Hydroxyl Group Patents (Class 526/318.42)
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Publication number: 20100120924Abstract: The present invention provides a novel base material for a dry solid dispersion, a solid dispersion containing the base material, and a composition containing the dispersion; the solid dispersion of the present invention, which contains a poorly soluble component with improved dissolvability, can be obtained by mixing a polyvinyl alcohol-based copolymer, as a base material for the dry solid dispersion, with a poorly soluble component, and then heating it.Type: ApplicationFiled: April 15, 2008Publication date: May 13, 2010Applicant: DAIDO CHEMICAL CORPORATIONInventors: Shunji Uramatsu, Akane Kida, Hitoshi Shinike, Toshinobu Uemura, Yoshinobu Fukumori
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Patent number: 7709052Abstract: Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.Type: GrantFiled: October 9, 2003Date of Patent: May 4, 2010Assignee: BASF AktiengesellschaftInventors: Rainer Dyllick-Brenzinger, Roland Ettl, Franca Tiarks, Ulrich Riebeling
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Patent number: 7649067Abstract: The present invention relates to a vinyl ester based polymer latex composition obtainable by free radical emulsion polymerization in substantial absence of a protective colloid and in the presence of no or small amounts of a surfactant, and to a process of making the same. The invention further pertains to a dispersion incorporating said vinyl ester based polymer latex composition, products comprising said dispersion, and various uses of the dispersion.Type: GrantFiled: October 19, 2005Date of Patent: January 19, 2010Assignee: Wacker Polymers, L.P.Inventors: Helmut Zecha, Holger Kuenstle
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Patent number: 7638563Abstract: The polycarboxylic acid concrete admixture of the present invention exhibits properties such as decreasing the concrete viscosity, improving the slump-retaining ability, and suppressing bleeding water, and is improved in the ability to cement compositions or the like. The above-mentioned polycarboxylic acid concrete admixture comprises a polycarboxylic acid polymer containing a polyalkylene glycol in the side chain, wherein the polycarboxylic acid polymer is obtained by polymerizing monomer components containing an alkyl (meth)acrylate monomer and a specific polyalkylene glycol unsaturated monomer and unsaturated carboxylic acid (salt) monomer, and it has a specific weight average molecular weight.Type: GrantFiled: May 7, 2004Date of Patent: December 29, 2009Assignee: Nippon Shokubai Co., Ltd.Inventors: Tomotaka Nishikawa, Toru Uno, Hirokazu Yamamoto, Yukiko Nishikawa, Hiromichi Tanaka, Tomiyasu Ueta
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Publication number: 20090298722Abstract: This invention provides acrylate polymers having at least two different ester groups. The ester groups are selected from the following: a) an aralkyl group; b) a linear alkylether group; c) a polyethoxylated alkylaryl group; and d) a polyethoxylated alkyl group, with the proviso that at least one of said ester groups is selected from b) or d). Processes for preparing such polymers and processes for breaking emulsions with these acrylate polymers are also provided.Type: ApplicationFiled: May 29, 2009Publication date: December 3, 2009Applicant: BJ SERVICES COMPANYInventor: Harold L. Becker
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Patent number: 7514205Abstract: An antireflection film-forming composition having excellent coatability, capable of significantly inhibiting production of fine microbubbles and capable of forming an antireflection film with a sufficiently decreased standing-wave effect, and having excellent solubility in water and alkaline developers is provided. The composition comprises a polymer having at least one polymerization unit with a hydroxyl group-containing organic group on the side chain, preferably a copolymer having at least one recurring unit of the following formula (2) and/or at least one recurring unit of the following formula (3) and at least one recurring unit of the following formula (4), and/or a salt thereof: wherein R1 and R2 represent a hydrogen atom, a fluorine atom, or a monovalent organic group, m is an integer of 1-20, and A represents a divalent coupling means.Type: GrantFiled: March 16, 2006Date of Patent: April 7, 2009Assignee: JSR CorporationInventors: Nakaatsu Yoshimura, Keiji Konno, Norihiro Natsume
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Publication number: 20090082535Abstract: To provide: a (meth)acrylic acid copolymer, which exhibits excellent chelating ability, dispersibility, and gel resistance, and can be preferably used in various applications, for example, in a dispersant such as an inorganic pigment and a metal ion, a detergent builder, and a water treatment agent such as a corrosion inhibitor and a scale inhibitor; and a method for producing the (meth)acrylic acid copolymer; and an application thereof.Type: ApplicationFiled: March 30, 2006Publication date: March 26, 2009Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Masato Nakano, Shigeru Yamaguchi, Koji Fukuhara
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Patent number: 7417102Abstract: A coating composition comprises at least one material dispersed in a vinyl or acrylic polymer, wherein the vinyl or acrylic polymer comprises (a) one or more anchor group monomer units (a) having an ionizable or active hydrogen functionality or a functionality that forms a covalent bond with the dispersed material, wherein the ionizable functionality is other than a carboxylic acid group in which the carbonyl carbon is separated from the closest ethylenically unsaturated carbon by at least four atoms and the anchor group monomer units (a) are other than those having polyoxyalkylene groups; (b) about 5% to about 45% by weight of one or more stabilizer monomer units (b) having a carboxylic acid group in which the carbonyl carbon is separated from the closest ethylenically unsaturated carbon by at least four atoms, having polyoxyalkylene groups, having gamma-hydroxy carbamate or beta-hydroxy carbamate groups, and combinations thereof; and (c) up to about 50 percent by weight of aromatic monomer units.Type: GrantFiled: March 21, 2006Date of Patent: August 26, 2008Assignee: BASF CorporationInventors: Walter H. Ohrbom, Nicholas Caiozzo, Sergio Balatan, Zenon Paul Czornij, Clair J. Certo, Janice E. Echols, Paul J. Harris
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Patent number: 7326525Abstract: Disclosed herein are top anti-reflective coating polymers used in a photolithography process, methods for preparing the anti-reflective coating polymer, and anti-reflective coating compositions comprising the disclosed anti-reflective coating polymers. The top anti-reflective coating polymers are used in immersion lithography for the fabrication of a sub-50 nm semiconductor device. The top anti-reflective coating polymer is represented by Formula 1 below: wherein R1, R2 and R3 are independently hydrogen or a methyl group; and a, b and c represent the mole fraction of each monomer, and are independently in the range between about 0.05 and about 0.9. Because the disclosed top anti-reflective coatings are not soluble in water, they can be used in immersion lithography using water as a medium for the light source. In addition, since the top anti-reflective coatings can reduce the reflectance from an underlayer, the uniformity of CD is improved, thus enabling the formation of ultrafine patterns.Type: GrantFiled: March 16, 2005Date of Patent: February 5, 2008Assignee: Hynix Semiconductor Inc.Inventor: Jae-chang Jung
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Patent number: 7256246Abstract: The present invention relates to compositions comprising poly-HEMA having a peak molecular weight between about 25,000 and about 100,000 , preferably between 25,000 and 80,000 and a polydispersity of less than about 2 to less than about 3.8 respectively and covalently bonded thereon, at least one cross-linkable functional group. The present invention further relates to low polydispersity poly-HEMA suitable for making the crosslinkable prepolymers, processes for functionalizing and purifying said poly-HEMA to form said crosslinkable prepolymers, viscous solutions made from said crosslinkable prepolymers, hydrogels made from said viscous solutions and articles made from said crosslinkable polymers, hydrogels and viscous solutions.Type: GrantFiled: November 8, 2004Date of Patent: August 14, 2007Assignee: Johnson & Johnson Vision Care, IncInventors: Ture Kindt-Larsen, Per Wolff, Jens-Erik Sørensen, Frederik Resen Steenstrup, Hèlène Rossignol, Frank F. Molock
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Patent number: 7183368Abstract: Disclosed is a chemical-amplification negative-working photoresist composition used for photolithographic patterning in the manufacture of semiconductor devices suitable for patterning light-exposure to ArF excimer laser beams and capable of giving a high-resolution patterned resist layer free from swelling and having an orthogonal cross sectional profile by alkali-development. The characteristic ingredient of the composition is the resinous compound which has two types of functional groups, e.g., hydroxyalkyl groups and carboxyl or carboxylate ester groups, capable of reacting each with the other to form intramolecular and/or intermolecular ester linkages in the presence of an acid released from the radiation-sensitive acid generating agent to cause insolubilization of the resinous ingredient in an aqueous alkaline developer solution.Type: GrantFiled: November 8, 2004Date of Patent: February 27, 2007Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Hideo Hada, Takeshi Iwai, Satoshi Fujimura
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Patent number: 7147994Abstract: Disclosed herein are a top anti-reflective coating polymer used in a photolithography process, a method for preparing the anti-reflective coating polymer, and an anti-reflective coating composition comprising the anti-reflective coating polymer. The disclosed top anti-reflective coating polymer is used in immersion lithography for the fabrication of a sub-50 nm semiconductor device. The top anti-reflective coating polymer is represented by Formula 1 below: wherein R1, R2 and R3 are independently hydrogen or a methyl group; and a, b and c represent the mole fraction of each monomer, and are in the range between 0.05 and 0.9. The top anti-reflective coating formed using the anti-reflective coating polymer is not soluble in water and can be applied to immersion lithography using water as a medium for a light source. Since the disclosed top anti-reflective coating can reduce the reflectance from an underlayer, the uniformity of CD is improved, thus enabling the formation of an ultrafine pattern.Type: GrantFiled: January 11, 2005Date of Patent: December 12, 2006Assignee: Hynix Semiconductor Inc.Inventor: Jae-chang Jung
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Patent number: 7125944Abstract: It is an object of the present invention to provide a cement admixture capable of exhibiting high cement dispersing ability at low addition levels, in particular capable of displaying excellent initial dispersing ability and dispersion retaining ability even in a high water reducing ratio range, and a cement composition in which this admixture is used.Type: GrantFiled: May 28, 2002Date of Patent: October 24, 2006Assignee: Nippon Shokubai Co., Ltd.Inventors: Akihiko Yamashita, Hiromichi Tanaka, Tsuyoshi Hirata, Toru Uno, Yoshiyuki Onda
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Patent number: 7030177Abstract: The present invention provides a powdery dispersant for hydraulic compositions, which is excellent in pumping before drying and in pressure resistance and humidity resistance, which comprises one or more copolymers obtained by polymerizing a specific vinyl monomer (1) such as an ethylenically unsaturated carboxylic acid derivative having a polyoxyalkylene group with a specific vinyl monomer (b) such as (meth)acrylic acid etc., wherein the average number of C2-4 oxyalkylene groups or oxystyrene groups added is 45 to 150, (a)/[(a)+(b)]×100 ranges from 15 to 45 (mol-%), and at least a part of the copolymers are monovalent or polyvalent metal salts.Type: GrantFiled: April 22, 2004Date of Patent: April 18, 2006Assignee: Kao CorporationInventors: Daisuke Shibai, Kyoichi Shirota
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Patent number: 7030178Abstract: The present invention provides a powdery dispersant for hydraulic compositions, which is excellent in pumping before drying and in pressure resistance and humidity resistance, which comprises one or more copolymers obtained by polymerizing a specific vinyl monomer (1) such as an ethylenically unsaturated carboxylic acid derivative having a polyoxyalkylene group with a specific vinyl monomer (b) such as (meth)acrylic acid etc., wherein the average number of C2-4 oxyalkylene groups or oxystyrene groups added is 45 to 150, (a)/[(a)+(b)]×100 ranges from 15 to 45 (mol-%), and at least a part of the copolymers are monovalent or polyvalent metal salts.Type: GrantFiled: June 22, 2004Date of Patent: April 18, 2006Assignee: Kao CorporationInventors: Daisuke Shiba, Kyoichi Shirota
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Patent number: 6927267Abstract: A pressure-sensitive adhesive polymer comprising a reaction product of a C1 to C20 alkyl (meth)acrylate, an ethylenically unsaturated carboxylic acid, a C2 to C8 hydroxyalkyl (meth)acrylate, a vinyl aromatic, optionally a ethylenically unsaturated monomer containing sulfonic acid, and optionally a vinyl ester of a carboxylic acid. The pressure-sensitive adhesive polymer can provide adhesion and cohesion in a temperature range from ?30° C. to 50° C. for the All-temperature pressure-sensitive adhesive market.Type: GrantFiled: March 7, 2002Date of Patent: August 9, 2005Assignee: BASF AGInventors: Luis Varela de la Rosa, Timothy P Sanborn, Dieter Urban
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Patent number: 6900279Abstract: A composition that includes a non-gelled copolymer that includes one or more residues of a first polymerizable ethylenically unsaturated monomer containing a pendant amide, ester or carboxylic acid group. The nearest neighboring monomer residues of the majority of the first monomer residues along the copolymer molecule do not contain pendant carbonyl functional groups. The amide, ester or carboxylic acid group of the residues of the first monomer are the post polymerization transesterification, transamidification or hydrolysis reaction product of a C1-C4 alkyl ester group in the unreacted first monomer with a compound selected from amine functional compounds and hydroxy functional compounds. The reacted copolymer is substantially free of cyclical structures resulting from the transesterification, transamidification or hydrolysis reaction. The compositions may be thermosetting compositions useful in multi-layer composite coatings.Type: GrantFiled: January 21, 2003Date of Patent: May 31, 2005Assignee: PPG Industries ohio, Inc.Inventors: Simion Coca, Gregory J. McCollum, James B. O'Dwyer, Edward R. Coleridge, Steven V. Barancyk
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Patent number: 6855785Abstract: A heat-curable composition comprising (I) at least one constituent whose molecule comprises on average (A) at least one functional group containing at least one bond which may be activated by means of heat and/or actinic radiation, and/or (B) at least one reactive functional group which is able to undergo thermal crosslinking reactions with groups of its own kind and/or with complementary reactive functional groups, with the proviso that there are always groups (A) and (B) in the composition; said constituent excluding the polyurethane dispersion synthesized from aliphatic polyisocyanates, compounds containing isocyanate-reactive functional groups and containing bonds that may be activated with actinic radiation, low molecular mass aliphatic compounds containing isocyanate-reactive functional groups, compounds containing isocyanate-reactive functional groups and dispersing functional groups, neutralizing agents for the dispersing functional groups, blocking agents for isocyanate groups, and/or compounds cType: GrantFiled: August 22, 2001Date of Patent: February 15, 2005Assignee: BASF Coatings AGInventors: Hubert Baumgart, Uwe Meisenburg, Karl-Heinz Joost
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Patent number: 6846892Abstract: The present invention relates to compositions comprising poly-HEMA having a peak molecular weight between about 25,000 and about 100,000, preferably between 25,000 and 80,000 and a polydispersity of less than about 2 to less than about 3.8 respectively and covalently bonded thereon, at least one cross-linkable functional group. The present invention further relates to low polydispersity poly-HEMA suitable for making the crosslinkable prepolymers, processes for functionalizing and purifying said poly-HEMA to form said crosslinkable prepolymers, viscous solutions made from said crosslinkable prepolymers, hydrogels made from said viscous solutions and articles made from said crosslinkable polymers, hydrogels and viscous solutions.Type: GrantFiled: February 14, 2003Date of Patent: January 25, 2005Assignee: Johnson & Johnson Vision Care, Inc.Inventors: Ture Kindt-Larsen, Per Wolff, Jens-Erik Sørensen, Frederik Resen Steenstrup, Hélène Rossignol, Frank F. Molock
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Publication number: 20040266965Abstract: A method for making hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate. Also disclosed are coatings, films, hydrogels, cosmetic compositions, dermatological compositions, pressure sensitive adhesives containing the hydrophilic homopolymers or copolymers of poly 2-hydroxyethylmethacrylate. Further disclosed are methods of coating substrates with the hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate and hydrophilic pressure sensitive adhesives.Type: ApplicationFiled: March 12, 2004Publication date: December 30, 2004Applicant: Avery Dennison CorporationInventors: Daniel L. Holguin, H. Paul Barker, Kenneth S. Lin
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Publication number: 20040167309Abstract: The monomer of the present invention is represented by the following Formula 1: 1Type: ApplicationFiled: March 1, 2004Publication date: August 26, 2004Inventors: Nobuya Saegusa, Akihiro Honma, Hajime Yamada, Takamasa Kawashima, Shojiro Kuwahara
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Patent number: 6774192Abstract: The present invention provides: a photosensitive resin composition, which can form uniform coating films having higher coating film strength without causing surface contamination, decrease of evenness of coating films, decrease of film thickness, and coloring by decomposition in heat treatment of subsequent steps, and has good sensitivity of exposure. The photosensitive resin composition comprises a lactone-ring-containing polymer (A) as an essential component, wherein: the lactone-ring-containing polymer (A) is obtained by carrying out polymerization of comonomers and lactonization at the same time wherein the comonomers include a 2-(hydroxyalkyl)acrylate ester and an acidic-group-containing monomer; and the lactone-ring-containing polymer (A) is obtained by almost quantitatively carrying out lactonization of a 2-(hydroxyalkyl)acrylate ester structural unit.Type: GrantFiled: December 2, 2001Date of Patent: August 10, 2004Assignee: Nippon Shokubai Co., Ltd.Inventors: Hideo Asano, Kenichi Ueda, Minoru Yamaguchi, Masatoshi Yoshida, Tomomasa Kaneko, Shingo Kataoka
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Patent number: 6743880Abstract: The present invention provides a method for the preparation of hydrophilic water insoluble, gel-free copolymers of 2-hydroxyethyl methacrylate and at least one of acrylic acid or methacrylic acid, and 2-hydroxyethyl methacrylate, 4-hydroxybutyl acrylate and acrylic or methacrylic acid, where the copolymers are prepared in a solution of water and alcohol using monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities up to about 0.15% by weight and substantially in the absence of a chain transfer agent. The copolymers are convertible to water soluble copolymers by pH adjustment. The invention also provides a method for the preparation of a copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate, and a homopolymer of 2-hydroxyethyl methacrylate in a solution of water and either a monoalcohol or a polyhydric alcohol.Type: GrantFiled: April 26, 2002Date of Patent: June 1, 2004Assignee: Avery Denison CorporationInventor: Daniel L. Holguin
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Patent number: 6706836Abstract: A method for the preparation of gel-free poly 2-hydroxyethyl methacrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight into alcohol, polymerizing the 2-hydroxyethyl methacrylate to form a polymerization mixture, and removing the alcohol. Hydrophilic pressure sensitive adhesives are provided by adding polyethylene glycol to the polymerization mixture prior to removing the alcohol.Type: GrantFiled: March 31, 2000Date of Patent: March 16, 2004Assignee: Avery Dennison CorporationInventors: Daniel L. Holguin, H. Paul Barker, Ivan S. P. Lee, Kenneth S. Lin
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Patent number: 6653427Abstract: A method for the preparation of gel-free poly 2-hydroxyethyl methacrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight into a solution of alcohol and water and polymerizing. The present invention also provides a method for the preparation of gel-free homopolymer of 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent in an alcohol or in solution of alcohol and water. The present invention also provides a method for the preparation of gel-free copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight with monomeric 4-hydroxybutyl acrylate into a solution of alcohol and water.Type: GrantFiled: January 10, 2001Date of Patent: November 25, 2003Assignee: Avery Dennison CorporationInventor: Daniel L. Holguin
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Publication number: 20030170563Abstract: The photosensitive polymer includes a first monomer which is norbornene ester having C1 to C12 aliphatic alcohol as a substituent, and a second monomer which is maleic anhydride. A chemically amplified photoresist composition, containing the photosensitive polymer, has an improved etching resistance and adhesion to underlying layer materials, and exhibits wettability to developing solutions.Type: ApplicationFiled: March 10, 2003Publication date: September 11, 2003Inventors: Dong-Won Jung, Sang-Jun Choi, Si-Hyeung Lee, Sook Lee
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Patent number: 6617373Abstract: Ophthalmic lenses, such as corneal contact lenses, include a lens body made of a composition including a lens body made of a composition including a first crosslinked polymer material which is water swellable, and a second polymeric material, other than the first material, selected from water soluble polymeric materials, water swellable polymeric materials and mixtures thereof. The second material is physically immobilized by the first material. Such lenses provide increased water retention and/or increased water content and/or increased modulus and/or reduced friction which increases lens wearer comfort. Compositions and methods for providing such lenses and compositions are also provided.Type: GrantFiled: December 13, 2001Date of Patent: September 9, 2003Assignee: Ocular Sciences, Inc.Inventors: Jiri Sulc, Zuzana Krcova
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Publication number: 20030100694Abstract: The present invention provides a method for the preparation of hydrophilic water insoluble, gel-free copolymers of 2-hydroxyethyl methacrylate and at least one of acrylic acid or methacrylic acid, and 2-hydroxyethyl methacrylate, 4-hydroxybutyl acrylate and acrylic or methacrylic acid, where the copolymers are prepared in a solution of water and alcohol using monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities up to about 0.15% by weight and substantially in the absence of a chain transfer agent. The copolymers are convertible to water soluble copolymers by pH adjustment. The invention also provides a method for the preparation of a copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate, and a homopolymer of 2-hydroxyethyl methacrylate in a solution of water and either a monoalcohol or a polyhydric alcohol.Type: ApplicationFiled: April 26, 2002Publication date: May 29, 2003Applicant: Avery Dennison CorporationInventor: Daniel L. Holguin
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Patent number: 6566472Abstract: Binder formulations based on aqueous polymer dispersions having a minimum film-forming temperature of below 10° C. and comprising at least one binder polymer P in the form of an aqueous dispersion comprising at least one anionic emulsifier and at least one nonionic emulsifier.Type: GrantFiled: August 17, 2000Date of Patent: May 20, 2003Assignee: BASF AktiengesellschaftInventors: Roland Baumstark, Stefan Kirsch, Rolf Dersch, Johannes Dobbelaar, Michael Melan
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Patent number: 6552140Abstract: An air-activatable polymerisable composition useful, in the field of adhesives, sealants, surface coatings, moulding resins and composite matrices, comprises: a) at least one free-radically polymerisable monomer, b) an activator system for effective polymerisation of the free-radically polymerisable monomer, said activator system comprising at least one auto-oxidisable compound which is a beta diketone, c) a soluble ionic salt, particularly a transition metal salt, d) and a weak acid or a latent weak acid, with the proviso that the composition does not contain a peroxide, or a peroxide precursor which produces peroxide in the absence of air, or any ingredient which is a significant source of radicals in the absence of air.Type: GrantFiled: March 16, 2001Date of Patent: April 22, 2003Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Rory B. Barnes
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Patent number: 6531564Abstract: A water-soluble polymeric adhesion promoter is represented by the following formula (I): wherein R is a hydrogen atom, a hydroxyl group or a lower alkyl group having 1 to 4 carbon atoms, and m and k are numbers selected such that m/k is in the range from about 1/0.001 to about 1/0.1, and such that that the polymer (I) has a weight average molecular weight of about 3,000 to about 600,000.Type: GrantFiled: June 28, 2002Date of Patent: March 11, 2003Assignee: Samsung Electronics Co., Ltd.Inventors: Se Yong Oh, Chan Eon Park, Sang Min Song
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Publication number: 20030040593Abstract: The monomer of the present invention is represented by the following Formula 1: 1Type: ApplicationFiled: April 16, 2002Publication date: February 27, 2003Inventors: Nobuya Saegusa, Akihiro Honma, Hajime Yamada, Takamasa Kawashima, Shojiro Kuwahara
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Publication number: 20020193542Abstract: The photosensitive polymer includes a first monomer which is norbornene ester having C1 to C12 aliphatic alcohol as a substituent, and a second monomer which is maleic anhydride. A chemically amplified photoresist composition, containing the photosensitive polymer, has an improved etching resistance and adhesion to underlying layer materials, and exhibits wettability to developing solutions.Type: ApplicationFiled: August 15, 2002Publication date: December 19, 2002Inventors: Dong-Won Jung, Sang-Jun Choi, Si-Hyeung Lee, Sook Lee
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Patent number: 6455654Abstract: A water-soluble polymeric adhesion promoter is represented by the following formula (I): wherein R is a hydrogen atom, a hydroxyl group or a lower alkyl group having 1 to 4 carbon atoms, and m and k are numbers selected such that m/k is in the range from about 1/0.001 to about 1/0.1, and such that that the polymer (I) has a weight average molecular weight of about 3,000 to about 600,000.Type: GrantFiled: January 18, 2001Date of Patent: September 24, 2002Assignee: Samsung Electronics Co., Ltd.Inventors: Se Yong Oh, Chan Eon Park, Sang Min Song
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Patent number: 6437027Abstract: The present invention relates to a process for producing a powdery dispersant for preparing hydraulic compositions, which process includes adding an reducing agent to a solution predominantly containing a polycarboxylate polymer compound having a polyalkylene glycol chain, drying the resultant mixture, and pulverizing the dried product; the resultant powdery dispersant for preparing hydraulic compositions; and a hydraulic composition containing the dispersant. According to the present invention, there can be provided a powdery dispersant for preparing a hydraulic composition, which has excellent fluidity and dispersibility. The dispersant can be added to cement in advance.Type: GrantFiled: July 27, 2000Date of Patent: August 20, 2002Assignee: Taiheiyo Cement CorporationInventors: Hirotaka Isomura, Hiroshi Hayashi, Kazuhisa Tsukada, Koichi Soeda, Kenjiro Makino, Masaki Takimoto
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Publication number: 20020106568Abstract: The present invention provides: a photosensitive resin composition, which can form uniform coating films having higher coating film strength without causing surface contamination, decrease of evenness of coating films, decrease of film thickness, and coloring by decomposition in heat treatment of subsequent steps, and has good sensitivity of exposure. The photosensitive resin composition comprises a lactone-ring-containing polymer (A) as an essential component, wherein: the lactone-ring-containing polymer (A) is obtained by carrying out polymerization of comonomers and lactonization at the same time wherein the comonomers include a 2-(hydroxyalkyl)acrylate ester and an acidic-group-containing monomer; and the lactone-ring-containing polymer (A) is obtained by almost quantitatively carrying out lactonization of a 2-(hydroxyalkyl)acrylate ester structural unit.Type: ApplicationFiled: December 2, 2001Publication date: August 8, 2002Applicant: Nippon Shokubai Co., Ltd.Inventors: Hideo Asano, Kenichi Ueda, Minoru Yamaguchi, Masatoshi Yoshida, Tonomasa Kaneko, Shingo Kataoka
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Patent number: 6426373Abstract: Among other things, a photopolymerizing one-component dental material is prepared, containing: 1) 80-10 weight-% of at least one polyfunctional urethane methacrylate and/or at least one polyfunctional urethane acrylate, 2) 10-30 weight-% of at least one polyfunctional acrylate resin, 3) 10-30 weight-% of at least one reactive thinner, 4) 0-20 weight-% of bis-GMA and/or at least one ethoxylated bisphenol-A-dimethacrylate, 5) 0-10 weight-% of at least one filler, 6) 0-1 weight-% of at least one photoinitiator, and. 7) 0-1 weight-% of at least one color pigment.Type: GrantFiled: August 12, 1999Date of Patent: July 30, 2002Assignee: Heraeus Kulzer GmbH & Co. KGInventors: Frank Stange, Albert Erdrich, Novica Savic, Teresa Puchalska
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Patent number: 6410655Abstract: A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C., and satisfy the following conditions (1) to (3): (1) the emulsion polymer forming the outermost phase contains from 1 to 20 mass % of an ethylenic unsaturated monomer having at least one of a polyethylene glycol chain and a polypropylene glycol chain, (2) at least one phase of inner phases from the outermost phase of the different phase structure emulsion particles comprises an emulsion polymer of an ethylenic unsaturated monomer having a glass transition temperature of from 30° C. to 110° C., and (3) the binder has a minimum film-forming temperature of at most 10° C.Type: GrantFiled: December 8, 2000Date of Patent: June 25, 2002Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Masayoshi Okubo, Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
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Patent number: 6372815Abstract: Ophthalmic lenses, such as corneal contact lenses, include a lens body made of a composition including a lens body made of a composition including a first crosslinked polymer material which is water swellable, and a second polymeric material, other than the first material, selected from water soluble polymeric materials, water swellable polymeric materials and mixtures thereof. The second material is physically immobilized by the first material. Such lenses provide increased water retention and/or increased water content and/or increased modulus and/or reduced friction which increases lens wearer comfort. Compositions and methods for providing such lenses and compositions are also provided.Type: GrantFiled: April 18, 2000Date of Patent: April 16, 2002Inventors: Jiri Sulc, Zuzana Krcova
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Patent number: 6369143Abstract: A radiation-sensitive polymer and a chemical amplification resist composition based on the polymer, which can be easily controlled in sensitivity by regulating the content and kind of the carboxylic acid-grafted norbornene derivatives in the matrix polymer and is superior in adherence to substrate and dry etch resistance, so that it can be formed into resist patterns improved in transparency, photosensitivity and resolution by use of KrF or ArF excimer lasers. The polymer is represented by the formula I: wherein, X is an acid-dissociable grafted norbornene derivative selected from the group consisting of the formulas II and III; Y is a carboxylic acid-grafted norbornene derivative represented by the formula IV, and l, m, n and o each are a repeating number not more than 0.5, satisfying the condition that l+m+n+o=l and 0.4≦o≦0.Type: GrantFiled: June 21, 1999Date of Patent: April 9, 2002Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Joo-Hyeon Park, Seong-Ju Kim, Dong-Chul Seo, Sun-Yi Park
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Patent number: 6361768Abstract: A novel hydrophilic ampholytic polymer synthesized by reacting polymerizable amino and carboxy functional ethylenically unsaturated monomers, together with a non-ionic hydrophilic monomer, to provide a polymer having a glass transition temperature (Tg) above about 50° C., and optionally hydrophobic monomer(s), and cross-linking monomer(s). The copolymer is precipitated from a polymerization media which includes a suitable organic solvent. The resulting copolymer is in the form of a fine powder, with submicron particle size. As such it is suitable for use as a thickener or rheology modifier in personal care formulations, such as shampoo, conditioner, and the like, as a bioadhesive, and for other pharmaceutical applications.Type: GrantFiled: December 29, 1998Date of Patent: March 26, 2002Assignee: PMD Holdings Corp.Inventors: Ramiro Galleguillos, Jodi A. Budrevich, Joseph A. Chiarelli, Harinath B. Bathina, Zahid Amjad
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Patent number: 6310159Abstract: The present invention refers to a paper surface sizing composition comprising a copolymer having: a) structural units derived from ethylenically unsaturated hydrocarbons; structural units derived from monomers selected from esters of ethylenically unsaturated mono-carboxylic acids, half-esters of ethylenically unsaturated dicarboxylic acids, allylethers and vinylethers and mixtures thereof; optionally c) structural units derived from ethylenically unsaturated monomers selected from monocarboxylic acids as well as salts and amides thereof, dicarboxylic acids as well as salts, amides and half-amides thereof, and cyclic anhydrides and imides of dicarboxylic acids and mixtures thereof; and optionally d) structural units derived from alkyl or amino-substituted alkyl acrylates or methacrylates with the proviso, that if no structural units c) are present, the structural units b) are derived from monomers selected from half esters of ethylenically unsaturated dicarboxylic acids.Type: GrantFiled: January 19, 1999Date of Patent: October 30, 2001Assignee: The Dow Chemical CompanyInventors: Jürgen Eiffler, Roger Carlsson, Jürgen Hermanns, Stephen Oliver
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Publication number: 20010020076Abstract: The present invention provides a production process for a terminal-end-stabilized glyoxylic acid (salt)-based polymer, which process enables to reduce the amount of the polymerization solvent, as recovered or removed after the end of the polymerization (before the start of the hydrolysis) or after the end of the hydrolysis, without lowering the production efficiency. The production process for a terminal-end-stabilized glyoxylic acid (salt)-based polymer comprises the step of polymerizing a monomer component including a glyoxylic acid ester in order to produce the terminal-end-stabilized glyoxylic acid (salt)-based polymer, wherein a terminal end stabilizer is used as a reaction medium of the polymerization.Type: ApplicationFiled: February 22, 2001Publication date: September 6, 2001Applicant: Nippon Shokubai Co., Ltd.Inventors: Takuya Saeki, Akihiko Kanzaki, Junichi Nakamura, Yoshikazu Fujii, Shigeru Yamaguchi
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Patent number: 6254804Abstract: An oxygen scavenger composition, for use in or with plastics materials, includes a polymer or oligomer having at least one cyclohexene group or functionality. The composition produces only low levels of volatile or extractable (from a plastics material in which it is incorporated) products as a consequence of oxygen scavenging.Type: GrantFiled: December 20, 2000Date of Patent: July 3, 2001Assignee: Cryovac, Inc.Inventors: Andrew E. Matthews, Craig Depree
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Patent number: 6232419Abstract: The present invention provides a novel class of polymer antiscalants which are polymers comprising a 1,2-dihydroxy-3-butene monomer unit and at least one monomer unit derived from the groups consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit —(CH2—CH═CH—CH2—O)—.Type: GrantFiled: November 9, 1999Date of Patent: May 15, 2001Assignee: Nalco Chemical CompanyInventors: Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
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Patent number: 6194531Abstract: A method for producing a cross-linked polymer manifesting a high absorption capacity and having a small content of soluble component by a convenient and expeditious process with high productivity is provided. An absorbent resin such that disposable diapers and other products incorporating the absorbent resin manifest outstanding qualities and a method for the production of the absorbent resin are proposed.Type: GrantFiled: June 3, 1997Date of Patent: February 27, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Takumi Hatsuda, Toru Yanase, Yasuhiro Fujita, Kazuki Kimura