Mixture Contains Solid Polymer Derived From Reactant Containing Oxygen Heterocycle Patents (Class 525/74)
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Publication number: 20120252922Abstract: The present invention relates to a polymer composition comprising a polypropylene, an adhesive polymer and an oxygen absorbing composition. The invention also relates to the use of said composition for the manufacture of processed goods.Type: ApplicationFiled: October 15, 2010Publication date: October 4, 2012Applicant: REPSOL YPF, S.A.Inventors: José Sancho Royo, Begoña Peña García, Icíar Martínez Cebrián, Julia Mena Martínez, Sagrario Ruiz Herrero, Rosa Parrilla Martín, Manuel López Reyes
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Patent number: 8217114Abstract: An aqueous coating resin composition comprising a water-dispersible nonionic resin (A) and a water-dispersible anionic core-shell resin (B), characterized in that the water-dispersible nonionic resin (A) contains a polyoxyalkylene group-containing polymerizable unsaturated monomer (a1) at 5-50 mass % of the total polymerizable unsaturated monomer used for production of the resin (A), and the water-dispersible anionic core-shell resin (B) contains an anionic group in the resin. It is possible to provide aqueous coating compositions exhibiting both satisfactory coating manageability and finished appearance.Type: GrantFiled: August 29, 2007Date of Patent: July 10, 2012Assignee: Kansai Paint Co., Ltd.Inventors: Yohichi Kawaguchi, Teppei Oohori, Terutaka Takahashi
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Patent number: 8207265Abstract: This invention comprises a film useful as an adhesive, a composition useful to make the film, and a laminate comprising the film contiguous with at least one metal substrate, at least one foam substrate or combination thereof. The composition comprises (a) at least one anhydride grafted olefin polymer, (b) at least one high density polyethylene, and (c) at least one elastomer which preferably has a tensile elongation at break of at least about 585%, a density of at most about 0.900 g/cm3 or a combination thereof. The anhydride grafted olefin polymer or combination thereof is preferably present in an amount of from about 20 to about 40 weight percent, the high density polyethylene or combination thereof is preferably present in an amount of from about 40 to about 60 weight percent, and the elastomer or combination thereof is preferably present in an amount of from about 17 to about 30 weight percent.Type: GrantFiled: October 16, 2007Date of Patent: June 26, 2012Assignee: Dow Global Technologies LLCInventors: Robert L. McGee, Julie R. Hatlewick
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Patent number: 8197947Abstract: Adhesive compositions comprising a first copolymer of butene-1 and propylene; a second copolymer of ethylene and a comonomer selected from butene-1, hexene-1, and octene-1; a polyolefin grafted with an ethylenically unsaturated carboxylic acid or acid derivative; and an olefin polymer resin, and multilayer structures comprising the adhesive composition.Type: GrantFiled: December 1, 2009Date of Patent: June 12, 2012Assignee: Equistar Chemicals, LPInventors: Maged G. Botros, Charles S. Holland
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Publication number: 20120142863Abstract: The present invention provides a vinyl ester resin composition obtained by an improved production method and having improved quality, by providing a minute polymer particle-containing vinyl ester resin composition containing 100 parts by weight of a vinyl ester resin, 1 to 100 parts by weight of a minute polymer particle, and 0 to 100 parts by weight of a vinyl monomer, wherein the primary particle size of the minute polymer particle is 0.05 ?m to 1 ?m, and the minute polymer particles are dispersed in the form of primary particles in the minute polymer particle-containing vinyl ester resin composition.Type: ApplicationFiled: May 27, 2010Publication date: June 7, 2012Applicant: KANEKA CORPORATIONInventor: Masahiro Miyamoto
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Publication number: 20120115635Abstract: Disclosed herein are hard and flexible compositions, i.e., compositions which have a flexural modulus that is less than the value that is expected based on the composition's hardness. The compositions preferably have a hardness/modulus relationship represented by the formula H?11.889 Ln(M)+47, where H is the hardness of the composition, in JIS-C, and M is the flexural modulus of the composition, in ksi; or a softness/stiffness relationship represented by the formula if M<110, then H?8.5218 Ln(M)+32.5 if M?110, then H?72.5, where H is the hardness of the composition, in Shore D, and M is the flexural modulus of the composition, in ksi.Type: ApplicationFiled: November 8, 2010Publication date: May 10, 2012Inventors: Michael J. Sullivan, Robert Blink, David A. Bulpett, Mark L. Binette, Brian Comeau
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Patent number: 8168710Abstract: A golf ball having a core, a cover layer, and an optional intermediate layer disposed between the core and the cover layer is disclosed and described. One or more of the core, the cover layer, or the intermediate layer is formed of a highly neutralized polymer blend of an acid copolymer and a metallocene-catalyzed copolymer, an olefinic block copolymer, a sufficient amount of a suitable cation source and a fatty acid or salt of a fatty acid. The highly neutralized polymer blend is neutralized from 80% to 100% while still retaining processability. Further, the core can have a diameter of 0.5 inches to about 1.62 inches and an Atti compression less than or equal to 105. The cover layer can have a material hardness between about 30 and 70 Shore D.Type: GrantFiled: June 1, 2009Date of Patent: May 1, 2012Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Michael J. Sullivan, Kevin M. Harris
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Patent number: 8158721Abstract: This invention relates to processes for the preparation of a dynamically vulcanized alloy comprising at least one isobutylene-containing elastomer and at least one thermoplastic resin. More specifically, the processes produce dynamically vulcanized alloys with unique morphological features which have good impermeability and low temperature flexibility.Type: GrantFiled: June 13, 2008Date of Patent: April 17, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: William G. Stevenson, Joseph M. DeLucia, Michael K. Lyon, Jianya Cheng
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Patent number: 8148466Abstract: Thermoplastic polymer compositions, films, containers, laminates and fibers can comprise a modified polymer. The said modified polymer having a moiety comprising a half-ester reaction product of cyclodextrin and metal and/or organic group covalently bonded to some portion of the half-acid moieties. The cyclodextrin compound, grafted to the polymer structure, can scavenge impurities, permeants, or other undesirable volatile contaminants. The cooperation between the modified polymer's carboxylic acidic groups, basic groups and grafted cyclodextrin can provide active barrier properties to a film, web, fiber or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film, web or fiber preventing the permeant from passing into the interior of a container, or the contaminant can be scavenged from the enclosed headspace or surrounding environment.Type: GrantFiled: May 23, 2005Date of Patent: April 3, 2012Assignee: Cellresin Technologies, LLCInventors: Willard E. Wood, Neil J. Beaverson
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Publication number: 20120077048Abstract: Graft compositions, useful for tie-layer adhesives, are disclosed. The graft compositions comprise the reaction product of a live, grafted polyolefin and an olefin elastomer. The grafted polyolefin is first made by heating a polyolefin and an unsaturated monomer. Further reaction of the live, grafted polyolefin with an olefin elastomer provides the graft composition. Grafting efficiency is boosted dramatically by the presence of the olefin elastomer and use of the additional reaction step. The graft composition, when formulated into a tie-layer adhesive at low concentration, affords multilayer structures with good adhesion and high clarity.Type: ApplicationFiled: September 29, 2010Publication date: March 29, 2012Inventor: Maged G. Botros
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Patent number: 8142855Abstract: A method of applying a curable composition to a substrate is disclosed. The composition comprises a polyene and a active hydrogen-containing compound that are capable of undergoing a Michael Addition reaction. The reaction is conducted in the presence of a tertiary phosphine catalyst. The components of the composition are sprayed in separate streams whereby the streams overlap prior to contacting the substrate and the composition cures quickly on the substrate.Type: GrantFiled: September 12, 2008Date of Patent: March 27, 2012Assignee: PPG Industries Ohio, IncInventor: Mark P. Bowman
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Patent number: 8143328Abstract: The present invention relates to a methacryl resin composition having excellent impact strength and transmittancy, and more specifically, to a graft copolymer prepared by preparing graft prepolymer by inputting a monomer mixture comprising 60 to 100 wt % of alkyl methacrylate, and 0 to 40 wt % of one or more compound selected from a group consisting of aromatic vinyl compound and alkyl acrylate compound to perform graft polymerization and adding acid, salt, or polymer coagulant when the monomer conversion of the polymerization is 70% to 95% and then continuously performing the polymerization to have an increased particle size to 100 to 500 nm in a graft polymerization process among processes of preparing the graft polymer including a seed-rubber core-graft polymerization process, a preparing method thereof, and a methacryl resin composition including the graft polymer.Type: GrantFiled: August 20, 2009Date of Patent: March 27, 2012Assignee: LG Chem Ltd.Inventors: Dong-jo Ryu, Jeong-heon Ahn, Se-eun Lee
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Patent number: 8119702Abstract: The present invention provides a resin composition consisting of a functionalized polypropylene (PP) and a functionalized styrenic thermoplastic elastomer (TPS). The functionalized PP is a PP grafted with N-vinyl pyrrolidone (NVP) and glycidyl methacrylate (GMA), and the functionalized TPS is a TPS grafted with acrylamide or methacrylamide. The functionalized PP and the functionalized TPS are subjected to melt blending to obtain the resin composition with a slight cross-linking structure due to the reaction between GMA and acrylamide or methacrylamide, therefore the resin composition presents good physical properties. Besides, the resin composition without additional plasticizer or other small molecular organic compounds can be utilized in blood bags, blood transfusion and collection apparatuses, etc. Thus, it does not release small molecular substances which are of potential harm to human body during use.Type: GrantFiled: September 27, 2010Date of Patent: February 21, 2012Assignee: Changchun Institute of Applied Chemistry Chinese Academy of SciencesInventors: Shifang Luan, Jinghua Yin, Zhongzhi Li, Jianwei Wang, E Zhang, Huawei Yang
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Patent number: 8119735Abstract: A golf ball having a cover having a pearlescent effect is disclosed. The cover comprises a first thermoplastic and a second thermoplastic having an index of refraction that differs from an index of refraction of the first thermoplastic by at least about 0.5 percent. The cover further comprises a compatibilizer.Type: GrantFiled: January 26, 2009Date of Patent: February 21, 2012Assignee: Acushnet CompanyInventors: Edmund A. Hebert, Murali Rajagopalan
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Patent number: 8114933Abstract: The thermoplastic rubber grafted copolymer resin composition comprising (A) about 100 parts by weight of a rubber grafted copolymer prepared by (a1) about 10 to 100 parts by weight of a rubber-modified grafted copolymer and (a2) about 0 to 90 parts by weight of copolymer prepared by vinyl cyanide compound/aromatic vinyl compound or methyl methacrylate or N-phenyl maleimide/vinyl cyanide monomer or aromatic vinyl monomer/methyl methacrylate or N-phenyl maleimide; (B) about 1 to 30 parts by weight of a maleic anhydride copolymer; and (C) about 1 to 20 parts by weight of a clay treated with a compound containing reactive functional groups; wherein said compound containing functional groups has a radical-polymerizable group and an onium ion that can ion-exchange with said clay.Type: GrantFiled: May 31, 2007Date of Patent: February 14, 2012Assignee: Cheil Industries Inc.Inventors: Tae Uk Kim, Hee Seok Na, Duk Hee Kim
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Publication number: 20120035324Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.Type: ApplicationFiled: August 2, 2011Publication date: February 9, 2012Applicant: HUTCHINSONInventors: Nicolas Garois, Philippe Sonntag, Grégory Martin, Matthieu Vatan, Jacques Drouvroy
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Publication number: 20110303263Abstract: The invention relates to the use in a photovoltaic module of a film of a composition as a backsheet or as an encapsulant, this composition comprising, with respect to the total weight of the composition: from 1 to 99% of a polyethylene having an ethylene whose level by weight is greater than or equal to 80% chosen from the homopolymers of ethylene and the copolymers of ethylene and another alpha-olefin; from 99 to 1% of a polyolefin B, other than A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides. The invention further relates to a photovoltaic module comprising the film of the composition according to the invention and also a process for the manufacture of this module.Type: ApplicationFiled: December 14, 2009Publication date: December 15, 2011Applicant: Arkema FranceInventors: Catherine Corfias-Zuccalli, Laurent B. Cartier, Samuel Devisme, Stephane Bizet
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Patent number: 8076407Abstract: Hot melt adhesives are provided that have improved heat resistance. The adhesives comprise a metallocene polyolefin, an amorphous ?-olefin polymer, a tackifier and a functional polyolefin. The functional polyolefin is used in an amount sufficient to increase the heat resistance. A preferred functional polyolefin is a maleated polyolefin such as maleated polypropylene. A preferred tackifier is a hydrogenated hydrocarbon tackifier.Type: GrantFiled: February 8, 2008Date of Patent: December 13, 2011Assignee: Henkel AG & Co. KGaAInventors: Richard J. Ellis, Michaela Stolbova
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Publication number: 20110269879Abstract: The present invention relates to a high-strength inflammable blend resin composition including a polyphenylene sulfide resin and a polyethylene terephthalate resin. More specifically, the resin composition of the present invention includes: a basic blend resin containing 10 to 80 wt. % of a polyphenylene sulfide resin, and 20 to 90 wt. % of a polyethylene terephthalate resin; and 0.1 to 20 parts by weight of a modified polystyrene or a styrene-based elastomer with respect to 100 parts by weight of the basic blend resin.Type: ApplicationFiled: December 30, 2009Publication date: November 3, 2011Applicant: SK Chemicals Co., Ltd.Inventors: Sung-Gi Kim, Jae-Bong Lim, Jong-In Lee, Chang-Hyun Lee, Sung-Su Bae, Sang-Mook Lee
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Publication number: 20110254204Abstract: The present invention relates to methods of modulating the gloss of plastics materials and products made from them, such as articles in the automotive industry e.g. for the interior of automobiles, as well as the use of certain additives for that purpose and related invention embodiments. The modulating comprises adding a modified polymer as matting agent to a polymer composition used as polymer substrate for the articles.Type: ApplicationFiled: October 21, 2009Publication date: October 20, 2011Applicant: BASF SEInventors: Martin Brunner, Gregor Huber, Laurent Simonpietri, Michael Tinkl
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Patent number: 7989083Abstract: To provide an acid-modified polypropylene resin which can be used for an adhesive capable of bonding a polyolefin type resin and a polar resin with sufficient force, its production process and a resin composition using it. An acid-modified polypropylene resin, which is obtained by grafting an organic acid component to a polypropylene resin, wherein the polypropylene resin is an isotactic polypropylene resin, the grafted amount X (wt %) of the organic acid component in the acid-modified polypropylene resin is within a range of from 1.0 wt % to 20.0 wt %, and the melt flow rate Y (g/10 min) of the acid-modified polypropylene resin satisfies the expression: Y?18.5 exp(0.82X), a process for producing such an acid-modified polypropylene resin, a resin composition using it and a laminate.Type: GrantFiled: April 28, 2006Date of Patent: August 2, 2011Assignee: Mitsubishi Chemical CorporationInventors: Kenichi Morikawa, Katsutoshi Ohno
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Publication number: 20110129667Abstract: Adhesive compositions comprising a first copolymer of butene-1 and propylene; a second copolymer of ethylene and a comonomer selected from butene-1, hexene-1, and octene-1; a polyolefin grafted with an ethylenically unsaturated carboxylic acid or acid derivative; and an olefin polymer resin, and multilayer structures comprising the adhesive composition.Type: ApplicationFiled: December 1, 2009Publication date: June 2, 2011Applicant: Equistar Chemicals, LPInventors: Maged G. Botros, Charles S. Holland
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Publication number: 20110082256Abstract: A polyolefin compound including: A) at least one thermoplastic olefin copolymer including the reaction product of olefin 1 and olefin 2, wherein: olefin 1 is a C2 based olefin and olefin 2 is a C3 to C8 ?-olefin or olefin 1 is a C3 based olefin and olefin 2 is a C4 to C8 ?-olefin; B) at least one functional polymer, the functional polymer content in the polyolefin compound being between 1 and 75 weight percent of the combined components A and B; wherein the thermoplastic olefin copolymer and the functional polymer form a co-continuous phase; wherein: a) an 12 melt index of the polyolefin compound is from about 1 to about 15 as measured using ASTM D 1238; b) a Shore A hardness of the polyolefin compound is from about 55 to about 100 as measured using ASTM D2240; c) a flexural modulus of the polyolefin compound is from about 0.8 to about 30 kpsi as measured using ASTM D790.Type: ApplicationFiled: May 29, 2009Publication date: April 7, 2011Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Felipe Martinez, Pankaj Gupta, Ashish Batra
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Patent number: 7919559Abstract: Disclosed herein is a chemical-resistant and impact-resistant thermoplastic resin composition having excellent hydrolysis resistance. The thermoplastic resin composition comprises (A) about 1 to about 97.9% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 97.9% by weight of a rubber modified aromatic vinyl copolymer resin; (C) about 1 to about 97.9% by weight of a polyester resin; and (D) about 0.1 to about 97% by weight of an amorphous cycloaliphatic diol modified polyester.Type: GrantFiled: December 16, 2008Date of Patent: April 5, 2011Assignee: Cheil Industries Inc.Inventors: Jee Kwon Park, Jun Myung Kim, Jin Hwan Choi, Jae Won Lee
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Patent number: 7910655Abstract: A polymer composition includes a polyarylene sulfide resin, a olefinic graft copolymer, and a fluorinated polyolefin resin. Some embodiments may additionally comprise an epoxy compound and/or a filler. In some embodiments, the compositions have good flame retardancy, impact strength, and flexural strength.Type: GrantFiled: May 22, 2006Date of Patent: March 22, 2011Assignee: Cheil Industrial Inc.Inventors: Nam Joong Baek, Han Soo Chung
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Patent number: 7901595Abstract: The invention relates to an electrically conductive elastomer mixture and to a method. The mixture comprises a thermoplastic styrene elastomer and, as an electrically conductive filler, metal-containing particles. The mixture further comprises a polymer which is an acid-grafted, acid-anhydride-grafted or acid-copolymer and which forms an IPN (Interpenetrating Polymer Network) network structure with the styrene elastomer.Type: GrantFiled: March 21, 2007Date of Patent: March 8, 2011Assignee: Premix OyInventors: Taisto Vilkman, Mikko Karttunen, Lisa Wikström
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Patent number: 7847027Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.Type: GrantFiled: December 29, 2006Date of Patent: December 7, 2010Assignee: Eastman Kodak CompanyInventors: Peter J. Ghyzel, Joseph F. Bringley, David J. Giacherio, Lawrence P. DeMejo, Terry C. Schultz, Todd Emrick
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Publication number: 20100304051Abstract: The invention provides a composition comprising the reaction product of a mixture comprising the following: A) at least one functionalized ethylene-based polymer formed by reacting an ethylene-based polymer with at least one anhydride-containing compound and/or at least one carboxylic acid-containing compound; B) at least one ethylene-based polymer; C) at least one anhydride-containing compound and/or at least one carboxylic acid-containing compound; and wherein the composition comprises from 0.05 to 1.0 weight percent, based on the total weight of the composition, of one or more grafted anhydride-containing compounds and/or one or more grafted carboxylic acid-containing compounds.Type: ApplicationFiled: September 3, 2008Publication date: December 2, 2010Applicant: Dow Global Technologies Inc.Inventors: Olaf Henschke, Gabriele Goethel
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Publication number: 20100266837Abstract: The invention relates to multiphase compositions of matter comprising at least an acrylic phase and a hydrocarbon phase, and more specifically to pressure sensitive adhesive compositions of matter of an acrylic-hydrocarbon polymer and an additional hydrocarbon component which has a molecular weight of at least 1,000 and may include one or both of an oligomeric hydrocarbon and a polymeric hydrocarbon.Type: ApplicationFiled: February 12, 2010Publication date: October 21, 2010Applicant: AVERY DENNISON CORPORATIONInventors: Nagarajan SRIVATSAN, Prakash MALLYA, Daniel L. HOLGUIN, Dominique WOUTERS, Eric L. BARTHOLOMEW, Liza P. LOFTON
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Publication number: 20100261845Abstract: The invention relates to the low molecular weight compatibilizing additive package having many advantageous effects, which improves the compatibility of different thermoplastic and/or thermosetting polymers and/or fillings, functional additives just as composites containing natural and/or artificial strengthening fibres, and relates to its preparation and application processes.Type: ApplicationFiled: October 14, 2008Publication date: October 14, 2010Applicant: Pannon EgyetemInventors: Laszlo Bartha, Norbert Miskolczi, Csilla Varga
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Publication number: 20100249314Abstract: The present invention provides a chemical and impact resistant thermoplastic resin composition that can have improved extrudability. In one embodiment, the thermoplastic resin composition comprises a base resin including (A) about 1 to about 98% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 98% by weight of a rubber modified styrene copolymer resin; and (C) about 1 to about 98% by weight of a polyester resin; and about 1 to about 6 parts by weight of an aromatic vinyl-vinyl cyanide copolymer resin having a weight average molecular weight of about 1,000,000 to about 5,000,000, per 100 parts by weight of the base resin comprising (A)+(B)+(C). In another embodiment, the thermoplastic resin composition comprises a base resin including (A) about 1 to about 98% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 98% by weight of a rubber modified styrene copolymer resin; and (C) about 1 to about 98% by weight of a polyester resin; and (E) about 0.Type: ApplicationFiled: June 10, 2010Publication date: September 30, 2010Applicant: CHEIL INDUSTRIES INC.Inventors: Jee Kwon PARK, Jun Myung KIM, Jin Hwan CHOI, Jae Won LEE
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Patent number: 7781523Abstract: The present invention relates to styrene-based thermoplastic resin compositions in which 1-10 weight part of a low-gloss additive selected from a group consisting of polyolefin copolymer(C) containing glycidyl methacrylate functional groups, styrene polymer(D) harboring two or more carboxyl functional groups per molecule, and a mixture of them, was added to 100 weight part of basic resin composed of 30-70 weight part of graft copolymer(A) containing rubber modified styrene and 30-70 weight part of copolymer(B) harboring styrene. The thermoplastic resin composition of the present invention has excellent impact strength and satisfactorily low gloss.Type: GrantFiled: August 26, 2005Date of Patent: August 24, 2010Assignee: LG Chem, Ltd.Inventors: Byoung-il Kang, Han-jong You, Seong-lyong Kim
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Publication number: 20100202050Abstract: The present invention provides an optical film that includes i) an acryl resin, and ii) 20 to 65 parts by weight of a core-shell type graft copolymer that includes a core having a rubber component and a shell including a polymer having a weight average molecular weight that is the same as or higher than a weight average molecular weight of a polymer constituting the i) acryl resin based on 100 parts by weight of the acryl resin, a retardation film, and an electronic device including the same.Type: ApplicationFiled: September 19, 2008Publication date: August 12, 2010Applicant: LG CHEM, LTD.Inventors: Byoung-II Kang, Chang-Hun Han, Dae-Woo Lee, Jae-Bum Seo, Jung-A Yoo, Song-Taek Oh
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Publication number: 20100174036Abstract: Disclosed is a method for preparing polyolefin-based adhesives. In the method, a maleated polyolefin is blended, in sequence, with a polyolefin elastomer and then with a linear low density polyethylene. The polyolefin-based adhesive made according to the method of the invention shows improved clarity and adhesion in multilayer polyolefin films.Type: ApplicationFiled: January 8, 2009Publication date: July 8, 2010Inventors: Chun D. Lee, Maged G. Botros, Charles S. Holland
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Patent number: 7741407Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.Type: GrantFiled: December 13, 2006Date of Patent: June 22, 2010Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
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Publication number: 20100098935Abstract: This invention comprises a film useful as an adhesive, a composition useful to make the film, and a laminate comprising the film contiguous with at least one metal substrate, at least one foam substrate or combination thereof. The composition comprises (a) at least one anhydride grafted olefin polymer, (b) at least one high density polyethylene, and (c) at least one elastomer which preferably has a tensile elongation at break of at least about 585%, a density of at most about 0.900 g/cm3 or a combination thereof. The anhydride grafted olefin polymer or combination thereof is preferably present in an amount of from about 20 to about 40 weight percent, the high density polyethylene or combination thereof is preferably present in an amount of from about 40 to about 60 weight percent, and the elastomer or combination thereof is preferably present in an amount of from about 17 to about 30 weight percent.Type: ApplicationFiled: October 16, 2007Publication date: April 22, 2010Inventors: Robert L. McGee, Julie R. Hatlewick
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Patent number: 7700689Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.Type: GrantFiled: May 31, 2006Date of Patent: April 20, 2010Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 7670523Abstract: Regrind is mixed with at least one low density metallocene polyethylene to increase the amount of regrind that can be used in a thermoformed article.Type: GrantFiled: January 25, 2007Date of Patent: March 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Anthony Poloso, Allen T Mika
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Patent number: 7645832Abstract: A thermoplastic elastomer having adhesion to steels, where the thermoplastic elastomer includes a dynamically crosslinked rubber, from more than 2.0 to 10 parts of a metal oxide or salt, and from 10 to 200 parts by weight of a functionalized polyolefin having pendant polar functional groups, where the polar functional groups are present at a level of 0.5 to 3.5 mole percent of the total repeating units of said functionalized polyolefin and the functionalized polyolefin is derived from polymerizing at least one monoolefin to form a semicrystalline polymer or is derived from hydrogenating the polydiene blocks of a block copolymer, and where the parts by weight are based on 100 parts by weight of crosslinked rubber.Type: GrantFiled: March 8, 2006Date of Patent: January 12, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiguo Hu, Jim Lee Johnson
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Patent number: 7625961Abstract: The present invention relates to a composition, which can be referred to as a biopolymer, including fermentation solid and thermoactive material. The present invention also includes methods of making the biopolymer, which can include compounding fermentation solid and thermoactive material. The present biopolymer can be formed into an article of manufacture.Type: GrantFiled: June 14, 2004Date of Patent: December 1, 2009Assignee: POET Research, Inc.Inventor: Michael J. Riebel
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Patent number: 7528194Abstract: The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.Type: GrantFiled: February 2, 2004Date of Patent: May 5, 2009Assignee: Ciba Specialty Chemicals Corp.Inventors: Jochen Fink, Michael Roth, Rudolf Pfaendner
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Publication number: 20090111942Abstract: Disclosed are methods for making a surface modified biomedical device involving (a) exposing a biomedical device having a plurality of biomedical device surface functional groups to one or more ethylenically unsaturated-containing organic compounds having a reactive group that is co-reactive to the biomedical device surface functional groups of the biomedical device; and (b) graft polymerizing a hydrophilic reactive monomer having a complementary reactive functionality with the ethylenically unsaturated functionalities of the ethylenically unsaturated-containing organic compounds on or near the surface of the biomedical device thus forming a biocompatible surface on the biomedical device. The methods disclosed are two-step methods and do not include any additional surface treatment steps.Type: ApplicationFiled: October 25, 2007Publication date: April 30, 2009Applicant: BAUSCH & LOMB INCORPORATEDInventors: Weihong Lang, Yu-Chin Lai, Daniel J. Hook
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Publication number: 20090035594Abstract: Rheologically-modified functionalized polyolefins and tie-layer adhesive blends formulated therewith which exhibit improved adhesion in multi-layer barrier films are provided. Multi-layer barrier shrink films having improved adhesion are also disclosed.Type: ApplicationFiled: August 1, 2007Publication date: February 5, 2009Inventors: Chun D. Lee, Maged G. Botros
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Publication number: 20080234433Abstract: Methods of preparing a graft copolymer comprising a plurality of different grafts wherein the methods employ an epoxide macroinitiator and an early transition metal radical ring opening catalyst without the need for any epoxide protection/deprotection steps. Such a process results in graft copolymers having complex polymer architectures.Type: ApplicationFiled: March 21, 2008Publication date: September 25, 2008Inventor: Alexandru Dragos Asandei
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Patent number: 7304111Abstract: A problem of the invention is to provide a propylene copolymer which is excellent in adhesion to crystalline propylene-based polymers and which is excellent in solubility and compatibility with polar resins, a process for producing the same, and a composition containing the subject polypropylene copolymer. The invention is concerned with a polypropylene copolymer, which is characterized by having a polymer principal chain (A) derived from a propylene-based polymer having (1) a prescribed requirement as defined by the 13C-NMR spectral measurement and having (2) a melting point [Tm] by a differential scanning calorimeter of not higher than 100° C., or a crystal melting heat of less than 5 J/g; and a side chain containing a polymer chain (B) which is different from the principal chain, with a weight ratio of (A)/(B) being in the range of from 20/1 to 1/20, a composition containing the subject copolymer, and a process for producing the subject copolymer.Type: GrantFiled: August 22, 2005Date of Patent: December 4, 2007Assignee: Mitsubishi Chemical CorporationInventors: Masato Onoe, Kazuyuki Hata
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Patent number: 7300978Abstract: This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.Type: GrantFiled: February 23, 2004Date of Patent: November 27, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann, Samuel Evans, Alfred Steinmann
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Patent number: 7279528Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.Type: GrantFiled: September 19, 2002Date of Patent: October 9, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Anne Vera Macedo, Kenneth Lewias, John Richard Shutt
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Patent number: 7276557Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.Type: GrantFiled: September 19, 2002Date of Patent: October 2, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Anne Vera Macedo, Kenneth Lewtas, John Richard Shutt
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Patent number: 7267887Abstract: A shaped composite article comprising a substrate and an adherend, which are comprised of different materials and are bonded together through a layer of an adhesive composition comprising as the main ingredient (i) a cyclic structure-containing conjugated diene polymer having a degree of cyclization of 30-95%, or (ii) a modified cyclic structure-containing conjugated diene polymer having a degree of cyclization of 30-95%, and having added thereto 0.1-20 wt. % of an ?,?-ethylenically unsaturated carboxylic acid anhydride, wherein the ratio of {amount of (I)/[amount of (I)+amount of (II)]} is at least 60 wt. %, where (I) is an acid anhydride group added and (II) is a dicarboxylic acid group formed by hydrolysis of an acid anhydride group (I).Type: GrantFiled: October 16, 2002Date of Patent: September 11, 2007Assignee: Zeon CorporationInventors: Shizuo Kitahara, Yasushi Tanaka, Atsushi Hayashi
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Patent number: 7223814Abstract: An adhesive composition is provided comprising at least one copolymer comprising repeating units from ethylene and at least one ?-olefin, at least one tackifier resin, and at least one grafted polyolefin; wherein said adhesive composition has an onset of fiber tear of less than about 35° F. Articles and processes for producing the adhesive composition is also provided.Type: GrantFiled: November 17, 2003Date of Patent: May 29, 2007Assignee: Eastman Chemical CompanyInventors: Laura Lee Martin, Stephen Dale Orth