From Aldehyde Monomer Patents (Class 526/315)
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Patent number: 4438239Abstract: A synthetic organic resin is coated with a continuous layer of contiguous, tangential, individual microspheres having a uniform diameter preferably between 100 Angstroms and 2000 Angstroms. The microspheres are an addition polymerized polymer of an unsaturated aldehyde containing 4 to 20 carbon atoms and are covalently bonded to the substrate by means of high energy radiation grafting. The microspheres contain reactive aldehyde groups and can form conjugates with proteins such as enzymes or other aldehyde reactive materials.Type: GrantFiled: March 30, 1981Date of Patent: March 20, 1984Assignee: California Institute of TechnologyInventors: Alan Rembaum, Richard C. K. Yen
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Patent number: 4431787Abstract: Polymerizable acrylic monomers, and anaerobic adhesives which contain such monomers, wherein the acrylic monomers contain internal chain unsaturation in addition to terminal acrylic unsaturation.Type: GrantFiled: May 20, 1981Date of Patent: February 14, 1984Assignee: Eschem Inc.Inventor: Gerhardt P. Werber
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Patent number: 4413070Abstract: Microspheres of acrolein homopolymers and co-polymer with hydrophillic comonomers such as methacrylic acid and/or hydroxyethylmethacrylate are prepared by cobalt gamma irradiation of dilute aqueous solutions of the monomers in presence of suspending agents, especially alkyl sulfates such as sodium dodecyl sulfate. Amine or hydroxyl modification is achieved by forming adducts with diamines or alkanol amines. Carboxyl modification is effected by oxidation with peroxides. Pharmaceuticals or other aldehyde reactive materials can be coupled to the microspheres. The microspheres directly form antibody adducts without agglomeration.Type: GrantFiled: March 30, 1981Date of Patent: November 1, 1983Assignee: California Institute of TechnologyInventor: Alan Rembaum
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Patent number: 4390594Abstract: This invention relates to a novel group of plasticizers for polyvinyl butyral wherein the plasticizer comprises a mixture of at least one triethylene glycol diester of a monocarboxylic acid having a carbon chain comprising 7 or 8 carbon atoms and at least one dialkyl adipate in which the alkyl group contains from 3 to 8 carbon atoms or at least one alkyl alkylaryl adipate.Type: GrantFiled: December 1, 1981Date of Patent: June 28, 1983Assignee: Saint Gobain VitrageInventor: Daniel Dages
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Patent number: 4381367Abstract: Paper sizing agents in the form of an aqueous preparation of maleic acid anhydride copolymers of which the anhydride groups had been reacted either with organic or inorganic bases or with primary-tertiary diamines and the reaction products subsequently reacted with epichlorohydrin or with inorganic or organic acids to form salts, the copolymers being made up of polymerised units of(a) from 5 to 75%, by weight, of an aromatic vinyl compound;(b) from 10 to 75%, by weight, of acrylic and/or methacrylic acid C.sub.1 -C.sub.18 alkyl esters;(c) from 5 to 35%, by weight, of maleic acid anhydride;(d) from 0 to 25%, by weight, of other vinyl monomers; and(e) from 0.1 to 10%, by weight, based on the sum of monomers (a) to (d) (which amounts to 100%, by weight), of an unsaturated aldehyde or of an enol ether derived therefrom.The copolymers are produced by radical polymerisation preferably in the absence of solvents.Type: GrantFiled: December 7, 1981Date of Patent: April 26, 1983Assignee: Bayer AktiengesellschaftInventors: Wulf von Bonin, Peter Mummenhoff, Heinz Baumgen
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Patent number: 4342863Abstract: A plastic lens composed of a cured product of a mixture or a reaction produce of (A) a compound containing at least 2 unsaturated cycloacetal groups per molecule, (B) a compound containing at least 2 mercapto groups per molecule and (D) an aliphatic polyvinyl compound selected from the group consisting of ethylene glycol diacrylate, ethylene glycol dimethacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol tetraacrylate and dipentaerythritol hexaacrylate.Type: GrantFiled: February 12, 1981Date of Patent: August 3, 1982Assignees: Showa Denko K.K., Showa Highpolymer Co., Ltd.Inventors: Yorikatsu Hohokabe, Eiichiro Takiyama
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Patent number: 4322491Abstract: This invention relates to an improvement in a mixture which is polymerizable by radiation and contains, as the essential constituents, (a) a polymeric binder, (b) a polymerization initiator which can be activated by radiation, and (c) a compound of the formula I ##STR1## in which R.sub.1 is a divalent aliphatic group having 1 to 15 carbon atoms which also can be partially replaced by hetero-atoms, a divalent cycloaliphatic group having 3 to 15 carbon atoms, or a mixed aliphatic-aromatic group having 7 to 15 carbon atoms, and A is an electron-attracting radical. The invention also relates to a radiation-sensitive resist material using the improved radiation-polymerizable mixture.Type: GrantFiled: December 24, 1980Date of Patent: March 30, 1982Assignee: Hoechst AktiengesellschaftInventors: Jurgen Sander, Klaus Horn
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Patent number: 4315089Abstract: Abstract of the disclosure: Novel polymers which have K values of from 20 to 140 and which contain structural units of the general formula--CH.sub.2 --C(R.sup.1 A)--where R.sup.1 is H or CH.sub.3 and A is an aromatic radical which contains aldehyde groups and has the formula ##STR1## where R.sup.2 is H, OH, O-alkyl, alkoxyalkyl or O--Si(CH.sub.3).sub.3. The polymers are prepared by polymerizing the corresponding monomers CH.sub.2 .dbd.C(R.sup.1 A) in the presence of free-radical initiators.Type: GrantFiled: November 13, 1979Date of Patent: February 9, 1982Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Guenter Wulff, Ahmed Akelah
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Patent number: 4289865Abstract: Disclosed herein are monomeric compounds having the formula: ##STR1## wherein: R and R.sup.1 are independently hydrogen, halide or alkyl;R.sup.2 and R.sup.3 are independently hydrogen, alkyl, cycloalkyl, aryl or aralkyl;q is 0 or 1; andAr is arylene wherein no more than one of R.sup.2 and R.sup.3 is hydrogen, and a method of preparing same. These monomers can be homopolymerized or copolymerized with one or more other monomers to yield polymers having desirable solubility characteristics. In particular, copolymerizable ethylenically unsaturated monomers can comprise aldehyde-containing vinylaryl ethers to yield crosslinkable polymers useful in relief image materials or as binders in photographic layers.Type: GrantFiled: March 21, 1979Date of Patent: September 15, 1981Assignee: Eastman Kodak CompanyInventors: John C. Wilson, Paul D. Yacobucci
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Patent number: 4276351Abstract: Polyvinyl butyral plasticized with tetraethyleneglycol di-2-ethylhexanoate and laminates thereof with one or more sheets of glass.Type: GrantFiled: June 30, 1980Date of Patent: June 30, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas R. Phillips
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Patent number: 4267091Abstract: Binders which comprise (A) an aqueous emulsion of a copolymer A, having a glass transition temperature of 0-50.degree. C., of monoolefinically unsaturated carboxylic acid esters, with or without styrene, vinyl acetate, vinyl chloride and acrylonitrile, which copolymer contains, as copolymerized units, small amounts of monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids and/or their amides (of which the nitrogen atoms may or may not be alkyl-substituted and/or alkylol-substituted) and small amounts of monomers containing carbonyl groups, (B) from 0.05 to 1 mole, per mole of carbonyl groups present in the copolymer A, of a water-soluble aliphatic dihydrazine compound and (C) from 0 to 0.Type: GrantFiled: April 17, 1979Date of Patent: May 12, 1981Assignee: BASF AktiengesellschaftInventors: Hans J. Geelhaar, Erich Penzel, Gregor Ley
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Patent number: 4259469Abstract: Disclosed herein are monomeric compounds having the formula: ##STR1## wherein: R and R.sup.1 are independently hydrogen, halide or alkyl;R.sup.2 and R.sup.3 are independently hydrogen, alkyl, cycloalkyl, aryl or aralkyl;q is 0 or 1; andAr is arylene, and a method of preparing same.These monomers can be homopolymerized or copolymerized with one or more other monomers to yield polymers having desirable solubility characteristics. In particular, copolymerizable ethylenically unsaturated monomers can comprise aldehyde-containing vinylaryl ethers, to yield crosslinkable polymers useful in relief image materials or as binders in photographic layers.Type: GrantFiled: March 21, 1979Date of Patent: March 31, 1981Assignee: Eastman Kodak CompanyInventors: John C. Wilson, Paul D. Yacobucci
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Patent number: 4230772Abstract: Aqueous, solution or emulsion, and solvent based compositions comprising a crosslinked vinyl addition polymer having methacrylaldimine crosslinking groups are useful as coatings, binders and adhesives. The polymers are prepared from a crosslinkable composition comprising (A) a vinyl addition homopolymer or copolymer of methacrolein and (B) a compound having at least two amine-function groups selected from primary amine and primary amine-generating groups. A method of use is described in which crosslinking is at ambient temperatures.Type: GrantFiled: April 2, 1979Date of Patent: October 28, 1980Assignee: Rohm and Haas CompanyInventors: Graham Swift, Benjamin Bartman, Harry J. Cenci
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Patent number: 4230771Abstract: Laminates of glass and polyvinyl butyral plasticized with tetraethyleneglycol di-n-heptanoate.Type: GrantFiled: August 31, 1979Date of Patent: October 28, 1980Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas R. Phillips
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Patent number: 4225689Abstract: Disclosed herein are monomeric compounds having the formula (I): ##STR1## wherein: R, R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or alkyl having from 1 to 4 carbon atoms;R.sup.4 is arylene having 6 to 18 carbon atoms;m is an integer from 1 to 4; andn is an integer from 0 to 4.These monomers can be homopolymerized or copolymerized with one or more other polymerizable monomers, and can particularly be copolymerized with those monomers having substituents which are susceptible to attack or degradation by a base. The resulting crosslinkable polymers are useful in relief image materials, such as photoresists and lithographic plates.Type: GrantFiled: July 26, 1978Date of Patent: September 30, 1980Assignee: Eastman Kodak CompanyInventor: John C. Wilson
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Patent number: 4210565Abstract: Ambient or low-temperature curable solutions or aqueous dispersions of (1) a polymer containing units polymerized from a monomer mixture of (a) from about 0.25% to about 30% by weight of a polymerizable aldehyde, and (b) at least one copolymerizable mono-ethylenically unsaturated monomer, with (2) a curing agent selected from the group of dicarboxylic acid bis-hydrazides, dicarboxylic acid bis-hydrazones, and acrylic oligomers and low molecular weight acrylic solution polymers containing a plurality of pendant hydrazide or hydrazone groups. The solutions or dispersions are useful as general industrial coatings, maintenance coatings, furniture and appliance coatings, heavy transportation coatings, automobile refinishes and plastics coatings.Type: GrantFiled: February 2, 1979Date of Patent: July 1, 1980Assignee: Rohm and Haas CompanyInventor: William D. Emmons
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Patent number: 4209604Abstract: Polymerizable acrylic monomers, and anaerobic adhesives which contain such monomers, wherein the acrylic monomers contain internal chain unsaturation in addition to terminal acrylic unsaturation.Type: GrantFiled: January 7, 1976Date of Patent: June 24, 1980Assignee: Estech Specialty Chemicals CorporationInventor: Gerhardt P. Werber
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Patent number: 4191838Abstract: Acryloxy- and methacryloxy-alkyl-propanals and a process for their manufacture by esterifying the corresponding .beta.-hydroxyalkylpropanals with acrylic acid and methacrylic acid, respectively, in the presence of an acid esterification catalyst and of an inert diluent.Type: GrantFiled: May 1, 1978Date of Patent: March 4, 1980Assignee: BASF AktiengesellschaftInventors: Franz Merger, Friedrich Towae, Erich Penzel