With Ethylenic Reactant Patents (Class 525/59)
  • Publication number: 20030032722
    Abstract: There is provided an acrylic resin film having good matted appearances and good printing characteristics, e.g., little suffering missing prints when printed.
    Type: Application
    Filed: March 14, 2002
    Publication date: February 13, 2003
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Yukio Kitaike, Hideyuki Fujii, Kazuhiko Nakagawa
  • Patent number: 6515078
    Abstract: A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: February 4, 2003
    Assignee: Lord Corporation
    Inventor: Robin F. Righettini
  • Patent number: 6506844
    Abstract: A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: January 14, 2003
    Assignee: Lord Corporation
    Inventor: Robin F. Righettini
  • Patent number: 6500897
    Abstract: The present invention is a hydrolytically modified, biodegradable polymer and a method of making a hydrolytically modifiable a biodegradable polymer. In a preferred embodiment, the invention is a method of grafting polar groups onto biodegradable polymers and modified biodegradable polymer compositions produced by the method. The polymer compositions are useful as components in flushable and degradable articles. Water-sensitive polymer blends and method of making those polymer blends are also disclosed.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: December 31, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, David M. Schertz
  • Patent number: 6495623
    Abstract: A polyvinyl alcohol having at least 1.9 mol % of 1,2-glycol bonds is used as a dispersant for emulsion polymerization or a dispersant for suspension polymerization, and this ensures good polymerization stability even when its amount used is reduced. The aqueous emulsion comprising the polyvinyl alcohol is resistant to water and the viscosity of the aqueous emulsion depends little on ambient temperatures. The vinylic polymers obtained through suspension polymerization in the presence of the polyvinyl alcohol are yellowed little, and the waste water in the suspension polymerization pollutes little the environment.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 17, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Seiji Tanimoto, Naokiyo Inomata, Naoki Fujiwara
  • Publication number: 20020135098
    Abstract: The present invention provides a method for producing an ethylene-vinyl alcohol copolymer resin composition, said method comprising: a) introducing into an extruder an ethylene-vinyl alcohol copolymer resin having a water content of at least 0.5 weight % and an additional component; b) kneading the resin and the additional component whereby to form an ethylene-vinyl alcohol copolymer resin composition; and c) discharging said resin composition from the extruder; wherein said method further comprises feeding water in a liquid state to the extruder and/or removing water in a liquid state from the extruder. Thereby, strand-breakage or cutting errors are suppressed and thus, molded products such as pellets can be provided with a stable shape.
    Type: Application
    Filed: January 22, 2002
    Publication date: September 26, 2002
    Applicant: KURARAY CO. LTD.
    Inventors: Hiroshi Kawai, Masao Hikasa, Takaharu Kawahara, Toshio Tuboi
  • Patent number: 6444757
    Abstract: A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.
    Type: Grant
    Filed: June 11, 1999
    Date of Patent: September 3, 2002
    Assignee: Lord Corporation
    Inventor: Robin F. Righettini
  • Patent number: 6407145
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.
    Type: Grant
    Filed: September 17, 1998
    Date of Patent: June 18, 2002
    Assignee: Novartis AG
    Inventor: Beat Müller
  • Patent number: 6395817
    Abstract: Aqueous based graft emulsion copolymers comprising a polymer having a plurality of hydroxyl groups, preferably a vinyl alcohol homo- or copolymer, grafted with a polyethylene. The graft emulsion copolymer can be prepared by polymerizing ethylene and, optionally another ethylenically unsaturated monomer, in an aqueous solution of a polymer having a plurality of pendent hydroxyl groups, especially poly(vinyl alcohol). The graft emulsion copolymer product can have a polyethylene content ranging from 50 to 95 wt %, hydroxyl-containing polymer ranging from 5 to 50 wt %, and up to 45 wt % of another polymerized ethylenically unsaturated monomer. Polymerization is carried out in an aqueous solution containing at least 5 wt %, preferably 10 wt %, of a hydroxyl-containing polymer having a degree of polymerization of 50 to 2200, preferably 100 to 500.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: May 28, 2002
    Assignee: Air Products Polymers, L.P.
    Inventors: John Joseph Rabasco, William Edward Lenney
  • Patent number: 6368772
    Abstract: Process for functionalizing a water-soluble or water-dispersible polymeric organic binder, in which unmodified, water-soluble or water-dispersible polymeric organic binders are reacted with one or more polar aprotic swelling agents which are compatible with the binder, with thorough mixing with one or more compounds which have groups capable of free radical polymerization, compositions obtainable thereby and radiation-sensitive mixtures which contain, as essential components, the above composition, at least one photopolymerization initiator, if required one or more ethylenically unsaturated, photopolymerizable low molecular weight compounds which are compatible with the polymeric binder and further conventional additives and/or assistants, and radiation-sensitive letterpress or relief printing plates which can be produced therefrom.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: April 9, 2002
    Assignee: BASF Drucksytems GmbH
    Inventors: Thomas Telser, Uwe Stebani, Alfred Leinenbach, Markus Tönnessen
  • Patent number: 6355347
    Abstract: This invention relates, in general, to methods of making blend compositions of an unmodified polyvinyl alcohol and a metallocene polyolefin or grafted metallocene polyolefin and thermoplastic film and fiber structures comprising these blend compositions. More specifically, this invention relates to methods of making substantially water-free films and fibers comprising unmodified polyvinyl alcohol and a metallocene polyolefin or grafted metallocene polyolefin.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: March 12, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: David Michael Schertz, James Hongxue Wang, Gregory J. Wideman, William S. Pomplun
  • Patent number: 6350518
    Abstract: This invention relates, in general, to methods of making blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer and thermoplastic film and fiber structures comprising these blend compositions. More specifically, this invention relates to methods of making substantially water-free films and fibers comprising unmodified polyvinyl alcohol and a thermoplastic elastomer.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: February 26, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: David Michael Schertz, James Hongxue Wang, Gregory J. Wideman, William S. Pomplun
  • Patent number: 6346570
    Abstract: Provided are a water resistant composition comprising a uniform mixture of (A) at least one of modified polyvinyl alcohol containing either from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms, from 0.01 to 1 mol % of silyl groups, or from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms and from 0.01 to 1 mol % of silyl groups and (B) an organotitanium compound having a chelating ligand, in a blend ratio of component (A) to the component (B) between 99.99/0.01 and 60/40 by weight; a coating agent comprising the composition; a thermal recording material having a coat layer of the composition; and an ink-jet recording material having an ink-absorbing layer of the composition.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: February 12, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Somemiya Kazuyuki, Sadahiko Shiraga, Naoki Fujuwara, Atsushi Jikihara, Toshiyuki Akasawa
  • Patent number: 6294609
    Abstract: Particularly useful as a barrier layer in packaging, e.g. multilayer structures, is a composition based on an ethylene-vinyl alcohol copolymer comprising: 50 to 98% by weight of an EVOH copolymer 1 to 50% by weight of a polyethylene (A) 1 to 15% by weight of a polyethylene (B) being a blend of a polyethylene (B1) and a polyethylene (B2) chosen from elastomers, very-low-density polyethylenes and metallocene polyethylenes, the blend of (B1) and (B2) being cografted by an unsaturated carboxylic acid or a functional acid derivative thereof.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: September 25, 2001
    Assignee: Atofina
    Inventors: Denis Bertin, Denis Germain
  • Patent number: 6288165
    Abstract: A process for producing vinyl acetate polymers comprises, after polymerization of at least one monomer comprising vinyl acetate, adding a conjugated polyene having a boiling point of at least 20° C. Saponified products of the vinyl acetate polymers obtained by this process can give molded articles causing little coloring and generation of gel-like agglomerates.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: September 11, 2001
    Assignee: Kuraray Co., Ltd.
    Inventors: Takeshi Moritani, Kaoru Ikeda, Akimasa Aoyama, Takaharu Kawahara, Yukihiro Ohara, Naoshi Nakagawa, Toshinori Tsugaru
  • Publication number: 20010020065
    Abstract: There is a vinyl 4-hydroxybenzal-vinylalcohol-vinyl acetate copolymer, a 4-t-butoxycarbonyloxybenzal-vinyl alcohol-vinyl acetate copolymer and a vinyl 4-t-butoxycarbonyloxybenzal-vinyl 4-hydroxybenzal-vinyl alcohol-vinyl acetate copolymer suitable for photoresist and methods for preparing the same. The latter two polymers contain 4-hydroxybenzal groups all or parts of which are protected with t-butoxycarbonyl group. Superior in transparency, thermal stability, mechanical strength, and adhesiveness to silicon wafer, the photoresists prepared from the protected copolymers can enhance the resolution of fine circuit by virtue of low weight loss upon the thermal treatment after exposure.
    Type: Application
    Filed: March 21, 2001
    Publication date: September 6, 2001
    Applicant: Hyundai Electronics Industries Co., Ltd.
    Inventors: Jin Baek Kim, Hyun Woo Kim
  • Patent number: 6265509
    Abstract: The invention relates to a novel process for the production of mouldings, in particular contact lenses, in which a soluble prepolymer comprising units containing a crosslinkable group and at least one unit containing a modifier is crosslinked in solution, and to mouldings, in particular contact lenses, obtainable by this process. The present invention likewise relates to novel prepolymers which can be employed in the novel process, in particular derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 which comprises from about 0.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: July 24, 2001
    Assignee: Novartis AG
    Inventor: Beat Müller
  • Patent number: 6248498
    Abstract: Disclosed are photoresist compositions comprising a polymeric backbone and a quaternary heterocyclic pendant group, particularly usefull in the preparation of screen printing and sandblast etching photoresists. The pendant groups comprise furanyl substituted quaternary heterocyclic groups, as seen in the formula: where n ranges from 0 to 4 and Z denotes the atoms necessary to complete a substituted or unsubstituted nitrogen containing heterocyclic ring.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: June 19, 2001
    Assignee: The Chromaline Corporation
    Inventor: Alexander S. Gybin
  • Patent number: 6235836
    Abstract: There is a vinyl 4-hydroxybenzal-vinylalcohol-vinyl acetate copolymer, a 4-t-butoxycarbonyloxybenzal-vinyl alcohol-vinyl acetate copolymer and a vinyl 4-t-butoxycarbonyloxybenzal-vinyl 4-hydroxybenzal-vinyl alcohol-vinyl acetate copolymer suitable for photoresist and methods for preparing the same. The latter two polymers contain 4-hydroxybenzal groups all or parts of which are protected with t-butoxycarbonyl group. Superior in transparency, thermal stability, mechanical strength, and adhesiveness to silicon wafer, the photoresists prepared from the protected copolymers can enhance the resolution of fine circuit by virtue of low weight loss upon the thermal treatment after exposure.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: May 22, 2001
    Assignees: Hyundai Electronics Industries Co., Ltd., Korea Advanced Institute of Science and Technology (“KAIST”)
    Inventors: Jin Baek Kim, Hyun Woo Kim
  • Patent number: 6214933
    Abstract: A composition comprises a polyolefin, such as polyethylene, as a major constituent and poly(ethylene oxide) as a minor constituent. The composition exhibits an inverse phase morphology so that the poly(ethylene oxide) forms a continuous phase and the polyolefin forms a dispersed or discontinuous phase in the film. Desirably, the polyolefin and the poly(ethylene oxide) are grafted with a polar, vinyl monomer. The composition can be used in disposable personal hygiene articles.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: April 10, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, David M. Schertz
  • Patent number: 6187397
    Abstract: The film comprises a central layer, composed of a mixture of radical low density polyethylene and of conventional linear polyethylene, sandwiched between two outer layers comprising at least 50% by weight of conventional linear polyethylene, with a relative density of 0.918-0.930, which are devoid of metallocene linear polyethylene, each of the outer layers having a thickness representing 5 to 25% of the total thickness of the film.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: February 13, 2001
    Assignee: Societe de Conditionnement et Industrie Societe Anonyme Ceisa
    Inventor: Michel Grangette
  • Patent number: 6180689
    Abstract: The present invention concerns a fluid loss control agent for a petroleum industry (or analogous) cement slurry, comprising a surfactant and a micro-gel obtained by chemical cross-linking of a polyvinyl alcohol. The micro-gel and the surfactant are advantageously compatible with a wide range of petroleum industry cement additives and can also produce compositions which are gas tight.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: January 30, 2001
    Assignee: Schlumberger Technology Corporation
    Inventor: Eric Moulin
  • Patent number: 6172180
    Abstract: The present invention relates to a block copolymer containing 1-50 first polymer segments and 1-50 second polymer segments. Each first polymer segment has an average mole fraction of monomers possessing a branch point of 0.0001 to 1, whereas each second polymer segment has an average mole fraction of monomers possessing a branch point of 0 to 0.5. The average molecular weights range from 5-2,000 kDa for the first polymer segments, which constitute 5-95% by weight of the block copolymer. The average molecular weights also range from 5-2,000 kDa for the second polymer segments, which constitute 5-95% by weight of the block copolymer. The ratio of the average mole fraction of monomers possessing a branch point of the second polymer segments to that of the first polymer segments is 0 to 0.5. An example of such a copolymer has ethylene oxide or ethylene oxide/propylene oxide as the first polymer segment and polysulfone as the second polymer segment. This block copolymer can further be blended with a bulk polymer.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: January 9, 2001
    Assignee: Circe Biomedical, Inc.
    Inventors: Lawrence F. Hancock, Stephen M. Fagan, Claudy J.-P. Mullon
  • Patent number: 6166117
    Abstract: A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C.sub.1-5 alkyl ester thereof.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: December 26, 2000
    Assignee: Kuraray Co., Ltd.
    Inventor: Hirotoshi Miyazaki
  • Patent number: 6150460
    Abstract: Novel polyfunctional glyoxylated compounds and compositions containing the same are disclosed which are particularly suitable for use as crosslinking components in curable compositions and also find use in imparting wet adhesion properties to water-based paints and coatings. A process for preparing novel polyfunctional glyoxylated compounds is also disclosed.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: November 21, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Balwant Singh, Laurence Wu-Kwang Chang
  • Patent number: 6140018
    Abstract: The invention provides a photosensitive resin and a photosensitive resin composition having excellent water resistance after hardening, excellent developability, and excellent patterning characteristics, and a pattern formation method making use of the composition. The invention provides saponified PVA photosensitive resin which contains structural units represented by formulas (I) and (II): ##STR1## the content of the structural units represented by formulas (I) and (II) in the resin being 0.5-10 mol % with respect to entirety of the structural units of the saponified product of PVA.
    Type: Grant
    Filed: August 5, 1999
    Date of Patent: October 31, 2000
    Assignee: Toyo Gosei Kogyo Co., Ltd.
    Inventors: Noriaki Tochizawa, Mitsuharu Miyazaki, Takaho Ito
  • Patent number: 6051657
    Abstract: There is disclosed a method for preparing a silyl-functional living cationic polymer which can be subsequently coupled to form a moisture-curable telechelic system, said method comprising reacting, in the presence of a Lewis acid,(A) at least one cationically polymerizable monomer with(B) an initiator of the formula ##STR1## wherein R is selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having 6 to 10 carbon atoms, R' is a divalent aliphatic hydrocarbon group having at least 3 carbon atoms, X is halogen, Y is selected from the group consisting of halogen, alkoxy. acyloxy and hydroxyl groups and a is 1, 2 or 3.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: April 18, 2000
    Assignees: Dow Corning Asia, Ltd., University of Massachusetts Lowell
    Inventors: Rudolf Faust, Savvas E. Hadjikyriacou, Toshio Suzuki
  • Patent number: 6028141
    Abstract: Novel polyfunctonal glyoxylated compounds and compositions containing the same are disclosed which are particularly suitable for use as crosslinking components in curable compositions and also find use in imparting wet adhesion properties to water-based paints and coatings. A process for preparing novel polyfunctional glyoxylated compounds is also disclosed.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: February 22, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Balwant Singh, Laurence Wu-Kwang Chang
  • Patent number: 6022913
    Abstract: The present invention provides a container for retort packaging comprising a laminated film having an outermost layer comprising a layer formed of a cross-linked structure containing ester bonds between poly(meth)acrylic acid (A) and polyalcoholic polymer (B); a resin composition having at least the chemical structures (X) [poly(meth)acrylic acid (A) residue], (Y) [poly(meth)acrylic acid (A)-polyalcoholic polymer (B) residue] and (Z) [metal cross-linked ionic residues], wherein the degree of esterification defined by the equation: degree of esterification=c/(b+c+d) is from 0.01 to 0.5 and the degree of ionization defined by the equation: degree of ionization=c/(b+c+d) is from 0.01 to 0.9 (wherein b, c and d represent the molar ratios of the carbon-oxygen double bond in the chemical structure of the resin composition; and a gas barrier film comprising the same.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: February 8, 2000
    Assignee: Kureha Chemical Industry Co. Ltd.
    Inventors: Hideaki Tanaka, Hiroyuki Ohba, Tomoaki Sato, Tomohisa Hasegawa
  • Patent number: 6020436
    Abstract: A universal method to make photosensitive polymers from poly(vinyl alcohol) and poly(vinyl pyridine) is disclosed which generally does not require final purification. These polymers comprise a heterocyclic, light-sensitive pendant group including a moiety having the formula: ##STR1## wherein Z.sup.1 denotes the atoms necessary to form a substituted or unsubstituted aromatic heterocyclic ring; Z.sup.2 denotes the atoms necessary to form a substituted or unsubstituted aromatic or aromatic heterocyclic ring; R is hydrogen or a substituted or unsubstituted alkyl group; M is a divalent organic moiety; Y is a residue from a grafting group that is capable of grafting the pendant group onto a polymeric backbone.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: February 1, 2000
    Assignee: The Chromaline Corporation
    Inventors: Alexander S. Gybin, Lawrence C. Van Iseghem
  • Patent number: 6001903
    Abstract: There is disclosed a synthetic resin powder comprising a polymer made from an ethylenically unsaturated monomer or a diolefinic monomer and a polyvinyl alcohol chemically bonded through a sulfide bond at an end thereof to the surface of a particle of the polymer. Although the synthetic resin powder of the present invention can be in the form of powder during transportation, it can easily be dispersed in water by adding water thereto under stirring, because it is excellent in dispersibility in water and blocking resistance. The synthetic resin powder is excellent also in film forming properties, and thus can preferably be used as an admixture for a mortar, etc.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: December 14, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Masato Nakamae, Toshiaki Sato
  • Patent number: 5994008
    Abstract: The present invention relates to a composition for forming a fluorescent film for a display and a method of forming a fluorescent film for forming a display surface of a display unit. The composition for forming a fluorescent film for a display has an aqueous medium in which photosensitive resin having a styryl pyridium photosensitive group having an internal salt structure and a fluorescent material which easily reacts with acid are dispersed. The composition is applied to the display surface of a display unit so that a fluorescent layer is formed. Then, the fluorescent material layer is developed to form the fluorescent material layer into a predetermined pattern, and then the fluorescent material layer formed into the predetermined pattern is baked so that a fluorescent film is formed.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: November 30, 1999
    Assignee: Futaba Denshi Kogyo K.K.
    Inventors: Yukio Ogawa, Yoshihisa Yonezawa, Katsutoshi Kougo, Kazuyoshi Ishikawa, Shigeo Itoh, Tetsuaki Tochizawa, Yasuo Kuniyoshi, Toru Shibuya, Hideo Kikuchi
  • Patent number: 5985996
    Abstract: This invention relates to a binder containing the units A, B, C, D and E, wherein A is present in an amount of 10 to 60 mole % and is of the formula ##STR1## B is present in an amount of 1 to 30 mole % and is of the formula ##STR2## C is present in an amount of 5 to 60 mole % and is of the formula ##STR3## D is present in an amount of 0 to 60 mole % and is of the formula ##STR4## and E is present in an amount of 1 to 40 mole % and is of the formula ##STR5## wherein X is an aliphatic, aromatic or araliphatic spacer group,R.sup.1 is hydrogen or an aliphatic, aromatic or araliphatic group,R.sup.2, R.sup.3 and R.sup.4 are hydrogen or alkyl groups with carbon numbers of from 1 to 18 andY is a saturated or unsaturated chain- or ring-shaped spacer group, and photosensitive compositions containing this binder.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: November 16, 1999
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Harald Baumann, Udo Dwars, Celin Savariar-Hauck, Hans-Joachim Timpe
  • Patent number: 5939488
    Abstract: The subject invention provides reactive hot melt adhesive compositions comprising polyurethane prepolymers which have an isocyanate index greater than one and which are prepared from a low hydroxyl number composition comprising high molecular weight polyester diols which have a relatively low melting point. These reactive hot melt adhesive compositions have a faster setting speed than conventional reactive hot melt adhesive compositions. The subject invention also provides a method for bonding articles together which uses such reactive hot melt adhesive compositions and articles which comprise the reactive hot melt adhesive compositions.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: August 17, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: James W. Nowicki, Robert S. Wallach
  • Patent number: 5880216
    Abstract: A polyvinyl alcohol is provided containing structural units of the following formula (I) at a molar fraction of 0.05-0.50 and the structural units of the following formula (II) at a molar fraction of 0.0001 to 0.50; ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and X are as desribed herein, and its use in preparation of gels, particularly hydrogels, effective for use in wound dressing materials.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: March 9, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Masao Tanihara, Yoshiharu Fukunishi
  • Patent number: 5849840
    Abstract: A dispersing stabilizer including (A) a polyvinyl alcohol resin containing oxyalkylene groups and having a surface tension of 35 to 55 dyne/cm at 20.degree. C. as a 1% by weight aqueous solution, or said resin and (B) a water-soluble polymer or a polyvinyl alcohol resin having a low degree of hydrolysis and a low degree of polymerization. When using the dispersing stabilizer of the present invention, both of a porosity and a bulk density of a polyvinyl resin particle can be improved at the same time, and, in addition, a distribution of particle size and a uniformity of porosity can be further improved.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: December 15, 1998
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Motokazu Maruhashi, Kizo Ohnishi
  • Patent number: 5849841
    Abstract: The invention relates to a novel process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and to mouldings, in particular contact lenses, obtainable by this process. The present invention likewise relates to novel water-soluble, crosslinkable polymers, in particular those comprising units of formula (III or IIIa), in which R.sub.1 and R.sub.2, independently of one another, are hydrogen, a C.sub.1 -C.sub.8 alkyl group, an aryl group or a cyclohexyl group, where these groups can be monosubstituted or polysubstituted, R.sub.3 is hydrogen or a C.sub.1 -C.sub.4 alkyl group, and R.sub.
    Type: Grant
    Filed: July 30, 1997
    Date of Patent: December 15, 1998
    Assignee: CIBA Vision Corporation
    Inventors: Andreas Muhlebach, Beat Muller
  • Patent number: 5849810
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.5 to approximately 80% of units of formula I ##STR1## wherein R is lower alkylene having up to 8 carbon atoms,R.sup.1 is hydrogen or lower alkyl andR.sup.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: December 15, 1998
    Assignee: CIBA Vision Corporation
    Inventor: Beat Muller
  • Patent number: 5847048
    Abstract: This invention concerns polymers, having fluoroalkoxy side chains, which are made by a novel process comprising reacting a polymer containing hydroxyl groups, especially poly(vinyl alcohol), with a fluorinated olefin in the presence of a base. The resulting polymers are useful in coatings, as in optical wave guides, and antireflective coatings and in other optical devices.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: December 8, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Andrew Edward Feiring
  • Patent number: 5837752
    Abstract: Compositions for bone repair have been developed based on linear hydrophobic degradable polymers and monomers or macromers, at least one of which includes an anhydride linkage. The monomers and/or macromers crosslink each other but not to the linear polymer to form semi-interpenetrating networks. The compositions can include various excipients, therapeutic and/or diagnostic agents. The compositions can be polymerized in the presence of dissolvable particles such as inorganic salts and proteinaceous materials to provide a porous polymer network. The compositions can be injected into a patient and polymerized in situ or can be polymerized ex vivo and implanted. When polymerized ex vivo, the composition can be shaped into various articles, such as pins, screws, and hollow tubes, which can be used to repair broken bones.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: November 17, 1998
    Assignee: Massachusetts Institute of Technology
    Inventors: Venkatram R. Shastri, Robert S. Langer, Peter J. Tarcha
  • Patent number: 5807657
    Abstract: A polyvinyl alcohol base photosensitive resin comprised of a polyvinyl alcohol base polymer compound with the structural units of formulae (I) and (II) ##STR1## as well as a photosensitive resin composition comprising this resin and, optionally, an anionic additive and a method of forming a pattern using this photosensitive composition. R.sup.1 is a residue of a heterocyclic ring with quaternarized aromatic species, R.sup.2 is hydrogen atom or lower alkoxyl group, M is 0 or 1, and n is 1 to 6. X.sup.1, X.sup.2 are hydrogen atom, sodium, potassium or ammonium ion. These resins aid in water solubility, compatibility and sensitivity and are used in forming screen printing plates, black matrix or phosphor pattern formation of color cathode ray tubes, color filters, color printing proofs and etching resists.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: September 15, 1998
    Assignee: Toyo Gosei Kogyo Co., Ltd.
    Inventors: Hideo Kikuchi, Noriaki Tochizawa, Yasuo Kuniyoshi
  • Patent number: 5807927
    Abstract: A process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and mouldings, in particular contact lenses, obtainable by this process; and novel water-soluble, crosslinkable polymers which can be employed in the crosslinking process, in particular those based on polyvinyl alcohol having a molecular weight of at least about 2000 which comprises units of the formulae: XI and XII, XI and XIII or XI, XII and XIII. In said Formulae, U is (a) or --Y--NH--CO--O--Z--O--CH.dbd.CH.sub.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: September 15, 1998
    Assignee: CIBA Vision Corporation
    Inventors: Friedrich Stockinger, Beat Muller
  • Patent number: 5789464
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.5 to approximately 80% of units of formula I ##STR1## wherein R is lower alkylene having up to 8 carbon atoms,R.sup.1 is hydrogen or lower alkyl andR.sup.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: August 4, 1998
    Assignee: CIBA Vision Corporation
    Inventor: Beat Muller
  • Patent number: 5783628
    Abstract: A modified polyvinyl alcohol is disclosed, which comprises the following structural units (I) and (II) and has a weight average molecular weight of from 3,000 to 400,000: ##STR1## wherein R.sup.1 represents H or CH.sub.3 ; and M.sup.1 represents H, an alkali metal, ammonium, alkylammonium, or alkanolammonium. The modified polyvinyl alcohol may be sulfonated. The modified polyvinyl alcohol is used as a dispersant such as a drilling fluid additive.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: July 21, 1998
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Yada, Yoshihiro Kawamori, Hiroshi Nishiguchi, Akira Kitada, Yoshiyuki Mori
  • Patent number: 5760154
    Abstract: The present invention relates to water-soluble, acid groups-containing graft copolymers which are at least partially biodegradable and are based on polyhydroxy compounds and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing said graft copolymers at temperatures of up to 200.degree. C. by means of radical polymerization initiators, in that a total mixture is polymerized which consists of 1-60%-wt. of polyhydroxy compounds, their derivatives or their mixtures, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: June 2, 1998
    Assignee: Stockhausen GmbH & Co., KG
    Inventors: Frank Krause, Helmut Klimmek
  • Patent number: 5705553
    Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Rolf Kuropka
  • Patent number: 5674946
    Abstract: The invention relates to activated support materials which comprise epoxy-substituted poly(meth)acrylamides, characterized in that:a) the base support contains aliphatic hydroxyl groups,b) the covalently bonded polymers are bonded to the support via a terminal monomer unit,c) the polymers contain monomer units of the formula I,d) the monomer units are linearly linked, ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are H or CH.sub.3,R.sup.4 is H or alkyl having 1-5 carbon atomsandn is an integer between 1 and 5 and to the use thereof.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: October 7, 1997
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Egbert Muller
  • Patent number: 5652305
    Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids and processed into sheet, film, fiber and other objects which exhibit an useful balance of barrier and strength properties.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: July 29, 1997
    Assignee: Rohm and Haas Company
    Inventors: Robert Mark Amici, Edward Ewart LaFleur, William James Work
  • Patent number: 5637637
    Abstract: This invention relates to waterborne copolymeric colorant compositions having a dye covalently bonded in the polymer backbone which is prepared by emulsion polymerization of an alkaline solution of a reactive dye and a vinyl monomer. The waterborne copolymeric colorant compositions are useful in formulating waterborne coatings, paints, inks, and primers in various household, personal care and cosmetic applications.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: June 10, 1997
    Assignee: Eastman Chemical Company
    Inventors: Mahendra K. Sharma, Imelda L. Watson
  • Patent number: 5583163
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is cross-linked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.5 to approximately 80% of units of formula I ##STR1## wherein R is lower alkylene having up to 8 carbon atoms,R.sup.1 is hydrogen or lower alkyl andR.sup.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 10, 1996
    Assignee: Ciba Geigy Corporation
    Inventor: Beat Muller