Utilizing An Apparatus With Two Or More Physically Distinct Zones Patents (Class 525/53)
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Patent number: 8106139Abstract: Embodiments of the invention provide a class of mesophase separated propylene/?-olefin block interpolymers with controlled block sequences. The propylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block propylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (“TREF”), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the propylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: January 31, 2012Assignee: Dow Global Technologies LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Li Pi Shan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20120022214Abstract: The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.Type: ApplicationFiled: January 27, 2010Publication date: January 26, 2012Applicant: Dow Global Technologies LLCInventors: Mark B. Davis, Dale M. Elley-Bristow, William J. Michie, JR., Stephanie M. Whited, Theresa J. Hermel-Davidock
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Patent number: 8084544Abstract: Process for preparing a water-absorbent resin comprising carrying out a reversed-phase suspension polymerization in multi-steps of two or more steps. The water-absorbent resin is prepared by subjecting a water-soluble ethylenically unsaturated monomer to the reversed phase suspension polymerization. This process for preparing a water-absorbent resin involves adding an aminocarboxylic acid compound to at least one step in the second and subsequent steps to carry out the polymerization reaction. The resulting water-absorbent resin can be suitably used in a hygienic material. The water-absorbent resin has a high degree of water-retention, including a high degree of water absorption under pressure. It also has a high water absorption rate, and contains only a small amount of water-soluble substances.Type: GrantFiled: June 30, 2006Date of Patent: December 27, 2011Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Shinya Fukudome, Junichi Takatori, Kenya Matsuda, Yasuhiro Nawata
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Patent number: 8080610Abstract: A monomer recycle process for fluid phase in-line blending of polymers is provided.Type: GrantFiled: March 4, 2008Date of Patent: December 20, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Alan Anthony Galuska, James Richardson Lattner
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Publication number: 20110294940Abstract: Method for the preparation of a sticky high impact heterophasic polypropylene (HECO) in a reactor facility comprising in series (i) a first reaction system, (ii) a first conveying line connecting the first reactor system with a second reactor system comprising an outlet, (iii) a second conveying line connecting the outlet with a purge bin comprising a feeder, and (iv) a conveying system being connected with the feeder, and the preparation of said heterophasic polypropylene (HECO) comprises the steps in the order of (a) producing in said first reactor system the polypropylene matrix (M), (b) transferring at least a part of said polypropylene to said second reactor system via the first conveying line, (c) producing in said second reactor system the elastomeric copolymer obtaining the heterophasic polypropylene (HECO), (d) discharging said heterophasic polypropylene (HECO) from said second reactor system via the outlet, (e) transferring said discharged heterophasic polypropylene (HECO) via the second conveying lType: ApplicationFiled: November 18, 2009Publication date: December 1, 2011Applicant: Borealis AGInventors: Pauli Leskinen, Olli Tuominen, Veli-Matti Keinänen
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Publication number: 20110294937Abstract: Method for the preparation of a sticky random propylene copolymer (R-PP) in a reactor facility comprising in series (i) a first reaction system, (ii) a first conveying line connecting the first reactor system with a second reactor system comprising an outlet, (iii) a second conveying line connecting the outlet with a purge bin comprising a feeder, and (iv) a conveying system being connected with the feeder, and the preparation of said random propylene copolymer (R-PP) comprises the steps in the order of (a) producing in said first reactor system a propylene homopolymer (H-PP) or a random propylene copolymer (R-PP1), (b) transferring at least a part of said polypropylene to said second reactor system via the first conveying line, (c) producing in said second reactor system a random propylene copolymer (R-PP2) obtaining the random propylene copolymer (R-PP), (d) discharging said random propylene copolymer (R-PP) from said second reactor system via the outlet, (e) transferring said discharged random propylene coType: ApplicationFiled: November 18, 2009Publication date: December 1, 2011Applicant: Borealis AGInventors: Pauli Leskinen, Olli Tuominen, Veli-Matti Keinänen
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Publication number: 20110293865Abstract: Branched PHA compositions, and related methods and articles are disclosed.Type: ApplicationFiled: June 19, 2009Publication date: December 1, 2011Applicant: Metabolix, Inc.Inventors: Allen R. Padwa, Yelena Kann
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Patent number: 8053529Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer products, said process comprising: 1) contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions in a reactor or reactor zone with a composition comprising at least one olefin polymerization catalyst and a cocatalyst and characterized by the formation of polymer chains from said monomer or monomers; 2) transferring the reaction mixture to a second reactor or reactor zone and optionally adding one or more additional reactants, catalysts, monomers or other compounds prior to, commensurate with, or after said transfer; and 3) causing polymerization to occur in said second reactor or reactor zone to form polymer chains that are differentiated from the polymer chains formed in step 1); said process being characterized by addition of a chain shuttling agent to the reaction mixture prior to, during, or subsequent to step 1) such that at least some of the resultinType: GrantFiled: September 14, 2006Date of Patent: November 8, 2011Assignee: Dow Global Technologies LLCInventors: Edmund M. Carnahan, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel
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Patent number: 8025847Abstract: Reactor systems suitable for the polymerization of an olefin monomer including first and second loop reactors effective for the polymerization of an olefin monomer and polymers formed therefrom are described herein.Type: GrantFiled: May 11, 2010Date of Patent: September 27, 2011Assignee: Total Petrochemicals Research FeluyInventors: Louis Fouarge, Carl VanCamp
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Publication number: 20110207883Abstract: The present invention relates to an impact-resistant olefin polymer composition including a polypropylene matrix having a weight average molecular weight and an ethylene-containing polymer including an ethylene-propylene copolymer having a molecular weight higher than the weight average molecular weight of the polypropylene matrix, the composition containing about 20 to 35 percent xylene solubles, and the xylene solubles fraction of the composition containing less than about 39 weight percent ethylene units, based on the combined weight of olefin monomers in the copolymer. The present invention further relates to impact copolymer compositions with a melt flow rate greater than about 8 that meet or exceed all pallet testing requirements.Type: ApplicationFiled: February 24, 2010Publication date: August 25, 2011Inventors: Antonios K. Doufas, Carol R. Barvinchak, Edward Catalina
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Patent number: 7989551Abstract: A process for the polymerization of one or more addition polymerizable monomers to form a copolymer comprising multiple regions or segments of differentiated polymer composition or properties comprising contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions with a composition comprising at least one olefin polymerization catalyst, a cocatalyst and a chain shuttling agent, said process being characterized by formation of at least some of the growing polymer chains under differentiated process conditions such that two or more blocks or segments formed within at least some of the resulting polymer are chemically or physically distinguishable.Type: GrantFiled: January 30, 2006Date of Patent: August 2, 2011Assignee: Dow Global Technologies LLCInventors: Daniel J. Arriola, Edmund M. Carnahan, Marilyn Bokota, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel, Pamela J. Stirn
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Patent number: 7985799Abstract: A process for preparing polyolefin blends comprising: a) polymerizing in a solution phase propylene or 1-butene to prepare a polymeric solution containing a semicrystalline polymer component; b) polymerizing in a solution phase 1-hexene or 1-octene to prepare a polymeric solution containing an amorphous polymer component; c) mixing the polymeric solutions obtained from steps a) and b); d) subjecting the mixture of step c) to a devolatilization step to separate a polyolefin blend comprising a semicrystalline component and an amorphous component; the polymerization steps a) and b) being carried out in two polymerization reactors connected in parallel.Type: GrantFiled: May 8, 2006Date of Patent: July 26, 2011Assignee: Basell Poliolefine Italia s.r.l.Inventors: Luigi Resconi, Daniele Bigiavi
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Publication number: 20110177272Abstract: The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.Type: ApplicationFiled: July 2, 2009Publication date: July 21, 2011Applicant: Total Petrochemicals Research FeluyInventors: Rita De Luca, Philippe Hoslet
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Patent number: 7981982Abstract: A process for the preparation of a propylene copolymer composition having a Flexural modulus lower than 500 MPa, a total ethylene content higher than 9% and a Xylene soluble fraction at room temperature higher than 20% comprising at least one polymerization step carried out in a gas-phase polymerization reactor comprising at least two interconnected polymerization zones said process being characterized by the fact that at least 30% by weight of said xylene soluble fraction is produced in the polymerization step carried out in a gas-phase polymerization reactor comprising at least two interconnected polymerization zones.Type: GrantFiled: May 7, 2008Date of Patent: July 19, 2011Assignee: Basell Poliolefine Italia s.r.l.Inventors: Camillo Cagnani, Enrico Beccarini, Claudio Cavalieri
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Publication number: 20110172362Abstract: The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 ?m. The molding composition has a density at a temperature of 23° C. in the range from 0.948 to 0.953 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight.Type: ApplicationFiled: February 24, 2011Publication date: July 14, 2011Applicant: BASELL POLYOLEFINE GMBHInventors: Joachim Berthold, Lutz-Gerd Heinicke, Gerhardus Meier
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Publication number: 20110165357Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 937 to 950 kg/m3, a melt index MFR5 of from 0.3 to 3.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 30.Type: ApplicationFiled: May 25, 2009Publication date: July 7, 2011Applicant: BOREALIS AGInventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlof, Tarja-Tuulikki Turpeinen, John Severn
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Publication number: 20110160396Abstract: The present invention provides a thermoplastic resin composition which comprises (A) a (meth)acrylic acid alkyl ester-based polymer forming a network-shaped disperse phase; and (B) an aromatic vinyl-cyanide vinyl based copolymer forming a continuous phase. The thermoplastic resin composition of the present invention can have an excellent low gloss characteristics while maintaining basic physical properties of a weather resistance, impact strength, thermal resistance, and delamination characteristics.Type: ApplicationFiled: December 28, 2010Publication date: June 30, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Young Sub Jin, So Young Kwon, Sung Kwan Kim, Hwan Seok Park, Jae Keun Hong, Byeong Do Lee, Chul In Lim
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Publication number: 20110160397Abstract: The present invention provides a weather resistant thermoplastic resin with low gloss and a method of preparing the same. The thermoplastic resin of the present invention comprises a (meth)acrylic acid alkyl ester-based polymer (A) and a (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B), and an aromatic vinyl-cyanide vinyl based copolymer (C), wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase.Type: ApplicationFiled: December 29, 2010Publication date: June 30, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: So Young Kwon, Young Sub Jin, Sung Kwan Kim, Byeong Do Lee
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Publication number: 20110152454Abstract: The invention relates to a method for production of grafted polyethylene comprising the following steps: a) fermentation of primary renewable material with optional purification to give at least one alcohol chosen from ethanol or a mixture of alcohols comprising ethanol; b) dehydration of the alcohol obtained to give in a first reactor at least one alkene selected from ethylene and mixtures of alkenes containing ethylene and optional purification of the alkene to give ethylene; c) polymerization, in a second reactor, of the ethylene to give polyethylene; d) isolation of the polyethylene obtained in step c); e) grafting the polyethylene with at least one grafting monomer selected from the unsaturated carboxylic acids or theifunctional derivatives thereof, the unsaturated dicarboxylic acids having 4-10 carbon atoms and the functional derivatives thereof being C1-C8 alkyl esters or glycidyl ester derivatives of the unsaturated carboxylic acids and the metal salts of the unsaturated carboxylic acids.Type: ApplicationFiled: July 27, 2009Publication date: June 23, 2011Applicant: Arkema FranceInventors: Samuel Devisme, Fabrice Chopinez, Jean-Laurent Pradel, Guillaume Le, Thomas Roussel
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Patent number: 7947783Abstract: The present invention relates to a polyethylene composition wherein (i) the composition has an MFR2 of 0.05 to 100 g/10 min, (ii) the environmental stress crack resistance ESCR measured in hours according to ASTM 1693, condition B and E-modulus EM measured according to ISO 527-2: 1993 in MPa satisfy the following relation: ESCR>?EM h/MPa+1150 h.Type: GrantFiled: October 6, 2006Date of Patent: May 24, 2011Assignee: Borealis Technology OyInventors: Svein Eggen, Katrin Nord-Varhaug, Siw Bodil Fredriksen
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Publication number: 20110108121Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI27/210 of from 2 to 50.Type: ApplicationFiled: May 25, 2009Publication date: May 12, 2011Applicant: BOREALIS AGInventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlöf
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Patent number: 7928162Abstract: A process for fluid phase in-line blending of plasticized polymers is provided.Type: GrantFiled: September 9, 2008Date of Patent: April 19, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Alan Anthony Galuska, Robert Patrick Reynolds, Jr., John W. Chu, Bryan R. Chapman, Patrick Brant, Sudhin Datta
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Publication number: 20110086978Abstract: The present invention provides an apparatus and a method for continuous hydrogenation of conjugated diene polymer. By feeding the conjugated diene polymer, a catalyst composition and a hydrogen to the apparatus for hydrogenation. This apparatus for hydrogenation includes at least one hydrogenation reaction unit each comprising at least one a hydrogenation reactor with an outlet and at least one heat exchanger. In the hydrogenation reaction unit, the conjugated diene polymer, the catalyst composition and the hydrogen are mixed in a non-mechanical mixing mode and proceed hydrogenation with heat exchanger being connected to the outlet of the hydrogenation reactor.Type: ApplicationFiled: December 14, 2010Publication date: April 14, 2011Inventors: Chen-Pao Huang, Kuei-Lun Chen
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Patent number: 7910662Abstract: The invention discloses improved processes to halogenate polymers. In particular, the invention discloses to improved processes to halogenate polymers made from C4-1012 isoolefins.Type: GrantFiled: December 28, 2005Date of Patent: March 22, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: David Yen-Lung Chung, Michael Francis McDonald, Robert Norman Webb, Richard Dwight Hembree
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Patent number: 7910637Abstract: A process for in-line blending of plasticizers and polymers is provided.Type: GrantFiled: September 9, 2008Date of Patent: March 22, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Alan Anthony Galuska
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Publication number: 20110062108Abstract: The invention relates to a polyethylene moulding composition having a multimodal molecular mass distribution and comprising a first ethylene homopolymer fraction (I), a second ethylene copolymer fraction (II) and a third ethylene copolymer fraction (III). The moulding composition has a density at a temperature of 23° C. in the range from 0.945 to 0.953 g/cm3, an MFR (190° C./5 kg) in the range from 2 to 7 g/10 min and a viscosity number VN3 of the total mix of ethylene homopolymer fraction (I), copolymer fraction (II) and ethylene copolymer fraction (III), measured in accordance with ISO/R 1191 in decalin at a temperature of 135° C., in the range from 200 to 250 cm3/g. The invention further relates to the use of such a moulding composition for producing high-strength injection-molded screw cap closures for bottles comprising beverages, especially carbonated beverages.Type: ApplicationFiled: December 13, 2008Publication date: March 17, 2011Inventors: Joachim Berthold, Diana Doetsch nee Boos, Gerhardus Meier, Albert Weber
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Publication number: 20110060103Abstract: Embodiments of the invention provide a class of mesophase separated butene/?-olefin block interpolymers with controlled block sequences. The butene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (TREF'), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: March 10, 2011Applicant: Dow Global Technologies Inc.Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20110032621Abstract: Embodiments of the invention provide a class of mesophase separated ethylene/?-olefin block interpolymers with controlled block sequences. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: February 10, 2011Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20110021700Abstract: The invention relates to a process for producing a grafted rubber comprising: a) providing an ethylene propylene rubber having a weight average molecular weight (Mw) of at least 80 kg/mol in a continuous extrusion reactor by feeding the rubber in a slab/melt dosing unit and transporting the rubber to the continuous extrusion reactor by a melt pump; b) drying the rubber in the continuous extrusion reactor to a moisture content of between about 0.2 and about 0.5 wt %; c) providing the dried rubber to a first injection zone of the continuous extrusion reactor at a temperature of between 190 and 250° C.Type: ApplicationFiled: December 1, 2008Publication date: January 27, 2011Applicant: DSM IP ASSETS, B.V.Inventors: Patric Meessen, Franciscus Victoire Paulus Houtvast, Johannes Hendrik Geesink, Joe Zhaoyao Qiu
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Patent number: 7872071Abstract: The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing protective coatings on steel pipes. The molding composition has a density at a temperature of 23° C. in the range from 0.94 to 0.95 g/cm3 and an MFI190/5 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C.Type: GrantFiled: November 17, 2005Date of Patent: January 18, 2011Assignee: Basell Polyolefine GmbHInventors: Joachim Berthold, Ludwig Böhm, Heinz Vogt
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Patent number: 7851550Abstract: A method for surface crosslinking water-absorbing resin of the present invention includes a step (1) of obtaining a wet mixture, a step (2) of obtaining a dried particulate composition, and a step (3) of carrying out a surface crosslinking reaction. With this, since a processing time of each step becomes short, it is possible to mass produce the water-absorbing resin having excellent physical properties. Moreover, a method for manufacturing the water-absorbing resin of the present invention includes a modifying step and a cooling step. The modifying step and/or the cooling step are/is carried out by using stirring means including a rotation axis having a plurality of stirring boards, and the stirring means includes the stirring board having a specific thickness and/or a scraping blade having a specific shape. With this, it is possible to suppress the generation of the fine powder in the modifying step and/or the cooling step.Type: GrantFiled: December 20, 2006Date of Patent: December 14, 2010Assignee: Nippon Shokubai Co., Ltd.Inventors: Kenji Kadonaga, Yorimichi Dairoku, Shin-ichi Fujino, Hiroko Okochi, Yoshio Irie, Hideyuki Tahara
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Publication number: 20100308007Abstract: Polyolefin composition, comprising in percent by weight: 1) 75-85% of a copolymer of propylene, said copolymer containing up to 15% by weight, of ethylene and/or C4-C10 ?-olefin(s) and having a fraction soluble in Xilene at room temperature lower than 6% by weight, and 2) 15-25% of a copolymer of ethylene with one or more C4-C10 ?-olefin(s) containing from 10 to 25% by weight of said C4-C10 ?-olefin(s); said composition having the value of MFR, measured at 230° C., 2.16 kg, of less than 2.5 g/10 min, the total content of ethylene of from 14 to 22% by weight, the total content of C4-C10 ?-olefin(s) of less than 4.5% by weight, the ratio of the total content of ethylene to the total content of C4-C10 ?-olefin(s) equal to or higher than 4, the value of the intrinsic viscosity of the total fraction soluble in xylene at room temperature equal to or less than 1.5 dl/g, and the ratio of the amount of component 2) and the amount of C4-C10 ?-olefin(s) in component 2) equal to or higher than 0.80.Type: ApplicationFiled: February 4, 2009Publication date: December 9, 2010Inventors: Paola Massari, Marco Ciarafoni, Gisella Biondini, Paolo Goberti
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Publication number: 20100305270Abstract: A product comprising a cold water soluble film wherein: a) the film comprises a copolymer of vinyl alcohol (VOH) with a minor amount of 2-acrylamido-2-methyl propane sulfonic acid in free acid form or as a salt of the free acid (AMPS); and b) the film has a harsh chemical dissolution time of less than about 80 seconds measured by the harsh chemical dissolution test method after 8 weeks.Type: ApplicationFiled: August 11, 2010Publication date: December 2, 2010Inventor: Richard Vicari
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Publication number: 20100286325Abstract: The present invention relates to aqueous binder compositions obtainable by emulsion polymerization of (A) at least one C1-C10 alkyl (meth)acrylate, and/or a vinylaromatic compound having up to 20 C atoms, or mixtures thereof (monomers A), (B) and also, if appropriate, further monomers B, and (C) at least one water-soluble alkyd resin having a weight-average molecular weight between 5000 and 40 000 Da, wherein the polymerization of the monomers A and also, if appropriate, B and the alkyds C is carried out in the form of a parallel feed process, and also to their preparation and use in coating materials.Type: ApplicationFiled: June 12, 2008Publication date: November 11, 2010Applicant: BASF SEInventors: Roelof Balk, Sebastian Roller, Rolf Dersch, Uwe Dittrich
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Patent number: 7816447Abstract: The invention relates to the production of polymers using polymerization processes and reactor systems including a plurality of multi-zone circulating reactors. In particular, the invention relates to the production of impact copolymers using reactor systems including a plurality of multi-zone circulating reactors.Type: GrantFiled: August 23, 2004Date of Patent: October 19, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kevin Wayne Lawson, Lawrence Carl Smith, Randell Wayne Dickey, Robert Tan Li, Prasadarao Meka
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Patent number: 7799866Abstract: The method for producing a propylene-ethylene block copolymer in accordance with the present invention has: a first polymerization process which is performed using two or more polymerization tanks connected in series and in which a solid catalyst or a prepolymerized catalyst containing a solid catalyst, and propylene are continuously supplied to a first polymerization tank; and a second polymerization process in which propylene, ethylene, and polypropylene particles continuously extracted from the last polymerization tank of the first polymerization process are supplied to a polymerization tank to produce a propylene-ethylene block copolymer, wherein the average retention time of the polypropylene particles in each polymerization tank of the first polymerization process is 0.1 to 1.5 h and the sum total of average retention times of polypropylene particles in the polymerization tanks of the first polymerization process is 1.5 to 3.0 h.Type: GrantFiled: December 22, 2008Date of Patent: September 21, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Shin-ichi Kumamoto, Noriyuki Satou, Masaki Endo
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Patent number: 7795359Abstract: The invention provides a continuous-flow process for producing a polymeric material. The process of the invention comprises the steps of: introducing at least two solutions, each comprising one or more reactants, into a microreactor to mix the two solutions to form a reacting solution, wherein the one or more reactants are selected from the group consisting of a monomer, an initiator, a coupling agent, a prepolymer, a macromer, and mixtures thereof; feeding continuously the reacting solution into a flow-through polymerization reactor in a coil form, wherein the flow-through polymerization reactor is capable of providing a residence time sufficient for (co)polymerizing the reactants to form a polymer with a desired polydispersity, wherein the flow-through polymerization reactor is immersed in an ultrasonic bath to minimize or substantially eliminate unwanted high-molecular-weight fractions of the polymer.Type: GrantFiled: March 1, 2006Date of Patent: September 14, 2010Assignee: Novartis AGInventors: Brian Gerrard Devlin, Troy V. Holland, Dawn Alison Smith, Alexander Azzawi
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Publication number: 20100210789Abstract: The present invention relates to a compounding method for producing impact-modified thermoplastic compositions with a low content of volatile organic compounds (hereinafter VOCs), wherein relatively inexpensive polymer raw materials with a comparatively elevated initial VOC content may be used, resulting in lowered production costs for producing such VOC-reduced polymer compositions.Type: ApplicationFiled: February 18, 2010Publication date: August 19, 2010Applicant: BAYER MATERIALSCIENCE AGInventors: Andreas SEIDEL, Hans-Jüergen THIEM
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Publication number: 20100190926Abstract: The present invention provides bimodal polyethylene resins in which the high molecular weight ethylene copolymer component typically has a relatively narrow molecular weight distribution, with short chain branching content being substantially constant across its molecular weight distribution. The resins of this invention are typically characterized by improved toughness and resistance to slow crack propagation properties making them useful for pressure pipe applications.Type: ApplicationFiled: March 17, 2010Publication date: July 29, 2010Applicant: Chevron Phillips Chemical Company LPInventors: Rajendra K. Krishnaswamy, Qing Yang
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Publication number: 20100168330Abstract: An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm?(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.Type: ApplicationFiled: March 12, 2009Publication date: July 1, 2010Applicant: Dow Global Technologies Inc.Inventors: Mehmet Demoirors, Teresa P. Karjala, Christopher R. Eddy, Lonnie G. Hazlitt, Pak-Meng Cham, Sarat Munjal, Wallace W. Yau
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Publication number: 20100152382Abstract: An in-or polymer blend including (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.Type: ApplicationFiled: December 15, 2008Publication date: June 17, 2010Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Carlos U. De Gracia, Keith Edward Jolibois, Cesar A. Garcia-Franco, Ronald Raymond Thackston
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Publication number: 20100152383Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.Type: ApplicationFiled: December 15, 2009Publication date: June 17, 2010Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
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Patent number: 7737222Abstract: A pressureless pipe and polymer composition for making such a pipe as well as the use of the polymer composition for pressureless pipes and supplementary parts, are disclosed. The polymer composition is characterized in that the polymer comprises a multimodal ethylene polymer including a copolymer of ethylene and a C4-C10 &agr; -olefin comonomer; the ethylene polymer has a total density of 953-958 kg/m3 and a MFR5 of 0.2-2.0 g/10 min; the ethylene polymer has a modulus of elasticity, determined according to ISO 178 of 1300-1700 MPa; the ethylene polymer has a resistance to slow crack growth, determined according to ASTM F 1473 of more than 1.5 hrs.Type: GrantFiled: March 31, 2005Date of Patent: June 15, 2010Assignee: Borealis Technology OyInventors: Mats Bäckman, May-Lis Andersson, Carl-Gustaf Ek, Kenneth Lund, Markku Vahteri
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Patent number: 7728077Abstract: A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature ([?]sol) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR/[?], , , , equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.Type: GrantFiled: March 22, 2005Date of Patent: June 1, 2010Assignee: Basell Pololefine Italia s.r.l.Inventors: Anteo Pelliconi, Enea Garagnani, Giampaolo Pellegatti, Antonella Angelini
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Publication number: 20100120981Abstract: Provided are ethylene copolymers and a process for preparing the same. More specifically, provided are ethylene copolymers exhibiting excellent processibility and physical properties due to its multimodal molecular weight distribution index, through a multi-stage process by using reactors connected in series or in parallel in the presence of catalyst composition containing transition metal catalyst, and a process for preparing the same.Type: ApplicationFiled: September 11, 2009Publication date: May 13, 2010Inventors: Daeho Shin, Choonsik Shim, Jisu Jeong, Sungseok Chae, Myungahn Ok, Seungbum Kwon, Dong-Cheol Shin, Ho-Seong Lee
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Publication number: 20100113692Abstract: In one embodiment, an apparatus for continuous production of a partially polymerized composition comprises: a reactor for formation of monomer to be partially polymerized; and a polymerization reactor for continuously receiving the monomer to be partially polymerized from the reactor in which it is formed and partially polymerizing the monomer. In another embodiment, an apparatus for continuous production of a partially polymerized composition comprises: a polymerization reactor for continuously receiving monomer to be partially polymerized and for partially polymerizing the monomer therein, wherein the polymerization reactor comprises an essentially straight tube for a heating portion and wherein the heating portion is essentially free of internal mixing apparatus.Type: ApplicationFiled: November 4, 2008Publication date: May 6, 2010Inventors: James E. McGuire, JR., Andrew C. Strange, Daniel E. Lamone
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Publication number: 20100113693Abstract: The invention relates to a process for preparing polymethylolated melamine and polymethylolated melamine compounds polyetherified with alkanol, wherein the methylolation reaction is carried out in a kneading reactor.Type: ApplicationFiled: January 13, 2005Publication date: May 6, 2010Applicant: BASF AktiengesellschaftInventors: Jörg Schneider, Günter Scherr, Rainer Erhardt, Andreas Eichfelder, Martin Reif, Stefan Hirsch, Hans Schupp, Christel Hittinger, Alain Robert
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Publication number: 20100113694Abstract: A process for preparing modified thermoplastic vulcanizate compositions, the process comprising the steps of introducing molten thermoplastic vulcanizate and a free-radical source, where the thermoplastic vulcanizate includes cured rubber dispersed within a thermoplastic matrix.Type: ApplicationFiled: October 15, 2009Publication date: May 6, 2010Inventors: Hari P. Nadella, Jianya Cheng
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Patent number: 7700023Abstract: A method for producing an environment protective foamed thermoplastic resin polymer comprises using an extruder with a helical rod to be driven to rotate. The extruder has a feeding section, a melting section, a mixing section and a heating-shaping section formed therein. The method includes a plurality of steps, in which thermoplastic resin is heated, melted in the melting section and moved into the mixing section, and hollow expansion balls are fed into the extruder to be evenly mixed with the melted thermoplastic resin. Then the hollow expansion balls are slightly heated and inflated, and moved into the heating-shaping section, and then the balls are heated at foaming temperature, foamed and inflated. After being injected through a nozzle, the melted thermoplastic resin and the hollow balls become a foamed thermoplastic resin polymer with a preset thickness and shape.Type: GrantFiled: November 15, 2006Date of Patent: April 20, 2010Inventor: Shui-Mu Wang
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Publication number: 20100084363Abstract: The instant invention is a high-density polyethylene composition, method of producing the same, injection molded articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.920 to 0.946 g/cm3, and a melt index (I21.6) in the range of 1 to 15 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 30 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3.Type: ApplicationFiled: October 25, 2007Publication date: April 8, 2010Inventors: William J. Michie, JR., Stephanie M. Whited, Nathan J. Wiker, Dale M. Elley-Bristow