Solid Graft Or Graft-type Copolymer Derived From Ethylenic Reactants Only Patents (Class 525/64)
  • Patent number: 8816008
    Abstract: The invention relates to an impact modified thermoplastic resin comprising a polymeric impact modifier with a core-shell structure comprising 2-octylacrylate.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: August 26, 2014
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Stephane Girois, Pascale Dargelos, Magali Bergeret-Richaud
  • Publication number: 20140235791
    Abstract: Films (or a cap layer of co-extruded films) and methods of forming the same are described herein. The films generally include a modified olefin based polymer including polypropylene and from 1 wt. % to 30 wt. % polylactic acid (PLA), wherein the modified olefin based polymer exhibits a seal initiation temperature (SIT) that is at least 5° C. less than a seal initiation temperature of the polypropylene absent the PLA and a hot tack range of at least 20° C.
    Type: Application
    Filed: March 20, 2014
    Publication date: August 21, 2014
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Fengkui Li, John Ashbaugh
  • Patent number: 8809455
    Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
    Type: Grant
    Filed: August 27, 2009
    Date of Patent: August 19, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Anthony Jay Dias, Rodney May
  • Publication number: 20140228517
    Abstract: A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.
    Type: Application
    Filed: April 15, 2014
    Publication date: August 14, 2014
    Applicant: FINA TECHNOLOGY INC.
    Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
  • Publication number: 20140227516
    Abstract: A carbon fiber sizing agent imparts good bonding performance to carbon fiber, is used to reinforce a thermoplastic matrix resin, and provides a carbon fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the carbon fiber strand. The sizing agent for carbon fiber is used to reinforce thermoplastic matrix resin. The sizing agent essentially contains a polymer component having a glass transition temperature of at least 20 deg.C. and exhibits no endothermic peaks indicating an endothermic heat of fusion due to crystalline melting of at least 3 J/g in a determination with a DSC. The weight ratio of the polymer component is 10 to 100 wt % of the nonvolatile components of the sizing agent. The polymer component is at least one component selected from the group consisting of an aromatic polyester resin, aromatic polyester-polyurethane resin and amine-modified aromatic epoxy resin.
    Type: Application
    Filed: October 15, 2012
    Publication date: August 14, 2014
    Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
  • Publication number: 20140228518
    Abstract: Methods for obtaining toughened products from unsorted post-consumer plastics is disclosed. A toughened plastic composition is further disclosed, which includes a first thermoplastic polymer, a different second thermoplastic polymer, and a maleic anhydride-grafted ethylene/propylene rubber compatibilizer.
    Type: Application
    Filed: April 16, 2014
    Publication date: August 14, 2014
    Applicant: King Abdulaziz City for Science and Technology
    Inventors: Fares D. Alsewailem, Abdulmajeed M. Algaflah, Yazeed A. Binkheder
  • Patent number: 8802751
    Abstract: The invention relates to impact-modified polymer compositions, containing a polymer blend of polycarbonate with polyester and/or polyamide, plus an impact modifier blend of core/shell and functional polyolefin impact modifiers. The impact modifiers can provide the polymer blend composition with improved impact strength at equivalent loading, and also allow for higher amounts of polyester and/or polyamide in the blend without sacrificing impact strength.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: August 12, 2014
    Assignee: Arkema Inc.
    Inventors: Jason M. Lyons, Stephane Girois
  • Patent number: 8779050
    Abstract: The present invention relates to non-aging, impact-modified polycarbonate compositions and molding compositions comprising: A) from 60 to 86 parts by weight (based on the sum of components A+B+C) of aromatic polycarbonate and/or aromatic polyester carbonate, B) from 4 to 12 parts by weight (based on the sum of components A+B+C) of graft polymer comprising: B.1 from 10 to 50 wt. % (based on the graft polymer B) of a shell of at least one vinyl monomer, and B.2 from 90 to 50 wt. % (based on the graft polymer B) of a graft base of silicone-acrylate composite rubber, C) from 10 to 30 parts by weight (based on the sum of components A+B+C) of a polymer or copolymer based on vinyl monomer, and D) from 0 to 20 parts by weight of polymer additives.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: July 15, 2014
    Assignee: Bayer Materialscience AG
    Inventors: Achim Feldermann, Andreas Seidel, Eckhard Wenz
  • Patent number: 8759431
    Abstract: A durable polyoxymethylene composition includes a polyoxymethylene copolymer with 1,3-dioxolane as a comonomer, a lubricant, an inorganic filler, a nucleating agent including a sodium salt, a stabilizer, an anti-static agent. A ramp is made of the durable polyoxymethylene. The ramp and the durable polyoxymethylene have excellent micro-wear-resistant property.
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: June 24, 2014
    Assignee: Min Aik Technology Co., Ltd.
    Inventors: Jung-Pao Chang, Chi-En Lin
  • Patent number: 8753728
    Abstract: The properties of melt blends of specific aliphatic-aromatic copolyesters and starch are improved by addition of a combination of polylactic acid, graft copolymers such maleic anhydride grafted polyethylene and maleic anhydride grafted polystyrene, and a hindered phenolic antioxidant. The blends exhibit increased melt strength and maximum draw down ratio versus blends of only aliphatic-aromatic copolyesters and starch. Films made from the blend are compostable and exhibit an attractive combination of mechanical and rheological properties for packaging materials.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: June 17, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Rameshchandra M Gohil
  • Publication number: 20140161858
    Abstract: Thermoplastic elastomer compositions are described comprising multigraft copolymers. The multigraft copolymers can comprise a rubbery polymeric backbone and a plurality of glassy polymeric side chains, each attached at one of a plurality of branch points randomly spaced along the backbone. The copolymer materials have high tensile strength, high strain at break, and low residual strain after elongation. The compositions can be used as adhesives and in a wide variety of high tech, medical, and commodity applications.
    Type: Application
    Filed: September 30, 2011
    Publication date: June 12, 2014
    Applicant: University of Tennessee Research Foundation
    Inventors: Jimmy W Mays, Liane Weidisch, Samuel P Gido, Christina Weidisch
  • Publication number: 20140155537
    Abstract: Disclosed herein is a curable composition comprising ethylene copolymer elastomer, a relatively small amount of a polyamide, and optionally a compatibilizer wherein curable composition demonstrates improved heat aging properties without the loss of tensile strength. Also disclosed is the process for making such curable ethylene copolymer elastomer.
    Type: Application
    Filed: November 20, 2013
    Publication date: June 5, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Steven R. Oriani
  • Patent number: 8742014
    Abstract: An object of the invention is to provide a liquid resin composition with low viscosity while containing polymer particles. Further, another object of the invention is to provide a liquid resin composition containing a large quantity of polymer particles without increasing the viscosity of the liquid resin composition. A liquid resin composition of the invention is comprising a liquid resin component and polymer particles each having an elastic core layer, an intermediate layer formed with a monomer having two or more double bonds and coated on the core layer, and a shell layer coated on the intermediate layer; wherein the polymer particles are dispersed at a ratio of their volume average particle diameter (Mv) to their number average particle diameter (Mn) of 3 or lower.
    Type: Grant
    Filed: September 9, 2008
    Date of Patent: June 3, 2014
    Assignee: Kaneka Corporation
    Inventor: Shinya Hongo
  • Publication number: 20140147660
    Abstract: Provided is a thermoplastic resin composition having excellent weather resistance, impact resistance, and fluidity and also excellent color developing properties and residence heat stability. A graft copolymer (A) prepared by graft polymerization of a certain amount of a specific monomer (a2) onto a certain amount of composite rubber (a1) composed of a conjugated diene rubber polymer and a cross-linked acrylic ester polymer. The tetrahydrofuran-soluble portion of the composite rubber (a1) has a weight-average molecular weight of 50000 or more in terms of polystyrene and a degree of swelling in toluene of 7.0 or more, or in the composite rubber contained in the graft copolymer, the number of particles having an equivalent-circle diameter of 150 nm or less is 50% or less of the total number of the composite rubber particles.
    Type: Application
    Filed: July 11, 2012
    Publication date: May 29, 2014
    Applicant: NIPPON A&L INC.
    Inventors: Takumi Miyahiro, Masanori Ito, Seiji Tamai, Fumitoshi Takeda, Kazunori Takahashi, Tomoyoshi Akiyama, Hajime Tomita, Haruki Okuno, Shunsaku Kubota, Masaaki Okada, Atsushi Hashimoto, Yoshiaki Takada, Nobuyuki Nakashima, Jiichiro Yoshida, Takayoshi Fujiwara, Shouta Kosaka
  • Publication number: 20140141189
    Abstract: Injection stretch blow molded (ISBM) articles containing a bio-based polymers and methods of forming the same are described herein. The method generally includes providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid to form a polymeric blend; injection molding the blend into a preform; and stretch-blowing the preform into an article.
    Type: Application
    Filed: November 22, 2013
    Publication date: May 22, 2014
    Applicant: FINA TECHNOLOGY, Inc.
    Inventors: Fengkui Li, Luyi Sun, John Ashbaugh, David Rauscher, Leland Daniels, Robert Dotter
  • Patent number: 8716382
    Abstract: Disclosed are a thermoplastic polyester elastomer resin composition and a molded article comprising the same. More specifically, disclosed is a thermoplastic polyester elastomer resin composition which comprises a glycidyl group-modified ethylene-octene based copolymer resin, as a chain extension/hydrolysis resistance agent for blow and extrusion molding to improve melt viscosity, and increases a molecular weight through reaction extrusion and thus exhibits superior heat resistance, weather resistance, heat aging resistance, hydrolysis resistance, fatigue resistance properties, melt viscosity and parison stability, and in particular, exhibits superior blow molding, contains no gel, reduces production of odor-causing substances such as volatile organic compounds (TVOC) during blow molding, and maintains a balance between physical properties, moldability and operation environments.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: May 6, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Sang Wook Na, Ho Dong Kim, Mi Ah Lee, Gi Dae Choi, Ji Seon Kim
  • Publication number: 20140110880
    Abstract: A thermoplastic elastomer compound is disclosed having a high strain recovery rate and a high strain fixity rate to provide shape memory, preferably manageable shape memory. One type of thermoplastic elastomer compound is comprises a maleated styrenic block copolymer and polycaprolactone to achieve the shape memory. A second type of thermoplastic elastomer compound comprises styrene-ethylene/butylene-styrene and a paraffin wax having less than about 0.5% oil content. Shape modes of articles made from the thermoplastic elastomer compound can be altered by at least one thermo-mechanical event to cause deformation of the compound from a first shape to a second shape with retention of the compound in the second shape for any reasonable time interval.
    Type: Application
    Filed: May 30, 2012
    Publication date: April 24, 2014
    Applicant: POLYONE CORPORATION
    Inventor: Liang Xu
  • Patent number: 8703869
    Abstract: The invention relates to impact-modified polycarbonate compositions which are distinguished by high heat resistance and good melt flow behavior. In addition, the moldings produced from the compositions according to the invention in an injection-molding process can be metallised, the resulting metallised moldings having a surface with a particularly high and, in particular, homogeneous gloss. The invention thus also provides the metallised moldings produced from the compositions according to the invention.
    Type: Grant
    Filed: March 23, 2010
    Date of Patent: April 22, 2014
    Assignee: Bayer Materialscience AG
    Inventors: Andreas Seidel, Eckhard Wenz, Hans-Jü{umlaut over ( )}rgen Klankers
  • Publication number: 20140066565
    Abstract: The provided is a polypropylene/polylactic acid resin composition comprising a polypropylene resin, a polylactic acid resin, a reactive compatibilizer, optionally an impact modifier and an inorganic filler, having excellent heat resistance, impact resistance and flexural modulus.
    Type: Application
    Filed: September 3, 2013
    Publication date: March 6, 2014
    Applicant: Samsung Total Petrochemicals Co., Ltd.
    Inventors: Jin Seong JEONG, Do Hoon LEE, Young Joo LEE
  • Patent number: 8664334
    Abstract: A resin composition is described that is excellent in strength, impact resistance, heat resistance and moldability, while further allowing for a reduction in the amount of CO2 needed for its production. The resin composition includes a styrene-based resin (A), an aliphatic polyester (B) and at least one species selected from a compatibilizer (C) and a dicarboxylic anhydride (D), wherein the compatibilizer is preferably at least one species selected from: (C-1) a methyl methacrylate polymer; (C-2) a vinyl-based polymer to which an epoxy unit or acid anhydride unit is copolymerized; (C-3) a graft polymer in which a methyl methacrylate unit is grafted to a rubbery polymer; and (C-4) a block copolymer having a polylactide segment and a vinyl-based polymer segment.
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: March 4, 2014
    Assignee: Toray Industries, Inc.
    Inventors: Sadanori Kumazawa, Akiyoshi Tamai, Hiroyuki Ohme, Sadayuki Kobayashi
  • Publication number: 20140058019
    Abstract: Disclosed are a thermoplastic polyester elastomer resin composition and a molded article comprising the same.
    Type: Application
    Filed: April 2, 2013
    Publication date: February 27, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Sang Wook Na, Ho Dong Kim, Mi Ah Lee, Gi Dae Choi, Ji Seon Kim
  • Patent number: 8653188
    Abstract: The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load. The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: February 18, 2014
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Tatsuya Toneri, Masaaki Mawatari
  • Patent number: 8642701
    Abstract: Injection stretch blow molded (ISBM) articles containing a bio-based polymers and methods of forming the same are described herein. The method generally includes providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid to form a polymeric blend; injection molding the blend into a preform; and stretch-blowing the preform into an article.
    Type: Grant
    Filed: February 8, 2011
    Date of Patent: February 4, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Luyi Sun, John Ashbaugh, David Rauscher, Leland Daniels, Robert Dotter
  • Patent number: 8642700
    Abstract: A thermoplastic composition suitable for making articles having low gloss and good impact resistance at low temperatures is disclosed. The composition contains (A) 10 to 90 percent relative to the weight of the composition (pbw) of an aromatic (co)poly(ester)carbonate, (B) 10 to 90 pbw of first graft (co)polymer containing a graft base selected from the group consisting of polyurethane, ethylene vinyl acetate, silicone, ethylene-propylene diene rubbers, ethylene propylene rubbers, acrylate rubbers, diene rubbers, and polychloroprene, and a grafted phase, (C) 1 to 20 pbw of a linear glycidyl ester functional polymer comprising repeating units derived from one or more glycidyl ester monomers and (D) 1 to 20 pbw of a second graft (co)polymer containing a core and shell wherein the core contains an interpenetrated network of poly(meth)alkyl acrylate and polyorganosiloxane, and wherein the shell contains poly(meth)acrylate.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: February 4, 2014
    Assignee: Bayer MaterialScience LLC
    Inventors: Marina Rogunova, James P. Mason, Xiangyang Li
  • Patent number: 8637130
    Abstract: A molded part that is formed from a thermoplastic composition that contains a polylactic acid, propylene/?-olefin copolymer, and a polyolefin compatibilizer is provided. The propylene/?-olefin copolymer can be dispersed as discrete physical domains within a continuous matrix of the polylactic acid. Without intending to be limited by theory, it is believed that the discrete domains can help resist the expansion of the composition during a molding operation, which minimizes the degree of expansion experienced by the composition during molding in comparison to conventional polylactic acid compositions.
    Type: Grant
    Filed: February 10, 2012
    Date of Patent: January 28, 2014
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, Gregory J. Wideman
  • Publication number: 20130317173
    Abstract: Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article.
    Type: Application
    Filed: August 1, 2013
    Publication date: November 28, 2013
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Fengkui Li, John Ashbaugh, Gabriel Desille, Caroline Schils
  • Patent number: 8580890
    Abstract: The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.
    Type: Grant
    Filed: July 2, 2009
    Date of Patent: November 12, 2013
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Rita De Luca, Philippe Hoslet
  • Publication number: 20130281603
    Abstract: A thermoplastic resin composition comprises: (A) a graft copolymer resin comprising a core comprising a rubber polymer; and a shell formed by graft polymerization of acrylic acid alkyl ester monomer and/or methacrylic acid alkyl ester monomer, unsaturated nitrile monomer, and aromatic vinyl monomer on the surface of the core; (B) a non-graft copolymer resin comprising a copolymer which is formed by polymerizing acrylic acid alkyl ester monomer and/or methacrylic acid alkyl ester monomer, aromatic vinyl monomer, and unsaturated nitrile monomer; and a (co)polymer which is formed by polymerizing acrylic acid alkyl ester monomer, methacrylic acid alkyl ester monomer or a combination thereof; and (C) a siloxane impact reinforcing agent. The composition can have excellent impact strength and scratch resistance, and exhibits reduced or no cloudy white phenomenon at a low temperature.
    Type: Application
    Filed: June 24, 2013
    Publication date: October 24, 2013
    Inventors: Sung Hun Jin, Chang Do Jung, Bang Duk Kim, Jun Hong Park
  • Patent number: 8524832
    Abstract: The invention relates to a impact-modified bio-degradable polymer composition having large particle size impact modifiers dispersed in a continuous biodegradable polymer phase. The impact modifiers have a core-shell morphology and have average sizes of greater than 250 nm. The impact-modified composition has good impact properties and low haze. The biodegradable polymer is preferably a polylactide or polyhydroxy butyrate. The composition comprises 30-99.9 weight percent of degradable polymer and 0.1 to 15 weight percent of one or more impact modifiers.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: September 3, 2013
    Assignee: Arkema Inc.
    Inventor: Zuzanna Cygan
  • Patent number: 8519052
    Abstract: The present invention provides a resin composition for coating which is capable of exhibiting an excellent balance between coatability, impact resistance, moldability and chemical resistance, and capable of attaining a good coating appearance, for example, even when a large-size molded product is coated. The resin composition for coating according to the present invention comprises 84.9 to 98.9 parts by mass of the below-mentioned rubber-reinforced vinyl-based resin [A], 1 to 8 parts by mass of a polyester resin [B] and 0.1 to 7.
    Type: Grant
    Filed: April 4, 2011
    Date of Patent: August 27, 2013
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Kazuhiro Okamoto, Kazuya Egawa
  • Patent number: 8466233
    Abstract: A polylactic acid-based resin composition including a polylactic acid (A), a multilayered polymer (B) and a multilayered polymer (C), wherein the content of each of the multilayered polymer (B) and the multilayered polymer (C) is 0.5 to 8% by mass of the whole resin composition; the multilayered polymer (B) and the multilayered polymer (C) are each constituted of a core layer(s) and a shell layer(s); the core layer constituting the multilayered polymer (B) contains an acrylic rubber; and the core layer constituting the multilayered polymer (C) contains a composite rubber containing an acrylic component and a silicone component.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: June 18, 2013
    Assignee: Unitika Ltd.
    Inventors: Keisuke Kimura, Kazue Ueda
  • Patent number: 8466214
    Abstract: Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: June 18, 2013
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Philippe Hajji
  • Patent number: 8461261
    Abstract: Provided is a resin composition containing a resin component prepared by blending a graft copolymer with an engineering plastic, wherein the above graft copolymer is a graft copolymer satisfying (a) to (e) shown below: (a) a graft rate is 1 to 150% by mass, (b) a weight average molecular weight measured by GPC is 500 to 400000, (c) a molecular weight distribution (Mw/Mn) is 1.5 to 4, (d) a main chain is a polymerization chain containing 1 to 100% by mass of a monomer unit having a functional group interacting with the engineering plastic and (e) a side chain is a homopolymerization chain of a single kind selected from ?-olefins having 3 to 28 carbon atoms or a copolymerization chain of two or more kinds selected therefrom or a copolymerization chain comprising an ?-olefin unit having 3 to 28 carbon atoms and an ethylene unit which accounts for 50% by mass or less, and a mesopentad ratio [mmmm] of the polymerization chain is 30 to 80 mole %.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: June 11, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Manabu Nomura, Susumu Kanno, Ryo Aburatani, Shuji Machida
  • Patent number: 8461271
    Abstract: Provided is a production process for a graft copolymer or a thermoplastic resin composition containing the above graft copolymer, which comprises graft-polymerizing 100 parts by mass of a combination of 20 to 100% by mass of a reactive polyolefin and 0 to 80% by mass of a polyolefin other than the reactive polyolefin with 0.2 to 300 parts by mass of at least one specific monomer under the presence of a radical initiator and which is useful as a sealant, a modifier for polyolefins, a surface treating agent, a primer treating agent, a coating agent component and the like.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: June 11, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Ryo Aburatani, Takenori Fujimura, Harumi Nakashima
  • Patent number: 8461260
    Abstract: Impact-modified polycarbonate compositions are disclosed that comprise a first graft polymer based on silicone-acrylate composite rubber as graft base, wherein the amount of silicone rubber is from 65 to 95 wt. % (based on the graft base), and a second graft polymer containing free copolymer, that is to say copolymer that is not chemically bonded to the rubber, and having a weight-average molecular weight of from 60,000 to 150,000 g/mol. The use of the polycarbonate compositions in the production of molded articles, and to the molded articles themselves are also disclosed. The compositions and molding compositions have an optimum combination of good elongation at tear, good hydrolytic stability and low melt viscosity.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: June 11, 2013
    Assignee: Bayer Intellectual Proeprty GmbH
    Inventors: Achim Feldermann, Eckhard Wenz, Andreas Seidel, Evgueni Avtomonov
  • Patent number: 8461262
    Abstract: A biodegradable fiber that is formed from a thermoplastic composition that contains polylactic acid, a plasticizer, and a compatibilizer is provided. The compatibilizer includes a polymer that is modified with a polar compound that is compatible with the plasticizer and a non-polar component provided by the polymer backbone that is compatible with polylactic acid. Such functionalized polymers may thus stabilize each of the polymer phases and reduce plasticizer migration. By reducing the plasticizer migration, the composition may remain ductile and soft. Further, addition of the functionalized polymer may also promote improved bonding and initiate crystallization faster than conventional polylactic acid fibers. The polar compound includes an organic acid, an anhydride of an organic acid, an amide of an organic acid, or a combination thereof. Such compounds are believed to be more compatible with the generally acidic nature of the polylactic acid fibers.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: June 11, 2013
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ryan J. McEneany, Vasily A. Topolkaraev, Aimin He
  • Patent number: 8445581
    Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: May 21, 2013
    Assignee: Polynovo Biomaterials Pty Limited
    Inventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
  • Publication number: 20130122262
    Abstract: A carbon fiber bundle includes carbon fibers and a copolymerized polyolefin attached to the surface of the carbon fibers. The copolymerized polyolefin contains an aromatic vinyl compound and an acid and/or acid anhydride as copolymerization components. The amount of the copolymerized polyolefin attached is 0.01 to 10 parts by mass per 100 parts by mass of the carbon fiber bundle. The carbon fiber bundle may be used or contained in a random mat, a composite material, and various molded articles.
    Type: Application
    Filed: January 9, 2013
    Publication date: May 16, 2013
    Applicant: TEIJIN LIMITED
    Inventor: TEIJIN LIMITED
  • Patent number: 8415428
    Abstract: The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: April 9, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Daisuke Shimizu, Yasuhiro Kusanose, Yoshifumi Araki, Masahiro Fujiwara
  • Patent number: 8404354
    Abstract: The invention discloses water-based paint compositions which comprise a copolymer of polymerizable unsaturated monomer having polyoxyalkylene chain; hydroxyl-containing polymerizable unsaturated monomer having no polyoxyalkylene chain; polymerizable unsaturated monomer having at least one cationic functional group selected from the group consisting of tertiary amino groups and quaternary ammonium salt groups; at least one monomer selected from the group consisting of bridged alicyclic hydrocarbon group-containing polymerizable unsaturated monomers and C6-18 alkyl group-containing polymerizable unsaturated monomers; and other polymerizable unsaturated monomer: a hydroxyl-containing resin: and a melamine resin having a weight-average molecular weight within the range of 1,000-5,000. The invention also discloses film-forming methods using the compositions.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: March 26, 2013
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yoshiyuki Yukawa, Takashi Tanaka
  • Patent number: 8399101
    Abstract: Disclosed is a toughened poly(hydroxyalkanoic acid) resin composition comprising poly(hydroxyalkanoic acid) and an impact modifier comprising a core/shell polymer that does not comprise a vinyl aromatic comonomer, having a refractive index not greater than 1.5; wherein the core comprises elastomer and the shell comprises non-elastomeric polymer. Also disclosed are packaging materials and packaged products comprising the composition.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Benjamin Andrew Smillie, Julius Uradnisheck
  • Patent number: 8383726
    Abstract: Disclosed is a thermoplastic resin composition having excellent impact resistance at a low temperature, while maintaining high transparency; this thermoplastic resin composition is obtained by compounding an impact resistance improver into a thermoplastic resin, the impact resistance improver being composed of a graft copolymer which is obtained by polymerizing a vinyl monomer component in the presence of a polymer mixture containing a polymer having butadiene units as an essential component and a polymer having styrene units as an essential component, the polymer mixture containing 45 to 65% by mass of the butadiene units and 35 to 55% by mass of the styrene units.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: February 26, 2013
    Assignees: Mitsubishi Rayon Co., Ltd., Cheil Industries Inc.
    Inventors: Osamu Okunaka, Hiroyuki Nishii, Takashi Shouji, Keiji Nakamura, Tae Uk Kim, Byung Choon Lee
  • Patent number: 8378023
    Abstract: The present invention provides a polyketone composition having about 40˜90 wt % of polyketone, about 5˜40 wt % of polyamide, and about 5˜20 wt % of modified rubber. The composition of the present invention greatly improves the impact resistance of polyketone, which has increased heat resistance, chemical resistance, fuel permeation resistance, abrasion resistance or the like, and thus may be widely applied in various industrial fields, such as automotive parts including wheel covers, wheel caps, fuel filler necks, fuel tanks, fuel tubes, center fascias, door handles, roof rack covers, gear, junction boxes, connectors, seat backs or the like, electric/electronic parts, and household items, thereby providing durability of the parts and price competition.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: February 19, 2013
    Assignees: Hyundai Motor Company, Desco Co., Ltd., Hyosung Corporation
    Inventors: Choon Soo Lee, Min Hee Lee, Bong Hyun Park, Seong Hoon Lee, Jong Hwal Kim, Sung Kyoun Yoon, Byoung Gook Kang
  • Publication number: 20130041084
    Abstract: Disclosed is a curable silicone composition for preparing release layers and pressure sensitive adhesives, and to substrates bearing a layer of the cured composition. More specifically, this invention relates to a silicone composition, curable in the absence of both catalysts and actinic radiation comprising a cyclic anhydride copolymer and an amine-terminated polysiloxane.
    Type: Application
    Filed: August 8, 2011
    Publication date: February 14, 2013
    Inventors: Joon Chatterjee, Timothy D. Filiatrault, Hae-Seung Lee, David S. Hays, Naimul Karim, Babu N. Gaddam
  • Patent number: 8367773
    Abstract: A process is described for obtaining a chemical blend of a polyolefin with a poly(hydroxy carboxylic acid) by mixing poly(hydroxy carboxylic acid) with at least one polyolefin in the presence of a compatibilising compound having at least one polymerisable double bond and at least one electrophilic functional group. The invention also relates to the chemical blend obtainable according to this process, as well as the use of the compatibilising compound to obtain chemical blends of polyolefin with poly(hydroxy carboxylic acid).
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: February 5, 2013
    Assignee: Total Petrochemicals Research Feluy
    Inventor: Thierry Coupin
  • Patent number: 8362145
    Abstract: A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: January 29, 2013
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
  • Publication number: 20130005893
    Abstract: The present invention relates to a polyolefin composition for an interior sheet/film. The polyolefin composition of the present invention for an interior sheet comprises 70 to 99 wt % of polyolefin and 1 to 30 wt % of modified polyethylene terephthalate having a melting point of 130 to 180° C. The polyolefin composition of the present invention is environmentally friendly and has good physical properties such as workability, printing characteristics, and adhesiveness. In addition, sheets having various thicknesses can be produced by extrusion without having to stretch the sheets, and thus the sheets can be used separately or in combination in various application fields.
    Type: Application
    Filed: February 12, 2010
    Publication date: January 3, 2013
    Applicant: SK Global Chemical Co., Ltd.
    Inventors: Sang Min Kwon, Seok Kim, Tae Keun Lee, Woon Ki Chung
  • Publication number: 20120328866
    Abstract: The present invention provides a resin composition which comprises: (A) a saponifed ethylene-vinyl ester copolymer; (B) a rubber-like graft polymer; and (C) a polyalkylene ether unit-containing polymer. The inventive resin composition, which employs the saponfied ethylene-vinyl ester copolymer, is excellent in impact resistance.
    Type: Application
    Filed: March 10, 2011
    Publication date: December 27, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Noriyoshi Inoue, Hideshi Onishi
  • Patent number: 8338533
    Abstract: The present invention relates to non-aging, impact-modified polycarbonate compositions and molding compositions comprising: A) from 60 to 86 parts by weight (based on the sum of components A+B+C) of aromatic polycarbonate and/or aromatic polyester carbonate, B) from 4 to 12 parts by weight (based on the sum of components A+B+C) of graft polymer comprising: B.1 from 10 to 50 wt. % (based on the graft polymer B) of a shell of at least one vinyl monomer, and B.2 from 90 to 50 wt. % (based on the graft polymer B) of a graft base of silicone-acrylate composite rubber, C) from 10 to 30 parts by weight (based on the sum of components A+B+C) of a polymer or copolymer based on vinyl monomer, and D) from 0 to 20 parts by weight of polymer additives. Components B and C are present in a ratio of the parts by weight of B:C in the range from 1:1.3 to 1:3.5.
    Type: Grant
    Filed: June 15, 2009
    Date of Patent: December 25, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Achim Feldermann, Andreas Seidel, Eckhard Wenz
  • Patent number: 8318851
    Abstract: Disclosed are compositions comprising: (i) 5-45 wt. % of an acrylonitrile-styrene-acrylate (ASA) graft copolymer or acrylate-modified ASA, (ii) 2-82 wt. % of at least one polyestercarbonate which is a block polyestercarbonate comprising organic carbonate blocks alternating with arylate blocks, said arylate blocks comprising ester structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid, and having a degree of polymerization of at least about 4; and (iii) 5-60 wt. % of at least one rigid thermoplastic polymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate, or mixtures thereof, wherein wt.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: November 27, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Franciscus Maria Huijs, Robert Dirk van de Grampel, Ronald Akkermans