Mixed With A Reactant Containing More Than One 1,2-epoxy Group Per Mole Or Polymer Derived Therefrom Patents (Class 525/524)
  • Patent number: 11851603
    Abstract: A highly thermally conductive composition is provided, such composition comprising: (A) An organopolysiloxane composition; (B) a filler treating agent; (C) a thermal stabilizer; and (D) thermally conductive filler mixture, comprising: (D-1) a small-particulate thermally conductive filler having a mean size of up to 3 ?m, (D-2) spherical aluminum nitride having a mean size of from 50 to 150 ?m, (D-3) boron nitride having a mean size of from 20 to 200 ?m.
    Type: Grant
    Filed: November 7, 2018
    Date of Patent: December 26, 2023
    Assignees: DOW SILICONES CORPORATION, DOW GLOBAL TECHNOLOGIES LLC (DGTL)
    Inventors: Xiaolian Hu, Jiguang Zhang, Yan Zheng, Hongyu Chen, Chen Chen, Dorab Bhagwagar, Darren Hansen
  • Patent number: 11390783
    Abstract: An adhesive comprising a getter material and optionally a solvent comprising a catalyst activatable by means of an external stimulus for the reaction of the getter material with a permeate can tolerate brief contact with permeates such as moisture in particular before user application, without any significant impairment of getter capacity.
    Type: Grant
    Filed: June 3, 2019
    Date of Patent: July 19, 2022
    Assignee: TESA SE
    Inventors: Christian Schuh, Klaus Keite-Telgenbüscher, Chris Gäbert
  • Patent number: 11274245
    Abstract: To provide a curable composition which can easily form an optical film with good fluorescence efficiency and includes quantum dots (B), a film made of a cured product of the curable composition, an optical film for a light-emitting display element made of the film, a light-emitting display element panel including the optical film, and a light-emitting display equipped with the light-emitting display element panel. A film is formed by curing a curable composition which includes an epoxy compound (A) having two or more epoxy groups and including a cyclic structure other than an oxirane ring, quantum dots (B), and an acid generator (C).
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: March 15, 2022
    Assignee: TOKYO OHKA KOGYO CO., LTD.
    Inventors: Hiroki Chisaka, Kunihiro Noda, Dai Shiota
  • Patent number: 10947428
    Abstract: Disclosed herein are compositions including (a) a first component comprising (1) an epoxy-adduct that is the reaction product of reactants comprising a first epoxy compound, a polyol, and an anhydride and/or a diacid and (2) a second epoxy compound; (b) rubber particles having a core/shell structure and/or graphenic carbon particles; and (c) a second component that chemically reacts with the first component at ambient or slightly thermal conditions. Also disclosed herein are compositions including (a) an epoxy-capped flexibilizer; (b) a heat-activated latent curing agent; and optionally (c) rubber particles having a core/shell structure and/or graphenic carbon particles; (d) an epoxy/CTBN adduct; and/or (e) an epoxy/dimer acid adduct. The heat-activated latent curing agent may include at least one reaction product of reactants including an epoxy compound and an amine and/or an alkaloid.
    Type: Grant
    Filed: December 7, 2015
    Date of Patent: March 16, 2021
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Umesh C. Desai, Tien-Chieh Chao, Masayuki Nakajima, Kaliappa G. Ragunathan
  • Patent number: 10363724
    Abstract: A resin composition including an epoxy resin (A), a curing agent (B), and vinyl polymer particles (C), in which the contained amount of epoxy resin (a1) having a molecular weight of 100-480 is 30-90 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of epoxy resin (a2) having a molecular weight of 2,000-40,000 is 10-70 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of the vinyl polymer particles (C) is 2-30 parts by mass per 100 parts by mass of the epoxy resin (A), and the instantaneous maximum thickening value of the vinyl polymer particles obtained by the following method is 0.3-5.0 Pa·s/° C.
    Type: Grant
    Filed: October 14, 2015
    Date of Patent: July 30, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Takuya Teranishi, Akira Oota, Masahiro Ichino, Toru Kondo
  • Patent number: 10358565
    Abstract: The present invention relates to a UV-curable ink composition, a method for producing a bezel pattern of a display substrate using same, and a bezel pattern produced thereby, the UV-curable ink composition comprising a colorant, an epoxy compound, an oxetane compound and a photopolymerization initiator, wherein the content ratio of the epoxy compound to the oxetane compound is 1:0.5-1:6.
    Type: Grant
    Filed: September 30, 2015
    Date of Patent: July 23, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Sung-Eun Park, Yong-Sung Goo, Seung-A Back, Joon-Hyung Kim
  • Patent number: 10329465
    Abstract: The present invention relates to adhesive compositions containing a prepolymer which can be obtained by reacting a reaction mixture containing: at least one epoxy resin; at least one polyetherdiamine or polyethertriamine; at least one carboxyl-terminated butadiene-acrylonitrile copolymer (CTBN); and rubber particles having a core/shell structure. The invention also relates to methods for curing said compositions, to the cured adhesive compositions thus obtained, to the use thereof for bonding components and to the components thus obtained.
    Type: Grant
    Filed: June 19, 2017
    Date of Patent: June 25, 2019
    Assignee: Henkel AG & Co. KGaA
    Inventors: Christian Holtgrewe, Harald Kuester, Thomas Bachon, Rainer Schoenfeld
  • Patent number: 10287478
    Abstract: Curable resin compositions comprising an epoxy resin and a hydrazide curing agent and methods for using the curable resin compositions in cementing and/or remedial operations in a subterranean formation are provided. In one embodiment, the method may comprise combining an epoxy resin and a curing agent to form a curable resin composition, wherein the curing agent comprises a hydrazide curing agent; introducing the curable resin composition into a subterranean formation; and allowing the curable resin composition to at least partially cure.
    Type: Grant
    Filed: January 16, 2015
    Date of Patent: May 14, 2019
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Matthew Grady Kellum, Gregory Robert Hundt, Paul Joseph Jones, Jeffery Dwane Karcher
  • Patent number: 10010907
    Abstract: The present invention provides a method for color register spraying of a hub, which includes machining and turning for glossy finish after spraying a black paint on the surface of a hub, and then spraying a color transparent paint onto the hub. The method provided by the invention achieves a spraying-based color register effect through spraying of the color transparent paint, which greatly improves the production efficiency and is available for batch production.
    Type: Grant
    Filed: June 22, 2016
    Date of Patent: July 3, 2018
    Assignee: CITIC Dicastal CO., LTD
    Inventors: Le Zhang, Shengchao Zhang, Yongning Wang, Zhihua Zhu, Changhai Li
  • Patent number: 10011678
    Abstract: The invention relates to a binder resin which is a plastified epoxide-amine adduct P comprising an adduct EA made of epoxide resins E and amines A, optionally modified by incorporation of unsaturated fatty acids F?, which adduct is plastified by incorporation of a fatty acid amide M, or a mixture M? of the said fatty acid amide M with a glyceride mixture GX which is a mixture of at least two glycerides selected from the group consisting of a triglyceride GT, a diglyceride GD, and a monoglyceride GM, to a process for its preparation, and to a method of use thereof as primer for wood, mineral, and metal substrates.
    Type: Grant
    Filed: October 21, 2014
    Date of Patent: July 3, 2018
    Assignee: ALLNEX AUSTRIA GMBH
    Inventor: Roland Feola
  • Patent number: 9957387
    Abstract: An epoxy resin composition having components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×103 to about 1×104 Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) are as follows: (A) About 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin blend; (B) Dicyandiamide; (C) Diaminodiphenyl sulfone and (D) Urea compound.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: May 1, 2018
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Nobuyuki Arai, Alfred P. Haro, Jonathan C. Hughes, Norimitsu Natsume
  • Patent number: 9670356
    Abstract: A matrix material for a carbon fiber-reinforced composite comprises a matrix resin as a resin component. The matrix resin contains both a first epoxy resin and a second epoxy resin or only the first epoxy resin, further contains a third epoxy resin, and has an average epoxy equivalent weight of 109 to 162. The first epoxy resin contains a polyfunctional glycidylamine-type epoxy resin. The second epoxy resin contains at least one of a p-aminophenol-type epoxy resin and a tetramethylbiphenol-type solid epoxy resin. The third epoxy resin contains a bisphenol A-type epoxy resin having a weight-average molecular weight of 8000.
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: June 6, 2017
    Assignees: HONDA MOTOR CO., LTD., FUKUI PREFECTURAL GOVERNMENT
    Inventors: Shuichiro Yoshida, Keiichi Kondo
  • Patent number: 9598573
    Abstract: A curable resin composition which comprising (A), (B) and (C) as follows: (A) 100 parts by mass of polyfunctional epoxy component which contains (A1) a trifunctional epoxy compound having three glycidyl groups in a molecule and (A2) a tetrafunctional epoxy compound having four glycidyl groups in a molecule, wherein (A1):(A2) is 10:90 to 90:10 in terms of mass; (B) 25 to 200 parts by mass of a cyanic acid ester compound having two or more of cyanato groups; and (C) 0.5 to 20 parts by mass of an imidazole compound as a curing agent.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: March 21, 2017
    Assignee: Adeka Corporation
    Inventors: Yuichiro Deguchi, Takahiro Mori, Yoshihiro Fukuda, Takeru Ohtsu
  • Patent number: 9574045
    Abstract: The present invention provides an epoxy resin composition including an epoxy resin represented by the following formula (1) and an epoxy resin represented by the following formula (2):
    Type: Grant
    Filed: July 31, 2013
    Date of Patent: February 21, 2017
    Assignee: ASAHI KASEI E-MATERIALS CORPORATION
    Inventors: Teruhisa Yamada, Kenzo Onizuka, Kozo Yoshida, Seiji Yamaguchi
  • Patent number: 9315704
    Abstract: A pressure sensitive adhesive construct comprising: (a) a backing substrate; and (b) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive includes a product made from at least one epoxidized vegetable oil and at least one dibasic acid or anhydride, or a combination of a dibasic acid or anhydride and a monobasic acid or anhydride.
    Type: Grant
    Filed: June 7, 2011
    Date of Patent: April 19, 2016
    Assignee: Oregon State University
    Inventors: Kaichang Li, Anlong Li
  • Patent number: 9284434
    Abstract: A re-epoxidized polyfunctional epoxy resin composition comprising the reaction product of: (I) an epoxidized polyfunctional epoxy resin oligomeric composition comprising a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of: (i) an aliphatic or cycloaliphatic hydroxyl-containing material; (ii) an epihalohydrin, (iii) a basic-acting substance, in the presence of (iv) a non-Lewis acid catalyst; and (v) optionally, one or more solvents; (II) an epihalohydrin; (III) a basic acting substance; in the presence of (IV) a non-Lewis acid catalyst; and (V) optionally, one or more solvents. A curable epoxy resin composition of the re-epoxidized polyfunctional epoxy resin composition and a thermoset of the curable composition is also disclosed.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: March 15, 2016
    Assignee: BLUE CUBE IP LLC
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 9255177
    Abstract: A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.
    Type: Grant
    Filed: June 14, 2012
    Date of Patent: February 9, 2016
    Assignee: Blue Cube IP LLC
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 9157013
    Abstract: A solid dry to the touch at ambient temperature structural adhesive which can be cured at elevated temperature and which can be molded at an intermediate temperature is provided as well as the use of the adhesive for bonding metals.
    Type: Grant
    Filed: May 9, 2011
    Date of Patent: October 13, 2015
    Assignee: Zephyros, Inc.
    Inventor: Michael Czaplicki
  • Patent number: 9068074
    Abstract: An object of the present invention is to provide a composition for the formation of a cured epoxy resin, wherein the composition can suppress a curing reaction at a low temperature to thereby enhance one-pack stability, and can also be subjected to a heating treatment to thereby effectively cure a resin. The present invention provides a composition for the formation of a cured epoxy resin, the composition comprising the following components (A), (B) and (C): (A) an epoxy resin; (B) a clathrate compound of a carboxylic acid derivative represented by formula (I): R(COOH)n??(I); and an imidazole compound represented by formula (II); and (C) a tetrakisphenol type compound represented by formula (III).
    Type: Grant
    Filed: October 15, 2010
    Date of Patent: June 30, 2015
    Assignees: NIPPON SODA CO., LTD., NISSO CHEMICAL ANALYSIS SERVICE CO., LTD.
    Inventors: Kazuo Ono, Natsuki Amanokura, Hitoshi Matsumoto, Emi Nakayama
  • Patent number: 9040607
    Abstract: An adhesive composition includes a first part comprising about 15 to about 60 wt % of an epoxy compound, about 35 to about 80 wt % of an epoxy novolac, and about 5 to about 25 wt % of an epoxy-based reactive diluent based on the total weight of epoxy compound, epoxy novolac, and reactive diluent; and a second part comprising less than about 20 wt % of a hydroxyaromatic solvent, about 80 to about 99 wt % of a Mannich base, and about 1 to about 20 wt % of a tertiary amine, based on the total weight of hydroxyaromatic solvent, Mannich base, and tertiary amine, the first and second parts being present in a volume ratio of about 0.8:1 to about 1.2:1. Additives to further enhance the properties may be included. A method of forming an adhesive layer includes applying the adhesive composition to a surface.
    Type: Grant
    Filed: March 13, 2012
    Date of Patent: May 26, 2015
    Assignee: BLACK & DECKER INC.
    Inventor: James E. Surjan
  • Publication number: 20150119500
    Abstract: This invention relates to an epoxy resin composition and its application in marine maintenance and repair coating with improved overcoatability.
    Type: Application
    Filed: April 24, 2012
    Publication date: April 30, 2015
    Applicant: Dow Global Technologies LLC
    Inventors: Amy Song, Hongyu Chen
  • Publication number: 20150093320
    Abstract: A liquid carbon precursor composition including (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid composition prior to adding optional components and curing, has a neat viscosity of less than 10,000 mPa-s, at 25° C.; and wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25° C. prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; a cured liquid carbon precursor composition; a carbonized material made from the above liquid carbon precursor composition; and processes for producing the above compositions.
    Type: Application
    Filed: May 17, 2013
    Publication date: April 2, 2015
    Inventors: Hamed H. Lakrout, Maurice J. Marks, Ludovic Valette
  • Patent number: 8974905
    Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer.
    Type: Grant
    Filed: October 13, 2014
    Date of Patent: March 10, 2015
    Assignee: Cytec Technology Corp.
    Inventors: Junjie Jeffrey Sang, Dalip Kumar Kohli, Kunal Gaurang Shah
  • Publication number: 20150018456
    Abstract: Disclosed herein are polyglycidyl ethers of the formula: where R, m, Q, p and Z are as defined here. Also disclosed are methods of forming said polyglycidyl ethers and methods of using said polyglycidyl ethers to make epoxy resin oligomers and polymers, including powder coatings.
    Type: Application
    Filed: February 22, 2013
    Publication date: January 15, 2015
    Inventors: Robert E. Hefner, JR., Erich J. Molitor
  • Patent number: 8928158
    Abstract: An epoxy resin composition for encapsulating a semiconductor device includes a curing agent, a curing accelerator, inorganic fillers, and an epoxy resin, the epoxy resin including a first resin represented by Formula 1: wherein R1 and R2 are each independently hydrogen or a C1 to C4 linear or branched alkyl group, and n is a value from 1 to 9 on average.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: January 6, 2015
    Assignee: Cheil Industries Inc.
    Inventors: Seung Han, Ju Mi Kim, Sung Su Park, Eun Jung Lee
  • Patent number: 8921497
    Abstract: An adhesive for anchoring materials in or to concrete or masonry exhibits a shorter cure time than previous adhesives and comprises an epoxy compound and a curing agent of at least one aliphatic amine and at least one tertiary amine, optionally with a reactive dilent, which possesses sufficent strength to pass ICBO Heat Creep Test at 110 degrees F. and the ICBO Damp Hole Test at 75 degrees F.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: December 30, 2014
    Assignee: Illinois Tool Works Inc.
    Inventor: Jim Surjan
  • Patent number: 8916656
    Abstract: A glass printing ink and a glass printing lacquer comprising at least one pigment, at least one photoinitiator, at least two resins and radicial photoinitiators. One resin is an epoxy resin having an average molecular weight based on bisphenol A, diluted in a UV hardening monomer. The other resin is a resin which contains free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups. Also, the use of the glass printing ink and glass printing lacquer when printing a glass substrate and to a method for printing a glass substrate.
    Type: Grant
    Filed: July 1, 2013
    Date of Patent: December 23, 2014
    Assignee: Marabu GmbH & Co., KG
    Inventors: Saskia Lehmann, Wolfgang Schaefer
  • Patent number: 8912295
    Abstract: It is an object to provide a liquid thermosetting composition that yields an epoxy resin having physical properties of the cured product such as high flexural strength along with adequate handleability as liquid, to be used in transparent sealants for optical semiconductors, such as transparent sealants for LEDs (light-emitting devices) and the like. There is provided a thermosetting composition containing an epoxy compound that a side chain between a triazinetrione ring and an epoxy group substituted on the triazinetrione ring is long (elongated).
    Type: Grant
    Filed: February 9, 2010
    Date of Patent: December 16, 2014
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Toshiaki Takeyama, Takeo Moro
  • Patent number: 8907025
    Abstract: The present invention is to provide an adhesive agent composition, including: a main agent containing a polyether polyurethane polyol and a bisphenol A-type epoxy resin; and a curing agent, wherein the polyether polyurethane polyol is obtained by reacting a polyalkylene glycol including repeating units each having a carbon number of 3 or 4 and an alkane diol monomer with an organic diisocyanate at an equivalent ratio (NCO/OH) of 0.7 or more but less than 1, a weight average molecular weight thereof is in the range of 20,000 to 70,000, and an urethane bond equivalent thereof is in the range of 320 to 600 g/eq, and wherein a number average molecular weight of the bisphenol A-type epoxy resin is in the range of 400 to 5,000, and the bisphenol A-type epoxy resin is of a solid state or a semisolid state at normal temperature.
    Type: Grant
    Filed: January 20, 2012
    Date of Patent: December 9, 2014
    Assignee: Toyo Ink SC Holdings Co., Ltd.
    Inventors: Hiroki Sugi, Bungo Yasui, Seiji Maeda, Katsuyuki Ueki, Kenshiro Shimada
  • Patent number: 8895148
    Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: November 25, 2014
    Assignee: Cytec Technology Corp.
    Inventors: Junjie Jeffrey Sang, Dalip Kumar Kohli, Kunal Gaurang Shah
  • Patent number: 8889803
    Abstract: To provide an epoxy polymerizable composition which exhibits low curing shrinkage and high workability and which gives a cured article having a high refraction index and high heat resistance. The epoxy polymerizable composition contains (A2) fluorene epoxy compound having the following general formula (1) or (2), (A3) epoxy compound having a softening point of 30° C. or less, and (B1) thiol compound having two or more thiol groups in one molecule.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: November 18, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yasushi Takamatsu, Yugo Yamamoto, Yuichi Ito
  • Publication number: 20140316081
    Abstract: The present invention provides a cationically curable resin composition for assembling hard disk devices which comprises a resin having a cationically polymerizable functional group (a component A) and a cationic polymerization initiator (a component B), the component B being at least one selected from the group consisting of X+(SbF6)?(B1), X+(B(C6F5)4)?(B2) and X+((Rf)nPF6-n)?(B3) (in the formulae, X+ is iodonium or sulfonium, Rf is a fluorinated alkyl having 1 to 6 carbon atoms, and n is an integer of 1 to 6). The invention also provides a hard disk device manufacturing method using the composition, and a hard disk device assembled with the composition.
    Type: Application
    Filed: November 20, 2012
    Publication date: October 23, 2014
    Applicant: KYORITSU CHEMICAL & CO., LTD.
    Inventors: Shigeki Toyama, Yoshitomo Denpou
  • Patent number: 8865143
    Abstract: A reversely thermo-reversible hydrogel composition comprising a water soluble block copolymer comprising at least two blocks of polyethylene oxide and at least one block of polypropylene oxide, and at least one associative gelling adjuvant having water solubility less than 0.5 g/100 ml, preferably less than 0.3 g/100 ml at 20° C., and being capable of forming water soluble inter-molecular complexes with the water soluble block copolymer in water. The hydrogel composition exhibits improved gelling efficiency, enhanced solubility and/or stability for water sparely soluble and insoluble pharmaceutical agents. The hydrogel compositions are useful in a variety of pharmaceutical and cosmetic products and applications, such as esophageal, otic, vaginal, rectal, ophthalmic, treatments of disorders and imperfections of the skin, and treating and/or preventing alopecia and restoring and/or promoting hair growth.
    Type: Grant
    Filed: March 21, 2012
    Date of Patent: October 21, 2014
    Assignee: Broda Technologies Co., Ltd.
    Inventors: Shao Xiang Lu, Jeffrey Lu, Letian Liu
  • Patent number: 8859695
    Abstract: A hem-curing epoxy resin composition, that includes an epoxy resin A having more than one epoxy group per molecule on average; a curing agent B for epoxy resins, which is activated at a temperature in a range of 100° C. to 220° C.; and an activator C for epoxy resin compositions, wherein activator C is a compound of formula (I), or is a reaction product between a compound of formula (Ia) and an isocyanate or an epoxide.
    Type: Grant
    Filed: May 29, 2013
    Date of Patent: October 14, 2014
    Assignee: Sika Technology AG
    Inventors: Karsten Frick, Ulrich Gerber, Juergen Finter, Andreas Kramer
  • Publication number: 20140275343
    Abstract: An epoxy resin adduct comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least one reactive compound having two or more active hydrogen atoms per molecule, wherein the active hydrogen atoms are reactive with epoxide groups are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Curable compositions, methods of curing, cured compositions, and articles comprising the epoxy resin adducts are also disclosed. The epoxy resin adduct has improved cure behavior and provides cured compositions having increased glass transition temperature, good weatherability, and a low total chlorine content.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 18, 2014
    Inventors: Robert E. Hefner, JR., Ray E. Drumright
  • Patent number: 8815401
    Abstract: A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: August 26, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yoshihiro Kato, Takeshi Nobukuni, Masayoshi Ueno
  • Publication number: 20140235792
    Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.
    Type: Application
    Filed: April 29, 2014
    Publication date: August 21, 2014
    Inventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George C. Jacob, Marty J. Null
  • Publication number: 20140213697
    Abstract: The present invention relates to a curable composition which comprises epoxy resin, epoxy-group-bearing reactive diluent and the hardener 2,2?,6,6?-tetramethyl-4,4?-methylenebis(cyclohexylamine), curing thereof, and the cured epoxy resin obtainable therefrom, and the use of 2,2?,6,6?-tetramethyl-4,4?-methylenebis(cyclohexylamine) as a hardener for epoxy resins in curable compositions with epoxy-group-bearing reactive diluent.
    Type: Application
    Filed: January 27, 2014
    Publication date: July 31, 2014
    Applicant: BASF SE
    Inventors: Achim KAFFEE, Miran YU, Monika CHARRAK, Kirsten DAHMEN, Veit STEGMANN, Gerd HADERLEIN, Alexander PANCHENKO
  • Patent number: 8785524
    Abstract: A spray coatable adhesive composition used for bonding silicon dies to a rigid substrate, preferable a silicon substrate is disclosed. The adhesive composition includes an epoxy based resin, a thermal acid generator, a photoacid generator and a solvent. The epoxy based resin includes a mixture of a solid bisphenol A epoxy resin and a liquid or semi-liquid hydrogenated bisphenol A epoxy resin at a weight ratio ranging from about 80:20 to about 65:35. The adhesive composition has a low viscosity which allows it to be spray coated on a rigid substrate and form thin film adhesive which allows silicon dies to be bonded with precise placement on the silicon substrate.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: July 22, 2014
    Assignee: Funai Electric Co., Ltd.
    Inventors: Xiaoming Wu, Paul Dryer, David Rhine, Anna Pearson, Jeanne Marie Saldanha Singh, Richard Wells, Joel Provence
  • Publication number: 20140182903
    Abstract: An object is to provide a resin composition that has excellent dielectric properties, that yields a highly heat-resistant cured product, that provides a low viscosity when made into a varnish, and that has a high Tg and a high flame retardancy without containing halogen. The resin composition contains a polyarylene ether copolymer (A) that has an intrinsic viscosity, measured in methylene chloride at 25° C., of 0.03 to 0.12 dL/g and that has an average of 1.5 to 3 phenolic hydroxyl groups in molecular terminal position per molecule, a triphenylmethane-type epoxy resin (B) that has a softening point of 50 to 70° C., and a cure accelerator (C), wherein the content of the polyarylene ether copolymer (A) is 60 to 85 mass parts where the total of the polyarylene ether copolymer (A) and the epoxy resin (B) is 100 mass parts.
    Type: Application
    Filed: July 13, 2012
    Publication date: July 3, 2014
    Applicant: PANASONIC CORPORATION
    Inventors: Takashi Sagara, Hidetaka Kakiuchi, Keiko Kashihara, Yuki Kitai, Hirosuke Saito, Daisuke Yokoyama, Hiroaki Fujiwara
  • Patent number: 8765835
    Abstract: There is provided a curable composition having a low viscosity and high cationic curability. A curable composition including an epoxy compound of Formula (1): [in Formula (1), A is a monocyclic aliphatic hydrocarbon group optionally containing an epoxy group; R1, R2, R3 and R4 are independently a hydrogen atom or a C1-10 alkyl group; n1 and n2 are independently an integer of 2 to 6; n3 and n4 are individually an integer of 2; and n5 and n6 are individually an integer of 1], and an acid generator.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: July 1, 2014
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Toshiaki Takeyama, Yuki Endo, Sayoko Yanagisawa
  • Patent number: 8758549
    Abstract: The present invention relates to heat-curable compositions containing a mixture of reactive epoxy resins that contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and at least one latent hardener.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: June 24, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Pablo Walter, Mustapha Benomar, Stefan Kreiling, Angelika Troll, Rainer Schoenfeld
  • Patent number: 8759422
    Abstract: An adhesive composition comprising elastomeric polymer, epoxy resin, reactive diluent, and filler, is suitable for use within the electronics industry, and in particular for wafer back side coating adhesives. The elastomeric polymer is a mixture of a vinyl elastomer and an epoxy elastomer; the reactive diluent is a combination of two or more diluents, one of which must have carbon to carbon unsaturation, providing cross-linking within the composition after cure; and the filler is a non-conductive filler.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: June 24, 2014
    Assignee: Henkel IP & Holding GmbH
    Inventors: Eric C. Wang, Kevin Harris Becker, Qizhuo Zhuo
  • Publication number: 20140163180
    Abstract: A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.
    Type: Application
    Filed: June 14, 2012
    Publication date: June 12, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventor: Robert E. Hefner, JR.
  • Patent number: 8742018
    Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.
    Type: Grant
    Filed: January 5, 2009
    Date of Patent: June 3, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George Jacob, Marty J. Null
  • Patent number: 8722816
    Abstract: A solder resist having both adequate sensitivity at photo-irradiation and alkali developability, and the solder resist forming a cured product which is excellent in dimensional stability against temperature change, does not exhibit brittleness, and further, is excellent in water resistance, electrical insulation, thermal cycle test resistance (TCT resistance) and the like is provided, and further, a dry film having a solder resist layer, a cured product and a printed wiring board are provided. The solder resist comprising an acid-modified vinyl ester synthesized from an epoxy compound, a phenol compound, an unsaturated monobasic acid and a polybasic acid anhydride, wherein the epoxy compound contains a crystalline epoxy resin having a melting point of 90° C. or more, and the phenol compound contains a compound having a bisphenol S structure.
    Type: Grant
    Filed: March 4, 2008
    Date of Patent: May 13, 2014
    Assignees: Nippon Shokubai Co., Ltd., Taiyo Holdings Co., Ltd.
    Inventors: Nobuaki Otsuki, Manabu Akiyama, Shouji Minegishi, Masao Arima
  • Patent number: 8716413
    Abstract: A method for the preparation of a photocurable resin by a reaction comprising the following steps i) reacting a mixture of a novolak type epoxy resin (A) and a dicyclopentadiene-phenol glycidylether resin (B) with ii) an advancement component (C) containing at least 2 phenolic hydroxyl groups per molecule; iii) reacting with an unsaturated monocarboxylic acid (D); and iv) esterification of the unsaturated group containing resin obtained from the steps of i) to iii) with a polycarboxylic acid anhydride or a carboxylic acid anhydride (E) is disclosed.
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: May 6, 2014
    Assignee: Huntsman Advanced Materials Americas LLC
    Inventors: Kai Dudde, Sabine Pierau, Martin Roth
  • Patent number: 8717130
    Abstract: The present invention relates to a lacquer composition, particularly an adhesive and corrosion-protective lacquer for rare earth magnets, on the basis of an epoxy resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the lacquer composition includes 5 to 20 wt. %, with respect to the amount of solid resin in the base of the epoxy resin mixture, of a highly viscous epoxy resin based on bisphenol-A with an elastomer content of more than 30 wt. %.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: May 6, 2014
    Assignee: Vacuumschmeize GmbH & Co. KG
    Inventor: Lothar Zapf
  • Patent number: 8686069
    Abstract: The solvent resistance of epoxy resins toughened with polyethersulfone is improved by using low molecular weight polyethersulfone. The resulting thermoplastic toughened epoxy resins are useful for making prepreg for aerospace applications.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: April 1, 2014
    Assignee: Hexcel Corporation
    Inventor: Yen-Seine Wang
  • Patent number: 8673108
    Abstract: This invention relates to compositions useful as adhesives and more particularly to the preparation of epoxy-based adhesive composition with improved impact resistance and good adhesion to oily metal substrates.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: March 18, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Jeng-Li Liang, Rajat K. Agarawal, Gregory A. Ferguson, Olaf Lammerschop, Frank Dittrich, Rainer Schoenfeld