Abstract: A water-soluble reactive binder, characterized by a combination of at least three of the components(a) at least one halogen-free polycarboxylic acid compound;(b) at least one salt-forming substance selected from the group consisting of alkali metal, alkaline earth metal and quaternary ammonium salts, organic bases and ammonia;(c) at least one component selected from the group consisting of(c1) a polymer containing OH groups; and(c2) an epoxide compound,wherein the components (a) to (c2) are present as such or at least partially in chemically bonded form, a process for its preparation, an article coated with said binder and an adhesive containing said binder.
Type:
Grant
Filed:
March 16, 1979
Date of Patent:
December 23, 1980
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Kurt Kraft, Gerd Walz, Thaddaus Wirth, Ernst-August Theiling
Abstract: Boron containing phenol/formaldehyde resins can be isolated from their reaction media by evaporating said resins in a spiral flow evaporator which has a ratio between throughput and tube cross section from 0.1 to 1.5 and a ratio between throughput and evaporation surface from 100 to 400.
Type:
Grant
Filed:
November 6, 1979
Date of Patent:
November 4, 1980
Assignee:
Bayer Aktiengesellschaft
Inventors:
Manfred Schmidt, Eberhard Bandtel, Walter Traudisch, Georg Spott, Dieter Freitag
Abstract: Infusible cured phenolic resin fibers of the present invention have a birefringence of at least 2.times.10.sup.-3 with the x-ray diffraction pattern of the fibers showing an amorphous halo. The tenacity of infusible cured phenolic resin fibers is significantly increased by subjecting the fibers to sufficient longitudinal tension as to cause at least about 30% elongation of the fibers. The Young's modulus of elasticity of the fibers is also significantly increased thereby. Preferably the resulting stretched infusible cured phenolic resin fibers have a tenacity of at least about 4 g./den.
Type:
Grant
Filed:
May 22, 1978
Date of Patent:
June 10, 1980
Assignee:
The Carborundum Company
Inventors:
James Economy, Francis J. Frechette, Luis C. Wohrer
Abstract: The present invention provides fibres of urea formaldehyde, melamine formaldehyde, phenol formaldehyde, and mixtures thereof, modified by inorganic oxyacid radicals derived from inorganic oxyacids of sulphur, salts of such inorganic oxyacids, phosphate radicals, phosphite radicals, borate radicals and mixtures thereof.
Type:
Grant
Filed:
December 5, 1977
Date of Patent:
May 13, 1980
Assignee:
Imperial Chemical Industries Limited
Inventors:
Richard G. C. Henbest, Kenneth McGregor
Abstract: Phenol-formaldehyde resoles and novalacs are cured at temperatures of from about 0.degree. C. to about 150.degree. C. and at pressures ranging from about atmospheric pressure to about 5 atmospheres to produce highly cross-linked resins when divinylbenzene is used as a cross-linking agent together with a minor amount of an acidic catalyst.
Abstract: Flameproof reinforced and/or filled polyamide moulding compositions containing a combination of red phosphorus and phenol/aldehyde resins as flameproofing agent.
Type:
Grant
Filed:
July 25, 1978
Date of Patent:
March 18, 1980
Assignee:
Bayer Aktiengesellschaft
Inventors:
Peter Tacke, Dieter Neuray, Dietrich Michael
Abstract: The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO).sub.2 B--O--B--(OR).sub.2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C.sub.1 -C.sub.4 alcohol.
Type:
Grant
Filed:
February 2, 1979
Date of Patent:
January 8, 1980
Assignee:
Bayer Aktiengesellschaft
Inventors:
Manfred Schmidt, Dieter Freitag, Hermann Fries, Erich Esch
Abstract: The title compounds are of the formula P --O--R--.sub.n R').sub.mwherein:P is a polymer matrix of sufficient structure and molecular weight so as to be substantially water- and hydrocarbon-insoluble;R is --CH.sub.2 CH.sub.2 O--, --CH.sub.2 CH.sub.2 CH.sub.2 O--, ##STR1## --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 O- or a combination thereof; R' is hydrogen, hydrocarbyl or inertly-substituted hydrocarbyl;n is an integer of 3 to about 40; andm is a real number such that the weight percent of --O--R--.sub.n R') groups is at least about 1 percent of the total weight of the compound.A representative example of these compounds is the reaction product of a poly(ethyleneglycol ether) having a weight average molecular weight of about 300 and a chloromethylated polystyrene resin. These polymer-supported poly (alkyleneglycol ethers) are useful phase-transfer catalysts for a wide variety of reactions, such as alkylation, displacement and carbene formation.