Mixture Contains Solid Polymer Derived From Reactant Containing Ether Or Hydroxyl Group Patents (Class 525/79)
  • Patent number: 4600747
    Abstract: ABS-moulding compositions consisting of a thermoplastic copolymer and a graft polymer with rubber-like graft base exhibit an improved flame resistance if the total mixture contains a compound corresponding to the formulae ##STR1## polymerized into one or both components, wherein R.sub.1 represents C.sub.2 -C.sub.6 -alkylene,R.sub.2 represents hydrogen or methyl,R.sub.3 represents a direct bond or C.sub.1 -C.sub.4 -alkylene, andR.sub.4 represents hydrogen, methyl or CH.sub.2 --OOC--CH.sub.2 --CO--CH.sub.3.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: July 15, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Zabrocki, Christian Lindner, Friedmann Muller, Joachim Doring
  • Patent number: 4555546
    Abstract: Compatibilized polymer blends are described comprising a blend of olefin polymer, cross-linkable acrylic ester copolymer rubber, and a compatibilizing amount of a graft copolymer comprising acrylic ester copolymer compatibilizing segments and olefin polymer compatibilizing segments.
    Type: Grant
    Filed: November 27, 1984
    Date of Patent: November 26, 1985
    Assignee: Monsanto Company
    Inventor: Raman Patel
  • Patent number: 4542179
    Abstract: The addition of styrene-acrylonitrile copolymer to acrylic core-shell thermoplastic elastomers reduces mold shrinkage and improves surface hardness. The compositions are useful as moldable and extrudable rubber goods.
    Type: Grant
    Filed: September 24, 1984
    Date of Patent: September 17, 1985
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: John C. Falk, Leland B. Kliever
  • Patent number: 4533698
    Abstract: A thermoplastic resin composition consists essentially of (A) 100 parts by weight of a rubber-containing styrene type resin and (B) 1 to 45 parts by weight of a polymeric substance selected from the group consisting of a homopolymer of an acrylic acid ester, copolymers of an acrylic acid ester, and a mixture of these polymers, said component (B) having a solubility parameter of from 8.4 to 9.8 (cal/c.c.).sup.1/2, a glass transition temperature of 20.degree. C. or below, a gel content of 70% by weight or below, and relative viscosity of a substance soluble in methylethyl ketone of 20 or below.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: August 6, 1985
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tetsuro Maeda, Akihiro Okamoto, Yoshimitsu Shimizu, Takashi Nomoto
  • Patent number: 4530957
    Abstract: Crosslinked, preferably acrylic, preferably melamine crosslinked, polymer particles formed by reactions comprising free radical addition polymerization of:(a) between about 0.5 and about 20 weight percent each of first and second monomers, each bearing functionally capable of crosslinking reaction with the other and additionally wherein the first monomer is ethylenically unsaturated and the second monomer bears multiple crosslinking functionality and no ethylenic unsaturation,(b) between about 60 and about 99 weight percent of at least one other monoethylenically unsaturated monomer;in the presence of (I) an organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer, and (II) polymeric dispersion stabilizer wherein the precursor of the first segment of the stabilizer comprises a long chain hydrocarbon molecule having only one reactive group per molecule, preferably being a carboxyl group.
    Type: Grant
    Filed: January 5, 1983
    Date of Patent: July 23, 1985
    Assignee: Ford Motor Company
    Inventors: Ares N. Theodore, Mohinder S. Chattha
  • Patent number: 4518743
    Abstract: This invention relates to thermoplastic moulding compositions of vinyl chloride polymers, certain ABS-copolymers, certain resin-like copolymers, certain acrylate copolymers and, optionally, diene copolymers for the production of films having improved resistance to ageing.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: May 21, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Karl-Heinz Ott, Walter Uerdingen, Hans-Eberhard Braese, Helmut Hurnik
  • Patent number: 4518515
    Abstract: This invention relates to thermoplastic moulding compositions of vinyl chloride polymers, certain graft polymers, certain resin-like copolymer additives and certain rubber-like copolymers for the production of films having improved resistance to ageing.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: May 21, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Ott, Christian Lindner, Walter Uerdingen, Hans-Eberhard Braese, Helmut Hurnik
  • Patent number: 4480069
    Abstract: Crosslinked, preferably acrylic, polymer particles characterized in that the particles formed by free radical addition polymerization of:(a) between about 0.8 and about 20 weight percent each of first and second ethylenically saturated monomers each bearing functionality capable of crosslinking reaction with the other; and(b) between about 98.
    Type: Grant
    Filed: January 5, 1983
    Date of Patent: October 30, 1984
    Assignee: Ford Motor Company
    Inventors: Ares N. Theodore, Mohinder S. Chattha
  • Patent number: 4384078
    Abstract: A graft copolymer is obtained by graft-polmerizing a vinyl or vinylidene monomer onto a rubber trunk polymer which comprises a polyalkylene oxide monomer comprising 4 to 500 alkylene oxide groups together with an ethylenic unsaturation, and a conjugated diene and/or an alkyl acrylate.This graft copolymer alone or in a mixture thereof with another thermoplastic resin, because of the presence of the polyalkylene oxide monomer unit incorporated in the rubber trunk polymer, provides a resin composition possessing excellent antistatic property, which, practically, is not lowered by washing.
    Type: Grant
    Filed: June 30, 1981
    Date of Patent: May 17, 1983
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masaki Ohya, Akio Kobayashi, Takeo Ogiwara, Yoshikatsu Satake
  • Patent number: 4352910
    Abstract: As an impact modifier copolymer to be blended with a vinyl chloride resin, a multilayer copolymer comprising a hard core polymer containing a relatively small quantity of a conjugated diene, a rubbery inner layer polymer containing a relatively large quantity of a conjugated diene, and an outer layer polymer comprising, for example, a copolymer of styrene and methyl methacrylate which is compatible with a vinyl chloride resin is used, whereby a vinyl chloride resin composition well balanced between impact strength and anti-stress-whitening property can be obtained.
    Type: Grant
    Filed: October 20, 1981
    Date of Patent: October 5, 1982
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takayuki Katto, Zenya Shiiki
  • Patent number: 4332919
    Abstract: A multiply grafted copolymer is obtained by graft-polymerizing onto non-elastic trunk polymer particles (a) a monomer mixture (b) comprising an elasticity-imparting monomer selected from conjugated dienes and acrylates, a polyalkylene oxide monomer comprising 4 to 500 alkylene oxide groups together with a terminal double bond and an optional ethylenically unsaturated monomer, and an ethylenically unsaturated monomer (c) in order. An antistatic resin composition comprising this multiply grafted copolymer alone or a mixture of this copolymer and a thermoplastic resin compatible therewith can utilize the rubbery polymer component (b) more effectively than an antistatic resin composition comprising a graft copolymer obtained by graft-polymerizing an ethylenically unsaturated monomer (c) onto a trunk polymer comprising a mere copolymer of a monomer mixture (b), and thus can provide an improved antistatic effect.
    Type: Grant
    Filed: June 2, 1981
    Date of Patent: June 1, 1982
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Akio Kobayashi, Takeo Ogihara
  • Patent number: 4287316
    Abstract: A transparent resin composition comprising (1) 6 to 100% by weight of a nitrile graft copolymer comprising a rubber trunk polymer and a branch polymer grafted thereon, which has been obtained by graft-polymerizing onto the rubber trunk polymer a monomer mixture containing an unsaturated nitrile and a monomer copolymerizable therewith, and (2) 0 to 94% by weight of a random copolymer of an unsaturated nitrile and a monomer copolymerizable therewith, the resin components of the resin composition other than the rubber trunk polymer constituting a matrix resin, wherein(a) said rubber trunk polymer has a glass transition temperature of not higher than 0.degree. C. and constitutes 4 to 25% by weight of the resin composition,(b) the unsaturated nitrile constitutes 25 to 90% by weight of the matrix resin in the resin composition,(c) the difference in the refractive indexes between the rubber trunk polymer and the matrix resin is not more than 0.
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: September 1, 1981
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Akira Kaneko, Masaki Ohya, Masayasu Suzuki, Akio Kobayashi
  • Patent number: 4267282
    Abstract: In the process of melting a blend of nitrile polymer and lubricous additive with a screw-plasticizing unit, the improvement which involves having an absorptive anti-slip agent such as rubber crumb in admixture with the blend when charging the plasticator to minimize feeding problems.
    Type: Grant
    Filed: September 18, 1978
    Date of Patent: May 12, 1981
    Assignee: Monsanto Company
    Inventor: Edward F. Tokas
  • Patent number: 4260701
    Abstract: Improved composition for a fingernail coating having an acrylic binder, a peroxide catalyst, a tertiary amine accelerator, and a polymeric filler at least partially soluble in the coating. The acrylic binder contains a monoethylenically unsaturated monomer comprising at least a major proportion of methoxyethyl methacrylate. A polyfunctional monomer may be present that copolymerizes with the monoethylenically unsaturated monomer, for crosslinking and toughening.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: April 7, 1981
    Assignee: Lee Pharmaceuticals
    Inventor: Henry L. Lee, Jr.
  • Patent number: 4243769
    Abstract: Compatibilized blends and composites of materials containing nitrile functionality with materials normally incompatible therewith are formed by mixing the components in the presence of an acid compatibilizing agent.
    Type: Grant
    Filed: October 4, 1977
    Date of Patent: January 6, 1981
    Assignee: National Distillers and Chemical Corp.
    Inventor: Ervin G. Pritchett
  • Patent number: 4237037
    Abstract: A powder coating composition comprising(A) 70 to 97% by weight of an ethylene resin mixture composed of(A-1) an ethylene copolymer having a melt index of 1 to 50 and containing at least one comonomer selected from the group consisting of alpha-olefins other than ethylene, dienes, vinyl acetate, vinyl alcohol, acrylic acid, functional derivatives of acrylic acid, methacrylic acid and functional derivatives of methacrylic acid, and(A-2) a graft copolymer of polyethylene having grafted thereto an unsaturated carboxylic component, the amount of said unsaturated carboxylic component being 0.001 to 2% based on the weight of the ethylene resin mixture (A), and(B) 3 to 30% by weight of a hydrocarbon wax having a number average molecular weight of about 400 to about 3,000 and a density of not less than 0.9 g/cm.sup.3, said wax having an acid value of up to about 5 when it is a modified wax.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: December 2, 1980
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventor: Takao Takahashi
  • Patent number: 4229549
    Abstract: An alkyl acrylate copolymer comprises 60 to 99.5 wt. % of a C.sub.2 -C.sub.12 alkyl acrylate component, 0.1 to 10 wt. % of a polyfunctional monomer component having one or more conjugated double bond and one or more non-conjugated double bond and 0 to 35 wt. % of a comonomer component. A thermoplastic resin composition comprises 97 to 70 wt. parts of a rigid thermoplastic resin and 3 to 30 wt. parts of the alkyl acrylate copolymer.
    Type: Grant
    Filed: March 22, 1978
    Date of Patent: October 21, 1980
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Seiji Usami, Masanori Oota, Hitoshi Takita, Hideyuki Hashizume
  • Patent number: 4206290
    Abstract: A resinous composition having fire retardance, impact resistance and easy workability is obtained by blending (1) about 80 to 30 parts by weight of an ABS resin with (2) about 20 to 70 parts by weight of (i) a vinyl chloride resin compound comprising 100 to 5 parts by weight of a copolymer resin consisting essentially of 0.5 to 40% by weight of a higher alkyl vinyl ether and 99.5 to 60% by weight of vinyl chloride and (ii) 0 to 95 parts by weight of a polyvinyl chloride resin.
    Type: Grant
    Filed: August 11, 1978
    Date of Patent: June 3, 1980
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Haruhiko Yusa, Masanori Oota, Kazuo Takahashi, Humio Akutsu