With Sicp, Spfi, Or Polymer Thereof Patents (Class 525/58)
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Patent number: 6881492Abstract: A composition suitable for forming a primer layer on a polymer sheet comprising: a) polyethyleneimine; b) latex; wherein the latex has a Tg lower than 25° C. and c) a hydrophilic colloid material. A method of coating the composition is also disclosed.Type: GrantFiled: September 27, 2002Date of Patent: April 19, 2005Assignee: Eastman Kodak CompanyInventors: Yuanqiao Rao, DeBasis Majumdar, Robert J. Kress, David E. Decker
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Patent number: 6838516Abstract: The present invention relates to a water dispersible polyisocyanate composition comprising (a) an aliphatic polyisocyanate or a mixture of aliphatic polyisocyanates or a mixture of aliphatic polyisocyanates with other polyisocyanates; and (b) a reaction product of component (a) with a component selected from the group consisting of: (ii) a polyether diol or triol or a mixture thereof wherein a weight ratio of ethylene oxide (EO) to propylene oxide (PO) of the polyether diol and triol is greater than about 60:40, and the polyether diol has a molecular weight of about 300 to 1600 g/mole, and the polyether triol has a molecular weight of about 450 to 2400 g/mole; and (ii) a mixture of polyether monol and polyether polyol, wherein the polyether polyol is selected from the group consisting of polyether diol, triol and a mixture thereof wherein a weight ratio of EO to PO of the polyether monol, diol and triol is greater than about 60:40, and the polyether diol and triol have the molecular weights as defined aboType: GrantFiled: July 26, 2002Date of Patent: January 4, 2005Assignee: Great Eastern Resins Industrial Co., Ltd.Inventors: Shenghong A. Dai, Jui-Ming Chang, Tsai-Lung Chen, Will Yang
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Patent number: 6831129Abstract: An object of the present invention is to provide a resin-coated copper foil for manufacturing printed wiring boards that excel in total balance of properties of flame retardation, resin flow, water resistance, and peeling strength. The resin-coated copper foil comprises a resin layer on one side of a copper foil, and is characterized in that the resin layer comprises a resin composition having the following composition: a. a high polymer having cross-linkable 5 to 30 parts by weight functional groups in the molecule, and a cross-linking agent therefor b. an epoxy resin that is liquid at 5 to 30 parts by weight room temperature c.Type: GrantFiled: May 24, 2002Date of Patent: December 14, 2004Assignee: Mitsui Mining & Smelting Co. Ltd.Inventors: Tetsuro Sato, Tsutomu Asai, Toshifumi Matsushima
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Patent number: 6815080Abstract: The present invention relates to a thermoplastic resin composition comprising an ethylene-vinyl alcohol copolymer and a modified polyester type thermoplastic elastomer produced by modifying a polyester type thermoplastic elastomer with an unsaturated carboxylic acid or its derivative, and a multi-layer laminate comprising a layer A comprising the thermoplastic resin composition as defined in the above, and at least one layer B comprising a thermoplastic resin composition other than the composition as defined in the above.Type: GrantFiled: April 14, 2003Date of Patent: November 9, 2004Assignee: Mitsubishi Chemical CorporationInventor: Masatoshi Omori
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Patent number: 6808752Abstract: Coating composition including a film-forming component, further including (a) a product formed by reacting a mixture including carboxy functional polymer, hydroxy functional polymer, or a mixture thereof, or ethylenically unsaturated monomer, with epoxy resin, and (b) a polyvinyl alcoholic-containing phenolic resol resin. Also provided is a method of coating a metal substrate with said coating composition. Further provided is a composite material comprising a metal substrate having at least one surface covered with a cured film of the coating composition.Type: GrantFiled: March 15, 2002Date of Patent: October 26, 2004Assignee: The Valspar CorporationInventor: Thomas R. Mallen
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Publication number: 20040210000Abstract: A method of improving ink stability. A block co-polymer is added to either an under-/overprinting vehicle or an ink vehicle. The polymer increases chemical interactions between the ink the print media. The under-/overprinting vehicle and the ink vehicle interact through electrostatic interactions while the polymer increases smearfastness by interacting with the print media through non-covalent interactions.Type: ApplicationFiled: May 7, 2004Publication date: October 21, 2004Inventor: David M. Schut
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Patent number: 6790499Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, and an additive combination, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The additive combination comprises compounds selected from at least two groups wherein the groups are (i.) poly(vinyl alcohol) or ethylene/vinyl alcohol copolymer, (ii.) polyhydric alcohols and (iii.) polyacrylamide, polymethacrylamide or copolymer of acrylamide or methacrylamide. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.Type: GrantFiled: December 20, 2001Date of Patent: September 14, 2004Assignee: Ciba Speicalty Chemicals CorporationInventors: Stephen M Andrews, Paul A. Odorisio, Dirk Simon
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Publication number: 20040157991Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: ApplicationFiled: December 2, 2003Publication date: August 12, 2004Inventor: Antoni Kozlowski
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Patent number: 6767961Abstract: The present invention discloses water-soluble compositions comprising a blend of poly(ethylene oxide) and poly(vinyl alcohol) that have improved ductility over water-soluble compositions comprising poly(vinyl alcohol) alone. In one desirable embodiment of the present invention, the poly(ethylene oxide) component of the blend is grafted. Grafted poly(ethylene oxide) resins have improved processability and improved blend compatibility with poly(vinyl alcohol). Films comprising a melt blend of poly(vinyl alcohol) and grafted poly(ethylene oxide) have improved melt processability as well as other improved properties. Films comprising compositions of the present invention have improved ductility over films comprising poly(vinyl alcohol) alone while retaining much of the high strength and water solubility exhibited by such poly(vinyl alcohol) films.Type: GrantFiled: June 19, 2000Date of Patent: July 27, 2004Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James Hongxue Wang, David Michael Schertz
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Patent number: 6759480Abstract: The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.Type: GrantFiled: September 26, 2000Date of Patent: July 6, 2004Assignee: AtofinaInventors: Alain Bouilloux, Christophe Lacroix, Jean-Marc Le Blevec, Thibaut Montanari
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Patent number: 6706391Abstract: An anisotropically electroconductive film, which has a high reliability in its capacity for conducting electricity and also a good adhesion under such an adhesive condition that the film is heated at a temperature of 130° C. or less for a short period of time, has a layer of an adhesive within which electroconductive particles are distributed. The adhesive is composed of a thermosetting resin composition including a base resin, a reactive compound, an organic peroxide and a reaction accelerating compound, and also the electroconductive particles incorporated into the thermosetting resin composition. The base resin is a polyacetalized resin which is obtained by acetalizing a polyvinyl alcohol. The reactive compound is at least one selected from a group consisting of acryloxy group-bearing compounds, methacryloxy group-bearing compounds and epoxy group-bearing compounds. The reaction accelerating compound is a compound which has a radically reactive group and alkali-reactive group as its end groups.Type: GrantFiled: July 26, 2001Date of Patent: March 16, 2004Assignee: Bridgestone CorporationInventors: Ryo Sakurai, Hidetoshi Hiraoka, Tokuo Okada, Teruo Miura, Yasuhiro Morimura
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Patent number: 6683120Abstract: A bioadhesive composition for use as a skin adhesive, the composition formed by polymerizing with cross-linking and/or entanglement an aqueous reaction mixture comprising effective amounts of at least one monomer dissolved or suspended therein and capable of forming a hydrogel on polymerization, optionally at least one cross-linking agent for the monomer, and water, said composition having an elastic modulus (G′) and a viscous modulus (G″), wherein the degree of polymerization and/or the degree of cross-linking and/or entanglement are selected to control the skin adhesion properties of the bioadhesive composition having regard to the rate of change of tan delta (G″÷G″) against frequency in a diagnostic portion of the frequency range 0.01 to 300 rad/s, typically the lower end of the said frequency range below about 100 rad/s.Type: GrantFiled: July 27, 2001Date of Patent: January 27, 2004Assignee: First Water LimitedInventor: Hugh Semple Munro
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Patent number: 6664333Abstract: Selectively cold-water responsive compositions constructed of combinations of polymers including at least one hydrolytically degradable polymer and at least one cold-water soluble polymer are provided. Additionally, methods of making and using selectively cold-water sensitive compositions are described. In one embodiment, the method comprises combining a polylactide and a cold-water soluble polyvinyl alcohol at a temperature above the melting point of the polymer having the higher melting point, and below the decomposition point of the polymer having the lower decomposition point, to form a homogeneous polymer blend is also provided. The cold-water responsive properties of the compositions of the present invention may be varied include water dispersible, water disintegratable, and water weakenable.Type: GrantFiled: March 1, 1999Date of Patent: December 16, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James Hongxue Wang, David Michael Schertz
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Patent number: 6664366Abstract: Thermally stable polymers comprising chain members derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polymer chain, are prepared using an interfacial method comprising the steps of: (a) combining at least one 1,3-dihydroxybenzene moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; (b) adding to the mixture from (a) a controlled stoichiometric ratio of at least one acid chloride and at least one base while maintaining the pH between about 4 and about 8.5, and (c) adjusting the pH of the reaction mixture to a value in the range of about 7 and about 9 following complete addition of acid chloride, and stirring the reaction mixture for a time sufficient to destroy any anhydride linkages in the polymer chain.Type: GrantFiled: March 25, 2002Date of Patent: December 16, 2003Assignee: General Electric CompanyInventors: James Manio Silva, David Michel Dardaris, Gregory Allen O'Neil, Joseph Anthony Suriano
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Patent number: 6653372Abstract: A process for preparing an addition-polymer powder suitable for modifying a binding mineral building material by drying an aqueous addition-polymer dispersion whose film has a glass transition temperature Tg≦30° C. and to which a drying assistant has been added comprises adding to the aqueous addition-polymer dispersion before drying only a drying assistant which will have a plasticizing or deplasticizing effect in the ready-to-use mix of the binding mineral building material with water and admixing the resulting dry addition-polymer powder with at least one assistant in the form of a finely divided solid which will have an opposite effect to the drying assistant added before drying.Type: GrantFiled: June 4, 1997Date of Patent: November 25, 2003Assignee: BASF AktiengesellschaftInventors: Joachim Pakusch, Joachim Roser, Maximilian Angel, Andree Dragon
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Patent number: 6649700Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and, optionally, (d) a resin that exists in the liquid form at room temperature.Type: GrantFiled: September 21, 2001Date of Patent: November 18, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
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Patent number: 6627673Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.Type: GrantFiled: July 24, 2001Date of Patent: September 30, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Vasily A. Topolkaraev, Dave A. Soerens
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Patent number: 6616944Abstract: The invention is directed to self-assembling, polymer-based delivery systems for proteins. The delivery systems comprises an active agent and a polyol ester of the invention, having a linear polyol containing six or more hydroxyl groups as a central backbone and biodegradable hydroxy carboxylic ester groups attached to the central backbone.Type: GrantFiled: March 8, 2001Date of Patent: September 9, 2003Assignee: Medinnova Gesellschaft fur Medizinsche Innovationen aus Adkademischer Forschung mbHInventors: Thomas Kissel, Armin Breitenbach, Tobias Jung, Walter Kamm
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Hyperbranched amphiphilic polymeric additives and polymer compositions with increased surface energy
Patent number: 6617397Abstract: The surface energy of polymeric substrates is increased by the application or incorporation of novel amphiphilic block copolymers. The block copolymer additives comprise a linear hydrophilic polymer or oligomer and a random hyperbranched polymer or oligomer and is completely or partially terminated with lipophilic end groups. The polymeric articles or constructions which benefit from the application or incorporation of the amphiphilic block copolymers in the areas of anti-fog, dissipation of static electricity, paintability, dyeability, printability, wicking of moisture, adhesion and polymer compatibility include carpet fibers, composite fibers, agricultural films, nonwoven coverstock, exterior automotive bumper fascia, packaging, hygienic products, incompatible polymer blends, laminated articles and eyewear.Type: GrantFiled: March 4, 2002Date of Patent: September 9, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: John James McNamara, Anunay Gupta, David Devore -
Patent number: 6596843Abstract: Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: interfacial method for preparing polymers comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, comprising the steps of: (a) preparing an aqueous solution comprising at least one resorcinol moiety, said solution having a pH less than or equal to about 5; (b) after step (a), preparing a mixture comprising the resorcinol moiety, at least one catalyst and at least one organic solvent substantially immiscible with water; and (c) adding to the mixture from (b) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.Type: GrantFiled: September 28, 2001Date of Patent: July 22, 2003Assignee: General Electric CompanyInventors: Daniel Joseph Brunelle, Paul Dean Sybert, Gregory Allen O'Neil, Joseph Anthony Suriano, Tiberiu Mircea Siclovan, Zhaohui Su
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Publication number: 20030125422Abstract: A method for manufacture of particles for powder coating is disclosed in which the particles are prepared from a suspension obtained from a mixture of a thermosetting resin solution and an aqueous solution containing a water-soluble polymer.Type: ApplicationFiled: November 15, 2002Publication date: July 3, 2003Applicant: Nippon Paint Co., Ltd.Inventors: Haruhiko Satoh, Yutaka Harada, Atsushi Yamada
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Patent number: 6559226Abstract: The present invention provides golf balls having a cover, a core, and optionally one or more intermediate layers between the cover and the core, wherein at least one of the cover, the core and, if present, the intermediate layer or layers, includes an anionic polymer. The anionic polymer has at least one of a neutralizable hydroxyl or dealkylable ether group, at least a portion of which are neutralized or dealkylated by a metal ion to provide anionic moieties. The anionic polymer compositions of the present invention can be used to provide improved characteristics to golf balls made therefrom.Type: GrantFiled: April 24, 2001Date of Patent: May 6, 2003Assignee: Achushnet CompanyInventor: Murali Rajagopalan
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Patent number: 6555607Abstract: A water-soluble resin composition comprising (1) a water-soluble resin, (2) a water-soluble crosslinking agent, (3) at least one of surface active agents selected from acetylene alcohols, acetylene glycols, polyethoxylates of acetylene alcohols and polyethoxylates of acetylene glycols, and (4) a solvent consisting of water or a mixture of water and a water-soluble solvent. This water-soluble resin composition is applied onto a resist pattern, then heated to crosslink by an acid supplied from the resist, followed by development to remove the non-crosslinked water-soluble resin coating layer. This water-soluble resin composition is excellent in coating characteristics on steps of resist patterns and in dimensional regulation upon fining of patterns so that resist patterns such as trench patterns and hole patterns can effectively be fined.Type: GrantFiled: February 28, 2001Date of Patent: April 29, 2003Assignee: Clariant Finance (BVI) LimitedInventors: Takashi Kanda, Hatsuyuki Tanaka
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Patent number: 6552123Abstract: Provided are melt-spun fibers comprising, as at least one component, a water-soluble polyvinyl alcohol, and a method for producing fibrous structures comprising the fibers. The thermoplastic polyvinyl alcohol fibers comprise, as at least one component, a water-soluble polyvinyl alcohol containing from 0.1 to 25 mol % of C1-4 &agr;-olefin units and/or vinyl ether units, having a molar fraction, based on vinyl alcohol units, of a hydroxyl group of vinyl alcohol unit located at the center of 3 successive vinyl alcohol unit chain in terms of triad expression of being from 70 to 99.9 mol %, having a carboxylic acid and lactone ring content of from 0.02 to 0.15 mol %, and having a melting point falling between 160° C. and 230° C., and contain from 0.0003 to 1 part by weight, relative to 100 parts by weight of the polyvinyl alcohol therein and in terms of sodium ion, of an alkali metal ion.Type: GrantFiled: December 16, 1999Date of Patent: April 22, 2003Assignee: Kuraray Co., Ltd.Inventors: Takashi Katayama, Kazuhiko Tanaka, Naoki Fujiwara, Tomoaki Kimura, Akihiro Hokimoto, Nobuhiro Koga, Hitoshi Nakatsuka, Yoshimi Umemura, Hiroshi Kanehira, Masao Kawamoto, Junyo Nakagawa
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Patent number: 6537468Abstract: The invention is directed at an ion-conductive solid polymer-forming composition, a binder resin and an ion-conductive solid polymer electrolyte comprising (A) a polymeric compound containing polyvinyl alcohol units and having an average degree of polymerization of at least 20, in which compound some or all of the hydroxyl groups on the polyvinyl alcohol units are substituted with oxyalkylene-containing groups to an average molar substitution of at least 0.3, (B) an ion-conductive salt, and (C) a compound having crosslinkable functional groups. The composition and the polymer electrolyte obtained therefrom have a high ionic conductivity and a high tackiness. Moreover, the polymer electrolyte has a semi-interpenetrating polymer network structure, giving it excellent shape retention.Type: GrantFiled: November 21, 2000Date of Patent: March 25, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Patent number: 6533964Abstract: The invention provides a novel polymeric compound comprising polyvinyl alcohol units and having an average degree of polymerization of at least 20, in which some or all of the hydroxyl groups on the polyvinyl alcohol units are substituted with oxyalkylene-containing groups to an average molar substitution of at least 0.3; a binder resin composed of this polymeric compound; an ion-conductive polymer electrolyte composition having a high ionic conductivity and high tackiness which lends itself well to use as a solid polymer electrolyte in film-type cells and related applications; and a secondary cell.Type: GrantFiled: November 22, 2000Date of Patent: March 18, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Patent number: 6531548Abstract: Disclosed are physical blends of poly(1,3-propylene 2,6-naphthalate) polymer compositions with other polymers in which the concentration of poly(1,3-propylene 2,6-naphthalate) is from 1 to 99 mole %.Type: GrantFiled: February 28, 2001Date of Patent: March 11, 2003Assignee: E. I. Du Pont de Nemours and CompanyInventor: Howard Chung-Ho Ng
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Patent number: 6524498Abstract: An electrolyte composition and a solid polymer electrolyte for electric double-layer capacitors are endowed with high ionic conductivity, high tackiness and shape retention. The invention is also directed at a polarizable electrode-forming composition and a polarizable electrode having a high adhesion, high dielectric properties, and excellent shape retention. A high-performance electric double-layer capacitor arrived at using the above compositions and components is additionally disclosed.Type: GrantFiled: November 22, 2000Date of Patent: February 25, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Publication number: 20030013806Abstract: A method of improving ink stability. A block co-polymer is added to either an under-/overprinting vehicle or an ink vehicle. The polymer increases chemical interactions between the ink the print media. The under-/overprinting vehicle and the ink vehicle interact through electrostatic interactions while the polymer increases smearfastness by interacting with the print media through non-covalent interactions.Type: ApplicationFiled: May 25, 2001Publication date: January 16, 2003Inventor: David M. Schut
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Patent number: 6506820Abstract: A method for manufacture of particles for powder coating is disclosed in which the particles are prepared from a suspension obtained from a mixture of a thermosetting resin solution and an aqueous solution containing a water-soluble polymer. The thermosetting resin solution contains A resin, B resin and an organic solvent wherein: (a) 0.5≦{(SP value of the A resin)−(SP value of the B resin)}≧1.5; (b) {(Tg of the A resin)−(Tg of the B resin)}≧10° C.; (C) 40° C.≦(Tg of the A resin)≦100° C., and, 20° C.≦(Tg of the B resin)≦50° C.; and (d) 5/95≦(a ratio in solids weight of the A resin to B resin)≦50/50.Type: GrantFiled: April 14, 1999Date of Patent: January 14, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Haruhiko Satoh, Yutaka Harada, Atsushi Yamada
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Patent number: 6500897Abstract: The present invention is a hydrolytically modified, biodegradable polymer and a method of making a hydrolytically modifiable a biodegradable polymer. In a preferred embodiment, the invention is a method of grafting polar groups onto biodegradable polymers and modified biodegradable polymer compositions produced by the method. The polymer compositions are useful as components in flushable and degradable articles. Water-sensitive polymer blends and method of making those polymer blends are also disclosed.Type: GrantFiled: December 29, 2000Date of Patent: December 31, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James H. Wang, David M. Schertz
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Patent number: 6485789Abstract: The invention provides a method of treating of a substrate by contacting the substrate with a fluorochemical composition that comprises a condensation product of a di- or tri-isocyanate and at least one polyether, the polyether being obtained as the reaction product of a fluorochemical substituted epoxide. Substrates treated in accordance with the invention have good stain release properties, particularly to oil stains or tea stains, so stains can be more easily removed from the treated substrate in a laundering procedure.Type: GrantFiled: September 24, 1999Date of Patent: November 26, 2002Assignee: 3M Innovative Properties CompanyInventors: Kathy E. M. L. A. Allewaert, Pierre J. Vander Elst, Rudolf J. Dams
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Publication number: 20020173580Abstract: Methods for making creping adhesives and using them in the creping of cellulosic fiber webs. The creping adhesives are a combination of polyamine-epihalohydrin and poly(vinyl alcohol). The method comprises the preparation and application of the creping adhesives to attain strong adhesion of fiber webs onto a drying surface, and the creping of the fiber webs to obtain a soft, bulky tissue paper web.Type: ApplicationFiled: July 9, 2002Publication date: November 21, 2002Inventor: Anthony J. Allen
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Publication number: 20020169253Abstract: The invention relates to a primer for plastic films which comprises a blend of poly(vinyl alcohol) and an adhesion promoter, specifically poly(ethylene imine) and a hardened epoxy resin. The invention is useful to improve the oxygen barrier properties of a plastic film.Type: ApplicationFiled: June 8, 2001Publication date: November 14, 2002Inventor: Dennis Emmett McGee
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Publication number: 20020136900Abstract: Coating composition including a film-forming component, further including (a) a product formed by reacting a mixture including carboxy functional polymer, hyrdroxy functional polymer, or a mixture thereof, or ethylenically unsaturated monomer, with epoxy resin, and (b) a polyvinyl alcoholic-containing phenolic resol resin. Also provided is a method of coating a metal substrate with said coating composition. Further provided is a composite material comprising a metal substrate having at least one surface covered with a cured film of the coating composition.Type: ApplicationFiled: March 15, 2002Publication date: September 26, 2002Applicant: The Valspar CorporationInventor: Thomas R. Mallen
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Patent number: 6449093Abstract: A optical body has at least two polymeric materials forming a reflective interface for at least one polarization of light. One optical body is a multilayer optical film that includes birefringent first optical layers and second optical layers interleaved with the first optical layers. Each first optical layer is formed using a polymer, such as a copolymer of polyethylene naphthalate. The second optical layers are formed so that they have a lower in-plane birefringence than the first optical layers for 632.8 nm light. Optical bodies can be used as, for example, polarizers and mirrors. The optical bodies can be formed using polymers that provide better index matching and are more easily protected from UV light without coloring the optical body.Type: GrantFiled: October 12, 1999Date of Patent: September 10, 2002Assignee: 3M Innovative Properties CompanyInventors: Timothy J. Hebrink, Peter D. Condo, William W. Merrill
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Patent number: 6444750Abstract: An improved PVOH-based coating solution for application to a polymeric substrate. The coating solution includes poly(vinyl alcohol), a formaldehyde-containing crosslinking agent and a crosslinking-promoting acid catalyst which lowers the pH of the solution to about 3.5 or less and, preferably, to about 3 or less. The coating solution exhibits improved viscosity stability, particularly with the addition of a second acid catalyst. The coating solution also provides improved crosslinking and oxygen barrier characteristics upon drying.Type: GrantFiled: March 6, 1995Date of Patent: September 3, 2002Assignee: ExxonMobil Oil Corp.Inventor: Robert E. Touhsaent
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Hyperbranched amphiphilic polymeric additives and polymer compositions with increased surface energy
Patent number: 6444758Abstract: The surface energy of polymeric substrates is increased by the application or incorporation of novel amphiphilic block copolymers. The block copolymer additives comprise a linear hydrophilic polymer or oligomer and a random hyperbranched polymer or oligomer and is completely or partially terminated with lipophilic end groups. The polymeric articles or constructions which benefit from the application or incorporation of the amphiphilic block copolymers in the areas of anti-fog, dissipation of static electricity, paintability, dyeability, printability, wicking of moisture, adhesion and polymer compatibility include carpet fibers, composite fibers, agricultural films, nonwoven coverstock, exterior automotive bumper fascia, packaging, hygienic products, incompatible polymer blends, laminated articles and eyewear.Type: GrantFiled: February 7, 2001Date of Patent: September 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: John James McNamara, Anunay Gupta, David Devore -
Patent number: 6433080Abstract: A bloom inhibitor which comprises (A) an alkylene oxide adduct of a saponified ethylene-saturated carboxylic acid vinyl ester copolymer, and (B) a polyether compound; a rubber composition comprising a rubber and the bloom inhibitor; and a vulcanized rubber in which blooming is prevented obtained by vulcanizing the rubber composition are provided.Type: GrantFiled: March 14, 2000Date of Patent: August 13, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Tohru Fujiki, Masaaki Tanaka
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Patent number: 6433079Abstract: Water-dilutable polyvinylbutyral dispersions obtainable by a two-stage reaction in the first stage of which at least one tertiary alkanolamine A and at least one diisocyanate B are reacted to the theoretically calculated NCO content and the amounts of components A and B are chosen such that the amount of substance of the diisocyanates B is from 0.8 to 1.3 times the amount of substance of the reactive hydroxyl groups in A and thereafter in the second stage a polyvinylbutyral C dissolved in a solvent which is inert towards isocyanates is reacted with the adduct AB from the first step to form the product ABC until all of the isocyanate groups have undergone complete reaction, the number of hydroxyl groups in C being at least ten times the number of isocyanate groups in the reaction product AB.Type: GrantFiled: May 25, 2000Date of Patent: August 13, 2002Assignee: Solutia Austria GmbHInventors: Martin Gerlitz, Maximilian Friedl, Thomas Fischer, Ernst Supper, Manfred Krassnitzer
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Patent number: 6420004Abstract: The invention concerns composite polyester films with good barrier properties relative to gases. More precisely, it concerns a biaxially drawn film, based on polyester and having improved barrier properties relative to gases, characterised in that it comprises a base polyester film of 5 to 50 &mgr;m, coated on one of its two surfaces with a deposit containing polyvinyl alcohol and a water dispersible copolyester with sulphonyloxy units, said composite film having permeability to oxygen measured at 23° C. under 50% relative humidity, not more than 5 cm3/m2/24 h. Said composite films have, besides being transparent and having barrier properties, excellent resistance to mechanical stresses, such as in particular crumpling.Type: GrantFiled: March 20, 2000Date of Patent: July 16, 2002Assignee: Toray Plastics Europe S.A.Inventors: Didier Veyrat, Eric Maitre
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Patent number: 6407145Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.Type: GrantFiled: September 17, 1998Date of Patent: June 18, 2002Assignee: Novartis AGInventor: Beat Müller
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Publication number: 20020065363Abstract: Selectively cold-water responsive compositions constructed of combinations of polymers including at least one hydrolytically degradable polymer and at least one cold-water soluble polymer are provided. Additionally, methods of making and using selectively cold-water sensitive compositions are described. In one embodiment, the method comprises combining a polylactide and a cold-water soluble polyvinyl alcohol at a temperature above the melting point of the polymer having the higher melting point, and below the decomposition point of the polymer having the lower decomposition point, to form a homogeneous polymer blend is also provided. The cold-water responsive properties of the compositions of the present invention may be varied include water dispersible, water disintegratable, and water weakenable.Type: ApplicationFiled: March 1, 1999Publication date: May 30, 2002Inventors: JAMES HONGXUE WANG, DAVID MICHAEL SCHERTZ
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Patent number: 6387853Abstract: Polymers are derivatized and then may be introduced into a wellbore, such as in a hydraulic fracturing treatment. A polymer may be a guar powder that is mixed with a organic solvent and derivatized using a derivatizing agent, such as sodium chloroacetate. The polymer is typically derivatized in bulk prior to introduction into the wellbore. The derivatized polymer may be hydrated and/or crosslinked prior to introduction into the wellbore.Type: GrantFiled: March 27, 1998Date of Patent: May 14, 2002Assignee: BJ Services CompanyInventors: Jeffrey C. Dawson, Subramanian Kesavan, Hoang V. Le
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Publication number: 20020049281Abstract: The present invention provides a process for the production of hyaluronic acid (HA) derivatives cross-linked with another polymer, in particular multiple e.g. double cross-linked hyaluronic acid derivatives. The invention also provides novel cross-linked derivatives, products containing them and their uses in cosmetic, medical and pharmaceutical applications.Type: ApplicationFiled: August 2, 2001Publication date: April 25, 2002Inventors: Xiaobin Zhao, Catherine Alexander, Jane Fraser
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Patent number: 6359062Abstract: Coating composition including a film-forming component, further including (a) a product formed by reacting a mixture including carboxy functional polymer, hydroxy functional polymer, or a mixture thereof, or ethylenically unsaturated monomer, with epoxy resin, and (b) a polyvinyl alcoholic-containing phenolic resol resin. Also provided is a method of coating a metal substrate with said coating composition. Further provided is a composite material comprising a metal substrate having at least one surface covered with a cured film of the coating composition.Type: GrantFiled: March 2, 1999Date of Patent: March 19, 2002Assignee: The Valspar CorporationInventor: Thomas R. Mallen
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Patent number: 6333109Abstract: The present invention has an object to provide a novel water-swellable crosslinked polymer composition which exhibits excellent saltwater absorption speed and capacity under a load. This object can be achieved in the case where, in a water-swellable crosslinked polymer composition comprising a blend of water-swellable crosslinked polymer particles of basicity in water and water-swellable crosslinked polymer particles of acidity in water, the water-swellable crosslinked polymer particles of basicity in water are unified with the water-swellable crosslinked polymer particles of acidity in water through ionic bondings in a state where water is present between the particles, wherein the ionic bondings are formed in a state where water is present between the particles by neutralization of at least part of acid groups of the water-swellable crosslinked polymer particles of acidity in water with the water-swellable crosslinked polymer particles of basicity in water.Type: GrantFiled: August 11, 1999Date of Patent: December 25, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Shigeru Sakamoto, Yoshifumi Adachi, Toshimasa Kitayama
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Patent number: 6313221Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and/or (d) a resin that exists in the liquid form at room temperature.Type: GrantFiled: May 26, 2000Date of Patent: November 6, 2001Assignee: Nippon Paint Co., Ltd.Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
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Patent number: 6294602Abstract: A resin composition comprising (A) an ethylene-vinyl alcohol copolymer, (B) a polyamide resin, (C) an ethylene-unsaturated carboxylic acid random copolymer or its metal salt, and (D) a thermoplastic resin except the resins noted above, of which the solubility parameter (as calculated from the Fedors' formula) is not more than 11. The resin composition has good compatibility, excellent barrier properties, mechanical strength, flexibility, drawability, melt stability, scrap recyclability, heat sealability, coatability, stain resistance and transparency.Type: GrantFiled: May 4, 1999Date of Patent: September 25, 2001Assignee: Kuraray Co., Ltd.Inventors: Hiroyuki Shimo, Yasuhiko Haneda, Syuichi Kanao
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Patent number: 6221952Abstract: An aqueous emulsion composition is provided that includes, as the dispersoid, a (co)polymer that contains at least one monomer unit selected from ethylenic unsaturated monomers and dienic monomers, and, as the dispersant, (A) a polyvinyl alcohol (co)polymer, and (B) a condensate of an alkali metal salt of an aromatic sulfonic acid with formaldehyde in a ratio, (A)/(B), of from 100/0.05 to 100/100 in terms of the solid content of the two. The composition is characterized by its fluidity such that the apparent viscosity of the composition is prevented from being lowered relative to the increase in the shear rate of the composition, and that the apparent viscosity of the composition is increased relative to the increase in the shear rate thereof. In addition, the composition has excellent high initial adhesiveness and viscosity-increasing ability.Type: GrantFiled: June 9, 1998Date of Patent: April 24, 2001Assignee: Kuraray Co., Ltd.Inventor: Masato Nakamae