced without impairing processing properties. Additionally, said composition entails reduced mold fouling phenomenon in the molding operation. Vulcanizate rubber thereby obtained can be advantageously used as industrial parts and electric parts.Type: GrantFiled: August 17, 1998Date of Patent: September 5, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Tetsuo Tojo, Takashi Hakuta, Mikio Hosoya
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Patent number: 6113988Abstract: The invention relates to coating compositions comprising:(A) from 5 to 60% by weight of at least one polyester-modified polyacrylate resin consisting of:(a1) from 20 to 60% by weight of at least one polyester and(a2) from 40 to 80% by weight of at least one hydroxyl-containing polyacrylate resin which has been prepared at least in part in the presence of component (a1),(B) from 1 to 35% by weight of at least one hydroxyl-containing, siloxane-modified polyacrylate resin, and(C) from 5 to 50% by weight of an isocyanate crosslinking agent,and to a process for the production of a protective and/or decorative coating with such coating compositions, and to their use as topcoats and refinish coating materials.Type: GrantFiled: April 30, 1998Date of Patent: September 5, 2000Assignee: BASF Coatings AgInventors: Harald Borgholte, Olaf Hallmann
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Patent number: 6100332Abstract: A coating composition comprising a mixture of a methyl-rich silicone resin (S-1) and an acrylic resin (A-1) obtained by polymerizing at least one radical polymerizable vinyl monomer (M-1), or a reaction product obtained by reacting the silicone resin (S-1) with the radical polymerizable vinyl monomer (M-1) is suitable for coating carrier particles to form an electrophotographic carrier.Type: GrantFiled: January 20, 1999Date of Patent: August 8, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yuji Yoshikawa, Masaaki Yamaya
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Patent number: 6093782Abstract: Crosslinkable compositions comprise novel organosilicon compounds (B.sup.1) containing Si-bonded hydrogen atoms and comprising(a) units of the formulaH.sub.a R.sub.2-a SiO.sub.2 O.sub.2/2 (I),where R is as defined in claim 1 and a is 0, 1 or 2, with the proviso that at least 20 mol % of the units of the formula (I) are ones in which a is 1 or 2,(b) carbostructural units G (II), where G are identical or different and are each a trivalent to decavalent aliphatic hydrocarbon radical having from 7 to 30 carbon atoms per radical, which may contain one or more heteroatoms selected from the group consisting of oxygen, boron, silicon, tin or titanium, with the proviso that at least three Si atoms are connected to one another via G,(c) units of the formula ##STR1## where b is 0, 1 or 2, with the proviso that b in formula (III') is not 2 and with the proviso that the units of the formula (III) or (III') are connected via the Si atoms to the carbostructural units G and(d) units of the formulaH.sub.c R.sub.3-c SiO.sub.Type: GrantFiled: December 1, 1998Date of Patent: July 25, 2000Assignee: Wacker-Chemie GmbHInventors: Christian Herzig, Oliver Zollner
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Patent number: 6084006Abstract: A method for manufacturing a color filter comprises a step for charging an ink comprising a thermosetting resin composition onto an opening of a black matrix provided on a transparent substrate and a step for curing the ink by heat treatment. The thermosetting resin composition comprises either a coloring agent, a multifunctional epoxide having at least two glycidyl groups and a compound crosslinked by the multifunctional epoxide; or a coloring agent, a cellulose-reactive compound and a compound crosslinked by the cellulose-reactive compound.Type: GrantFiled: September 8, 1997Date of Patent: July 4, 2000Assignee: Canon Kabushiki KaishaInventors: Akio Kashiwazaki, Katsuhiro Shirota, Koichiro Nakazawa, Masashi Hirose
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Patent number: 6034199Abstract: Acetylenic maleates, fumarates and related derivative compounds are new compositions of matter having the formula:R.sub.1 O.sub.2 C--CH.dbd.CH--CO.sub.2 R.sub.2wherein R.sub.1 may be an organic moiety containing at least two carbon atoms triply bonded one to the other as:--C.tbd.C--and R.sub.2 may be hydrogen, an organic moiety, or R.sub.1 ; suitable for use as liquid injection molding inhibitors either singly or in combination with themselves or other liquid injection molding inhibitors when used for the process of liquid injection molding curable compositions enabling an increase in the size of articles manufactured therefrom, which new compositions of matter cure into the polymerizable or curable resins thereby creating new compositions of matter as cured resins from which said articles of manufacture are produced.Type: GrantFiled: November 24, 1997Date of Patent: March 7, 2000Assignee: General Electric CompanyInventors: Philip J. McDermott, Michael J. O'Brien, Edward M. Jeram
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Patent number: 6031019Abstract: Aqueous ink for ink-jet printing comprises an emulsion of fine polymer particles and contains at least one compound selected from an amino acid or a salt thereof and the like.Type: GrantFiled: February 4, 1998Date of Patent: February 29, 2000Assignee: Kao CorporationInventors: Takehiro Tsutsumi, Koji Azuma, Michitaka Sawada, Tadashi Sakuma, Kenji Kaida, Shigemi Wakabayashi, Tetsuya Ueno, Kuniyasu Kawabe
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Patent number: 6028148Abstract: A silicone rubber composition comprises a silicone rubber and porous inorganic fine powders holding dimethyl-silicone oil.Type: GrantFiled: August 27, 1993Date of Patent: February 22, 2000Assignee: Canon Kabushiki KaishaInventor: Toshiyuki Miyabayashi
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Patent number: 6022921Abstract: The mechanical properties of addition-crosslinked silicone rubber are improved when the silicone rubber is brought into contact with a compound (A) having at least one aliphatically unsaturated multiple bond. In particular, the compression set is lowered.Type: GrantFiled: November 4, 1998Date of Patent: February 8, 2000Assignee: Wacker-Chemie GmbHInventors: Frank Achenbach, Christof Worner, Armin Fehn, Otto Rothenaicher
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Patent number: 6020446Abstract: It is an object of the invention to improve the adhesive property of a curable composition mainly comprising a reactive silyl group-containing saturated hydrocarbon polymer when applied to various adherends and to improve the weathering-resistant adhesive property of said composition when applied to various glass products, in particular heat ray-reflecting glass products.The present invention relates to a curable composition which comprises (A) a saturated hydrocarbon polymer containing at least one silicon-containing group having a hydroxyl group or hydrolyzable group bound to the silicon atom and capable of crosslinking by forming a siloxane bond, (B) a silane coupling agent and (C) a compound containing, within the molecule thereof, an unsaturated group capable of polymerizing upon reaction with atmospheric oxygen and/or a photopolymerizing substance.Type: GrantFiled: October 22, 1998Date of Patent: February 1, 2000Assignee: Kaneka CorporationInventors: Toshihiko Okamoto, Makoto Chiba, Masashi Sakaguchi, Junji Takase
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Patent number: 6017587Abstract: The present invention relates to electrically conductive silicone compositions comprising an organopolysiloxane containing at least two alkenyl groups per molecule, an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, a platinum group metal containing catalyst, a conductive metal particulate, a precrosslinked elastomeric silicone particle, and a non-reactive volatile diluent. The electrically conductive silicone compositions of this invention are useful as electrically conductive adhesives and coatings for electrical and electronic devices. The cured electrically conductive silicone compositions of this invention have high electroconductivity and rubbery elasticity.Type: GrantFiled: July 9, 1998Date of Patent: January 25, 2000Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.Inventors: Don Lee Kleyer, Michael Andrew Lutz, Katsutoshi Mine, Osamu Mitani, Kazumi Nakayoshi, Bernard Vanwert
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Patent number: 5998501Abstract: A process for producing an aqueous ink for inkjet printing capable of giving an elevated print density of printed matters, being improved in fixability to the material to be printed, water resistance and improved storage stability and scarcely scorching onto a printer head. This process comprises dissolving a salt-forming group-having polymer and a hydrophobic dye in a water-insoluble organic solvent to obtain a solution, adding water and a neutralizing agent optionally together with a surfactant to the solution to ionize the salt-forming group of the polymer, emulsifying the resulting mixture, and removing out the solvent from the emulsion to obtain an ink containing an aqueous dispersion of the polymer particles in which the dye has been encompassed.Type: GrantFiled: February 2, 1998Date of Patent: December 7, 1999Assignee: Kao CorporationInventors: Tekehiro Tsutsumi, Koji Azuma, Michitaka Sawada
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Patent number: 5990269Abstract: The improved water-soluble photosensitive resin composition comprises a high-polymer compound represented by the general formula (I): ##STR1## (where X is Na, K or NH.sub.4) and a water-soluble polymer which is either polyvinylpyrrolidone or a copolymer of vinylpyrrolidone and vinylimidazole or both. The composition is applied to a substrate, exposed through a mask pattern and developed to form a photocured pattern and, thereafter, a light absorber is applied to the entire surface of the substrate and dried, followed by stripping away the photocured pattern and the overlying light absorber to form a black matrix pattern. The composition is suitable for use as a photoresist in the manufacture of black matrices as on color CRTs and capable of efficient formation of photocured patterns with high sensitivity by shorter times and lower intensities of exposure.Type: GrantFiled: November 21, 1997Date of Patent: November 23, 1999Assignees: BASF Aktiengesellschaft, Tokyo Ohka Kogyo Co., Ltd.Inventors: Karin Neubecker, Stefan Stien, Stephan Kothrade
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Patent number: 5981659Abstract: The invention relates to the use of precrosslinked silicone elastomer particles with an organopolymer shell as the formulation constituent in powder coating material compositions based on thermoplastic or thermosetting binding agents, the silicone elastomer particles containing (a) 5 to 95% by weight, in relation the total weight of the copolymerisate, of a nucleus polymer of the general formula (R.sub.w SiO.sub.2/2).sub.x.(RSiO.sub.3/2).sub.y.(SiO.sub.4/2).sub.z with x=5 to 99.5 mol %, y=0.5 to 95 mol %, z=0 to 30 mol %, and (b) 5 to 95% by weight, in relation to the total weight of the copolymer, of a shell made of an organopolymer of ethylenically mono or multi-unsaturated monomers, R standing for identical or different monovalent C.sub.1 -C.sub.6 alkyl or alkenyl residues or substituted hydrocarbon residues.Type: GrantFiled: March 6, 1998Date of Patent: November 9, 1999Assignee: Wacker-Chemie GmbHInventors: Michael Geck, Walter Goeblmeier, Bernward Deubzer, Ekkehard Patrick
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Patent number: 5977282Abstract: Oraganopolysiloxanes of the general formula ##STR1## where R.sup.1 =identical or different aliphatic or aromatic hydrocarbon radicals,R.sup.2 =CH.sub.2 CH.sub.2 O(CR.sup.4 R.sup.5).sub.x OC(O)CR.sup.6 .dbd.CHR.sup.7, whereR.sup.4, R.sup.5, R.sup.6 and R.sup.7can be identical or different radicals and are each a H or alkyl radical, branched or unbranched, having up to a total of 6 C atoms and x has a value from 3 to 11, where --(CR.sup.4 R.sup.5)-- can also be a cyclic aliphatic or aromatic radical,R.sup.3 =R.sup.2 or R.sup.1,a=0 to 50 andb=0 to 500,but at least one radical R.sup.2 is attached terminally and/or laterally.Type: GrantFiled: December 1, 1997Date of Patent: November 2, 1999Assignee: Th. Goldschmidt AGInventors: Thomas Ebbrecht, Georg Feldmann-Krane, Stefan Silber, Stefan Stadtmuller
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Patent number: 5977243Abstract: The invention relates to aliphatically unsaturated organosilicon compounds having 2 to 17 silicon atoms, to processes for their preparation and to their use in crosslinkable organopolysiloxane compositions, especially in compositions which can be crosslinked peroxidically or by hydrosilylation.Type: GrantFiled: December 4, 1996Date of Patent: November 2, 1999Assignee: Wacker-Chemie GmbHInventors: Herbert Barthel, Johann Schuster, Richard Weidner, Michael Stepp, Volker Frey
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Patent number: 5969035Abstract: Low molecular weight siloxane fluids are thickened by silicone elastomers. The silicone elastomers are made by crosslinking reactions of .tbd.Si--H containing siloxanes and an unsaturated hydrocarbon such as an alpha, omega-diene, in the presence of a low molecular weight siloxane fluid. The .tbd.SiH siloxane is first partially reacted with either a monoacrylate functionalized polyether or a monomethacrylate functionalized polyether. It is then crosslinked by the alpha, omega-diene in the presence of the low molecular weight siloxane fluid. An elastomer, i.e. gel, with polyether groups is produced. The elastomer gel can be swollen with the low molecular weight siloxane fluid under shear force to provide a uniform silicone paste. The silicone paste has excellent spreadability upon rubbing, and possesses unique Theological properties in being thixotropic and shear thinning.Type: GrantFiled: February 6, 1998Date of Patent: October 19, 1999Inventors: David Randall Meinhardt, Shizhong Zhang
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Patent number: 5948339Abstract: Acetylenic maleates, fumarates and related derivative compounds are new compositions of matter having the formula:R.sub.1 O.sub.2 C--CH.dbd.CH--CO.sub.2 R.sub.2wherein R.sub.1 may be an organic moiety containing at least two carbon atoms triply bonded one to the other as:--C.tbd.C--and R.sub.2 may be hydrogen, an organic moiety, or R.sub.1 ; suitable for use as liquid injection molding inhibitors either singly or in combination with themselves or other liquid injection molding inhibitors when used for the process of liquid injection molding curable compositions enabling an increase in the size of articles manufactured therefrom, which new compositions of matter cure into the polymerizable or curable resins thereby creating new compositions of matter as cured resins from which said articles of manufacture are produced.Type: GrantFiled: November 19, 1997Date of Patent: September 7, 1999Assignee: General Electric CompanyInventors: Philip J. McDermott, Michael J. O'Brien, Edward M. Jeram
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Patent number: 5942591Abstract: A solventless curable silicone release composition contains (A) a branched organopolysiloxane having a vinyl group attached to a silicon atom at an end of its molecular chain, (B) an organohydrogenpolysiloxane having at least three SiH groups in a molecule, and (C) a platinum group metal catalyst. The composition is easily applicable to a thin gage and cures into a releasable silicone coating ensuring light release at high speeds. A release sheet having the cured coating formed thereon has improved release characteristics.Type: GrantFiled: June 19, 1997Date of Patent: August 24, 1999Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hideyuki Itoh, Toshio Ohba, Kenichi Isobe, Shinji Irifune, Takamasa Toyoda
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Patent number: 5932649Abstract: Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materials also are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.Type: GrantFiled: November 1, 1993Date of Patent: August 3, 1999Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Daniel F. Graves
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Patent number: 5929164Abstract: A method of thickening solvents involves reacting (A) an .tbd.Si--H containing polysiloxane with (B) an alpha, omegadiene; conducting the reaction in the presence of a platinum catalyst and (C) a solvent; continuing the reaction until a gel is formed by crosslinking and addition of .tbd.Si--H across double bonds in the alpha, omega-diene; adding additional solvent and a post cure quenching agent to the gel; and subjecting the solvent, the post cure quenching agent, and the gel to shear force until a paste is formed.Type: GrantFiled: November 5, 1997Date of Patent: July 27, 1999Assignee: Dow Corning CorporationInventor: Shizhong Zhang
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Patent number: 5928794Abstract: This invention relates to the preparation of an addition curable composition having self adhesion to substrates. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 1.4 hydrosilyl groups per molecule, a platinum group metal containing catalyst, an alkoxy silicon compound and a titanium compound having Ti--O--C bonds. Another embodiment of this invention is a method of adhering the addition curable composition to a substrate surface.Type: GrantFiled: December 3, 1997Date of Patent: July 27, 1999Assignees: Dow Corning GmbH, Dow Corning CorporationInventors: Robert Edward Kalinowski, Mary Kay Tomalia, Andreas Thomas Franz Wolf, Ming Hsiung Yeh
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Patent number: 5922816Abstract: A polyester-polycarbonate composition comprising (A) at least one polyester prepared by the reaction of at least one alkenediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst, (B) at least one polycarbonate, (C) at least one silyl phosphate, the silyl phosphate being present in an amount effective to inhibit ester-carbonate interchange in the composition, optionally, (D) an organic or inorganic colorant, particularly, acid sensitive organic or inorganic colorants, (E) an impact modifier, and (F) a stabilizer. A method for stabilizing polyester-polycarbonate compositions against ester-carbonate interchange is also provided.Type: GrantFiled: April 17, 1995Date of Patent: July 13, 1999Assignee: General Electric CompanyInventor: Douglas George Hamilton