Abstract: An actinic radiation-curable, rust-preventive coating composition suitable for use in temporary protection of steel products from rusting and having improved rust preventing property even in the presence of oil on the steel surface is disclosed. The coating composition comprises: (A) from 10 to 50 parts by weight of a vinyl polymer having a glass transition temperature of not lower than 5.degree. C. and a solubility parameter in the range of 9 to 11.5; (B) from 50 to 90 parts by weight of one or more polymerizable compounds having at least one unsaturated group capable of initiating reaction by actinic radiation; and (C) from 0.1 to 20 parts by weight of an organic phosphate of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; Y is a straight or branched chain alkylene having 2 to 20 carbon atoms which may be interrupted by one or more ester or oxy linkages and/or aromatic rings; and n is an integer of 1 to 3.

Abstract: The present invention relates to compounds of the general formula I ##STR1## in which R.sup.1, R.sup.1', R.sup.2, A and n are as defined in the description, a process for their preparation, their use and also hydrogels prepared using them.

Abstract: Alkenylphosphonic and -phosphinic acid esters of 1,1,1-tris(hydroxymethyl)alkanes and of 2,2-bis-hydroxymethyl-1,3-propanediol are useful as cross-linking agents in polymeric hydrogels.

Abstract: A polymer for use as a deflocculant in drilling muds comprising at least one unsaturated carboxylic acid or its anhydride or salt, at least one unsaturated sulfonic acid or its salt, at least one unsaturated cationic-containing monomer, and optionally, one or more unsaturated non-ionic monomer and/or one mono or di phosphate ester of an unsaturated alcohol.

Abstract: A terpolymer mixture having emulsifying and emulsion stabilizing properties comprising a mixture of (1) a water soluble vinyl monomer, (2) a water insoluble vinyl monomer having 12 to 30 carbon atoms and (3) a polymerizable vinyl monomer containing acid groups. The terpolymer may be used in combination with oil and water to form stable oil-in-water emulsions or in enhanced oil recovery procedures.

Abstract: This invention relates to novel polymer compositions which are useful for water treatment. These novel compostions are comprised of polymers of -60 ,.beta. ethylenically unsaturated monomer(s), preferably containing carboxylic acid or carboxylic amide functionalities, and amine-containing allyl ether monomers.

Abstract: The present invention provides the polymer particles prepared by polymerizing monomer components which comprise as at least a part of polymerizable components a monomer of the formula (I): ##STR1## , wherein R is hydrogen atom or methyl group, n is a number of from 0 to 30 and m is a number of from 0 to 30 provided that m+n.gtoreq.1 and a process for preparing the polymer particles.

Abstract: Acrylic polymers with carboxylic acid and small amounts of phosphorus-containing strong acids are good pigment dispersants for use in water-based coating compositions.

Abstract: Phosphonium mordanting polymer, that is capable of fixing acid dyes and that comprises randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer capable of quenching singlet oxygen e.g. N-vinylimidazole or 2-methyl-1-vinylimidazole;B represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile or methacrylonitrile;n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group e.g. n-butyl, a substituted C.sub.1 -C.sub.8 alkyl group e.g. a methylol group, a cyanoethyl group or an aralkyl group, a cycloalkyl group, an aryl group e.g. phenyl, or a substituted aryl group;X.sup.- represents an acid anion e.g. a halogen anion e.g. Cl.sup.-, Br.sup.- or I.sup.-, or an anion derived from an inorganic acid e.g. NO.sub.3.sup.-, HSO.sub.4.sup.-, SO.sub.4.sup.--, H.sub.2 PO.sub.4.sup.

Abstract: A copolymer useful for magnetic paints is provided which is composed of (1) at least 60% by weight of vinyl chloride units, (2) 0.1 to 4.0% by weight, as a sulfur- or phosphorus-containing strong acid group, of strong acid group-containing monomer units (3) at least 0.1% by weight, as the hydroxyl groups, of units of a monomer which gives a side chain represented by the formula --X--OH wherein X is an organic group, and (4) 0 to 20% by weight of units of another monomer.

Abstract: Novel water soluble polymers containing an hydroxyl alkyl aminoalkylene phosphonate functionality are disclosed. These polymers have utility as deposit control agents effective in a number of water systems such as cooling, boilers conversion coating, paper and pulp processing and gas scrubbing.The polymers are formed from the polymerization of ethylenically unsaturated compounds with a compound having the structure: ##STR1## in which R.sub.1 is an hydroxyl substituted or nonsubstituted lower alkylene group, R.sub.2 is H or lower alkyl group, R.sub.3 is a lower alkylene group and M is H or water soluble cation.

Abstract: New composition of polymers and methods of use are disclosed. The polymers are water soluble and are composed of repeat units formed from an .alpha., .beta. ethylenically unsaturated compound, and repeat units formed from allyl alkylene phosphonates.

Abstract: Disclosed are nadimido-substituted cyclophosphazene derivatives and thermosets thereof. The thermosets are useful as high temperature, flame resistant matrices for composites and as metal adhesives.

Abstract: Disclosed are nadimido-substituted cyclophosphazene derivatives and thermosets thereof. The thermosets are useful as high temperature, flame resistant matrices for composites and as metal adhesives.

Abstract: A water thickening terpolymer of polymerized units of (A) about 50 to 98 mole percent of acrylamide, (B) about 1.9 to 49.9 mole percent of an alkali metal salt or ammonium salt of acrylic acid, and (C) about 0.1 to 5 mole percent of a copolymerizable ionic surfactant containing (1) an acrylyl or methacrylyl group, (2) a pendant hydrophobic group of 6 to 24 carbon atoms, and (3) an ionic polar group.

Abstract: Alpha-aminoethylene phosphonate betaines of the formula ##STR1## R.sup.1 is hydrogen or methyl; X is ##STR2## a is 0, 1, 2 or 3, with the condition that when X is ##STR3## that a be greater than 1; R.sup.2 and R.sup.3 are independently C.sub.1 -C.sub.6 alkyl, aryl, benzyl, or cyclohexyl;Y is hydrogen or hydroxyl;b is 0, 1, 2, or 3;Z is C.sub.1 -C.sub.6 alkyl, aryl, benzyl, cyclohexyl, or ##STR4## and M is hydrogen, metallic cation, or ammonium ion are disclosed as are homo- and copolymers thereof.

Abstract: Process for the preparation of polymers of vinylphosphonic acid in water with the aid of catalysts which form free radicals, which comprises heating vinylphosphonic acid and (meth)acrylic acid to temperatures of 40.degree. to 120.degree. C. in water in the presence of 1 to 5.5% by weight of aliphatic peroxy esters and/or diacyl peroxides which dissociate by half in one hour at temperatures below 122.degree. C., the total amount of vinylphosphonic acid being taken together with up to 30% by weight, based on the total amount of monomer, of (meth)acrylic acid and the remainder of the (meth)acrylic acid being added in the course of the reaction.The copolymers are suitable for use in detergent and cleaning agents.

Abstract: Pulverulent crosslinked copolymers are prepared by polymerizing monomer mixtures consisting of(a) from 70 to 99.99% by weight of monoethylenically unsaturated carboxylic acids, their amides and/or esters of such carboxylic acids and aminoalcohols,(b) from 0.001 to 10% by weight of a diethylenically or polyethylenically unsaturated monomer and(c) from 0 to 20% by weight of other monoethylenically unsaturated monomersin supercritical carbon dioxide under superatmospheric pressure in the presence of a free radical initiator.

Abstract: Water-soluble copolymers containing a statistical distribution of 1-86% by weight of structural units of the formula ##STR1## 9-80% by weight of units of the formula ##STR2## 5-90% by weight of units of the formula ##STR3## and up to a total of 30% by weight of one or more units of the formulae ##STR4## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms;R.sup.2 and R.sup.5 independently of one another are each hydrogen or methyl;R.sup.3 and R.sup.4 independently of one another are each hydrogen, methyl or ethyl, or together R.sup.3 and R.sup.4 are trimethylene or pentamethylene;Y is a direct bond, phenylene or a moiety of the formula --CO--NH--C(CH.sub.3).sub.2 --CH.sub.2 --;X.sym. is H.sym. or a cation;and said copolymers are useful as dyestuff auxiliaries and leather retanning agents.

Abstract: Adhesion promoters for metal substrates for paints cross-linkable with U.V. or E.B. radiations or with peroxides of general formula: ##STR1## (wherein R, m and n have the meaning which we will specify in the disclosure), obtained by means of the reaction of glycidyl acrylate and/or glycidyl methacrylate with dihydrophosphonoacetic acid.

Abstract: A highly adherent photopolymerizable composition comprises a (hydroxy)phosphinylalkyl monomer of the formula ##STR1## wherein R is hydrogen, methyl or ethyl and R' and R" are selected independently from hydrogen and alkyl of 1-10 carbon atoms; at least one copolymerizable ethylenically unsaturated monomer and a photoinitiator.

Abstract: Alpha-aminoethylene phosphonate betaines of the formula ##STR1## R.sup.1 is hydrogen or methyl; X is ##STR2## or CH.sub.2 ; a is 0, 1, 2, or 3, with the condition that when X is ##STR3## that a be greater than 1; R.sup.2 and R.sup.3 are independently C.sub.1 -C.sub.6 alkyl, aryl, benzyl, or cyclohexyl;Y is hydrogen or hydroxyl;b is 0, 1, 2, or 3;Z is C.sub.1 -C.sub.6 alkyl, aryl, benzyl, cyclohexyl, or ##STR4## and M is hydrogen, metallic cation, or ammonium ion are disclosed as are homo- and copolymers thereof.

Abstract: Process for the preparation of polymers of vinylphosphonic acid in protic diluents with the aid of catalysts which form free radicals, which comprises heating vinylphosphonic acid at temperatures of 40.degree. to 130.degree. C. in a total of 10 to 150% by weight of protic diluents for a total of 4-60 hours in the presence of 1.0 to 5.5% by weight of aliphatic peroxy-esters, diacyl peroxides and/or aliphatic azo compounds which decompose by half in one hour at temperatures below 122.degree. C.

Abstract: New cotelomer compounds having the formula I ##STR1## and salts thereof wherein A is a random polymeric residue comprising at least one unit of formula II ##STR2## and at least one unit of formula III, different from a unit of formula II, ##STR3## and B is hydrogen or a residue A; wherein m and n are integers such that the sum of m+n is an integer of from 3 to 100, the ratio of n:m being from 99 to 1:1 to 99, provided that the resulting telomers are water-soluble and wherein m and/or n in a residue A may be the same as or different from m and/or n in a residue B; R is hydrogen, methyl or ethyl;R.sub.1 is a residue -OX, wherein X is hydrogen, an alkali- or alkaline earth metal, ammonium or an amine residue;R.sub.2 is hydrogen, methyl or a residue --CO.sub.2 R.sub.5, wherein R.sub.5 is hydrogen or a straight- or branched chain alkyl residue having 1 to 8 carbon atoms;R.sub.3 is hydrogen, a straight- or branched chain alkyl residue having 1 to 4 carbon atoms, hydroxymethyl or a residue --CO.sub.2 R.sub.

Abstract: Flame retardant alkenyl aromatic compounds which are vinylbenzyl diaryl phosphine oxides and a method for their preparation are described. They may be polymerized into higher molecular weight flame retardant materials which, in turn, may be admixed with polyphenylene ether resins to form thermoplastic flame resistant molding compositions. The present materials are more resistant to losses in the flame retardancy upon thermal processing, e.g., molding, because the active flame retardant agent, phosphorus, is chemically bound to the polymeric matrix.

Abstract: A high temperature, pressurized process is described to synthesize phosphonated acrylamide polymers represented by the structure: ##STR1## wherein X is from the group H, OR, Cl, Br, I, --COOM, --SO.sub.3 M, ##STR2## and mixtures thereof.

Abstract: A process for the preparation of a thermoset polymer having good adhesive properties comprising reacting a compound containing a plurality of oxazoline groups with an alkenyl phosphonic acid at a temperature of from about room temperature to about 300.degree. C. is described.

Abstract: The invention is (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof.In another aspect, the invention is a polymeric composition which comprises the reaction product of:(a) between about 0.5 and 100 percent by weight of a (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof; and(b) between about 0 and 99.5 weight percent of a compound containing a polymerizable 1,2-ethylenically unsaturated moiety.

Abstract: A dispersion stabilizer for dispersing solid particles into a liquid medium, which comprises resin particles bearing a zwitter-ionic group in the molecule, said resin particles each having substantially an average particle size of not more than 1500 .ANG. when measured by electron microscopic observation.

Abstract: An adhesive composition comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 50 parts by weight of a compound represented by general formula I or II: ##STR1## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR2## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, and optionally replaced by a halogen atom, or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R.sub.4 ' (when b is 2 or 3) being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least three carbon atoms, and (b) 50 to 98.5 parts by weight of a vinyl monomer copolymerizable with the above compound; and 0.01 to 20 parts by weight of a curing agent.

Abstract: Copolymers of a predominant proportion of an alkyl allyl ammonium halide and a vinyl phosphonic acid, optionally with other copolymerizable vinylidene monomers, form aqueous acid gel compositions when added to the aqueous acid, along with a gelling agent selected from titanium or zirconium compounds, and gel destabilizing compounds containing fluoride, sulphate or phosphate anions, the apparent viscosity and time of stability of the acid gel composition being controlled by the addition of these ingredients. These acid gels are particularly effective as fracture-acidizing fluids in deep, hot oil or gas well stimulation.

Abstract: Curable bisimide resin compositions containing 4,4'-bismaleimidodiphenylmethane, 1 to 20% of a compound of formula I ##STR1## and optionally 2 to 20% of a compound of formula II ##STR2## may be used in solution or as melts to produce fibre-reinforced resins.

Abstract: A radiation curable pressure-sensitive adhesive composition comprising 100 parts by weight of a liquid oligomer having one or more acrylic unsaturated double bonds in its molecule, 0.2 to 20 parts by weight of a thiol compound and 0.5 to 30 parts by weight of acrylic monomer has high cohesion and is excellent in adhesiveness.

Abstract: Crosslinked copolymers wherein crosslinking is effected with crosslinking bridge members of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another are each hydrogen or alkyl with 1 to 4 carbon atoms and m represents a number from 0 to 6 are prepared by copolymerization of monomers with vinylphosphonic acid (ester)-anhydrides and the new crosslinked polymers according to the invention are suitable for the preparation of acid-soluble coatings and encapsulation materials.

Abstract: Novel organophosphates of the general formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents H or CH.sub.3, m is a numeral of 1-5 and n is a numeral of 1-2, and adhesives comprising them.

Abstract: The invention relates to processes for the synthesis of tertiary phosphine oxides and sulfides.The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group.Tertiary phosphine oxides and sulfides are complexing agents of high stability.

Abstract: The char residue formation of molded compositions, upon combustion, is improved by incorporating into the moldable composition a char-forming polymer containing recurring units of at least one monomer capable of undergoing tautomerization, at least one monomer capable of undergoing a nucleophilic substitution reaction by said monomer capable of undergoing tautomerization and, optionally, at least one additional copolymerizable monomer.

Abstract: Film forming compositions are disclosed which can be utilized to make vapor barrier films having low water vapor transmission, good flame retardancy and low smoke generation characteristics. The compositions of the present invention contain an internally plasticized vinyl chloride copolymer resin as a major polymer component, rather than an externally plasticized vinyl chloride polymer, or a blend of a vinyl chloride polymer and chlorinated polyethylene.

Abstract: Dental liner and primer compositions having improved adhesion to dentin and containing a metal dissolved in a polar organic solvent, said metal being selected from Fe, Cu, Mn, Co, Sn, Cr, Ni, and Zn.

Abstract: This invention provides an adhesive composition which comprises 1 part by weight of (a) a compound of the general formula: ##STR1## wherein R.sub.1 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, COOR', wherein R' represents a hydrocarbon group of 1-20 carbon atoms optionally containing halogen or halogen;R.sub.2 is as defined for R.sub.1 ;R.sub.3 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, halogen or CN;R.sub.4 represents (COX.sub.2).sub.m1 (CO).sub.m2 (ZCO).sub.m3 (Z).sub.m4 Ra wherein Ra represents an organic residue of 6-60 carbon atoms and a valency of m+n ; m1, m2, m3 and m4 each represents an integer of 0-4 and satisfies m1+m2+m3+m4.ltoreq.m; X.sub.2 represents O, S or NRb, (wherein Rb represents H or alkyl of 1-4 carbon atoms and Z represents O or S;X.sub.1 is as defined for X.sub.

Abstract: "Living" polymers and their preparation from acrylic-type or maleimide monomers and organosilicon, -tin or -germanium initiators.

Abstract: Metal chelates of water soluble copolymers with polyvalent metal ions contain a statistical distribution of 1-86% by weight of structural units of the formula ##STR1## 9-80% by weight of units of the formula ##STR2## 5-90% by weight of units of the formula ##STR3## and up to 30% by weight of one or more units of the formulae ##STR4## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms; R.sup.2 and R.sup.5 independently of one another are each hydrogen or methyl;R.sup.3 and R.sup.4 independently of one another are each hydrogen, methyl or ethyl or together are a trimethylene or pentamethylene;Y is a direct bond, phenylene or a moiety of the formula --CO--NH--C(CH.sub.3).sub.2 --CH.sub.2 --; andX.sup..sym. is a cation or H.sup..crclbar.

Abstract: This invention provides an adhesive composition which comprises 1 part by weight of (a) a compound of the general formula: ##STR1## wherein R.sub.1 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, COOR' wherein R' represents a hydrocarbon group of 1-20 carbon atoms optionally containing halogen or halogen:R.sub.2 is as defined for R.sub.1 ;R.sub.3 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, halogen or CN;R.sub.4 represents (COX.sub.2).sub.m1 (CO).sub.m2 (ZCO).sub.m3 (Z).sub.m4 Ra wherein Ra represents an organic residue of 6-60 carbon atoms and a valency of m+n; m1, m2, m3 and m4 each represents an integer of 0-4 and satisfies m1+m2+m3+m4.ltoreq.m, X.sub.2 ; represents O, S or NRb, wherein Rb represents H or alkyl of 1-4 carbon atoms and Z represents O or S;X.sub.1 is as defined for X.sub.

Abstract: A self-curing water dispersed emulsion or solution polymerized polymer comprises copolymerizing ethylenically unsaturated monomers including (i) alkylol acrylamide monomer, (ii) functional monomer such as carboxyl, hydroxyl, amine, or amide functional monomer, (iii) phosphated monomer, and (iv) other ethylenically unsaturated monomer.

Abstract: A mixture consisting of a polymaleimide and a copolymerizable monomer or a prepolymer formed from these two compounds contains, as the polymerization catalyst, an ethane which is substituted by aromatic groups and hydroxyl groups or halogen (cf. formula II), such as benzpinacol. The mixture is stable on storage and heat-curable. It can be cured, while at the same time being shaped to give mouldings, sheet-like structures, laminates, adhesive bonds or foams, for example by casting or compression moulding.

Abstract: The invention relates to a new phosphorus-containing polymer, polyvinylmethylphosphinic acid. It is prepared by polymerization, preferably catalytic, of vinylmethylphosphinic acid or a salt thereof. The new polymer possesses valuable properties and is used, in particular, in the production of offset printing plates which have a light-sensitive layer.

Abstract: Copolymers of a mono vinyl-substituted aryl hydrocarbon monomer, an imide derivative of an unsaturated cyclic anhydride and a bis(hydrocarbyl) vinylphosphonate are useful as fire retardant additives.

Abstract: Phosphonopolyester oligomers are prepared from hydroxyalkylated 2,2',-bis(3-allylphenyl-4-hydroxy) alkanes and phosphonyl dihalides. The oligomers are useful in the preparation of polyester resins, epoxy resins, and polyurethanes.

Abstract: A polymer capable of forming an anisotropic melt characterized in that the polymer chain includes residues of cross-linking reactants at a concentration sufficient to give a polymer with a melt viscosity of not greater than 10.sup.7 Nsec/m.sup.2 measured by capillary rheometry at a shear rate of 10.sup.4 N/m.sup.2. The polymers exhibit favorable shear dependent viscosity characteristics in that the viscosity is high under low shear conditions and is low under high shear conditions, as judged by the viscosity characteristics of polymers of the same composition but not containing the residues of cross-linking reactants.

Abstract: An adhesive cementing agent is provided for the hard tissues of the human body, which contains a phosphoric or phosphonic acid ester compound containing at least one polymerizable functional group and either a group of the formula ##STR1## or a group of the formula ##STR2## or a high molecular weight compound obtainable by polymerizing the compound either alone or as a comonomer unit. This adhesive cementing agent has a high affinity for the tooth, bone and other hard tissues of the human body and enjoys prolonged stability in wet environments.