Mixture Contains Solid Polymer Derived From Reactant Containing Nitrogen Heterocycle Patents (Class 525/73)
  • Patent number: 6586097
    Abstract: These crosslinked microparticles between 10-300 nm in size are obtained by dispersion polymerization, in non-aqueous medium which is non-solvent for the polymer formed, of a composition of ethylenically unsaturated polymerizable compounds, comprising: at least one monomer A, comprising only one ethylenic unsaturation, giving the microparticles formed in the said non-aqueous medium self-stabilization during and after polymerization, without any addition of polymer having the function of a stabilizing agent, tither before, during or after polymerization, at least one compound B comprising at least two ethylenic unsaturations and optionally, depending on the case: at least one compound C comprising only one ethylenic unsaturation and/or at least one compound D which is different from A, B and C and comprising at least one ethylenic unsaturation which can undergo radical-mediated polymerization and at least one second reactive function f1 which is other than an ethylenic unsaturation.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: July 1, 2003
    Assignee: Cray Valley, S.A.
    Inventors: Jean-Pierre Pascault, Ludovic Valette, Benoit Magny
  • Publication number: 20020188064
    Abstract: The present invention is directed to a polymeric composition including a poly(alkenyl-co-maleimide) and an inorganic salt. Optionally, an extender is included. The composition exhibits good strength and vibration damping properties.
    Type: Application
    Filed: May 22, 2001
    Publication date: December 12, 2002
    Applicant: Bridgestone/Firestone Research, Inc.
    Inventors: Xiaorong Wang, Victor J. Foltz
  • Patent number: 6475475
    Abstract: Combinations of polymer compounds and hair treatment compositions containing them are described, which have improved film-forming properties and improved hair-fixing properties, particularly increased elasticity of the polymer film or the treated hair. The polymer compound combinations include at least one terpolymer of vinyl pyrrolidone, vinyl caprolactam and basic acryl amide monomer and at least one anionic or anionizable polymer with anionic or anionizable groups.
    Type: Grant
    Filed: December 4, 2000
    Date of Patent: November 5, 2002
    Assignee: Wella Aktiengesellschaft
    Inventors: Susanne Birkel, Michael Lede
  • Patent number: 6455634
    Abstract: The present invention relates to a blend of at least one (meth)acrylate polymer and at least one amorphous propylene-derived polymer, and an optional tackifier that provide pressure sensitive adhesive compositions in which improved peel adhesion to at least one of low and relatively high surface energy substrates can be achieved.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: September 24, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Ashish K. Khandpur, Eugene G. Joseph, Greggory S. Bennett
  • Patent number: 6448343
    Abstract: The formation of thermoplastic vulcanates may be accomplished with two polymers, wherein one polymer is grafted, or copolymerized with a carboxylic acid anhydride, which acid anhydride grafted polymer then is reacted with an amino silane, which reacts with the acid anhydride and then cross links.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: September 10, 2002
    Assignee: Crompton Corporation
    Inventors: Jacques F. Schombourg, Peter Kraxner, Willy Furrer, Abdellatif Adberrazig
  • Publication number: 20020122947
    Abstract: Coating composition comprising one or more compounds having functional groups which are reactive to olefinically unsaturated bonds, and a citraconimide functional compound, e.g., benzyl citraconimide, octyl citraconimide, or methoxy propyl citraconimide and/or an itaconimide functional compound as a reactive diluent. The reactive diluents are particularly suitable for use in oxidatively drying coating compositions, such as alkyd based coatings, or coating compositions which are curable by radical copolymerization.
    Type: Application
    Filed: October 18, 2001
    Publication date: September 5, 2002
    Inventors: Keimpe Van Den Berg, Frederik Rous, Robert Paul Klaasen, Heert Andringa, Huig Klinkenberg, Berend Hoving
  • Publication number: 20020120062
    Abstract: The present invention relates to a thermoplastic resin composition comprising a rubber-reinforced thermoplastic resin (A) obtained by graft polymerizing a monomeric mixture (b) comprising an aromatic vinyl compound, a vinyl cyanide compound and optionally other copolymerizable monomeric compound(s) in the presence of a rubber-like polymer (a),
    Type: Application
    Filed: December 20, 2001
    Publication date: August 29, 2002
    Inventors: Tadashi Nagahara, Masanori Suzuki, Kazuki Iwai
  • Patent number: 6417259
    Abstract: The present invention relates to a process of forming a high damping, soft polymer gel. The method involves mixing a polyalkylene grafted poly(alkenyl-co-maleimide) with a poly(alkenyl-co-maleimide) and an extender so as to form a gel.
    Type: Grant
    Filed: June 5, 2000
    Date of Patent: July 9, 2002
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz
  • Patent number: 6403705
    Abstract: The invention concerns molecular rods, their uses in a method for fixing and/or crystallising macromolecules, the resulting products and uses of said products in the field of materials and structural biology, in particular as biosensors or as biomaterials. Said molecular rods have a structure represented by the general formula (I) and said method essentially consists in incubating, for at least 15 minutes, a biological macromolecule in solution with a molecular rod as defined by the formula, in suitable temperature and pH conditions.
    Type: Grant
    Filed: February 6, 2001
    Date of Patent: June 11, 2002
    Assignees: Commissariat a L'Energie Atomique, Centre National de la Recherche Scientifique-CNRS
    Inventors: Fabrice Balavoine, Charles Mioskowski, Patrick Schultz
  • Patent number: 6353054
    Abstract: The present invention is generally directed to a process for forming a diene-rubber grafted centipede polymer. The process includes copolymerizing a copolymer comprising a maleimide and at least one block chosen from the group consisting of vinyl aromatic hydrocarbons, R1R2ethylenes, or alkyl vinyl ethers with an amine. The amine is further functionalized with at least one functional group capable of grafting to a diene rubber. The copolymer is cocured with a diene rubber to form the diene-rubber grafted centipede polymer.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: March 5, 2002
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Edward D. Kelley
  • Patent number: 6350800
    Abstract: A polymeric gel composition comprising a polymer including an anhydride unit and an alkenyl unit, a crosslinking agent, a maleated polyalkylene, an extender, and an organic fatty acid is provided. The polymeric gel composition has superior high-temperature stability, mechanical strength, and moldability.
    Type: Grant
    Filed: June 5, 2000
    Date of Patent: February 26, 2002
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, James E. Hall, Victor J. Foltz
  • Publication number: 20020004571
    Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Application
    Filed: May 14, 2001
    Publication date: January 10, 2002
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Publication number: 20010025082
    Abstract: A syndiotactic polystyrene copolymer resin composition with high impact strength, which comprises: (A) about 1-99 weight % of a syndiotactic polystyrene copolymer which is polymerized from at least one macromonomer having an active polymerization group at its end and at least one styrene monomer; and (B) about 99-1 weight % of at least one rubber phase resin and/or at least one thermoplastic resin.
    Type: Application
    Filed: January 19, 2001
    Publication date: September 27, 2001
    Inventor: Joon Yong Park
  • Patent number: 6255387
    Abstract: A derivatized blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and then reacted with an organic compound to derivatize the blend. The sheared derivatized blend of polymers can function as a shear stable multifunctional viscosity index improver with improved low temperature properties and, in some cases, dispersancy antioxidant and anti-wear properties.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: July 3, 2001
    Assignee: Ethyl Additives Corporation
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 6225404
    Abstract: A thermoplastic compound comprising at least one linear or branched thermoplastic polymer or copolymer, having at least one reactive or graftable site (F1), which polymer is compounded with at least one hyperbranched dendritic polyester macromolecule being composed of a monomeric or polymeric nucleus and one or more monomeric or polymeric branching or spacing chain extenders. The macromolecule is optionally chain terminated and/or functionalized, whereby terminal chain extender functions, chain termination and/or functionalization provides the macromolecule with at least one reactive or graftable site (F2) being reactive to or graftable onto said reactive or graftable site (F1). In a further aspect, the invention relates to a thermoplastic composition comprising two or more components, whereby at least one is said thermoplastic compound. In yet a further aspect, the invention relates to a thermoplastic article made of one or more thermoplastic compounds, whereby at least one is said thermoplastic compound.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: May 1, 2001
    Assignee: Perstorp AB
    Inventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Mansson
  • Patent number: 6191217
    Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkyl vinylether-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: February 20, 2001
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz, Terrence E. Hogan
  • Patent number: 6140426
    Abstract: The present invention relates to thermoplastic graft polymer moulding compositions for high-gloss applications, which exhibit a reduced tendency of the additives to exude out of the thermoplastic composition during processing, and which exhibit reduced deposit build-up in the mould.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: October 31, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bahman Sarabi, Herbert Eichenauer, Edgar Leitz, Heinrich Alberts, Thomas Eckel, Dieter Wittmann
  • Patent number: 6133354
    Abstract: The present invention teaches a method for enabling the formation of a high damping composition. The method includes mixing a centipede polymer, i.e., a poly(disubstituted ethylene-co-maleimide) polymer, and plasticizers or extenders within a non-vulcanized thermoplastic elastomer to form a relatively high damping gel composition.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: October 17, 2000
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz, David F. Lawson, Naruhiko Mashita
  • Patent number: 6103450
    Abstract: A photosensitive polymer, a dissolution inhibitor, and a chemically amplified photoresist composition containing the photosensitive polymer and the dissolution inhibitor are provided. The photosensitive polymer is a copolymer polymerized with 5-norbornene-2-methanol derivative monomer having a C.sub.1 to C.sub.20 aliphatic hydrocarbon as a side chain, and a maleic anhydride monomer. The dissolution inhibitor is a tricyclodecane derivative or a sarsasapogenin derivative, each having an acid-labile group as a functional group. The chemically amplified photoresist composition containing the photosensitive polymer and/or dissolution inhibitor has a strong resistance to etching and excellent adherence to underlying layer.
    Type: Grant
    Filed: March 26, 1999
    Date of Patent: August 15, 2000
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Sang-jun Choi
  • Patent number: 6100366
    Abstract: The present invention provides: a cyclic imino ether group containing polymer with an extremely reduced amount of residual cyclic imino ether group containing monomer; and a production process therefor. The cyclic imino ether group containing polymer is obtained by a process including the step of polymerizing a monomer component including a cyclic imino ether group containing monomer, and contains a cyclic imino ether group containing monomer unit in the ratio of not less than 0.1 mol %, wherein the amount of the cyclic imino ether group containing monomer remaining in the polymer is not more than 15 ppm.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: August 8, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshitomo Nakata, Kazumi Fujioka
  • Patent number: 6093773
    Abstract: A compound comprising a blend of polypropylene with the reaction product of a functionalized polypropylene and polyether amine in which the polyether amine is grafted onto the functionalized polypropylene in a customary mixing apparatus is disclosed. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed.
    Type: Grant
    Filed: August 3, 1999
    Date of Patent: July 25, 2000
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Randall Keith Evans, Richard Joseph Gilbert Dominguez, Richard James Clark
  • Patent number: 6087453
    Abstract: This invention provides a vulcanizable rubber composition comprising (a) 100 parts by weight of a nitrile-containing highly saturated copolymer rubber obtained by hydrogenating the conjugated diene portions of an unsaturated nitrile-conjugated diene-unsaturated carboxylic acid ester copolymer, (b) 10 to 100 parts by weight of a metallic salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, (c) 0.1 to 30 parts by weight of an organic peroxide vulcanizing agent, and optionally (d) 0.5 to 30 parts by weight of a compound of a group 2A metal in the periodic table. The vulcanized product of this composition is useful as a seal for Freons because it is excellent in low-temperature resistance and resistance to Freon gas permeation and has resistance to the production of cracks in the rubber surface due to the foaming of Freon gas.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: July 11, 2000
    Assignee: Nippon Zeon Co., Ltd.
    Inventor: Koichi Nishimura
  • Patent number: 6080815
    Abstract: The present invention relates to a process for producing a thermoplastic resin having high impact strength and good surface gloss, which comprises graft copolymerizing at least a vinyl cyanide compound and at least an aromatic vinyl compound for a short period of less than about 3 hours in the presence of rubber latex having high gel content. The rubber latex can be a mixture of two or more rubber latices having different particle size. The graft copolymer has the characteristics such that the degree of the inner occlusion into the resin is decreased and the degree of surface grafting is increased. Thereby, the resulted thermoplastic resin has a very high impact strength and good surface gloss, and the processability is greatly improved. In addition, when the graft copolymer is polymerized the level of coagulum formation is greatly decreased.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: June 27, 2000
    Assignee: LG Chemical Limited
    Inventors: Chang-Hong Lee, Young-Min Kim, Jin-Nyoung Yoo
  • Patent number: 6072002
    Abstract: A thermoplastic molding composition which features improved impact and flow properties as well as reduced opacity is disclosed. The composition contains(A) 15 to 50 percent of a grafted rubber which contains (a) a crosslinked rubber substrate which contains, as a core, about 1 to 25% relative to its weight of at least one vinylaromatic polymer, and (b) a grafted phase, and(B) 85 to 50 percent of a copolymeric matrix.The composition, which contains no additional grafted rubber components, is also characterized in that (i) the substrate amounts to 60 to 90 percent, and grafted phase amounts to 40 to 10 percent, relative to the weight of the grafted rubber and that (ii) the grafted rubber has a monomodal size distribution and that (iii) the grafted rubber has a weight average particle size of about 0.2 to 1.0 microns.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: June 6, 2000
    Assignee: Bayer Corporation
    Inventors: Moh Ching Oliver Chang, Richard M. Auclair
  • Patent number: 6069202
    Abstract: Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: May 30, 2000
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Krishna Venkataswamy, Jacques Horrion
  • Patent number: 6048930
    Abstract: The present invention teaches a method for enabling the formation of a high damping compound. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product within a rubber formulation to form a relatively high damping compound. The present invention also contemplates a rubber compound composition and an article manufactured from the composition.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: April 11, 2000
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz
  • Patent number: 6031048
    Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: February 29, 2000
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Randall Keith Evans, Richard J.G. Dominguez, Richard J. Clark
  • Patent number: 6015859
    Abstract: A thermoplastic polymer composition contains at least two distinct polymers, characterized in that it comprises at least one polymer P1 containing at least one reactive function and at least one modified polyolefin P2 containing at least one succinimide ring substituted on the nitrogen by a reactive group, the ring being carried either by the main chain or by a side chain, and optionally at least one third polymer P3 selected from the group formed by polymers and copolymers obtained by polymerisation of one or more olefinic compounds. A mixture of polymers comprises at least one composition as defined above and at least one other polymer P5 which is identical to or different from polymer P3 and optionally at least one other polymer P6 which is identical to or different from polymer P1.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: January 18, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Yves Camberlin, Serge Gonzalez, Frederique Hauviller
  • Patent number: 5994468
    Abstract: The instant invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(maleimide-co-alkenyl benzene) polymer with a nylon and an alkyl diamine under substantially dry conditions sufficient to form a nylon grafted poly(maleimide-co-alkenyl benzene) polymer product; and, dispersing the nylon grafted poly(maleimide-co-alkenyl benzene) polymer product with an extender oil sufficient to form the gel. The instant invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: November 30, 1999
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz, James E. Hall, Naruhiko Mashita, Hideo Takeichi
  • Patent number: 5985998
    Abstract: A novel class of interpenetrating polymer networks which are dispersible in conventional coating solvents is disclosed. Such dispersions are useful in preparing protective and/or decorative film coatings and are particularly useful in photosensitive or imaging formulations such as photoresists, solder masks and the like. These polymer networks are comprised of at least two interpenetrating crosslinked polymers. At least one of the polymer networks is formed by polymerization in a solvent. In one embodiment of this invention, at least one polymer network is prepared from macromers to produce a polymer system having functionalized branch or graft linear segments. The solvent dispersible interpenetrating networks of this invention are particularly useful as binders in addition polymerizable photosensitive compositions containing crosslinking monomers such as solder masks. Upon exposure to actinic radiation and suitable thermal curing, solder mask coatings of such photosensitive compositions form multiple, e.g.
    Type: Grant
    Filed: February 11, 1999
    Date of Patent: November 16, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Eugene G. Sommerfeld, Frank Schadt, III
  • Patent number: 5981657
    Abstract: The present invention provides a thermally resistant resin composition containing PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized with a basic metal compound containing a metal element of the group 2B, 3B, 4B or 5B of the periodic table; thermally resistant PS and PPO each with an acid group which is also neutralized in the same manner as described above; and a method for miscible preparation of PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized similarly.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: November 9, 1999
    Assignee: Sony Corporation
    Inventors: Yasuhito Inagaki, Tsutomu Noguchi, Hidemi Tomita
  • Patent number: 5965666
    Abstract: This invention relates to a resin composition having high impact strength at low temperatures, comprising a polyamide, a graft copolymer obtained by graft polymerizing a monomer mixture of an aromatic vinyl monomer and a vinyl cyanide monomer to a conjugated diene rubber, a copolymer comprising an aromatic vinyl monomer, a vinyl cyanide monomer and other vinyl monomer copolymerizable with the aromatic vinyl monomer and the vinyl cyanide monomer, a modified hydrogenated block copolymer comprising a conjugated diene rubber and styrene or its derivatives to which has been grafted an unsaturated carboxylic acid or an unsaturated carboxylic anhydride, a copolymer comprising an aromatic vinyl monomer, a maleimide monomer, an unsaturated carboxylic acid or an unsaturated carboxylic anhydride, and other vinyl monomer copolymerizable with the aromatic vinyl monomer, and a graft copolymer obtained by graft polymerizing a maleic anhydride to an ethylene-propylene rubber.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: October 12, 1999
    Assignee: Cheil Industries, Inc.
    Inventors: Jung-Kee Koo, Hee-Gu Yeo, Jong-Chul Lim
  • Patent number: 5955541
    Abstract: A thermoplastic resin composition which has low rigidity such as bending strength, bending modulus and tensile strength, high impact resistance, and further low stress and large energy absorption at the time of impact, high heat deformation resistance and excellent moldability and comprises 5 to 65 by weight of the copolymer (I) having Tg (glass transition temperature) of not more than 20.degree. C., 20 to 80 parts by weight of the maleimide copolymer (II) and 15 to 75 part by weight of the graft copolymer (III) having a graft ratio of 10 to 70% so that the total amount of the copolymers (I), (II) and (III) becomes 100 parts by weight, can be obtained.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: September 21, 1999
    Assignee: Kaneka Corporation
    Inventors: Kazuhito Wada, Ikuhiro Mishima, Shigemi Matsumoto
  • Patent number: 5952423
    Abstract: Plastic compositions, containers useful in the storage of red blood cells, and methods for providing such red blood cell storage containers and for storing red blood cells are disclosed. The plastic composition includes a polyolefin copolymer and a plasticizer. The flexibility of such plastic compositions and containers made thereof is substantially unchanged upon heating to a high temperature relative to its flexibility before such heating.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: September 14, 1999
    Assignee: Baxter International Inc.
    Inventors: Shaye-Wen Shang, Michael Tung-Kiung Ling, Lecon Woo
  • Patent number: 5948860
    Abstract: Disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer and (c) a polar group-containing olefin polymer composition obtained by heating (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. Also disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer, (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. The propylene polymer compositions of the present invention are excellent in properties of being coated with various coatings.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: September 7, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Shoji Hiraoka, Masayoshi Yamaguchi, Hajime Inagaki, Mikio Hashimoto
  • Patent number: 5942576
    Abstract: A compound comprising a blend of polypropylene with the reaction product of a functionalized polypropylene and polyether amine in which the polyether amine is grafted onto the functionalized polypropylene in a customary mixing apparatus is disclosed. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: August 24, 1999
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Randall Keith Evans, Richard Joseph Gilbert Dominguez, Richard James Clark
  • Patent number: 5910538
    Abstract: A thermoplastic molding composition containing a blend of polycarbonate, vinyl copolymer, such as SAN, and a graft polymer, such as ABS is disclosed. The invention resides in the finding that the incorporation of a compatibilizing agent which comprises a polymeric resin having a number average molecular weight of at least about 21,000 and which is miscible with the grafted phase of the graft polymer and which contains secondary amine reactive groups in its structure yields stable compositions having improved mechanical properties especially at low temperatures.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: June 8, 1999
    Assignee: Bayer Corporation
    Inventors: Allen R. Padwa, Venkatarayaloo Janarthanan
  • Patent number: 5907010
    Abstract: Graft copolymers are obtainable by reactingA) polyarylene ethers,B) polyamides andC) copolymers which contain cyclic, .alpha.,.beta.-unsaturated dicarboxylic anhydridesand are used for the preparation of thermoplastic molding materials or as compatibilizers for polymer blends based on polyarylene ethers and polyamides.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: May 25, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Norbert Guntherberg
  • Patent number: 5883190
    Abstract: Thermoplastic moulding compositions containingI) At least one graft polymer which is obtainable by emulsion polymerisation of for example styrene and acrylonitrile under special conditions,II) At least one graft polymer that can be obtained by solution, bulk or suspension polymerisation of for example styrene and acrylonitrile in the presence of a rubber,III) At least one rubber-free copolymer of for example styrene and acrylonitrile,and their use for producing mouldings.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: March 16, 1999
    Assignee: Bayer AG
    Inventor: Herbert Eichenauer
  • Patent number: 5883189
    Abstract: Thermoplastic moulding compositions of the ABS type, containingI) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a mixture comprising a butadiene polymer latex (A) having a particle diameter d.sub.50 of .ltoreq.320 nm, a particle diameter distribution of 30 to 100 nm in width and a gel content of .ltoreq.70 wt. % and a butadiene polymer latex (B) having a particle diameter d.sub.50 of .gtoreq.370 nm, a particle diameter distribution of 50 to 500 nm in width and a gel content of .gtoreq.270 wt. %,II) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a butadiene polymer latex (C) having a particle diameter d.sub.50 of from 110 to 150 nm, a particle diameter distribution of 20 to 50 nm in width and a gel content of from 80 to 98 wt. %, andIII) at least one rubber-free copolymer composed of resin-forming monomersand the use of the moulding compositions for the production of mouldings.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: March 16, 1999
    Assignee: Bayer AG
    Inventors: Herbert Eichenauer, Edgar Leitz
  • Patent number: 5837773
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution. The sheared blend of polymers can function as a shear stable dispersant viscosity index improver with improved lower temperature properties or the hydrocarbon base for multifunctional for viscosity index improvers, motor fuel additives or polymeric dispersants.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: November 17, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 5824741
    Abstract: This invention relates to impact-resistant thermoplastic moulding compositions based on a graft rubber, a thermoplastic resin and a small quantity of a free acid-functional nitrile rubber.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: October 20, 1998
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Werner Tischer, Rolf-Volker Meyer
  • Patent number: 5811491
    Abstract: A glass fiber-reinforced thermoplastic resin excellent in providing a balance between processability, tapping strength and heat resistance. The composition comprising (A) 10 to 60% by weight of a terpolymer which comprises N-phenylmaleimide, styrene and acrylonitrile, (B) 5 to 20% by weight of a graft polymer which comprises at least one rubber selected from the group consisting of a conjugated diene rubber, an ethylene-propylene rubber and an ethylene-butylene rubber comprising ethylene and butylene, to which rubber styrene and acrylonitrile are graft polymerized, (C) 10 to 80% by weight of a copolymer which comprises styrene and acrylonitrile, and (D) 5 to 35% by weight of glass fiber, wherein(a) the terpolymer has an intrinsic viscosity of 0.20 dl/g to 0.70 dl/g, (b) the copolymer has an intrinsic viscosity of 0.40 dl/g to 1.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 22, 1998
    Assignees: Sumitomo Dow Limited, Toyota Jidosha Kabushiki Kaisha
    Inventors: Yasutoshi Jagawa, Takeyoshi Nishio, Kiyoshi Ogura, Mikio Hirai
  • Patent number: 5789496
    Abstract: A method for the removal, separation, and concentration of cesium cations from a source solution which may contain larger concentrations of other alkali metal ions comprises bringing the source solution into contact with a polymeric resin containing poly(hydroxyarylene) ligands. The poly(hydroxyarylene) ligand portion(s) of the polymeric resins has affinity for cesium, thereby removing cesium from the source solution. The source solutions from which the cesium has been removed may then be treated or disposed of as desired and the cesium cations are then removed from the polymeric resin through contact with a much smaller volume of a receiving solution in which these cesium cations are soluble and has greater affinity for such cations than does the poly(hydroxyarylene) ligand or protonates the ligand, thereby quantitatively stripping the completed cesium cations from the ligand and recovering them in concentrated form in said receiving solution.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: August 4, 1998
    Assignee: IBC Advanced Technologies, Inc.
    Inventors: Bryon J. Tarbet, Garren Maas, Krzysztof E. Krakowiak, Ronald L. Bruening
  • Patent number: 5744250
    Abstract: The present invention relates to bonding resins having excellent adhesion to polar polymers, particularly ionomers, acid copolymers and ethylene vinyl alcohol copolymer. These resins preferably contain: 1) an ethylene polymer or copolymer (ungrafted, grafted or partially grafted); 2) a grafted elastomer; and 3) optionally, an ethylene alpha olefin copolymer which is wholly or partially grafted. Preferred grafting comonomers include maleic anhydride and derivatives thereof.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: April 28, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: I-Hwa Lee, Stephen Robert Tanny, Anthony Matthew Angelo, Stewart Carl Feinberg
  • Patent number: 5741853
    Abstract: Thermoplastic moulding compositions of the ABS type ofI) at least one graft copolymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, in the presence of at least two butadiene polymer latices of types (A) and (B), which each contain, copolymerized, 0 to 50 wt. % of a further vinyl monomer, and wherein the weight ratio of monomers used to butadiene polymers used is 25:75 to 70:30, andII) at least one copolymer of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, characterized in that the butadiene polymer latex (A) has a particle diameter d.sub.50 .ltoreq.320 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: April 21, 1998
    Assignee: Bayer AG
    Inventors: Herbert Eichenauer, Ulrich Jansen, Karl-Erwin Piejko, Edgar Leitz
  • Patent number: 5728775
    Abstract: A heat-resistant high-nitrile polymer composition obtained by the graft copolymerization of 100 parts by weight of a monomer mixture comprising 50 to 80% by weight of an unsaturated nitrile monomer, a maleimide monomer, an aromatic vinyl monomer, and a monomer copolymerizable with the foregoing monomers, in the presence of 1 to 40 parts by weight of a conjugated diene-based synthetic rubber containing not less than 50% by weight of a conjugated diene monomer unit, wherein the concentration of residual maleimide monomer in the polymer composition is not greater than 200 ppm by weight. This polymer composition is suitable for use as a molding material for extrusion molding, blow molding, injection molding and the like, and is useful in applications which require gas barrier properties, chemical resistance, non-adsorptive properties and the like, and which require use in automobiles, heat resistance sufficient for heat filling, and safety and hygienic properties.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: March 17, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hiroaki Narisawa, Masahiro Kaneko, Mitsuo Kawata, Syuichi Yamaguchi, Shinichi Asai, Makoto Someda
  • Patent number: 5719232
    Abstract: ABS type thermoplastic moulding compounds obtainable byA) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. %B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced,C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: February 17, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Adolf Schmidt, Herbert Eichenauer, Ulrich Jansen
  • Patent number: 5714541
    Abstract: Thermoplastics built up from N-(2-ethyl-6-methyl)phenylmaleimide and styrene, it being possible for all or some of the styrene to be replaced by at least one other monomer component.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: February 3, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Erwin Piejko, Herbert Eichenauer, Torsten Groth, Josef Kasbauer, Bernd-Michael Konig
  • Patent number: 5705553
    Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Rolf Kuropka