With Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 525/57)
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Publication number: 20100028545Abstract: Provided are a polymer solution to be coated to manufacture a transparent conductive polymer film, a method of manufacturing the polymer solution, and a method of manufacturing a transparent conductive polymer film using the polymer solution. The polymer solution includes: polyvinyl alcohol (PVA) for controlling electrical conductivity of the transparent conductive polymer film; polyvinylacetamide (PNVA) for controlling structural strength of the polymer solution; polyacrylamide (PAAM) for controlling frictional resistance and an adhesion characteristic; nitric acid functioning as an electron-acceptor in an oxidation-reduction reaction; methyl methacrylate (MMA) for controlling transmittance of the transparent conductive polymer film; and a normal methyl pyrrolidone (AMP) solvent for maintaining viscosity of the polymer solution.Type: ApplicationFiled: August 4, 2008Publication date: February 4, 2010Applicants: KYUNG SIK KIM, YOUNG JIN KIM, KYO JIN LEE, MASAMI GOTOInventor: Young-min Choi
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Publication number: 20090285511Abstract: A film having a cross directional tear/machine directional tear ratio below 1 is described. The film has a sealant layer with a cyclic olefin copolymer. The film can be used in the manufacture of packages having an easy cross-direction tear open feature. There are also provided methods for the production of the film and packages made of the film.Type: ApplicationFiled: July 28, 2009Publication date: November 19, 2009Applicant: PLIANT CORPORATIONInventor: Dinesh Aithani
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Publication number: 20090258300Abstract: The invention provides a fiber which is excellent in electrolyte absorption and retentivity and oxidation resistance and is suitable for use as a separator for alkaline secondary batteries. The invention is an ethylene/vinyl alcohol-derived copolymer fiber comprising an ethylene/vinyl alcohol-derived copolymer (A) having the following structural unit (1): (wherein R1 represents a hydrogen atom or an organic group; X represents a bonding chain other than ether bond; n represents 0 or 1; and R2 to R4 each represent a hydrogen atom or an organic group).Type: ApplicationFiled: November 14, 2006Publication date: October 15, 2009Applicant: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Takamasa Moriyama, Kaoru Inoue
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Publication number: 20090227718Abstract: Disclosed is a polyvinyl alcohol aqueous dispersion having excellent storage stability which is capable of forming a coating film with excellent water resistance and transparency even when it is dried at room temperature. Also disclosed are a composition and a coating agent for paper. Specifically disclosed is an aqueous dispersion of a resin which is composed of a polymer containing at least 20 weight % of a vinyl monomer unit (A) having an epoxy group and a vinyl alcohol polymer (B) while having a weight ratio (A)/(B) of 2/100-200/100. The weight ratio of (A) bonded to (B) is not less than 50% relative to the total weight of (A), and the average particle size of the resin determined by dynamic light scattering is not more than 500 nm.Type: ApplicationFiled: May 16, 2005Publication date: September 10, 2009Applicant: Kuraray Co.LTD.Inventors: Seiji Tanimoto, Naoki Fujiwara
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Publication number: 20090186235Abstract: An object of the present invention is to provide a resin composition in which generation of burned deposit and buildup occurring in a recycled layer is suppressed without adding a specific additive as well as a multi-layer structure using the same. The invention relates to a resin composition comprising an ethylene-vinyl alcohol copolymer (A) comprising the following structural unit (1) and at least one thermoplastic resin (B) selected from the group consisting of polyolefin and polystyrene as well as a multi-layer structure comprising the resin composition: wherein X represents a bonding chain which is an arbitrary bonding chain excluding an ether bond, R1 to R4 each independently represents an arbitrary substituent, and n represents 0 or 1.Type: ApplicationFiled: April 25, 2006Publication date: July 23, 2009Applicant: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Hideshi Onishi, Takamasa Moriyama, Kaoru Inoue
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Publication number: 20090171022Abstract: Adhesive compositions for styrene polymers are provided. The adhesives are suitable for use as tie-layers in multi-layer films and sheets and comprise a polyolefin base resin, a functionalized polyolefin and a combination of styrene triblock copolymers.Type: ApplicationFiled: January 2, 2008Publication date: July 2, 2009Inventor: Maged G. Botros
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Publication number: 20090156740Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 100 parts by weight, per 100 parts by weight of elastomer of a polymer nanofiber having a thickness ranging from 20 to 200 nm.Type: ApplicationFiled: October 30, 2008Publication date: June 18, 2009Inventors: Annette Lechtenboehmer, Frank Schmitz
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Publication number: 20090149593Abstract: It is an object of the present invention to provide an aqueous ethylene-vinyl alcohol-based copolymer dispersion which is excellent in long-term storage stability and in film-forming properties even when subjected to low-temperature or short-time drying or applied to give thick coats and can give coatings showing high gas barrier performance. The prevent invention is an aqueous ethylene/vinyl alcohol-based copolymer dispersion, which comprises: (A) an ethylene/vinyl alcohol-based copolymer with an ethylene content of 15-65 mole percent and a degree of saponification of not lower than 80 mole percent, (B) a base-neutralized ethylene/?,?-unsaturated carboxylic acid-based copolymer and (C) a polyvinyl alcohol with a degree of saponification of 75-100 mole percent and a degree of polymerization of 100-3500, the content of the polyvinyl alcohol (C) being 0.5-100 parts by weight per 100 parts by weight of the ethylene/vinyl alcohol-based copolymer (A).Type: ApplicationFiled: November 25, 2005Publication date: June 11, 2009Applicants: SUMITOMO SEIKA CHEMICALS CO., LTD., KURARAY CO., LTD.Inventors: Yuhei Funabiki, Norihiro Sugihara, Kazutoshi Terada, Yukio Ozeki, Michiyuki Nanba
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Patent number: 7534829Abstract: Provided is a resin composition comprising 1-99% by weight of a modified ethylene-vinyl alcohol copolymer (C) having an ethylene content of 5-55 mol %, which contains a specific structural unit (I) in an amount of 0.3-40 mol % and can be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500, and 1-99% by weight of a thermoplastic resin (T1) other than (C). Moreover, a multilayer structure in which the resin composition and a thermoplastic resin (T2) are laminated is also provided. Thus, a resin composition superior in barrier properties, transparency, stretchability, flexibility, flexing resistance and interlayer adhesiveness and various kinds of molded articles made thereof are provided.Type: GrantFiled: February 20, 2003Date of Patent: May 19, 2009Assignee: Kuraray Co., Ltd.Inventors: Shinji Tai, Kaoru Ikeda, Haruhisa Masuda, Tomoyuki Watanabe, Kouta Isoyama
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Patent number: 7531032Abstract: The invention is directed to an aqueous based resin coating and paint composition comprising as essential ingredients, a colorant, a polyvinyl acetate polymer/acrylic polymer emulsion blend primary binder, a polyvinyl-based film forming resin secondary binder, such as polyvinyl alcohol, and water with sufficient amount of a surface active agent to form a stable suspension. The coating or paint composition is applied onto an elastomeric or polyvinyl chloride surface until the coating can be thermally treated or evaporated to incorporate the coating into the elastomeric or polyvinyl chloride surface as a permanent color. The invention also comprises a method for the preparation of the aqueous-base coating composition in which the essential components are prepared as aqueous dispersions or emulsions which are blended together to form the final coating or paint composition.Type: GrantFiled: August 30, 2005Date of Patent: May 12, 2009Assignee: Mattel, Inc.Inventor: Abimael Cordova
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Publication number: 20090118416Abstract: Provided is an aqueous liquid dispersion having excellent water resistance and shelf viscosity stability, wherein (A) polymer particles mainly composed of at least one monomer unit selected from ethylenically unsaturated monomers and diene unsaturated monomers while containing 0.1-10% by weight of at least one crosslinkable unsaturated monomer unit selected from carboxyl group-containing unsaturated monomers, N-methylol (meth)acrylamide, N-butoxymethyl (meth)acrylamide, diacetone acrylamide and acetoacetoxyethyl (meth)acrylate; (B) a vinyl alcohol polymer containing 1-10% by mole of an ethylene unit and (C) a carboxyl group-containing vinyl alcohol polymer, or (E) a vinyl alcohol copolymer containing 1-10% by mole of an ethylene unit and 0.1-10% by mole of a carboxyl group-containing monomer unit; and (D) a crosslinking agent are contained at a certain solid content weight ratio. Also provided are a method for producing such an aqueous liquid dispersion, a composition, an adhesive and a coating material.Type: ApplicationFiled: July 3, 2006Publication date: May 7, 2009Applicant: KURARAY CO., LTDInventors: Masato Nakamae, Hideki Maki
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Patent number: 7521103Abstract: A coating compositions for providing substrates with oxygen barrier properties is disclosed. The substrate may be, for instance, a film, such as a polyester film. The coating composition includes a copolymer of maleic acid and acrylic acid and a copolymer of vinyl alcohol and a vinylamine. The barrier coating formed from the coating composition is typically less than about 1 micron in thickness and provides reduced oxygen transmission even at relatively high relative humidities.Type: GrantFiled: June 22, 2006Date of Patent: April 21, 2009Assignee: Mitsubishi Polyester Film, Inc.Inventor: Robert Giles Posey
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Publication number: 20090096130Abstract: A compound is described including one or more polymer (A) selected from propylene-ethylene block copolymers (A1), propylene homopolymers (A2) and a combination of copolymers (A1) and/or homopolymers (A2), at 30% to 90% by weight; one or more copolymer (B) selected from ethylene-alpha-olefin random copolymers (B1), hydrogenated styrene-ethylene-butadiene-styrene block copolymers (B2), ethylene-alpha-olefin block copolymers (B3), and a combination of two or more of copolymers (B1), copolymers (B2), and/or optional copolymers (B3), at 0% to 50% by weight; one or more mineral filler (C) at 0% to 30% by weight; one or more surface modifier (D) at 0% to 5% by weight; one or more additive (E) at 0% to 5% by weight; and one or more colorant (F) at 0% to 10% by weight. Associated articles and methods are also described.Type: ApplicationFiled: September 26, 2008Publication date: April 16, 2009Applicant: ADVANCED COMPOSITES, INC.Inventors: Frank E. Jones, III, Jason Fincher
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Publication number: 20090075105Abstract: Disclosed is a resin composition containing a polyvinyl alcohol resin (A) having an active hydrogen-containing functional group, and an N-amino poly(acrylamide)-based resin (B) having a (meta)acrylic acid structural unit represented by the general formula (1) below and an acrylamide structural unit represented by the general formula (2) below. This resin composition has high crosslinking rate, and enables to obtain a crosslinked product having excellent waterproof. (In the formula, R represents a hydrogen or a methyl group, and X represents a hydrogen or an alkali metal.Type: ApplicationFiled: February 20, 2007Publication date: March 19, 2009Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: Hiroyuki Ono, Shusaku Mandai, Katsumi Edasawa
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Publication number: 20090069494Abstract: A process is described for providing a polymer material by blending as a first component one or more hydrophilic polymers, and as a second component one or more neutralising chemicals, in the complete or substantial absence of water. In the absence of water, the components will not be aqueous solutions. Thus the components can be used in blending processes, and the present invention is able to form many other shapes and forms of material other than laminates on substrates.Type: ApplicationFiled: September 30, 2005Publication date: March 12, 2009Applicant: The Queen's University of BelfastInventors: Brian Alan Beadle, Graham Samuel Garrett, Alan Hugh Clarke
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Patent number: 7495056Abstract: The present invention provides: a novel water-absorbing agent, which exhibits an excellent absorption capacity under a load (AAP), gel layer liquid permeation rate under a load (FRUP), saline flow conductivity (SFC), and shape-maintaining property and ball burst strength (BBS) of a swollen water-absorbing agent aggregate, and excellent persistency of these effects for a long time. The water-absorbing agent, which comprises a polymer obtained by a process including the steps of polymerizing and then crosslinking a monomer including acrylic acid and/or a salt thereof, with the water-absorbing agent being characterized by: (1) exhibiting a free swelling capacity of not less than 23 g/g (GV), a gel deformation of not more than 12.5 cm under a short-time load (0.5 hrPT), and a gel deformation deterioration of not more than 3.Type: GrantFiled: June 9, 2006Date of Patent: February 24, 2009Assignee: Nippon Shokubai Co., Ltd.Inventors: Kazushi Torii, Toshimasa Kitayama, Nobuyuki Harada
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Publication number: 20090041963Abstract: [Problem] To provide a gas barrier resin composition that is excellent in oxygen absorbability and further excellent in adhesiveness to olefin resins, a structure comprising the same, and a multi-layer structure comprising the same. [Means for Dissolution] The oxygen-absorbing gas barrier resin composition comprises a cyclized product of a conjugated diene polymer and an ethylene/vinyl alcohol copolymer having a specified oxygen permeation rate. The oxygen-absorbing gas barrier resin composition further comprises an ?-olefin resin. The oxygen-absorbing gas barrier structure is obtained by molding the subject oxygen-absorbing gas barrier resin composition. The oxygen-absorbing gas barrier multi-layer structure comprises a layer of the subject oxygen-absorbing gas barrier structure and a sealing material layer.Type: ApplicationFiled: March 17, 2006Publication date: February 12, 2009Applicant: Zeon CorporationInventor: Shizuo Kitahara
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Publication number: 20090018252Abstract: [Object] To provide an aqueous emulsion which is excellent in mechanical stability and pigment compatibility and further is excellent in film transparency and solvent resistance, and a coating by the use thereof. [Solution Means] The object is achieved by the aqueous emulsion including a polymer having at least one monomer unit selected from the group consisting of a (meth)acrylate ester monomer unit, a styrene monomer unit and a diene monomer unit as a dispersoid, further including a vinyl alcohol polymer (A) having 1.9 mol % or more 1,2-glycol bond and a saponification degree of 70 mol % or more and a surfactant (B) as dispersants, wherein a weight ratio of (A)/(B) is 50/50 to 95/5 and an average particle diameter of dispersed particles is 0.5 ?m or less, and the coating by the use thereof.Type: ApplicationFiled: February 8, 2006Publication date: January 15, 2009Applicant: Kuraray Co., Ltd.Inventors: Hideki Maki, Seiji Tanimoto, Masato Nakamae
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Publication number: 20090011601Abstract: It is disclosed an over-coating agent for forming fine-line patterns which is applied to cover a substrate having thereon photoresist patterns and allowed to shrink under heat so that the spacing between adjacent photoresist patterns is lessened, with the applied film of the over-coating agent being removed substantially completely to form or define fine trace patterns, further characterized by containing a copolymer or a mixture of polyvinyl alcohol with a water-soluble polymer other than polyvinyl alcohol. Also disclosed is a method of forming fine-line patterns using the over-coating agent. According to the invention, one can effectively increase the shrinkage amount (the amount of heat shrinking) of the agent, thereby achieving a remarkably improved effect of forming or defining fine-line patterns and which also present satisfactory profiles and meet the characteristics required of today's semiconductor devices.Type: ApplicationFiled: September 8, 2008Publication date: January 8, 2009Inventors: Yoshiki Sugeta, Fumitake Kaneko, Toshikazu Tachikawa, Kazumasa Wakiya
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Patent number: 7473735Abstract: The present invention provides a resin composition which comprises EVOH and a thermoplastic resin other than EVOH and which generates less odor and therefore is suitable for food packaging applications. The invention also provides an environmentally friendly method for producing a resin composition, without releasing any carboxylic acid such as acetic acid to the peripheral environment. A resin composition containing less carboxylate group is obtained by contacting an ethylene-vinyl alcohol copolymer resin with an aqueous solution containing both carbon dioxide gas and at least one additive selected from the group consisting of an alkali metal salt (A) and a boron compound (B) and then melt kneading with a thermoplastic resin (G) other than EVOH.Type: GrantFiled: July 22, 2004Date of Patent: January 6, 2009Assignee: Kuraray Co., Ltd.Inventors: Naohiko Uchiumi, Kaoru Ikeda, Noriyuki Kida, Tetsuya Hara, Syukiti Kawamura
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Publication number: 20080241566Abstract: Compositions for damping the vibration of mechanical components, such as those used in vehicles, are disclosed and described. The compositions comprise a water-based polymer resin and a drying control agent. The drying control agent minimizes the occurrence of cracks and swelling in the damping coating films when the coating films are baked and dried.Type: ApplicationFiled: March 30, 2007Publication date: October 2, 2008Inventors: Frank Hoefflin, Hua Ning, Patricia Heidtman
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Publication number: 20080227913Abstract: A carboxyl group-containing diene-based rubber latex composition comprising (a) a carboxyl group-containing diene-based rubber latex and one or more compounds selected from the following (b) to (e): (b) an organometallic crosslinking agent containing two or more hydroxyl groups each bonded to a metal atom; (c) a cationic property-deactivated, modified polyamine-based resin, a cationic property-deactivated polyamide-epichlorohydrin resin, a cationic property-deactivated polyamine-epichlorohydrin resin, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyvinyl alcohol, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyacrylamide, a cationic property-deactivated amine group- or quaternary ammonium base-containing carbohydrate, or a polyacrylamide, polyvinyl alcohol, or carbohydrate into which a crosslinkable functional group is introduced; (d) an anionic or nonionic polyvinyl alcohol, anionic or nonionic polyacrylamide, or anionic or nonType: ApplicationFiled: December 27, 2007Publication date: September 18, 2008Applicant: FOUR ROAD RESEARCH LTD.Inventor: Kazuo KOIDE
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Publication number: 20080206582Abstract: The present invention refers to an adhesive composition in the form of watery dispersion with a polymer as the dispersoid, an ethylene unsaturated monomer and a first dispersing agent from a modified polyvinyl alcohol and at least a vinyl alcohol polymer as a further dispersing agent. The adhesive composition according to the invention has the advantage that it possesses good adhesion and flow properties and a surprisingly high water stability under an almost neutral pH value, wherein the disadvantages of an acidic adhesive composition, such as e.g. the discoloration of certain wood types, corrosion promoting properties and the premature crosslinking in the batch are avoided.Type: ApplicationFiled: June 29, 2004Publication date: August 28, 2008Inventors: Werner Scholtyssek, Holger Brandt, Kai Robke, Ulf Walkling
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Publication number: 20080207829Abstract: The present invention relates to a polyvinylbutyral (PVB) composition that is useful for blending with other polymers. The PVB composition of the present invention can be stored and used at ambient temperature without the occurrence of blocking by the PVB.Type: ApplicationFiled: May 1, 2008Publication date: August 28, 2008Inventors: George Henry Hofmann, Win-Chung Lee
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Publication number: 20080207809Abstract: A dip-forming composition, comprising: a carboxyl group-containing diene-based rubber latex; and one or more compounds selected from the following (a) to (e): (a) an organometallic crosslinking agent containing two or more hydroxyl groups each bonded to a metal atom; (b) a cationic property-deactivated modified polyamine-based resin, a cationic property-deactivated polyamide-epichlorohydrin resin, a cationic property-deactivated polyamine-epichlorohydrin resin, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyvinyl alcohol, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyacrylamide, a cationic property-deactivated amine group- or quaternary ammonium base-containing carbohydrate, or a polyacrylamide, polyvinyl alcohol, or carbohydrate into which a crosslinkable functional group is introduced; (c) an anionic or nonionic polyvinyl alcohol, anionic or nonionic polyacrylamide, or anionic or nonionic carbohydrate to which a water resType: ApplicationFiled: March 21, 2008Publication date: August 28, 2008Applicant: Four Road Research Ltd.Inventor: Kazuo Koide
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Publication number: 20080182937Abstract: Disclosed are a composition, a process that can be used to produce the composition, and an article comprising or produced from the composition wherein the composition comprises or is produced from PVOH and a polyol ester plasticizer; the PVOH includes a PVOH homopolymer or copolymer; the polyol ester plasticizer includes an esterified polyol having one or more ester groups and at least one free hydroxyl group; and the process comprises combining PVOH with a polyol ester plasticizer under a condition sufficient to transesterify the poly(vinyl alcohol).Type: ApplicationFiled: January 26, 2007Publication date: July 31, 2008Inventors: David C. Urian, Peter A. Morken, Donna Lynn Visioli
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Publication number: 20080176998Abstract: The present invention is a composition useful for coating the surface of paper wherein the coating composition is an aqueous solution comprising less than 40 wt % water and consisting essentially of a polyvinyl alcohol copolymer that is at least about 95% hydrolyzed, and a process for preparing the same.Type: ApplicationFiled: March 17, 2008Publication date: July 24, 2008Inventors: Elliott Echt, Peter A. Morken, G. Michael Collins
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Publication number: 20080160062Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain at least one region of polymeric material. The at least one region of polymeric material contains at least one polymer selected from the following (a) at least one polymer that contains a polyol chain having charged groups along its length, (b) at least one polymer that contains a polyol chain having biodegradable polymer side chains along its length and (c) a combination thereof.Type: ApplicationFiled: August 10, 2007Publication date: July 3, 2008Applicant: Boston Scientific Scimed, Inc.Inventor: Robert E. Richard
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Patent number: 7393895Abstract: A method of forming a poly(arylene ether)-containing solid concentrate is described. The method includes blending a poly(arylene ether), a thermosetting resin, and a compatibilizing agent in the presence of a solvent to form a homogeneous solution, and removing the solvent to yield the solid concentrate. The solid concentrate is useful for preparing curable conditions.Type: GrantFiled: August 23, 2007Date of Patent: July 1, 2008Assignee: Sabic Innovative Plastics IP B.V.Inventors: Michael John Davis, James Estel Tracy
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Publication number: 20080112911Abstract: A process for manufacturing a highly water-soluble vinyl alcohol-N-vinyl amine copolymer with a degree of hydrolysis higher than 93%, including a hydrolysis reaction of a vinyl alcohol-N-vinyl formamide copolymer with an alkaline metal hydroxide in methanol wherein the process is carried out with more than 1.5 mol of the alkaline metal hydroxide per mol of N-vinyl formamide units and without addition of water. A higher water soluble vinyl alcohol-N-vinyl amine copolymer obtained by this process and the use thereof.Type: ApplicationFiled: January 26, 2006Publication date: May 15, 2008Applicant: ERKOL, S.A.Inventors: Juan Carlos Rodriguez Esteban, Alfredo Seco Carracedo, Maria del Carmen Palau Vall, Joseba Iñaki Iragorri Sainz
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Publication number: 20080114124Abstract: A process for producing an aqueous dispersion of at least two preformed polymers each at least partially modified by grafted addition polymers produced in a solution of the polymers, comprising the steps of i) providing a solution in organic carrier liquid of a first preformed polymer, consisting of diepoxy resin, and at least one other preformed polymer excluding polyesters ii) mixing the solution containing the polymers with ethylenically unsaturated monomers, said monomers comprising an effective amount of copolymerisable dispersing moiety iii) providing an effective amount of a grafting polymerisation initiator iv) allowing or causing the monomers to polymerise and graft to at least some of the preformed polymers to form a solution of modified polymers v) optionally adding crosslinking agent to solution iv) vi) dispersing the solution of modified polymers, and optionally crosslinking agent, in aqueous medium to form a stable dispersion of particles.Type: ApplicationFiled: December 16, 2005Publication date: May 15, 2008Inventors: Riaz Ahmad Choudhery, David John Dyer, Brian David Milligan, Stuart Douglas Smith
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Publication number: 20080112984Abstract: The invention relates to hydrogels containing polyvinyl alcohols and/or polyvinyl alcohol copolymers having special geometries, methods for the production of said hydrogels, and the use of the hydrogels as materials in the biomedical and pharmaceutical field, for producing contact lenses, for the controlled release of active substances, as a carrier material for inclusion-immobilized biocatalysts, a carrier material for transition metal catalysts, a material for producing reactive membranes, an additive to drilling fluid, a displacing agent in oil recovery, a cement additive and an additive to highly viscous liquids such as crude oil to improve the flowability and increase the speed of conveyance, and a component of cosmetic products.Type: ApplicationFiled: April 22, 2005Publication date: May 15, 2008Applicant: Celanese Venures GmbHInventors: Jorg Schulte, Tim Dickner, Monika Bruckmann, Jorg Schottek, Uwe Blank
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Patent number: 7354654Abstract: A thermoplastic polymer composition having good flexibility and excellent barrier properties with respect to gases and organic liquids, which can be adhesively bonded to a polyolefin resin, this composition comprising an ethylene-vinyl alcohol copolymer (A), a polymer mixture (B) composed of a block copolymer (I) mainly comprising a vinyl aromatic polymer block and a conjugated diene polymer block which may be hydrogenated, and a rubber softener (II), and a polyolefin resin (C), wherein at least part of the block copolymer (I) is modified at a modification ratio of 0.05 wt. % or higher so as to have a functional group capable of reacting with the ethylene-vinyl alcohol copolymer (A), wherein the ISO type A hardness of the thermoplastic polymer composition is not less than 30 and not higher than 90, and the oxygen permeation coefficient is 20,000 mL·20 ?m/m2·day·atm or less.Type: GrantFiled: December 8, 2003Date of Patent: April 8, 2008Assignee: Kuraray Co., LtdInventors: Haruhisa Masuda, Hiromichi Nakata, Eiji Nakamura, Toshiyuki Zento, Isamu Okamoto, Motohiro Fukuda
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Patent number: 7335699Abstract: A description is given of water-soluble aminoplast ether copolymers of the following structural type: wherein Z is a glycoluril central unit, B is a radical of an essentially water-insoluble polymer and R1 is a radical of a hydrophilic organic compound. The ratio R1:B is selected within a range of about 1.5 to 4:1 and the overall mass of the water-soluble aminoplast ether copolymer is from about 2000 to 50 000 g/mol such that the copolymer is soluble in water and may be used as a dispersant for e.g. pigments in polar solvents, e.g. water.Type: GrantFiled: December 17, 2002Date of Patent: February 26, 2008Assignee: Sud-Chemie AGInventors: Klaus Dziwok, Inge Krämer, Norbert Schall, Helmut Coutelle, Sabine Huth, Alan Steinmetz, Thadeus Schauer, Heinz Greisiger, Mark Entenmann
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Publication number: 20080027175Abstract: The present invention relates to novel polymers, which are based on poly(vinyl ester) copolymers and poly(vinyl alcohol) copolymers having excellent thermal properties because of their special composition and to the use of said polymers. The poly(vinyl alcohol-polyalkene) copolymers and polymer mixtures obtained in this way are characterized by a strongly modified melting behavior compared to linear poly(vinyl alcohols).Type: ApplicationFiled: December 3, 2004Publication date: January 31, 2008Applicant: Celanese Ventures GmbHInventors: Monika Bruckmann, Tim Dickner, Joerg Schottek, Joerg Ludwig Schulte, Uwe Blank
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Publication number: 20080021156Abstract: The invention provides a method for compounding olefin resins with barrier resins to produce thermoplastic polymer blends that can be used to make molded or extruded articles having barrier properties to organic solvents.Type: ApplicationFiled: December 19, 2006Publication date: January 24, 2008Inventors: Thierry Arpin, Olivier Rozant
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Publication number: 20080009585Abstract: A water-soluble substrate, and more particularly a water-soluble substrate that is resistant to contact with small amounts of water, and methods of making the same are disclosed. At least one of the substrate's surfaces comprises first discrete zones having a water-solubility which is less than the water-solubility of said water-soluble substrate. The first discrete zones represent from 10% to 90% of the surface area of said first or second surface.Type: ApplicationFiled: July 2, 2007Publication date: January 10, 2008Inventor: Vincenzo Catalfamo
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Patent number: 7288593Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group. Preferably, the modified EVOH comprises structures IV, V, and VI: wherein x is an integer greater than or equal to 1, y is an integer greater than or equal to 1, z is an integer greater than or equal to 1, and R comprises a cycloalkenyl group. The modified EVOH is useful in oxygen barrier applications, such as a forming an oxygen barrier layer of a packaging article. Also disclosed are methods of modifying ethylene vinyl alcohol polymers, and using the modified EVOH to make packaging articles with a superior barrier to entry by atmospheric oxygen.Type: GrantFiled: July 10, 2006Date of Patent: October 30, 2007Assignee: Cryovac, Inc.Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
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Patent number: 7262261Abstract: Condensation products of dihydroxyaromatics A, alone or in mixture with mono- or polyhydroxyaromatics C, with diepoxides or polyepoxides B which have been alkylolated by reaction with aldehydes D and whose alkylol groups may have been etherified with alcohols, a process for preparing them, and a method of use thereof in particular as compositions for coating the inside of foodstuff and beverage packaging forms made from metals.Type: GrantFiled: November 6, 2003Date of Patent: August 28, 2007Assignee: Surface Specialities Germany GmbH & Co. KGInventors: Gerhard Brindöpke, Oliver Etz, Paul Oberressl, Bodo Wixmerten
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Patent number: 7255904Abstract: The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.Type: GrantFiled: August 31, 2001Date of Patent: August 14, 2007Assignee: Kuraray Co., Ltd.Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Mizuho Maeda
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Patent number: 7247390Abstract: Herein is disclosed an oxygen barrier composition comprising an oxygen barrier polymer and an oxygen scavenging polymer. Preferably, the oxygen barrier polymer is selected from polymers or copolymers of vinyl alcohol, polyesters, polymers or copolymers of vinylidene dichloride, polymers or copolymers of epoxies, polysulfones, polymers or copolymers of acrylonitrile, polymers or copolymers of isocyanates, or polyamides other than MXD6; and the oxygen scavenging polymer either comprises an ethylenic backbone and a cyclic olefinic pendant group of structure I, or a polyester group of structure II or structure III: wherein q1, q2, q3, q4, and r are independently selected from hydrogen, methyl, or ethyl; m is —(CH2)n—, wherein n is an integer from 0 to 4, inclusive; X is null or a linking group; and, when r is hydrogen, at least one of q1, q2, q3, and q4 is also hydrogen. The oxygen barrier composition can be formed into an oxygen barrier layer of a packaging article.Type: GrantFiled: September 21, 2000Date of Patent: July 24, 2007Assignee: Chevron Phillips Chemical Company, LPInventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
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Patent number: 7226976Abstract: Provided are a latent curing agent that gives an epoxy resin composition with improved storage stability and low-temperature curability; and a curable epoxy resin composition prepared by mixing the said curing agent and an epoxy compound. The epoxy resin composition has improved storage stability, and cures at lower temperatures for a shorter period of time than conventional ones. The latent curing agent for epoxy resin comprises two components, (A) a radically polymerized polymer of a monomer having at least a polymerizable double bond, which has at least a tertiary amino group in the molecule, and (B) a polymer having at least a hydroxyl group in the molecule, and forms a solid solution that is solid at 25° C.Type: GrantFiled: April 21, 2005Date of Patent: June 5, 2007Assignee: Ajinomoto Co., Inc.Inventors: Hiroyasu Koto, Junji Ohashi, Hiroshi Sakamoto, Masato Kobayashi
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Patent number: 7179882Abstract: The present invention relates to low viscosity polymer polyols and to a process for the preparation of these low viscosity polymer polyols. These polymer polyols comprise the free-radical polymerization product of (A) a base polyol, (B) a pre-formed stabilizer, and (C) at least one ethylenically unsaturated monomer, in the presence of (D) at least one free-radical polymerization initiator, and (E) at least one polymer control agent. The total amount of polymer control agent present in the polymer polyols of the present invention ranges from greater than about 5.0% up to about 20% by weight, based on 100% by weight of the polymer polyol.Type: GrantFiled: August 2, 2004Date of Patent: February 20, 2007Assignee: Bayer Materialscience LLCInventors: Rick L. Adkins, Scott A. Guelcher, James R. Charron, John E. Hayes
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Patent number: 7175918Abstract: The present invention relates to polyolefin compositions that incorporate an acrylic/polyether comb-branched copolymer, articles made from the compositions, such as polyolefin films and polyolefin fibers, and methods for making the compositions and the articles.Type: GrantFiled: April 27, 2004Date of Patent: February 13, 2007Assignees: Equistar Chemicals, LP, Lyondell Chemical Technology, L.P.Inventors: Anil W. Saraf, Steven A. Schwartz, Edward T. Shawl, Michael Bridges, Venki Chandrashekar
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Patent number: 7176257Abstract: The present invention has an object of the present invention to provide a polyvinyl acetal resin for heat-developable photosensitive materials as well as a heat-developable photosensitive material while solving such problems as coating solution pot life, coloration of heat-developable photosensitive material, fog, poor gradation, insufficient sensitivity and poor undeveloped film storability and making it possible for the materials to acquire good image characteristics. The present invention is constituted of a polyvinyl acetal resin for heat-developable photosensitive materials which is a polyvinyl acetal resin synthesized by the acetalization reaction between a polyvinyl alcohol and an aldehyde and which comprises having a degree of polymerization of 200 to 3,000, a residual acetyl group content of 0 to 25 mole percent and a residual hydroxyl group content of 17 to 35 mole percent, as calculated while regarding one acetal group as two acetalized hydroxyl groups, a water content of not more than 2.Type: GrantFiled: March 2, 2004Date of Patent: February 13, 2007Assignee: Sekisui Chemical Co., Ltd.Inventor: Yoshitaka Miyake
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Patent number: 7166341Abstract: Water-soluble or water-dispersible hotmelt adhesives are prepared using graft copolymers produced by graft copolymerizing olefinically unsaturated monomers onto polyalkylene oxides. The adhesives additionally contain at least one resin which improves tackiness and the compatibility of the adhesive components. Other components such as polymers, plasticizers, and additives may also be present. The adhesives are especially suited for use in the labelling of recyclable or reuseable hollow containers. The adhesive may be completely separated from the hollow containers and dissolved in an alkaline washing liquor even at low temperatures.Type: GrantFiled: January 21, 2004Date of Patent: January 23, 2007Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)Inventors: Marcus Heemann, Thomas Moeller, Ingo Gensch, Wolfgang Klingberg
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Patent number: 7109272Abstract: A styrene/hydrogenated diene block copolymer characterized in that it has in side chains at least one kind of functional groups selected from the group consisting of a boronic acid group and a boron-containing group capable of converting into a boronic acid group in the presence of water, the content of the functional groups in the copolymer is 100 to 2,000 ?eq/g, and the weight ratio of the styrene units to hydrogenated diene units contained in the copolymer is from 5/95 to 70/30. By thus incorporating a sufficient amount of boron-containing groups, a highly reactive styrene/hydrogenated diene block copolymer is provided.Type: GrantFiled: April 26, 2005Date of Patent: September 19, 2006Assignee: Kuraray Co., Ltd.Inventors: Kaoru Ikeda, Hiroshi Kawai
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Patent number: 7071259Abstract: Functionalized propylene polymer compositions useful as coupling/compatibilizing agents are provided. The compositions are a mixture of two different functionalized propylene polymers. Polypropylene composites containing fillers and/or non-compatible resins and formulated using the mixed functionalized coupling/compatibilizing agents are also provided.Type: GrantFiled: July 27, 2004Date of Patent: July 4, 2006Assignee: Equistar Chemicals, LPInventor: Maged G. Botros
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Patent number: 7064158Abstract: A resin composition comprising 70 to 99.9% by weight of ethylene-vinyl alcohol copolymer (A) and 0.1 to 30% by weight of a thermoplastic resin (B) other than the ethylene-vinyl alcohol copolymer (A) is provided. In the resin composition, an ethylene content ETa (mol %) and a degree of saponification SDa (%) of the ethylene-vinyl alcohol copolymer (A) satisfy the following equations (1) and (2): 25?ETa?55??(1) 90?SDa<99, ??(2) and an oxygen absorption rate of the resin composition is 0.01 ml/m2·day or more.Type: GrantFiled: August 31, 2001Date of Patent: June 20, 2006Assignee: Kuraray Co., Ltd.Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya
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Patent number: 7041731Abstract: This invention provides a method for producing a saponified ethylene-vinyl acetate copolymer in which visible imperfections (particularly fish eyes) of the saponified copolymer is inhibited. In this invention, a mixture solution is prepared by adding water to a methanol solution after saponifying an ethylene-vinyl acetate copolymer, and insoluble materials are removed from this mixture solution. Various types of filter or centrifugal separator are used to remove insoluble materials. It is preferable that the weight ratio of methanol to water is from 5:5 to 9:1, the concentration of the saponified copolymer is from 30 to 60 wt %, and the temperature is from 55 to 80° C. This method is particularly suitable for producing a saponified ethylene-vinyl acetate copolymer having an ethylene content of 20 to 70 mol % and a saponification degree of at least 95 mol %.Type: GrantFiled: July 21, 2003Date of Patent: May 9, 2006Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Toshio Tuboi